RECEIVED RX929!

24 June 2003 

Mr. Steve Trent 

Fluor Hanford Inc. 

825 Jadwin Ave. 

Richland, WA 99352 

Subject: Contract No. 630 

Analytical Data Package 

Dear Mr. Trent: 

OOGOOSS 

JUN 2W3 

RECEIVED 

Enclosed are the hard copy analytical reports for the batch numbertfraction indicated 

(marked X) in the following table: 

LvLI Batch # 

Date Received 5-02-03 

._......._................._ _......_...._._...__ .............._._...... -- 

# SamDIe3 1 6 

Pest1PCB I X 

Herbicides I X 

The electronic data deliverable (EDD) will be emailed shortly. If you have any 

questions, please don't hesitate to contact me at (610) 280-3012. 

Project Manager 

208 Welsh Pool Road • Exton, PA 1 9341-1 31 3 • (610) 280-3000 • Fax (610) 280-3041 

X 

st 

RX929! 

AUG 1 1 

EDMC

0 

Lionville Laboratory, Inc. 

VOA ANALYTICAL DATA PACKAGE FOR 

TNUHANFORD F03-006 H2194 

DATE RECEIVED: 05/02/03 LVL LOT # :0305L329 

CLIENT ID LVL # MTX PREP # COLLECTION EXTR/PREP ANALYSIS 

B16W79 001 S 03LVJ055 04/28/03 N/A 05/16/03 

B16W80 002 -S 03LVJ055 04/28/03 N/A 05/16/03 

B16W81 003 S 03LVJ055 04/29/03 N/A 05/16/03 

B16W82 004 S 03LVJ055 04/29/03 N/A 05/16/03 

B16W83 005 S 03LVJ055 04/29/03 N/A 05/16/03 

B16W90 006 S 03LVJ055 04/28/03 N/A 05/16/03 

B16W90 006 MS S 03LVJ055 04/28/03 N/A 05/16/03 

B16W90 006 MSD S 03LVJ055 04/28/03 N/A 05/16/03 

LAB QC: 

VBLKSX MB1 S 03LVJ055 N/A N/A 05/16/03 

VBLKSX MB1 BS S 03LVJ055 N/A N/A 05/16/03 

JUN 2003 N 

RECEIVED

Client: TNU-HANFORD B03-006 W.O.#: 11343-606-001-9999-00 

LVL #: 0305L329 Date Received: 05-02-2003 

SDG/SAF # H2194/B03-006 

GC/MS VOLATILE 

Six (6) soil samples were collected on 04-28,29-2003. 

The samples and their associated QC samples were analyzed according to criteria set forth in Lionville 

Laboratory OPs based on SW 846 Method 8260B for TCL volatile target compounds on 05-16-2003. 

The following is a summary of the QC results accompanying these sample results and a description of 

any problems encountered during their analyses: 

All results presented in this report are derived from samples that met LvLI's sample acceptance 

policy. 

2. Samples were analyzed within holding time. 

3. Non-target compounds were not detected in the samples. 

4. All surrogate recoveries were within EPA QC limits. 

5. All matrix spike recoveries were within EPA QC limits. 

6. All blank spike recoveries were within EPA QC limits. 

The method blank contained the common laboratory contaminants Methylene Chloride and 

Acetone at levels less than the CRQL. 

8. Internal standard area and retention time criteria were met. 

9. "I certify that this sample data package is in compliance with SOW requirements, both 

technically and for completeness, other than the conditions detailed above. Release of the data 

contained in this hard-copy data package has been authorized by the Laboratory Manager or a 

designee, as verified by the following signature." 

f,.r J. Michael Taylor Da"te 

President 

Lionville Laboratory Incorporated 

son\group\data\voa\mu-hanfo d\0305.329.doc 

The insults presented in this report relate only to the analytical testing and conditions of the samples at receipt and during storage. All pages of this report arc integral parts of the 

analytical data. Therefore, this report should only be reproduced in its entirety of 1 8 pages. 

208 Welsh Pool Road • Exton, PA 19341-1313 a (610) 280-3000 • Fax (610) 280-3041

DATA QUALIFIERS 

GLOSSARY 

U = Compound was analyzed for but not detected. The associated numerical value is the estimated 

sample quantitation limit which is included and corrected for dilution and percent moisture. 

J = Indicates an estimated value. This flag is used under the following circumstances: 1) when 

estimating a concentration for tentatively identified compounds (TICS) where a 1:1 response is 

assumed; or 2) when the mass spectral data indicate the presence of a compound that meets the 

identification criteria but the result is less than the specified detection limit but greater than zero. 

For example, if the limit of detection is 10 ug/L and a concentration of 3 ug/L is calculated, it is 

reported as 3J. 

B = This flag is used when the analyte is found in the associated blank as well as in the sample. It 

indicates possible/probable blank contamination. This flag is also used for a TIC as well as for 

a positively identified TCL compound. 

E = Indicates that the compound was detected beyond the calibration range and was subsequently 

analyzed at a dilution. 

D = Identifies all compounds identified in an analysis at a secondary dilution factor. 

I = Interference. 

NQ = Result qualitatively confirmed but not able to quantify. 

A = Indicates that a TIC is a suspected aldol-condensation product. 

N = Indicates presumptive evidence of a compound. This flag is only used for tentatively identified 

compounds (TICS), where the identification is based on a mass spectral library search. It is applied 

to all TIC results. For generic characterization of a TIC, such as chlorinated hydrocarbon, the N 

code is not used. 

X = This flag is used for a TIC compound which is quantified relative to a response factor generated 

from a daily calibration standard (rather than quantified relative to the closest internal standard). 

Y Additional qualifiers used as required are explained in the case narrative. 

mmz\10.94\g1oss.bna 

3

ABBREVIATIONS 

BS = 

BSD = 

MS = 

MSD = 

DL = 

NA 

DF = 

NR = 

SP, Z = 

mmzV 0-94\gloss.bna 

LYLI 

GLOSSARY 

Indicates blank spike in which reagent grade water is spiked with the CLP matrix spike solutions 

and carried through all the steps in the method. Spike recoveries are reported. 

Indicates blank spike duplicate. 

Indicates matrix spike. 

Indicates matrix spike duplicate. 

Suffix added to sample number to indicate that results are from a diluted analysis. 

Not Applicable. 

Dilution Factor. 

Not Required. 

Indicates Spiked Compound.

TECHNICAL FLAGS FOR MANUAL INTEGRATION 

Manual quan modifications or integrations are performed routinely to improve the data 

quality for a variety of technical reasons. Documentation of these modifications should be 

clear and concise. The following "flags" are used to indicate the technical reasons for quan 

modifications: 

MP - Missed Peak: manually added peak not found by automatic 

quan program. 

PA - Peak Assignment: quan report was changed to reflect correct 

peak assignment. 

RI - Routine Integration: routine integrations are performed for 

some analytes that are consistently integrated improperly by the 

automatic integration programs. Examples are the 

dichlorobenzene isomers on the VOA packed column and 

benzo(b)fluoranthene/benzo(k) flu oranthene which are poorly 

resolved on the BNA column. 

SP - Split Peak: the automatic integration improperly split the peak; 

a manual integration was performed to get the correct area. 

CB - Coe lution/Background: peak was manually integrated to 

eliminate contribution from coeluting compounds, background 

signal, or other interference. 

PI - Proper Integration: a peak with poor or inconsistent integration 

(e.g., excessive tail) was properly integrated manually. 

RTW 21-21-035/A48/93

RFW Batch Number: 0305L329 


Volatiles by GC/MS, HSL List 

Report Date: 05/30/03 11:39 

Client: TNOBANFORD F03-006 H2194 Work Order: 11343606001 Page: la 

Cust ID: B16W79 B16W80 B16W81 B16W82 B16W83 B16W90 

Sample RFW#: 001 002 003 004 005 006 

Information Matrix: SOIL SOIL SOIL SOIL SOIL SOIL 

D.F.: 1.04 1.11 1.14 1.04 1.11 1.02 

Units: ug/Kg ug/Kg ug/Kg ug/Kg ug/Kg ug/Kg 

Toluene-d8 98 $ 101 % 100 % 102 % 100 $ 101 $ 

Surrogate Bromofluorobenzene 104 % 106 % 106 % 107 $ 107 % 109 

Recovery 1,2-Dichloroethane-d4 105 % 103 % 110 % 108 $ 112 % 114 

Chloromethane 11 U 12 U 12 U 11 U 12 U 11 U 

Bromomethane 11 U 12 U 12 U 11 U 12 U 11 U 

Vinyl Chloride 11 U 12 U 12 U 11 U 12 U 11 U 

Chloroethane 11 U 12 U 12 U 11 U 12 U 11 U 

Methylene Chloride 6 U 6 U 2 JB 2 JB 3 JB 3 JB 

Acetone 13 B 7 JB 8 JB 9 JB 10 JB 7 JB 

Carbon Disulfide 6 U 6 U 6 U 6 U 6 U 6 U 

1,1-Dichloroethene 6 U 6 U 6. U 6 U 6 U 6 U 

1,1-Dichloroethane 6 U 6 U 6 U 6 U 6 U 6 U 

1,2-Dichloroethene (total) 6 U 6 U 6 U 6 U 6 U 6 U 

Chloroform 6 U 6 U 6 U 6 U 6 U 6 U 

1,2-Dichloroethane 6 U 6 U 6 U 6 U 6 U 6 U 

2-Butanone 11 U 12 U 12 U 11 U 12 U 11 U 

1,1,1-Trichloroethane 6 U 6 U 6 U 6 U 6 U 6 U 

Carbon Tetrachloride 6 U 6 U 6 U 6 U 6 U 6 U 

Bromodichloromethane 6 U 6 U 6 U 6 U 6 U 6 U 

1,2-Dichloropropane 6 U 6 U 6 U 6 U 6 U 6 U 

cis-1,3-Dichloropropene 6 U 6 U 6 U 6 U 6 U 6 U 

Trichloroethene 6 U 6 U 6 U 6 U 6 U 6 U 

Dibromochloromethane 6 U 6 U 6 U 6 U 6 U 6 U 

1,1,2-Trichloroethane 6 U 6 U 6 U 6 U 6 U 6 U 

Benzene 6 U 6 U 6 U 6 U 6 U 6 U 

Trans-1,3-Dichloropropene 6 U 6 U 6 U 6 U 6 U 6 U 

Bromoform 6 U 6 U 6 U 6 U 6 U 6 U 

4-Methyl-2-pentanone 11 U 12 U 12 U 11 U 12 U 11 U 

2-Hexanone 11 U 12 U 12 U 11 U 12 U 11 U 

Tetrachloroethene 6 U 6 U 6 U 6 U 6 U 6 U 

1,1,2,2-Tetrachloroethane 6 U 6 U 6 U 6 U 6 U 6 U 

Toluene 6 U 6 U 6 U 6 U 6 U 6 U 

•= Outside of EPA CLP QC limits.

RFW Batch Number: 0305L329 Client: TNUHANFORD F03-006 H2194 Work Order, 11343606001 Paa • lb 


Chlorobenzene 

Ethylbenzene 

RFW#: 

Xylene (total) 

N-butylbenzene 

*= Outside of EPA CLP QC limits. 

001 002 003 004 005 006 

6 U 6 U 6 U 6 U 6 U 6 U 

6 U 6 U 6 U 6 U 6 U 6 U 

6 U 6 U 6 U 6 U 6 U 6 U 

6 U 6 U 6 U 6 U 6 U 6 U 

6 U 6 U 6 U 6 U 6 U 6 U


Volatiles by GC/MS, HSL List Report Date: 05/30/03 11:39 to 

RFW Batch Number: 030SL329 Client: TNUHANFORD F03-006 H2194 Work Order: 11343606001 Page: 2a 

Cust ID: B16W90 B16W90 VBLKSK VBLKSS BS 

Sample RFW#: 006 MS 006 MSD 03LVJ055-MB1 03LVJ055-MB1 

Information Matrix: SOIL SOIL SOIL SOIL 

D.F.: 1.06 1.00 1.00 1.00 

Units: ug/Kg ug/Kg ug/Kg ug/Kg 

Toluene-d8 102 % 104 % 100 % 94 % 

Surrogate Bromofluorobenzene 112 % 114 % 102 % 96 % 

Recovery 1,2-Dichloroethane-d4 123 % 122 % 94 % 92 % 

Chloromethane 11 U 10 U 10 U 10 U 

Bromomethane 11 U 10 U 10 U 10 U 

Vinyl Chloride 11 U 10 U 10 U 10 U 

Chloroethane 11 U 10 U 10 U 10 U 

Methylene Chloride 4 JB 3 JB 2 J 2 JB 

Acetone 8 JB 8 JB 6 J 6 JB 

Carbon Disulfide 6 U 5 U 5 U 5 U 

1,1-Dichloroethene 107 % - 120 % 5 U 97 % 

1,1-Dichloroethane 6 U 5 U 5 U 5 U 

1,2-Dichloroethene (total) 6 U 5 U 5 U 5 U 

Chloroform 6 U 5 U 5 U 5 U 

1,2-Dichloroethane 6 U 5 U 5 U 5 U 

2-Butanone 11 U 10 U 10 U 10 U 

1,1,1-Trichloroethane 6 U 5 U 5 U 5 U 

Carbon Tetrachloride 6 U 5 U 5 U 5 U 

Bromodichloromethane 6 U 5 U 5 U 5 U 

1,2-Dichloropropane 6 U 5 U 5 U 5 U 

cis-1,3-Dichloropropene 6 U 5 U 5 U 5 U 

Trichloroethene 90 % 100 % 5 U 99 % 

Dibromochloromethane - 6 U 5 U 5 U 5 U 

1,1,2-Trichloroethane 6 U 5 U 5 U 5 U 

Benzene 86 % 95 % 5 U 91 % 

Trans-1,3-Dichloropropene 6 U 5 U 5 U 5 U 

Bromoform 6 U 5 U 5 U 5 U 

4-Methyl-2-pentanone 11 U 10 U 10 U 10 U 

2-Hexanone 11 U 10 U 10 U 10 U 

Tetrachloroethene 6 U 5 U 5 U 5 U 

1,1,2,2-Tetrachloroethane 6 U 5 U 5 U 5 U 

Toluene 93 % 104 % 5 U 90 

•= Outside of EPA CLP QC limits. 

====f1

RFW Batch Number: 0305L329 Client: TNOHANFORD F03-006 H2194 Work Order: 11343606001 Page: 2b 

Cust ID: B16W90 B16W90 VBLRSX VBLRSX BS 

Chlorobenzen 

Ethylbenzene 

%ylene (total) 

N- butylbenzene 


RFW#: 006 MS 006 MSD 03LVJ055-MB1 03LVJ055-MB1 

94 % . 107 % 5 U 94 % 

6 U 5 U 5 U 5 U 

6 U 5 U 5 U 5 U 

6 U 5 U 5 U 5 U 

6 U 5 U 5 U 5 U

Lionville Laborato ry Use Only Custody Transfer Record/Lab Work Request Page-.of--^- 

FIELD PERSONNEL: COMPLETE ONLY SHADED AREAS 110h Nflf fABOFAJORVINC 

Client ::Efn I- JAQnR(3(r—^ 

Est Final Proj. Safnplhlg Date 

C= O 

Refrigerator# 

#!Type Container 

Liquid 

'x Z 

Project # 

solid 

Project ContactlPhone # 

Lionville Laboratory ory rWest 

Manager Q^ 

OC Elzxc Del —c^' 

TAT 250 CkX 

volume 

Proaerveuvec 

Liquid 

Solid 

— 

ORGANIC 

_ 

INORG 

_ — — 

Date Rec'd 

MATRIX 

CODES: 

S- son. 

SE - Sedime 

^'c?-f_-1 

ID 

5- t b- o D 

Date Due -•c-i-r=r^ 7'" r (.t 

matrix 

OC 

Client lDlDeacription 

C(h3sisn 

ANALYSES —^. 

ÔUESTED 

_ 

MaWx Co^lected Collected 

¢ 

O 

Q 

m 

m m 

a a 

£ 

= 

1 

m 

Z 

O 

Lionville Laboratory Use Only 

C 

j 

nt 

SO - Show 

MS MSD 

U 

H 

C- 

H 

W- Water 

0- Oil 

A - Air 

DS - Drum 

Sokds 

DL - Drum 

Liquids 

L- EP/TCLP 

Leachato 

WI- Wipe 

X. Other 

cIn 

Al 

3 

. ^. 

F - Fish 

1 3 

DATEIREVISIONS: Lionville Laboratory Use Only 

Special S Dec Instructions: 'jxA^ 1"f"PNr, c. C- 5-14-0 1 17 Pw h: b - Ib -ds 

Samples were/ Tamper Resislar4 Seal was: 

p /^ 

or 

\ F(")^-("X')(/} S (d+ 2041 —s . Outer 

401. F}dJ A^ Af 13_ y! ^. ^^. Cr• ya 

Hand De Delivered Pack gen or N 

( f 

^-r 

I e yy^^ S Airbill # 

3 (45 , N z P^ • 56 S# LC : C(, )

FH-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F"6-62 I Page 1 of 1 

Collector 

Johansen/Pop e/P6ster 

Project Designation 

200-PW-2 /200-PW4 OU - B orehole Soil Sampling 

Ice Chest No. C^-p L OS 

/C 

Shipped To fztzx 0f 

POSSIBLE SAMPLE HAZARDS/RE 

Special Handling and/or Storage 

22 c 

SAMPLE ANALYSIS 

Company Contact Telephone No. 

LC Hulstram 373-3928 

Sampling Location 

216-A-37 (C4106); (12.5'-157 

Field Logbook No. 

HNF-N-3361 

COA 

117504ESIO 

OEM Property No. ^y .O 

24 V 

Preservation 

Type of Container 

No. of Con ta iner(s) 

Volume 

Sample No. Matrix • Sample Date Sample Time 

B16W79 SOIL & G3 

P ro ject Coordinator 

TRENT, Sl Price Code $N Data Turnarouo 

SAF No. 

F03-006 

Method of Shipment 

Federal Express 

COW 4C Cool 4C - cDat 4C rime Nmc 

aG 

aG aG aG a 

I I 1 I I 

120ml, 60WL 120ml, 60•l, 60mL 

Clumnim NOLNO3- ailaGnsse- ssitem(1)' Td -M 

Hex - 71% 3512 413.1 speeid 

Air Quality q 

Bill of Lading/Air Bill No. 0295 PC - 

N OF POSSESSION Sign/Print Names SPECIAL INSTRUCTIONS 

b7. s3 

Relinquished B ved Fro DatNCmte liar 2o ved B/Stored In 

R. 

r«^ I 37q2-0 

DaWTimeu 

^ 

L l Z8o3 1 6 / 5 

^.3 . f 4 r 

mpon both Iwasene and diesel range compounds fran W1PH-D analysts. 

•• The labommry ism 

Relmq ' ed By/Rctmved Fm Da&T— f ) 

oo Received By/Stored N Daterime th (Ij-i'ccMire.m 09 °- °990 T mI Sr fzaroo Tbori 

8tZ OJ 

(Thl ' +a^ . r.^.__ r.._ _ 

elinquished By ved FAmm /^^/t ^ Dat&T= 

Sic j E l daQa 10 Recdved By/Sum:d D&VUTime 

F — x 

di q By 

t{f 

ved From Dardfime 

S t 6 3 0,7 

Recd In Dmd['ime 

LJ-03 01 Y, 

Relinquished By/Removed F•tan Duelfime Received By/ In Dat.Tunc 

Relinquished By/Removed From Daterr me Received By/Stored In DausTime 

a\v^\ 

Personnel not available to 

relinquish samples onl the 3728 

Ref # .L^ on 

1-1--IQ3 

LABORATORY R-rived By - Title Date/fime 

SECTION 

FINAL SAMPLE Disposal Method Dispmed By DatcTime 

DISPOSITION 

SHI-EE-011 (03101/2002) 

45 Days 

Ma tr ix 

s-Sau 

sE d s.es 

ro-sau 

n-suaF 

oDu 

DL,V.Lalr b 

DI' Drvm Lipii4s 

w w, 

uw^ 

v-v pw^.. 

X. 

i

FR-Central Plateau 

00-PW-2/200-PW-4 OU - Borehole So il Samp: 

Chest No.`g L 

I POSSIBLE SAMPLE 

By/Removed Kom 

By/Remotved From 

av/Removed From 

96 0 Sc 


Samp le No. datrix 

BISWSO SOIL 

LABORATORY Received By 

SECTION 


I y, 1 tgC 

DaWrme rtes 

, 5I o3 

CHAIN OF CUSTODY/SAMPLE ANALYSIS I 


LC Hulstrom 373-3929 

Sampling Loca tion 

216-A-37 (C4106); (17.5'-20) 

Field Logbook No. COA 

HNF-N-3361 

Time 

117504ESIO 

ORaite Property No. /1 o r{ 6 Z i! 

Preserva tion 

Type of Con tainer a0 

No. of Container(s) 

Volume 

Cod 4C t4CJ Cod Coal4C Cod CCWC 4 Nwu 

t 1 1 I 

aG 

120m1, 60mL 120mL 60ML 

Hn -71 96 1 353.2 1 413.1 

tE UEST 

Project Coordinator 

rRENT, 

Price 

SJ 

Code 8N 

3AF No. 

Air Quality q 

?03-M 

detbod of Shipment 


F03-006-63 Page 1 of 1 

Bi ll 

of Ladiag/Alr Bill Na Cyr 0_5?, L 

Ttltu -3D 

161 

Data Turnaround 

45 Days 

Names 

atd 

SPECIAL INSTRUCTIONS 

^^ 

I 

° The labo 

Matrix 

ra 3719 8 

,d In 

LI 

7 

lf^ 

tjs 

Datdfime 

..........'.,A` 

repan both kerosene and diesel range compmmdi 

from WIPH-D analysis. - — 

'1u N k 

.^ 

tory is to 

Yrdl 

saad;s. 

sn a a. 

wads 

s el6a3NeWmi / /OC) 

-237 `/2 } 

W.W. 

Detdfurw 

( ) 

s s 

n1 In 

N 

1n 

:d N 

^. 

DmNfime 

Q 4 r. 

Dmerfime 

DatrJfime 


relinquish samples from the 3728 

Ref # Mon 

FINAL SAMPLE Diepoml Method 

DISPOS 

Disposed By Datdfime 

IT 

ION 

;HI-EE-011 (03/012002) 

Title 

Dardfime 

V 

V-V 

z.a

FR-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-64 Page ! of i 

Collector Company Contact Telephone No. Project Coordinator 

Johan sen/Pope/P fister LC Hulshom 373-3928 TRENT, SJ 

Project Designa ti 

on Sampling Location SAY N o. 

200-PW-2 1100-PW-4 OU - Borehole Soil Sampling 216-A-37 (C4106); (27.5'-30 1) F03-W6 

Price Code 8N Data Turnaround 

Air Quality p 

Ice Chest No.rnrn p 

Field Logbook No. COA Method of Shipment 

Fk C, ( d S,6 

(40, HNF-N-3361 117504ESIO Federal Expre ss 

Shipped To e eoe Ottsite Property No. /I ..j mi 

Bill of Lading/Air Bill No. ^^.^ O ^^ J 

POSSIBLE SAMPLE HA7A"S/REMARKS 


Preservation 



Volume 

l, O ^G ti zz 

Coda Ceaa Coda Haae Neae 

aG aG aG aG 

I I 1 1 1 

120ML 60m]. 120mL 60mi. 6UDL 

chmm:w 

Ha . 7196 

N07/N07- 

157.2 

QI4 7" 

ell.! 

Tddim w S.= t SAMPLE ANALYSIS 

) 

speeiY 

d l 

^1v 

d 7 . 

Sample Na Matrix • Sample Date Sample Time 

B16W81 SOIL IUUL) 

P 

1 i,(.TD 

45 Days 

CHAIN OF POSSESSION 

y/R F 

Ref wished ByMemoved From 

I 

Da 

Sign/Print Namesrp^ ime 

Received By/Stored ID 

(^ 

Y• V 

ime 1 Ya- Received B tomd N 

1 

vJf e 

D tdTime / t j 

?^ Q3 

SPECIAL INSTRUCTIONS /^rp-- ` D d) 

- 

upon both kemseoe and diesel range compounds from WIPH-D analysis. 

^g y `` n =' ` !/L Z/v3 

•' The labuatary is b 

Matrix • 

s-sdt 

W-y 

so-sdd 

s SW, 

oww.e, 

Relinquishedved From, 

ay 

teliIoquishrA BY/R ved From 

.J-r r^ 

R nq ' ted B ved Fmm 

^ 

RelinquishedBy/Removed From 

( 

1 e 

178tdrime 

Date rime 

Ihtdrime 

l o 

Received 0 /Sto d In 

Dmetrime 

Received By/Slmed N^ 

Receiv ZBtl o In 

DaWfime 

2. -u3 O 

Received N Dwerrime 

//cx 

- 


relinquish samples from the3728 

Ref#^0n_^ 

Ds-D 

Tn 

wo-wyc 

truwn 

v veµ+awe 

x•aa 

3 !loo ^! 0 3 DL•D,w I.iryN[ 

LABORATORY Received By Tide DatdFime 

SECTION 

FINAL SAMPLE Disposal MMDd D is posed By Date/rube 

DISPOSITION 

BHI-EE-011 (0310112002) 

9 wU

FH-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-65 I P29t 1 of 


Johansen/Pope/Pfister LC Hulstrom 373-3928 TRENT, SJ 

Project Designation Sampling Location SAX No. 

200-PW-2200-PW-4 OU - Borehole Sod Sampling 216-A-37 (C4106), (37.5'4(y) F03-006 

G 

Ice Chest N o. / Field Logbook No, COA Method of Shipment 

Q 

O S 

Y HNF-N-3361 117504ESIO Federal Express 

Shipped To

FH-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS RE UEST F03-006-66 Page t of t 

Collector 

Johansen/Pope/Pfister 

Project Designa tion 

200-PW-2/100-PW4 OU - Borehole Soil Sampling 

Ice Cheat G 

No.(F. 9 6 0,5'.0 

Shipped To 

POSSIBLE SAMPLE HAZARDS/REMA 






216-A-37 (C4106); (47.5'-50') 

Fie 

f N 336 No. I5 04ES IO 

Olfsite Property No. 

Prese rva tion 

/) v 



TRENT, S1 Price Code 8N 

SAF No. 

F03.006 

Method 

Federal E pr 

ess 

Air Quality q 

-C ZZ Q Bill of Lading/Air Bill No. 5& 

30 03/7 C-- 

Cod 4C COW 4C Caul 4C Nape Nom 

aG 

No. of Container(s) I 

Volume 


B16W83 SOIL () 0do 

aG aG aG aG 

I 

120mL 60mL 120ML 60mL /60;Z— 

Chr 

Flat-7196 

NO2/NO3. 

351.1 

Oil&Crtram- 

411.1 

?4 

Seeinmi (I)ia 

Speed 

lnluv

FR-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-73 Pag< 1 of 1 


Johansen/Pope/Pftster LC Hulstrom 373-3929 TRENT, SJ 

Project Designation Sampling Location SAF No. 

200-PW-2200-PW-4 OU - Borehole Soil Sampling 216-A-37 (C4106); (17.5'-201 F03-006 

Ice Chest No. G / ` /' 

L^ C 


HNF-N-3361 117504ESIO Federal Express 

Shipped To /-e &2êg^4 -/*et Offsite Property No. A_6 6 3 0 ZZ c 

!T 




Pratrvatloo 

Type of Con tainer 


Volume 

Samp le No. Ma tr ix Sample Date Samp le Time 

B16W90 SOIL Zed' (s Y to 

Cod 4C Cod 4C Cm 4C N. wee 

eG aG aG aG 

I 1 I 1 1 

120mL 60mL 120ml. 60ml, 60mL 

atrmuum N077NO3 . 0ilk Greau- Seeh®(1)ie Tritium-10 

Ha- 7196 353.2 413.1 Sprdd 

t y 

P riCe Code 8N 

Air Quality q 

Bill of Lading/Air Bill No. d;E- os p ^- 

Da Tur 

Data oarouo 

45 Days 

77 

2 L n; Matrix' 

1 


emoved F e/Time 

Sigo/Print Names 

Received By/Stored N 

3725s 

Date rime 

Z$ 03 Y,S 

SPECIAL INSTRUCTIONS q 

-'e 

The laboratory is te 

report 1e both kerosene and diesel range compounds from WFPH-D analysis..yy^r 

Sow 

Ic[^ -7 

moed FroDa[drime Re ce ived By/St ored In DatNfim< 

1 

,, 

4- 37 I „ 3 al6o WSJ La" Sio3 >/oU ^ ` `^/^y^`3 

^7 

Relinquished 1 By(R m Daerrime /too Received By/Stored DalNrime 

a-^'r 

M.D. swim 

d t7 3 f'-' G 7^ T'r uww. 

wirer°„ 

R inq ' By/R ved F WI-Wire 

ro m Daelfime Received^7i/ ^bL N DaHfime 


Re linquished By/Re nnoved F 

relinquish ampless rota the 3728 

i h 

Ref # 013 /= ^'G 

ro m DetrJTime Received ByIS[ d In Datdrime 

Daidrime 

Re linquished By/Removed F rom Daterrime Received By/Stored In __ 

LABORATORY Received By Title Dae?ime 

SECTION 

FINAL SAMPLE Disposal Merited D is posed By Datdflme 

DISPOSITION 

BHI-EE-011 (03/0111002) 

v-vâwe 

x-owe

IM 

FH-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-74 l ragc a — _ 

Collector 

Company Contact Telephone No, Project Coordinator 

Johansen/Pope/Pfister - 

LC Hulstm m 373-3928 TRENT, S] 

Project Designation Sampling Loca tion - SAF No. 

200-PW-2/200-PW-4 OU - Bo rehole Soil Sampling 216-A-37 (C4106); (0 3) F03-006 

Ice Chat No. 

J(0 

0 Field Logbook No. COA Method of Shipment 

HNF-N-3361 117504FS10 Federal Express 

Shipped To 405103 JZre ON Offsite Proper ty No. /l a, 3 O z--7 0 

/TCJ [i 

POSSIBLE SAMPLE FIAZARDS/REMARKS 



Preserva tion 


No. of Coutsiner(s) 

Volume 


WSW SOIL 'Z (S O 4 

Cad 4C Cod eC 

aG aG 

I 

I 

60ML 250mL 

Pesticides - Cmura 

amt Ifeddcide, 

Frnetst 

Bill of Lading/Air Bill No.S S1r 

Price Code 8N Data Turnarou 

Air Quality E] 45 Days 

N OF POSSESSION Sign/Print Nam" SPECIAL INSTRUCTIONS Matrix 

emoved F m Clatdrime Received By/Slored In Date/1'ime 

Pr 372$ °fL`d o,3 4q,5 

' uished B /Removed F m Date/rime Received By/Stored In Datdrime 

1H 17D 5103 1100 d 5 i o3 /loo 

Relinquished By/Removed 4mm DawTime Received By/Swled N Daterrime 

Rel u' Byemuved From Datrnime 

^ 

Relinquished By/Removed .. 

From 

Date/Time 

Q 

OU /CG 

Received / ore In Dale?ime 

Receive t eel In 

--;-0 Datefrime 

Relinquished By/Rcmowd From Date/rime Received By/Smred N DaneTime 

) - 

\ajom39283 

to 

Peôope\ scot suet 

Samples I I ^^ 

i -y 

LABORATORY Received By Title Date/Tin a 

SECTION 

FINAL SAMPLE 

DISPOSITION 

BHI-EE-011 (0310111002) 

Disposal Method 

tevivic, 

(tef N 

on 

Disposed By 

D.Wrime 

ys l 

anbtl 

v-sxdc 

w "'° 

A-" 

os-oN. soi.a 

DL- nnw Liqîtl, 

w Wi, 

x-aM

I 

LIONTVILLE LABORATORY INCORPORATED 

SAMPLE RECEIPT CHECKLIST 

DENT: " NLt Hwn rr) 

urchasc Order/Project: 1 

DATE: S 

1^. 

SOWN !Release H: —F03-00(, 

Zamtory 

SM #: 

C3^s L 3 2 

VOTE: ALL ENTRIES MARKED "NO" MUST BE EXPLAINED IN THE COMMENT SECTION 

1. Custody seals on coolers or shipping yes 13 No q u see Com—n—nnt 

container intact, signed and dated?, 

2. Outside of coolers or shipping containers are Yes q No O NIA O see Comment N 

free from damage? 

3. Airbill it recorded? yes q No q N/A O see Comment N 

4. All expected paperwork received (coc and 

other client specific: historical data, 

alpha bete or other screening data as 

applicable)? (paperwork sealed in plastic 

bag and taped to inside lid) 

^Xyts 

q No q NIA O see Comment N 

S. Semple containers are$inrad? `'C^' yes q No q N/A D see Comment N 

6. Custody seals on sample containers intact, R Yes ONO O N/A O we Comment N 

signed and dated? 

7. All samples on coc received? 61 es q No q NIA q see Comment N 

S. All sample label information matches coc? es ONO q N/A- 77 see Comment N 

9. Laboratory QC samples designated on coc? (q yes 13 No g'WA q see Comment N 

(QC stickers placed on bottles?) 

10. Shipment meets LvLI Sample Acceptance y es ONO q N/A O sec Comment N 

Policy?' (identify all bo ttles not within 

policy. See reverse side for policy) 

11. Where applicable, bar code labels are q Yes q No ),N/A q gee Comment N 

affixed to coc? 

12. coc signed and dated? 

Ills ONO q NIA q see Comment N 

13. coc will be faxed or emailed to client? / Q y es•. q No q N/A q see Comment f 

14. Project Manager/Client contacted / 

concerning discrepancies? (name/deie) 

q Yes q No L lA q see comment N 

Cooler N / temp (°C) and Comments: 

EeG q(,, -Us Co 

Laboratory Sample Custodian: In ^^ 

Laboratory Project Manager: ^^(l rye^ ray r I


BNA ANALYTICAL DATA PACKAGE FOR 


DATE RECEIVED: 05/02/03 LVL LOT # :03051,329 


B16W79 001 S 03LE0575 04/28/03 05/14/03 06/07/03 

B16W80 002 S 03LE0575 04/28/03 05/14/03 06/07/03 

B16W80 002 MS S 03LE0575 04/28/03 05/14/03 06/07/03 

B16W80 002 MSD S 03LE0575 04/28/03 05/14/03 06/07/03 

B16W81 003 S 03LE0575 04/29/03 05/14/03 06/07/03 

B16W82 004 S 03LE0575 04/29/03 05/14/03 06/07/03 

B16W83 005 S 03LE0575 04/29/03 05/14/03 06/08/03 

B16W90 006 S 03LE0575 04/28/03 05/14/03 06/08/03 

LAB QC: 

SBLKTK MB1 S 03LE0575 N/A 05/14/03 06/07/03 

SBLKTK MB1 BS S 03LE0575 N/A 05/14/03 06/07/03

Client: TNU-HANFORD F03-006 W.O.#: 11343-606-001-9999-00 

LVL #: 0305 1,329 Date Received: 05-02-2003 

SDG/SAF # H2194/F03-006 

SEMIVOLATILE 


The samples and their associated QC samples were extracted according to Lionville Laborato ry OPs based 

on method 3550 on 05-14-2003 and analyzed according to c riteria set forth in Lionville Laboratory OPs 

based on SW 846 Method 8270C for client specified Semivolatile t arget compounds on 06-07,08-2003. 

The following is a summary of the QC results accomp anying the sample results and a description of any 

problems encountered during their analyses: 

All results presented in this repo rt are derived from samples that met LvLI's sample accept ance 

policy. 

2. Samples were extracted outside of holding time as per client instructions because the analysis has 

been added later; however, samples were analyzed within required holding time. 

3. Non-target compounds were detected in the samples. 

4. All surrogate recove ries were within EPA QC limits. 

5. All matrix spike recoveries were within EPA QC limits. 

6. All blank spike recoveries were within EPA QC limits. 

7. Inte rn al standard area and retention time c riteria were met. 

8. Manual integrations are performed according to OP 21-06A-125 to produce quality data with the 

utmost integ rity. All manual integrations are required to be technically valid and properly 

documented. Appropriate technical flags are defined in the Glossary ("Technical Flags For M anual 

Integration"). 

9. I certify that this sample data package is in compli ance with SOW requirements, both technically 

and for completeness, other th an the conditions detailed above. Release of the data contained in 

this hard-copy data package has been autho rized by the Laborato ry Manager or a designee, as 

verified by the following signature. 

iZ^ 7 

y^J. Michael Taylor Date 

President 


som\gomp\data\bna\mu-hanford-0305-329.doc 

The results presented in this report relate only to the analy tical testing and conditions of the samples at receipt and du ri ng storage. All pages of this report are integral pans of the analytical 

data. Therefore, this repo rt should only be reproduced in its en tirety of 2 7 pages. 

208 Welsh Pool Road • Exton, PA 19341-1313 • (610) 280-3000 • Fax (610) 280-3041


GLOSSARY 

U = Compound was analyzed for but not detected. The associated numerical value is the estimated 

sample quantitation limit which is included and corrected for dilution and percent moisture. 

3 = Indicates an estimated value. This flag is used under the following circumstances: 1) when 

estimating a concentration for tentatively identified compounds (TICS) where a 1:1 response is 

assumed; or 2) when the mass spectral data indicate the presence of a compound that meets the 

identification criteria but the result is less than the specified detection limit but greater than zero. 

For example, if the limit of detection is 10 ug/L and a concentration of 3 ug/L is calculated, it is 

reported as 33. 

B This flag is used when the analyze is found in the associated blank as well as in the sample. It 

indicates possible/probable blank contamination. This flag is also used for a TIC as well as for 

a positively identified TCL compound. 

E = Indicates that the compound was detected beyond the calibration range and was subsequently 

analyzed at a dilution. 

D = Identifies all compounds identified in an analysis at a secondar y dilution factor. 

= Interference. 

NQ = Result qualitatively confirmed but not able to quantify. 

A = Indicates that a TIC is a suspected aldol-condensation product. 

N = Indicates presumptive evidence of a compound. This flag is only used for tentatively identified 

compounds (TICs), where the identification is based on a mass spectral library search. It is applied 

to all TIC results. For generic characterization of a TIC, such as chlorinated hydrocarbon, the N 

code is not used. 

X This flag is used for a TIC compound which is quantified relative to a response factor generated 

from a daily calibration standard (rather than quantified relative to the closest internal standard). 

Y = Additional qualifiers used as required are explained in the case narrative. 

mmz\10.94\gloss.bna 

Flo

ABBREVIATIONS 

BS = 

nl 1 

MS = 

MSD = 

DL = 

NA = 

DF = 

NR = 

SP, Z = 

m=\10./994\g1oss.bns 

L 

GLOSSARY 

Indicates blank spike in which reagent grade water is spiked with the CLP matrix spike solutions 

and carried through all the steps in the method. Spike recoveries are reported. 




Suffix added to sample number to indicate that results are from a diluted analysis. 



Not Required. 

Indicates Spiked Compound. 

91

TECHNICAL FLAGS FOR MANUAL INTEGRATION 

Manual quan modifications or integrations are performed routinely to improve the data 

quality for a variety of technical reasons. Documentation of these modifications should be 

clear and concise. The following "flags" are used to indicate the technical reasons for quan 

modifications: 

RFW 21-21-035/Aa/93 

YLI^ 

MP - Missed Peak: manually added peak not found by automatic 

quan program. 

PA - Peak Assignment: quan report was changed to re flect correct 

peak assignment. 

RI Routine Integration: routine integrations are performed for 

some analytes that are consistently integrated improperly by the 

automatic integration programs. Examples are the 

dichlorobenzene isomers on the VOA packed column and 

benzo(b)fluoranthene/benzo(k) flu oranthene which are poorly 

resolved on the BNA column. 

SP - Split Peak: the automatic integration improperly split the peak; 

a manual integration was performed to get the correct area. 

CB - Coelution/Background: peak was manually integrated to 

eliminate contribution from coeluting compounds, background 

signal, or other interference. 

PI - Proper Integration: a peak with poor or inconsistent integration 

(e.g., excessive tail) was properly integrated manually.


Semivolatiles by GC/MS, Special List 

Report Date: 06/12/03 11:133 

RFW Batch Number 030SL329 Client: TNUBANFORD F03-006 82194 Work Order: 11343606001 Page: la Q. 


Sample RFW#: 001 002 002 MS 002 MSD 003 004 


D.F.: 1.00 1.00 1.00 1.00 1.00 1.00 

Units: UG/KG UG/KG UG/KG UG/KG UG/KG UG/KG 

Nitrobenzene-d5 67 t 75 % 73 w 73 k 78 71 g 

Surrogate 2-Fluorobiphenyl 64 & 72 & 70 %, 71 t 72 t 71 

Recovery Terphenyl-d14 82 k 94 t 87 P6 88 w 98 !k 93 %; 

Phenol-d5 68 k 76 %; 73 t 74 g 78 t 74 %; 

2-Fluorophenol 59 t 67 % 66 k 67 67 t 63 !k 

2,4,6-Tribromophenol 63 W 69 t 72 %; 70 %r 60 k 67 %; 

Phenol 360 U 350 U 67 71 350 U 350 U 

bis(2-Chloroethyl)ether 360 U 350 U 350 U 350 U 350 U 350 U 

2-Chlorophenol 360 U 350 U 63 k 65 w 350 U 350 U 

1,3-Dichlorobenzene 360 U 350 U 350 U 350 U 350 U 350 U 

1,4-Dichlorobenzene 360 U 350 U 66 t 66 %, 350 U 350 U 

1,2-Dichlorobenzene 360 U 350 U 350 U 350 U 350 U 350 U 

2-Methylphenol 360 U 350 U 350 U 350 U 350 U 350 U 

2,2 1 -oxybis(1-Chloropropa ne) 360 U 350 U 350 U 350 U 350 U 350 U 

3- and/or 4-Methylphenol 360 U 350 U 350 U 350 U 350 U 350 U 

N-Nitroso-di-n-propylamine 360 U 350 U 67 %, 67 t 350 U 350 U 

Hexachloroethane 360 U 350 U 350 U 350 U 350 U 350 U 

Nitrobenzene 360 U 350 U 350 U 350 U 350 U 350 U 

Isophorone 360 U 350 U 350 U 350 U 350 U 350 U 

2-Nitrophenol 360 U 350 U 350 U 350 U 350 U 350 U 

2,4-Dimethylphenol 360 U 350 U 350 U 350 U 350 U 350 U 

bis(2-Chloroethoxy)methane 360 U 350 U 350 U 350 U 350 U 350 U 

2,4-Dichlorophenol 360 U 350 U 350 U 350 U 350 U 350 U 

1,2,4-Trichlorobenzene 360 U 350 U 67 1; 66 %; 350 U 350 U 

Naphthalene 360 U 350 U 350 U 350 U 350 U 350 U 

4-Chloroaniline 360 U 350 U 350 U 350 U 350 U 350 U 

Hexachlorobutadiene 360 U 350 U 350 U 350 U 350 U 350 U 

4-Chloro-3-methylphenol 360 U 350 U 67 k 67 t 350 U 350 U 

2-Methylnaphthalene 360 U 350 U 350 U 350 U 350 U 350 U 

Hexachlorocyclopentadiene 360 U 350 U 350 U 350 U 350 U 350 U 

2,4,6-Trichlorophenol 360 U 350 U 350 U 350 U 350 U 350 U 

2,4,5-Trichlorophenol 890 U 870 U 870 U 870 U 870 U 880 U 

*= outside of EPA CLP QC limits.

RFW Batch Number: 0305L329 Client: TNUHANPORD P03-006 82194 Work Order: 11343606001 Page: lb 


2-Chloronaphthalene 

2-Nitroaniline 

Dimethylphthalate 

Acenaphthylene 

2,6-Dinitrotoluene 


Acenaphthene 

2,4-Dinitrophenol 

4-Nitrophenol 

Dibenzofuran 


Diethylphthalate 

4-Chlorophenyl-phenylether 

Fluorene 


4,6-Dinitro-2-methylphenol 

N-Nitrosodiphenylamine (1) 

4-Bromophenyl-phenylether 

Hexachlorobenzene 

Pentachlorophenol 

Phenanthrene 

Anthracene 

Carbazole 

Di-n-butylphthalate 

Fluoranthene 

Butylbenzylphthalate 

3,31-Dichlorobenzidine 

Benzo(a)anthracene 

Chrysene 

bis(2-Ethylhexyl)phthalate 

Di-n-octyl phthalate 

Benzo(b)fluoranthene 

Benzo(k)fluoranthene 

Benzo(a)pyrene 

Indeno(1,2,3-cd)pyrene 

Dibenz(a,h)anthracene 

Benzo(g,h,i)perylene 

2-Butoxyethanol 

Benzyl alcohol 


RFW#: 001 002 002 MS 002 MSD 003 004 

360 U 350 U 350 U 350 U 350 U 350 U 

890 U 870 U 870 U 870 U 870 U 880 U 

360 U 350 U 350 U 350 U 350 U 350 U 

360 U 350 U 350 U 350 U 350 U 350 U 

360 U 350 U 350 U 350 U 350 U 350 U 

890 U 870 U 870 U 870 U 870 U 880 U 

360 U 350 U 67 %, 67 %, 350 U 350 U 

890 U 870 U 870 U 870 U 870 U 880 U 

890 U 870 U 70 W 61 W 870 U 880 U 

360 U 350 U 350 U 350 U 350 U 350 U 

360 U 350 U 80 %, 81 %, 350 U 350 U 

360 U 350 U 350 U 350 U 350 U 350 U 

360 U 350 U 350 U 350 U 350 U 350 U 

360 U 350 U 350 U 350 U 350 U 350 U 

890 U 870 U 870 U 870 U 870 U 880 U 

890 U 870 U 870 U 870 U 870 U 880 U 

360 U 350 U 350 U 350 U 350 U 350 U 

360 U 350 U 350 U 350 U 350 U 350 U 

360 U 350 U 350 U 350 U 350 U 350 U 

890 U 870 U 67 % 62 t 870 U 880 U 

360 U 350 U 350 U 350 U 350 U 350 U 

360 U 350 U 350 U 350 U 350 U 350 U 

360 U 350 U 350 U 350 U 350 U 350 U 

360 U 350 U 350 U 350 U 350 U 350 U 

360 U 350 U 350 U 350 U 350 U 350 U 

360 U 350 U 78 k 80 %, 350 U 350 U 

360 U 350 U 350 U 350 U 350 U 350 U 

360 U 350 U 350 U 350 U 350 U 350 U 

360 U 350 U 350 U 350 U 350 U 350 U 

360 U 350 U 350 U 350 U 350 U 350 U 

21 J 350 U 21 J 350 U 350 U 350 U 

360 U 350 U 350 U 350 U 350 U 350 U 

360 U 350 U 350 U 350 U 350 U 350 U 

360 U 350 U 350 U 350 U 350 U 350 U 

360 U 350 U 350 U 350 U 350 U 350 U 

360 U 350 U 350 U 350 U 350 U 350 U 

360 U 350 U 350 U 350 U 350 U 350 U 

360 U 350 U 350 U 350 U 350 U 350 U 

360 U 350 U 350 U 350 U 350 U 350 U 

360 U 350 U 350 U 350 U 350 U 350 U

RFW Batch Number: 030SL329 Client: TNUHANFORD F03-006 H2194 Work Order: 11343606001 Pape: lc 


RFW#: 001 002 002 MS 002 MSD 003 004 

Tributylphosphate 45 S 350 U 350 U 350 U 350 U 350 U 

(1) - Cannot be separated from Diphenylamine. *= Outside of EPA CLP QC limits. 

M


Semivolatiles by GC/MS, Special List Report Date: 06/12/03 11:1 

RFW Batch Number: 03051,329 Client: TNURANFOR.D P03-006 H2194 Work Order: 11343606001 Page: 2a 

Cust ID: B16W83 B16W90 SBLKTK SBLKTK BS 

Sample RFW#: 005 006 03LE0575-NB1 03LE0575-MB1 


D.F.: 1.00 1.00 1.00 1.00 

Units: UG/KG UG/KG UG/KG UG/KG 

Nitrobenzene-d5 78 Y 88 Y 76 Y 73 Y 

Surrogate 2-Fluorobiphenyl 74 Y 82 Y 72 Y 71 Y 

Recovery Terphenyl-d14 93 Y 104 Y 86 Y 92 Y 

Phenol-d5 75 Y 85 Y 77 Y 73 Y 

2-Fluorophenol 67 Y 74 Y 66 Y 66 Y 

2,4,6-Tribromophenol 66 Y 77 Y 67 Y 71 Y 

___________'___`___°_________________________ fl=====__===== fl=====__===== fl=====__=====f1=====__=====fl=====__=====f1 

Phenol 350 U 350 U 330 U 70 Y 

bis(2-Chloroethyl)ether 350 U 350 U 330 U 330 U 

2-Chlorophenol 350 U 350 U 330 U 65 Y 

1,3-Dichlorobenzene 350 U 350 U 330 U 330 U 

1,4-Dichlorobenzene 350 U 350 U 330 U 66 Y 

1,2-Dichlorobenzene 350 U 350 U 330 U 330 U 

2-Methylphenol 350 U 350 U 330 U 330 U 

2,2'-oxybis(1-Chloropropane) 350 U 350 U 330 U 330 U 

3- and/or 4-Methylphenol 350 U 350 U 330 U 330 U 

N-Nitroso-di-n-propylamine 350 U 350 U 330 U 69 Y 

Hexachloroethane 350 U 350 U 330 U 330 U 

Nitrobenzene 350 U 350 U 330 U 330 U 

Isophorone 350 U 350 U 330 U 330 U 

2-Nitrophenol 350 U 350 U 330 U 330 U 

2,4-Dimethylphenol 350 U 350 U 330 U 330 U 

bis(2-Chloroethoxy)methane 350 U 350 U 330 U 330 U 

2,4-Dichlorophenol 350 U 350 U 330 U 330 U 

1,2,4-Trichlorobenzene 350 U 350 U 330 U 68 Y 

Naphthalene 350 U 350 U 330 U 330 U 

4-Chloroaniline 350 U 350 U 330 U 330 U 

Hexachlorobutadiene 350 U 350 U 330 U 330 U 

4-Chloro-3-methylphenol 350 U 350 U 330 U 68 Y 

2-Methylnaphthalene 350 U 350 U 330 U 330 U 

Hexachlorocyclopentadiene 350 U 350 U 330 U 330 U 

2,4,6-Trichlorophenol 350 U 350 U 330 U 330 U 

2,4,5-Trichlorophenol 880 U 870 U 830 U 830 U 

*= Outside of EPA CLP QC limits.

RFW Batch Number • 0305L329 Client: TNOHANFORD F03-006 H2194 Work Order: 11343606001 Paae: 2b 

Cust ID: B16W83 B16W90 SBLKTK SBLKTK BS 

2-Chloronaphthalene 


Dimethylphthalate 

Acenaphthylene 



Acenaphthene 

2,4-Dinitrophenol 

4-Nitrophenol 

Dibenzofuran 


Diethylphthalate 

4-Chlorophenyl- phenylether 

4- Nitroaniline 

4,6-Dinitro-2-methylphenol 

N-Nitrosodiphenylamine (1) 

4-Bromophenyl-phenylether 

Hexachlorobenzene 

Pentachlorophenol 

Phenanthrene 

RFW#: 

Carbazole 

Di-n-butylphthalate 

Fluoranthene 

Pyrene 

Butylbenzylphthalate 

3,31-Dichlorobenzidine 

Benzo(a)anthracene 

Chrysene 

bis(2-Ethylhexyl)phthalate 

Di-n-octyl phthalate 

Benzo(b)fluoranthene 

Benzo(k)fluoranthene 

Benzo(a)pyrene 

Indeno(1,2,3-cd)pyrene 

Dibenz(a,h)anthracene 

Benzo(g,h,i)perylene 

2-Butoxyethanol 

Benzyl alcohol 


005 006 03LE0575 -MBI 03LE0575 -MBI 

350 U 350 U 330 U 330 U 

880 U 870 U 830 U 830 U 

350 U 350 U 330 U 330 U 

350 U 350 U 330 U 330 U 

350 U 350 U 330 U 330 U 

880 U 870 U 830 U 830 U 

350 U 350 U 330 U 68 $ 

880 U 870 U 830 U 830 U 

880 U 870 U 830 U 79 t 

350 U 350 U 330 U 330 U 

350 U 350 U 330 U 83 % 

350 U 350 U 330 U 330 U 

350 U 350 U 330 U 330 U 

350 U 350 U 330 U 330 U 

880 U 870 U 830 U 830 U 

860 U 870 U 830 U 830 U 

350 U 350 U 330 U 330 U 

350 U 350 U 330 U 330 U 

350 U 350 U 330 U 330 U 

880 U 870 U 830 U 82 t 

350 U 350 U 330 U 330 U 

350 U 350 U 330 U 330 U 

350 U 350 U 330 U 330 U 

350 U 350 U 330 U 330 U 

350 U 350 U 330 U 330 U 

350 U 350 U 330 U 81 w 

350 U 350 U 330 U 330 U 

350 U 350 U 330 U 330 U 

350 U 350 U 330 U 330 U 

350 U 350 U 330 U 330 U 

350 U 350 U 330 U 51 J 

350 U 350 U 330 U 330 U 

350 U 350 U 330 U 330 U 

350 U 350 U 330 U 330 U 

350 U 350 U 330 U 330 U 

350 U 350 U 330 U 330 U 

350 U 350 U 330 U 330 U 

350 U 350 U 330 U 330 U 

350 U 350 U 330 U 330 U 

350 U 350 U 330 U 330 U

RFW Batch Number: 030SL329 Client: TNUBANFORD F03-006 82194 Work Order: 11343606001 Page: 2c 

Cust ID: B16WS3 B16W90 SBLKTK SBLKTK BS 

RFW#: 005 006 03LE0575-MB1 03LE0575-NB1 

Tributylphosphate 350 U 350 U 330 U 330 U 

(1) - Cannot be separated from Diphenylamine. *= Outside of EPA CLP QC limits.

1F 

SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET 

TENTATIVELY IDENTIFIED COMPOUNDS 

Lab Name: Lionville Labs, Inc. Work Order: 11343606001 

Client: TNUHANFORD F03-006 H2194 

CLIENT SAMPLE NO. 

Matrix: (soil/water) SOIL Lab Sample ID: 0305L329-001 

Sample wt/vol: 30.0 (g/mL) G Lab File ID: D060720 

Level: (low/med) LOW Date Received: 05/02/03 

k Moisture: _ 6 decanted: (YIN)_ Date Extracted: 05/14/03 

Concentrated Extract Volume: 1000(uL) Date Analyzed: 06/07/03 

Injection Volume: 2.0(UL) Dilution Factor: 1_00 

GPC Cleanup: (YIN) N pH: 7.0 

CONCENTRATION UNITS: 

Number TICS found: 3 (ug/L or ug/Kg) UG K 

1 1 

JB16W79 

CAS NUMBER COMPOUND NAME RT EST. CONC. Q 

1. JALDOL CONDENSATE 1 3.550 1 2001 JAB 

1 2 • JALDOL CONDENSATE 1 4.124 1 200001 JAB 

1 

I 

3. 

JUNKNOWN 

1 

1 20.6261 1001 J 

FORM 1 SV-TIC RFW (v3.3) 

I

1F CLIENT SAMPLE NO. 


TENTATIVELY IDENTIFIED COMPOUNDS I IB16W80 



Matrix: (soil/water) SOIL Lab Sample ID: 03051,329-002 

Sample wt/vol: 30.0 (g/mL) Lab File ID: D060721 


w Moisture: 4 decanted: (YIN)— Date Extracted: 05/14403 

Concentrated Extract Volume: 1000(UL) Date Analyzed: 06/07/03 

Injection Volume: 2.0(UL) Dilution Factor: 1_00 



Number TICs found: 2 (ug/L or ug/Kg) UG/KG 

CAS NUMBER COMPOUND NAME I RT EST. CONC. Q 

1. JALDOL CONDENSATE 3.539 2001 JAB 

2. IALDOL CONDENSATE 1 4.122 1 200001 JAB 


13

IF CLIENT SAMPLE NO 



B16W81 






% Moisture: 4 decanted: (Y/N)_ Date Extracted: 05/14/03 


Injection Volume: ?2. (uL) Dilution Factor: 1.00 

GPC Cleanup: (Y/N) N pH: 7.0 


Number TICS found:. (ug/L or ug/Kg) UG/KG 

I 

1 1. 

1 3. 


JUNKNOWN 3.178 1001 J 

2. IALDOL CONDENSATE 

JALDOL CONDENSATE 

1 

1 

3.543 

4.143 

1 

1 

1001 

300001 

JAB 

JAB 


4




B16W82 




Sample wt/vol: 30.0 (g/mL) Q Lab File ID: D060725 


% Moisture: 6 decanted: (Y/N) _ Date Extracted: 05/14/03 


Injection Volume: 2_0(uL) Dilution Factor: 1.00 

GPC Cleanup: (Y/N) N pH: 7.0 


Number TICs found: (ug/L or ug/Kg) G K 

1 2. 


1. (UNKNOWN 3.182 1001 J 

JALDOL CONDENSATE 3.556 2001 JAB 

3. IALDOL CONDENSATE 4.130 300001 JAB 

FORM 1 SV-TIC RFW (v3.3)

1F 





CLIENT SAMPLE NO. 

lB16W83 

I 


Sample wt/vol: 30.0 (g/mL) Lab File ID: D060804 


k Moisture: _5 decanted: (YIN)- Date Extracted: 05114/03 

Concentrated Extract Volume: 1000(UL) Date Analyzed: 06/08/03 

Injection Volume: 2_0(uL) Dilution Factor: 1.00 



Number TICs found: (ug/L or ug/Kg) UGJKG 


1. JUNKNOWN 3.175 1 3001 J 

2. IALDOL CONDENSATE 3.549 1 2001 JAB 

3. JALDOL CONDENSATE 1 4.123 1 200001 JAB 


116



TENTATIVELY IDENTIFIED COMPOUNDS I 

1B16W90 


I 

Client: TNUHANFORDF03-006 H2194 



Level: (low/med) Low Date Received: 05/02/03 

W Moisture: 4 decanted: (Y/N) _ Date Extracted: 05/14/03 


Injection Volume: 20(uL) 

GPC Cleanup: (Y/N) N 

Number TICS found: 3 

Dilution Factor: 1`00 

pH: 7.0 


(ug/L or ug/Kg) U KG 

1 1 1 1 

CAS NUMBER COMPOUND NAME RT EST. CONC. 1 Q 1 

1. JUNKNOWN 3.177 1 2001 J 1 

2. IALDOL CONDENSATE 3.551 1 3001 JAB 1 

3. 1ALDOL CONDENSATE 1 4.160 1 300001 JAB 1 


/7



TENTATIVELY IDENTIFIED COMPOUNDS I ISBLKTK 



Matrix: (soil/water) SOIL Lab Sample ID: 03LE0575-MB1 

Sample wt/vol: 30.0 (g/mL) Ci 

Level: (low/med) LOW 

t Moisture: decanted: (Y/N) _ 

Concentrated Extract Volume: 1 0(uL) 

Injection Volume: 2.0(uL) 

Lab File ID: D060718 

Date Received: 05/14/03 

Date Extracted: 05/14/03 

Date Analyzed: 06/07/03 

Dilution Factor: 1.00 

GPC Cleanup: (YIN) N pH: 710 


Number TICs found: 3 (ug/L or ug/Kg) G K 

I 

I 

CAS NUMBER 

I 

COMPOUND NAME 

I I 

RT EST. 

CONC. Q 

1. IALDOL CONDENSATE 1 3.543 2001 JA 

I 

2. IALDOL CONDENSATE 1 4.125 200001 JA 

I 

3. 

JUNKNOWN 

1 

1 21.471 801 J I 


I 

I 

I

L% Yuri vr•r• r 1, -- . - 

1 

VL FIELD PERSONNEL: COMPLETE ONLY SHADED AREAS 1 

Lionville Laborato ry Use Only Custody Transfer Record/Lab Work Request Page —L- Di__^- 

03C)-,5L-&?-9 

Client MO 1- AQO ^ t0C Tll? k Q" D 

Refrigerator # 

Eat Final P Sam Data 

^ PNn9 #Ryes Container 

Project J13'^'J^lo[n- —' ^1- 4499 f^0'd 

Project Contact/Phone # Volume 

Lionville Laboratory Project Manager Q^ 

OC Del. °] TAT 

Pre serv a tives 

Liquid 

- 

Liquid 

Solid C&CL 12n. 

ORGI 

INORG 

r- Id- o] ANALYSES 

Q Q Z 

REQUESTED O ZW 

Date Recd C:t Date Due T9—T'[T^T ^` ^î(•t 

U - 

MATRIX 

CODES: 

S- Soli 

SE - Sediment 

Lan 

Client ID/Description on 

Matrix 

C 1Of81 

(3) 

Matrix 

Date rrse z 

Co llected Collected 

a7 


u N 

K 

C 

so - said MS MSD 

H N 

SL - Sludge 

W - Water 

O- Oil 3 

A - Air 

DS- Drum 

Solids 

DL - Drum 

L Liqui Li ds 

Leechate 

WI - Wipe 

X - Other 

F- Fish 

1 

coa 3 

1 3 

DATEIREVISIONS: Lionville Laboratory U se Only 

Speciallnstrncdona:` - .n 1 f gYiY, QC S-04- 0 s 1, Pu [â1 ^.a ^r}^= sd^ -Ie 

Samples we Tamper Resistant Seal was: 

AA 

5 (e. P 4l "'i '006 ^dd III 13 N W [^ er, Ca 1) OW , or t) Present on Outer 

Hand Delivered _ Package(f) or N 

b 

3.(-{ ^__N^^^ 56 Sv C(, FI 1 .NUi ^L S A"olll • _ # 2) ckage Outer 

'7 JN/^LC!p_ (^tCJL07_N Package( Y) or N 

4 INN30, 1 C9fO LPH Q 'G L* H o ia21 1C 0(a C3[ 2) Ambient or hill 3) Pmsent n Sample 

5. OP[O ^DRO x R4 

3 ) Received in ood 

CondWon C or N 

Y) or 

4) Unbroken on 

N 

Relinquished 

by 

Received 

by 

pate Time 

S 

RetingWshad Received 

by by 

Q ^„ 

7a 

Dolts * 

wowr;F Tuna Discrependes Between 

Samples Labels and 

COC Record? Y or 

4) Samples 

Properly P/rE^gerved 

or N 

L'J 

5) Received Widen 

Holding Ti s 

Sample U or N 

COC Record Present 

Upon Samoa Rec't 

Y or N 

Cooler 

F P (+Fx L NOTES' M or N Temp. -C 

RE ITT "" 1 3 

~ 

r 

iI

FH-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-62 JpW 1 of 1 



Johansen/Popeftster LC Hulstrom 373-3928 TRENT, SJ 


Air Quality 0 

200-P W-71100-PW-4 OU - Bo re 

hole Soil Sampling 216-A-37 (C4106); (12.5'-157 F03-W6 

O S ^ Field Logbook No. COA Method of Shipment 

Ice Chest No. ^yJ C- q I 

/C. / tP HNF-N-3361 I17504ES10 Federal Express 

Shipped To i^R^ O(aite Property No. .7 O Bi ll of Lading/Air Bill No.,5 6 E 

Ealikhffffi 22 0 l^ — 

POSSIBLE SAMPLE HAZARDSIRFAWdS 



Prese rvation 



Volume 


Bi6W79 SOIL 03 

Cods Ced eC Cods None tine 

a G a0 VG a0 

I 

I20m l. 

I 

Quit, 

1 

12OUL 

t 

Oral, 15^- 

sec ivao )I 

O.W,iem M)UM- WkGeue- Tritium -M 

H.-71% 3532 413.1 Spend 

Imuu b . 

N OF POSSESSION Sign/Print Names SPECIAL. INSTRUCTIONS O 777.3 

a'-filtetaboeme7 . 1' f cn 0 ^' p fa,. •• The hdxuatory u [o 

Relia9uished ved F Datdllme t ^T eceived B /Stored In Datefrime^[ 

report troth kem=e and diesel tinge eompouade from W7PH-D nulysia. 

QC^= 37

FR-Central, Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-63 I Page 1 of 1 

Collector 



200-PW-2 1200-PW4 OU - Borehole Soil Sampling 

Ice Chest No x?9 C (^/ Sc 


m 

LC Hulstm 373-3928 


216-A-37 (C4106); (17.5'-20') 

Field Logbook 

HNF-N 

I5 04ES IO 

Shipped To 7(o 

Ofbite P ro perty Na /} e 

J'^^ 

6 ^ 

POSSIBLE SAMPLE RAZARDS /REMARKS 



Preserva tion 


Na of Container(a) 

Volume 


B16WBO SOIL ZS 0 3 (: Q, 


TRENT, Si SJ Price Code 8N Data Turnaround 

SAF No. 

F03-W 

Method 


Cud CC Cud 4C Cod eC Nape N. 

aG aG aG aG 

I 1 I 1 1 

120m 120m!, 60m l, 120mL 60mL 60mL 

Chrmrmm NO2MO3 . Wk Crtea,- See it. (1)at Tritium- H3 

Ha-7196 353.2 41 3.1 Spedd 

nmru 

Air Quality p 

Bill of Lading/Air Bill No. ^ d- Osl G 

45 Days 

AlN OF POSSESSION Sign/Print Names 

Relinquished /Rmovcd Front, ime ( Received By/Stumd in 

L 

/ /t g•Jl $ 

C rJ 

Relinquished By/R By/Removed F 

q < 

Date/Time 

LJZ8.0^ j! y f 

7> 

SPECIAL INSTRUCTIONS . f ^jei y^t s^^ l 

•• •• The tabomtory, ism 

mpon both kerosene and die sel range compounds from WiPH-D amlysis. 

— 

on- 

Matrix 

s-san 

s^ 

5;-sk,* 

srsW^ 

W-W,e, 

0a 

D D 

D-. 

Dates-1m' 

Received By/&omd In 

6 IP, 37Z iU S i 0 51 1 5 

r DaL^lfime 

b ,3 q!s&r 

Relinquished By/Re" Datdltme 1 s e0 Reemved By/Stwed N 

S J 51 o'S 

GAL-G Q12 ti 6 

^J l O ^ //O Cl 

Dare/fwe 

179, Nick:63-hieWnium-237 ,y Z/Q^ 

N 

;K 

Relbp By/Removed Most Derdfime 

, 

Rdmgws hed ^Byêonved 

Fsam^ 

Recei / In 

RKelved^ 

Daterrime 

y ^ 

O9 

^- 

DdeRime 



wrw,a 

wv 

wen°"° 

x^ 

Relinquished BylRcotov ed Ftuiat Datdrime Received By/Stored In Daterrime 

Ref # Mon 

LABORATORY Received By Tide DateMma, 

SECTION 

FINAL SAMPLE Dispos i Method Disposed By Date/rime 

DISPOSITION 

oui cc^tt 1103 101/2002) 

SWiOt 

a-D— t W,

FR-Central Plateau Project CHAIN OF CUSTODYJSAMPLE ANALYSIS REQUEST F03-006-64 

Collector Company Contact Telephone No. 

LC Huhtrom 

373-3928 


200-PW-2200-PW-4 OU - Borehole Soil Sampling 

Ice Chest No. ^-/^ / 

OF POSSESSION 

377-5( 5 1 0 

Relinquished By/Rtmoved From 

J 

FH-Central Plateau P roject CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-65 I Pella 1 of 1 

Collector Company Contact Telephone No. Project Coo rdioator 

Johi msen/PopdKister LC Hulsuom 373-3928 'TRENT. Sl 

Project Resigna tion Sampling Loca tion 

200-PW-2/200-P W-4 OU - Borehole Soil Sampling 216-A-37 (C4106); (37.5'-40') 

From 

By woo Emm 

Relinquished By/Removed Fran 


SECTION 

FINAL SAMPLE DisPoSid Merl 

DISPOSITION 

) 

1 

-A -4in 

Date/fine f 

4. 

Drtc/fime 

0,5 

Daterrime 

I --A Personnel not available to 

relinquish samples front the 3728 

^'9Yz Refk on cT l_L/01 

Tit le 

repot bah kerosene and diesel moat cconapoounds from 

Disposed By 

SA006 

Ice Cheat No / Field Logbook No. COA Method of Shipment 

/ 

M L 9.6 O s Y HNF-14.3361 117504ES10 Federal Express 

Shipped To rz 45^-(-J Dffsite Property No.!1 ,n ^D 

A0 

POSSIBLE SAMPLE HAZARDS/REMARKS 



Preserva tion 


No. of Containers) 

Volume 

Sample Sample Time 

Bl OW82 SOIL 

SHI-EE-011 (03101/2002) 

Cool4C Cod 4C Cod 4C Nam Nam 

'C 

2 0 

aO aG 

1 1 I 1 

120mL 60m1. 120mL 60m1. 60mL 

CN.,A. NOVNO3- Qlacreare- sees)' T66--HI 

Hex-7195 353.2 4 13.1 pedd 

P rice Code 814 Data Turnarou 

Air Quality El 

Bill of Lading/Air Bill No. ^ — ^^^ 

a 

/1 21& 7 Matrix 

, lea6rbee+4' •• The labomto ry is to 

i-D analysis.tl^ SE^Yas^ 

SOSSda 

1 1/O f 

DatelT"mre 

Date/Time 

45 Days 

n-nws 

W - W'"' 

DS- 

OS-nnw Sd;N 

m.o,w r+ww 

r-r 

wo-w;R 

e-fie 

9.yyna m 

x-aw I

FH-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-66 J PW ! Collector 

Of 

! 

Johansen/Pope/PSster 




LC Hulstrom 373.3928 


216-A-37 (C4106); (47.5-5 (r) 

lee Chat No. OR C- 4 (v O 15' r— 1177504FSIO 


TRENT, Sl Price Code 8N 

SAF No. 

F03.006 

McF (Express 

Air Quality q 

Shipped To &7,le O(fsite Property No. A-0 3 Q Z Z O Bill of Lading/Air Will No. s ^—^ o3 L 

POSSIBLE SAMPLE HAZARDSIREMARiff 



Praerndon 


Cod 4C Cod do Cod 4C Nom Nape 

aG aG aG aG aG 

No. of Con tainer(s) I ) ) 

Volume 


I20,nL 60ML 120raL 60m l, 60mL 

CMOmlom 

He 71% 

NGVNO3- 

353.2 

Oils Cresrc- 

413.1 

Seahem( 1)0 

spew 

Tmiwo-10 

imupai. 

° I 

B16W83 SOIL 17 IJ^ 

I 

JIM 


45 Days 

CHAIN OF POSSESSION Sign/P rint Names SPECIAL INSTRUCTIONS I GG /f 

Matrix 

•• 

••The laboratory is m 

B Fm DatNr Received By/Stored Is = 2-'-- 

s-sd 

report both kerosene and diesel range compamds from WIPH-D a dy,i& 

sa•seao.rr 

a 

ms 

SOSdia 

Rc' uislKd B /R From D ,ry11Cfs 

W.W. 

D Oa 

Ile k Ih • u1orS 

"-"" 

DYD mSdN 

DVDnuv lvWiOt 

Tn^ 

wHwi, 

x 

Received y/St N 

D dri a L^•aaCJ 1 wnnuof - om r, Isar m mn umc7o 

N'r4N•63' N 7 

1 7^ Ll . "L— - an 3 ron^z^ Yl^t /6l 

Relinquished BxamvAd Fmm 

um 

Receved By/Stored 

Dazdrime 

3 2 5 1 o-) 1 l eo rj &Ai,1 S ) 0 -5 110b 

Relinquished By/Remo F m Datefrime 

Received BY/S ti Datdrime 

:txi 1 0 31 10 0 rV t- 


R By ved From S _ Dstdrime Received to - & Timc 

relinquish 

mpla from the 

LIM 

Ref i1 

3728 

00 ^—L/i'^ 

Relinquished By/Removad From Ductrime Received By/ Datdrinc 

LABORATORY Re SECTION 

ceived By Tide D.Wrime 

FINAL SAMPLE 

DISPOSITION 


Duposed By DaWrime 

RHI_EE-011 (03/0112002)

FR-Central Plateau 

200-PW-2/200-PW -4 OU - Boreho le Soil Sampl 

lee Cheat No. ef^ C p 

Shipped To /'F ^l K^'^ 

C).5 

POSSIBLE SAMPLE HAZARDS/REMAMI 

I Special Handling and/or Storage 

OF POSSESSION 

By/Removed From 


Datdfime 

07 

Daldfime 

CHAIN OF CUSTODY/SAMPLE ANALYSIS 


LC Hillstrom 373-3928 


216-A-37 (C4 106); ( 1 7.5-20') 

Fie Id Logbook No. 

HNF-N-3361 II7504FS10 OA 

Offsite Proper ty No. ^'J7 ZZ C) 

I P* 372 

By/Shed In 

Preserva tion 


No. of Contsiuer(s) 

Volume 

Sample No. Matrix Sample Date Sample Time 

SOIL /t- (0 

Date rime 

ZS OS (6 YS 

SPECIAL INSTRUCTIONS 9 f(/2 bra f Matrix 

report both kerosene and diesel range compolmd3 f rom WTPH-D analysis. 

Datdfime 

S 103 1/0 C) 

Datdrime 

L>n^^_ ~tizsz— ,^f^c `ÎLy^°) 

Datdrime 

Of 

Date/Tina, 

Datdrime 

Cad 4C I Cod

l 

M-Central Plateau P roject CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-7 4 


Johanscr3Pope/Pfister LC Hulsnom 373-3928 TRENT, SJ 

Project Designation Sampling Lo cation SAF No. 

200-PW-2/200-PW4 OU -Borehole Soil Sampling 216-A-37 (C4106); (0.5) F03-M 

Ice Chest No. ^y^ 

Fi eld Logbook No. COA Method of Shipm ent 

G le C— Q S G 


Shipped To 465163.'2^ C 2A 

. z 




Offsite Properly No. /j Z L7 ^1 

O#e 3 G.- C/ 

Preservation 



Volume 

Sample No, Matrix Sample Date Sample Time 

B16W91 SOIL •Z (j 0 

Coal 4C Cad 4C 

aG aG 

I I 

60ML 250mL 

Penicida- Clint. 

8081 lit aidda- 

ernslst 

11.6. 

_ - 

Price Code xN Data Turnarouo 

Air Quality q 45 Days 

Bill of Lading/Air Bill N o. C ^Ly- 0,51 7 .^ 

J 

CH a N OF POSSESSION Sign/Print Names SPECIAL INSTRUCTIONS Matrix 

emoved m Dadfime Received By/Stwed In Datdrime 

^^ {^ 3y2$ ^z^ 03 

/6YS 

PR-4uisdied BY/Removed F Datdrime Re so-svaae 

ce " IPr 5103 1166 

ived By/Stwed In 

3 

Date/fine 

î o S il0a " ""' 

elwquished BY/RRetttovaJ rom DateJTime 

1y— S I O' 

Relkwilrd BY moved From Dndrime 

Q 

OU 

Received B Y/St 

/GG 

Received 

N 

N 

Datdrime 

Dwdrime 

! 

b\e to 

tent av\ from tl e ^ 

pecsonBel 

A-Air 

os-o,.w saw. 

a.-oûwa 

wrWyp 

17's 

F 

? 

--Y-v 

hsamp ly 

v-vim' " 

x-ar 

ro Relnquished By/Rcu ved m 1741d1'imC Received BY d !n Date/Time 

$^ 

telir,4ots^. on 

Relinquished By/Removed F 

Ref 

ro m Datdrime Re ce ived By/saxed in DatdCane 


SECTION 

FINALSAMPLE 

DISPOSITION 

BHI-EE-011 (03/01/2002) 


Tide 

Dispo s ed By 

Datdrime 

Date/Tune 

s.am 

^-^ 

strswr

LIONVILLE LABORATORY INCORPORATED 


IENT: 1 n u 

chase Order/Project: DATE: 

Trat 

SOW#/Release#; F63-00(,, 

ory SDG #: 

CEOs l_ 3 Z 

w 

S o^ c^ 

)TE: ALL ENTRIES MARKED "NO" MUST BE EXPLAINED IN THE COMMENT SECTION 

1. Custody seals on coole rs or shipping ONO 0 see Comment 


2. Outside of coole rs or shipping containe rs are Yes ONO O NIA O see Comment # 

free from damage? / 

3. Airbill # recorded? Iyu O No O N/A D see Comment # 

4. All . expected paperwork received (coc and / 

other client specific: historical data, hea O No O NIA O see Comment # 

alpha/beta or other s creening data as 



S. Sample containers are intact? 7^. Yes O No O N/A q sec Comment # 

6. Custody seals on sample containe rs intact, y Yes ONO O NIA O see Comment # 

///^' 

signed and dated? - 

7. All samples on coc received? 

^ 

.tt^s ,,`Y q No l7 NIA O $cc Comment # 

a. All sample label information matches coc? 

^^ 

6cs ONO O NIA • b sec Comment # 

9. Laboratory QC samples designated on coc? O Yes ONO bWA q ace Comment # 


W. Shipment meets LvLI Sample Acceptance yes O No O NIA O we Comme nt # 

Policy? (identify all bo ttles not within 

Policy. See reve rs e side for policy) 

IL Where applicable, bar code labels are O yes ONO ,IN/A O see Comment # 



13. coc will be faxed or emailed to client? 

14. Project Manage/Client contacted 

concerning discrepancies? (nante/date) 

Cooler # / temp (°C) and Comments: 

4 E12C, / 1 .3 

CG.,'' 

`-Yes ONO O NIA O see Comment # 

/ 

MAY,Yes • ONO O NIA O m Comment # 

O Yes . 

ONO 191v/A o see Comment # 

Laboratory Sample Custodian; 

Laboratory Project Manager: 

^^^1 

1 ^ 2^


HBGX ANALYTICAL DATA PACKAGE FOR 

TNU-HANFORD F03-006 eZllj 



B16W91 007 S 03LE0531 04/28/03 05/05/03 05/07/03 

B16W91 007 MS S 03LE0531 04/28/03 05/05/03 05/07/03 

B16W91 007 MSD S 03LE0531 04/28/03 05/05/03 05/07/03 

LAB QC: 

PBLKSR MB1 S 03LE0531 N/A 05/05/03 05/07/03 

PBLKSR MB1 BS S 03LE0531 N/A 05/05/03 05/07/03 

PBLKSR MB1 BSD S 03LE0531 N/A 05/05/03 05/07/03 

4 

3p# U3 

d 

n , ^Â 

6 

"^^ Zt LL^^' 6 

^f4'4^

Client: TNU HANFORD F03-006 W.O.#:11343-606-001-9999-00 

LVL#: 0305L329 Date Received: 05-02-03 

SDG/SAF#: H2194/F03-006 

HERBICIDE 

One (1) soil sample w as collected on 04-28-03. 

The sample and its associated QC samples were extracted on 05-05-03 and analyzed according to Lionville 

Laborato ry OPs based on SW846, 3rd Edition procedures on 05-07-03. The extraction and analysis procedure was 

based on method 8151A. 

The following is a summary of the QC results accompanying the sample results and a description of any problems 

encountered during their analyses: 

1. All results presented in this repo rt are derived from samples that met LVLI's sample acceptance policy. 

2. All required holding times for extraction and analysis have been met. 

3. The method bl ank was below the repo rting limits for all target compounds. 

4. All surrogate recoveries were within acceptance criteria. 

5. All blank spike recoveries were wi thin acceptance criteria. 

6. Four (4) of sixteen (16) matrix spike recove ries were outside acceptance criteria. A copy of the Sample 

Discrepancy Repo rt (SDR) h as been enclosed. 

7. All initial calibrations associated with this data set were within acceptance criteria. 

8. All continuing calibration standards analyzed prior to sample ex tracts were within acceptance criteria. 

9. To the best of my knowledge, this data report is in compliance with the terms and conditions of the 

purchase order, both technically and for completeness, for o ther than the conditions detailed in the case 

narrative. Release of the data contained in this hard copy data package and in the elec tronic data 

submi tted on diske tt e has been authorized by the cognizant laborato ry manager or his/her designee to 

be accurate as verified by the following signature. 

(^0^^ 05-1(#-03 

lain Daniels Date 

Laboratory Manager 

Lionville Laborato ry Incorporated 

pef\l/ r:\group\data\herb\\mu\04L329.doc 

The results p re 

sented in this re 

po rt 

relate only to the analy tical testing and conditions of the samples at receipt aid during storage. All pages of this re 

po rt 

are integral pans of the 

analytical dam. Therelb e, this report should only be reproduced in its en ti 

rety of 15 pegs. 

208 Welsh Pool Road • Exton, PA 19341-1313 • (610) 280-3000 • Fax (610) 280-3041 q

Lionville Laborato ry Sample Discrepancy Repo rt (SDR) SDR#: 036C-00 00 

Initiator: A o ^— 1,t ^,. 

Date: 5- S lo3 

Client: r(Vv 

Batch: 0)ns 1.- 32 

Samples: 1. s o - 

Method: sW84 6/MQAVwy1c1.P/ 

Parameter )4v In 

Matrix: So. i 

Prep Batch: o I t, c o sat 

1. Reason for SDR 

a. CDC Discrepancy _ Tech Profile Error _ Client Request Sampler Error on C-O-C 

Transcription Error — Wrong Test Code _ Other 

b. General Discrepancy 

_ Missing Sample/Extract _ Container Broken — Wrong Sample Pulled _ Label ID's Illegible 

_ Hold Time Exceeded Insufficient Sample _ Preservation Wrong _ Received Past Hold 

_ Improper Bo ttle Type _ Not Amenable to Analysis 

Note: Ve rified by [Log-in] or [Prep Group) (circle)... signatu re/dale: 

c. Problem (Include all relevant specific results; a ttach data if necessa ry) 

1l S 17 l-o.... 41, ^1 C. Ps_.^ F J SYC c 7'ic. h.( G^. 

3 

2. Known or Probable Causes(s) 

3. Discussion and Proposed Action Other Desc ription: 

— Re-log 

_ Entire Batch 

Following Samples: s A ^rlr5, 

_ Re-leach 

_ Re-extract 

_ Re-digest 

_ Revise EDD 

Change Test Code to 

_ Place On/Take Off Hold (circle) 

4. P ject Manager Instructions ... signature/date: 

_ Concur with Proposed Action 

_ Disagree with Proposed Action; See Instruction 

_ Include in Case Narrative 

_ Client Contacted: 

Date/Person 

_ Add 

Cance l 

5. Final Action ... signature ldate: Other Explanation: 

Verified re-[log][leach][ext [analysis] (circle) 

_3ncluded in Case Na 

_ Hard Copy COC Revised 

Electronic COC Revised 

EDD Corrections Completed 

When Final Action has been recorded, forward original to QA Specialist for distribution and filing. 

Route Distribution of Completed SDR Route Dist ri bution of Completed SDR 

X Initiator _ _ Metals: Beegle 

X Lab General Manager. M. Taylor — _ Inorganic: Perrone 

X Project Mgr: Stone/Johnson/Haslett _ _ GC/LC: Kiger 

X Technical Mgr: Wesson/Daniels — MS: Rychiak/Layman 

X QA (file) — _ Log-in: Melnic 

_ Data Management: Feldman — Admin: Soos 

Sample Prep: BeegWKiger — _ Other. 

QA-1 05-A-0e01 

1 

.h , y S

3M GLOSSARY 


OF HERBICIDE DATA 

U = Indicates that the compound was analyzed for but not detected. The minimum 

detection limit for the sample (not the method detection limit) is reported with the U 

(e.g., IOU). 

= Indicates an estimated value. This flag is used in cases where a target analyte is 

detected at a level less than the lower quantification level. If the limit of 

quantification is 10 ug/L and a concentration of 3 ug/L is calculated, it is reported as 

3J. 

B = This nag is used when the ana)yte is found in the associated blank as well as in the 

sample. It indicates possible/probable blank contamination. 

E = Indicates that the compound was detected beyond the calibration range and was 

subsequently analyzed at a dilution. 


ABBREVIATIONS 

BS = indicates blank spike in which reagent grade water is spiked with the CLP matrix 

spiking solutions and carried through all the steps in the method. Spike recoveries 

are reported. 

BSD = 

MS = 

MSD = 




DL = indicates that recoveries were not obtained because the extract had to be diluted for 

analysis. 

NA = 


DF = Dilution Factor. 

NR — 

Not Required. 

SP = Indicates Spiked Compound. 

M

^3 vLl 

GLOSSARY OF HERBICIDE DATA 

P = This flag is used for an Herbicide target analyse when there is greater than 

25% difference for detected concentrations between the two GC columns 

(see Form ?). The lower of the two values is reported on Form I and 

flagged with a T". 

D This flag identifies all compounds identified in an analysis at a secondary 

dilution factor. 

C = This flag applies to a compound that has been confirmed by HPLC. 

R:/SHARE(H PLCIOLCSCGLOS 

5


Herbicides, Special List 

Report Date: 05/09/03 15:59 

RFW Batch Number: 030SL329 Client, TNU-HANFORD F03-006 Work Order: 11343606001 Page: 1 

Cust ID: B16W91 B16W91 B16W91 PBLKSR PBLKSR BS PBLKSR BSD 

Sample RFW#: 007 007 MS 007 KSD 03LR0531-Be 1 03LB0531-MB1 03LE0531-NB1 


D.F.: 1.00 1.00 1.00 1.00 1.00 1.00 

Units: ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg 

Surrogate: DCAA 63 88 49 k 84 1; 70 !k 92 

__________________________________________°== fl=====__=====fl=====__===== fl=====__=====fl===== __=====fl==== =__=====f1 

Dal,apon 180 U 73 k 58 !k 170 U 69 % 79 t 

Dicamba 72 U 83 %, 40 * 16 67 U 60 !k 89 k 

Dichloroprop 180 U 76 t 49 * t 170 U 65 % 86 %, 

2,4'-D 36 U 65 46 33 U 61 & 78 

2,4.,5-TP (Silvex) 18 U 71 16 65 17 U 66 81 !k 

2,4,5-T 18 U 70 44 * 17 U 64 t 82 

2,4'-DB 180 U 72 t 44 * 170 U 60 !9 82 

Din seb 18 U 75 k 70 't 17 U 74 $ 84 k 

U= Analyzed, not detected. J= Present below detection limit. B= Present in blank. NR= Not reported. NS= Not spiked. 

!^= Percent recovery. D= Diluted out. I= Interference. NA= Not Applicable. *= Outside of EPA CLP QC

Lionville Laborato ry Use Only Custody Trawer Kecorurâu VVVI n teerrMMwwo .uy^^_.T 

Client —TV%%- -lC)cCA—t- 

Est Final Proj. Sampling Date rrtyps Container 

Project M 1 j nN e- [ril - C U 

Project ContacUPhone # - Volume 

Li onville ;Laboratory Project Manager 

0C Exxc Del _ aDAC^ _ TAT 

Date Recd ^ -G {^ Date Due C>^1 

FIELD PERSONNEL: COMPLETE ONLY SHADED AREAS 

A B 

c 

Remserarorr a 

Preserva tives 

Liquid 

Shcd 

Lib 

Sold 

ANALYSES 

REQUESTED -^ O 

ORGANIC INORG 

Z 

zm aU 

ti x U 

M at rix 1 Lionville Laborato ry MATRIX 

CODES: 

5 - Sol 

SE - Sediment 

SO - Solid 

SL - Sludge 

w- water oilO- 

A. Air 

DS - Drum 

Solids 

DL - Drum 

LiquW 

a 

Client IDIDescription 

OC 

C n) rr 

MS MSD 

Matrix 

Time 

Collected Collected 

1 

1 

QJ 

Use Only 

C 

N I~ 

3 3 

3 

1 

l" 

L- EP/6CLP 

Leaehete 

wl - Wipe 

X- Omer 

F . Fish 

Ina 

PON 

Cl I 

1 

3 

V LI 

Specfal Insbuctfons:r-4"-) I t la l t t X ©G 

T 

DATEIREVISIONS: 

^' 


Samples were/ Tamper Resistant Seat was: 

C`xl 't^ r U^-^^ / /y 2 

1) Shipped _— or t) Present on Outer 

^Y 

3. 

q 2) Ambient or 11 

Hand Deffvered _ Package or N 

(f, 

Arrtxx Y 2) Unbroken_ on Outer 

Package Y or N 

3) Received in Owd 

S. Condition C or N 4) Unbroken on 

i 4) Samples Sample C-) or N 

6. 

Property Pr rved Record Present 

Relinquished Received 

Date 

^^ Relln quished Received 

Date Time Discrepancies Behveen Y' or N Upon Samp^ Rec't 

by 

by by by Samples Labels and 55 Received Within 

UY or N 

y^ Q A^ a n ee 

COC Record? Y or N^ 

NOTES: 

F OE - ^(^ 

11 or N Temp. -C 

RE ITT 0L-:)-(- 

3) Present n 

Sample 

Y,) or N

FH-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-62 Page 1 O 1 

Collector 

Johansen/Pope(P fister 

Project D es igna tion 

200-PW-2!100-PW-4 OU- Borehole Soil Sampling 

Ice Chest No. rF 

C— 

q 

/C ! 




216-A-37(C4106);(125-1 5) 


TRENT, SJ Price Code $N 

SAF No. 

F03-M 

OS' FieHNLogbook 36 17 04 10 Method ExP 

ES 

Express 

Air Quality . q 

Shipped To t7^^ Off Property No. _ " ^.j ^,y ' ^7 O Bi ll of Lading/Air Bill No. C-^ r7^. 

4E>^nt 

POSSIBLE SAMPLE RAZARDSIREMkRkS 



Preservation 

Coa14C Cad 4C Cod4C Nape Noce 

Type of Container so ` G aG aG 


Volume 

i$ampic No. Matrix • Samp le Date Sample Time 

B16W79 , SOIL ,tf O^ l 

1 1 1 1 1 

120ml. 60mL 120ML 60mL 60nil. 

c7aam:,,a NOVNO2- Oha C..,,e- see iy Tdam-H3 

rlv-7196 3512 417.1 Spedd 

IN OF POSSESSION Sign/P rint Names SPECIAL INSTRUCTIONS 2 t e3 

7 

0, fig i' r90 n ^" - 

Relirquished B ved Frorrk Datdfime Rexived By/stored in 

p 

RC^ i ' ` 37c p 

Daze/Tim, 

E 

42So3 16 / J 

"' 

6mamM IeK and diese ang

F11-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS RE QUEST F03-006-63 J PW 1 of 1 


JohanuaWPop elPfster LC Huistrom 373-3928 TRENT, Sl 

Project Designation Sampling Loca tion SAF No. 

200-PW-2200-PW-4 OU - Bo re hole Soil Sampling 216-A-37 (C4106); (17.5'-20') F03-M 

lee Chat No. (! 


1..^ C ^^ J b HNF-N-3361 117504FS10 Federal Express 

Shipped To XCL 

Z v 

Offsite Property No. n r{ 

77-0 5 

.# 

e 




Preservation 



Volume 

(Sample No. Matrix • Sample Date Sample Time 

B1 6W60I SOIL 

Cod /C Cool C 

Dan/Time 

yr " 

D'D 

o D— am 

SJ 6F1 1- 

Relirpw dBy/RamOVW fforn Daldl'ime Rees /St U Dazelfime 

Relinquished By/Removed F ro m Datefrona Received By ored In Date/rime 

ReI' /Removed F ro mgaisM'd B By/Removed 

m Datelfime 

SECTION 

Received By/Stored In 

l 

Datrlrime 



Ref H )-ft- ^ 

Reccivd By Tide Dwe/rime 

FINAL SAMPLE Disposal Method Disposed By DatetTime 

DISPOSITION 

BHI-EE-011 (031012002) 

DInDûm Lpu+ls 

.wi, 

x

F111-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-64 >w ! of 1 

Collector 

Johansei3Pope/P6ster 


200-PW-2 /200-PW-0 OU - Borehole Soil Sampling 

lee ChestNo Ik C^ p / s/ 

6 r^P"^ ,b r* 

Shipped To 

OC41 1NC Cr•••v rlo T^/ '1'aa^ 


Special , Handling and/or Storage 



LC Hulsnom 

373-3928 

Sampling Lo ca tion 

216-A-37 (C4106),(27.5'-3(Y) 

Field Logbook 

HNF N-33 IN0. 

1504FSIO 


TRENT, Sl Price Code $N Data Turnaround 

SAF No. 

F03.006 

Method of 

Federal 

Air Quality q 

Offto Property No. O Bill of Lading/Air Bill No. ^^.^ O ^^ J 

Preserva tion 

—T 


Na of Container(s) 

Volume 


Cod 4C Cool aC Cod aC N. Noce 

aG aG aG aG 

1 1 1 1 1 

120mL 6OmL 120mL 60ML 60mL 

Chrooaom NO2NO3- Oil a G.- See 4.(1) Tm .-In 

H -71% 353.2 411 1 

lanDw, 

i7 

BibW81 SOIL ^. `^ I LO(/J 


sW y^ F ime 

ff 

Sign/print Names 


n 

Y 

_L 

I r 

trlf c 

Received B 

I 

toyed la D t eRime f ^/ 

• Z-4- Co 

Received By/Stored U 

^J 

DatdrMe 

3 //af 

Received By/Steed In 

Daleffune 

Reli uis lied By/Removed Fmm 10C I't^"t 

9 

elillquished moved Fmm ^ 

3 /! oo 

Relinquished Bym veal Fromî"1C 

;^ 

Re nqui B 

- 

caved From 

(11 e ti — 

Dale/Tune Receive 8 /for N Daldfime 

.3 =^,^,^'— 

—. 2--J3 6,+. ' 

Relinquished By/Removed From Dazdrime Received By red In DatcTime 


e 

q L d j 

mpon both kerosrne and dinel Wage comptamds frmn VI PH-D an alysis. 

1'g3r4eL-fil' D t ^ m-rL 


relinquîQ sh samples from the 3728 

Ref p tiLon 

LZ ) 

^/ /J7 

"The labonto7 u to 

LABORATORY Received By Title Dwelflme 

SECTION 

FINAL SAMPLE Disposal Wdmd Disposed By Dindrime 

DISPOSITION 

BHI-EE-011 (03/01/2002) 

45 Days 

f (,F 

Matrix 

s-sai 

sa-smw+ 

so sad 

sHVuase 

a a7 

A. 

D5-D. DL U1 

_D. Gwn. 

r-ru.m 

WI-Wipc 

I, uwa 

v-v^sn+w 

Xb w 

0

FH-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-65 I PW 1 of s 

Collector 




Ice Chest No 

/ 

L 9.b 

O s Y 

Company Con tact 

Telephone No. 



216-A-37 (C4106); (37.5'-401 


HNF-N-3361 

COA 

117504ES10 

Shipped To

FH-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS RE QUEST F03-006-66 Page 1 of 1 

Collector 

JohansenlPope/Pfister 



Ice Chest No.OR C 4 G O S ^ 

Shipped To eax 

1115 

POSSIMCE SAMPLE HAZARDSIREMA 49 



Company Con tact Telephone No. 



216-A37 (C4106); (47.5'-50) 

FieIIdNFLogbook -331 o. ; 

0 04ESI0 


TRENT, SJ 

SAF No. 

F03-W6 

M Feed of Sh pems; ent 

Offsite Property N o. Q Z z O Bill of Lading/Air BBI No. 

Preservation 



Volume 

%Sample No. Matrix • Sample Date Sample Time 

Cod 4C cod 4C Cod 4C Narc Nom 

aG aG aG eG aG 

I 1 1 I 

120mL Wait, 120ml. 60m l, 60 nL 

(3amdam 

Ilan-7196 

N0LNO3- 

351.2 

51 6W83 SOIL 7< 

ws.er^ 

413.1 

sslwa(1)' 

SpedY 

N 

Triuwn -B3 

l 

5! 

p rice Code $N 

Air Quality q 

NZ., ., 


tin B Fm Datefr' a 

Sign[Print Names SPECIAL INSTRUCTIONS ^( GL ej 

Received By/Stored In = le L 

•• . 

report both kerosene and diesel range compounds from WTPH-D analysis, 

a N3M 

Re uidWB /R From 

s. 

Dat 

.a y 

(I) 

Mi N k 

" 

- tronm 

Nepp, ar-237 

u 

- r, Ltaoptc rtmn ovum- 

G 

Person 

samples fron to 

relinquish 

P es from the 37.,2.8 

Aef p 

l'koo 

â j •'-IVY Received y/St 

11S 

In 

3 7Z- L4 . 61-4 o 3 

Rel-wishedB 

3 z 

Relinquished By/Remo 

d From efrane 

S 1 0 -)11 0 0 

F m DaWTune 

Received By/Stored 

s 

Received By/St In 

Datdfime 

S l o^ 

DaWTune 

10a 

(rJ4-(.t; 

- u By ved Fmm 

` 

e linquished By/R=m d From 

cS 1 03 

Datdfime 

-0 

DatoTime 

1/00 I-IJ CF 

Received to d 

ieceivedBy/Stakdt, 

Datdrime 

S,a-d3 

Damrrime 

•• The laboratory is to 

LABORATORY Received By Title Datc/rime 

SECTION 

FINAL SAMPLE DiY059 Medmd Disposed By Dateffime 

DISPOSITION 

BHI-EE-011 (03/01/2002) 

Da ta Turnaround 

45 Days 

Ma tr ix 

S-sm 

se-SvX.. 

SO^Sditl 

st-saaa 

W. wuu 

A'A'r 

o^ 

wt-w e 

w t.wipe 

vv5^ 

Xo 

rJ

FR-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS RE VEST F03-006.73 J PaV ! of 1 

Collector Company Contact Telephone No. P ro ject Coordinator 

JohanseNPope/Pfister LC Hulstrom 373-3928 TRENT, T, SJ 


200-PW-2200-PW.4 OU - Borehole Soil Sampling 216-A-37 (C4106); (17.5'-201 F03-W6 

Ice Chest No.q / e2C l p 

D 

S S. 


HNF-N-3361 

COA 

117504ESIO 



Price Code gN 

Air Quality q 

Shipped To Offsite Property No. 11 a '3 

fT 

2- 2- Q 

Bill of Lading/Air Bill No., 0 j 

I y POSSIBLE SAMPLE HAZARDS/REMAR 

C— 

Preserva tion 

Cod 4C Cod 4C C d 4 Nap 

- 

No 




No. of Contiiner(s) 

Volume 

Sample No. Matrix • Sample fate Sample Time 

aG aG aG aG 

1 I 1 1 1 

120mL 60ML 120. 1, 60ad, 60mL 

Ch av® N( 121NO3- OilkGrrase . Secitem(1) n Tritium-w 

Ha 71% 3513 413.1 Spedal 

waaiw t y 

13 1 6tN90 SOIL 0; /S- TO 7 11 

P ^^ 


45 Days 


emoved Fm drime 

Sign/Print Names 

Received By /Stored In 

3725- 

Date/rime 

ZS 03 /C YS 

SPECIAL INSTRUCTIONS Y DL a 3 

q 

- 

report both kerosene and diesel range compounds from WIPH-D amlysis. 

•• 'Ile iabontory is to 

Matrix 

s-sa1 

50-Sdia 

R. k.(, W,#d By/Removed Fr Date/Time 

A- ;77r S / n 3 

Received By/Stmed N 

//6v Z C.c 

Date/Cim• 

Si 03 

uro- 

n-vmse 

1/0 C) 1â ".u.:”-"' s ^°3 

w.wa, 

0 oa 

Relinquisistd By[R Ca^M 

, f 

m DateRime Rece ved By/Stort d 

i 

Date/rime 

a-w 

J V O 7 I IO t^ rv t G 

ioq ' bcd By/Rc ved From Daterrime Received In DateTime 

Relinquished By/Removed F rom DatetTime Received By/5 d In Faint 

Relinquished By/Removed From 

Datefrime Received By/Smred N Date/rime 

D 


relinqu 1 shtsamples front 3728 

/1 

Ref # / on 

LABORATORY 

SECTION 

Received By Title Datefrime 

FINAL SAMPLE Disposal Medwd Disposed By DatNrime 

DISPOSITION 

BHI-EE-011 (03101/2002) 

Sa y"„„ 

DS Dnm Wr 

DI'pun 4pì0r 

w 

r.-u,da 

v.vesaaron 

x-w.. 

It '

M-Central Plateau Project CHAIN OF CUSTODUSAMPLE ANALYSIS REQUEST F03-006-74 rage t m i 


Collector Company Contact Telephone No. P ro ject Coordina tor 

Johansen/Pope(PSster LC H illstrom 373-3928 TRENT, SJ 

Project Designation Sampling Loca tion SAF No. Air Quali ty q 45 Days 

200-PW-2200-PW-4 OU - Bo re hole Soil Sampling 216-A-37 (C4 106); (0.5) F03-006 

Ice Chat No. 

L (^ 

05(o 

Feld Logbook No. COA Method of Shipment 


Shipped To nabs 63 ,Ki C 214 Otttite Properly No. /J a, Z O ^7 ^t 

Ci (/ 

POSSIBLE SAMPLE HAZARWREMARKS 



Prese rvation 


Na of Container(s) 

Volume 


B16W91 SOIL .L (S O 

CodK Codk 

AG aG 

I I 

60nd, 250m, 

Pevlcldm- 

U81 

Chi.. 

Herbicide, - 

svnetst 

Bi ll 

of Lading/Alr Bill No.s 

j- Q3 •^ 

OF POSSESSION - Sigu/Print Nam es SPECIAL INSTRUCTIONS Matrix • 

emovedF m 

mv.d F m 

DaWTime 

DstJfime 

'ved ByMored In Daterrime 

^—F Pr 37 2-t 5ezti 03 aq,5 

Received By/Stored In Date(fime 

s1¢^ 

SAS a 

So-Sde 

srv.aa 

S)03 1100 03 Ilod W.W. 

Relinquished BY/Removed ro m 

DatwTime 

6^L^* llt;_ S i v oo 

Received By/St 

F^ 

In Date fune 

A-" 

nS-o^Sde. 

at.o,,.a uwm 

By emoved From Detdfime Received / In Da 11 me 

wt ww 

Relinquished By/Removed Fram Datdrime Reeeiv N Date?ime 

ReWuldshtd By/Rm ved From Date/Time Received By/S tored In Date rime 

C) 

Qeôotwl nol F (rout 

es I 

h 

to\tn4oi5^ 5^^^ 

p0 

Wef 1! 

LABORATORY Received By Tide Dwdrime 

SECTION 

FINAL SAMPLE Disposal Method Disposed By DaWrime 

DISPOSITION 

BHI-EE-011 (0310112002) 

1 

. 

x asa



DENT: I-M ( liar o,^ 

urchese Order/Project: DATE: S a-63 

1^. 

70ra 

OW# / Release #: Y(^ 3- C\Q(,, 

, 8 tsory 

SDG #: 

3^0s L- 32g 

40TE: ALL ENTRIES MARKED "NO" MUST BE EXPLAINED IN THE COMMENT SECTION 

1. Custody seals on coolers or shipping 


Yu ONO q NIA see omment 

2. Outside of coole rs or shipping containers are ` es ONO O NIA O see Comment # 


3. Airbill # recorded? Yes ONO q N/A 0 w Comme nt N 

4. All . cxpected paperwork received (coc and 

other client specific: historical data, e5 q No O N/A O see Comment # 

alpha beta or other screening data as 



5. Sample containers art intact? 

Yes O No O N/A O sec Comment # 

6. Custody seals on sample containers intact, es q No OVA O see Comme nt # 


/! 


8. All sample label information matches coc? 

Ycs 

3)e 

ONO O N/A 0 M Comment It 

° ONO ON/A• •-O see commcnt# 

P"Y 

9. Laboratory QC samples designated on coc? O Yes ONO 'WA O see Comment # 


10. Shipment meets LvLI Sample Acceptance [ g y es ONO q N/A O see Comme nt # 


policy. See reverse side for poli cy) 

11. Where applicable, bar code labels are q Yu ONO 0 M Comment It 

af fix ed to coc? 

12. coc signed and dated? 1 u q No q N/A q see Comment # 

13. coc will be faxed or emailed to client? /m / Ycs . ONO q N/A O Me Comme nt # 

1 4. Project Manager/Client contacted 

concerning discrepancies? (name/date) 

Cooler # / temp (eC) and Comments: 

^2C pia os [p / 3 

Laboratory Sample Custodian: 


q Y es ONO W


PEST / PCB ANALYTICAL DATA PACKAGE FOR 


DATE RECEIVED: 05/02/03 LVL LOT # :0305 1,329 

CLIENT ID LVL # MTX PREP # COLLECTION EXTR / PREP ANALYSIS 

B16W91 007 S 03LX0536 04/28/03 05/05/03 05/23/03 

B16W91 007 MS S 03LX0536 04/28/03 05/05/03 05/23/03 

B16W91 007 MSD S 03LX0536 04/28/03 05/05/03 05/23/03 

LAB QC: 

PBLKUG MB1 S 03LX0536 N/A 05 / 05/03 05/23/03 

PBLKUG MB1 BS S 03LX0536 N/A 05/05/03 05/23/03 

4 

3UN 03 

4 

\5tr._ . oe^

Client: TNU-HANFORD F03-006 

LVL #: 0305L329 

SDG/SAF # H2194/F03-006 

PESTICIDE 

One (1) soil sample was collected on 04-28-2003. 

Analytical Report 

W.O. #: 11343-606-001-9999-00 

Date Received: 05-02-2003 

The sample and its associated QC samples were extracted on 05-05-2003 and analyzed according to 

Lionville Laboratory OPs based on SW846, 3rd Edition procedures on 05-23-2003. The extraction 

procedure was based on method 3540 and the extracts were analyzed based on method 8081A. 

The following is a summary of the QC results accompanying the sample results and a description of any 


1. 

All results presented in this report are derived from a sample that met LvLI's sample acceptance 

policy. 

2. The required holding time for extraction and analysis has been met. 

3. The method blank was below the reporting limits for all target compounds. 

4. Two (2) of ten (10) surrogate recoveries were outside acceptance criteria. However, EPA CLP 

surrogate recovery criteria were met (i.e., no more than one outlier per sample). 

5. All blank spike recoveries were within acceptance criteria. 

6. One (1) of twelve (12) matrix spike recoveries was outside acceptance criteria. A copy of the 

Sample Discrepancy Report (SDR) has been enclosed. 


8. All continuing calibration standards analyzed prior to sample extracts were within acceptance 

criteria. 

9. I certify that this sample data package is in compliance with SOW requirements, both 


contained in this hard-copy data package has been authorized by the laboratory Manager or a 

designee, as verified by the following signature. 

I' Daniels Date 

taboratory M ager 


som4:\gmupklaWMl\tnu hanf1ord\0305-329.pes 

The results presented in this report relate only to the analytical testing and conditions ofthe samples at receipt and during storage. All pages of this report are integral pans of the 

analytical data. "erefore, this tepon should only be reproduced in its entirety of g pages. 02 

208 Welsh Pool Road a Exton, PA 19341-1313 • (610) 280-3000 • Fax (610) 280-3041

Lionville Laboratory Sample Discrepancy Repo rt (SDR) SDR #: t53%.c.2o5 

Initiator: -,t) .!•w Batch: 03 051-3z9 Parameter: 06o8 1+v 

__ 

Date: 

(0 I, 1 0' Samples: 00"1 'ii Matrix: so. I 

Client: -70 A Method: sw cAM1CLP1 Prep Batch: o3t--eco53 b 


a. CDC Discrepancy — Tech Profile Error Client RequestSampler Error on C-O-C 

Transcription Error _ Wrong Test Code _ Other 


_ Missing Sample/Extract _ Container Broken _ Wrong Sample Pulled _ Label ID's Illegible 

Hold Time Exceeded Insufficient Sample _ Preservation Wrong _ Received Past Hold 

_ Improper Bottle Type _ Not Amenable to Analysis 

Note* : Verified by [Log-In) or [Prep G roup] (circle)... signature/date: 

c. Problem (Include all relevant specific results; attach data if necessa ry) \ 

rn oc'Ir.,„f— 5e4.e^ ûP^^cale wAs h; 

1, 

^}, 4 - 

1 

N ^ K S.pr Izc 'e—C Cdk 

3Â7-' . -T1. 

7 ( . 

no (1^ fi p s «bow C-Q r .c (..; t s (^ y, 4^ -D ►DT. 

Q o'L (rari^ 


3. Discussion and Proposed Action Other Description: 

_ Re-log ro 

_ Entire Batch s l3 

Following Samples: 

_ Re-leach 

_ Re-extract 

_ Re-digest 

_ Revise EDD 

_ Change Test Code to 

lace On/Take Off Hold (circle) 

4. P oject Manager Instructions ... signaturetdate: 

Concur with Proposed Action 




Date/Person 

_ Add 

Cancel 

5. Final; Action...signarure ldate: 

Other Explanation: 

nfied re-[ log][leach][extract][di 

rlciuded in Case Narrative 



— EDD Corrections Completed 

na Ircle) 

When Final Action has been recorded, forward original to CIA Specialist for distribution and filing. 

Route Distribution of Completed SDR Route Distribu ti 

on of Completed SDR 

X Initiator 

_ _ Metals: Beagle 

X Lab General Manager. M. Tay lor_ _ Inorganic: Perrone 

X Project Mgr. Stone/Johnson/Haslett _ _ GC/LC: Kiger 

X Technical Mgr: Wesson/Daniels _ _ MS: Rychlak/Layman 

_ XX QA (file) _ _ Log-in: Melnic 

Data Management Feldman _ Admin: Soos 

_ Sample Prep: Beegle/Kiger _ _ Other: 

(]A-105-A-0801 

^ 

^j

(1(,yIVIMLpyy(„Q,MI- 

DATA QUA EMM 

GLOSSARY OF PESTICIDE/PCB DATA 

Il = Indicates that the compound was analyzed for but not detected. The minimum 

detection limit for the sample (not the method detection limit) is reported with the 

U (e.g, 1M. 

J indicates an estimated value. This flag is used in cases where a target analyte is 


quantification is • 10 ug/L and a concentration of 3 ug/L is calculated, it is reported 

as 31 

B 

E 


ABBREVIATIONS 

This flag is used when the analyte is found in the associated blank as well as in 

the sample. It indicates possible/probable blank contamination. 

Indicates that the compound was detected beyond the calibration range and was 


BS = indicates blank spike in which reagent grade water is spiked with the CLP matrix 

spiking solutions and carried through all the steps in the method. Spike 

recoveries are reported. 

BSD = 

MS 

MSD = 

DL 

NA = 

DF = 

NR = 

SP 




Indicates that recoveries were not obtained because the extract had to be diluted 

for analysis. 



Not Required. 

= Indicates Spiked Compound. 

q

^QMM1116W16GRÎN^. 

GLOSSARY OFPESTICIDE/PCB DATA 

P This flag is used for an PESTIC IDE/PCB target analyte when there is 

greater than 25% difference for detected concentrations between the two 

GC columns (see Form X1 . The lower of the two values is reported on 

Form I and flagged with a ?". 

D This flag identifies all compounds identified in an analysis at a seconda ry 

dilu tion factor. 

C 

R :IS 

This flag applies to a compound that has been confirmed by GC/MS, 

FLCREST1CME/PCBGLOS 

s


Pesticide/PCBs by GC, CLP List Report Date: 05/28/03 17:55 

RFW Batch Number: 030SL329 Client, TNOHANFORD F03-006 H2194 Work Order: 11343606001 Page: 1 ':^-D- 

Cust ID: B16W91 B16W91 B16W91 PBLICUG PBLKUG BS 

Sample RFW#: 007 007 KS 007 NSD 03LK0536 -NB1 03L%0536-NB1 

Information Matrix: SOIL SOIL SOIL SOIL SOIL 

D.F.: 1.00 1.00 1.00 1.00 1.00 

Units: UG/KG UG/KG UG/KG UG/KG UG/KG 

Surrogate: Tetrachloro-m-xylene 100 W 95 k 105 %; 100 % 95 

Decachlorobiphenyl 125 * 1; 120 125 * t 120 !k 115 . 

____________________________________`___===== f1=====__===== f1=====__===== f1=====__=====f1=====__===== fl=====__=====f1 

Alpha-BHC 1.8 U 1.8 U 1.8 U 1.7 U 1.7 U 

Beta-BHC 1.8 U 1.8 U 1.8 U 1.7 U 1.7 U 

Delta-BHC 1.8 U 1.8 U 1.8 U 1.7 U 1.7 U 

gamma-BHC (Lindane) 1.8 U 104 % 114 1.7 U 104 %; 

Heptachlor 1.8 U 98 % 106 1.7 U 102 !t 

Aldrin 1.8 U 94 k 104 1; 1.7 U 96 t 

Heptachlor epoxide 1.8 U 1.8 U 1.8 U 1.7 U 1.7 U 

Endosulfan I 1.8 U 1.8 U 1.8 U 1.7 U 1.7 U 

Dieldrin 3.6 U - 112 t 121 k 3.3 U 112 $ 

4,4'-DDE 3.6 U 3.6 U 3.6 U 3.3 U 3.3 U 

Endrin 3.6 U 118 96 128 %, 3.3 U 115 %r 

Endosulfan ii 3.6 U 3.6 U 3.6 U 3.3 U 3.3 U 

4,4'-DDD 3.6 U 3.6 U 3.6 U 3.3 U 3.3 U 

Endosulfan sulfate 3.6 U 3.6 U 3.6 U 3.3 U 3.3 U 

4,4'-DDT 3.6 U 114 !k 124 * % 3.3 U 107 $ 

Methoxychlor 18 U 18 U 18 U 17 U 17 U 

Endrin ketone 3.6 U 3.6 U 3.6 U 3.3 U 3.3 U 

Endrin aldehyde 3.6 U 3.6 U 3.6 U 3.3 U 3.3 U 

alpha-Chlordane 1.8 U 1.8 U 1.8 U 1.7 U 1.7 U 

gamma-Chlordane 1.8 U 1.8 U 1.8 U 1.7 U 1.7 U 

Toxaphene 180 U 180 U 180 U 170 U 170 U 

U= Analyzed, not detected. S= Present below detection limit. B= Present in blank. NR= Not reported. NS= Not spiked. 

^= Percent recovery. D= Diluted out. I= Interference. NA= Not Applicable. *= Outside of EPA CLP QC

Lionville laborato ry Use On ly Custody Transfer Recom/Lao WOO nCyuVOL rd1jv I v, 1 

SL.3^ 


Client ^nl 1{^ ^j?).-[YY o R°trlg°r't°r s a 

Est Final Pro]. Sampling Date pr 

YPe Container 

Project to 

Liquid 

Project COnticbVhOne I volume 

so li 

Llomrille 

d 

Laboratory Pro]ec4 Manager CL 

Preserva tives - - - - 

OC - Del °^- _ TAT 

ORGAMC INORG 

Date Recd {^î Date Due 1n-1-tl 

ANALYSES 

LWuid 

Soil 

REQUESTED --^ O z< 

a a 2 U 

MATRIX 

CODES: 

S- Sod 

SE - Sediment 

Lab 

ID Client IDvD dptlon 

- Matrix 

^„n 

(W) 

Ma trix Date nme 


= 

do 

u 

L ionvil le Laboratory Use Only 

99 

x 

& 

10 

C 

j 

(^ 

SO - Sold 

SL- Sludge 

w • Water 

MS MSD 

N N 

O- Oa 

A- Air Drum 

DS - 

3 

Solids 

DL- Drum 

Liquids r 

L- EP?CLP 

Leechate 

wl - Wipe 

X - Omer 

F- Fish 

1 3 

V LI I 

Special Instructions: 

I 1,^,., 

l l.- ` j 

©^ 

\ X 

DATE/REVISIONS: 

1. 


Samples were/ Tamper FesStanl Seal was 

^S is "FU7/ 1) Shippetl ^/— or 7) Present Outer 

2 • Hand Delivered — Packaged or N 

Airbll X 2) Unbroken on Outer 

3. 

Package Y or N 

4. 

5. 

2) Amblem orN 

3) Received in 

Condition C 

3) Present Sample 

N 

1.1 or 

or N 4) Unbroken on 

Received DMe nma 

a. 

Relinqu ished Rece 

4) Samples 

Prapedy Pr rued 

Sample C-) or N 

Record Present 

iv Relinquished 

by I ry 

ed 

by I by 

^^ 

O A 

Data 

yrw 

Time Discrepancies Between 

Samples Labels 

COC Record? Y moor 

or N 

5 ed Within 

Upon Semple Rec't 

or N 

I ' 402 t_' % HdduV 

NOTES: 

F Fr+F - T77 or N Temp. -C 

RE ItTE LY03 3a

M—Central Plateau P roject CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-62 I Paee t of t 

Collector 

Johansen/PoWNster 



Ice Chest No. C 

/C L 

Shipped To 

POSSIBLE SAMPLE RAZARD 


O S / 

/^/¢ 

22r 





216-A-37 (C4106); (12.5'-151 - 

Field F F No. 

N N 335 

Olfaite Property No. ^y 

V 

Preservation 



Co iner(s) 

Volume 


B16W79 SOIL 

11504ES I0 


TRENT, SJ Price Code 8N 

SAF No. 

F03.006 

Method press 

Federal Ex 

Ô Bill of Lading/Air Bill No. 

Cod 4C Cod 4C - Coa14C Noes None 

aG aG . G oG 

I I I I 

120mL 60ML 120ML 60ml, /6L 

CTmmhs NO2M3- aiacreue . Smirnn(0' rmetm -xt 

H. -71% 353.2 4u.1 stKdd 

IN OF POSSESSION Sign/Print Names SPECIAL INSTRUCTIONS /I 2 z a3 

elinquished B ved Fm DaWrum (f` Received B /Stored m Dmeainic 

Ref= ( 3-72-O- q L î^3 6 /(^ 

eh 'shed By/Removed F_7Zt 13 

DatNr®e '' Re ce ived ByStoved In Date/rime 

cS O^ ^^^8 

eli,ximshed BylR From Datefrme 

Received BY/Stomd 

Datdrime 

SJ I E datQ>z 0 

el' B Svcd From Dme/rmre 

S.^.a3 O 

—6 r X 

Re«i t m DaWTime 

S.a.Q. Q _ 

Relinquished By/Removed Fmm Datertime Received B In Datr/raoe 

languished By/Retroved From Daterime Received By/Stored in Dater®e 

Air Quality p 

dF E--),5 PJr, 

•a-TheIft a J a t' f to o j f •• The laboratory is to 

report both kemune and diesel mile compounds from WIPH-D analysis. 

(1) Tedi etims 00 S e9 90 Tom] Sr Isotopic{ Thai 

a, e- 

-tom / 

.4— V iZ LOJ 

Persoimel not available to 

relinquish samples rota the 3728 

LABORATORY Received By Tide Datefrlme 

SECTION 

FINAL SAMPLE Disposal Method Duposed By Date/Rme 

DISPOSITION 

BHI-EE-011 (03101/2002) 

Ref # 

Data Turnarou 

45 Days 

Matrix 

se 

so-sda 

M-&WV 

W.W. 

o-1 

os-oe.. sam 

tx'ne Lrl 

Tom. M-wpe 

V-V 

v'vèe"'°° 

x-ane

F$-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-63 I 

Collector Company Contact Telephone No. Project Coordina tor 



200-PW-2200-PW-4 OU - Borehole Soil Sampling 216-A-37 (C4I06); (17.5'-20) F03-006 

Ice Chest No ^-/^ Q 

L''` /^ 

(! 


J b kDdF-N-3361 117504ESIO Federal Express 

par i of ! 

Price Code $r( Data Turoa ro 

Air Quality q 

Shipped To - 

Z 0 

OfGite Property No. /l o i{ 

40 cJ 

^1 

CJ 

Bill of Lading/A r Bill No. a^ QS y G 

/ 

POSSIBLE SAMPLE HAZARDS(REMARKS 



Prese rvation 



Volume 


B16W80 SOIL Z{r Uj (;o J^ 7L 

Cad 4C Cod 4C Cod 4C None N. 

aG aG aG aG 

I I I ) I 

120m], Wait, Word. 60nd, 611mL 

aaamhw NO2 03 . nit& Caere- scene.(I)h. T66,111 

H.-71% 353.2 4 13.1 Spedd 

Cl 

45 Days 

IN OF POSSESSION Sign/Print Names 

Relisgtdshed /Rmnovsd Fmm ime ived By^rs3e«w )n 

/A g72 $ 

e uqut96ed By/Removed F Diedfune Received By/Stored In 

s 11 - 37Zg s 1 133 1 %(56 bJfrrllF 

Rel 

Bylkeenovel Daterrime 1100 Re 

shed 


DaWrnne 

•• 

L' 

7 Z$G`^ Ib 141 

report both kerosene and diesel range compounds from wIYH-D analysis. 

Date/fume 

— 

S / 03 

1 10 C) .I1P M,,kel-6l Nnm^nium-237 

----^—__ ^^^zs/o3 


- 

Matrix' 

5-seit 

sa.s^meu 

so 9a 4 

9-siwse 

W.W. 

0..71;, 

us-m.m saw 

ce ived By/Stor d In 

SJ 6 L 

s 1 03 fzgJ2 Eh 

Rel' By/Rmmved ^âae ReceivdkQ /St fa 

e.CY>'l^ 

elm"shed By/Remm2d Fin n 

Date/rime 

Datdfime 

O Y6 



to o muwa. 

wi w,, 

s-Wua 

v-vaaam 

x-omn 

Daterrnne Received toed In Dat 

dfaae 

eIvpuished By/Removed Dat&Time 

Ref # Mon 5/x_/0 

From Datdrime Received By/Stored N 

LABORATORY Received By Tide Datdfime 

SECTION 

FINAL SAMPLE Disposal Method Disposed By Datdfime 

DISPOSITION 

BHI-EE-011 (03101/2002)

FE-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-64 1page I of I 


Johansen/Pope/P fister LC Hulstrom 373-3928 TRENT, SJ 

Project Designation Sampling Lo ca tion SAF No. 

200-PW-21200-PW-4 OU - Borehole Sod Sampling 216-A-37 (C4106); (27.5'-30) F03 0" 

Ice Chest No. may} / 

EP, C, q (,p O .5,6 

Feld Logbook No. COA Method of Shipment 

HNF-N-3361 117504ES10 Federal Exp ress 

Shipped To e.4e OQsile Property No. ,[]_d O Bill of Lading/Air Bill No. 

POSSIBLE SAMPLE HA7,ARDS/REMARICS 


Preservation 



Con 

Volume 

Cod eC Cad eC Cool /C None None 

SIG A aG aG 

I I 1 I 1 

120011, 60m 60m], 12001E 60m], 60 a). 

Cloomn. NO24403 - Oak Co.. Seehao (1) Tdtiom-N) 

Flat-)196 )5).) 413.1 SgciJ 

l 

- SAMPLE ANALYSIS II tJ 

v 

Sample No. Matrix " Sample Date Sample Time 

B16W81 SOIL 

Price $]v Data Turnarou 

Air Quality q 

45 Days 

el' 


y 

By/Removed From 

I 

Sign/Mat Names 

cane lved By/Sto ted In P^ 

1 ` 

im I't^ Received fl taed m 

3 I 

tern e 

D teirime I k 

. Z-'- ^ 

SPECIAL INSTRUCTIONS d) 

a . •' The Iabonto ry is to 

mpott both kerosene and diesel range compouodt from WPPH-D analysis. 

^'k" sv N 

J' / 

)" //7 Z/ J3 

Matrix " 

s-sdi 

-ysan 

so-swu 

n-smsa 

W eW- 

Relinquished OyAtFinoved Fran kne Received ived BY/Stomd In 

ae rime 

1106 

A-A 

os ore sdm 

37 11 oa ^J 103 oi, a L4 a. 

Refmgmshed B y/R ved Fm DmNI'ime 

Received By/Stomd In Daterrime 

' 

Personnel not 

Re ved From Da111C Recei m N DnlNrime 

available to 

.,^ 0> '^ 7- ' 63 C relinquish samples from the 3728 

Ref ffIf—On 

Rehoquidted By/Rmved By/RemovedFrom 

Dateffune Received By red In Dsterrime 

LABORATORY Recdved BYTitle SECTION 

Date/Taue 

FINAL SAMPLE 

DISPOS 

Disposal Method Disposed By Datefrime 

IT 

ION 

BHI-EE-011 (03/012002) 

qM 

wn 

InigN 

v-v'Nm

FH-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-65 Paee 1 of 1 


Johanua/Popupfister LC Hulstrom 373-3928 TRENT, SJ 

Project Designation Sampling Loca tion ^No• 

200-PW-2200-PW-4 OU - Borehole Soil Sampling 216-A-37 (C4 106); (37.5'-40) F03-006 

Ice Chest No.! O S Field Logbook No. COA Method of Shipment 

L 7,4 Y HNF-N-3361 117504ESIO Federal Express 

Shipped To 

5BG 

POSS IBLE SAMPLE RAZARDSW24ARK 

Property No.11 .^ 

/l-Cl 

^^ 

Bill of Lading/Nr Bill No. b 

Preservation 

Pre va tioR 

Cod 4C Cod K C od aC Nom Nom 




No. of Con tainer(s) 

Volume 


aG aG aG aG 

1 l t 1 1 

120m1, 60ML 120mL 60m 1, 60mL 

M.ad. NO2RI03 - OIIaCeeme . aeehea(1)' Trahm-w 

N -71% 353.2 413.1 Spedd 

`vv 

1 

Price Code 8N Data Turnarouo 

Air Quality EJ 

45 Days 

B16WB2 SOIL ,`l-r9 f (f q0 F 

CRAIN OF POSSESSION Sign/Print Names SPECIAL INSTRUCTIONS Wk— 22 T3 

' a " The labo ra Ma 

tory is to 

tr ix 

p Re S-W, 

ce ived By/Stored in IF IZC—t ime 

/ IqU\ report bah kerosene and diesel range cear pounds boat WTPH-D analysis. ^y6^ 

Re' By ved From DdWTakI ^, Received /Stoned In ' L. p ^r-e.^ 

12 "—.-=r=e-^7iT 

'i 

_ /1 ( die_ y/ ^^ t 1/OS 

w- Wee. 

POs 

ebngnusbed By 

3 Z 

ved Fmm n 

s j o 3 

^ 

lloo 

Received By/Stored Ihldfime 

1 0"!> 106 

cos-n„m sae 

m.om. uwa 


J O 

Date/l ime 

1 

Received By/St to Dste/fane 


Mme w7.Wia• 

L-Upw 

v.Vq 

lun 

Front, DaWTone N Date/Time 

o3 

i relinquish samples from the 3728 

09 A Ref # -f lLon S /L_l cJ 

X' 

elmgtdshed By/Removed From Datr/rime ReceivedBf/SuIred /S N Datr/ffine 

LABORATORY Received By Tide Datdfime 

SECTION 

FINAL SAMPLE Disposal Method Disposed By DatcTum 

DISPOSITION 

BHI-EE-0 11 (03101/1002)

F11-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-66 Page 1 of 1 

Collector 

JohansentPope/Pfister 

Project D es ignation 

200-PW-2200-PW4 OU -Borehole Soil Sampling 

lee Chest No. ^'^ C Q O 

Company Contact Te le phone No. 

LC Hulstrom_ 373-3928 


216-A-37 (C4106); (47.5'-5(Y) 


HNF N-3361 I 

COA 

117504ESIO 


TRENT, SJ 

SAF No. 

F03-006 



Price Code 8N 

Air Quality q 

Shipped To lffsite Property No. O Z D Bill of Lading/Air Bill No. s ^^ 

A0 :5 Z— O^ L 

POSSIBLE SAMPLE HAZARDSIREMA 



Preservation 



Volume 


Coot 

Cent 

CaeieC t'ne Nees 


I I 1 I 

120ml, 60ml, 120mL 60mL 60mL 

Ciaemum 

1Ia^-)196 

NOVNW) 

553. 2 

aiaoroe- 

4111 

B16W83 SOIL 7 7 


BY. 

Sign/Print Nam es 

Dater Received By/Stamd to r ire_ 

/ 

Ta 

See . (W 

SparL1 

Tmwm-1n 


LG Pf 

•^ . 

report both kerosene and diesel rm8e connpounds from WIYH-D amlysls. 

)jyquisWB 

P 

From ^L 

N Y 

Dat , ^%00 Re ce ived y/St N^ 

^ 

4.ê L e ff ( 1) n — ou 

. 0 w,-.Fds3 xe„o—„,m_2 ^ 

3 t'g;_—__^ 

r, Isotope um noun~ 

71 L ô j 

Relinquished ByasmdGd From 

10111drune, 

Received By/Stared 

Datefrime 

3 2 1 0-) l 1 00 g S) O^ j00 

Relinquished By/Reme F to Daterene 

S 1 03 

R ByIR ved From Dale/Tme 

eInitushcdBy/Rem +vedFrom DetJCune 

Received By/Storedl. 

I /00 T't' L 

Received §y/$t d 

,jyL^ 

Received By 

DeWTune 

s.,, ^3e 

DatHfime 

Personnelnot available to 

relin uish sam P I es f 

Ref# / ^ 

rom the 3728 

.^+1-on 

- 

t 

/ 

The laboratory is to 

LABORATORY Received By Tide Date Time 

SECTION 

FINAL SAMPLE 

DISPOSITION 

Disposal Wiled 

Disposed By 

Datelrune 

BHI-EE-011 (03/012002) 

Dam Turaaro 

45 Days 

Matrix 

s-sen 

sec-s.m.ee 

so-sd'd 

n-auaae 

0-0d 

mm, 

ni t). m 

r+rmue 

wt-v” 

X^

F11-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-73 JPw 1 4 

Collector Company Contact Telephone Na Project Coordinator 

Johansen/Popeftster LC H illstrom 373.3928 TRENT, SJ 

Project Designa ti on Sampling Location SAY No. 

200-PW-21200-PW-4 OU - Borehole Soil Sampling 216-A-37 (C4106); (17.5'-29) F03-006 

Ice Chest No. —{(^5y 

I— 1z C 

p / 

i l^ 

C 

03 


HNF-N-3361 I 

COA 

117504ES10 



Bill of Lading/Air Bill No. 

Shipped To ^^+^ ,^^rL Offsite Property No. 1t ^ ,3 0 Z 2 o 

IT 3 

POSSIBLE SAMPLE HAZARDSIRE 


Pr Preservation 



Volume 

Cod 4C Cod 4C Coot 4C N. Nor 

aG aG aG aG a 

1 I 1 1 1 

120mL 60mL 120nd, 60mL 60mL 

Chromium N=403- Oil&Cave- Sxuem(gm T ritium .M 

Hex-71% 3 52.2 413.1 spe ci d 

SAMPLE ANALYSIS rI 

Sample Na Matrix • Sample Date Sample Time 

B16W90 SOIL 0; S' 00 

A ^` 

Prue Code $N Data Turoarouo 


ash ^- 

CHAIN OF POSSESSION SigdPrint Names SPECIAL INSTRUCTIONS q f/2 L emoved F mle Received Byômd N 

Rc-P I R 3775s 

Daterrime - 

ZS o3 /6 y5 

d 

- 

repo 

'• The laboratory is to 

Matrix 

sns 

rt botll kerosene and diceel range compounds from WIPli-D analysis. ss-smAe. 

Rd. fished By/Removed Fm DatcTum, 

R - I a°r 37 2d / o 

j 

x16 0 

Received By/Stored In Datelrirme 

ZJ LZ 5103 /,'CC) 

a..:-., , ,7 

`l 

jlto) 

mn- 

W-W r 

os-o,^„sam 

EYDatdrime c7 ^j 07 1100 

eceived By/Store tieDaWrim 

F= t: G m.mê w 

By td F T-T 

ro m Da Nrime 

G3 0 i5 

Relinquished By/Removed F 

Received in DuseTime 

S--,X,03 0 


nd 

v vgeawo 

x-aê 

ro mDidrJTimis Received By/S In Doerrime relioquishh amplerfrom 

the 3728 

Relinquished By/Removed From Date/Pbme Received By/St ored In Datdrime 

Ref # t r - on = = 00; 

LABORATORY Received By Title Daterrime 

SECTION 

FINAL SAMPLE Disposd Method Disposed By Daterrime 

DISPOS IT ION 

BHI-EE-011 (03101 12002)

M-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS RE UEST F03-006-74 ^^ 1 Df i 

Collector Company Contact Te le phone No. Project Coordinator 

Johansen/PopelP lister LC Hulstmm 373-3928 TRENT, SJ 

Project Daignation Sampling Location SAF No. 

200-PW-2200-PW-4 OU- Boreho le Soil Sampling 216-A-37 (C4I06); (0.5') F03.006 

Ice Chat No. 6—R ^ 

Fie ld Logbook No. COA Method of Shipment 

G 09'(,0 

HNF-N-3361 117504ES10 Federal Express 

Shipped To W5163 ,^ 214 Offsite Property No.// a, (/ Y O y Z ^r 

! / C/ 

^ V 

POSSIBLE SAMPLE HAZARDSIREMARKS 

Preservation 

cod K Cad eC 


- 




Volume 

Sample No. Ma tr ix • Samp le Date Samp le Time 

B16W91 SOIL Zy 0 

I 

aG sG 

I I 

60a 250m1, 

Penmdemer 

CNom- 

Reaivae- 

Frnatst 

Bill of Lading/Air Bill No .5 

Price Code 8N Data Turnaroun 


N OF POSSESSION Sign/Print Names SPECIAL INSTRUCTIONS Matrix 

proved m 

61 

P /Removed F m 

;r 

elinquidied Byatemoved tom 

batdChne 

DatwTime 

5103 11 0 c) 

Ihtdl'ime 

ved By/Stored N Date rime 

pc-F 37a$ ^Z^ 03 /bYS 

Received By/Stored In DateTime 

d / o-5 /lod 

Received By/St In Datrllime 

s-sm 

^-° 

so-Ww 

st-9w, 

^" 

MAv 

D5-on mW 

Bykemovexl From Daterriene Received $y/ In ^^ê 

0 

.1fj',- ! Dacdfime O 

Relinquished By/Removed From Dstefrime 

Received BY t In 

rlinquWmd By/Removed From DateTime Received By/Stored to Datefrime 


SECTION 

FINAL SAMPLE 134oa 111 Method 

DISPOSITION 

BHI-EE-011 (03/012002) 

Tide 

; f om the, T 

Qenon01 noa+P 

_ - 

re\in4uil5âol^ 

lief 1♦ +^ 

Dwposed By 

DaWrmw 

Datcrrime 

T-rawe 

wl-wipe 

,,;a„



IENT: IT{U Hat^ r 

chase Order/Projeot: DATE: S °^ 

7SOW# / Release #: F63-00(, 

"story SDG il: 

Czos (- S ag 

ITE: ALL ENTRIES MARKED "NO" MUST BE EXPLAINED IN THE COMMENT SECTION 

1, Custody seals on coolers or shipping 

container intact, signed and dated?. 

es ONO 0 WA 0 see Comment N 

2. Outside of coolers or shipping containers are Yes ONO O NIA O see Comment N 


3, Airbill M recorded? 

y es 

)I 

ONO O NIA O sec Comment N 

4. All ,expected paperwork received (coc and 

other client specific: historical data 

alphwbeta or other screening data as 



IXYcs ONO O N/A O see Comment N 

S. Sample containers "'Ve ntact? es ONO O NIA O see Comment N 

6. Custody seals on sample containers intact, es ONO O NIA O see Comme nt N 


7. All samples on coc received? Yes O No O N/A O see Comment if 

8, All sample label information matches coc? 

pots 

ONO O N/A • O 

sec Comment N 

9. Laboratory QC samples designated on coc? O Yes ONO 6WA O see Comment N 

(QC stickers placed on bottles?) /° 

10, Shipment meets LvLI Sample Acceptance yu ONO O N/A O see Comme nt N 

Policy? (identify all bottles not within 

policy, See reverse side for policy) 

11. Where applicable, bar code labels are O yes ONO 11ZLIN/A O see Comment N 



/ ^ 

cs ONO O N/A O at Comment N 

13. coc will be faxed or e ntailed to client? QYes • ONO O N/A O see Comment N 

14.-Project Manager/Client contacted 

conce rn ing discrepancies? (name/date) 

Cooler # / temp (°C) and Commen ts : 

E, .CC. cif-05(, / t .3 


O Yes q No t9'fa/A q sec Comment N

DATE RECEIVED: 05/02/03 


PCB ANALYTICAL DATA PACKAGE FOR 


°n 

LVL LOT # :0305 1, 329 


B16W79 001 

B16W80 002 

B16W81 003 

B16W81 003 MS 

B16W81 003 MSD 

B16W82 004 

B16W83 005 

B16W90 006 

LAB QC: 

PBLKTS MB1 

PBLKTS MB1 BS 

S 03LE0576 04/28/03 

S 03LE0576 04/28/03 

S 03LE0576 04/29/03 

S 03LE0576 04/29/03 

S 03LE0576 04/29/03 

S 03LE0576 04/29/03 

S 03LE0576 04/29/03 

S 03LE0576 04/28/03 

S 03LE0576 N/A 

S 03LE0576 N/A 

05/14/03 05/21/03 

05/14/03 05/21/03 

05/14/03 05/21/03 

05/14/03 05/21/03 

05/14/03 05/21/03 

05/14/03 05/21/03 

05/14/03 05/21/03 

05/14/03 05/21/03 

05/14/03 05/22/03 

05/14/03 05/22/03 

I ^^ 

C

Client: TNiJ-HANFORD F03-006 

LVL #: 0305L329 

SDG/SAF # 1 12194/1703-006 

PCB 



W.O.#: 11343-606-001-9999-00 


The samples and their associated QC samples were extracted on 05-14-2003 and analyzed according to 

Lionville Laboratory OPs based on SW846, 3rd Edition procedures on 05-21,22-2003. The extraction 

procedure was based on method 3540 and the extracts were analyzed based on method 8082 for Aroclors 

only. 

The following is a summary of the QC results accompanying the sample results and a description of any 


1. All results presented in this report are derived from samples that met LvLI's sample acceptance 

policy. 

2. Samples were extracted outside of holding time. A copy of the Sample Discrepancy Report 

(SDR) has been enclosed. 

3. Samples and their associated QC samples received a Sulfuric Acid and Sulfur cleanup. 


5. One (1) of twenty (20) surrogate recoveries was outside acceptance criteria. However, EPA CLP 

surrogate recovery criteria were met (i.e., no more than one outlier per sample). 

6. The blank spike recoveries were within acceptance criteria. 

7. All matrix spike recoveries were within acceptance criteria. 



criteria. 





Gi 

n Daniel ate 

Laborato anager 


somtr:\group\datatpest\mu hanford\0305-329.pcb 

The results presented in this report relate only to the analytical testing and conditions of the samples at receipt slid during storage. All pages of this report are integral parts of the 

analytical data. Therefore, this report should only be reproduced in its entirety of 1 5 pages. 

208 Welsh Pool Road a Exton, PA 19341-1313 a (610) 280-3000 • Fax (610) 280-3041

Lionville Laborato ry Sample Discrepancy Repo rt (SDR) SDR #: 

Initiator: a o ^- - ^-, , \, • Batch: 03o L 3i5. Parameter: 

Date: b W) \ U ) Samples: I- 6- Matrix: 

Client: 'r IV Method: SW84 61MCAVWV1CLP/ Prep Batch: 

O , C r3 . 

Sor] 

oa L-E- ail/, . 


a. CDC Discrepancy _Tech Profile Error 

Transcription Error 

Client Request 

_ Wrong Test Code 

Sampler Error on C-O-C 

_ Other 


_ Missing Sample/Extract Container Broken —Wrong Sample Pulled _ Label ID's Illegible 

_ Hold Time Exceeded 

_ Improper Bo ttle Type 

_ Insufficient Sample 

_ Not Amenable to Analysis 

_ Prese rvation Wrong _ Received Past Hold 

Note: Verified by (Log-In] or [Prep Group] (cirde) ... signatu re/dale: 

c. Problem (Include all relevant specific results; a ttach data if necessa ry ) 



_ Re-log 



(v 4 

—'Re-leach 

Re-extract 

_ Re-digest 

_ Revise EDD 


— Place Onfrake Off Hold (circle) 

4. Project Manager Instructions ... signatu,e/datc 



_ Include in Case Na rrative 


Date/Person 

_ Add 

Cancel 

5. Final Action... signature/date: °tr7 N Other Explanation: 

Verified re-Ilog][leach][extract][digest][onelysis] (circle) 

3_ ]ncluded in Case Na rrative 



_ EDD Corrections Completed 

When Final Action has been recorded, forward original to QA Specialist for distribution and filing. 

Route Distribution of Completed SDR Route Distribution of Completed SDR 

X Initiator _ _ Metals: Beagle 

X Lab General Manager. M. Taylor _ _ Inorganic: Perrone 

_ X Project Mgr: Stone/Johnson/Hasle tt_ _ GC/LC: Kiger 

_ X Technical Mgr: Wesson/Daniels _ MS: Rychlak/Layman 

— X QA (file) _ _ Log-in: Melnic 

_ _ Data Management: Feldman _ Ad min: Soos 

_ Sample Prep: Beegle/Kiger _ _ Other. 

QA-105-A-0601 

r

tRMp1NCE1@Ntl^Y't. 

DATA QUALIFXFOS 

U 

GLOSSARY OF PESTICIDE/PCB DATA 

Indicates that the compound was analyzed for but not detected. The minimum 

detection limit for the sample (not the method detec ti 

on limit) is reported with the 

indicates an es timated value. This flag is used in cases where a target analyte is 


quantification is'] o ug/L and a concentra tion of 3 uglL is calculated, it is repo rted 

as 3J. 

B = This flag is used when the analyte is found in the associated blank as we ll as in 

the sample. It indicates possible/proliable blank contamination. 

E = indicates that the compound was detected beyond the calibra tion range and was 

subsequently analyzed at a dilu tion. 


A 33 13REVIATJ ONS 

BS s Indicates blank spike in which reagent grade water is spiked with the CLP matrix 

spiking solutions and carried through all the steps in the method. Spike 

recoveries are repo rt ed. 

DSD 

MS 

MSD = 

DL = 

NA = 

indicates blank spike duplicate. 



Indicates that recoveries were not obtained because the extract had to be diluted 

for analysis. 


DE = Dilution Factor. 

NR = 

SP - 

Not Required. 

Indicates Spiked Compound.

P 

D 

^CIHHUICtSIdIMN^- 

GLOSSARY OFPESTICIDE/PCB DATA 

This flag is used for an PESnCIDWCB target analyte when there is 

greater than 25% difference for detected concentrations between the two 

(,C columns {see Form X^. The lower bf the two values is reported on 

Form I and flagged with a "P" 

This flag iden tifies all compounds iden ti 

fied in an analysis at a secondary 


C = This flag applies to a compound that has been confirmed by GC/MS. 

RJSaApZ,V^SnCMWCBGLOS


PCBs by GC Report Date: 06/17/03 15:45 

RFW Batch Number , 030SL329 Client, TNUHANFORD F03-006 B2194 Work Order: 11343606001 Page: 1 

Cust ID: B16W79 B16W80 B16W81 B16w81 B16WSI B16W82 

Sample RFW#: 001 002 003 003 MS 003 MSD 004 


D.F.: 1.00 1.00 1.00 1.00 1.00 1.00 


Surrogate: Decachlorobiphenyl 100 W 90 t 95 !k 

Tetrachloro-m-xylene 60 t 75 k 85 

Aroclor-1016 16 U 16 U 16 U 

Aroclor-1221 16 U 16 U 16 U 

Aroclor-1232 16 U 16 U 16 U 

Aroclor-1242 16 U 16 U 16 U 

Aroclor-1248 16 U 16 U 16 U 

Aroclor-1254 16 U 16 U 16 U 

Aroclor-1260 16 U 16 U 16 U 

Cust ID: B16W83 B16W90 PBLKTS 

PBLKTS BS 

Sample RFW#: 005 006 03L80576 -MB1 03LE0576-MB1 


D.F.: 1.00 1.00 1.00 1.00 


Surrogate: Decachlorobiphenyl 120 %; 100 %, 105 k 100 t 

Tetrachloro-m-xylene 120 * 90 % 85 W 85 

105 95 105 

90 85 90 

98 t 96 16 U 

16 U 16 U 16 U 

16 U 16 U 16 U 

16 U 16 U 16 U 

16 U 16 U 16 U 

16 U 16 U 16 U 

102 % 96 % 16 U 

_____________________________________________ fl=====__===== fl=====__===== fl=====__===== f1=====__===== f1=====__=====f1 

Aroclor-1016 

Aroclor-1221 

16 

16 

U 

U 

16 

16 

U 

U 

15 

15 

U 

U 

92 

15 U 

I(lLr 

Aroclor-1232 16 U 16 U 15 U 15 U 

Aroclor-1242 16 U 16 U 15 U 15 U 

Aroclor-1248 16 U 16 U 15 U 15 U 

Aroclor-1254 16 U 16 U 15 U 15 U 

Aroclor-1260 16 U 16 U 15 U 94 !k 


t= Percent recovery. D= Diluted out. I= Interference. NA= Not Applicable. *= Outside of EPA CLP QC

Lionville Laborato ry Use Only 

X51-3a- 

Custody Transfer Record/Lab Work Request Page-Loft 

FIELD PERSONNEL: COMPLETE ONLY SHADED AREAS n r?^ 

Refrigerator # 2, 

Client ^T-n 1- "0C&r!(- 1=n^-o[1 O 

aqua 

Est. Es Final Pro j Sam Dlin9 Data 

#'lfYpe container 

Project# 

PrG^Ct ContacWhons # 

Volume 

Lionville Laboratory Project Manager 1:^n 

Preservatives 

Ef vLl 

Solitl. [ 

oC Del. TAT 

ORGANIC INORG 

Date Rec'd C: , ? ^_ Date Due 

6- It,. o] 

z 

y-i°r* T'_fl^+t•± 

ANALYSES—^ Q < a m 

m 

m 

REOUESTED O > 

Z 

m 

m U 

a s 2 

`m V - 

MATRIX 

CODES: 

s - Sea 

SE - Sediment 

Lap 

ID CIie Client IDIDeacripd on 

Matrix 

OC 

Chosen 

(be) 

Matra 

Date Time 

C ollected Col lected 

= 

j 

u 

(J 

'dla 


(^ 

U 

C 

0 

G 

j 

SO - SeaH 

MS MSD 

F+ 

SL- SNtlge 

W - Water 

0- OII 

A- Air 

DS- Drum 1 3 

S ol ids 

DL- Drum 

Ucods 

L- EP/TCLP 

114 

Leac mte 

WI- Wipe 

3 

X Other 

F- ' Fish 

~ 

1 3 

Special Insbuctions. n " elm ©C 

DATEIREVISIONS: 

S-1+01, 1. pu C(af ^.e lêê ;-Ib btl) 

r 'ta1 

t-T rU^W^ 5 (rte p 41 --# -g0^ f}dd A^,A! 3 da ^t g•.(d Cr, Ca, 

Relinquished 

F 

f' 

Ex 

^^ 

Received 

Date Time 

liquid 

flRE ITT '' 

I I 

I 

Solid 

3 


Samples we Tamper Resistant Seal was'. 

) Shipped ^/—or 1) Present nouter 

Hand Deuvered _ Packagea) or N 

3 tT— S^ S#^LCe CI. FI BO) IVat ;T Anbtll# 2)Unbraki on Outer 

1N1 ^^Dz!'JFY_W Package Y or N 

4 1NH3N r^-r0 V ii db *14 ri QliI X 0(aCJC 2)Ambiem or !ftq 

` 

3)Present Sample 

3) Received Good ood ^ or N 

S OPCe ODO4 r Q fz R.^ 

Condition 

Y"1 or N 

4) Unbroken on 

4) Samples Sample U or N 

6. 

Progeny Pr rved 


Ragn quished Received Date * Time Discrepancies Between Y or N 

Upon Sampia Rec't 

by by 

Samples Labels end 6) Ring 71 Within V or N 

Q 1•^ 

COC Record? Y or , 'â ^ n^ 

N) Holding 71 s Cooler 

NOTES: M or N Temp. -C 

,—

FH-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS RE VEST F03406-62 t dt i 


JohansenlpopdPCster LC Huistrom 373-3928 TRENT, SJ 

price Code 8N Data Turnaround 


200-PW-2200-PW4 OU - Borehole Soil Sampling 

Sampling Loca tion I 

216-A-37 (C4106); (12.5'-151 

SAF No. 

F03-006 

Ice Chest No. "-7^ L q / 

/C 

os /- 

Y 


HNF-N-3361 

COA 

117504ESIO 


Federal Exp ress 

Shipped To 


VrX0f 

IZo 

O/faue Property No. n Bill of Lading/Air Bill No. Cî'>d ^?^_ 

Special Handling and/or Stooge 


Preservation 

Cud 4C (ad 4c - Cod 4C NM Nom 

Type of Container aG aG &13 80 

No. of Coohiner(s) 

Volume 


816WT9 SOIL G^ 

I I I I 

120mL 60nd. 120m. 60ML 60mL 

bmmimi NOLNO3- OilkOtease- See item (1)' Tritium-IO 

14,71% 353.3 413.1 Spedd 

(Dingo . 

Air Quality q 45 Day& 

IN OF POSSESSION 

Reiinguidw B ved F DatNl'tme 


(9Cr Re3êived Byrstetw N G 

nr 

)2c—F) A 372.p 

(' p 

7 zgo0 

Date?ime 

1 6 / 

SPECIAL INSTRUCTIONS E 2 r j 

a w . f f 50 0 C t r 

1cpon ^ knomne aM diesel nap campamds fmm W'IPH.D analysis. 

•• The tabomory is to 

`f F^-Têêemn-âOi e._...^ .., so m T_..t e.. ) Relitp ' By/Removed Frod DatoTime)) Received By/S(oted N 

-aJ 

Datdrime 

01 //00 

^1C Thorium 17Md 

c1/tzù7 

6 

7»t. r;.t......L spa: 

elioquidxd By/Retta Fsom /^ DatcJ = ived By/3tased Datdfime 

S 1 C^ AI E C^taXQ ) o F C r x 

Reli ByIR ved Fsom DarTuric Rxei t N ^îmC 

'tell L e3 0 S'c3 v: Q 

elaquia6ed ByMemoved From DudTime lterzived Byfsuv4d In D.Wrime 

Relinquished By/Rw ved Ftum DaWTime txeived By/3wrod In Datcrrime 

Personnel not availabl e to 

relinquish samples rom the 3728 

A 

RefN1.f_.on 

LABORATORY Received BY Tide Dwarrimt 

SECTION 

FINAL SAMPLE Dispusd Method Disposed By Dahrrhne 

DISPOS IT ION 

SHI-EE -011 (03/0112002) 

Matrix 

s-xtt 

Se-s asi 

so-seua 

9- s 

oo;i" 

•`^ 

os ommseam 

wnvrwe 

t.-w a 

v-vy sm 

X

C 

FR-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-63 ! of 1 

Collector 

JohanscnlPopef tster 


200-PW-2200-PWA OU - Borehole Soil Sampling 

lee Chest No.L?g Q6 C jj 0 §c 

Shipped To 



2 0 

SAMPLE ANALYSES 



Samp li ng Location 

216-A-37 (C4I06); (17.5'-201 

Field FLogbook No. 

I O O4FS10 

0f6ite Property No. /( q ^ v 7 +I 

7TH G—L- 

Preserva600 


No. of Con tainer(s) 

Volume 

Sample No. Matrix • Sample Date Sample Tune 

B16W80 SOIL 

OF POSSESSION Sign/Print Nam es 


TRENT, Sl Price Code 8N Data Turnaround 

SAF No. 

F03-006 

E iippmment 

h th 

Fal 

cudK cudC Cool 4C Nom pone 

aG a G aG aG 

I I I I 1 

12Umt, 60mL 120nd, 60ML domL 

Ovemkm 

Flea-'1196 

Reliagnishedved Flom ime Received ByllStomd In 

c 

1,7,'t yz 

DaWfime 

if, 141 

ReGsgmdlcd By/Removed F q 

6 I A- e377iU S 

Dudfime 

Received Bylstored In 

^^ I lCA 

T Daldrime 

i)J(ts4-(.^ tJ 0^ IIO C^ 

el7isW By/Renlo 

SOAL 

DawTime 1 too Receiv ed Byed /Stw N 

51 03 F;B 6;K 

Datefrime 

Rd' By/Removed Mon. Dard(ime Recmvgd$ /St In Date7iine 

Relu gwshed By/Removed From Dale/rime Rewwd oN md 

DaWfine 

el' By/Removed From DaWrime Received By/Stmed In DaWfime 

LABORATORY RmervWBY SECTION 

FINAL SAMPLE asPosW Me" 

DISPOSITION 

BHI-EE-011 (03/012002) 

N119M07- 

377,1 

ous.erd,e- 

417.1 

Seeitemp ) m 

Spetld 

IN x10 

A v4 

Air Quality q 

Bib of Lading/Air Bill No. I) d- ZF Os y G 

a 

Tma,m_w 

+dl 

11 

45 Day 

SPECIAL INSTRUCTIONS I Matrix' 

•• 

report both kerosene sod diesel range caopouods from WTPH-D analysis. 


srtait 

$9SO 

- - 

so-sima 

.I'79 NicLel^t Nenlwiimt-237 ^ 

v/ 

p 

W.W. 

o-au 

x'ak 

ô msdm 

o.w. Lk,^ 

Personnel samples tt 

relinquish sample from 

the 3728 

Ref N ,on 

TitleDat errime 

Duposed By 

DaWT=e 

v'vwr 

x^

FR-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS RE UEST F03-006-64 Ipw 1 of I 

olketor Company Contact Tetephooe No. Project Coordinator 

Johansen/Popc/Pfister LC Huls trom 373.3928 TRENT, SJ 


200-PW-200-PWA OU - Borehole Soil Sampling 216-A-37 (04106); (27.5'-30) F03-M 

Ice Client No. 

Ck C, 

p / O cam/ 

Logbook 

3361No 115 04FSIO 

Method 

Feder fExprpesmseot 

al 


Air Quality q 

Shipped To G ee ete `# 3b 

Offiite Property No. O Bi ll of Lading/Air Bill No. Q^.^ O ?^ 



I I 


Preservation 


cud.c Cod 4C Cod k Nom Nose 

aG AG aG 

No. of Coaminer(s) I 1 1 t 1 

Volume 

120mL filled, 120mL 60mL 6thnL 

Chramioo NO2/NO3- Oaa.Gra - see kam (1) Tdaum - Bl 

3141.-71% 3511 41 3.1 spend 

t 'a dt 

Y d 7 

`J 

P ^^ N' 

1;.t;Ta 

45 Day 

Sample No. Matrix • Sample (late Sample Time mommisman 

B1 6w81 SOIL `^ `^ I^pLt^ n r^ 

CHAIN OF POSSESSION Sign/P rint Names SPECIAL INSTRUCTIONS Matrix 

y/R p loot Received By/Stored In 

J f f vrL 

D err' a 

report both kerosene and diesel rose compounds fim IYfPH-D analysis. 

•' The laboratory u w 

a-seu 

yyysw 

so-sdd 

Re' By/Removed Fran 

Relinquished vad From 

3 

ReWquishod By From 

1 t 

D ma ^^^^ Received B bred In 

3 f 

ane Received By/Stomd In 

f I oe 

DsWCm1e Received By/Stomd In 

D e/rime / y 

Z^- 

1/^ 

03 

Datdrime 

q. Neon ' rT a L 

% P 

, 

(/tZ/d3 

s SUas 

w-wun 

o-aa 

"-" 

o nom. "° 

muor 

vM a 

Re nq ' B ved From 

( 1 f O 

Daterrime 

,} Qey 

Receiv 

ex 

/ tm U Date rime 

2.03 p , 

Personnel not a vailable to 

v-Vy . 

z -ai^ 

ReWKwsbcd ByRtmnved Form DawTma Received By N Datell ime 

LABORATORY 

SECTION 


Ref #C6_on —:^ /_L/P 

Received By Tide Datdrime 

FINAL SAMPLE Disposal Method Disposed By Daw7we 

DISPOSITION 

BHI-EE-011 (031012002)

FR-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-65 1 of 1 

Collector Company Contact Te lephone No. Project Coordinator 

JohansenlPope/P6ster LC Hulstlom 373-3928 TRENT, SJ 


200-PW-2200-PW4 OU - Borehole Soil Sampling 216-A-37 (C4I06); (37.5'-40') F03-006 

lee Chest No // Field Logbook No. COA Method of Shipment 

e— 9.6 O S Y HNF-N-3361 117504ESIO Federal Express 

Price Code 8N Data Turnarou 


Shipped To

FH-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-66 1 of 1 

Collector 

JohansedPopdPlster 



tee Chest No. (FR C g S 


LC H illstrom 373-3928 


216-A-37 (C4106); (47.5'-501 


HNF-N-3361 

COA 

117504ESIO 

nn 

Shipped To - &7 /9 Offiite Property No. 2e 3 Q Z Z O 

POSSIBLE SAMPLE fWARD&REKARFU 



Preservation 


No. of Canhiner(s) 

Volume 



SAF No. 

F03-006 



CadK Cud aC Cod eC N. Nape 

.G aG aG aG 'G 

I 1 1 1 

120mL fAmL Mail, Wad. 60nd. 

C lvodw NOLNOI- Oaa Geese- S. ka W ,w Tim.-ID 

seen. ttsa 353.2 413.1 sped) 

Air Quality q 

Bill of Lading/Air Bill No. 'C ^-^ 


B16W83 SOIL 777 3 77 7771 

CHAIN OF POSSESSION Sign/P rint Names SPECIAL I 

By Fm Daterri Received By/Stored in tr W- — 

•• ^Tlw tube, 

tepwt both ketosene and diesel Hoge compounds from WIPH-D analy sis. 

/ 

a 

Q9;,Ni.MI-61 

NlMm'nm2^. 

, IsryLOto^—ry^c mo um- 

G T t1/`t /Gy 

9 7 as 

- 


Refpuish sam samples p from the 372 8 

e fJ^ pyws6ed /Rrmo From t^ 

DawThne 

^y lWn 

^• ^'% 

Received Y 

Î d^ I 

B 

/ Z 

df t^' 

Lj . a^ 

• 0 3 

Relluxinsited B 

3 2 

From 

1 0'3 

werrimc 

11 0o 

Received By/Stored ted 

S GAS 

wdT 

S I C IOa 

ReOnqumited By/Remo F 

(L 

Re" By ved From 

S 

DmWT— 

1 D 3 

Dawf11O 

1 /00 

Received By/St U 

1"' L- L 

ReceivedL t d ^L 

Datdriroe 

S^ ^ e 

Retrofit stied By/Removed Front Re ce ived By/SwWn Datefrime 

y / 

C— 


LABORATORY 

^L 

Rece SECFION 

ived By Tide DaWrime 

FINAL SAMPLE 

DISPOSITION 

Disposal Medved Dispo sed By DataTunc: 

BHI-EE-011 (03/012002) 

Data Turns,roun 

45 Days 

Matrix' 

swi 

s[-Saierr 

so•sdu 

srwdac 

W. Wâ^ 

^ 

a•nv 

wi-wi 

wi-wive 

trua+s 

x-vwa.^

FI3-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F034W73 I Pase 1 of I 

Collector Company Conta ctTelephone No. Project Coordinator 

Johnnsen/Popr/Pfister LC Hulsrrom 373-3928 TRENT, Si 

Project Daignadon Sampling Location SAF No. 

200-PW-2f200-PW-4 OU - Borehole Soil Sampling 216-A-37 (C4106); (17.5'-20') F03-006 

Ice Chat Na ,^{^ q 


C' C- C 1 p 0 3 S- - HNF-N-3361 117504ESIO Fed er al Express 

Shipped To ,l^jy^t OHaite Proper ty N o. 1t a ''1 Z Z- o 

!T^ 3 

POSSIBLE SAMPLE HAZARn$/It MA 



Preservation 



Volume 


B16W90 SOIL a; 

Cod 4C Cod 4C Cad 4C None Nine 

aG aG aG' aG 

t I 1 t I 

120ml, 60ML 120mL 60mL 60ML 

Oma:am 

N -71% 

NOLNOI- 

3531 

Oa&Ge 

413.1 

- S:Nm([ 

SprdY 

Tmwm-M 

t y 

1 

A a^ 

Price Code gN Data Turnaro und 

Air Quality q 

Bi ll 

of Lading/Air B01 Na 3rf^ Oi P 

45 Day-S-- 


emoved F Abnorrime 

Sign/Pdnt Nam es SPECIAL INSTRUCTIONS '/ l L 4; 9 Matrix 

AC ived By/Suxed In Datell'ime 12C'F I 

- . •• The laboratory is to 

s-sm 

le ' uisiwd By/Removed F Datdrime 

1 Vl- 37Z,d' J / et) rl 00 

1 

r 372^s y Zs o3 6 VS 

Received By/Stored N Detdrime 

^TJ [.^ r' /a 7/Oct 

report b oth kerosene and dim[ range compounds tr am WTPH-D analysis. 

on 

Om:y(inL. î. nr...e 717 

I .^"^S'^ °^^Ly7°) 

sa seams 

so-sx'r 

y-yrae 

W Weir 

elirapdshed 

^ 

J 

m Datc/Time Received By/Smred 

07 1100 F'— G 

DaWTime 

A-u. 

DS-Dnue 

m.-D— uau. 

By cod From DurnmK Received ti Datcffune 

s ,< 03 0 -i 0 0 

RelinquishedBy/RemovedFrom Dtterrime Received By/St in Daterrruie 

Relinquished By/Rrmovcd Fmm 

LABORATORY 

SECIRON 

Deterrent Received By/SWW N Datefrime 


relinquìsh{,..sSS}amples from the 3772287, 

Ref # ôn rS /^/yam 

Received By Tide Daterriroe 

FBVAL SAMPLE Disposal Method Disposed By Dawrune 

DLSPOSITION 

BHI-EE-011 (031012002) 

_ 

M_W, 

Vvvq 

x-ax, j

Co l 

FH-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST FVJ-Wjb /4 1' b- 

lector Company Contact Telephone No. P ro ject Coordinator 

Johansen/PopdPBster LC Hulstrom 373.3926 TRENT, SJ 


200-PW-2200-PW4 OU - Borehole Soil Sampling 216-A-37 (C4106); (0.5') F03.006 

Ice Chat Na [,^ q / ` Field Logbook Na COA Method of Shipment 

c^ C— t tp 0 W 

HNF-N-3361 117504FS 10 Federal Express 

7 

Shipped To t10,31 63 I \ C 21% ORshe Property No. /f ^ 3 O 7 



SAMPLEANALYSIS 

Preserndon 

^'V 

TypeofContsiner 

No. of Cootainer(s) 

Volume 

Sample No. Matrix • Sample fate Sample Time 

B16W9t SOIL 'ZtS 0 

P5F--: 

!/ 

cods Cod 4C 

aG aG 

I I 

6aa 250m1- 

Pesticide'met 

H bidde- 

mnstst 

Bill of Lading/Air Bill Nos 


Air Quality q 

r^ 

45 Days 

N OF POSSESSION Sigo/Print Names SPECIAL INSTRUCTIONS Matrix 

F Davlrine Recei ved By/Stowd In Datefrime 

By/Remaved F m 

DaR?tme 

Receive d By/St«W 1n 

Drtdfmte 

1;P-1 M 5103 1106 d 0 '5 /lod 

Relinquished 9y/Remnve9mm DatdTime 

S 1 Q 

Recerved By/Sut6d In 

Q V ^^ 

Datcai ne 

Relkq.is1pd BY emoved From DaWr'nts Re ceivedN Dme/rime 

from ° 1T2^ 

Dxte/rime ^- 

Dawrime 

Personr!e1 mPIts 

RelinquisttW BylRennved From Received By t In hs 5 1^— 

reGuGau fy oo 

gef a 

Relinquished By/Removed From Date/riote Received By/Stored In Dutause 

LABORATORY Received By Ti tl SECTION 

e Daterrime 

FINAL SAMPLE 

DISPOSITION 

>SwOW Moro 

- 

Deposed By 

Drtdrtnte 

BHI-EE-011 (031012002) 

W.W. 

o 

e-•" 

oc-= 

dL i 

nL 0.vm 4y^M1s 

w1-v" 

- ,,,



WENT: IIÛ Hor'N es ONO O N/A O see Comment N 

13. coc will be faxed or emailed to client? +Uya• ONO O N/A O see Comment N 

14. Project Manager/Client contacted 


Cooler t4 / temp (°C) î and Comments: 

G 

(n GS Co / 1.3` 


r^^^Jyl 

Laboratory Project Manager: 1 I 

q Yes O No /A q sec Comment N


GRO ANALYTICAL DATA PACKAGE FOR 




B16W79 001 S 03LVJ515 04/28/03 N/A 06/15/03 

B16W80 002 S 03LVJ515 04/28/03 N/A 06/15/03 

B16W81 003 S 03LVJ515 04/29/03 N/A 06/15/03 

B16W82 004 S 03LVJ515 04/29/03 N/A 06/15/03 

B16W82 004 MS S 03LVJ515 04/29/03 N/A 06/15/03 

B16W82 004 MSD S 03LVJ515 04/29/03 N/A 06/15/03 

B16W83 005 S 03LVJ515 04/29/03 N/A 06/15/03 

B16W90 006 S 03LVJ515 04/28/03 N/A 06/15/03 

LAB QC: 

TBLKIZ MB1 S 03LVJ515 N/A N/A 06/15/03 

TBLKIZ MB1 BS S 03LVJ515 N/A N/A 06/15/03 

^1 Zl 

V1 CP

Analytical Repo rt 

Client: TNiJ-HANFORD F03-006 W.O.#: 11343-606-001-9999-00 

LVL #: 0305L329 Date Received: 05-02-2003 

SDG/SAF # 112194/1`03-006 

GRO 


The samples and their associated QC samples were analyzed according to Lionville Laborato ry OPs 

based on SW-846 method 8015 for G asoline Range Organics (GRO) on 06-15-2003. The analysis met 

the intent of method WTPH-G. 



1. All results presented in this repo rt are derived from samples that met LVLI's sample acceptance 

policy. 

2. Samples were analyzed outside of holding time. A copy of the Sample Discrepancy Report 


3. The method blank was below the repor ting limits for all target compounds. 

4. All surrogate recove ries were within accept ance criteria. 

The blank spike recovery was within acceptance criteria. 

6. The matrix spike recoveries were within acceptance criteria. 

All initial calibrations associated with this data set were within accept ance criteria. 


criteria. 

I certify that this sample data package is in compliance with SOW requirements, both 


contained in this hard-copy data package has been authorized by the laborato ry Manager or a 


r i^3 

I ' Daniels Date 

aboratory ager 


som\r\gmup\&Mt gm\mu-hanford\0305-329.doc 

The re 

sults presented in this repo rt relate only to the analytical tes ting and condi tions of the samples at receipt and during storage. All pages of this report are integral pans of the 

analytical data. Therefo re, this repo rt should only be rep roduced in its entirety of 1 5 pages. 


Lionville Laborato ry Sample Discrepancy Repo rt (SDR) SDR#: ,,) 3E,(,2t)- 

Initiator: 3 d-^ t-` ` Batch: 03os t-3 .1- 4, - Parameter: D Gti L1 

Date: 1044(-) Samples: /}tt Matrix: ro-t 

Client: -rµ' Method: SW846/MCAVNN1CLPI Prep Batch: o3w7 5- 


a. CDC Discrepancy _ Tech Profile Error 

Transcription Error 

Client Request — 

_ Wrong Test Code Other 

Error on C-O-C 


_ Missing SamplelExlract _ Container Broken _ Wrong Sample Pulled _ Label ID's Illegible 

_ Hold Time Exceeded Insufficient Sample _ Prese rvation Wrong _ Received Past Hold 


Note': ve rified by [Log-In) or (Prep Group] (circle)... signature/date: 

c. Problem (Include all relevant specific results; attach data if necessa ry) 



_ Re-log 



_ Re-[each 

Re-extract 

_ Re-digest 

_ Revise EDD 


_ Place Onffake Off Hold (circle) 

4. P ject Manager Instructions...signatureidste: 





Date/Person 

_ Add 

Cancel 

5. Final Action... signature/date: 7M7 1, 4 Other Explanation: 

^ erlfied re-[log][leach]lextract][digest 

_/Included 

I in Case Narrative 




(lrcle) 

When Final Action has been recorded, forward original to QA Specialist for distribution and filing. i 

Route Distribution of Completed SDR Route Distribu ti 

on of Completed SDR 

X Initiator _ Metals: Beagle 

_ X Lab General Manager. M. Taylor 

_ 

Inorganic: Perrone 



_ X QA (file) _ _ Log-in: Melnic 

_Date Management: Feldman — Admin: Soos 

_ _ Sample Prep: Beegle/Kiger _ _ Other. 

Qn- 105-A-osoi

QLVMU1 GLOSSARY OF GASOLINE RANGE ORGANICS DATA 




(e.g., IOU). 

3 = Indicates an estimated value. This flag is used in cases where a target analyte is 



3J. 

B = This flag is used when the analyte is found in the associated blank as well as in the 





ABBREVIATIONS 

BS = Indicates blank spike in which reagent grade water is spiked with the CLP matrix 


are reported. 

BSD = Indicates blank spike duplicate. 

MS = Indicates matrix spike. 

MSD = Indicates matrix spike duplicate. 

DL = Indicates that recoveries were not obtained because the extract had to be diluted for 

analysis. 

NA = Not Applicable. 


NR = Not Required. 


I

O vL! 

GLOSSARY OF GASOLINE RANGE ORGANICS DATA 

D = This flag identifies all compounds identified in an analysis at a secondary 


C = This flag applies to a compound that has been confirmed by GUMS. 

R:/SHARE/GCVOLATILE/GCV OLATILEGLOS.DOC


GAS RANGE ORGANICS Report Date: 06/18/03 12:38 CQ 

RFW Batch Number: 030SL329 Client, TNUHANFORD F03-006 H2194 Work Order: 11343606001 Page: 1 


Sample RFW#: 001 002 003 004 004 MS 004 MSD 


D.F.: 1.00 1.00 1.00 1.00 1.00 1.00 


Fluorobenzene 79 % 74 % 81 % 82 % 79 % 78 % 

_____________________________________________ fl=====__=====f1=====__=====fl=====__=====fl==== =__=====fl= ====__=====fl 

Gasoline Range Organics (GRO) 33 U 30 U 30 U 33 U 93 % 104 

Cust ID: B16W83 B16W90 TBLKIZ TBLKIZ BS 

Sample RFW#: 005 006 03LVJ515-MB1 03LVJ515 -MB1 


D.F.: 1.00 1.00 1.00 1.00 


Fluorobenzene 82 % 78 % 94 % 96 

_____________________________________________ f1=====__=====fl=====__=====f1=====__=====f1=====__=====fl=====__=====fl 

Gasoline Range Organics (GRO) 30 U 33 U 30 U 106 % 


%= Percent recovery. D= Diluted out. I= Interference. NA= Not Applicable. *= Outside of EPA CLP QC 

q 

X 

9


51_3 

Cl ient_S N 1--^y^r^rd Fns- o 

U rot' unw r v— - 

Custody Transfer Record/Lab Work Request Page-LD+__.I_- 


Refrigerator x 

Est. Final Proj. Sampling Date Mrype Container 

Project # 11^'Î^' / ^ o- rr1- ggi19 tÛ 

Project ContaLKlPhrxle N Volume 

Lionville Laboratory Project Nane9er Q^$ 

OC Del ° TAT 

Date Recd ^'^ {l-5 Date Due _^0 YV T^ Jrw-, 

L iquid So li 

d 

Liquid 

So li 

d 

M INORG 

ANALYSES Z 

REOUESTED = U. 

MATRIX 

CODES: 

S- Soo 

SESediment - 

IUb 

Client IDVDesedpUon 

matrix 

OC 

Chosen 

ma 

Dare Time Z 

l 

'*4 

Lionvil le Laboratory Use Only j 

(L 

tr so St. - 

S L - Sludge 

W. Water 

0- al 

A - Air 

OS - Drum 

Solids 

OL - Drum 

Liquids P TC 

MS TM-SO 

ix 


J C 

N N 

i 

L- E /rIP 

Leachate .^ 

WI- Wipe 

X. Other 

F. Fish 

1 3 

Yl^knx ^ c- 

^ vLl 

Special Instructions:'1 

G,^ ^_' \ 

^JA ^ TUJ r Vo DATHREVISIONS: 

s-,^-o, P qÂt : ^â b -16 d 

^1 n A f 

5 (Q4 p0 41 —► -00 b 441 A f11 l^ BL &. Cd Cr. Ca 

^' 

Liorwige Laboratory Use Only 

Samples were/ 

Tamper Resistant Seal was: 

1) Shipped or 1) Present on Outer 

Hand Delivered _ Package (f) or N 

3 jib___ F.j; P Se / T- C- ,. C(, )Ì N,a Ndt ^T, a^rll ^ _ x 

nî^+!" 

2) ckaga on Outer 

Packege^ a N 

4. 100A. 7-cpfa Vii wa* 14 . o i.7 x . 06,0C 

S. 

2) Ambie nt orV 3) PmS - Sample 

Y) or N 

O PGO QDtk7 & IQQ 31 Received in ood 

Condition C or N 

y 4) N„ap^- on 


by 

4) Samples Sample C) or N 

S 

Property PeNed 



Date rime Discrepancies Between rY or N 

Dat 

by 

F 

e Time 

Upon Sample RecY 

by by Samples Labels and 

Q' S) Received Within YJ or N 

A` 

; COC Record? Y or N 

J 

PrIFx 

_ /^Q^ ^^ i►^n Holding Ti s Coote r 

0M u. NOTES: or N Temp.C 

RE ITTER1 .3aa 

^

FH-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-62 JNF 1 of 1 

Collector 

JohansentPopdMster 

Project Doignation 

200-PW.2/200-PW4 OU - Borehole Soil Sampling 

Ice Cheat Na ^y^ 

/C. ` q 

! ft 

O S /- Y 

Shipped To ertel* I 

Zc 2 






Sampling L oc ation I 

216-A-37 (C4106); (12.5'- 1 51 


HNF-N-3361 

COA 

117504ESIO 


TRENT, SJ 

SAF No. 

F03-006 



p rice Code 8N 

Air Quality q 

I Offfi Property No. s 2 -2 O Bill of Ladiag(Air Bill No. C^^^ PC— 

Preatrvatioo 


No. otCoohioer(s) 

Volume 


B16W79 SOIL fj 4 l 

cadsc cndac - cads No.. Haa 

1 I 1 1 1 

120mL Word, 120mL Wool. Ord, 

CMamutm NOLNO3- Oil a C..- S. st.(1) T ritium-3U 

Hu-71% 353.2 413.1 spe cial 

rHAIN OF POSSESSION Sign/Print Names SPECIAL INSTRUCTIONS 7 

R msised 8 wd F Dattrf^mm ^^^ Received B /Stoed In 

Dsterrime 

t3 p 

KC^) 372 ^f Z gC)53 16 

Retinqdwted BylRanaved F 

_ 1 72— 

Datdfope 

RelinquidtW By/Remo From Datdfime 

j)po 

sic, ► E daQQ )100 

J. 

a 

Z Z a3 

f'-^ laboratory t A 1' f to 0 "t fiv__ ** The laboratory is to 

report both kerosene and dim[ range compounds from WTPH-D armiysts. 

ftJ '^ -' nn. c..,..: eo m 7 nl Sr Isotopic Thmi !T Mri .^..-7»i . r_.t,..._i^ . 

Received By/Stored in 

Datdrime 

_ t^ 

cJ O^ //DO,r 

L//T.zle] 

air 

ived By/Stored 

DatcTime 

—6-0 IF 'N" 

Re' B /R vxd From Datdfime 

Recei la Dgdrima 

o3 0 

75- 'a3--0 O ,-. 

Relinquished By/Removed From Datefrime Received ByfStodd In DatuTiime 

Relinquished By/Removed Fmm Datefrime ived By/Stored In Datdrrme 

Persoonel not available to 

relincloull samples ron, the 3728 

Ref R 117 /_L1123 

LABORATORY Received By Tide Datdrime 

SECTION 

FINALSAMPLE Disposai Metlmd Dispased By DaWr= 

DISPOSITION 

81-1I-EE-011 (03101/2002) 

Data Turna ro und 

45 Days 

-ey, 

Matrix 

s- Sa-sews 

so-swr 

y-yot^ 

W.W. 

o-ou 

T^ 

waxspe 

v-vwae. 

FVM

C 

FH-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS RE UEST F0}006{3 I P RF 1 Of 1 

Collector 

Johansen/Popeftster 



letChestNo-erg C Q^ ^! 

jj 

Shipped To 



b 

Z 6 


Company Con tact Telephone No. 

LC Huls trom 373-3928 

Sampling location 

216-A-37 (C4106); (17.5'-20') 

Field LFoogg-b3o3o61N o. 

1 I5 04ES10 


TRENT, Sl Price Code 8N Dam Turnaround 

SAF No. 

F03-006 

Method of E Sh iirp^ment 

Air Quality q 

Offshe Property No. /( o ^L 6 zz d Bill of fadiog/Alr Bill No. d^ Q3y G 

/ 

Preservation 


No. of Co Container(s) 

Volume 

Sample No. Ma tr ix • Sample Date Sample Time 

B16W80 SOIL Z(f G3 ^0 7`` )C 

cadet cads cad 4c N. None 

&G aG aG aG 

I t I 1 1 

120mL 60,fl- 120mL 60mL 60mL 

mroaw tn NovNOt- Oaacame- smhaa (O;a TWr - I1 

HO-71% 353,2 4111 Sp" 

A ^( 

0} 

a 

45 Days 

AIN OF POSSESSION Sign/P rint Names 

Relinquished /Removed From - e6 Received BY/Swmd In 

1A 1-7,1b 

DakJrime 

4 

SPECIAL INSTRUCTIONS T 71 Matrix 

/Z Reliogmshed BY/Removed FrooK Datorfi nt 


pep q 

I la- $ 7 Zg S' o 3 1 1 t6o brSCrr>ri.^' 

R,,Iwtbed By Dstell'ime 1\00lleceived By/Staed In 

SJ GAL 

51 03 I=E E>1, 

f/ U 

Tc5 

Date (fime 

J l O / f 0 C) 

Date/rime 

•• 

•• The lebacatoty, is to 

repon bah kerosene and dicwl range compounds 6mn N?PII-D atulysis. 

- 

' 129 N;eke46 3.,mduo,-237 

, 

^J yy(,//^zl°^ 

iN 

s-ai 

w-sar 

v-siwr 

a-w 

U 

a.o— t:wWr 

Relinqui BY/Remaved ûTpOC Rem'vgdB /S In Date/Tune 

wrw;•. 

clinquidud By/Removed Frown DuerFme Rmived / orcd In Dudrime 

Reltaqualted By/Removed Faun DatetTime Received By/Stared In Dale/rime 

Personnel not available to t 


Ref N I-ft-- ort 

LABORATORY Received BY Tine Dateffime 

SECTION 

FINAL SAMPLE DLVwW Mahod Disposed By Daterrime 

DISPOSITION 

BHI-EE-011 (03101/2002) 

x

FH-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006fi t J PaF 1 Of 

Collector Company Contact Te le phone Na Project Coordinator 

Johanscnllsope/PSster LC Hulstrom 373-3928 TRENT, SJ 


200-PW-2200-PW-4 OU - Borehole Soil Sampling 216-A-37 (C4106),(27.5 1-3V) F03-006 

M C-- 

fee CheNNa q 0 t^ 

(e 

FidHNLogbook No. 

11504ESIO 

Method of 

Shipped To G C^ A 3 

Oftsite P ro perty No. ,[lam ^{ O Bill of lading/Mr Bill No. 

POSSIBLE SAMPLE HAZARDS (REMARKS 


Prese rvation 


No. of Container(a) 

Volume 

Cod aC Cod 4C Cad 4C No m None 

aG aG sG aG 

1 1 1 1 I 

120ml, 60ML 120mL 60mL 60m1, 

Chmmium NO2/ 1403 . Oa&Gate- see kem (I) Tritium -H3 

Stu-0196 353.2 4 13 .1 sprit 

SAMPLE ANALYSIS d 1 


r ^tY 

p 

77, 

d7 

Price Code $N Data Turnaround 


B16W81 SOIL a7 `^ I^,pLL) 

CHAIN OF POSSESSION Sign/Print Names SPECIAL INSTRUCTIONS L d) Matrix 

shed y p rime Rived By/Stored In ^^^ D te/fi < 

•• The laboretory is to 

s-sd1 

CK7 

report both ke rosene and diesel =at compounds 6mn WIPH-D analys is. 

Ral BY/Removed From Da ime 11C^•- Received B cored In D te/rime / 4 

I I ?fir 43 

Relinquished ved From i^ Received By/Stored N Datdrime 

fk^ 

n.u:.4. 6, H't m-,,, 

' 

%J 

L2 /^^ 

-}7^ 

^l^lU 

j 

f^ 

so-rxr 

v-suds: 

(.a 

A-na 

D;D SAn 

'5 -7Z4 fl 04D SJ 03 DL-Dmm Epistle 

eiingwgwd BY ved Ftom Da m 

Received B Y/Stored 

In Daterrime 

/ 

R B ved From 

Relinquished BY/Removed From 

Dmerritne 

. ,. cr) y 

DaWrime Recciv B / t 

eceived B 

U 

N 

Datcaime 

.r.; .;,,3c , 

DaWrime 



Ref M1 5 5 /- L—lp j 

7 

LABORATORY 

SECTION 

Removed By Tide =L 

Dwefrime 

FINAL SAMPLE Disposd M ethod Disposed By Date 7ime 

DISPOSITION 

BHI-EE-011 (031012002) 

wi-w* 

L-UqW 

vv,a.,,ao

FH-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-65 I PW 1 of 1 

Collector 

JohanscriMopelPfister 


200-PW-2200-PWA OU - Borehole Soil Sampling 

Ice Chat No* p^p ( / 

vfs= L 9.^ O 5 Y 

Company Contact Tekphone No. 

LC Hulsuom 

373-3928 


216-A-37 (C4106); (37.5'-40) 


HNF-N-3361 

COA 

117504ESIO 


TRENT, SJ 

SAF No. 

F03-006 



P rice Code 8N Data Turnaround 

Air Quality q 

Shipped To C-L70 ite Property No.^2 Bill of Lading/Air Bill No. ^^^ 

cJ 




Preservation 



Volume 


Cod 4C Cod eC Coot Now Noce 

aG aG aG 

I 1 1 

120mL 60ML 120ml. 60mL 

C7uumiun 

Nees-71% 

NG2MW- 

333.2 

Gilareaea G- 

413.1 

JaG 

Tmkun-IB 

45 Days 

B16W82 SOIL LW-262- 0200 E 


B F 

SigdP rint Nam es 

Received BY/Stored N '3^ PiC-- t one 

I ` 

N 

ishW ByfflIcilved From / Received PyPStcxcd N Distance 1 ( um- 

dinquishod B ved F_TW awaTunc 

3 2 6 1 

03 //00 

Relinquished nquished By/Removed From 

DaWTir 

^) p 1 

By aoo From ^^ 

l' Qc+ 

Re ce ived By/Stmed 

Datdruoe 

rs 1 0 ,5 1 /OL,) 

Received B 103 Datdfime 

Recei S In Detefl'ime 

-,^ 03 C1 9 YS 

ehngwshed By/Rnmved F rom Date/fanc Received BY'PjAed In Daldfime 

SPECIAL INSTRUCTIONS 10— w 2 ale - 

ee rs to ee The laboratory is to 

repo rt both kerosene an d diesel range compounds from WTPH-D analysis. 

Personnel not available [o 

relinquish sampl es from 11, 3728 

Ref p 1,;3 on cS /_Ll 03 

LABORATORY Reeeived By TitleDatrlfime 

SECTION 

FINAL SAMPLE Disposal Method Disposed By DateTane 

DISPOSITION 

BHI-EE-011 (0310112002) 

Matrix 

s-so^t 

sa.^.Â 

so-sdr 

w Sw,io 

A-"h 

Tvi'ioae 

i 

VWMgm 

V 

v- vesenm 

X'

FR-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS RE UEST F03-006 66 " 'et 1 of 1 

Collector 

Johansen/Popeftster 

Proj ect Designation 





216-A-37 (C4106); (47.5'-50') 

Ice Chest No.^.-^ C 

4 tG 0 5 


HNF-N-336 1 

Shipped To 

^/ 

e?vee ORsite P roperty No. 

POSSIBLE SAMPLE HAZARDSWXMARkg 7 ' 



Preservation 


No. of Conhiner(s) 

Volume 

Sample No. Matrix • Sample Dole: Sample Time 

COA - 

117504ESIO 

A-C :5 O Z Z 0 

Project Coordin ator 


SAF No. 

F03-W6 



Cod aC Cod 1C Cad IC Non Nape 

aG aG aG aG 

1 i 1 1 

120ML 60ML 120m1. 60.1, 

Air Quality E] 

B81 of Lading/Air Will No. s ^^^— 

t60.L 

Oweaiiun NO2 NO3- Oa30raee- Smkm(I)ia Trimw-H3 

Hax-71% 353.1 41 3.1 spedd 

B16W83 SOIL (/ f 1< 

I 

CHAIN OF POSSESSION Sign/Print Names SPECIAL [NSTRUCCIONS GL a-f 

1' By Fm Dater' Received By/Stored In - C-. — 

•• 

Jy(grrs6ea H /Ram 

( ! 

From 

lalb 

DA 1'buo 

• t4uCS 

Re^lirquiahed 

B From ima 

3 z 1 0-) 1160 

Relinquished By/Reno F m DaWfaae 

1 03 I /o0 

a 

Received y/Stec N ri of a iâc r 

1 7e- 4 . at-4 - 0 3 

Received BY/Stored 

S 

Date?ima 

c5" ) c) -5 110b 

Received By/Storedl. 

DaWTme 

FeFb L 

By ved Fmm Date/fime Received ,hL' I a 

f 

S..;i.-J3 t 

Itclinitutshed By/Removed Fonts Date/fime Received By/Stolodta Datef ime 

N 

repro both kerosene and diesel range con"uds from WTPH-D analysis. 

(1) - noon — o r, Isotoprc num num 

122 N'^rJe l-61 fil 

- 

Nennmi .m- 

> 

7 

f^,r, : ^t 


pis wh samples f 

Ref / h 

rom the 3728 - 

tLSJ-on _ /_L/ 

031F C— 

17 

•• The labomrary is to 

LABORATORY Received By Title Daterime 

SECTION 

FINAL SAMPLE D40W Method Disposed By Datefrime 

DISPOSITION 

BHI-EE-011 (03101 12002) 


45 Days 

Matrix' 

s-sdr 

se^ 

so-sda 

W swan 

a-a 

osôn,s s•aae 

n oam3yae 

TKO 

vn•vnpe 

U

FH-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-73 Page 1 of 1 




200-PW-2/100-PW4 OU - Borehole Soil Sampling 216-A-37 (C4106); (175-20) F03-M 

Ice Chat No. p / ` /' 


(^ C ` o 3 C 

HNF-N-3361 117504FSIO Fede ra l Express 

Shipped To /'Z &Z124 


Special Handling end/or Storage 

•f *'r Offsite Pro per ty No. 11 ^2 Z Q 

/T 3 

SAMPLE ANALYSIS - 

Preserva tion 



Volume 


8N90 161 

SOIL 6 3 X 6 

Cod 4C Cod 4C Cad 4C Nooe Nom 

aG aG aG aG a 

I 1 1 1 1 

120ml. 60ML 120ml, 60m1- 60ml. 

Chrwdwn 

Hv-31% 

NOLNO3- 

353.2 

Ofi6Cunak- 

413.1 

Seeiten(W. 

Spa" 

Tdt6m- 143 

4 

Inwomu 

d / 

Price Code $N Data Turnaraun 

Air Quality q 

Bin of Lading/Air Bill No. ^r os p 

45 Days 


glgved F mx 

Sign/Print Nam es 

Received By/Stomd to Dateffime 

P,C^ IA' 3?nr yZS O`3 /6 y5 

SPECIAL INSTRUCTIONS q `T 2L A; 

- 00 The labo ratory is to 

repo 

Matrix' 

s-sdt 

rt Re' uisbed By/Rmooved F 

372d' 

Daterrime 

! c 3 0 60 

Received By/Stared In DateTime 

M-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST I rv^-uvo- - 

Collector Company Con tact Telephone No. Project Coordinator 

Met Code 


8N 


200-PW-2200-PW-4 OU - Borehole Soil Sampling 216-A-37 (C4106); (0.51 F03-006 

Ice Chest No. ^^yy^^ q / 


G s<

DENT: I ICU Hw.^+v 



rchese Order/Projeot: DATE: 

sow# / Release #: YU 3- 00(o 

iliiratory sDG C 

CyQS l.. 32 ^ 

OTE: ALL ENTRIES MARKED "NO" MUST BE EXPLAINED IN THE COMMENT SECTION 

1. Custody seals on coolers or shipping 7yes QNo 0 NIA 0 see Comment 


A 

2. Outside of coole rs or shipping containers are Q Yes O No O NIA q see Comment M 


3. A)rbill # recorded? Îyes q No q NIA O see Comment N 


other client specific: historical data, O No q NIA O see Comme nt N 

alphabets or other screening data as 



5. Sample containers arekintaet? ^Q yes O No O N/A O see Comment N 

6. Custody seals on sample containers intact, LYYes O No O N/A 0 sec Comme nt N 

( 

-- 1 


7. All samples on coc received? Yu O No O NIA O sec Comment N 

S. All sample label information matches coc? eS O No O NIA • t] see Comme nt M 

9. Laboratory QC samples designated on coc? 0 Yes O No oWA q am Commem N 

(QC slickers placed on bottles?) / 

10. Shipment meets LvLI Sample Acceptance 

Policy? *(identify all bottles not within 

policy. See reverse side for polity) 

IQ 

y es o No q N/A q see Comment N 

11. Where applicable, bar code labels are O Yes O No NIA O see Comment N 

affix ed to coc? 

12. coc signed and dated ? es O No 0 N/A O see Comment N 

13. coc will be faxed or emailed to client? Lf/Ya• q No O NIA O see Comment N 

)4. Project Manager/Client contacted q yu q No tit/A q sec Comment N 


Cooler $1 / temp (eC) and Comments: 

4 E2G qL -05 (p / 1,3" 

Laboratory Sample Custodian: '] 

Laboratory Project Manager: ,(/ A 

P) 

G


DRO ANALYTICAL DATA PACKAGE FOR 



CLIENT ID LVL # MT% PREP # COLLECTION EXTR/PREP ANALYSIS 

B16W79 001 S 03LE0577 04/28/03 05/14/03 05/16/03 

B16W80 002 S 03LE0577 04/28/03 05/14/03 05/16/03 

B16W81 003 S 03LE0577 04/29/03 05/14/03 05/16/03 

B16W82 004 S 03LE0577 04/29/03 05/14/03 05/16/03 

B16W82 004 MS S 03LE0577 04/29/03 05/14/03 05/16/03 

B16W82 004 MSD S 03LE0577 04/29/03 05/14/03 05/16/03 

B16W83 005 S 03LE0583 04/29/03 05/15/03 05/19/03 

B16W90 006 S 03LE0577 04/28/03 05/14/03 05/16/03 

LAB QC: 

ELK MB1 S 03LE0577 N/A 05/14/03 -05/19/03 

ELK MB1 BS S 03LE0577 N/A 05/14/03 05/19/03 

ELK MB1 S 03LE0583 N/A 05/15/03 05/20/03 

ELK MB1 BS S 03LE0583 N/A 05/15/03 05/20/03 

^026272 I ^^ J^' 

At 

JUN 2003 ^, 

N 

" 

7 A 

^l 

U 

^'j(Ql{


LVL #: 03051,329 

SDG/SAF # H2194/F03-006 

DIESEL RANGE ORGANICS 

Six (6) soil samples were collected on 04-28,29-2003 


W.O. #: 11343-606-001-9999-00 


The samples and their associated QC samples were extracted on 05-14,15-2003 and analyzed according 

to Lionville Laboratory OPs based on SW846, 3rd Edition procedures on 05-16,19,20-2003. The 

extraction procedure was based on method 3540 and the extracts were analyzed based on method 8015B. 

The analysis met the intent of method WTPH-D. 

The following is a summary of the QC results accompanying the sample results and a description of an y 



policy. 

2. Samples were extracted outside of holding time. A copy of the Sample Discrepancy Report 


3. The method blanks were below the reporting limits for all target compounds. 

4. All surrogate recoveries were within acceptance criteria. 

The blank spike recoveries were within acceptance criteria. 




criteria. 




designee, as verified by t1A following signature. 

Laboratory Incorporated 

so n\r:\gmup\datatdr6lnu hanford\0305-329.doc 

The results presented in this report relate only to the analytical testing and conditions afthe samples at receipt and during storage. All pages of this report are integral parts of the 

analytical data. Therefore, this report should only be reproduced in its entirety of 1 5 page. 

208 Welsh Pool Road a Exton, PA 19341-1313 a (610) 280-3000 a Fax (610) 280-3041 

r 

ate

Laboratory Sample Discrepancy Report SDR °^ 

Lionville 

rY p p Y p (SDR) SDR#: 

Initiator: Batch: 0301'!. ?vim . Parameter: DD a u 

Date: b 1 15[ d) Samples: & tt Matrix: s 0 -I 

Client: -r n3 Method: SW84 61MCAMICLP/ Prep Batch: 03 L-t7 s- -)i. t-r 

f. Reason for SDR 

a. COC Discrepancy _ Tech Profile Error C li 

ent Request Sampler Error on C-O-C 



_ Missing Sample/Extract _ Container Broken _ Wrong Sample Pulled _ Label ID's Illegible 

Hold Time Exceeded Insufficient Sample _ Preservation Wrong _ Received Past Hold 


Note* : Verified by [Log-in) or [Prep Group] (cirde}..signatu reldste: 


SA^P \e w^r< 2Plrc^ri t a1) S to .Cl j1o^^. 



_ Re-log 

_ Entire Batch ^/4t r . 


_ Re-leach 

_ Re-extract 

_ Re-digest 

_ Revise EDD 



4. P ject Manager Instructions ... signaturelda 





Date/Person 

_ Add 

Cancel 

5. Final Action... signature/date: b ww- Other Explanation: 

.Verified re-[log][leach][extra 

_ Included it Case Narrativ 

_ Hard Copy COC Revise 


EDD Correc 

digest][a slysts] (circle) 

ti 

ons Completed 

When Final Action has been recorded, forward original to QA Specialist for distribution and filing. [ 

Route Distribution of Completed SDR Route Dist ribution of Completed SDR 

_ 

X Initiator 

X Lab General Manager. M. Tay lor 

_ 

_ 

_ Metals: Beagle 

_ Inorganic: Perrone 

_ X Project Mgr. Stone/Johnson/Haslett_ _ GC/LC: Kiger 

_ X Technical Mgr: Wesson/Daniels _ _ MS: Rychlak/Layman 

_ 

— 

_ 

X QA (file) 

_ Data Management: Feldman 

Sample Prep: Beegle/Kiger 

_ 

_ 

_ 

_ Log-in: Melnic 

Admin: Soos 

_ Other. 

oA.ôs-f,-osoi ^

OLVIL GLOSSARY OF DIESEL RANGE ORGANICS DATA 




(e.g., l0U). 

J = Indicates an estimated value. This flag is used in cases where a target analyte is 

.detected at a level less than the lower quantification level. If the. limit of 


3J. 



E = Indicates that the compound was detected beyond the calibration range and, was 



ABBREVIATIONS 



are reported. 





analysis. 




SP = Indicates Spiked Compound.

,DvI 

GLOSSARY OF DIESEL RANGE ORGANICS DATA 



C = This flag -applies to a compound that has been confirmed by GUMS. 

5


DIESEL RANGE ORGANICS BY GC 

Report Date: 05/24/03 11:27` 

RFW Batch Number, 030SL329 Client TNOHANFORD F03-006 H2194 Work Order; 11343606001 Page: 1 v2 


Sample RFW#: 001 002 003 004 004 MS 004 MSD 


D.F.: 1.00 1.00 1.00 1.00 1.00 1.00 

Units: mg/Kg mg/Kg mg/Kg mg/Kg mg/Kg mg/Kg 

p-Terphenyl 69 $ 87 $ 93 $ 94 $ 97 $ 101 $ 

_____________________________°__________===== fl=====__===== fl=====__===== f1=====__===== fl=== ==_°=====f1===== __=====f1 

Diesel Range Organics 12.8 U 12.5 U 12.5 U 12.7 U 72 $ 70 

Kerosene 12.8 U 12.5 U 12.5 U 12.7 U 12.7 U 12.7 U 

Cust ID: B16W83 B16W90 BLK BLK BS BLK BLK BS 

Sample RFW#: 005 006 03LE0577 -MB1 03LE0577 -MB1 03LE0583 -MB1 03LE0583-MB1 


' - D.F.: 1.00 1.00 1.00 1.00 1.00 1.00 

Units: mg/Kg mg/Kg mg/Kg mg/Kg mg/Kg mg/Kg 

p-Terphenyl 108 $ 104 $ 106 $ 91 $ 109 V 92 1; 

_______________°________________________=====fl=====__===== f1=====__=====f1=====__=====fl=====__=====fl=====__=====f1 

Diesel Range Organics - 12.7 U 12.5 U 12.0 U 74 $ 12.0 U 74 $ 

Kerosene 12.7 U 12.5 U 12.0 U 12.0 U 12.0 U 12.0 U 


$= Percent recovery. D= Diluted out. I= Interference. NA= Not Applicable. *= Outside of EPA CLP QC 

41,PoA^


i51-3a- 

Client 7- 11" FCQ'S--C cLO 

V roN eNtt rlr.v .-- 

Custody Transfer Record/Lab Work Request Page-Lot-1- 


Refrigerator# 

Est Final Pro). Sampling Date- 

J P 9 mype Container 

Protect x1!.,.'21'2`1 nr a- rrt - gRg9 ^^^ 

Project COntactftor er if volume 

LionvBle Laboratory Protecrrt^ -^^ r Cc's 

OC Del _1 LA TAT 

Liquid 

soetl - 

Liquid 

sow Sol 

Preservatives — 

r1NORG 

DateDate Recd5-?{ Due 

6- l y_ o] 

-rr"r—+_T T^ rl d.t 

ANALYSES __► 

REDUESTED m 

0 

m 

U 

MATR IX 

CODES: 

S - sou. 

SE - Sediment 

SO - sow 

ID 

Client ID/Description 

Marble 

OC 

^^ Mates 

MS MSD 

Ala Time 

Coitect9tl Collected 

_ 

d) 

J Lionville Laboratory Use Only 

U 

H 

C 

In 

C 

N 

SL- Sludge 

W - Water 

O- on 

A- Air 3 

DS- Drum 

Solids 

DL- Drum 

Liquids 

L- EP/rCLP 

Leachate 

WI- Wipe 

X - omar 

F- Fish 

1 3 

^9 vLl 

. 3 

DATEIREVISIONS: Lionville Laborato ry Use Only 

Special Instructions : n 12 latllX ©G C-1+0 3, 1 , 1 u Câf ^ê l^r,e :b-Ib tl) 

^,^" ^ ^.Samples were/ Tamper FlasiaUn! Seal was.' 

r 

t S ^^.J VV 5gv^(d^ '-'y -006 AJd A^ Af.3. 6C 4 CJ. Cr, C 1) Shipped s/— or 1) P wr re sent on Outer 

2 0 41 —i— Hand Delivered _ Package 6l or N 

pC 

3_ lid NI r P(r S6 SP^ LI. ° Ct, FI.) Nat t+L AvGg 2) Unbrokon Outer 

Package Y on N 

or 

4. 'NkUN 35(010 "Oil o yt*" . () (10c 2) Ambient or it 3) Present Sample 

Y) or N 

oPCe OD^ 3)Recetvedtn ood 

5. (UR4 

Cond it ion C or N 4) Unbroken on 

4) Samples Sample U or N 

6. 

Property PWerv^ 

Relinquished ReceWad Relin wished - Received 

CDC Record Present 

q Date Time Discrepancies Between Y or N 

Jbyy 

Date, by Upon Recl 

by by Samples Labels aM 

5) Received Within a N 

A„ ^►s e^^w CDC Record? Y or 

Q 

Holding Ti a Cooler 

F Pr'r x 

î NOTES: M pr N Temp. 1- 2—S -C 

RE ITT 5 SZ4 3a

FR-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-62 1 palic 1 of j 

Te le 

phone No. Project Coordinator 

JolmseNPopdPfister LC Hulsttom 373-3926 TRENT, SJ 

Collector Company Conta ct 

Project Designation Samp li 

ng Location SAF No. 

200-PW-21200-PW-4 OU - Borehole Soil Sampling 216-A-37 (C4106); (12.5-15) F03-W6 

Ice Chest No.^ 

!_ 

/ O S / Field Logbook No. COA Method of Shipment 

tP Y 

HNF-N-3361 117504ES10 Federal Express 

Price Code 8N Data Turnarouu 

Air Quality 45 Days 

q y 

Shipped To Wereof Olfsite Property No. Ô Bill of Lading/Air Bill No. (3^Q^ ^^_ 

2z o 

POSSIBLE SAMPLE RAZkRDVRMkRKS 

Cod 4C Cnd 4C Cod 4C Naee Noce 

Prese rvation 




No. of Contai ner(s) 

Volume 

Sample No. Matrix Samp le Date Samp le Time 

aG aG aG aG 

1 I I 1 1 

120m l. Wed. 12omL 60mL bpd, 

Clvoewm N07M03 . Oil&Qrrase- saiaaa(t)' TnW -M 

Hex-71% 3533 413.1 SIX," 

B16W79 SOIL G3 T^ 

IN OF POSSESSION Sign/Print Names SPECIAL INSTRUCTIONS 1:61- Z 1 r3 

Matrix 

^Frelabamtet7 ^ I 500 r 

• The laboratory is to 

Relinquished B ved F Dalerfime ^^ Received B /B road In Dwaine 

s-sou 

L3C2) .7 b i f ZI& ,2 1 g 515 report bo th kerosene and diesel range compounds ds from WTPH-D analysis. 

yE-yas^ 

KK f 3cJ 

x-0 v/ 

So-SdN 

yK^F 

Rdinq ished By/Rrmoved F 

DatwT= , 11 Received BY/Stood le `Datdfime '(+I 

00 w-ww 

T-^-.:. _ a,.. e.-,,.. oo m cool Sr Isorop c Tba' 

fn..... i»r. r:....., 

cJ 01 1r00 lY/ L// / 

_17,^ F L'L L Oj o-au 

Relinquished By Fmm Detdfime Reuived BY/Stoed DetNCume 

ps-p,,,n slim 

SJC-7*c.-E d;-Q2 0 F Ir IF m-_^ Lqu^ 

Reli ,By Fmm DatcTm Retei N DaWTiute 

S 

t a 3 

Relinquished BylRemoved F rom Daterfun Received liffStca4d In Dme/flme 

Relinquished By/Renoved From 

Datdfime Received ByMoted In Datefime 


relinquish samples rom the 3728 

Ref #-on 1-.^--1 

LABORATORY Received By SECTION 

Tale Dale/fume 

FINAL SAMPLE 

DISPOSITION 

Disposal M&AW 

Disposed By Dudfime 

BHI-EE-011 (0310112002) 

\\ 

M 

av-win 

v vàom° 

x ^w


Collector Company Contact Telephone No, Project Coordinator 

Johansen/PoperPfister I.0 Hulstmm 373-3928 TRENT, SJ 

Project Designa ti on Sampling Loca tion SAF No. 

20 0.PW-2200-PW-4 OU - Boreho le Soil Sampling 216-A-37 (C4106); (17.5'-20 F03-006 

Ice Chat C No-e-1^` 9( 0 § Field Logbook No. 

Shipped To ,`- f o b 

Otfsite Property No. 

Z 

POSSIBLE SAMPLE ARKS 



Preservation 


No. of Conminer(s) 

Volume 


B16WBO SOIL G3 (,o 

7TU cJ 

I I70504FS10 

CJ 

Method ^Hf SShhippmment 

Cod 4C CodK Cod 4C Nam N-1 

aG aG aG aG a 

I 1 I I 1 

120mL 60ML 120m1- 60m1, 64mL 

Chromium NOZW03- Oil&Gone- seta®(1)in Tiuum-H3 

H - 7196 353.3 4 13.1 spndat 

A ^( 

Price Code 8N Data Turmmn: 

Air Quality q 

Bill of Lading/Air Bill No. 5 d^ Q3t G 

dl 

45 Days 

IN OF POSSESSION Sign/Print Names SPECIAL INSTRUCTIONS /J^ Y L s r.3 Matrix 

eGngoidvd /Removed From Wnc Received By^/Smted In Dalw lrk!oe 

•• 


s.sau 

mpw both kerosene and diesel moat compounds Gam WTPH-D mulysm. 

`^ ^n g7Z $ 4tZ^ tp u 

=add 

Rcliogwshed By/Rwtoved From-' ^înm 

6 I A- 3726 5 

Received By/Stoted In Date/I'ime 

10-5 1 t eC b '}(33ted-d- 

(' 

J l O^ 1 10C) 

dinqushed By/R Date/Time 1 \OO Received By/Sloted to Dme/fime 

- no- 

I29 N' k "3 Neptul um-237 ^ y 

r `N 

/ 

iy 

SJ 6A1- s I o3 ti EX _mow 

w 

By/Removed m Datdrime Rtcti ved-B /S N Date/fine 

f 

Reli aga ished By/Removed From DLLdfime 

( eLVYI^ 

Received / ored In 

D^^. 9 3 Pe rsonnel not available to 

sample from the 3728 

Re)mggrdahed By/Remp32a From Date/Time Received By/Stored In Datdfime 

Ref q on 

LABORATORY Re ceived By ride Dat crime 

SECTION 

FINALSAMPLE Disposal Method Deposed By Dstdfime 

DISPOSITION 

BHI-EE-011 (03101/2002) 

n SWF 

W.W. 

o-oa 

A-" 

v-veamim v-v

FR-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-64 J PW 1 of 1 


Johmiseti/PopdP6ster LC Hulstrom 373-3928 TRENT, SJ 

Project Designa ti on Sampling Loca tion SAF No. 

200-PW-2/200-PW 4 OU - Borehole Soil Sampling 216-A-37 (61106); (27.5'-30) F03-006 

lee Chat No. 

tk 

C'(, j / O c^j 

Shipped To 

6 ^V^C^ 3,b 

UER bI en` 

POSSIBLE SAMPLE HAZARD&RF,MARKS 



Fie F1'-Ng-b3o36 Na 

HN 

Ofaite Property No. /l A ^1., O 

fT--, e/ 

Preservation 

Type of Contains 

No. of Container(s) i 1 

Volume 

Sample No. Ma trix • Simple Date Sample Time 

B16W81 SOIL 

1 I5 04ES10 

Method ^fE3^hi^ rat 

Fed 

cod 4C Coolk 01,,14C Nam Nam 

aG aG ad] aG 

1 I 1 

120a 60mL 120ml. 60ML 60mL 

Chralime NOVNO3 . 0,181 sxnan( )) Tritium-H3 

Hn-71% 1531 411 1 speoY 

l 

Pnee Coda 

8N Data Toroarou 


Bill Of Lading/Air B ill No. O /^ 

eJ 

CHAIN OF POSSESSION Sign/Print Names SPECIAL INSTRUCTIONS /^4" ` L ^; 

ime RRReeeoved By/Slored !o ^/QL < 

e - . •• The laboratory is to 

L•7 

repo rt bmh kerosene and diesel tinge canpounds fmm WCPH-D analysis. 

lIM 

q)X 

F Ir 

Reg By/Ramoved From ime JVIf Received Iared 1. Wfime I Lj 

• l 

l ' 

.:J 

7-301- C 1'10. U:r4n1.61 N—in n' ,n.91] / - JL 7-1([3" J 

7/ 

inquished ved I= ire Rcowved By&ored In Datrlrate 

,!y/^— 

f/af 

1vN' 

IJ.t.Tb 

Matrix 

so-sda 

stslds 

O'W 

^'A° 

^0.m50 

3 1/ 00 15j 03 or>•oa.m>.,ar 

yp^ 

Relinquished Bynitinoved Fmm W Wrime Received BY/Smred In 7 Date?ime 

( 110 

pmeyy 

_ Personnel not available to 

-- 

x-oue 

v9d Date/Time Reai to 

_ 

. a ^ Q^.7. ^ r. . 03 G : relinquish samples fro m the 3728 

Ref#[-on 

Relinga isbed By/Removed F— DaWrime Received By In Daldfime 

LABORATORY 

=L 

Received By SEC'nON 

Tide DatwTime 

FINAL SAMPLE Disposal Method Disposed By Dmdrime 

DISPOSITION 

BHI-EE-011 (03 101W02)

FR-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-65 J PW 1 of I 

Collector 

]ohanseNPopelP6ster 


200-PW-2/200-PW-4 OU -Borehole Soil Sampling 


DC Hulstrom 373.3928 

Samp ling Location 

216-A-37 (C4106); (37.5'-49) 

Ice Chest No 

ek L 9.^ 

/ 

O S Y 


HNF-N-3361 

Shipped To

FH-Central Plateau P roject CHAIN OF CUSTODY/SAMPLE ANALYSIS RE UEST F03-006-66 Page 1 of I 

Collector 

Johanser3Pope/PLster 

Project VeAgnathm 

200-PW-2/200-PW-4 OU - Borehole Soil Sampling 

Ice Chat N o. ,^yy C 4 

Field 

eR 

/J 

Shipped To tile, 

POSSIBLE SAMPLE HAZARDSIREMA 



LC Hulstrom 

373-3928 


216-A-37 (C4I06); (47.5'-50') 

Logbook No. 

HNF-N-3361 

COA 

117504ESIO 


TRENT, SJ 

SAF No. 

F03-006 


Fed er al Express 

Price Code $N 

Air Quality q 

MG #11ij ORaite Properly No. Z ?— O Bill of Lading/Air Bill No. ^C ^^^ 


Preservation 



Volume 


B16W83 SOIL (/ 

C.0 4C Cod eC Codk Nacre Noce 

"G 

sG aG aG aG 

I I I I 

120mL 60mL 120ml. 60ML 60mL 

Cknai. 

Flu-71% 

NOVK03- 

1512 

Oil a C.- 

4 13 .1 

See Ws(5)ot 

SpCv1 

I;Nv 

Tlidwn-lrl 

t 

'^ I 

JIQ,1b: 

CHAIN OF POSSESSION Sign/Print Names SPECIAL INSTRUCTIONS K LL !'f 

By Fm Dawn Received By/Stored In = 1LL 

•• 

lepmt bah sca=nt and diesel range cmlpmmds from WTPH-D analysis. 

êlmnmsladB Fmm 

p ' 1. 

.r p 

• 

17m 

vr •â^Y '—/t7^ 

Received y/St 

♦' 

N 

I 

r!f a t t{-er1 

4 K— -O3 

(I) 

r^qi N'^4dfis . Nentuu ni,23 

1 

- r, Lsaagc uln um• 

eh.q.skd B From ale 

Received By/Staed 

Date/fime 

3Z $t o7 110o 

ekogw&%cd By/ltemo F Da1ef m 

(7^rrV^• J 0 3 l /^0 

Re' '' By ved From 

Relinquished ByMemoved From 

dTiOC a 

DaWfime 

s S)O lob 

Received By/S in DelrlCime 

1-e- t= 

Received F}yV$ 

• Sec. Die 

Received. By^/S Daldfime 


Refg uish samples from the 3728 

051PC— 


7 


LABORATORY 

SECTION 

R—ved By Title -^G 

Date/rime 

FINAL SAMPLE Disposal Method 

DISPOSITION J 

Dispo=d By Daleffime 

BHI-EE-0 11 (03101/2002) 

45 Days 

- 

Matrix 

so-sdu 

swswgs 

w. wau 

wi-wip 

wi•wpe 

LK-4w 

x•u 

es

FR-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS RE UEST F03-00&73 page I of 1 


Jobaracrt/Pope"Ster LC Hulsuom 373-3928 TRENT, 51 


200-PW-2200-PW4 OU - Borehole Soil Sampling 216-A-37 (C4106) , (17.5-29) F03-006 


Air Quality q 

Ice Chest No.^^{{yy 

('1L C 

p 

l 

/ 05 S- 

Feld Logbook No. 

HNF-N-3361 

COA 

117504ESIO 



/ n 

Shipped To `- &Z, 2,-f 4112 ORsite Property No. It 

IT 

^2 0 

2,z- 

Q 

3 

Bill of fading/Air Bill No. 

53^ OS p 

POSSIBLE SAMPLE HAZARDS/REMARKS( 


Preservation 


No. of Conminer(s) 

Volume 

I 

Coal cod 4c Cad Roar N ane 

aG aG aG aG 

I I 1 I I 

120mL 60m l. 120mL 60ml. 60mt. 

mrvmum NO2/NO3- Oak Leas- See Ym Il)m Tdtwm-ID 

H -0196 353.2 413.1 SP-W 

t r, 

SAMPLE ANALYSIS / 

A a^ 

45 Days 

Samp le No. Matrix • Sample Date Sample Time 

1316W90 SOIL 

1 

CHAIN OF POSSESSION Sign/Print Names 17. 

SPECIAL INSTRUCTIONS Ma tr ix 

emoved F uae Ar Rrefceived By/Stored In Datdrime 

F[^ I F} 3.1 Z`d yZS o3 /6 YS 

. •• The labo ratory is to 

«port both kerosene and diesel range compo u d3 from WTPH-D analys is . 

urn- 

- 

s-sou 

SE-5 bn a 

•_ < ._^: _avT 

. ed By/RemovedF 

Y4- 37 

Date/Tuna 

j f 

Reserved By/Stamd W Date/fine 

so-sw4 

srs6.rf 

w-w m 

a 3 o 6U cSJ LC S/o3 >/oU Imo+ ^ L ^^^y 2, 

o-oa 

^° 

JnqmyBxIlt ^ 

DaWrime 

0 7 I I0 0 

ecesed By/Stmed 

h-" G G- 

DaVJrime 

os omm sdm 

D3D. uvm. 

Rfinq4plied By/R From 

ReWpuished By/Removed From 

Datdrmle 

03 

Da1e/rune 

i^ 

Received W 

Received By/St in 

Datorrimc 

0 0 

Date rime 


relinquish sâmpiesjrom the 377228! 

Ref N 2a 

T- - 

1:wu 

v-vpe.aw• 

x-aK, 

onon Relinquished By/R®o3ea _- r5-1 

/ lye — 

I — Ortr/rhne Received By/Stored In Daldrime 

LABORATORY Received By Tide Datdrime 

SECTION 

FINAL SAMPLE Disposal Method _ Disposed By Dmdfime 

DISPOSITION 

BHI-EE-011 (0310112002)

M-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST I Puruuo t^ _ - - 


Johamen/PopdP6ster LC Huhlrom 373-3928 TRENT, Si 


200-PW-2/200-P W4 OU - Borehole Soil Sampling 216-A-37 (C4106); (0.51 F03-OM 

Ice Cheat No. GGYYM^ q // ^- 

// 


G^ [ b W 

HNF-N-3361 117504ESID Federal Express 

C- 

Shipped To 40516) ,' l l C 2i"e Odfaite Property No.// 2 O 

POSSIBLE SAMPLE tLkZAADS/REMARKS 

Spatial Handling and/or Storage 


Preservation 


No. of Coolsiner(s) 

Volume 


B16W91 SOIL 'Z(j 0 

/rvV 7,2-6) 

caal.c cads 

aG aG 

I I 

60mL 250ML 

P.IwAdetamt 

th6r 

Hcbiddes- 

FrMtsl 

Price Code $jv Data Turnaround 

Air Quality 

Bill of Lading/Air Bill No. C - O,^ ., 

J 

" 

45 Da S 

y 

CH A IN OF POSSESSION 

i 

^Date/rime 

ZIA 

rRZ^!e ew^r ^By/Removed F DaWrime 

/) 3 5)03 Iloo 

Sign/Priat Names 

Received By/Smted In DaleJfime 

^'^ ft372$ 1--2-4;0.3 l yS 

Rxeived SpSto ed In Dmelrime 

d J i o3 trod 

SPECIAL INSTRUCTIONS Matrix 

SOW 

stal.us 

"""° 

Relinqu ished By/Remoôed^pDaUlrime 

/mm 

Received BY 

Date rime 

^-^° 

os-a^ sotw, 

ot. o,ae wan. 

1Jc^,r.^ S I O " 00 ^C 

ByAorrowd Fir m Dsterrime Received UDmcrrime 

Rdioquished By/Removed From Due?ime Received By t In /—^ DasoTime , Pet,,nnnel tnP { °tr ê ^^2^ 

teGcWOls^ h I 

^ 

eluxiulsbed By/Remowd Fmm Duarrime Received By/Stored N Dmerrime 

wet it 


SECTION 

FINAL SAMPLE Disposal Method DRpmed By DatdDme 

DISPOSITION 

BHI-EE-011 (03101/2002) 

Title 

Duterfime 

wt F 

wveyu lo. 

X-



DENT: I — NU a n /U 

irchase Order/Project: DATE: ^ - 3-(\3 

SOW# / Release H: Y(^ 3 [\0( 

a"Uoratory SDG /!:O S 12 _ 

IOTE: ALL ENTRIES MARKED "NO" MUST BE EXPLAINED IN THE COMMENT SECTION 

1, Custody seals on coolers or shipping . Yes 0140 0 NIA El see Co;;;n 


2. Outside of coolers or shipping containers are yes ONO O N/A o see Commem N 


3. Airbill # recorded? >ya ONO O N/A O see Comment N 

4. Allexpected paperwork received (coc and 

other client specific: historical data, Wts O No O NIA o see Comment a 

opha/beta or other screening date as 

applicable)? (paperwork sealed in plas tic 

bag and taped to inside )id) 

5. Sample containers arF inta ct? yes ONO O NIA O see Comment a 

6. Custody seals on sample containers intact, Cs ONO DNA O see Commem M 


7. All Samples On COC received? 

^^ 

O^^ 

y ,^Y, 

8. All sample label information matches coc? /y • es ONO O NIA - i7 tee Comment a 

es 

O No O NIA O see Comment N 

9. Laboratory QC samples designated on coc? O Yes ONO QWA O see Commem a 


10. Shipment meets LvLI Sample Acceptance yu ONO O NIA O see Comment M 

Policy? (identify all bottles not within 


11. Where. applicable, bar code labels are o yes O No QfN/A O see Corna"t M 



C Iles ONO o WA O see Comment N 

13. coc will be faxed or emailed to client? m yes• ONO O N/A O see Comme nt # 


conce rn ing discrepancies? (nameldate) 

Cooler # / temp (eC) and Comments : 

Laborato ry Sample Custodian: 

O Yes O No L9' 1A O see Commas a 

Laboratory Project Manager: ^^


GCSC ANALYTICAL DATA PACKAGE FOR 




B16W79 001 S 03LE0578 04/28/03 05/14/03 05/14/03 

B16W80 002 S 03LE0578 04/28/03 05/14/03 05/15/03 

B16W80 002 MS S 03LE0578 04/28/03 05/14/03 05/15/03 

B16W80 002 MSD S 03LE0578 04/28/03 05/14/03 05/15/03 

B16W81 003 S 03LE0578 04/29/03 05/14/03 05/15/03 

B16W82 004 S 03LE0578 04/29/03 05/14/03 05/15/03 

B16W83 005 S 03LE0578 04/29/03 05/14/03 05/15/03 

B16W90 006 S 03LE0578 04/28/03 05/14/03 05/15/03 

LAB 4C: 

BLK MB1 S 03LE0578 N/A 05/14/03 05/14/03 

ELK MB1 BS S 03LE0578 N/A 05/14/03 05/14/03 

^ 

JUN 

2043 

y^ `r ^ N 

r. a 

a


LVL #: 0305L329 

SDG/SAF # H2194/1`03-006 

GC SCAN 



W.O. #: 11343-606-001-9999-00 


The samples and their associated QC samples were prepared according to method 3580A (waste dilutionlg 

into 5mL) on 06-14-2003 and analyzed on 06-14,15-2003 according to Lionville Laboratory OPs 

based on SW846, 3rd Edition procedures based on method 8015B for Methanol, Ethyl Ether and 1- 

Butanol. 



1. 

All results presented in this report are derived from samples that met LvLI's sample acceptance 

policy. 

2. Samples were prepared outside of holding time; however, samples were analyzed within required 

holding time. A copy of the Sample Discrepancy Report (SDR) has been enclosed. 


4. Surrogates are not currently employed in the methodology. 

5. All blank spike recoveries were within acceptance criteria. 

6. All matrix spike recoveries vote within acceptance criteria. 

All initial calibrations associated with this data set were within acceptance criteria. 


criteria. 





I ' Daniels Date 

aboratory anager 


r:\group\dahogcsc\tuuu\0305w329xAoc 

The results presented in this report relate only to the analytical testing and conditions of the samples at receipt and during storage. All pages of (his report are integral pans of the 

analytical data. Therefore, this report should only be reproduced in its entirely of 1 5 pages. 

02 


Lionville Laborato ry Sample Discrepancy Report (SDR) SDR #: o 36c ,c, 

Initiator: Jot,., L.0,. Batch: o3ost-315. Parameter: obc.ic Mfow*Eiva/T 

Date: 61"(1-Y Samples: I.9--5 Matrix: So- I 

Client: TafV Method: SWe4 6IMCAVwWCLP/ Prep Batch: 03 t-EOS-1Y. 


a. COC Discrepancy _Tech Profile Error 

Transcription E rror 

Client Request — 

_ Wrong Test Code Other 

Error on C-O-C 


_ Missing Samp le/Extract _ Container Broken _ Wrong Sample Pulled _ Label ID's Illegible 

Hold Time Exceeded Insufficient Sample _ Prese rvation Wrong _, Received Past Hold 


Note: Verified by [Log-In] or [P rep Group] (drde) ... signatureldale: 


5^^P\t5 p hi ^.ic^. x-0-75 P-a koÀ 



_ Re-log 



_ Re-leach 

_ Re-extract 

Re-digest 

Revise EDD 



p 

Ivy sK . 

4. P oject Mager instructions ... signatureldate: 

Concur w 

an ith Proposed Action 




_ 

Date/Person 

Add 

_ Cancel 

5. Final Action... signatureldate: 6 ( wr :, Other Explanation: 

Verified re-liog)lleach)(e ldigestlianalysis] (circle) 

^cluded in Case Narrative 

Hard Copy COC Revised 


_ EDD Co rrections Completed 

When Final Action has been recorded, forward original to QA Specialist for distribution and filing. i 

Route Distribution of Completed SDR Route Dist ri bution of Completed SDR 

X Initiator — _ Metals: Beegle 

_ X Lab General Manager: M. Taylor — _ Inorganic: Perrone 

X Project Mgr. Stone/Johnson/Haslett — _ GC/LC: Kiger 


_ X QA (file) _ _ Log-in: Melnic 

Data Management: Feldman _ Admin: Soos 

_ _ Sample Prep: Beegle/Kiger _. _ Other. 

aa.1 05-A- 0e0 1 

i

OLVMLIM 


GLOSSARY OF GC SCAN DATA 

U = Indicates that the compound was analyzed for but not detected. The miriimum 


(e.g., IOU). 




3J. 



E = Indicates that the compound was detected beyond the calibration range .and was 



ABBREVIATIONS 



are reported. 





analysis. 





M

a v 1 


P = This flag is used for an GC SCAN target analyte when there is greater than 


(see Form X). The lower of the two values is reported on Form I and 

flagged with a " " 



C = This flag applies to a compound that has been confirmed by GC SCAN. 

R./SHARE/GCVOLATILE/GCV OLATILEGLOS.DOC 

S


GC SCAN 

Report Date: 06/15/03 12:52 

RFW Batch Number: 0305L329 Client: THDHANFORD F03-006 H2194 Work Order: 11343606001 Page: 1 


Sample RFW#: 001 002 002 MS 002 MSD 003 004 


D.F.: 1.00 1.00 1.00 1.00 1.00 1.00 

Units: mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg 

_____________________________________________fl=====__===== fl=====__=====fl=====__=====f1=====__=====f1===== __=====fl 

Methanol 28 U 25 U 98 % 98 W 23 U 23 U 

Ethyl Ether 28 U 25 U 105 92 23 U 23 U 

1-Butanol 28 U 25 U 94 94 23 U 23 U 

Cust ID: B16W83 B16W90 BLK BLK BS 

Sample RFW#: 005 006 03LE0578-MB1 03LE0578-MB1 


D.F.: 1.00 1.00 1.00 1.00 

Units: mg/kg mg/kg mg/kg mg/kg 

___________°______________'°____________=====f1=====__=====fl=====__=====fl=====__=====fl=====__=====fl=====__=====f1 

Methanol 24 U 26 U 25 U 101 

Ethyl Ether 24 U 26 U 25 U 86 

1-Butanol 24 U 26 U 25 U 94 


t= Percent recovery. D= Diluted out. I= Interference. NA= Not Applicable. *= Outside of EPA CLP QC 

e\^tl

U ro ti oNw f (rto rju— /tvlu! wk, -^,.• 

Lionville Laboratory Use Only I Custody Transfer Record/Lab Work Request Page —L or_.l_ 

PI11; 


SL.^ 

Client —TV%?&D =SRSL F L),"S-cry p 

RehigeretorM ^ Z 

Est Final Prof. Sampling Date 

Project Y 1131 

;rrrype Container 

Liquid 

Z) --C.f,4Mf e- 

Project Contacf/Phone 0 Volume 

Lionville Laboratory Labor Project flAsnag e► n^ 

oC Dal _'RDI^ TAT 

Date Rec'd r1• U Date Due -f' o^ . k(,% — 

MATRIX 

CODES.- 

Liquid 1 

Solid 

Pressrvatwes — _ — — — 

ORGANIC INORG 

, to - 03 

t i .,` f r 7 

Matrix 

ANALYSES 

REQUESTED 

Q 

O 

> 

¢ 

Z 

CO 

n m 

m U 

a a 

.e 

m 

= 

j 

m 

2 U 

Lionville Laboratory Use Only j 

Chosen 

Client ID/Description 

Matrix 

soil u 

ID 

Collected Collected m In 

SE - Sediment ( 

J C 

MS MSD 

N M 

SL Stage 

W - Water 

0 . ai 

A- Air 

DS D ru - m 

Solids 

DL- Drum 

11 

1 3 

L - EP/TCPP 

Leachate . ^. 

WI • Wipe 

X- Other 

F . Fish 

1 3 

Special hs tructbns. ` _ DATE/REVISIONS: 

I 


Il t^lT`X ©C Pv C(,a, 1. 

S-1^•ol 1. 'b +e Oak -6-16-0) 

T 

Samples were! Temper Resistant Seal was: 

l t` f O y Be d 1) Shipped V— or 1) Present on Outer 

° dt 3Cp s lda z Dole Add A^ At 3 g. c1 Cr Ca 

Hand Delivered _ Package or N 

(fy) 

3.1NTf S^ i le /LL- C( • 1" I • NN .#0' fbt s arbii -# l -{---(r— 2) Unbmkp on Outer 

n/ ( y 

^^)^n_ .^^ Package(Y or N 

a. INA39 t1CM 1PH a bZwN. 06Z1X . GOC 2) Ambient or in 3)Present nSample 

S. OPCO ^DR/9 

()JA3)Received in ood 

()JA 

Condi tion C or N 

Y) or N 

I 4) Unbroken on 

Relinquished 

by 

J 

F A(,EX' 

Received 

Dale Time 

I 

B 


Q ^„ 

b 

ê 

Dete a 

tnnw 

Time 

4) Samples 

Properly erved 

Discrepancies es,L^H r or N 

Samples and^Withinin Tit 

CDC Re cord? Y or LN Holding 

NOTES: 

Sample U or N 

CDC Record Present 

Upon Sam/pie 

Rec't 

U or 

Cooler 1 

- N Temp. _5.-2_ °C 

RE ITT V- RZ441 .3 3

FH-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-62 JPWF 

Collector 

lohnnsen/Pope/Pfister 

Proje ct Designa tion 

200-PW-2200-P W-4 OU - Boreho le Soil Sampling 

lee Chest No. Lq / 

/^. ( V 

O 

Shipped To Rereof 

POSSIBLE SAMPLE HAZARDSIREMI 


Z Z rt 



LC Hulstrom - 373-3928 

Samp li 

ng Loca ti on I 

216-A-37 (C4I06); (12.5'-151 


HNF-N-3361 

COA 

117504FSIO 

Offske Property No. ' .7 O 

C^ 

Preservation 


No. of Cootainer(s) 

Volume 

Sample No. Matrix • Sample Date Sample Tithe 

B1 6W79 SOIL 


TRENT, Sl Price Code $N 

SAF No. 

F03-W6 



Cad 4C Gal 4C Caul eC N. Noae 

a G aG aG aG 

I I I 1 1 

120ml, 6OmL 120m I, 60mL 60m. 

Cwooiio NO7/NO3- WaGmne• sec' (I) - Twu.-m 

Flea, -7196 3533 413.1 $padd 

Bill of Lading/Air Bill No.^ 

Air Quality q 

IN OF POSSESSION 

ReOnquished B ved Fm Dmca(T me 


^9ffRneceived B /Stared In Datdfime 

'^ b t t Z&TO2 

P7 ( 

(7' S!5 

F J r-0 T / 

SPECIAL INSTRUCTIONS E Z a3 

.. f sO r 

report both kerosene and diesel range compounds fiom WIPH-D 0 ^' analysis. 

Reloci ished Fred Daterrime j 

160 

Received By/Stomd In 

Datefrlme 

cT O^ IIO O 

um- 

. ^7.Z O J 

Relinquished By/Reolo 

SJ(L E 

From 

/f^7 

ddXR 

Date/F' Received BY/Slaed 

0 F6- 17) EX, 

Datetime f 

By ved I= 

Relinqued BylRemoved F 

,5 

Deterrent: 

3 O 

Recti 1n Datefrime 

Se3 t7:' Q -- 

ro ish m 

DaucTucm ReceivedB St N Dwetrune 

Relinquished BylRemoved From Dwe(Flme Received By/Staed In Date/Time 


'(1) T-cein came p9i Stru $99n Total S isotopic ThoriTh1' oatI,-ied'ato- 

Persolmel not available to 

relinquish samples Tom37728 

Ref # —on io 

LABORATORY R ec eived By -. Tide Dmdrime 

SECTION 

FINAL SAMPLE Disposal Method Disposed By Daldrum, 

DISPOSITION 

BHI-EE-011 (03101/2002) 


45 Days 

Matrix 

s-^t 

so-aora 

st-sWeae 

W 

o-oo 

A-N 

w. 

ûL-p,e.l^yi6r 

T-r. 

Uu4ua 

x^

M-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F 

---I03-006-63 ê of j 

Collector Company Con tact Telephone No. Proje ct Coordinator 

Johansen/PopeJPfister LC Hulst rom 373-3928 TRENT, Sl 


200-PW-2/200-PW4 OU - Bo rehole Soil Sampling 216-A-37 (C4106); (17.5'-2(Y) F03-006 

Ice Chat No-oz C Q/ o ^ ` Field Logbook No. COA Method of Shipment 

j(o b HNF-N-3361 117504FSIO Federal Express 

Shipped To 

ZO 

O Mile Property No. ^{ 

cJ 

^l 

V 

POSSIBLE SAMPLE HAZARDWREMARKS - 





Coo 

Volume 

Samp le No. Matrix • Samp le Date Sample Tint 

B16WBO SOIL ?,^ (J^ (:o 

C9olaC CooleC CaoleC New N-1 

aG aG aG aG 

1 t I I 1 

120ML 6OmL 120m l. 6OmL 60 

0 

Ove.us N07MO3 - W&rams:- Seearm(I)m Tri tium-H3 

Hex-7196 353.2 013.1 Speeid 

Price Code 8N Data Turns 

Air Qua lity p 

Bill of Lading/Air Bill No. a-a 0 L 

1. 

y 

45 Days ys 

IN OF POSSESSION Sign/Print Names SPECIAL INSTRUCTIONS -'f fjei y^L Y a t Matrix 

Relinquished /Removed From ins; ev Re ceived By/Stored In Dmdfime 

DatdTime 

'up 

/rl 1,721 $ IfZT05 fb 141 

c 


elioqulshed BY/Removed F 

6 ) A- s'7 z g S i o 3 1 t ec 8J %rr>

FR-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-64 TPav 1 Of I 

Collector Company Con tact Telephone No. Project Coordinator 

JohanseNPope/P6ster LC Hulsnom 373-3928 TRENT, SJ 

Project Designation Sampling Location SAF No, 

200-PW-2200-PW4 OU -Borehole Soil Sampling 216-A-37 (C4106); (27.5'-30') F03-006 

fee Chest No. yJ 

OZ c, R 

// 

d ^b 


HNF-N-3361 

Shipped To - 6- Cx Otfsite Property No. he ^l v c^ 

POSSIBLE SAMPLE HAZARDSJREMKS AR 


Preservarioo 


No. of CoOminer(s) 

Volume 

^{ O 

COA 

117504ESIO 



Cod 4C Coal 4C Cod 4C Nm Noee 

aG 

A aG aG 

1 t 1 i it 

120mL 60mL 120m], 60rrrL 60m l, 

Price Code 8N Data Turnarouo 

Air Quality q 

Bill of Lading/Air Bill No. ^^.^ O^ ^C J 

Caraeium NONNO3- 00 e. Gnaw- See kem(I) Trirvm. H3 

Hes-71% 353.2 413.1 Spedd 

SAMPLE ANALYSISd t^ . 


B16W61 SOIL y. `^ ^lJ!ll) 

^l 

v 

1 J.t,Tp 

45 Days 

CHAIN OF POSSESSION Sigo/Print Names SPECIAL. INSTRUCTIONS 1I ` d) Matrix 

mm Regoved By/St..d 1. 

n 

^^f 

` 

tdri 

the 

report both kerosene and diesel range coupoumis f rom WTPH-D analysis. 

no laboratory is to 

Rel' wished By/ReorDVed From 

K 

isle J^^^ ReceivedB toed In 

..^-D/- 

.îqi uL.LC1^] Nent ^:,^..Ti'1 

ttc/riithe 

elinquatted ved Fr= 

i ^ ( 

dfime Received 8 /Stored la 

I t{ 

.^ 

- 4 YJ 

Datdfime 

'} 

II^ 

r 3 

3 It oa 15J 10 J 

Relinquished By/R ved Fttan Date/Time Received By/Stared N Date/rime 

- Personnel not available Re q ' ved From Dme/Cime Recei / t N Date/Iirae 

to 

,. Syr— , .r. . 03 relinq'uiQsh samples from the 3728 

Ref f[a^013 

Relinquished By/Removed From Dahlfime Received By red N DatwT me 

LABORATORY 

SECTION 

Received By Tide Datefrime 

FINAL SAMPLE Disposal Mathod Disposed By DatcTime 

DISPOSITION 

BHI-EE-011 (03/0112002) 

s-sdr 

sa-^^ 

wsotr 

s swec 

W.W. 

0-Dn 

a-â 

DYD—Li, 

DL-D^mv llp^ 

TK 

wl-wipe 

v-vepaa^ 

xis°

FH-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS RE QUEST F03-006-65 Page 1 Of 1 

collector Company Contact Telephone No. Project Coordioalor 

Johansen/Pope/P fistcr LC Hulstrom 373-3928 TRENT, Sl 


200-PW-2aWPW -4 OU - Rombok Soil Sampling 216-M37 (C4106); (37.5'-0(Y) F03-006 

Ice Cheat No. 

G Q.(o 

// 

O s Y 


HNF-N-3361 I 

COA 

117504ESIO 



Shipped To ^C 7 by Olfsite P roperty No. L1 ^ 3 

/T CJ jo Z-7-0 


7. 

POSSIBLE SAMPLE HAARDS(REMARKS 



Preserva tion 


No. of Co Container(s) 

Volume 


Cod 4C Coa14C Cod 4C Noe Noce 

aG aG aG aG 

1 1 1 1 1 

120m1, 60ml. 120ML 60mL 60mL 

- Clwo:lm 1402/1403- OJk Gwm- sft (I) Tdtiam-10 

HU-]196 353.2 413.1 SpaiY 

1mum+m 

\yN 


Air Quality q 

BlBW82 SOIL ,`l-rl 3 0qd j 

CHAIN OF POSSESSION Sign/P rint Names SPECIAL INSTRUCTIONS 3'f ^j'`- 2 z 1 

F By/Sloted N 'E a2` ime 

•• 

u o 

/ ` report both teroune and diesel range eompotmds bom WfPH-D analysis. 

MwsW B ved From / Received B /Scored U 

une t jrC>a 

•& o 7 ^. LIP. 

e0rgttisbed By ved F ioc Rmxived By/Stored ^^ 

. •• The laboratory is to 

45 Days 

/6 so-c 

( 

- o 

12,=; ^.Tai%.3i ' êPLe3-ia7 /^ f/2 ^// 11/0 

D6-Dmm6 d 

tl 3 Z) 0 3 // I Q ^, / /yV DVDrvm LpuiCs 

r-r 

WI-Wipe 

RcW qwA" By/Raooved From Datvfime Received By/St 1 103 Daterrime 

51 — Personnel not available to 

V-V o wm 

reli 

/' 

uish samples P from the 3728 

Xe' 

By From Datr/rtme Receive 1 In Dete/fuoe 

Ep 

eliogaished BY/Removed F rom Datcfrime Received Bf/Sdred In Datoll ime 

„^ a3 X3 7 Y5 Ref # L!3 on c,3 


Tole Datefrime 

FINAL SAMPLE 

DISPOSITION 


Disposed By DatNTime 

BHI-EE-011 (031012002) 

f 

Matrix 

s•sm 

sl-slw 

o-ou.er

FE-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-66 P &9e 1 of 1 

Collector Company Contact Telephone No. 

LC HuLnrom 373-3928 



la Chest No.OR C 4 (PC) S 

Shipped To î/

FH-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-73 Page 1 of 1 


Johansen/Pope/Pfister LC Hulshom 373-3928 TRENT, SJ 

P ro ject Designation Sampling Loca tion SAF No. 

200-PW-2200-PW-4 OU - Borehole Soil Sampling 216-A-37 (C4106); (17.5'-20) F03-M 


Air Quality q 

Ice Chat No.q ` 


ez C ` !^ o S^ HNF-N-3361 117504ES10 Federal Expr es s 

n 

Shipped To - / `- ^g,4 -f*-z Offsite Property No.,A 2 Z Z Q 

Bill of Lading/Air Bill No.^ a j r 

POSSIBLE SAMPLE FIAZARDS(REMA 



Preserva tion 

f'T 3 

Type of Container ao 


Volume 

Sample No. Matrix • - Sample Date Sample Time 

B161M1/90 SOIL (a 

cod eC Cod eC Cod 4C No: Na 

ao ao so 

1 I I I 1 

120.1- 60mL 120mL 60.4 6QnL 

Chromium NO2NM- Oil k Carrie- Smk.(1)in Tria..-R3 

Ha -71% 353.2 013.1 Sprd.l 

la.aatm t y 

1 r` 

P a^ 

45 Days 

CHAIN OF POSSESSION Sign/P rint Nam es 

SPECIAL INSTRUCTIONS 1/7 q q/ Matrix 

moved F Brune Received By/Srwed N Dete/I'ime •• The laborato ry is to 

port bo h kerosine and diesel range compounds from WTPH-D analysis. 

Re-P I Pr 37nr y 7-8 o3 16 VS sa-sN. r 

re 

so-sau 

' dished By/Relmved F D"u'T= Received By/Stmed In Dateffime 

onurn- 

Nîms 

I A- 372ir J I b 7 rl aU ZJ LC X/o3 9/oc) 1 6-i^,.u: 

_ ,i,_ 

w.w.a, 

^ c^^tyê} 

0. 1 

R^cllinquished By m Datefrime Received By/Smnd DatcTime 

( 

V^ J O / j D O r Ci l^J 

RAW By ved From DatcTune Received N Duefrime 

v3 i r VJ3 0 

Rel inquished By/Removed From Date/Tune Received By&oied In Datelrime 

Rckogmshed By/Removed From Iktdrune Receive BylStartd 1n DatNfime 


relinquishtcampl es from the 3728 

Ref #Lon /^_/0 

LABORATORY Rived By Tide Date fume 

SECTION 

FINAL SAMPLE Disposal Method Disposed By DaWrime 

DISPOSITION 

BHI-EE-011 (031012002) 

6-ur 

DS-D. Ld 

OVDrim llWa. 

vn.wwr 

et•" v-v.yeaa. 

x-ame

FU-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-000-74 ',- - 

Collector 

JohanaeNPope/Pfater 


200-PW-2200-PW-4 OU - Boreho le Soil Sampling 

Ice Chest No. &W C_ n / 

G —` b OS ^Wj 

Company Cont act Te lephone No. 

LC HubVOm 373.3928 

Sampling Loation 

216-A-37 (C4106); (0.5') 

Feld Logbook No. 

HNF-N-3361 

Shipped To ""051 o3 , \rte 21R Off" Property No' 




1too' 

Preservation 



Volume 


B16W91 SOIL ZfS p y 

V 

COA 

117504ESI0 

Z O Z^ z /7i 

f 

cuel6 Ced 4C 

aG aG 

I I 

60ML 250.uL 

P. Adder - 

so] 

Chic. 

flewd . 

Prutst 

N OF POSSESSION Sign/Print Names SPECIAL INSTRUCTIONS 

r â Dwz rime Received By/Stored In Daterrime 

^^ pr 372$ 52 Z_ 03 aYS 

R li ,-shed By/Ramved Filies Dst Jr ime 

57n 5103 1100 

Relinquished ygtemoved rum Do 

C) 

S ! o - 


Datdrime 

J Rio} Ilod 

•ved Byrst N DWdfime 

B emoved Fmm f>DUD^ Receved ti Datdrime 

- 

Relinquished By/Removed Form, DatM acne Received B In Dhterrime 

elinquished By/Remuved From Da4Jrime Received By/Stored In Dadrime 

LABORATORY 

SECTION 

FINAL SAMPLE 

DISPOSITION 

BHI-EE-011 (03/012002) 

P^Snnnel rot 

) li 6 sonil 

to\\nQ^ )S 

lief # , 1/ 

Proje ct Coordinator 


SAFNo. 

F03-006 



Bill of Lading/Air Bi ll 

saaaammamlimmommag 

(om n ?" 

I 

Air Quality E) 

No. C ^- 63 7 

J 

F C_ 

Received By Title Daterrime 

Disposal hkdwd 

Dapaacd By Daterl'ime 


45 Days 

Mat rix 

s-wt 

sesm... 

SG sa 

n_Sx r 

W.W. 

x'^" 

SAM 

n'^n^° & 

rnr. 

wt_w^ 

^tn°u v.V¢a+_ 

x-am


r SAMPLE RECEIPT CHECKLIST 

EN T: iTSi( HQA-V t!O^ 

:hale Order/Project: DATE: Sa-03 

SOWN / Release N: YU 3• bo(, 

)oratory SDG N: 

X05 L 3 2î 

PTE: ALL ENTRIES MARKED "NO" MUST 13E EXPLA]NED IN THE COMMENT SECTION 



yes 0 No 0 NIA s« Comment 

2. Outside of coole rs or shipping containers areY} Yes ONO p NIA O sec Comment M 


3. Airbill N recorded? Iy cs ONO p NSA 0 sec Comme nt N 

4. All expected paperwork received (coc and / 

other client specific: historical data, 


applicable)? (paperwork scaled in plastic 


^ 

"W u ONO p NIA q see Comment M 

5. Sample containers are intact? flyu q No q NIA 0 rec Comment M 

6. Custody seals on sample containe rs inta ct,^/p'` _yes p No p N/A p see Comment M 

signed and dated? _ . 


S. All sample label information matches coc7 

Pl Yes p No p NIA O see Comment tr 

e^lynt 

ONO 0 NIA • -to see Comment x 

9. Laboratory QC samples designated on coc? q Yes p No ^pp'WA q sec Comment x 

(QC stickers placed on bottles?) / - 

1 0. Shipment meets LvLI Sample Acceptance 



y es ONO p NIA O s« Comment N 

] 3. Where applicable, bar code labels are p y" ONO q set Comment N 

affixed to COO 

1 2. coc signed and dated? Wes ONO p NIA p see Comment K 

13. coc will be faxed or entailed to client? Is Yes• ONO q NIA 0 see Comme nt M 



Cooler N / temp (eC) and Comments: 

^ ^.2G î(o-G5(p ^ l 3'^— 

Oyu ONO l3la/A O see Comment K 



^( ^ 

&V' ' - o"? 

L 

I


8015 ANALYTICAL DATA PACKAGE FOR 




B16W79 001 S 03LE0586 04/28/03 05/15/03 05/15/03 

B16W80 002 S 03LE0586 04/28/03 05/15/03 05/15/03 

B16W81 003 S 03LE0586 04/29/03 05/15/03 05/15/03 

B16W81 003 MS S 03LE0586 04/29/03 05/15/03 05/15/03 

B16W81 003 MSD S 03LE0586 04/29/03 05/15/03 05/15/03 

B16W82 004 S 03LE0586 04/29/03 05/15/03 05/15/03 

B16W83 005 S 03LE0586 04/29/03 05/15/03 05/15/03 

B16W90 006 S 03LE0586 04/28/03 05/15/03 05/15/03 

LAB QC: 

BLK MB1 S 03LE0586 N/A 05/15/03 05/20/03 

BLK MB1 BS S 03LE0586 N/A 05/15/03 05/15/03 

r7Aj5- 2n62;P 

1 

ON 2003 

go to 

U OA 

FL 

1


C lient: TNU-HANFORD F03-006 W.O.#: 11343-606-001-9999-00 

LVL #: 0305 1,329 Date Received: 05-02-2003 

SDG/SAF # 112194/1703-006 

GC SCAN 


The samples and their associated QC samples were prepared according to method 3580A (w aste dilutionlg 

into 5mL) on 05-15-2003 and analyzed according to Lionville Laborato ry OPs based on SW846, 3rd 

Edition procedure, b ased on method 8015B on 05-15,20-2003 for Ethylene Glycol. 

The following is a summary of the QC results accomp anying these sample results and a description of 



policy. 

2. Samples were prepared outside of holding rime. A copy of the Sample Discrep ancy Report 


3. Surrogates are not currently employed in the methodology. 

4. The blank spike recovery was within acceptance criteria. 


6. All initial calibrations associated with this data set were within accept ance criteria. 

All continuing calibration standards analyzed prior to sample extracts were within accept ance 

criteria. 

8. I certify that this sample data package is in compli ance with SOW requirements, both 

technically and for completeness, other than the conditions detailed above. Rele ase of the data 

contained in this hard-copy data package h as been authorized by the laboratory Manager or a 


- - - ^ J^" s^ 

n Daniels e,11 



r9group\data*=\rums\0305-329.doc 

The re sults pre se nted in this repo rt relate only to the analytical testing and conditions of the samples at receipt and du ring storage. All pages of this repo rt are integral pa rts of the 

analytical data. Therefore, this re po rt should only be reproduced in its enti rety of 1 5 pages. 

02 

208 Welsh Pool Road • Exton, PA 19341-1313 • (610) 280-3000 • Fax (610) 280-3041 

ate

Lionville Laborato ry Sample Discrepancy Repo rt (SDR) 

jl t 

SDR#: O36c 1-%1( 

Initiator: ^^ L Date: 

Client: rN 3 

Batch: 0305 /- 3>- Sit, 3 >>, 1 ` PParameter. O&Lsc ire. 

Samples: rTrt ;zt , 011 Matrix: So-' 

Method: SW846/MCAWW/CLP 1 Prep Batch: ca3 say. 


a. CDC Discrepancy _Tech Profile Error Client Request Sampler Error on C-O-C 



_ Missing Sample/Extract _ Container Broken —Wrong Sample Pulled _ Label ID's Illegible 

Hold Time Exceeded Insufficient Sample _ Prese rvation Wrong _ Received Past Hold 

_ Improper Bo ttle Type _ Not Amenable to Analysis 

Note: Verified by (Log-In] or [Prep G roup] (drde) ... signature/date: 

c. Problem (Include all relevant specific results; a ttach data if necessa ry) 

Sumo is 3i%t _& P v tr.. yS P ti l^^Yd. 

y en p_ it ,S k..T ] t b I l G-c 


f P.- ] L 7 . 


_ Re-log N° t e 

_Entire Batch/ No H . is t ^ SP" Ptf S- r+l•ti" 

Following Samples: 6D 

_ Re-leach ^^ ^^fe rFr-- o^, ^^° T ^^) 

Re-extract 

_ Re-digest 

Revise EDD i 


Place On/Take Off Hold (circle) 

/1 p1^- S 

4. Pjô]ect Manager Instructions ... signature/date: 

V Concur with Proposed Action i 




Date/Person 

_ Add 

Cance l 

5. Final Action ... s gnature/date: t: W Other Explanation: 

Verified re-Ilog)[leachge t][digest)[analysis) (circ e) 

_ ncluded I in Case Narrative 




When Final Action has been recorded, forward original to CIA Specialist for distribution and filing. 

Route Distribution of Completed SDR Route Distribu tion of Completed SDR 

X Initiator _ _ Metals: Beagle 

_ X Lab General Manager. M. Taylor _ _ Inorganic: Perrone 


X Technical Mgr: Wesson/Daniels _MS: Rychlak/Layman 

XX QA (file) _ _ Log-in: Melnic 

Data Management: Feldman _ Admin: Soos 

_ Sample Prep: Beegle/Kiger _ _ Other. 

QA-105-A-0801 

3

LV=L= Ml 



U = Indicates that the compound was analyzed for but not detected. The miriimum 


(e.g., IOU). 




3J. 






ABBREVIATIONS 



are reported. 





analysis. 




SP = Indicates Spiked Compound.

0LVI M, 


P = This flag is used for an GC SCAN target analyte when there is greater than 


(see Form ?). The lower of the two values is reported on Form I and 

flagged with a ?" 



C = This flag applies to a compound that has been confirmed by GC SCAN. 

R:/SHARE/GC V OLATILE/GCV OLATILEGLOS.DOC


Nonhalogenated Volatiles by GC, Method 8015 Report Date: 06/19/03 15:11 

RFW Batch Number: 030SL329 Client: TNUHANFORD F03-006 H2194 Work Order: 11343606001 Page: 1 

Sample 

Information 

Cust ID: B16W79 816W80 B16W81 B16W81 B16W81 B16W82 

RFW#: 

Matrix: 

D.F.: 

Units: 

001 

SOIL 

1.00 

ug/Kg 

002 

SOIL 

1.00 

ug/Kg 

003 

SOIL 

1.00 

ug/Kg 

003 MS 

SOIL 

1.00 

ug/Kg 

003 MSD 

SOIL 

1.00 

ug/Kg 

004 

SOIL 

1.00 

ug/Kg 

_____________________________________________ fl=====__===== f1=====__===== fl=====__===== f1==== =__=====f1===== __=====fl 

Ethylene Glycol - 25.5 U 23.5 U 26.0 U 99 & 97 k 25.5 U 

Cust ID: B16W83 B16W90 BLK BLK ES 

Sample RFW#: 005 006 03LE0586-1481 03L80586-MB1 


D.F.: 1.00 1.00 1.00 1.00 

Units: ug/Kg ug/Kg ug/Kg ug/Kg 

_____________________________________________ f1=====__=====f1=====__=====fl=====__=====f1=====__=====f1=====__=====f1 

Ethylene Glycol 24.0 U 22.0 U 25.0 U 108 k 


k= Percent recovery. D= Diluted out. I= Interference. NA= Not Applicable. *= Outside of EPA CLP QC


•51.-3^ 

Client ^[^,l- ^Y'1^trl(t'^ ^(^?1-LY^L Q 

U YOH Prat* r trv, 

Custody Transfer Record/Lab Work Request Page-LOf-^- 


n e?) 

Est. Final Prof. Sampling Data . #lrype Container 

Project # I I Âlî-r'..r-^ u- mt - g44Q^^0 

Refrigerator N '^ Z 

Liquid 

vLl 

Solid j 

Project Contact/Phone # 

Lionville Laborato ry Projec2t Manager C1^ 

QC Del ^.>Jf.e^ TAT 

volume 

Preservatlws 

Sdid 

- 

ORGANIC 

_ 

INOFIG 

011 62CL 

_ _ - 

Date Recd ^'?{l^ 

MATRIX 

CODES: 

- 

S - Soil ID 

SE- Se diment 

SO - So 

t; - 16- 03 

Date Due i-cis 

Clbm IDIOeaeriptlon 

rFr^.r 

Matrix 

Clan 

ANALYSES_^ G 

REQUESTED O 


G 

m m 

co mo m 

f 

= 

j 

m 

OZ 

Lionville laboratory Use Only 

[ 

In 

3j 

, 

l 

li d 

SL - Sludge 

W - Water 

0- 00 

A - A 

MS r#sD 

U C 

ir 

DS- Drumi 

SoBds 

1 r 

DL - Drum 

Liquids 

L- EPrTCIP 

Leachate 

WI- Wipe 

r 

X - 

F- 

Other 

Fish 

ctl 1 3 

~ 3 

DATE/REYISIONS: 

Spacial Instructions: 

Llonvilb laborato ry Use Only 

X QC s-1 i-o^ ,. Pu coo i : ^^. ^rh = -16 bdf 

C^^. 

Samples were/ Tamper Resis tant Seal was: 

t' ^t 1 I 

^J-1-Fo-5(„ (r 5 âa ZOd I -1 -gOb A 

ttdd ilk A1. 13. f^ BL^ O^. ^^. ^Y. Ce. 

oOuter 

1)Sh Delverè/tlor 

1) Present op 

--c' 

Airbill # 

/Uv-r't 

3. TN (i u^^r S^ S^LC: C(. fl. ItrOÎ^Qt ^y; s _ ^ 2)ckage on Outer 

}-.1 

YY" fJ^^L.I`X_ D _ (JC^X 0 W Package Yn or N 

4. Irld3N 1 -CAM104 0 b21* N OIrZSX 010C z) Ambientor3) hYt 

Present Sample 

3) Received in or N 

O Pc0 Oj1R0 & RQ 

v' 

S. Condition C or N 4) Unbroken on 

4) Samples 

6. 

Sample C) or N 

Property Pr ed COC Record Present 

Relinquished Received Relinquished Received epancim Between N 

DIM Time 4Doe* me S^ 

Upon Samp^ /^ Rec't 

by bybPlea Label9 and 5) lding TI Within 

COC Record? Y or (/N^) 

lJ or N 

EEQ 

r P rI t ^/f\t At3 -T' NOTES:.vgybing TI Cooler 

riar N Temp. l 3 -C 

RE ITT t^ 3 3a

M-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-62 Page 1 of 1 

Collector Company Con tact Telephone No. Proj ec t Coordinator 


Proj ec t Designation Sampling Loca tion SAF No. 

200-PW-2200-PW-4 OU - Borehole Soil Sampling 216-A-37 (C4106); (12.5'-15 1 F03-006 

Ice Chest No. C5k L / OS Feld Logbook No. COA Method of Shipment 

/C V MF-N-3361 117504ES10 Fede ra l Express 

Shipped To Of(site Property No. 

POSSIBLE SAMPLE HA7ARD&REMAMO 



Preserva tio n 


No. of Contsiner(s) 

Volume 

Sample No. Matrix • Sample Date Sample Tim 

816W79 SOIL Sj G3 

2-2-0 

Cool 4C Caw 4C - Cod 4C Hooe Hox 

aG aG aG aG 

I I I l I 

120mL 60.1, 120.1. 60.1. 60ml, 

novaol- oad Grme- Seehm(0 Tmium -ro 

H-71% ea 

353.2 413.1 Spaitl 

Wmwo. 

IN OF POSSESSION Sign/Print Names SPECIAL INSTRUCTIONS 

Relinquished B ved F Datdruro (9fr Received /Stared N Date/vitae 

2C-'1= Ij 3928. 4 ZSv3 16 5`S 

Relioq" By/RemovWF DaWrune 


Air Quality q 

Bill of Lading/Air Bill No. CS E--Z05 PC` 

a\J 

` •_ ....^_ _ .,t.. __ 1" rSD 0 nC" r The laboratory is to 

repo rt both kerosene and diesel range canpmmds than WIPH-D analysis. 

S 0s //On ll^r 

;160 Received By/Stomd N WWI`me (}I TQi .,,, e^-: a990 Tml Sr LUnop "c Thorium (lLr--^ 

elioquis6ed By/R Fmm Detdl°tme eceived By/Sto red DaWfime 

a,.. r,..__...._ fine- 

45 Days 

t//tL of o.oa 

sic ncF o r= c Er m-a u, 

Ref By ved From î— Reai In Dat^1p10 

LCII 33 0 17 - s'J-63 p 

Relinquished By/Rnmved F ro m DawTime ReceivedB d In Dm rr;n.- 

Relinquished By/Remaved From 

DatNrime Received By/Stored in Date rime 

Persut trel not availabie to 

torn relinquish samPies the 3728 

Ref # -LP—on 

LABORATORY Received By Title Daterrime 

SECTION 

FINAL SAMPLE Disposal Method Disposed By Date fine 

DISPOSITION 

BHI-EE-011 (0310112002) 

Matrix' 

s Sal 

6a. 

so saa 

sSkdr 

w-w..., 

A-Aa 

DS-Dmu Shc6 

t 

w1- 

^L* a 

v-v.auaw. 

x-aee

C 

F11-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST n3-006-63 J PW i of 1 

collector - Company Contact Telephone No. Project Coordinator 

Johansen/Pope/PSster LC Hulstmm 373-3928 TRENT, Sl 

Project Designation Sampling Location - SAF No. 

200-PW-2/20D-PW-4 OU- Borehole Soil Sampling 216-A-37(C4106);(17.5-201 F03-006 

ke Chest No.erg C, ^! Fie ld Logbook No. COA Method of Shipment 

Jjrb HNF-N-3361 117504ES10 Federal Express 

Skipped To 

fzat 

POSSIBLE SAMPLE HAZARDS%EMARKS 


p 

Offsite P ro perty No. 

Preservation 



Volume 

"J ZZ 

cod 4C Cod IC Cod IC Nom 

aG aG aG aG a 

1 1 1 I I 


Air Quality q 

Bill of Lading/Air Bill No. Sam 03f G 

14--/ 

12DmL 60,111. 120ml. Watt, 60ML 

amdum No7M03 . Oil&()m - Sx:w( I)m nkwm -50 

Iln-7196 353.2 11 3.1 SPUW 

SAMPLE ANALYSIS f al 

a ^^ 

Sample No. Matrix • Sample Date Samp le Time 

BI 6W80 SOIL ZK G3 c c, }^ 

45 Days 

IN OF POSSESSION Si n/Print Names SPECIAL INSTRUCTIONS I/,1 Matrix • 

Re lingirished ved From ime Received By/Stoted IInn DatNfime 

•• 

••The labwatmy is to 

j°c^ /A g/ 2 $ If Z$0*3 

reWn bah kaoune and diesd Hoge compds 

compounds from WTPR-D analysm. 

s-sm 

r 

__ _ 

rb ys 

soar 

d6man^ 

m< 

In 0t3 

2 

{/ 

/C, 0 

A24 Nick W* kl Onmmn-237 n / 

W.W. 

BiA^z$ S 0 3 1l00Rb 

1 

(>^r(^ 

tJ 

v/ / 6-6u 

lmgdshW BylRmoo Date rime 1100 Receved By/Staed in DaWfim 

5J 6 s 1 0'S 1= E 6> oL-o L^^ 

Relimq By/Ramved am 

Rei ff inquis6ed B /Removed From Daterime 

y R=ived osed in 

Date/T 1111e 

p 

êrtwe 

Rdioq=bed ByM; ved Ftan DmeT= Received By/Sorted In Dawl ime 

Pe rsonnel not available to 


LABORATORY Received By Till - Doerr me 

SECTION 

FINAL SAMPLE Ditpoaal Method Disposed By Daterrime 

DISPOSITION 

BHI-EE-011 (03/0112002) 

- 

w-mp, 

L-Lww 

v-vspse=• 

x-aae

F14-Central Plateau P roject CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-64 Pas` I 

1 of t 



Johansen/PoWNster LC Hulstnom 373-3928 TRENT, SJ 

Proj ec t Designation Sampling Location SAF No. 

200-PW-2200-PW-4 OU - Bo rehole Soil Sampling 216-A-37 (C4106); (27.5-30) F01-W6 

Ice Chest No.p // `/ 

Uk 

^^--//^^ ^ (, f O 3b 


HNF-N-3361 

Shipped To 6-, ,4e d4 Offaite Property No. /) ?, O 

^^J u 




Preservation 



Volume 


COA 

117504ESIO 

Cod 4C COW 4C Cod4C Noce Nom 

aG aG aG aG 

I I I l t 

120m1, 60m l, 120mL 60m l, f 60mL 

anomium NO2/NO3- Oil&Geade- Sok.(1) Tdwm-H3 

ilea-7196 3532 413.1 Sped) 

P 

Air Quality q 

45 Days 


Federal Express ^- 

v 

Bill of Lading/Air Bill No. ^^^ Q ^^ J 

B16W81 SOIL T T T luu- 

CHAIN OF POSSESSION Sign/Print Names SPECIAL INSTRUCTIONS /J ^2 d ) Matrix 

Dattr doe ved By/Stowed In ^^L a 

-- 0.a 'a The labomlory is to ¢ 

mpon both kmosene and diesel range compounds from WfPH-D analysis. 

suya^d 

V 

so-sda 

Ref wished 8/Removed Fmm woe 1TdD— Received B toned ID terrime f Li 

sl-Nddo 

1 1J^..W-61 Nem^mi m-711 

1 

.'^ , 

1 , 2^ 

I 

LZ. .^ ^` /^/ Obn. 

A-M, 

Relin4uishw d ved From errme Received By/Stomd In Dam(Fauc 

!/Qf 

Ds-o—sdm 

3 / GO c5c O 3 DVDnm I+qutls 

ReluxuiabcdB ved Fmm fhtNfime Received By/Stoned In ^cTimC 

1 (I o 

Re ui B grooved Fmm Datcrrime _3 

Recei 

Q ^ 

y / t ti 

^. 

DatcTime 

- - d3 d 



Relinquished By/Removed Flom D+dwTime Received By In Date/rime 

Ref pt.a,Ôn — —LL—h2 

5-7 

LABORATORY Received By Title Datefrime 

SECTION 

FINAL SAMPLE Disposal Method Disposed By Dmertmte 

DISPOSITION 

BHI-EE-011 (03/01/2002) 

rÎ 

' I 

f^ 

6P 

w.wae 

L^ 

v-vetdam 

x-am

FH-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-65 J PaV 1 Of I 


Johansen/PopdP6ster LC Hulsrrom 373-3928 TRENT', SJ 

P roject Designation Sampling Loca tion SAF No. 

200-PW-2200-PW4 OU - Borehole Soil Sampling 216-A-37 (C4106); (37.5'-40') F03-M 


Air Quality q 

45 Days 

Ice Chest No. 

^ L Q 

D S / 

Y 


HNF-N-3361 

COA 

117504IO ES 



.^ 

Shipped To fz

FR-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-66 pass 1 of 1 

Collector 

Johnnsen/PopelPfister 


200-PW-2200-PW-4 OU - B orehole Soil Sampling 

Ice Chest No. ^.--^ C 4 

Shipped To 

O 

n 







216-A-37 (C4106); (47.5'-501 


HNF-N-3361 

Offalte Property No. 

Preserva tion 

Arc 

^ f 



Volume 

Sample No. Matrix • Sample Date Smnplc Time 

816W83 SOIL 

COA 

117504ESIO 

5 0 Z Z O 


TRENT, SJ 

SAF No. 

F03-006 


Federal Expre ss 

Cad CC Cad iC I Cad K Now I Now 

aG aG aG aG 

i 1 1 ) 

120ML 60ml. 120ML fz 

ammium 

Hex-7196 

N07JNO3- 

353.2 

00 A Gnus- 

413.1 

S. itsm(1)ia 

Sped 

r om 

m 

Prim Code sN 

Air Quality q 

Bill of Lading/Air Bill No. s ^-^- o 

Tdaum - H3 

t I 

CHAIN OF POSSESSION Sign/Print Names SPECIAL INSTRUCTIONS 6( 66 /f 

v ^BY/Stortd N - r^^ 

p Da Reoerved 

e mshad BY/Remdkvd Fsom 

klh 

Dawr 

T• 

i Wrr Received y/S 

tiv^ 1 

In D e/F e 1 k'^3 

7z 

4 • bf-- . 0 3 

iin9wshed B 

3 z 

Fmm 

$ 1 0-) 

ime 

1 1 00 

Received By/Stored 

g 

Delefrime 0 

S 1 ^ I oa 

Relinquished ByAtemo F Datr/fime 

'ved Byrst N DatHrime 

(rM1-t,l, 1 0 ^j 1100 

Fe e: 

Rel" d By ved From 

lioqumbed By/Rmouved From 

s 

DetJl'ime 

Dalefrime 

ReceivW 

Received By/St 

d ^^ 

d3 

Date/rime 

n^^/9^ 

report both kerosene and diesel mge compounds from WIPH-D analys is. 

( I) 

L7^Nirk,16 

- van 1um - o lsotoptc um um- 

'N min mm 7 ' L^r %y 

i//`L /`y 

f / ( 


Ref r 

uiishh sa mples from the 3728 - 

F-EJ-.on _^/1`/ 

•• The labo ra to 

ry 

LABORATORY Received By Ti tle DatNrime 

SECTION 

FINAL SAMPLE Disposal Method Disposed By DmNfime 

DISPOSITION 

BHI-EE-011 (03/01/2002) 


u to 

45 Da 

Matrix 

so-sdu 

sl-arose 

W-W. 

A-M 

7-Tios 

wT. 

L-LquA 

v-vâ;,o 

xor.

F11-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-73 Pw 1 of I 

Collector 


Project Deaignatio s 

200-PW.2/200-PWA OU - Borehole Soil Sampling 

Ice Chest No. ` /' 

lzC Cl 

1^ lO 0J L 

Shipped To - 

POSSIBLE SAMPLE 

Special handling and/or Storage 

-1* -4 



LC Huistrom 373-3928 

Sampling location 

216-A-37 (C4106); (17.5'-20') 


HNF-N-3361 

Offsite P ro perty No. 

Preservation 



Volume 

Sample No. Matrix • Samp le Date Samp le Time 

COA 

117504ESIO 

) C 2 0 Z Z 0 

fT 3 


TRENT, SJ Price Code 8N Data Turnaround 

SAF No. 

F03-W6 

cod.0 cow .c Cma aC Nom Noes 

aG aG aG aG a 

I I I I 

120osL 60n. 120nd, 60,uL 60mL 

B18W90 SOIL 0 3 S' ca fi 

Air Quality q 


Fede ra l Express^- 


Chromium 

Ba- 71 96 

NOV1107- 

353.2 

00A Grose 

41 3.1 - 

See 

n(1)in w 

spew 

7dfime-In 

l y 

CHAIN OF POSSESSION Sigo/Print Names SPECIAL INSTRUCTIONS j - 

ensoved F 

dfimeIJW 1V Received By/Staed In Date/Tune 

report both kerosene and diesel range compo 

- 

ds from o R IPH-D analysis. 


Rel' wished By/Ranoved Fro Date runs 

fZ,v - 1 0- 37zr J / o 3 aJ eO 

Relutquished By(R 

1 

J^1 

m DaWfime 

O 7 JIOO 

Bynt ved From 

D3 ii 

^—P R 3^ZSf ^/ Z$ 0316 VS 

R ec eived By/Stored In 

Dndrmc 

cS a/ (C" ,S 1o3 7/oU 

Received By/Sim 

r' G e^ 

Datefrime 

Rece ved N DmHI'ime 

o, 0 F - 

Relinquished By/Removed From Dstdfime Received By/" In Detelrime 

elingvid" By/Rm eoved From 

DaterF me 

ived By/Stored In DawTime 

LABORATORY 

SECTION 

1941 ti.•v.^. »t ^f^t `llli ite) 


relinquîsh/,.1s- amples from the 37,2,88 

Ref p a , - On l^/yL 

Received By Tide Date(fitoe 

FINAL SAMPLE Disposal Method Disposed By DalNrime 

DISPOSITION 

BHI-EE-0ii (0310112002) 

on 

45 Days 

Matrix' 

so-swu 

so-stwc 

W-W., 

D-0a 

A-" 

DYDrvmSdiN 

DL Dmm W,& 

wrwy 

L-umm 

x-V v-v`stlY1O"

FH-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-M-74 ^ %a - 

Collector Company Contact T el ephone No. Project Coordinator 

Juhanseo/PopHPfster LC Hulstrom 373-3926 TRENT, SJ 

Price Code 

Project Designation Sampling Loca tion SAF Na Air Quality q 

200-PW-2/200-PW-4 OU - Borehole Soil Sampling 216-A-37 (C4106); (0.5 j F03-D06 

lee Cheat No.^y^ Field Logbook No. COA Method of Shipment 

G R C— t ` W HNF-N-3361 I17504ESIO Federal Express 

Shipped To tOsi o3 (Ztht Offsite P ro perty No.n O 

^j-CJ 


Handling and/or Storage 


Preservation 



B16W91 SOIL 

Cod 4C Cadk 

aG JIG 

No. of Container(s) I I 

60m1. 250mL 

Volume 

hakidw- Chl 

teat He4idde,- 

FPA815 1 

Bill of Lading/Air Bill Nos 

gel Data Turnaround 

45 Days 

N OF POSSESSION Sign/Print Names SPECIAL INSTRUCTIONS Matrix 

tin wish enwvedF m DaWFime Received By/Stared N Datdtime 

pEF Pr 372$ ^zo3 /6zfS 

RIi wished BylaemovedP 

1` ,; 

Relinquished By/Reomved mm 

Ukq B emoved From 

Da.M. 

Dmdtime 

Received By/Stared In 

W.W. 

3 7n 5103 1100 non 

S ! 

Dattrrim Received By/St In Dmdrhnc 

03 mdo Gc' 

Datdfura Received N 

DaWrime 

/^ } Perso °u h' emgl ^lOm r^.132 xoua 

Relinquidied BylRemoved F rom DmeRirac Received By I In ^^tl1C 

ce\ 

p / 

ReiN 

li/oo 

etinquished Byfflmwved From I atdruue Recei ved By/Staed In DmdCime 

LABORATORY Received By Title Date?mw 

SECTION 

FINAL SAMPLE 

DISPOSITION 

DispoW Method 

Disposed By 

Datraime 

SHI-EE-011 (03101/2002) 

10 

s sm.. 

soww 

srswsa: 

Ans oa.ssdw 

m..w,^ wm r^ wt-w" 

L"Al



IENT: 11ÎU 1-ât,ô /^ 

:hale Order/Project:DATE: S a 

7^SOW#1Re)ease#: F63 - 00(p 

wratory SDG #: 

03Cst_3aq 

1T& ALL ENTRIES MARKED "NO" MUST 13E EXPLAINED IN THE COMMENT SECTION 

1, Custody seals on coolers or shipping Yes ONO D A 


0 see Comment 

2. Outside of coolers or shipping containers are yes ONO O N/A O see Comment N 


3. Airbill g recorded? 


other client speci fic: historical data, 




ycs ONO O N/A O see Comment N 

Î 

AA 

y(t es ONO O N/A O see Commem N 

S. Sample containe rs area intact? yes O No O NIA O see Comment N 

6. Custody seals on sample containers intact, es ONO O N/A D see Comment N 


(((( 

7. All samples on coc received? 'Yes ONO O NIA D see Comment N 

8. All sample label information matches coc? y+ • cs ONO O N/A • b see Comment N 

9. Laboratory QC samples designated on coc? q Yes ONO t3N/A O see Comment N 

(QC stickers placed on bo ttles?) 

10. Shipment meets LvLI Sample Acceptance yes ONO q N/A O see Comme nt N 

Policy? " (identify all bottles not within 

policy. See reverse side for poli cy) 

11. Where applicable, bar code labels are O Yes ONO ^,N/A D see Comment N 


12. coc signed and dated? 9v i u O No O N/A O see Comment N 

13. coc will be faxed or emailed to client? LQ^^ Yes • ONO O N/A O see Comme nt N 

14. Project Manager/Client conta cted 


Cooler N / temp (eC) and Comments : 

EeG q, (a -05 4^ / 1 .3 

Laboratory Sample Custodial 


O Yes q No /A O see Comment N


INORGANIC ANALYTICAL DATA PACKAGE FOR 


NI.`^^2^ 

252 ,a8\ 

^ 

,//^,y '003 

r ^ J 

L LLO` 

DATE RECEIVED: 05/02/03 LVL LOT # :0305L329 - 

CLIENT ID /ANALYSIS LVL # MTX PREP # COLLECTION EXTR/PREP ANALYSIS 

B16W79 

SILVER, TOTAL 001 S 03L0284 04/28/03 05/22/03 05/31/03 

SILVER, TOTAL 001 REP S 03LO284 04/28/03 05/22/03 05/31/03 

SILVER, TOTAL 001 MS S 03LO284 04/28/03 05/22/03 05/31/03 

ARSENIC, TOTAL 001 S 03LO284 04/28/03 05/22/03 05/31/03 

ARSENIC, TOTAL 001 REP S 03L0284 04/28/03 05/22/03 05/31/03 

ARSENIC, TOTAL 001 MS S 03LO284 04/28/03 05/22/03 05/31/03 

BORON, TOTAL 001 S 03LO284 04/28/03 05/22/03 05/31/03 

BORON, TOTAL 001 REP S 03LO284 04/28/03 05/22/03 05/31/03 

BORON, TOTAL 001 MS S 03L0284 04/28/03 05/22/03 05/31/03 

BARIUM, TOTAL 001 S 03LO284 04/28/03 05/22/03 05/31/03 

BARIUM, TOTAL 001 REP S 03LO284 04/28/03 05/22/03 05/31/03 

BARIUM, TOTAL 001 MS S 03L0284 04/28/03 05/22/03 05/31/03 

BERYLLIUM, TOTAL 001 S 03L0284 04/28/03 05/22/03 05/31/03 

BERYLLIUM, TOTAL 001 REP S 03LO284 04/28/03 05/22/03 05/31/03 

BERYLLIUM, TOTAL 001 MS S 03LO284 04/28/03 05/22/03 05/31/03 

BISMUTH, TOTAL 001 S 03LO284 04/28/03 05/22/03 05/31/03 

BISMUTH, TOTAL REP 001 REP S 03L0284 04/28/03 05/22/03 05/31/03 

BISMUTH, TOTAL SPIKE 001 MS S 03L0284 04/28/03 05/22/03 05/31/03 

CADMIUM, TOTAL 001 S 03LO284 04/28/03 05/22/03 05/31/03 

CADMIUM, TOTAL 001 REP S 03LO284 04/28/03 05/22/03 05/31/03 

CADMIUM, TOTAL 001 MS S 03L0284 04/28/03 05/22/03 05/31/03 

CHROMIUM, TOTAL 001 S 03L0284 04/28/03 05/22/03 05/31/03 

CHROMIUM, TOTAL 001 REP S 03LO284 04/28/03 05/22/03 05/31/03 

CHROMIUM, TOTAL 001 MS S 03LO284 04/28/03 05/22/03 05/31/03 

COPPER, TOTAL 001 S 03L0284 04/28/03 05/22/03 05/31/03 

COPPER, TOTAL 001 REP S 03LO284 04/28/03 05/22/03 05/31/03 

COPPER, TOTAL 001 MS S 03LO284 04/28/03 05/22/03 05/31/03 

MERCURY, TOTAL 001 S 03C0115 04/28/03 05/16/03 05/19/03 

MERCURY, TOTAL 001 REP S 03CO115 04/28/03 05/16/03 05/19/03 

MERCURY, TOTAL 001 MS S 03CO115 04/28/03 05/16/03 05/19/03 

NICKEL, TOTAL 001 S 03L0284 04/28/03 05/22/03 05/31/03 

NICKEL, TOTAL 001 REP S 03L0284 04/28/03 05/22/03 05/31/03 

NICKEL, TOTAL 001 MS S 03LO284 04/28/03 05/22/03 05/31/03 

LEAD, TOTAL 001 S 03L0284 04/28/03 05/22/03 05/31/03 

LEAD, TOTAL 001 REP S 03LO284 04/28/03 05/22/03 05/31/03 

f I °^. A7 

I 

^






LEAD, TOTAL 001 MS S 03L0284 04/28/03 .05/22/03 05/31/03 

ANTIMONY, TOTAL 001 S 03L0284 04/28/03 05/22/03 05/31/03 

ANTIMONY, TOTAL 001 REP S 03L0284 04/28/03 05/22/03 05/31/03 

ANTIMONY, TOTAL 001 MS S 03L0284 04/28/03 05/22/03 05/31/03 

SELENIUM, TOTAL 001 S 03L0284 04/28/03 05/22/03 05/31/03 

SELENIUM, TOTAL 001 REP S 03L0284 04/28/03 05/22/03 05/31/03 

SELENIUM, TOTAL 001 MS S 03L0284 04/28/03 05/22/03 05/31/03 

B16W80 


ARSENIC,. TOTAL 002 S 03L0284 04/28/03 05/22/03 05/31/03 

BORON, TOTAL 002 S 03L0284 04/28/03 05/22/03 05/31/03 




CADMIUM, TOTAL 002 S 03L0284 04/28/03 05/22/03 05/31/03 




NICKEL, TOTAL 002 S 03LO284 04/28/03 05/22/03 05/31/03 

LEAD, TOTAL 002 S 031,02B4 04/28/03 05/22/03 05/31/03 


SELENIUM, TOTAL 002 S 031,02B4 04/28/03 05/22/03 05/31/03 

B16WB1 


ARSENIC, TOTAL 003 S 03L0284 04/29/03 05/22/03 05/31/03 


BARIUM, TOTAL 003 S 03L0284 04/29/03 05/22/03 05/31/03 

BERYLLIUM, TOTAL 003. S 03L0284 04/29/03 05/22/03 05/31/03 

BISMUTH, TOTAL 003 S 03L0284 04/29/03 05/22/03 05/31/03 






2




DATE RECEIVED: 05/02/03 LVL LOT 4 :0305L329 


LEAD, TOTAL 003 S 03LO284 04/29/03 05/22/03 05/31/03 

ANTIMONY, TOTAL 003 S 03LO284 04/29/03 05/22/03 05/31/03 

SELENIUM, TOTAL 003 S 031,02B4 04/29/03 05/22/03 05/31/03 

B16W82 

SILVER, TOTAL 004 S 03LO284 04/29/03 05/22/03 05/31/03 




BERYLLIUM, TOTAL 004 S 03LO284 04/29/03 05/22/03 05/31/03 



CHROMIUM, TOTAL 004 S 03LO284 04/29/03 05/22/03 05/31/03 

COPPER, TOTAL 004 S 03LO284 04/29/03 05/22/03 05/31/03 

MERCURY, TOTAL 004 S 03CO115 04/29/03 05/16/03 05/19/03 


LEAD, TOTAL 004 S 03LO284 04/29/03 05/22/03 05/31/03 


SELENIUM, TOTAL 004 S 03LO284 04/29/03 05/22/03 05/31/03 

B16W83 





BERYLLIUM, TOTAL 005 S 03LO284 04/29/03 05/22/03 05/31/03 


CADMIUM, TOTAL 005 S 03LO284 04/29/03 05/22/03 05/31/03 

CHROMIUM, TOTAL 005 S 03LO284 04/29/03 05/22/03 05/31/03 

COPPER, TOTAL 005 S 03LO284 04/29/03 05/22/03 05/31/03 

MERCURY, TOTAL 005 S 03CO115 04/29/03 05/16/03 05/19/03 


LEAD, TOTAL 005 S 03LO284 04/29/03 05/22/03 05/31/03 


SELENIUM, TOTAL 005 S 03LO284 04/29/03 05/22/03 05/31/03 

B16W90 


3






ARSENIC, TOTAL 006 S 03L0284 04/28/03 05/22/03 05/31/03 

BORON, TOTAL 006 S 03L0284 04/28/03 05/22/03 05/31/03 

BARIUM, TOTAL 006 S 03L0284 04/28/03 05/22/03 05/31/03 


BISMUTH, TOTAL 006 S 03L0284 04/28/03 05/22/03 05/31/03 






LEAD, TOTAL 006 S 03L0284 04/28/03 05/22/03 05/31/03 


SELENIUM, TOTAL 006 S 03L0284 04/28/03 05/22/03 05/31/03 

LAB QC: 

SILVER LABORATORY LC1 BS S 03L0284 N/A 05/22/03 05/30/03 

SILVER, TOTAL MB1 S 03L0284 N/A 05/22/03 05/30/03 

ARSENIC LABORATORY LC1 BS S 03L0284 N/A 05/22/03 05/30/03 

ARSENIC, TOTAL MB1 S 03L0284 N/A 05/22/03 05/30/03 

BORON LABORATORY LC1 BS S 03L0284 N/A 05/22/03 05/30/03 

BORON, TOTAL MB1 S 03L0284 N/A 05/22/03 05/30/03 

BARIUM LABORATORY LC1 BS S 03L0284 N/A 05/22/03 05/30/03 

BARIUM, TOTAL MB1 S 03L0284 N/A 05/22/03 05/30/03 

BERYLLIUM LABORATORY LC1 BS S 03L0284 N/A 05/22/03 05/30/03 

BERYLLIUM, TOTAL MB1 S 03L0284 N/A 05/22/03 05/30/03 

BISMUTH, LCS LC1 BS S 03L0284 N/A 05/22/03 05/30/03 

BISMUTH, TOTAL MB1, S 03L0284 N/A 05/22/03 05/30/03 

CADMIUM LABORATORY LC1 BS S 03L0284 N/A 05/22/03 05/30/03 

CADMIUM, TOTAL MB1 S 03L0284 N/A 05/22/03 05/30/03 

CHROMIUM LABORATORY LC1 BS S 03L0284 N/A 05/22/03 05/30/03 

CHROMIUM, TOTAL MB1 S 03L0284 N/A 05/22/03 05/30/03 

COPPER LABORATORY LC1 BS S 03L0284 N/A 05/22/03. 05/30/03 

COPPER, TOTAL MB1 S 03L0284 N/A 05/22/03 05/30/03 

MERCURY LABORATORY LC1 BS S 03C0115 N/A 05/16/03 05/19/03 

MERCURY, TOTAL MB1 S 03C0115 N/A 05/16/03 05/19/03 

NICKEL LABORATORY LC1 BS S 03L0284 N/A 05/22/03 05/30/03 

NICKEL, TOTAL MB1 S 03L0284 N/A 05/22/03 05/30/03 

2






LEAD LABORATORY LC1 BS S 03L0284 N/A 05/22/03 05/30/03 

LEAD, TOTAL MB1 S 03L0284 N/A 05/22/03 05/30/03 

ANTIMONY LABORATORY LC1 BS S 03L0284 N/A 05/22/03 05/30/03 

ANTIMONY, TOTAL MB1 S 03L0284 N/A 05/22/03 05/30/03 

SELENIUM LABORATORY LC1 BS S 03L0284 N/A 05/22/03 05/30/03 

SELENIUM, TOTAL MB1 S 03L0284 N/A 05/22/03 05/30/03 

E

Client: TNU-HANFORD F03-006 W.O.#: 11343-606-001-9999-00 

LVL#: 0305L329 Date Received: 05-02-03 

SDG/SAF#: H2194/F03-006 

METALS CASE NARRATIVE 

This narrative covers the analyses of 6 soil samples. 

2. The samples were prepared and analyzed in accordance with methods checked on the 

attached glossary. 

3. All analyses were performed within the required holding times. 

4. All results presented in this report are derived from samples that met LvLI's sample 

acceptance policy. 

5. All Initial and Continuing Calibration Verifications (ICV/CCVs) were within the 90-110% 

control limits. 

6. All Initial and Continuing Calibration Blanks (ICB/CCBs) were within control limits (less 

than the PQL). 

7. All preparation/method blanks (MB) were within method criteria {less than the Practical 

Quantitation Limit (3X the IDL), MB value less than 5% of the RCRA limit, or samples 

greater than 20X MB value). Refer to the Inorganics Method Blank Data Summary. 

8. All ICP Interference Check Standards were within control limits. 

9. All laboratory control samples (LCS) were within the 80-120% control limits. Refer to the 

Inorganics Laboratory Control Standards Report. 

10. The matrix spike (MS) recoveries for 2 analytes were outside the 75-125% control limits. 

Refer to the Inorganics Accuracy Report. 

11. For analytes where the ICP MS is out-of-control, a post-digestion MS (PDS) and serial 

dilution are performed. A serial dilution is performed for Mercury. A PDS was prepared at 

meaningful concentration level for the following analytes: 

The results presented in this report relate only to the analytical testing and conditions of the samples at receipt and during storage. All pages of this 

report are integral parts of the analytical data. Therefore, this report should only be reproduced in its entirety of 8 pages. 


V 

FPS PDS 

Sample ID Element Concentration (ppbl % Recovery 

B16W79 Antimony 100 102.1 

Barium 200 37.7 

12. The duplicate analyses for 3 analytes were outside the 20% Relative Percent Difference 

(RPD) control limits. Refer to the Inorganics Precision Report. 

13. For the purposes of this report, the data has been reported to the Instrument Detection Limit 

(IDL). Values between the IDL and the Practical Quantitation Limit (PQL) are acquired in 

a region of less-certain quantification. 


technically and for completeness, other than the conditions detailed above. Release of the 

data contained in this hard-copy data package has been authorized by the Laboratory 

Manager or a designee, as verified by the following signature. 

C,----' 

Iain Daniels 



ginb/m05-329 

0(U -0C'03 

Date

METALS METHOD GLOSSARY 

The following methods are used as reference for the digestion and analysis of samples contained within this 

Lot#: 013 pSL 3 ?A 

Leaching Procedure: _1310 _1311 _1312 _Other: 

CLP Metals _ Digestion and _ Analysis Methods: _ILM03 .0_IJ M04.0 

Metals Digestion Methods: _3005A _3010A _3015 _3020A _3050B _3051 _200.7 _SS17 

Other: 

Metals Analysis Methods 

SW846 EPA 

EPA 

STD MTD OSWR USATHAMA 

Aluminum OIOB _200.7 99 

Antimony 010B _7041' _200.7 _204.2 99 

Arsenic ^01013 _7060A _200.7 _206.2 _3113B _99 

Barium / 09101 _200.7 _99 

Beryllium 3_4(1101 _200.7 99 

Bismuth ,/ 010B' _200.7' _1620 _99 

Boron 0101 _200.7 _99 

Cadmium 

Calcium 

Chromium 

_60101 7131A' _200.7 _213.2 

_¢b10B _200.7 

_360101 _7191' _200.7 _218.2 

_99 

_99 

_SS17 

Cobalt 010B _200.7 99 

Copper 

Iron 

_6010B _7211' _200.7 _220.2 

01013 _200.7 

99 

99 

Lead ÔlOB _7421' _200.7 _239.2 _3113B 99 

Lithium _6010B _7430' _200.7 _1620 99 

Magnesium 6010B _200.7 99 

Manganese 6010B / _200.7 99 

Mercury_7470A 3 7471A 1 _245.1 '_245.5 199 

Molybdenum _PUB _200.7 99 

Nickel _360101 _200.7 _99 

Potassium 6010B _7610' _200.7 _258.1' _99 

Rare Earths 6 OB' _200.7' _1620 99 

Selenium _ O10B _7740' _200.7 _270.2 _3113B _99 

Silicon _6010B' _200.7 _1620 99 

Silica10B _Si9 

_200.7 _1620 _99 

Silver 6010B _7761' _200.7 _272.2 99 

Sodium _6010B _7770' _200.7 _273.1' 99 

Strontium _6010B _200.7 _99 

Thallium 6010B _7841' _200.7 _279.2_200.9 _99 

Tin _6010B _200.7 99 

Titanium 6010B _200.7 99 

Uranium 6010B' _200.7' _1620 99 

Vanadium 6010B _200.7 99 

Zinc _6010B _200.7 _99 

Zirconium _6010B' _200.7' _1620 _99 

Other: Method: 4WI.03/M- I 8

METHOD REFERENCES AND DATA QUALIFIERS 

U = Indicates that the parameter was not detected at or above the reported limit. The 

associated numerical value is the sample detection limit. 

* = Indicates that the original sample result is greater than 4x the spike amount added. 

MB = Method or Preparation Blank. 

MS Matrix , Spike. 

MSD = Matrix Spike Duplicate. 

REP = Sample Replicate 

LCS = Laboratory Control Sample. 

NC = Not calculated. 

Not included in the method element list. 

2. Modified Hg: Hg and Hg2 require less total volume of digestate due to the 

autosampler analysis. Sample volumes and reagents for mercury determinations 

in water and soil have been proportionately scaled down to adapt to this semiautomated 

technique. The sample volume used for water analysis is 33 mL. For 

soils, approximately 0.3 grams of sample is taken to a final volume of 50 mL 

(including all reagents). 

3. Flame AA. 

4. Graphite Furnace AA. 

L•WI-033/N-04/98 

NJ

CLIENT: TNUHANPORD FO3-006 H2194 

WORK ORDER: 11343-606-001-9999-00 

SAMPLE 

: ...... 

SITE ID ANALYTB 

.................... ....................... 

-001 B16W79 Silver, Total 

Arsenic, Total 

Boron, Total 

Barium, Total 

Beryllium, Total 

Bismuth, Total 

Cadmium, Total 

Chromium, Total 

Copper, Total 

Mercury, Total 

Nickel, Total 

Lead, Total 

Antimony, Total 

Selenium, Total 


INORGANICS DATA SUMMARY REPORT 06/04/03 

LVL LOT #: 030SL329 

REPORTING DILUTION 

RESULT 

........ 

UNITS 

...... 

LIMIT 

.......... 

FACTOR 

........ 

0.13 a MG/KG 

0.13 

1.0 

1.7 MG/KG 0.34 1.0 

0.51 MG/KG 0.20 1.0 

165 MG/KG 0.02 1.0 

0.31 MG/KG 0.01 1.0 

0.53 u MG/KG 0.53 1.0 

0.04 a MO/KG 0.04 1.0 

8.5 MG/KG 0.10 1.0 

14.6 MG/KG 0.06 1.0 

0.02 MG/KG 0.02 1.0 

11.0 MG/KG 0.14 1.0 

3.9 MG/KG 0.24 1.0 

0.23 u MG/KG 0.23 1.0 

0.44 a MG/KG 0.44 1.0 

10



CLIENT: TNDHANPORD F03-006 H2194 LVL LOT #: 0305L329 

WORK ORDER: 11343-606-001-9999-00 

.................... ....................... 

SAMPLE SITE ID ANALYTE RESULT 

....... 

........ 

UNITS 

...... 


LIMIT 

.......... 

FACTOR 

........ 

-002 B16WBD Silver, Total 0.12 u MG/KG 0.12 1.0 

Arsenic, Total 2.2 MG/KG 0.34 1.0 

Boron, Total 0.58 MG/KG 0.19 1.0 

Barium, Total 86.6 MG/KG 0.02 1.0 

Beryllium, Total 0.18 MG/KG 0.01 1.0 

Bismuth, Total 0.52 u MG/KG 0.52 1.0 

Cadmium, Total 0.04 u MG/KG 0.04 1.0 

Chromium, Total 6.1 MG/KG 0.10 1.0 

Copper, Total 13.3 MG/KG 0.06 1.0 

Mercury, Total 0.02 u MG/KG 0.02 1.0 

Nickel, Total 7.8 MG/KG 0.13 1.0 

Lead, Total 3.0 MG/KG 0.24 1.0 

Antimony, Total 0.23 u MG/KG 0.23 1.0 

Selenium, Total 0.43 u MG/KG 0.43 1.0 

11

CLIENT: TNUHANPORD F03-006 H2194 

WORK ORDER: 11343-606-001-9999-00 

SAMPLE SITE ID ANALYTE 

... .... .................... ............vv....... 



Boron, Total 

Barium, Total 





Copper, Total 


Nickel, Total 

Lead, Total 





LVL LOT #: 03051,329 


RESULT 

........ 

UNITS 

...... 

LIMIT 

.......... 

FACTOR 

........ 

0.12 u MG/KG 

0.12 

1.0 

2.2 MG/KG 0.32 1.0 

0.36 MG/KG 0.19 1.0 

76.2 MG/KG 0.02 1.0 

0.21 MG/KG 0.01 1.0 

0.50 u MG/KG 0.50 1.0 

0.04 u MG/KG 0.04 1.0 

7.1 MG/KG 0.1 1.0 

12.0 MG/KG 0.06 1.0 

0.02 u MG/KG 0.02 1.0 

7.8 MG/KO 0.13 1.0 

2.9 MG/KG 0.23 1.0 

0.22 u MG/KG 0.22 1.0 

0.41 u MG/KG 0.41 1.0 

12

CLIENT: TNUHANFORD F03-006 H2194 

WORK ORDER: 11343-606-001-9999-00 

SAMPLE 

....... 


.................... ....................... 



Boron, Total 

Barium, Total 


Biemuth, Total 



Copper, Total 


Nickel, Total 

Lead, Total 





LVL LOT #: 0305L329 


RESULT 

........ 

UNITS 

...... 

LIMIT 

.......... 

FACTOR 

........ 

0.12 a MG/KG 

0.12 

1.0 

1.9 MG/KG 0.34 1.0 

0.36 MG/KG 0.20 1.0 

78.5 MG/KG 0.02 1.0 

0.15 MG/KG 0.01 1.0 

0.52 a MG/KG 0.52 1.0 

0.04 a MG/KG 0.04 1.0 

4.6 MG/KG 0.10 1.0 

13.6 MO/KG 0.06 1.0 

0.02 u MG/KG 0.02 1.0 

6.6 MG/KG 0.13 1.0 

2.7 MG/KG 0.24 1.0 

0.23 u MG/KG 0.23 1.0 

0.43 u MG/KG 0.43 1.0 

13

CLIENT: TNUHANPORD P03-006 H2194 

WORK ORDER: 11343-606-001-9999-00 

SAMPLE 

....... 


.................... ................ 

-005 816WS3 Silver, Total 

Areanic, Total 

Boron, Total 

Barium, Total 





Copper, Total 


Nickel, Total 

Lead, Total 







RESULT 

........ 

UNITS 

...... 

LIMIT 

.......... 

FACTOR 

........ 

0.12 u MG/KG 

0.12 

1.0 

2.4 MG/KG 0.34 1.0 

0.50 MG/KG 0.19 1.0 

79.6 MG/KG 0.02 1.0 

0.14 MG/KG 0.01 1.0 

0.52 u MG/KG 0.52 1.0 

0.04 u MG/KG 0.04 1.0 

7.0 MG/KG 0.10 1.0 

14.5 MG/KG 0.06 1.0 

0.02 a MG/KG 0.02 1.0 

7.0 MG/KG 0.13 1.0 

2.5 MG/KG 0.24 1.0 

0.23 a MG/KG 0.23 1.0 

0.43 a MG/KG 0.43 1.0 

14

CLIENT: TNURANFORD P03-006 H2194 

WORK ORDER: 11343-606-001-9999-00 


-00 6vy B16W90 silver, Total 

Areenic, Total 

Boron, Total 

Barium, Total 





Copper, Total 


Nickel, Total 

Lead, Total 





LVL LOT P: 030SL329 


RESULT UNITS LIMIT FACTOR 

0.12 u MG/KG 0.12 ` ` 1.0 

1.9 MG/KG 0.34 1.0 

0.42 MG/KG 0.20' 1.0 

74.9 MG/KG 0.02 1.0 

0.17 MG/KG 0.01 1.0 

0.53 u MG/KG 0.53 1.0 

0.04 u MG/KG 0.04 1.0 

6.2 MG/KG 0.10 1.0 

12.6 MG/KG 0.06 1.0 

0.02 u MG/KG 0.02 _ 1.0 

7.6 MG/KG 0.13 1.0 

2.9 MG/KG 0.24 1.0 

0.23 a MG/KG 0.23 1.0 

0.43 u MG/KG 0.43 1.0 

15


WORK ORDER: 11343-606-001-9999-00 


....... .................... ....................... 

SLANKI 03LO284-MB1 Silver, Total 


INORGANICS METHOD BLANK DATA SUMMARY PAGE 06/04/03 


Boron, Total 

Barium, Total 





Copper, Total 

Nickel, Total 

Lead, Total 



BLANKI 03C0115-MBI Mercury, Total 

LVL LOT #: 030SM29 


RESULT 

........ 

UNITS 

...... 

LIMIT 

.......... 

FACTOR 

........ 

0.12 u MG/KG 

0.12 

1.0 

0.33 u MG/KG 0.33 1.0 

0.19 a MG/KG 0.19 1.0 

0.03 MG/KG 0.02 1.0 

0.02 MG/KG 0.01 1.0 

0.51 u MG/KG 0.51 1.0 

0.04 u MG/KG 0.04 1.0 

0.10 u MG/KG 0.10 1.0 

0.06 u MG/KG 0.06 1.0 

0.13 a MG/KG 0.13 1.0 

0.23 u MG/KG 0.23 1.0 

0.22 u MG/KG 0.22 1.0 

0.42 u MG/KG 0.42 1.0 

0.02 u MG/KG 0.02 1.0 

16


WORK ORDER: 11343-606-001-9999-00 

SAMPLE SITS ID ANALYTE 

....... .................... ...................... 



Boron, Total 

Barium, Total 





Copper, Total 


Nickel, Total 

Lead, Total 




INORGANICS ACCURACY RRPORT 06/04/03 

SPIKED INITIAL 

SAMPLE RESULT 

4.9 0. 13u 

192 1.7 

93.8 0.51 

299 165 

5.2 0.31 

479 0. 53u 

4.7 0.04u 

28.2 8.5 

39.3 14.6 

0.21 0.02 

59.5 11.0 

52.4 3.9 

30.3 0.23u 

181 0.44u 


SPIKED 

AMOUNT 4RECOV 

5.2 94.2 

209 91.2 

104 89.4 

209 64.1 

5.2 94.0 

522 91.7 

5.2 90.4 

20.9 94.3 

26.1 94.6 

0.17 116.9 

52.2 92.9 

52.2 92.9 

52.2 58.0 

209 86.6 

DILUTION 

PACTOR(SPK) 

1.0 

1.0 

1.0 

1.0 

1.0 

1.0 

1.0 

1.0 

1.0 

1.0 

1.0 

1.0 

1.0 

1.0 

17


INORGANICS PRECISION REPORT 06/04/03 

CLIENT: TNUHANPORD P03-006 H2194 LVL LOT #: 030SL329 

WORK ORDER: 11343-606-001-9999-00 

INITIAL DILUTION 

SAMPLE 

....... 

SITE ID 

.................... 

ANALYTE 

........vv........... 

RESULT 

........ 

REPLICATE RPD 

......... ....... 

FACTOR(REP) 

........... 

-OOIREP B16W79 

Silver, Total 

0.13u 0.13u NC 

1.0 

Arsenic, Total 1.7 2.2 25.6 1.0 

Boron, Total 0.51 0.44 14.6 1.0 

Barium, Total 165 100 48.4 1.0 

Beryllium, Total 0.31 0.31 0.67 1.0 

Bismuth, Total 0.53u 0.53u NC 1.0 

Cadmium, Total 0.04u 0.04u NC 1.0 

Chromium, Total 6.5 12.3 36.5 1.0 

Copper, Total 14.6 13.9 4.9 1.0 

Mercury, Total 0.02 0.02 0.00 1.0 

Nickel, Total 11.0 12.1 9.5 1.0 

Lead, Total 3.9 3.9 0.00 1.0 

Antimony, Total 0.23u 0.23u NC 1.0 

Selenium, Total 0.44u 0.44u NC 1.0 

is


WORT( ORDER: 11343-606-001-9999-00 


LCS1 03L0284-LCl Silver, LCS 


INORGANICS LABORATORY CONTROL STANDARDS REPORT 06/04/03 

Arsenic, LCS 

Boron, LCS 

Barium, LCS 

Beryllium, LCS 

Bismuth, LCS 

Cadmium, LCS 

Chromium, LCS 

Copper, LCS 

Nickel, LCS 

Lead, LCS 

Antimony, LCS 

selenium, LCS 

LCS1 03C0115-LCl Mercury, LCS 

SPIKED SPIKED 

LVL LOT M: 0305L329 

SAMPLE AMOUNT UNITS iRECOV 

49.1 50.0 MG/KG 98.2 

931 1000 MG/KG 93.1 

471 500 MG/KG 94.2 

505 500 MG/KG 100.9 

24.2 25.0 MG/KG 96.8 

491 500 MG/KG 98.2 

24.6 25.0 MG/KG 98.4 

50.6 50.0 MG/KG 101.2 

127 125 MG/KG 101.8 

200 200 MG/KG 99.9 

243 250 MG/KG 97.4 

291 300 MG/KG 97.0 

890 1000 MG/KG 89.0 

6.9 6.2 MG/KG 110.7 

19

Lionville Laborato ry Use Only Custody Transfer Record/Lab Work Request Page —A— Of 


^JL--^ 

^ • '^ r 

C'_ '7i 

Client =h L140nR[C-6 1=n,.-j-Cnf 9 R efrigerator# Z 

VL^ 

Est Find Prot Sampling Date. 

Project# 11?24ZI-Cn[Y e-ci^%- ISICIS F1O 

/NType Container 

Liquid 

Solid 

Project Cordactiphone A. 

Liquid 

Volume 

Solid 

Lionville Laborato ry Protect Manager (,'^n 

OC 

P reserva tives 

2vcc Del --c^ TAT 

r - It,- o] ANALYSES—^ 

Date Recd -[l -73 -7i Date Due `-te r — 7r^j(.,_ 

ORGANIC 

?m 

INORG 

m 

! 

REOUESTED O > 

Z 

m '... _ Z U 

MATRIX Mix 

CODES: 

Lab 

S - son 

Clbnt IDIDescrlPlbn Chosen (y) Matrix 

Collected Colletled 

SE - Sediment 

1 Lionville Laborato ry Use Only j 

,3 

,y 

so - said 

St- SIIMge 

w- O- ON water 

A- Air 

DS - Drum 

Soft 

DL- Dean 

MS MSD 

H 

3 

3 

H 

3 

Liquids 

L- EE 

Leachate 

WI- Wipe: 

X - Other 

F - Fish 

Spacial Instruc tions: 

DATEA7EYISIONS: io L nville Labo ra tory Use Only 

,J—`1 t\ FO^J'(^^(^ 5 ^dt p O e1 F}Jtl A^ !IS 3 8. Ds 6: ^^, 

/ 

amples were 

Hand Delivers 

Tamper Resislam was 

Outer 

Package(f or 

Cr, 

00 

^ C u. 

,- 1 

Av 

3. 1 rtr P ^ 

or 

S6 S P,J, ( ,'JLS LC:I03 Airbill , #-.r'y 4 ^_^ IAIN N tNtO TPH ObZWN O\ZS ^ .O&OC, 

ODI^ ^&R4 

or 1 3 

J2 

)Ambient 

2) orI 

3) 

2) Unbrok^nôn Outer 

Package( or N 

3) Present 6n Sample 

Y or N 

Received 

5. OPC^ 

Vood 

Condition r or N 4) Unbroken on 


D 

5 

4) Samples 

Property P/r^^ arved 

Sample L^ or N 

GOC Record P resent 

at by 

f' 

by 

e Time 


Date a, 

by by 

p 

;^,• Vin!! 

1^c TAT„ 

u + 

R C 11 

ThRe Discrepancies Between 

Samples Labels and 

CO Record?Y or. 

3 

L:J or N 

5) Received Whin 

Holding n 

rV or N 

Upon SampRect 

or N 

Cooler 

Temp. 

-C 

--TT—t ( 3

iVr 

F11-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-62 


Johansen/PopelPfister LC Hillstrom 373-3928 TRENT, SJ 

roject Designation Sampling Lo ca tion I SAF No. 

200-PW-2/100-PW4 OU - Borehole Soil Sampling 216-A-37 (C4106); (12.5'-I5} F03-006 

Ice Chest No. ^ /C C_ 

Shipped To 

POSSIBLE SAMPLE HAZARDSfREMkRKS 


q^ OS^ Field Logbook No. COA Method of Shipment 

/ HNF-N-3361 117504ESIO Federal Expre ss 

Offaih Property No. 

z} 

Preservation 



Volume 

O v Z 

Nat I of I 

1 

Price Code 8N Data Turna ro und 


zo Bill of Lading/Air Bill No. t^^d ^^- 

Cad 4C C1.1 4C C.W4C None None 

aG aG aG aG 

I I I I I 

120mL 60m 1- 120ML 60mL 60mL 

O.W. NOLNO3- Otte Gt - 5«ium(1) Tmaua-In 

- 14,71% 753.2 413.1 sped) 

SAMPLE ANALYSIS t 


B16W79 SOIL 0^ 

iN OF POSSESSION 

elinquidted B ved F Datd[itne 

Sign/Print Names SPECIAL INSTRUC TIONS' 

2 2 i3 

tie Received /Stated In Dstdfime 

REI=N 3928 4zsv3 16915 r P A 

matrix 

both 

m ^ 

f sn 0 ^'t ' •• The lahomtory is to 

diced ratt8a fmm WTM anslysm 

Eye °0 4 T sl Sr laotopi Thorium ! ^ __ _ :+t. r 

sr seaê 

: _ d' taped By/Removed F Da dfvne 

e- 

Received Byrsto ed in 

Dateirmte 

j f10 

5-101 //Dm y^9^ ^^/LZ`/I 

so-sdu 

St-sky 

W.W. 

oaa 

elinquishedBFtom n ^Datûne 

SJC-rX E de^C2 0 

aos nw. Sdwt 

Received By/Staeed Datefrim 

r 6-n t: 22". 

el' B /R From Daw'fime 

S t o3 

in Daterrime 

S'a-0 O 

elioquiahed Byrttaooved From Daleri a Received In DsWluoe 

eliopushed By/Renavcd From Da diime Rectived By/Stored In Date/rmte 


the 377288 

relinquish samples rn 

Ref. on ^f^.._/^ 3^L 

LABORATORY Received BY Title - Datdfime 

SECTION 

FINAL SAMPLE Diapual Method 134osed By Datdrmte 

DISPOSITION 

BHI-EE-011 (03/01/2002) 

m-mx 

t-uevn 

X

F11-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-63 


Johansen/Pope/Pfister LC Hulst rom 373-3928 TRENT, SJ 


200-PW-7/200-PW4 OU- Bo re hole Soil Sampling 216-A-37(C4106);(I7.5'-201 F03-006 

Ice Chest No L (a^ 


J► o ^! b 


Shipped To OQsitt Propty er No. 

z 




Preservation 



Volume 


B16W80 SOIL Z^ Q3 's 

nJ ^ ZZ d 

Cad 4C Cco14C Cod 4C None None 

e G 

aG a G aG 

I I I I I 

120ml. 60mL 120mL 60ML 60m1. 


peodum 140LNO3- 011& e- S aan (1) n Tri um -m 

Hex-71% 353.2 411.1 Sped) 

AA 

n 

d) 

Price Code gN 

Page I °f ) 



M OF POSSESSION SignlPltnt Names SPECIAL INSTRUCTIONS /f bj 4i yl t v a 1 Matrix 

dinquished /Rmlloved Fmm dfma Received ByMomd In DetNlSm!e '• 


Tsai 

report both keroame and diesel more compounds from WIPH-D a nalysis. 

s^ 

^t'-F /A S72 b yZt^ tp 111 

elfiW& ed By/Removed F D^°'k 

By/Stored In 

qq 

T 

45 It^' 3 7 ZU 61 f' -5 1toG 

Dndrime 

b [3 G+4 

03 

elirapdahed By DaterTime 1 a 0O Received By/Staed in Dderrime 

SJ GALE 5103 NE FIX 

g yAteno vy Unto Datdrnne Rig In Datdrime 

11 

0O 

ICY rV) e GYM p f- 

dirptusbed Bydtemoved From D^ce d n 

Received omd in D° °"e 

Relinquished By/RennvW From DstNfvna Received BylStaed U 

LABORATORY Received fA' 

SECTION 

FINAL SAMPLE 

DISPOSITION 

BHI-EE-011 (031011002) 

Dispceal Method 

DMelCime 

170 Nickd-A'l-Neptw'nm-737 ^ ì 


re 

linquish samples from the 3728 

Ref# 't—on—a—U—I¢`- 

Title Dat err lrne 

Dapored By 

Daterfnne 

so-sdu 

W. ° 

MAir 

°^^° 

.a 

m-wi e 

µX V 

x 

nv"`0

FH-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-64 Pass t 1 



Johansen/PopeWster LC Hulskom 373-3928 TRENT, SJ 

SAY No. 

45 Days 

Project Designation Sampling Loca tion Air Quality q 

200-PW-21200-PW-4 OU - Borehole Soil Sampling 216-A-37 (C4106); (27.5'-301 F03-006 

Ice Chat No. p / // 

C^ (. (0 d ^b 

Shipped To 


HNF-N-3361 

POSSIBLE SAMPLE HAZARDS/REMARICS G 


COA 


117504ES10 Federal Express 

Oftsite Proper ty No. A 1 2 D Bitl of Lading/Air Bill No. 

Prese rva tion 



- Volume 



B16W61 SOIL 

(J J 

Coot 4C Cod K Cod IC Na m None 

aG aG 

LABORATORY 

SECTION 

Re ceived By T itle Daterrrn1e 

N YTNAL SAMPLE 

G 

^ DtSPOSITTON 

Dispwal Method Disposed By Datdrime 

art 

1 I 1 1 1 

120,%L 60mL 120mL 60ML 6gnL 

Ch. NOIJNO3- Oil A0rme- See itenU) TM:nn.to 

H.-7196 353.2 41 3.3 seedd 

t 1°'p t 

d1/ 

aG 

{^ BI LO 

CHAIN OF POSSESSION SPECIAL INSTRUCTIONS 4 ` d) Matrix 

Siga/Priot Names^p ^., 

sited F hne 

Re^tved By/Slored U 

tdfi e ` a 

n 

report both kerosene an e• The laboratory is to 

s-Son 

l 

d diesel range eompqurds from WTPH•D malysis. 

ss-weave 

Y. 

V SOStlY 

sast.as 

el' 8/Removed From hire jy40- Received ByIV;;ed 

y 

In tefrinne tl 

s 

Z-4- doq . e^.3 M:_ ad,--^,, 

L11, 21°3 

0 .1 

1 

1 

43 

d vgaished F ro m nne Re ceived ByMo rrd In Daterrime 

^^ 

r^ 

l^ 

A-" 

6os 

om.sam 

//ag 

-3 I / oa 5J j or.-o^ r:9dm 

T-TSa.e 

elm' "idKd By/Removed From R ec eived By/Stored in Datdfime 

;yAtl( 11 

Re B From Ate/Time to 

Dddrene 

elingruand ByAtemoved From 

BHI-EE-011 (MMIr002) 

P ersonne l w1 available to 

. . 03 relinq'uiQsh samples from the 3728 

Ref a f,aôn / (_/^ 

Datdfime U Date/lime 

amwe. 

L-L wr 

v-veae.,e. 

x-416:

FE-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-65 Pea° ! --f 1 



Johansen/PopOPlister LC Hulstrom 373-3928 TRENT, SJ 

Price Code 8N 

Project Designation Sampling Location SAP No. Air Quality q 45 Days 

200-PW-21200-PW4 OU -Borehole Soil Sampling 216-A-37 (C410 6); (375-40) F03-006 

Ice Cheat No.Field Logbook No. COA Method of Shipment 

erk L ( 

9. b O S ^ HNF-N-3361 117504ESIO Federal Express 

Shipped To

iV 

FR-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-00 66 

Collector 

Johanscn/Pope/P6ster 


200-PW-2/200-PW-0 OU - Borehole Soil Sampling 

Ice Chest No. / 

^^ G Q 6 O 

Shipped To 

POSSIBLE SAMPLE HAZARDS/REMAR 



t 


LC Hulst rom 373.3928 


216-A-37 (C4 106); (47.5'-50) 


HNF-N-3361 

COA 

117504ES I O 


TRENT, SJ 

SAF No. 

F03-006 



Price Code 

8N 

Air Quality q 

Ottsite Property No. ^-0 :5 Q Z ZO Bill of Lading/Air Bill No. .r7 ^-^- OS ^ 

Preserva tion 



Volume 


B16W83 SOIL () 

Cad 4C Cod 4C Cod 4C None Nave 


1 I I ) 

120mL 60mL IlOmL 60mL 60m1, 

CMann,u 

Nees-71% 

NONt403- 

353.2 

Oila.fneue- 

413.1 

See itae (1)tn 

Sped) 

1npivdi0 

Tdrlum-FD 

1. 

6 I 

CRAIN OF POSSESSION Sign/Printl klames SPECIAL INSTRUCTIONS 

'f LG if 

.'t •!— 

•• 

report both kerosene and diesel mge cornpmade f ro B F Daterr' 

m WiPH-D aodysis. 

Ly (1) hu - ob r, Isotopic um 

"1 H rxSJ2 1JM i 

` ^^^ e lit 

j 

Received By/Shaed In ^ r^--^- 

T a 

e shed /R From ^^ 17Ora 

y/S In D dri a 9 ,-A=J 

k l y 

I T^ LI q--LT- 3 

^^ 

Ita iahed From Dire 

Re d,ed By/Stored 

` 

3 L 1 O'7 11 00 


relinquish samples 

onP es from the 37.28 

Ref # 

Date/Time 

S tJ Q-5 ^f7a 

d'agrddred By/R F Detertine 

Received By in DetwTme 

S 1 ^^^ 0 I/^^ l V L 

R el' By From$O? 

ecervcd °"e 

S , 

By/Rm,,d From Dddrime Received BY Daterrine 


Tide 

FINAL SAMPLE Disposal MedW 

DISPOSITION 

BHI-EE-011 (0310112002) 

Disposed By 

The Iabomtory is to 

Page 1 of 1 


45 Days 

Datelrtnx 

Datdrrme 

Matrix" 

s-svl 

sa-sm..a 

so-axw 

sr-nde 

0 ° 

D s-ona 4 WW 

oUO,,.. uwu, 

r rreae 

ar-wye 

X- ee 

x

FH-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-00673 Pew 


Johansen/Pope/Pfister LC Huistrom 373-3928 TRENT, SJ 


200-PW-21200-PW4 OU . Borehole Soil Sampling 216-A-37 (C4106); (17.5'-29) F03-006 

tee Chest No. e—, R C p O 

^C- ^L 

Shipped To 

lo^^ J SQ L 

POSSIBLE SAMPLE HAZARDS/REMAR 


7 


Fie Logbook 

M f Shipment 

3 No 

1177504ES I O Federal 

Offsite Property No. A 6 -3 0 Z Z a 

Ir 

Preservation 



Volume 


B16W90 SOIL - (I g" la 

Cad 4C C.1 4C C.1 4C None None 

aG aG aG 

1 I I 1 1 

120mL 60mL 120mL Went. 60rrtL 

Chwnuum NOLNOS- Ol&Came- Seeit.(1)b Tritium - In 

Hu-71% 5531 413.1 Spernl 

1npraq tlj 

P 

Bill of Lading/Air Bill No. ,5 3&- OS r 

a^ 

J of J 


Air Quality q 45DayS 


emoved Fm atNfime 

e - 'shed ByMemovcd F Dwertme 

v ' (v4 577-r 5 1 0 3 11 60 

Sign/P rint Names 


Pr' 37ZSS U 

Received By/Sta x! In 

93J Ll 

SPECIAL INSTRUCTIONS q 17,770 

0 

uDttdrime 

1 - . '• The labo ratory is to 

report troth kerosene and diesel range contlmnds from WfPH-D analysis. 

/ Z$ 03 ^^ ys 

J 

DaIdTime 

onum 

31 ' 

Sio 3 1/0 C) 1 

01f t(a) 

Matrix 

s-5d1 

ya-syM 

sOSAN 

sasmea< 

W.W. 

dinquished B y) 

v 

By From 

S 

DaterThne 0 9 

vawr a 

11oo 

Received Byrstaed 

F=- G G- 

Received U 

Datefrmre 

Dudfune 

"-w 

rnw ma& 

arm eugw 

r+rrs 

w,-mp 

S v3 f U 0 

Relinquished BylRcmoved From Date/11me Peceived By1S'toAd In Daterrime 

elin"s ad By^^ro^ From DaWTur a Received By/8toed In DatetTime 


relinquish mplea rom the 372 

.,,88^, 

Ref # Lon 

LABORATORY Received By Title Datefrune 

SECTION 

FINAL SAMPLE Disposal Method Disposed By DateTme 

DISPOSITION 

BHI-EE-011 (03101/2002) 

W Vgtl/ n 

x-ase

FH-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS RE VEST F03-006-74 


P rice Code 8N Data Turnaround 

Johansen/Popeftster LC Hulstrom 373-3928 TRENT. SJ 

Project Designation Sampling Location SAFNo. 

2WPW-212W-PW- 4 OU - Bo re ho le Soil Sampling 216-A-31 (C4106); (0.5) F03-M 

Ice Chest No. & /^-'R 

^— 

q 


{ hWF-N-3361 117504ESIC Federal Express 

Shipped To (}^,^9103 ''Zlc-e 214 Offsi tt Property No. e, Z ^2- 0 

^//V V O 




Preservation 

Type or Container 


Volume 


131 6W91 SOIL 'yq 0 i 

C0.1 4C Cool 4C 

aG aG 

I I 

60ML 250mL 

Peeidde- chloro- 

0061 Hmddd®- 

UA0151 

Air Quality E] 45 Days .- 

Bill of Lading/Air Bill No.s ,Syr r) 

t^ V. 6,5 

IN OF POSSESSION Sign/Print Noma SPECIAL INSTRUCTIONS Matrix 

emmed m Daterri ne Received By/Swred In Datetfime 

s-sai 

I 

)Or 

Byf =wAd F 

KF—F— 1 Pr -17Z1 

Dat^p11E 

5103 11 06 

ecriwd Byl8toled In 

d 

Daterrime 

/ o} / l o o 

w saw 

qOH 

Relinquished y/Removed mm Daterrnm eceived By/StIn Deterrent 

. _ S 1 0 0o 25CED 15FX 

By4cromed From Da W 

terr°"e 

earlgwsmd By/RemOVed From 

o 

Duc/Time 

Receiver 

eceivedB 

N 

In 

Datdfime 

d 

Detefrime 

from 0e 

e1pata 

3308 

7 

Petsdnn Sarev 

IÎ/- 

Ielivwt A- on 

dhtq W*d By/Ranuved From Datrlfimt Recerwd By/Stored In Deterrine 

we It 

LABORATORY Reedad By 

SECTION 

FINAL SAMPLE 

DISPOSITION 

BHI-EE-011 (03/01/2002) 

D'epoaW Method 

Tide 

Detertime 

- Dopoaed By Deterrane 

'Âa 

os-a.o, sam 

M-vane 

w ^^ 

x-aner

IENT: I 

chase Order/Project: 

A 



Ha+,ô r^ 

sows / Release a: FU 3- oc^(y 

DATE: S a a3 

oratory SD 3 N: 

SOS C. 3 

)TE: ALL ENTRIES MARKED "NO" MUST BE EXPLAINED IN THE COMMENT SECTION 


container intact, signed and dated?.. 

Yea ONO 0 NIA0 see Comment 

2. Outside of coole rs or shipping containers arc es ONO E3 NIA 0 see Comment N 


3. Airbill N recorded? Iyes ONO q NIA O we Comment N 

4. All .expected paperwork received (coc and 

-other client specific: historical data, z1ves O No 0 NIA O see Comment N 

alphabets or other s creening data as 



S. Sample containers aVntact? ^pryer ONO O NIA 0 see Comment N 

6. Custody seals on sample containers intact, es 0 No, O N/A O see Comment N 

signed and dated? - . 

?. All samples on COC received? 


tt 

l 

Iy 

Pots 

t^ 

u ONO O NIA O see Comment N 

ONO ON/A- 17 eee Comme nt N 

9. Laboratory QC samples designated on coc? O Yes O No `,WA O see Comment N 


30, Shipment meets LvL1 Sample Acceptance ) y yu ONO O N/A O me Comme nt N 

Policy?' (identify all bo ttles n ot within 

policy. See reve rs e side for policy) 

11. Where applicable, bar code labels are 0 y^ ONO 'INIA O see Comment N 

affixed to ex? 

12. coc signed and dated? Wes ONO O NIA O see Comment N 

13. coc will be faxed or emailed to client? m Yes •- ONO O NIA O see Comment N 

14. Project Manager/Client conta cted 


Cooler 4 / temp (°C) and Comments: 

Laboratory 

ECC q(,-O5(v 


/ 1 ,3'^ 

— 

)IJ 

r , 

O y es ONO M A O see Comment N 

28

4?v - jw" 

Lionville Laboratory, Inc. 0, 



!^^£llltLO_^ 



B16W79 

% SOLIDS 001 S 03LWS061 04/28/03 05/05/03 05/06/03 

CHLORIDE BY IC 001 S 03LICA31 04/28 /03 05/16/03 05/16/03 

CHLORIDE BY IC 001 REP S 03LICA31 04/28/03 05/16/03 05/16/03 

CHLORIDE BY IC 001 MS S 03LICA31 04/28 /03 05/16/03 05/16/03 

FLUORIDE BY IC 001 S 03LICA31 04/28/03 05/16/03 05/16/03 

FLUORIDE BY IC 001 REP S 03LICA31 04/28 /03 05/16/03 05/16/03 

FLUORIDE BY IC 001 MS S 03LICA31 04/28/03 05/16/03 05/16/03 

NITRITE BY IC 001 S 03LICA31 04/28 /03 05/16/03 05/16/03 

NITRITE BY IC 001 REP S 03LICA31 04/28 /03 05/16/03 05/16/03 

NITRITE BY IC 001 MS S 03LICA31 04/28/03 05/16/03 05/16/03 

NITRATE BY IC 001 S 03LICA31 04/28 /03 05/16/03 05/16/03 

NITRATE BY IC 001 REP S 03LICA31 04/28 /03 05/16/03 05/16/03 

NITRATE BY IC 001 MS S 03LICA31 04/28 /03 05/16/03 05/16/03 

TOTAL CYANIDE 001 S 03LCO46 04/28 /03 05/21/03 05/21/03 

TOTAL CYANIDE 001 REP S 03LCO46 04/28 /03 05/21/03 05/21/03 

TOTAL CYANIDE 001 MS S 03LCO46 04/28/03 05/21/03 05/21/03 

PHOSPHATE BY IC 001 S 03LICA31 04/28/03 05/16/03 05/16/03 

PHOSPHATE BY IC 001 REP S 03LICA31 04/28/03 05/16/03 05/16/03 

PHOSPHATE BY IC 001 MS S 03LICA31 04/28 /03 05/16/03 05/16/03 

CHROMIUM VI 001 S 03LVIO41 04/28 /03 05/07/03 05/07/03 

CHROMIUM VI 001 MS S 03LVIO41 04/28 /03 05/07/03 05/07/03 

CHROMIUM VI 001 MSD S 03LVIO41 04/28 /03 05/07/03 05/07/03 

SULFATE BY IC 001 S 03LICA31 04/28/03 05/16/03 05/16/03 

SULFATE BY IC 001 REP S 03LICA31 04/28/03 05/16/03 05/16/03 

SULFATE BY IC 001 MS S 03LICA31 04/28 /03 05/16/03 05/16/03 

NITRATE NITRITE 001 S 03LN3A27 04/28 /03 05/22/03 05/22/03 

AMMONIA 001 S 03LAMA14 04/28/03 05/24/03 05/26/03 

OIL & GREASE BY GRAV 001 S 03LOG023 04/28 /03 06/04/03 06/05/03 

PH 001 S 03LPHO35 04/28/03 05/20/03 05/20/03 

PH 001 REP S 03LPHO35 04/28/03 05/20/03 05/20/03 

B16W80 

% SOLIDS 002 S 03LkS061 04/28/03 05/05/03 05/06/03 

CHLORIDE BY IC 002 S 03LICA31 04/28/03 05/16/03 05/16/03 

131




DATE RECEIVED: 05/02/03 LVL LOT #. :0305L329 



NITRITE BY IC 002 S 03LICA31 04/28/03 05/16/03 05/16/03 

NITRATE BY IC 002 S 03LICA31 04/28/03 05/16/03 05/16/03 

TOTAL CYANIDE 002 S 03LCO46 04/28/03 05/21/03 05/21/03 


CHROMIUM VI 002 S 03LVIO41 04/28/03 05/07/03 05/07/03 


NITRATE NITRITE 002 S 03LN3A27 04/28/03 05/22/03 05/22/03 

AMMONIA 002 S 03LAMA14 04/28/03 05/24/03 05/26/03 

OIL & GREASE BY GRAV 002 S 03LOG023 04/28/03 06/04/03. 06/05/03 

PH 002 S 03LPHO35 04/28/03 05/20/03 05/20/03 

B16W81 

W SOLIDS 003 S 03L%S061 04/29/03 05/05/03 05/06/03 










NITRATE NITRITE 003 REP S 03LN3A27 04/29/03 05/22/03 05/22/03 

NITRATE NITRITE 003 MS S 03LN3A27 04/29/03 05/22/03 05/22/03 

AMMONIA 003 S 03LAMA14 04/29/03 05/24/03 05/26/03 

OIL & GREASE BY GRAV 003 S 03LOG023 04/29/03 06/04/03 06/05/03 

PH 003 S 03LPHO35 04/29/03 05/20/03 05/20/03 

B16W82 

1; SOLIDS 004 S 03LWS061 04/29/03 05/05/03 05/06/03 





TOTAL CYANIDE 004 S -03LCO46 04/29/03 05/21/03 05/21/03 

02





CLIENT ID /ANALYSIS LVL # MIX PREP # COLLECTION EXTR/PREP ANALYSIS 





AMMONIA 004 S 03LAMA14 04/29/03 05/24/03 05/26/03 


PH 004 S 03LPHO35 04/29/03 05/20/03 05/20/03 

B16W83 

W SOLIDS 005 S 03L$S061 04/29/03 05/05/03 05/06/03 





TOTAL CYANIDE 005 S 03LCO46 .04/29/03 05/21/03 05/21/03 





AMMONIA 005 S 03LAMA14 04/29/03 05/24/03 05/26/03 


PH 005 S 03LPHO35 04/29/03 05/20/03 05/20/03 

B16W90 

k SOLIDS 006 S 03L$S061 04/28/03 05/05/03 05/06/03 










AMMONIA 006 S 03LAMA14 04/28/03 05/24/03 05/26/03 

AMMONIA 006 REP S 03LAMA14 04/28/03 05/24/03 05/26/03 

03






AMMONIA 006 MS S 03LAMA14 04/28/03 05/24/03 05/26/03 


OIL AND GREASE BY GR 006 REP S 03LOG024 04/28/03 06/05/03 06/06/03 

OIL AND GREASE BY GR 006 MS S 03LOG024 04/28/03 06/05/03 06/06/03 

PH 006 S 03LPH035 04/28/03 05/20/03 05/20/03 

B16W91 

W SOLIDS 007 S 03LWS061 04/28/03 05/05/03 05/06/03 

W SOLIDS 007 REP S 03LWS061 04/28/03 05/05/03 05/06/03 

LAB QC: 

CHLORIDE BY IC MB1 S 03LICA31 N/A 05/16/03 05/16/03 

CHLORIDE BY IC MB1 BS S 03LICA31 N/A 05/16/03 05/16/03 

FLUORIDE BY IC MB1 S 03LICA31 N/A 05/16/03 05/16/03 

FLUORIDE BY IC MB1 BS S 03LICA31 N/A 05/16/03 05/16/03 

NITRITE BY IC MB1 S 03LICA31 N/A 05/16/03 05/16/03 

NITRITE BY IC MB1 BS S 03LICA31 N/A 05/16/03 05/16/03 

NITRATE BY IC MB1 S 03LICA31 N/A 05/16/03 05/16/03 

NITRATE BY IC MB1 BS S 03LICA31 N/A 05/16/03 05/16/03 

TOTAL CYANIDE LCS L S 03LC046 N/A 05/21/03 05/21/03 

TOTAL CYANIDE LCS L S 03LC046 N/A 05/21/03 05/21/03 

TOTAL CYANIDE MB1 S 03LC046 N/A 05/21/03 05/21/03 

PHOSPHATE BY IC MS1 S 03LICA31 N/A 05/16/03 05/16/03 

PHOSPHATE BY IC MB1 BS S 03LICA31 N/A 05/16/03 05/16/03 

CHROMIUM VI MB1 S 03LVI041 N/A 05/07/03 05/07/03 

CHROMIUM VI MB1 BS S 03LVI041 N/A 05/07/03 05/07/03 

CHROMIUM VI MB1 BSD S 03LVI041 N/A 05/07/03 05/07/03 

SULFATE BY IC MB1 S 03LICA31 N/A 05/16/03 05/16/03 

SULFATE BY IC MB1 BS S 03LICA31 N/A 05/16/03 05/16/03 

NITRATE NITRITE MB1 S 03LN3A27 N/A 05/22/03 05/22/03 

NITRATE NITRITE MB1 BS S 03LN3A27 N/A 05/22/03 05/22/03 

AMMONIA MB1 S 03LAMA14 N/A 05/24/03 05/26/03 

AMMONIA MB1 BS S 03LAMA14 N/A 05/24/03 05/26/03 

AMMONIA MB1 BSD S 03LAMA14 N/A 05/24/03 05/26/03 

OIL & GREASE BY GRAV MB1 S 03LOG023 N/A 06/04/03 06/05/03 

OIL AND GREASE BY GR MB1 BS S 03LOG023 N/A 06/04/03 06/05/03 

m






OIL AND GREASE BY GR MB1 BSD S 03LOG023 N/A 06/04/03 06/05/03 

OIL & GREASE BY GRAV MB1 S 03LOG024 N/A 06/05/03 06/06/03 

OIL AND GREASE BY GR MB1 BE S 03LOG024 N/A 06/05/03 06/06/03 

OIL AND GREASE BY GR MB1 BSD S 03LOG024 N/A 06/05/03 06/06/03 

05

Client: TNU-HANFORD F03-006 H2194 

LVL#: 0305L329 


1. This narrative covers the analyses of 7 soil samples. 

W.O.#:11343-606-001-9999-00 


2. The samples were prepared and analyzed in accordance with the methods indicated on the 

attached glossary. 

3. The sample holding times as required by the method and/or contract were met with the 

exception of Total Cyanide samples as the request for analyses was past the sample holding 

times. 

4. The results presented in this report are derived from samples that met LvLI's sample 

acceptance policy. 

5. The method blanks were within the method criteria. 

6. The Laboratory Control Samples (LCS) were within the laboratory control limits. The 

duplicate LCS for Ammonia and Oil and Grease were within the 20% Relative Percent 

Difference (RPD) control limit. 

7. The matrix spike (MS) recoveries for Chloride, Fluoride, Nitrite, Nitrate, Total Cyanide, 

Chromium VI, Sulfate, Nitrate Nitrite, Ammonia and Oil and Grease were within the 75- 

125% control limits, however MS recovery for Phosphate was below the control limits at 

71.5°/x. 

8. The replicate analyses for Chloride, Fluoride, Nitrite, Nitrate, Total Cyanide, Phosphate, 

Sulfate, pH, Nitrate Nitrite, Ammonia, Oil and Grease and Percent Solids were within the 

20% Relative Percent Difference (RPD) control limit. 

The results p re sented in this report relate to the analytical testing and conditions of the samples upon receipt and during storage. All pages of this report are integral 

parts of the analytical data Therefore, this report should only be reproduced in its entirety of 29 pages. 

208 Welsh Pool Road • Exton, PA 19341-1313 • (610) 280-3000 • Fax (610) 280-3041 

06

9. Results for solid samples are reported on a dry weight basis. 

10. I certify that this sample data package is in comp liance with SOW requirements, both 

technically and for completeness, other than the conditions detailed above. Release of the 

data contained in this hard copy package h as been authorized by the Laborato ry Manager or 

a designee, as verified by the following signature. 

Iain Daniels Date 



njPU01329 

qUAVIIIE IAX00.^lpXl ICY. 

07


WET CHEMISTRY 

METHODS GLOSSARY FOR SOIL/SOLIDS SAMPLE ANALYSIS 

ASTM SW846 OTHER 

% Ash 

D2216-80 

% Moisture 

% Solids 

D2216-80 

^y – 

J D2216-80 

_ ILMO4.0 (e) 

_ ILMO4.0 (e) 

% Volatile Solids D2216-80 

ASTM Extraction in Water _ D3987-81/85 

BTU _ D240-87 

CEC _ 9081 _ c 

Chromium VI 

,^3060AI7196A 

Corrosivity _ by coupon _ by pH 

Cyanide, Total 

1110(mod) _ 9045C 

/ 

^/ 901OB/604 _ ILMO4.0 (e) 

Cyanide, Reactive — Section 7.3/9014 

Halides, Extractable Organic _ 9020B _ EPA 600/4/84-008 

Halides, Total 

_ 9020B _ EPA 600/4/84-008 

EP Toxicity _ 1310A 

Flash Point _ 1010 

Ignitability 1010 

Oil & Grease 9071 A J 4) 3 - I ê( 

Carbon, Total Org anic _ 9060 _ Lloyd Kahn (mod) 

Oxygen Bomb Prep for Anions _ D240-87(mod) 5050 

Petroleum Hydrocarbons, Total Recoverable _ 9071 _ EPA 418.1 

pH, Soil 

9045C 

Sulfide, Reactive _ Sec tion 7.3/9030B 

Sulfide _ 9030B(mod) 

Specific Gravity _ D1429-76C/ _ D5057-90 

Sulfur, Total _ 9056 

Synthetic Preparation Leach _ 1312 

Paint Filter _ 9095A 

Other: G 1 e,, d^t ;at..a d e f^ r^ ^ 

^^Method: EPR 

Other: r l,11n--Jz Method 

L-WI-034/&01/0 1' ` 

3cc')-Q('A ed- 

V EPA 313.12 

EP^4 3 55d - 3 

\ 1 

08


METHOD REFERENCES AND DATA QUALIFIERS 


U = Indicates that the parameter was not detected at or above the reported limit. The 

associated numerical value is the sample detection limit. 

* = Indicates that the original sample result is greater than 4x the spike amount added. 

ABBREVIATIONS 

MB = Method or Preparation Blank. 

MS = Matrix Spike. 

MSD = Matrix Spike Duplicate. 

REP = Sample Replicate 

LC = Laboratory Control Sample. 

NC = Not calculated. 

A suffix of -R, -S, or -T following these codes indicate a replicate, spike or sample 

duplicate analysis respectively. 

ANALYTICAL WET CHEMISTRY METHODS 

L-WI-034/D-02/01 

1. ASTM Standard Methods. 

2. USEPA Methods for Chemical Analysis of Water and Wastes (USEPA 600/4-79- 

020). 

3. Test Methods for Evaluating Solid Waste (USEPA SW-846). 

a. Standard Methods for the Examination of Water and Waste, 16 ed, (1983). 

b. Standard Methods for the Examination of Water and Waste, 17 ed, (1989)/18ed 

(1992). 

C. Method of Soil Analysis, Part 1, Physical and Mineralogical Methods, 2nd ed, 

(1986). 

d. Method of Soil Analysis, Part 2, Chemical and Microbiological Properties, Am. 

Soc. Agron., Madison, WI (1965). 

e. USEPA Contract Laboratory Program, Statement of Work for Inorganic Analysis. 

f. Code of Federal Regulations.



CLIENT: TNUHANFORD PO3-006 M2194 

WORK ORDER: 11343-606-001-9999-00 



SAMPLE 

....... 

SITE ID ANALYTS 

.................... ....................... 

RESULT 

........ 

UNITS 

...... 

LIMIT 

.......... 

FACTOR 

........ 

-001 B16M79 8 Solids 

93.9 4 0.01 

1.0 

Chloride by IC 14.3 MO/KG 1.3 1.0 

Fluoride by IC 1.3 u MG/KG 1.3 1.0 

Nitrite by IC 1.33 u MG/KG 1.33 1.0 

Nitrate by IC 1710 MG/KG 133 100 

Cyanide, Total 0.40 u MG/KG 0.40 1.0 

Phosphate by IC 1.3 a MG/KG 1.3 1.0 

Chromium VI 0.43 u MG/KG 0.43 1.0 

Sulfate by IC 32.0 MG/KG 1.3 1.0 

Nitrate Nitrite 499 MG/KG 20.0 100 

Ammonia, as N 266 MG/KG 4.2 1.0 

oil 6 Grease Gravimetrl 710 u MG/KG 710 1.0 

PH 7.5 SOIL PH 0.01 1.0 

-002 B16M60 8 Solids 95.7 4 0.01 1.0 

Chloride by IC 1.3 u MO/KG 1.3 1.0 


Nitrite by IC 1.31 u MO/KG 1.31 1.0 

Nitrate by IC 718 MO/KG 65.3 50.0 


- Phosphate by IC 1.3 u MO/KG 1.3 1.0 


Sulfate by IC 1.7 MO/KG 1.3 1.0 

Nitrate Nitrite 163 MG/KG 10.3 50.0 

Ammonia, as N 9.0 MO/KG 4.6 1.0 

Oil 4 Grease Gravimetri 696 u MG/KG 696 1.0 

PH 7.9 SOIL PH 0.01 1.0 

10



CLIENT: TNUHANPORD P03-006 M2194 

WORK ORDER: 11343-606-001-9999-00 



SAMPLE 

....... 


.................... ....................... 

RESULT 

........ 

UNITS 

...... 

LIMIT 

.......... 

FACTOR 

........ 

-003 B16N01 W Solids 96.0 4 0.01 

1.0 

Chloride by IC 1.3 u MG/KG 1.3 1.0 



Nitrate by IC 10.4 MG/KG 1.30 1.0 

Cyanide, Total 0.31 u MO/KG 0.31 1.0 

Phosphate by IC 1.3 u MG/KG 1.3 1.0 



Nitrate Nitrite 5.1 MG/KG 0.19 1.0 

Ammonia, as N 5.2 u MG/KG 5.2 1.0 

oil 4 Grease Gravimetri 694 u MG/KG 694 1.0 

PH 0.6 SOIL PH 0.01 1.0 

-004 B16W02 4 Solids 94.4 4 0.01 1.0 










Ammonia, as N 44.2 MG/KG 4.3 1.0 

Oil 4 Grease Gravimetri 706 u MG/KG 706 1.0 

PH 6.5 SOIL PH 0.01 1.0 

11



CLIENT: TNUBANPORD P03-006 H2194 LVL LOT N: 030SL329 

WORK ORDER: 11343-606-001- 9999-00 


SAMPLE 

....... 

SITE ID 

.................... 

ANALYTE 

....................... 

RESULT 

........ 

UNITS 

...... 

LIMIT 

.......... 

FACTOR 

........ 

-005 B16W83 

4 Solids 94.7 t 

0.01 

1.0 

Chloride by IC 1.3 a MG/KG 1.3 1.0 

Pluoride by IC 1.3 u MG/KG 1.3 1.0 




Phosphate by IC 1.3 a NO/KG 1.3 1.0 


sulfate by IC 2.1 MG/KG 1.3 1.0 



Oil 4 Grease Gravimetrl 704 u MO/KG 704 1.0 

PH 6.5 SOIL PH 0.01 1.0 

-006 B16W90 4 Solids 96.1 4 0.01 1.0 




Nitrate by IC 522 MG/KG 26.0 20.0 

Cyanide, Total 0.33 u NO/KG 0.33 1.0 




Nitrate Nitrite 143 MG/KG 3.7 20.0 


011 6 Grease Gravimatri 694 u MG/KG 694 1.0 

PH 8.0 SOIL PH 0.01 1.0 

12

CLIENT: THORANPORD P03-006 H2194 

WORK ORDER: 11343-606-001-9999-00 


....... .................... .......... 

-007 B16W91 4 Solids 



LVL LOT #: 03051,329 


RESULT UNITS LIMIT FACTOR 

........ ...... .......... ........ 

92.4 5 

0.01 

1.0 

13


WORK ORDER: 11343-606-001-9999-00 


....... 

SLANCI0 

.................... 

03LICA31-MB1 


INORGANICS METHOD BLANK DATA SUMMARY PAGE 06/06/03 

....................... 

Chloride by IC 

Fluoride by IC 

Nitrite by IC 

Nitrate by IC 

Phosphate by IC 

Sulfate by IC 

BLANKI 03LC046-MBI Cyanide, Total 

BLANCI0 03LV1041-MB1 Chromium VI 

BLANK10 03LN3A27-MB1 Nitrate Nitrite 

BLANCI0 03LANA14-MB1 Ammonia, ae N 

BLANKI0 03LOG023-MB1 Oil 6 Grease Gravimatri 

BLANK10 03LOG024-MB1 Oil 6 Grasse Gravimatri 



RESULT 

........ 

UNITS 

...... 

LIMIT 

.......... 

FACTOR 

........ 

1.2 u MG/KG 

1.2 

1.0 

1.2 u MG/KG 1.2 1.0 

1.25 u MG/KG 1.25 1.0 

1.25 u MG/KG 1.25 1.0 

1.2 u MG/KG 1.2 1.0 

1.2 u MG/KG 1.2 1.0 

0.50 u MG/KG 0.50 1.0 

0.40 u MG/KG 0.40 1.0 

0.20 u MG/KG 0.20 1.0 

5.0 u MG/KG 5.0 1.0 

667 u MG/KG 667 1.0 

667 u MG/KG 667 1.0 

14

SAMPLE SITE ID 

....... .................... 

-001 B16W79 

-003 B16N81 

ANALYTE 

Chloride by IC 


Nitrite by IC 

Nitrate by IC 



Soluble Chromium VI 

Insoluble Chromium VI 

Sulfate by IC 

Nitrate Nitrite 


INORGANICS ACCURACY REPORT 06/06/03 

CLIENT; TNUNANPORD P03-006 H2194 

WORK ORDER: 11343-606-001-9999-00 


SPIKED INITIAL SPIKED DILUTION 

SAMPLE 

....... 

RESULT 

....... 

AMOUNT 

...... 

4RECOV 

....... 

PACTOR(SPK) 

.......... 

41.6 14.3 27.0 100.9 

1.0 

26.1 0.45 27.0 94.6 1.0 

27.2 1.33u 27.0 100.6 1.0 

7010 1710 5320 99.5 200 

5.03 0.40u 5.30 95.0 1.0 

19.3 1.3 u 27.0 71.5 1.0 

4.5 0.43u 4.3 104.9 1.0 

1280 0.43u 1190 IOR.3 100 

74.5 32.0 53.0 80.2 2.0 

10.9 5.1 5.1 114.1 2.0 

15


INORGANICS ACCURACY REPORT 06/06/03 

CLIENT: TNUHANFORD 903-006 H2194 

WORK ORDER: 11343-606-001-9999-00 


SPIKED INITIAL SPIKED DILUTION 

SAMPLE 

....... 

SITE ID 

.................... 

ANALYTB 

...................... 

SAMPLE 

....... 

RESULT 

....... 

AMOUNT 

...... 

4RROOV 

....... 

FACTOR(SPK) 

.......... 

-006 B16W90 

Ammonia, as N 213 4.7 u 202 105.0 

1.0 

Oil & Grease Gravimetr 6450 694 u 6980 92.4 1.0 

BLANKI0 03LICA31-MB1 Chloride by IC 23.6 1.2 u 25.0 94.3 1.0 

Fluoride by IC 23.9 1.2 u 25.0 95.4 1.0 

Nitrite by IC 24.3 1.25u 25.0 97.1 1.0 

Nitrate by IC 24.4 1.25u 25.0 97.4 1.0 

Phosphate by IC 23.7 1.2 u 25.0 94.8 1.0 

Sulfate by IC 24.2 1.2 u 25.0 96.6 1.0 

BLANKI0 03LVI041-MBS Soluble Chromium VI 3.9 0.40u 4.0 .96.6 1.0 

Insoluble Chromium VI 1220 0.40u 1250 97.8 100 

BLANKI0 03LN3A27-MB1 Nitrate Nitrite 5.2 0.20u 5.0 104.0 1.0 

BLANKI0 O3LANA14-MB1 Ammonia, as N 196 5.0 u 200 96.0 1.0 

Ammonia, AS N NED 192 5.0 u 200 96.0 1.0 

BLANKI0 03L0O023-MB1 Oil & Grease Gravimatr 6430 667 u 6350 101.3 1.0 

Oil & Grease - Grav M 7230 667 u 6350 113.9 1.0 

BLAN(10 03L00024-MBS 011 & Grease Gravimetr 6160 667 u 6710 91.8 1.0 

Oil & Grease - Grav M 6270 667 u 6710 93.4 1.0 

NMI


WORK ORDER: 11343-606-001-9999-00 


....... .................... ...................... 

BLANKIO 03LAKA14-MB1 Ammonia, as N 

BLANKI0 03LOG023-MB1 Oil 6 Grease - Grav 

BLANKI0 03LOG024-MB1 Oil L Grease - Grav 


INORGANICS DUPLICATE SPIKE REPORT 06/06/03 


SPIKE#1 SPIKR#2 

►RECOV %RECOV %DIPP 

...... ...... ...... 

98.0 96.0 2.1 

101.3 113.9 11.7 

91.8 93.4 1.7 

17

CLIENT: TNUNANPORD P03-006 H2194 

WORK ORDER: 11343-606-001-9999-00 

SAMPLE SITE ID ANALYTB 

....... .................... ...............,. 

-001REP B16W79 Chloride by IC 


Nitrite by IC 

Nitrate by IC 



Sulfate by IC 

pe 

-003REP B16Wal Nitrate Nitrite 



LVL LOT N: 0305L329 


RESULT REPLICATE RPD FACTOR(REP) 

........ ......... ....... 

........... 

14.3 14.0 2.5 

1.0 

1.3 u 1.3 u NC 1.0 

1.33u 1.33u NC 1.0 

1710 1750 2.0 100 

0.40u 0.52u NC 1.0 

1.3 a 1.3 u NC 1.0 

32.0 32.5 1.6 1.0 

7.5 7.5 0.9 1.0 

5.1 5.2 3.6 1.0 

iv


WORK ORDER: 11343-606-001-9999-00 

SAMPLE BITE ID ANALYTE 

....... .................... ....................... 

-006REP B16N90 Ammonia, as N 

Oil 4 Grease Gravimetri 

-007REP B16W91 Y Solids 



LVL LOT N: 030SL329 


RESULT REPLICATE RPD FACTOR(REP) 

........ ......... ....... ........... 

4.7 u 5.2 u NC 1.0 

694 u 694 u NC 1.0 

92.4 92.6 0.48 1.0 

19

CLIENT: TNVHANPORD P03-006 H3194 

WORK ORDER: 11343-606-001-9999-00 

SAMPLE SITS ID ANALYTE 

....... .................... ...................... 

LCSS1 03LC046-LCS1 Cyanide, Total LCS 

LCSS2 03LC046-LCS3 Cyanide, Total LCS 


INORGANICS LABORATORY CONTROL STANDARDS REPORT 06/06/03 


SPIKED SPIKED 

SAMPLE AMOUNT UNITS 4RSCOV 

...... ...... ...... ...... 

1.84 3.0 MG/KG 91.8 

9.91 10.0 MG/KG 99.1 

20


5I--3a- 

Client =jb 1- N0[ Q-ACC'- -1507%-C 12C 0 

U 

y0A Dial r(rLo rtsti rrlu) v , vt max. 

Custody Transfer Record/Lab Work Request Page—Loft 


Est Final Proj. Sampling Date #rrype Container 

Project# 11?^V-!oC'1^=r'nt-^g9.t^^ 

I-) "^ 

Refrigerator #

F11-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-62 J PaP I Of t 


lohansetllPope/PHster LC Hulsimm 373-3928 TRENT, S] 

Project Daignatioo Sampling Location SAFNo. 

200-PW-2200-PW4 OU - Borehole Soil Sampling 216-A-37 (C4106); (12.5'-151 F03-006 

lee Chat No.q 

CkL (^ ^5 


HNF-N-3361 117504ES10 Fedend Express 

Price Code $]v Data Turnaround 

Air Quality q 

Shipped To 

o, 1C-9 

izerteipf 

.. 

22 0 

Off site Property No. Bill of Lading/Air Bill No-6 

'=—E -Z0 

5 P 

(^- 

POSSIBLE SAMPLE ` 



Preservation 



Volume 


B16W79 SOIL fj 03 

cod 4c Mml 4C Cod ac None Nom 

oG 

aG aG aG 

1. I 1 1 1 

120ML 6OmL 120mt" Wail, 60mL 

Cleaumn NOv 03- 09&Gam- seekmo (I)' Tres -W 

Iier-71% 353.2 413.1 Sp•dd 

45 Days 

OF POSSESSION 

Rdrownshod B ved Fmv 

Relioq ' By/Removed Fred 

/ (n^ 

.5-1 C7'14L.E^ .[1Q}(R„ 

Sign/P rint Noma SPECIAL INSTRUCTIONS /I 77r,3— 

aa"^tleisbnmsmy '- - , I. f so a ^'r - W. ` •• The laboratory DmN[in a eft eeeived B/Sto red In Datelrime 

is to 

37C^ ) 3^q e^ (}2SO2 g 5C^ 

repo rt butt kemsme mid diesel iescl range cmnpowds from W1PH-D amlysis. 1 

1^ 

^-Ô / 

Date/runej' 

_^ r__._-.:.— m. e..Y 09 qn Total Sr Isuopie Thori S'n.n aaar. re i. a:eceived 

BY/S In 

Date/rime 

oo 

, T os //Do y/t'L .^ 

66 / 

Date?ime r 15—P dff 

x 

1) JI'ime 

/ 

O 

Matrix 

s•>di 

-y6^ 

so-sem 

si-saes' 

9_mmv W-W. 

o.om 

"' n: 

oa-onvsww 

nr.om r:9,w 

el' Fmm 

ingmshed By/Remved From 

^ ^ 

S t'o3 

Drtdrime 

Rod 

eceivedB 

od In 

41,i 

t to 

DOWN= 

Sa o a 

Datefrime 


relinquish sampl esm the 3728 

M9a-Wye 

wv`° xoav 

Ref# -&— on 

Relinquished By/Removed Fmm DardTwe Received By/Stored In Datarime 

LABORATORY R ecei ved By TitleDate/Time 

SECTION 

FINAL SAMPLE Diapoal Method Disposed By Dwe/rime 

DISPOSITION 

BHI-EE-011 (03/01/2002) 

N 

;V



Johansen/Pope/Pfister ster LC Hulsm tm 

373-3928 

TRENT, Sl 

Project Designa tion Sampling Loca tion SAF No. 

200-PW-2t200-PW-4 OU -Bo rehole Soil Sampling 216-A-37 (C4106); (17.5'-201 F03-M 

Price Code $]v Data Turnaround 

Air Quality q 

Ice ChestNo-e 

C 96 

OS6 

Fiel^Nhaolt No. 

177504ESIO 

Method 


rat 

Shipped To 

" 

O[fsite Properly No. 

A-0 v ^ Z 

Bill of Lading/Air Bill No. a^ 

Q3)r L 


Cod ec cod 4C S-ad 6c Nom N-1 




No. ofLoonioer(a) ) 

Volume 

Sample No. Ma trix • Sample Date Sample Time 

B16W60 SOIL K G3 i1tts 1C 

aG aG sG aG 

1 ) ) I 

120mL 60mL 120 1111. 60mL 60mL 

Ouon:um NO2/NO3- wade- saeam(t)m Tdti.-Ha 

Hes-71% Ml 413 .1 Spedd 

a ^^ 

C► 

45 Days 

OF POSSESSION SigdPriotNamea SPECIAL INSTRUCTIONS ei y Ln of Matrix 

dtemoved From we eceisW By,,/^^S77taed In L>ate/fi/mê 

•• 

•• 

^ 


sâeo 

I ^ f 

,e S;7.1 

report both kwseoe and diesel range compounds from WIPH-D analysis. 

g-yam 

'P 

jF 1,4 $ 4/Z8n3 

lio9utshed ByMemovedF IWdC 

6 I s 7z$ S 10'5 Ito* 

By/Stored In Daterrime 

Imquishell By Datdl"me [ 100 By/stnted to Datb7unc 

A- s c,~aata S^ 07 li° ^ .U9 Ni kd.6i- Neotuum-237 

^V 

- 

q ° ^/°1 

5J 6AL s I °3 FE Eh a a^ 

By/Removed 

+^ 

DaWr— /S In Date lime 

By/Kd ^ From Daterfime 

Rccmvcd omd In - DWKrime 

eliogirislad By/Removed I— DaWT= _ BWStomd In 

DawTime 

© '(1j 

Personnel not available t 


Ref # Mon 

LABORATORY 

SECTION 

Received By Tide DawTime 

FINAL SAMPLE 

DISPOS 

Disposal Method Disposed By DaWrtme 

IT 

ION 

BHI-EE-011 (03101/2002) 

so-sad 

SOSA, 

w. W., 

vna 

^-m.e. sore 

wee 

c-tea° 

^°aaloi 

CT) 

CV

M-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-64 I Pw 1 of 1 

Collector 

Johnnsen/PopelPSster 


200-PW-2200-PW4 OU -Borehole Soil Sampling 

Ice Chest No. r..y^ C, p (0`^ 

G ^^ 

Shipped To 6^ C 3 Ie SBF.BJ.IN686IpW 

, 

nxar^ 

POSSIBLE SAMPLE HAZARDS/REMABKS 





216-A-37 (C4106); (27.5'-30^ 

Field Logbook FF-N-33 Na. 

OfB ite Property No./I O 

If'G 

Preserva tion 


No. of Coominer(s) 

Volume 

I15 04ES10 


TRENT, SJ Mee Code 8N Data Turnaround 

SAF No. 

F03.006 

Method d tEx Shipment 

eew4c cows caw4 woe woe 

NO aG aG w 

I I 1 1 1 

120olL 60mL 120nd, filled, fi0m(. 

Air Quality q 

Bill of Lading/Air Bill No. ^^^ O ^^ J 

auem:m NOVNW- aiaOre„e- Sec k;(it Tritium -x3 


Her- 71% 753.2 4 13.1 Sdel 

t 

d t 7 . 

Sample No. Matr ix • Sample Date Sample Time 

Bi 6W81 SOIL (. I^p(l) 

P ^^v 

1;•^.TD 

45 Days 

CHAIN OF POSSESSION Sign/Print Names SPECIAL INSTRUCTIONS '4'' ei r L d) Matrix 

y F mne geiv^ By/Stmed In e 

Wsbed By/Re6ved F 

Rr 

ro m one /Ta6- Received 11flT5ed N une I l j 

duquishod vod From inoe 

Received By/Stoned In 

Detr/rime 

03 1101 

37v 

flop Z 

Rdmquabed By/R FromDa1JImw Received BylSiwd N DateIrme 

( / 0 0 ex 

B ved From DatNCu ne 

Real t In Datdrime 

3 

y 

2 03 O 

Relinquished By/Removed From DatNfmte Received By In Datertime 

e 

report both kerosene and d euJ mile compounds fine WfPH D analyse. 

4101 bU kdQ-Nmnmijm 737. J Lill 



Ref#^pn 

% // ^^ 

. '• The Iabonmry¢ to 

LABORATORY R =L 

ec SECTION 

eived By Title DazNfime 

FINAL SAMPLE 

DISPOSITION 

Disposal Method Disposed By Detrlrlme 

BHI-EE-011 (03/012002) 

yi 

^ym^ 

n-amae 

p Z, 

o u.n, s•6a 

DUO 

wo-wpe 

1,Lw W 

v-ead+m v 

x

F11-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS RE UEST F03-006-65 Page 1 of 1 

Collector 


ro ject Designa tion 


Ice Chest No.// 

M L 9. (0 ^D 

S Y 

Shipped To fe ^ 




LC Hillstrom 373-3928 


216-A-37 (C4106); (37.5-0( Y) 


HNF-N-3361 

"/s• ) 45/_ Oflaite P ro perty No. Ll yt 


Preservation 


No. of Coutainer(s) 

Volume 


816W82 SOIL ?-Cf 3 C) 

Are V 

COA 

1175041510 

ZZ-0 


TRENT, SI 

SAF No. 

F03.M 



Cod aC Cod aC Cod aC None Nam 

aG aG aG aG 

1 1 1 t 1 

120ml. Wad, 120mL 60ad. Wa 

Clumyim N0NNO3 . Oil&G.. See ilse(1)' Tduum-30 

Hn01% 353.3 413.1 Spssyr 

tmmmo 

1 

Price Code 

Air Quality q 

Bill of La ding/Air B ill No. Sz^^ ^^^ 

8N Data Turnaround 

OF POSSESSION SignMrint Namn SPECIAL INSTRUCTIONS 

a Is . --The 

F Reouved By/Smred 

lahomtory is to 

1. IF ime 

rNmt 6dh kemaeae and diesel urge compounds from WIPH-D analysis. 

+rte sl (' 

By ved Flom 

Received /StmedN une / IRV — a , . 

I=AdD R_ 4.1 J171 lb .uW> 

elmgaished B ved F '^ 

3719 l 0 3 

linquiahed By/Removed Fmm f ateTm 

J O ) too 

Received By/Sromd 

e, 

Received By/S 

D&WT=e 

5 j o 5 Igo) 

103 DstNCmw 

By ems From DaWTime 

-0 

Rcoci 

Daldfime 

03 eTA 

elanwoshed By/Rmovad From Dardfile n MB/S 

Dater®e 

LABORATORY Reeci vedBy 

SECTION 

Persoluiel riot available to 

elinquish samples from the 3728 

Ref # la on eT /_L_LP 

^r> =got 

Tide DaWflele 

FINAL SAMPLE Disposal Method Duposcd By Daterrime 

DISPOSITION 

BHI-EE-011 (03101/2002) 

45 Days 

Matrix 

se-seamy 

so-sau 

ShaYtls 

a-w 

" Wi 

N1-Wlm 

tILVWd 

v.vye.m. 

X° 

. 

n

FH-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-66 Pale 1 of I 

Collector 

smdPopester 

Johan /Pfi 



Ice Cheat No. / 

(FR C 4 O 5- 

Company Contact Telephone No, 



216-A-37 (C4106); (47.5-50) 

Shipped To Iseale'4 Otfsite Property No. 





HNF-N-3361 I COA 

117504ESIO 

Preservation 



Volume 


B16W83 SOIL O 

?rc 2) 

Q Z Z Q 

Bill 


TRENT, SJ 

SAF No. 

F03-006 



Cool eC Cod eC Co ol eC Noee Noee 

aG no aG aG xG 

I I I 1 

120mL 60M, 120ML 60m]. 60mL 

Ouva000 

atmr-91% 

NO2/NO3. 

357.2 

War. 

413.1 

S. hem (I)in 

sped) 

N 

of Lading/Air Bill No. 

T' - - H7 

t 

6 / 

P rice Code 

8N 

Air Quality q 

p 

CHAIN OF POSSESSION Sign/Print Names SPECIAL INSTRUCTIONS it ^( LG 6f 

•' 

report both kerosene and diesel rage compounds from WTFH-D amlyau. 


relinquish n1i pies fmm the 3728 

Ref Sato 

By 

ReJlgymalsa B/R 

F 

From 

k-Ib 

Datrlf' 

Received By/Stowed In = L— 

^. 

J=Pahu a 

atdf Dear Received y/5 Ito a lâei 

•'+1juCS I 7^- 4 . ^ . 0 3 

U' B 

3 2- 

From 

1 0') 

ime 

11 0 0 

Received By/Stwed 

S 

Datdfume 

S 1 o'3 110b 

towished Bydtemo F atJf®e 

Received ved By/St B a ctrune 

G lEt t 

ved Fmm 

eliogwsW By/Removed Frain 

S l 0 3 

Îdfime 

DaWl mme 

1 /06 t iz- L 

Received=&2U 

Received By/Std" 

Sae 

Daterfime 

On _:5 

—C 

(I) anon - o ,Isotopm mm um 

"9^ticts^LNm^_s^^^ 7 ^'^ c/^tLlriy 

--The laboratory is to 

LABORATORY ReeeivW By Title Date(Tune 

SEC TI ON 

FINAL SAMPLE Diaposd Method - D°posed By Datà'kno 

DISPOSMON 

BHI-EE-011 (03/0 1/2002) 


45 Days 

Matrix 

s sin 

50 StlY 

si-si.ds 

W.W. 

a 'v'r 

wt -tee 

vn-mp< 

v-v'aam 

xo6v 

C^!

P-P1 of 1 

I F11-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-73 

Collector 

]ohansen/Pope/Pfister 

Company Contact 

LC Hulstran 

Telephone No. 

373-3928 


TRENT, Sl 


Project Designa tion Sampling Loca tion SAF No. 

200-PW-21100-PW-0 OU - Borehole Soil Sampling 216-A-37 (C4I06); (17.5'-20) F03-006 

lee Cheat No.p / ` C/' 


COA Method of Shipment 

C I l^ 03 


Shipped To /2 4*j Offsite Properly No. ZZ Q 

ITV 3 




Preservation 



Volume 


at 6W90 SOIL 6; S-tz> 

I 

Cod 4C Cod ac Cod C Noee Nwe 

vG 

aG aG aG 

I I I 1 I 

120ml. 6OmL 120ML 60ml. 60ml, 

area a NO2M03- OR&G.- See a®(1)' Tdiaoo-H3 

ilea-71% 3512 413.1 spcdY 

t^ 

.[ ,` 

P a^ 


B ill of Lading/Air Bill Na 

3 QSP c_ 

CHAIN OF POSSESSION Sign/Print Names SPECIAL INSTRUCTIONS Y 2 L C; Matrix 

emoved F mv: Raeeivd By/Stmed In DaWTc 

report both kerosene and diesel range compounds from WTPH-D analysis. 


^d 

I°crt I py' 37ZSS y Z.303 /4 YS 

Rd' unshed By/Removed Fro 

f'I",rame 

Received By/Stored in 

Datdfime 

iZZ ' 1 V} S 

Jbrgwshed BY/ Dafdfime Recisved By/SWmdJC Dadfiroe 

372,r I n 3 060 ZJ Le-A 110 3 7/OU 

03 1100 F° C G-X 

By/Re vd From f^'^ Received In DawTime 

03 ,r U o 

Relinquished By/Removed From DatJf^ Received ByAt In ^c(rimC 


Daklfime Received By/Stomd In Datc Time 

1'9" 'e 

x Vlt t°l 


relinquish{,.}5_amples from the 37,2,88 

Ref # on rS 11_l1G 

LABORATORY Received By Tits. DatcTi me 

SECTION 

FINAL SAMPLE Disposal MedW Disposed By Datarrime 

DISPOSITION 

BHI-EE-0 11 (03/01/2002) 

n 

so sdr 

a-aesp: 

W - W., 

o 

DS-o Ws 

me-U. Lu d 

T- wire 

e-Lb*w 

v-vgedw 

z-wQ

FH-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-74 1PROe 1 Of 1 




200-PW-7/100-PW4 OU - Bomhole Soil Sampling 216-A-37 (04106); (0.51 F03-006 

Ice Cheat No. 

L Q 09'(0 

oe L 1 

Shipped To (y bno3 ' (C C 21ht Offid Property No. #630 

POSSIBLE SAMPLE HAZARDWREMARKS 





Preservation 



Volume 


816W91 SOIL Z4 p i 

7 

!i 

Coot ac cod 4C 

aG aG 

I I 

60mL 250ML 

Paficidn- 

M1 

cwl 

H.Wdo- 

FrAatst 

Pri ce Code 8N Data Turnaround 


Bill of Lading/Air Bill Nos O,^ .) 

OF POSSESSION Sign/Print Names SPECIAL. INSTRUCTIONS Matrix 

emoved m Dwerrune Received By/Stortd In DatHrime 

^—F 14 37 2- t 17L zsr: 03 46 qS 

h hed By /Removed Fr6rn 

719 3 

Daterrm¢ 

5103 IIOO 


d 

Dedrime 

^/ 0 -5/Jos 

w sme 

oau 

dinqunbcd By/Removed/^/r rom DaWlum Re ceived By in DatrTm 

A-Atr 

ns.a..sam 

v[/r rl.^ S 1 03 Uso EhrD aX ot'om uyias 

yr',tnè 

Rd By emoved From Da[eA'une Received ]n I)atelfime 

Rel*Wshed By/Removed F rom Daie Rea' t In Date rime 

Relinquished By/Removed From Date rime Received By/Stored In DaWrime 

LABORATORY Rauived By 

SECTION 

v 

?"Son(% " QNCSaf{O^j1JÎ T 

teiWAOt 

lief # 

On %^ 

Tide Dwerrime 

FINAL SAMPLE Dispoed Method Disposed By Daterrime 

DISPOSITION 

BHI-EE-011 (03101/2002) 

' 

X pev 

FA

J 

LIONVILLE LABORA'T'ORY INCORPORATED 


LIENT: I 1Û Ha^,orc^ 

trchase Order/Project: DATE: S a' 

7or 

OW# / Release #: F03 - 00(o 

8 letsory SDG M O 5 L, 3 2-9_ 

TOTE: ALL ENTRIES MARKED "NO" MUST BE EXPLAINED IN THE COMMENT SECTION 

1. Custody seals on coolers or shipping Yes No 0 NIA 0 sec Comment 


2. Outside of coolers or shipping containers arees ONO o NIA O see Comment # 


3. Airbill # recorded? ^q Yes ONO O N/A O see Comme nt # 


other client specific: histo rical data, 

alphabets or other s cr 

eening data as 



t'u ONO O N/A O see Comme nt # 

/1X 

S. Samp le containers area intact? ONO O N/A O sec Comme nt # 

6. Custody seals on sample containe rs intact, es ONO O N/A O see Comment # 


7. All samples on coc received ? Yes ONO O N/A O we Comment # 


l m 

ONO ON/A- • Z7 see Commcm # 

9. Laboratory QC samples designated on coc? O Yes ONO )"N/A O see Comment # 

(QC stickers placed on bo ttles?) 

10. Shipment meets LvLI Sample Acceptance Y es ONO O N/A O see Comment # 

Poli cy? (identify all bo ttles not within 

policy. See reverse aide for policy) 

11. Where applicable, bar code labels are O YU ONO ' 12 N/A O see Comment It 


1 2. coc signed and dated? 

Îqû 

O No O NIA o see Comment # 

13. coc will be faxed or emailed to client? QYcs• ONO O NIA O see Comme nt # 



Cooler (! / temp (°C) and Comments: 

Etc G'i(0 -G5(4' 

/ 1,3" 


O Yes ONO A O see Comme nt # 

Laboratory Project Manager: 29

IÊSERLINE 

SRVICS 

E E 

June 17. 2003 

Mr. Steve Trent 


825 Jadwin Avenue 

Richland, WA 99352 

Reference: P.O. #630 

Eberline Se rvices R3-05-013-7507, SDG H2194 

Dear Mr. Trent: 

Enclosed is the data repo rt for six solid samples designated under SAF No. F03-006 received 

at Eberline Services on May 2, 2003. The samples were analyzed according to the 

accompanying chain-of-custody documents. 

Please call if you have any questions concerning this repo rt . 

Sincerely, 

m 

m^ 

Melissa C. Mannion 

Program Manager 

MCM 

Enclosure: Data Package 

N 

(,aR[C[1VV[0 

Analytical Services 

2030 Wright Avenue 

P.0, Box 4040 

Richmond, California 94804-0040 

(510) 235.2633 Fax (510) 235.0438 

Toll Free (600) 841.5467 

www.ebarlineservices.com

Eberline Services 

W.O. No. R3-05-013-7507 

Case Narrative 

1.0 GENERAL 


SDG H2194 

Page 1 of 2 

Fluor Hanford Inc. (FH) Sample Delivery Group H2194 was composed of six solid (soil) 

samples designated under SAF No. F03-006 with a Project Designations of: 200-PW- 

2/200-PW-4 OU — Borehole Soil Sampling. 

The samples were received as stated on the Chain-of-Custody documents. Any 

discrepancies are noted on the Eberline Services Sample Receipt Checklist. 

2.0 ANALYSIS NOTES 

2.1 Tritium Analyses 

No problems were encountered during the course of the analyses. 

2.2 Carbon-14 Analyses 


2.3 Nickel-63 Analyses 


2.4 Total Strontium Analyses 


2.5 Technetium-99 Analyses 


2.6 Iodine-129 Analyses 


2.7 Isotopic Thorium Analyses 


2.8 Neptunium-237 Analyses 

No problems were encountered during the course of the analyses.

Eberline Services 

W.O. No. R3-06-013-7507 

Case Narrative 

Case Narrative Certification Statement 


SDG H2194 

Page 2 of 2 

"I certify that this data package is in compliance with the SOW, both technically 

and for completeness, for other than the conditions detailed above. Release of 

the data obtained in this hard copy data package has been authorized by the 

Laboratory Manager or a designee, as verified by the following signature." 

Melissa C. Mannion Date 

Program Manager 

7 3

Prepared by 

E B E R L I N E S E R V I C E S/ R I C H M O N D 

SAMPLE DELIVERY GROUP H2194 

SDG 7507 Client Hanford 

Contact Melissa C. Mannion Contract No. 630 

Case no SDG H2194 

lWk,m Y^Qirrn^- 

Reviewed by 

S U M M A R Y D A T A S E C T I O N 

T A B L E O F C O N T E N T S 

About this section 1 

Sample Summaries 3 

Prep Batch Summary 5 

Work Summary 6 

Method Blanks 9 

Lab Control Samples 10 

Duplicates 11 

Matrix Spikes 12 

Data Sheets 13 

Method Summaries 19 

Report Guides 35 

End of Section 49 

Lab id EBRLNE 

Protocol Hanford 

Version Ver 1.0 

Form DVD-TOC 

Version 3.06 

Report date 06/17/03

EBERLINE SERVICES/RICHMOND 


SDG 7507 

Client Hanford 

Contact Melissa C. Mannion R E P O R T G U I D E Contract No. 630 


ABOUT THE DATA SUMMARY SECTION 

The Data Summary Section of a Data Package has all data, in several 

useful orders, necessary for first level, routine review of the data 

package for a Sample Delivery Group (SDG). This section follows the 

Data Package Narrative, which has an overview of the data package and a 

discussion of special problems. It is followed by the Raw Data Section, 

which has full details. 

The Data Summary Section has several groups of reports: 

SAMPLE SUMMARIES 

The Sample and QC Summary Reports show all samples, including QC 

samples, reported in one SDG. These reports cross-reference client and 

lab sample identifiers. 

PREPARATION BATCH SUMMARY 

The Preparation Batch Summary Report shows all preparation batches 

(lab groupings reflecting how work was organized) relevant to the 

reported SDG with information necessary to check the completeness and 

consistency of the SDG. 

WORK SUMMARY 

The Work Summary Report shows all samples and work done on them 

relevant to the reported SDG. 

iZui^TiY. 6039-OW-1,0010 

The Method Blank Reports, one for each Method Blank relevant to the 

SDG, show all results and primary supporting information for the blanks. 

LAB CONTROL SAMPLES 

The Lab Control Sample Reports, one for each Lab Control Sample relevant 

to the SDG, show all results, recoveries and primary supporting 

information for these QC samples. 

REPORT GUIDES 

Page 1 

SUMMARY DATA SECTION 

Page 1 

Lab id EBRLNE 



Form DVD-RG 

Version 3.06 


EBER L INE SER V ICES / RICHMOND 


SDG 7507 


Contact Melissa C. Mannion G U I D E, C o n t Contract No. 630 


DUPLICATES 

ABOUT THE DATA SUMMARY SECTION 

The Duplicate Reports, one for each Duplicate and Original sample pair 

relevant to the SDG, show all results, differences and primary 

supporting information for these QC samples. 

MATRIX SPIKES 

The Matrix Spike Reports, one for each Spiked and Original sample pair 

relevant to the SDG, show all results, recoveries and primary supporting 

information for these QC samples. 

DATA SHEETS 

The Data Sheet Reports, one for each client sample in the SDG, show all 

results and primary supporting information for these samples. 

METHOD SUMMARIES 

The Method Summary Reports, one for each test used in the SDG, show all 

results, QC and method performance data for one analyte on one or two 

pages. (A test is a short code for the method used to do certain work 

to the client's specification.) 

REPORT GUIDES 

The Report Guides, one for each of the above groups of reports, have 

documentation on how to read the associated reports. 

REPORT GUIDES 

Page 2 


Page 2 

Lab id EBRLNE 


version Ver 1.0 

Form DVD-RG 

Version 3.06 


SDG 7507 

Contact Melissa C. Ma..i: 

LAB 



LAB SAMPLE SUMMARY 

SAMPLE ID CLIENT SAMPLE ID LOCATION MATRIX LEVEL SAF NO 


Contract No. 630 


CHAIN OF 

CUSTODY COLLECTED 

R305013-01 B16W79 216-A-37 (C4106) SOLID F03-006 F03-006-62 04/28/03 13:50 

R305013-02 B16W80 216-A-37 (C4106) SOLID F03-006 F03-006-63 04/28/03 15:10 

R305013-03 B16W81 216-A-37 (C4106) SOLID F03-006 F03-006-64 04/29/03 07:45 

R305013-04 B16W82 216-A-37 (C4106) SOLID F03-006 F03-006 . 65 04/29/03 09:00 

R305013-05 B16W83 216-A-37 (C4106) SOLID F03-006 F03-006-66 04/29/03 10:20 

R305013-06 B16W90 216-A-37 (C4106) SOLID F03-006 F03-006-73 04/28/03 15:10 

R305013-07 Lab Control Sample SOLID F03-006 

R305013-08 Method Blank SOLID F03-006 

R305013-09 Duplicate (R305013-04) 216-A-37 (04106) SOLID F03-006 04129/03 09:00 

8305013-10 Spike (8305013-04) 216-A-37 (C4106) SOLID F03-006 04/29/03 09:00 

LAB SUMMARY 

Page 1 

Lab id EBRLNE 



Form DVD-LS 

SUMMARY DATA SECTION Version 3.06 

Page 3 Report date 06/17/03

sDG 7507 




Contact Melissa C. Mannion QC SUMMARY Contract No. 630 


CHAIN OF X SAMPLE BASIS DAYS SINCE LAB DEPARTMENT 

QC BATCH CUSTODY CLIENT SAMPLE ID MATRIX SOLIDS AMOUNT AMOUNT RECEIVED COLL SAMPLE ID SAMPLE ID 

7507 F03-006-62 B16N79 SOLID 93.9 149.0 g 05/02/03 4 R305013-01 7507-001 

F03-006-63 B16U80 SOLID 95.3 158.5 g 05/02/03 4 R305013-02 7507-002 

F03-006-64 816N81 SOLID 95.5 156.2 g 05/02/03 3 R305013-03 7507-003 

F03-006-65 B16N82 SOLID 94.5 152.0 g 05/02/03 3 R305013-04 7507-004 

F03-006-66 B16N83 SOLID 94.3 148.1 g 05/02/03 3 R305013-05 7507-005 

F03-006-73 B16N90 

OC SUMMARY 

Page 1 


Page 4 

Method Blank 

Lab Control Sample 

Duplicate (R305013-04) 

Spike (R305013-04) 

SOLID 95.9 160.9 g 05/02/03 4 R305013-06 7507-006 

SOLID R305013-08 7507-008 

SOLID R305013-07 7507-007 

SOLID 94.5 152.0 9 05/02/03 3 R305013-09 7507-009 

SOLID 94.5 152.0 g 05/02/03 3 R305013-10 7507-010 

Lab id EBRLNE 



Form DVD-QS 

Version 3.06 


SDG 7507 

Contact Melissa C. Mannton 

TEST MATRIX METHOD 

Alpha Spectroscopy 




PREP BATCH SUMMARY Contract No. 630 

PREPARATION 

BATCH 

ERROR 

20 % CLIENT MORE 

PLANCHETS 

RE BLANK 


ANALYZED 

LCS DUP/ORIG 

NP SOLID Neptunium in Soil 7060.151 5.0 6 1 1 1/1 

TH SOLID Thorium, Isotopic in Soil 7060-151 5.0 6 1 1 1/1 

Beta Counting 

SR SOLID Total Stronti um in Soil 7060-151 10.0 6 1 1 1/1 

TC SOLID Technetium 99 in Soil 7060-151 10.0 6 1 1 1/1 

Gamma Spectroscopy 

I SOLID Iodine 129 in Soil 7060-151 10.0 6 1 1 1/1 

Liquid Scintillation Canting 

C SOLID Carbon 14 in Soil 7060-151 10.0 6 1 1 1/1 

GUALI- 

MS/ORIG FIERS 

H SOLID Tritium in Soil 7060-151 10.0 6 1 1 1/1 1/1 X 

NI L SOLID Nickel 63 in Soil 7060-151 10.0 6 1 1 1/1 1/1 

Duplicates and Matrix Spikes are those with original (Client) sample in this Sample Delivery Group. 

Blank and LCS planchets are those in the same preparation batch as some Client, Duplicate or Spike sample. 

Lab id EBRLNE 


PREP BATCH SUMMARY Version Ver 1.0 

Page 1 Form DVD-PBS 



SD67507 

Contact Melissa C. Mannlon 

LAB SAMPLE 

CLIENT SAMPLE ID 



COLLECTED LOCATION MATRIX SUF- 


LAB WORK SUMMARY Contract No. 630 

RECEIVED CUSTODY SAF No PLANCHET TEST FIX ANALYZED REVIEWED BY METHOD 


R305013-01 B16W79 7507-001 C 05/28/03 06/17/03 MCM Carbon 14 in Soil 

04/28/03 216-A-37 (C4106) SOLID 7507-001 H 06/10/03 06/17/03 MCM Tritium in Soil 

05/02/03 F03-006-62 F03-006 7507-001 1 06/04/03 06/17/03 MCM Iodine 129 in Soil 

7507-001 NI—L 05/31/03 06/17/03 MCM Nickel 63 in Soil 

7507-001 NP 06/09/03 06/17/03 MCM Neptunium in Soil 

7507-001 SR 05/28/03 06/17/03 MCM Total Strontium in Soil 

7507-001 TC 06/16/03 06/17/03 MCM Technetium 99 in Soil 

7507-001 TH 06/04/03 06/17/03 MCM Thorium, Isotopic in Soil 

R305013-02 6161480 7507-002 C 05/28/03 06/17/03 MCM Carbon 14 in Soil 



7507-002 NI_L 05/31/03 06/17/03 MCM Nickel 63 in Soil 



7507-002 TC 06/16/03 06117/03 MCM Technetium 99 in Soil 



04129/03 216-A-37 (04106) SOLID 7507-003 H 06/11/03 06/17/03 MCM Tritium in Soil 

05/02/03 F03-006-64 F03-006 7507-003 I 06/06103 06/17/03 MCM Iodine 129 in Soil 

7507-003 NI _L 05/31/03 06/17/03 MCM Nickel 63 in Soil 






04/29/03 216-A-37 (04106) SOLID 7507-004 H 06/11/03 06/17/03 MCM Tritium in Soil 

05/02/03 F03-006-65 F03-006 7507-004 I 06/07/03 06/17/03 MCM Iodine 129 in Soil 






Lab id EBRLNE 


WORK SUMMARY Version Ver 1.0 

Page 1 Form DVD-LWS 



=SDG7507 




Conssa C. Mann", WORK SUMMARY, cont. Contract No. 630 

LAB SAMPLE 






04/29/03 216-A-37 (04106) SOLID 7507-005 H 06/11/03 06/17/03 MCM Tritium in Soil 







8305013-06 B16W90 7507-006 C 05/29/03 06/17/03 MCM Carbon 14 in Soil 


05102103 F03-006-73 F03-006 7507-006 1 06/10/03 06/17/03 MCM Iodine 129 in Soil 

7507-006 NI_L 05131/03 06/17/03 MCM Nickel 63 in Soil 

7507-006 NP 06/06/03 06/17/03 MCM Neptuni um in Soil 

7507-006 SR 05/28/03 06/17103 MCM Total Strontium in Soil 



R305013-07 Lab Control Sample 7507-007 C 05/29/03 06/17/03 MCM Carbon 14 in Soil 

SOLID 7507-007 H 06111/03 06/17/03 MCM Tritium in Soil 

F03-006 7507-007 I 06/10/03 06/17/03 MCM Iodine 129 in Soil 




7507-007 TC 06/15103 06/17/03 MCM Technetium 99 in Soil 


R305013-08 Method Blank 7507-008 C 05/28/03 06/17/03 MCM Carbon 14 in Soil 

SOLID 7507-008 H 06/11/03 06/17/03 MCM Tritium in Soil 

F03-006 7507-008 I 06/11/03 06/17/03 MCM Iodine 129 in Soil 






Lab id EBRLNE 






=SDG7,507 


SAMPLE DELIVERY GROUP N2194 


Contsa C. Mannion WORK SUMMARY, con t. Contract No. 630 

LAB SAMPLE 





R305013-09 Duplicate (R305013-04) 7507-009 C 05/29/03 06/17/03 MCM Carbon 14 in Soil 


05/02/03 F03-006 7507-009 I 06/11103 06/17/03 MCM Iodine 129 in Soil 

7507-009 NI-L 05/31/03 06/17/03 MCM Nickel 63 in Soil 





R305013-10 Spike (R305013-04) 7507-010 H 06/11/03 06/17/03 MCM Tritium in Soil 

04/29/03 216-A-37 (C4106) SOLID 7507-010 NI_L 05/31/03 06/17/03 MCM Nickel 63 in Soil 

05/02/03 F03-006 

TEST SAF No 

METHOD 

COUNTS 

OF TESTS BY SAMPLE 

REFERENCE 

TYPE 

CLIENT MORE RE BLANK LCS DUP SPIKE TOTAL 

C F03-006 Carbon 14 in Soil C14_CO%_LSC 6 1 1 1 9 

H F03-006 Tritium in Soil 906.0_H3_LSC 6 1 1 1 1 10 

1 F03-006 Iodine 129 in SoiL 1129_SEP_LEPS_GS 6 1 1 1 9 

NI — L F03-006 Nickel 63 in Soil N163_LSC 6 1 1 1 1 10 

NP F03-006 Neptunium in Soil NP237_LLE_PLATE_AEA 6 1 1 1 9 

SR F03-006 Total Stronti um in Soil SRTOT_SEP_PRECIP_GPC 6 1 1 1 9 

TC F03-006 Technetium 99 in Soil TC99_TR_SEP_LSC 6 1 1 1 9 

TH F03-006 Thorium, Isotopic in Soil THISO IE PLATE_AEA 6 1 1 1 9 

TOTALS 48 8 8 8 2 74 

Lab id EBRLNE 






7507-008 

SDG 7507 

Contact Melissa C. Mannion 

Lab sample id R305013-08 

Dept sample id 7507-008 

ANALYTE CAS NO 

EBER L INE SER V ICES / RICHMOND 


METHOD BLANK 

Client/Case no Hanford 


Method Blank 

SDG H2194 

Client sample id Method Blank 

Material/Matrix SOLID 

SAF No F03-006 

RESULT 

pCi/g 

2a ERR 

(COUNT) 

MDA 

pCi/g 

RDL 

pCi/g 

QUALI- 

FIERS TEST 

Tritium 10028-17-8 -0.065 0.17 0.30 400 U H 

Carbon 14 14762-75-5 -0.216 1.8 3.0 50 U C 

Nickel 63 13981-37-8 -2.75 1.4 2.4 30 U NI_L 

Total Strontium SR-RAD 0.100 0.16 0.30 1.0 U SR 

Technetium 99 14133-76-7 0.127 0.18 0.54 15 U TC 

Thorium 228 14274-82-9 0.041 0.081 0.31 U TH 

Thorium 230 14269-63-7 0.162 0.16 0.31 1.0 U TH 

Thorium 232 TH-232 0 0.081 0.31 1.0 U TH 

Neptunium 237 13994-20-2 0.036 0.073 0.11 1.0 U NP 

Iodine 129 15046-84-1 0.294 0.70 1.6 2.0. U I 

200-PW-2/200-PW-4 OU-Borehole Soil 

QC-BLANK #44677 

METHOD BLANKS 

Page 1 


Page 9 

Lab id EBRLNE 



Form DVD-DS 

Version 3.06 




7507-007 Lab Control Sample 

LAB CONTROL SAMPLE 

SDG 7507 Client/Case no Hanford SDG H2194 



Client sample id Lab Control Sample 

Dept sample id 7507-007 Material/Matrix SOLID 

ANALYTE 

RESULT 

PCi/g 

20 ERR 

(COUNT) 

MDA 

pCi/g 

ROL 

pCi/g 

OUALI- 

FIERS TEST 

SAF No F03-006 

ADDED 

pCi/g 

20 ERR 

pCi/g 

REC 

% 

3a LMTS 

(TOTAL) 

PROTOCOL 

Triti um 12.4 0.43 0.30 400 H 13.0 0.52 95 84-116 80-120 

Carbon 14 1730 35 9.0 50 C 1950 78 89 85-115 80-120 

Nickel 63 215 4.7 2.9 30 NI-L 228 9.1 94 84-116 80-120 

Total Stronti um 18.4 0.87 0.32 1.0 SR 21.0 0.84 88 84-116 80-120 

Technetium 99 121 2.9 0.55 15 TC 109 4.4 111 82-118 80-120 

Thorium 230 36.9 3.9 0.28 1.0 TH 40.8 1.6 90 83-117 80-120 

Neptuni um 237 17.7 1.7 0.11 1.0 NP 19.9 0.80 89 84.116 80-120 

Iodine 129 248 2.5 2.6 2.0 1 232 9.3 107 83-117 80-120 


QC-LCS #44676 

Lab id EBRLNE 


LAB CONTROL SAMPLES Version Ver 1.0 

Page 1 Form DVD-LCS 


Page 10 Report date 06/17/03 

LIMITS

SDG 7507 

Contact Melissa C. Manion 

DUPLICATE 

Lab sample id R305013.09 


ANALYTE 

7507-009 

% solids 94.5 

DUPLICATE 

pCi/g 

20 ERR 

(COUNT) 


ORIGINAL 


Dept sample id 7507.004 

MDA 

pCi/g 


DUPLICATE 

Received 05/02/03 

% solids 94.5 

RDL 

pCi/g 

OUALI- 

HERS TEST 

Client/Case no Hanford SDG H2194 


Client sample id B16WB2 

B16WB2 

Location/Matrix 216-A-37 (C4106) SOLID 

Collected/Weight 04/29103 09:00 152.0 g 

Custody/SAF No F03-006-65 F03-006 

ORIGINAL 

pCi/g 

20 ERR 

(COUNT) 

Tritium 148 1.5 0.26 400 H 154 1.6 0.27 4 21 

MDA 

pCi/g 

OUALI- 

Carbon 14 -0.788 1.5 2.6 50 U C -0.093 1.7 2.8 U - 

Nickel 63 .11.3 1.7 2.5 30 NI-L 14.4 1.8 2.5 24 36 

Total Strontium -0.012 0.12 0.26 1.0 U SR -0.012 0.12 0.25 U - 

Technetium 99 0.160 0.19 0.55 15 U TC 0.170 0.18 0.52 U - 

Thoriun 228 0.531 0.31 0.29 TH 0.299 0.23 0.29 56 140 

Thori um 230 0.379 0.23 0.29 1.0 TH 0.299 0.23 0.29 24 144 

Thorium 232 0.265 0.23 0.29 1.0 U TH 0.411 0.23 0.29 43 145 

Neptunium 237 0 0.079 0.12 1.0 U NP 0.032 0.063 0.095 U - 

Iodine 129 -0.482 1.3 2.9 2.0 U 1 0.256 0.87 2.0 U - 


QC-DUP#4 44678 

HERS 

RPD 

% 

Lab id EBRLNE 

3o PROT 

TOT LIMIT 


DUPLICATES Version Ver 1.0 

Page 1 Form DVD-DUP 



7507-010 



MATRIX SPIRE 

B16W82 

SDG 7507 Client/Case no Hanford SDG H2194 


MATRIX SPIKE 

ORIGINAL 

Lab sample id R305013-10 Lab sample id R305013-04 Client sample id B16W82 

Dept sample id 7507-010 Dept sample id 7507-004 Location/Matrix 216-A-37 (C4106) SOLID 

Received 05/02/03 CoLlected/Weight 04/29103 09:00 152.0 c 

% solids 94.5 % solids 94.5 Custody/SAF No F03-006-65 F03-006 

SPIKE 2a ERR MDA RDL OUALI- ADDED 2a ERR ORIGINAL 2a ERR REC 3a LMTS PROTOCOL 

ANALYTE pCi/g (COUNT) pCi/g pCi/9 PIERS TEST pCi/g pCi/g pCi/g (COUNT) X (TOTAL) LIMITS 

Triti um 196 2.0 0.30 400 X H 50.1 2.0 154 1.6 84 25-175 60-140 

Nickel 63 855 17 5.8 30 NIL 916 37 14.4 1.8 92 84-116 60-140 


DC-MS#4 44679 

Lab id EBRLNE 


MATRIX SPIKES Version Ver 1.0 

Page 1 Form DVD-MS 



7507-001 



SDG 7507 





W solids 93.9 


DATA SHEET 

B16W79 



Client sample id B16W79 


Collected/Weight 04/28/03 13:50 149.0 Q 


RESULT 

pCi/g 

2a ERR 

(COUNT) 

MDA 

pCi/g 

RDL 

pCi/g 

QUALI- 

FIERS TEST 

Tritium 10028-17-8 134 1.4 0.26 400 H 

Carbon 14 14762-75-5 1.47 1.8 3.0 50 U C 

Nickel 63 13981-37-8 1.81 1.5 2.5 30 U NI _L 

Total Strontium SR-RAD 1.70 0.26 0.25 1.0 SR 


Thorium 228 14274-82-9 0.572 0.29 0.34 TH 

Thorium 230 14269-63-7 0.143 0.14 0.27 1.0 U TH 

Thorium 232 TH-232 0.393 0.22 0.27 1.0 TH 

Neptunium 237 13994-20-2 0.016 0.031 0.047 1.0 U NP 

Iodine 129 15046-84-1 0.221 0.81 1.8 2.0 U I 


Lab id EBRLNE 


DATA SHEETS Version Ver 1.0 

Page 1 Form DVD-DS 





7507-002 B16W80 

DATA SHEET 

SDG 7507 





% solids 95.3 






Collected/Weight 04/28/03 15:10 158.5 a 


RESULT 

pCi/g 

2a ERR 

(COUNT) 

MDA 

pCi/g 

RDL 

pCi/g 

QUALI- 

FIERS TEST 

Tritium 10028-17-8 152 1.5 0.27 400 H 

Carbon 14 14762-75-5 0.302 1.5 2.6 50 U C 

Nickel 63 13981-37-8 2.64 1.6 2.6 30 NI_L 

Total Strontium SR-RAD 0.001 0.12 0.25 1.0 U SR 


Thorium 228 14274-82-9 0.187 0.22 0.36 U TH 

Thorium 230 14269-63-7 0.075 0.15 0.29 1.0 U TH 

Thorium 232 TH-232 0.299 0.23 0.29 1.0 TH 

Neptunium 237 13994-20-2 0 0.080 0.12 1.0 U NP 

Iodine 129 15046-84-1 -0.047 0.92 2.1 2.0 U I 


Lab id EBRLNE 








7507-003 B16W81 

DATA SHEET 

SDG 7507 





8 solids 95.5 








RESULT 

pCi/g 

20 ERR 

(COUNT) 

MDA 

pCi/g 

RDL 

pCi/g 

QUALI- 

FIERS TEST 

Tritium 10028-17-8 130 1.3 0.26 400 H 

Carbon 14 14762-75-5 -0.315 1.8 3.0 50 U C 

Nickel 63 13981-37-8 2.05 1.5 2.5 30 U NI _L 

Total Strontium SR-RAD -0.019 0.15 0.32 1.0 U SR 


Thorium 228 14274-82-9 0.348 0.31 0.37 U TH 

Thorium 230 14269-63-7 0.464 0.31 0.37 1.0 TH 

Thorium 232 TH-232 0.541 0.31 0.30 1.0 TH 

Neptunium 237 13994-20-2 0.072 0.072 0.11 1.0 U NP 

Iodine 129 15046-84-1 -0.152 0.83 1.9 2.0 U I. 


Lab id EBRLNE 








7507-004 B16W82 

DATA SHEET 

SDG 7507 





% solids 94.5 








RESULT 

pCi/g 

20 ERR 

(COUNT) 

MDA 

pCi/g 

RDL 

pCi/g 

QUALI- 

FIERS TEST 

Tritium 10028-17-8 154 1.6 0.27 400 H 

Carbon 14 14762-75-5 -0.093 1.7 2.8 50 U C 

Nickel 63 13981-37-8 14.4 1.8 2.5 30 NI_L 



Thorium 228 14274-82-9 0.299 0.23 0.29 TH 

Thorium 230 14269-63-7 0.299 0.23 0.29 1.0 TH 

Thorium 232 TH-232 0.411 0.23 0.29 1.0 TH 

Neptunium 237 13994-20-2 0.032 0.063 0.095 1.0 U NP 

Iodine 129 15046-84-1 0.256 0.87 2.0 2.0 U I 


Lab id EBRLNE 






EBE RLIN E SE RVIC ES /RICHMOND 


7507-005 B16W83 

DATA SHEET 

SDG 7507 





+k solids 94.3 








RESULT 

PCi/g 

2v ERR 

(COUNT) 

MDA 

pCi/g 

RDL 

pCi/g 

QUALI- 

FIERS TEST 

Tritium 10028-17-8 267 2.7 0.37 400 H 

Carbon 14 14762-75-5 -0.493 1.7 2.9 50 U C 

Nickel 63 13981-37-8 1.34 1.5 2.5 30 U NI _L 



Thorium 228 14274-82-9 0.376 0.23 0.29 TH 

Thorium 230 14269-63-7 0.300 0.23 0.29 1.0 TH 

Thorium 232 TH-232 0.376 0.23 0.29 1.0 TH 

Neptunium 237 13994-20-2 0 0.085 0.13 1.0 U NP 

Iodine 129 15046-84-1 -0.130 1.0 2.3 2.0 U I 


Lab id EBRLNE 








7507-006 B16W90 

DATA SHEET 

SDG 7507 





% solids 95.9 








RESULT 

pCi/g 

20 ERR 

(COUNT) 

MDA 

pci/g 

RDL 

pci/g 

QUALI- 

PIERS TEST 

Tritium 10028-17-8 147 1.5 0.27 400 H 

Carbon 14 14762-75-5 0.926 1.6 2.7 50 U C 

Nickel 63 13981-37-8 1.17 1.6 2.6 30 U NI _L 



Thorium 228 14274-82-9 0.307 0.23 0.29 TH 

Thorium 230 14269-63-7 0.268 0.23 0.29 1.0 U TH 

Thorium 232 TH-232 0.307 0.23 0.29 1.0 TH 

Neptunium 237 13994-20-2 0.040 0.079 0.12 1.0 U NP 

Iodine 129 15046-84-1 -0.070 2.0 4.4 2.0 U I 


Lab id EBRLNE 








Test NP Matrix SOLID Client Hanford 

SDG 7507 LAB METHOD SUMMARY Contract No. 630 

Contact Melissa C. Mannion NEPTUNIUM IN SOIL Contract SDG H2194 

RESULTS 

ALPHA SPECTROSCOPY 

t.as RAW SUF- Neptunium 

SAMPLE ID TEST FIX PLANCHET CLIENT SAMPLE ID 237 

Preparation batch 7060-151 

R305013-01 7507-001 B16W79 U 

R305013-02 7507-002 B16W80 U 

R305013-03 7507-003 B16W81 U 

R305013-04 7507-004 B16W82 U 

R305013-05 7507-005 816W83 U 

R305013-06 7507-006 B16W90 U 

R305013-07 7507-007 LCS (OC ID=44676) ok 

R305013-08 7507-008 BLK (OC ID=44677) U 

R305013-09 7507-009 Duplicate (R305013-04) - U 

Nominal values and limits from method RDLS Wi /g) 1.0 


METHOD PERFORMANCE 

tae RAW SUF- MDA ALIQ PREP DILU- YIELD EFF COUNT FWHM DRIFT DAYS ANAL- 

SAMPLE ID TEST FIX CLIENT SAMPLE ID pCi/g g FAC TION % % min keV KeV HELD PREPARED YZED DETECTOR 

Preparation batch 7060-151 20 prep error 5.0 % Reference Lab Notebook 7060 pg. 151 

R305013-01 B16W79 0.047 0.500 73 233 42 06/06/03 06109 SS-040 

R305013-02 B16W80 0.12 0.500 63 102 39 06/06/03 06/06 SS-010 

R305013-03 B16W81 0.11 0.500 75 102 38 06/06/03 06/06 SS-011 

R305013-04 B16W82 0.095 0.500 82 103 38 06/06/03 06/06 SS-015 

R305013-05 B16W83 0.13 0.500 63 103 38 06/06/03 06/06 SS-016 

R305013-06 B16W90 0.12 0.500 68 102 39 06/06/03 06/06 SS-039 

R305013-07 LCS (OC ID=44676) 0.11 0.500 71 103 06/06/03 06/06 SS-040 

R305013-08 BLK (OC ID=44677) 0.11 0.500 71 103 06/06/03 06/06 SS-041 

R305013-09 Duplicate (R305013-04) 0.12 0.500 65 103 38 06/06/03 06/06 SS-042 

(QC ID=44678) 

Nominal values and limits from method 1.0 0.500 20-105 100 180 


Page 1 


Page 19 

Lab id EBRLNE 



Form DVD-LMS 

Version 3.06 


Test NP Matrix SOLID 

SDG 7507 


PROCEDURES REFERENCE NP237_LLE_PLATE_AEA 

CP-060 Soil Preparation, rev 4 



LAB METHOD SUMMARY, cont. 

CP-071 Soil Dissolution, > 1.0g Aliquot, rev 2 

NEPTUNIUM IN SOIL 


CP-930 Neptunium from Solids and Water by Extraction 

Chromatography, rev 0 

CP-008 Heavy Element ElectropLating, rev 7 



Contract SIG H2194 

AVERAGES t 2 SD MDA 0.11 t 0.049 

FOR 9 SAMPLES YIELD 70 t 12 

Lab id EBRLNE 


METHOD SUMMARIES Version Ver 1.0 

Page 2 Form DVD-LMS 



Test TH Matrix SOLID 

SDG 7507 


RESULTS 

WLB 

RAW SUF- 



LAB METHOD SUMMARY 

THORIUM, ISOTOPIC IN SOIL 


SAMPLE ID TEST FIX PLANCHET CLIENT SAMPLE ID Thorium 230 


R305013-01 7507-001 

R305013-02 7507-002 

R305013-03 

7507-003 

R305013-04 7507-004 

R305013-05 7507-005 

R305013-06 7507-006 

R305013-07 7507-007 

R305013-08 7507-008 

R305013-09 7507-009 

816W79 U 

B16W80 U 

B 16W81 0.464 

B16W82 0.299 

B16W83 0.300 

B 16W90 U 

LCS (OC ID=44676) ok 

BILK (QC ID=44677) U 

Duplicate (R305013-04) ok 

Nominal values and limits from method RDLs (pCi/g) 1.0 

200-PW-2/200-PW-4 OI-Borehole Soil 




Contract SOO H2194 

I" RAW SUF- NAX MDA ALID PREP DILU- YIELD EFF COUNT FWHM DRIFT DAYS ANAL- 



R305013-01 B16W79 0.27 0.250 102 152 37 06/04/03 06/04 SS-039 

R305013-02 B16W80 0.29 0.250 95 152 37 06/04/03 06/04 SS-040 

R305013-03 B16W81 0.37 0.250 90 152 36 06/04/03 06/04 SS-041 

R305013-04 B16W82 0.29 0.250 93 152 36 06/04/03 06/04 SS-042 

R305013-05 B16W83 0.29 0.250 90 152 36 06/04/03 06/04 SS-043 

R305013-06 B16W90 0.29 0.250 84 152 37 06/04/03 06/04 SS-044 

R305013-07 LCS (DC ID=44676) 0.28 0.250 96 152 06/04/03 06/04 SS-047 

R305013-08 BLK (DC ID=44677) 0.31 0.250 85 153 06/04/03 D6/04 SS-G48 

R305013-09 Duplicate (R305013-04) 0.29 0.250 104 153 36 06/04/03 06/04 SS-049 

(QC ID=44678) 


Lab id EBRLNE 






Test TH Matrix SOLID 



SIG 7507 LAB METHOD SUMMARY, cont. 

Contact Melissa C. Mannion THORIUM, ISOTOPIC IN SOIL 

PROCEDURES REFERENCE THISO_IE_ PLATE _AEA 


CP-071 Soil Dissolution, > 1.Og Aliquot, rev 2 


CP-900 Thorium in Water and Dissolved Solid Samples by 

Extraction Chromatography, rev 1 

CP-008 Heavy Element Electroplating, rev 7 



Contract SDG H2194 


FOR 9 SAMPLES YIELD 93 x 14 

Lab id EBRLNE 








Test SR Matrix SOLID Client Hanford 


Contact Melissa C. Mannion TOTAL STRONTIUM IN SOIL Contract SDG H2194 

RESULTS 

BETA COUNTING 

LAB RAW SUF- Total 

SAMPLE ID TEST FIX PLANCHET CLIENT SAMPLE ID Strontium 


R305013-01 7507-001 816W79 1.70 

R305013-02 7507-002 B16W80 U 

8305013-03 7507-003 B16W81 U 

R305013-04 7507-004 816W82 U 

R305013-05 7507-005 B16W83 U 

R305013-06 7507-006 B16W90 U 

R305013-07 7507-007 LCS (DC ID=44676) ok 

R305013-08 7507-008 BLK (QC ID=44677) U 

R305013-09 7507-009 Duplicate (R305013-04) - U 

Nominal Values and limits from method RDLs (pCi/g) 1.0 

200-PW-2/200-PW-4 OU-BOreho Le Soil 


Lisa RAW SUF- MDA ALID PREP DILU- YIELD EFF COUNT FWHM DRIFT DAYS ANAL- 


Preparation batch 7060-151 2a prep error 10.0 % Reference Lab Notebook 7060 pg. 151 

8305013-01 B16W79 0.25 1.00 95 102 30 05/28/03 05/28 GRB-217 

R305013-02 B16W80 0.25 1.00 96 102 30 05/28/03 05/28 GRB-218 

R305013-03 816W81 0.32 1.00 78 102 29 05/28/03 05/28 GRB-219 

R305013-04 B16W82 0.25 1.00 95 102 29 05/28/03 05/28 GRB-220 

R305013-05 B16W83 0.27 1.00 91 102 29 05/28/03 05/28 GRB-221 

R305013-06 B16W90 0.25 1.00 98 102 30 05/28/03 05/28 GRB-222 

R305013-07 LCS (QC ID=44676) 0.32 1.00 78 102 05/28/03 05/28 GRB-223 

R305013-08 BLK (QC ID =44677) 0.30 1.00 81 102 05/28/03 05/28 GRB-224 

8305013-D9 Duplicate (R305013-04) 0.26 1.00 98 100 29 05/28/03 05/28 GRB-232 

(OC ID=44678) 


Lab id EBRLNE 




SL94MARY DATA SECTION Version 3.06 




Test SR Matrix SOLID 

SDG7507 LAB METHOD SUMMARY, cont. 

Contact Melissa C. Manion TOTAL STRONTIUM IN SOIL 

BETA COUNTING 




PROCEDURES REFERENCE SRTOT_SEP_PRECIP_GPC AVERAGES t 2 SD MDA 0.27 t0.061 

CP-060 Soil Preparation, rev 4 FOR 9 SAMPLES YIELD 90 t 17 

CP-071 Soil Dissolution, > 1.09 Aliquot, rev 2 

CP-381 Strontium in Solids, rev 1 

Lab id EBRLNE 








Test TC Matrix SOLID Client Hanford 


Contact Melissa C. Mannion TECHNETIUM 99 IN SOIL Contract SDG H2194 

RESULTS 

BETA COUNTING 

LAB RAW SUF- Technetium 

SAMPLE ID TEST FIX PLANCHET CLIENT SAMPLE ID 99 


R305013-01 7507-001 B16W79 U 

R305013-02 7507-002 B16W80 U 

R305013-03 7507-003 B16W81 U 

R305013-04 7507-004 816W82 U 

R305013-05 7507-005 816W83 U 

R305013-06 7507-006 B16W90 U 

R305013-07 7507-007 LCS (QC ID=44676) ok 

R305013-08 7507-008 BLK (GC ID=44677) U 

R305013-09 7507-009 Duplicate (R305013-04) - U 

Nominal values and limits from method RDLs (pCi/9) 15 

200-PW-2/200-PW-4 OU-Boreho Le Soil 


LAa RAW SUF- MDA ALIO PREP DILU- YIELD EFF COUNT F11HM DRIFT DAYS ANAL- 

SAMPLE ID TEST FIX CLIENT SAMPLE ID pCi/g g FAC TION X % min keV KeV HELD PREPARED YZED DETECTOR 


R305013-01 B16W79 0.55 1.02 90 50 49 06/12/03 06/16 GRB-217 

R305013-02 B16W80 0.55 1.03 89 50 49 06/12/03 06/16 GRB-218 

R305013-03 B16W81 0.57 1.02 87 50 47 06/12/03 06/15 GRB-203 

R305013-04 816W82 0.52 1.05 89 50 48 06/12/03 06/16 GRB-220 

R305013-05 B16W83 0.59 1.02 86 50 48 06/12/03 06/16 GRB-221 

R305013-06 B16W90 0.60 1.02 82 50 49 06/12/03 06/16 GRB-222 

R305013-07 LCS (QC ID=44676) 0.55 1.00 93 50 06/12/03 06/15 GRB-203 

R305013-08 BLK (QC ID=44677) 0.54 1.00 97 50 06/12/03 06/16 GRB-223 

R305013-09 Duplicate (R305013-04) 0.55 1.05 84 56 47 06/12/03 06/15 GRB-221 

(OC ID=44678) 

NominaL values and Limits from method 15 1.00 20-105 50 180 

Lab id EBRLNE 








Test TC Matrix SOLID 


Contact Melissa C. Mannion TECHNETIUM 99 IN SOIL 

PROCEDURES REFERENCE TC99_TR_SEP_LSC 

CP-071 Soil Dissolution, > 1.Og Aliquot, rev 2 

CP-021 Preparation of Tc-99m Tracer, rev 2 

CP-002 O.C. Preparation, rev 4 

CP-003 Addition of Carriers and Tracers, rev 5 

BETA COUNTING 

CP-542 Technetium-99 Purification (Soil) by Extraction 


CP-008 Heavy Element Electroplating,. rev 7 




AVERAGES t 2 SO MDA 0.56 t 0.050 

FOR 9 SAMPLES YIELD 89 1 9 

Lab id EBRLNE 






Test 1 Matrix SOLID 

SDG 7507 


RESULTS 

L" RAW SUF- 




IODINE 129 IN SOIL 

GAMMA SPECTROSCOPY 

SAMPLE ID TEST FIX PLANCHET CLIENT SAMPLE ID Iodine 129 


R305013-01 7507-001 B16W79 U 

R305013-02 7507-002 B16W80 U 

R305013-03 7507-003 B16W81 U 

R305013-04 7507-004 B16W82 U 

R305013-05 7507-005 B16W83 U 

R305013-06 7507-006 B16W90 U 

R305013-07 7507-007 LCS (GC ID=44676) ok 

R305013-08 7507-008 BLK (GC 10=44677) U 

R305013-09 7507-009 Duplicate (R305013-04) - U 

Nominal values and limits from method RDLS (pCi/g) 2.0 

200-PW-2/200-PW-4 OU-Boreho Le Soil. 





LAB RAW SUF- MDA ALIG PREP DILU- YIELD EFF COUNT FWHM DRIFT DAYS ANAL- 

SAMPLE ID TEST FIX CLIENT SAMPLE ID pCi/g 9 FAC TION % % min keV KeV HELD PREPARED YZED DETECTOR 


R305013-01 B16W79 1.8 0.500 65 932 37 06/04/03 06/04 XSPEC-004 

R305013-02 B16W80 2.1 0.500 58 1023 38 06/04/03 06/05 XSPEC-004 

R3050i3-03 B16W81 1.9 0.510 56 1394 38 06/04/03 06/06 XSPEC-004 

R305013-04 816W82 2.0 0.500 53 1436 39 06/04/03 06/07 XSPEC-004 

R305013-05 816W83 2.3 0.500 51 1137 40 06/04/03 06/08 XSPEC-004 

R305013-06 B166190 4.4 0.500 36 616 43 06/04/03 06/10 XSPEC-004 

R305013-07 LCS (GC ID=44676) 2.6 0.500 89 807 06/04/03 06/10 XSPEC-004 

R305013-08 BLK (GC ID=44677) 1.6 0.500 85 625 06/04/03 06/11 XSPEC-004 

R305013-09 Duplicate (R305013-04) 2.9 0.500 55 669 43 06/04/03 06/11 XSPEC-004 

(GC ID=44678) 



Page 9 


Page 27 

Lab id EBRLNE 



Form DVD-LMS 

Version 3.06 

Report date 06117/03



Test I Matrix SOLID 


Contact Melissa C. Mannion IODINE 129 IN SOIL 

PROCEDURES REFERENCE 1129_SEP_LEPS_GS 

CP-024 Iodine-129, Semple Dissotution, rev 3 

CP-530 Iodine-129 Purification, rev 0 

GAMMA SPECTROSCOPY 






Lab id EBRLNE 








Test C Matrix SOLID 

SDG 7507 LAB METHOD SUMMARY 

Contact Melissa C. Manion CARBON 14 IN SOIL 

RESULTS 

LAS RAW SUF- 

LIQUID SCINTILLATION COUNTING 

SAMPLE ID TEST FIX PLANCHET CLIENT SAMPLE ID Carbon 14 


R305013-01 7507-001 

R305013-02 7507-002 

8305013-03 7507-003 

R305013-04 

7507-004 

8305013-05 7507-005 

R305013-06 7507-006 

R305013-07 

7507-007 

R305Oi3-08 7507-008 

R305013-09 7507-009 

B16W79 

B16W80 U 

B 16W81 U 

B16W82 U 

B16W83 

B 16W90 

LCS (QC ID=44676) ok 

ELK (OC ID=44677) U 

Duplicate (R305013-04) - U 

Nominal values and limits from method RDLs (pCi/g) 50 

200-PW-2/200-PW-4 OU-BorehoLe Soil 


U 

U 

U 




1,A9 RAW SUF- MDA ALIQ PREP DILU- YIELD EFF COUNT FWHM DRIFT DAYS ANAL- 



R305013-01 B16W79 3.0 0.328 100 100 30 05/28/03 05/28 LSC-004 

R305013-02 816W80 2.6 0.380 100 100 30 05/28/03 05/28 LSC-004 

R305013-03 B16W81 3.0 0.331 100 100 29 05/28/03 05/28 LSC-004 

R305013-04 B16W82 2.8 0.350 100 100 29 05/28/03 05/28 LSC-004 

R305013-05 B16W83 2.9 0.341 100 100 30 05/28/03 05/29 LSC-004 

R305013-06 B16W90 2.7 0.374 100 100 31 05/28/03 05129 LSC-004 

R305013-07 LCS (QC ID=44676) 9.0 0.328 100 10 05/28/03 05129 LSC-004 

R305013-08 BLK (OC. ID =44677) 3.0 0.328 100 100 05/28/03 05/28 LSC-004 

R305013-09 Duplicate (R305013-04) 2.6 0.386 100 100 30 05/28/03 05/29 LSC-004 

(QC ID=44678) 

Nominal values and limits from method 50 0.328 50 180 

Lab id EBRLNE 






Test C Matrix SOLID 

SDG 7507 


PROCEDURES REFERENCE C14_COX_LSC 

CP-251 Tritium/Carbon-14 Oxidation, rev 5 



LAB METHOD SUMMARY, cont 

CARBON 14 IN SOIL 





AVERAGES t 2 SO MDA 3.5 t 4.1 


Lab id EBRLNE 








Test H Matrix SOLID Client Hanford 


Contact Melissa C. Mannion TRITIUM IN SOIL Contract SDG H2194 

RESULTS 

taa RAW SUF- 


SAMPLE ID TEST FIX PLANCHET CLIENT SAMPLE ID Tritium 


R305013-01 7507-001 B16W79 134 

R305013-02 7507-002 816W80 152 

R305013-03 7507-003 816W81 130 

R305013-04 7507-004 B16W82 154 

R305013-05 7507-005 B16W83 267 

R305013-06 7507-006 B16W90 147 

R305013-07 7507-007 LCS (QC ID=44676) ok 

R305013-08 7507-008 BLK (QC ID=44677) U 

R305013-09 7507-009 Duplicate (R305013-04) ok 

R305013-10 7507-010 Spike (R305013-04) ok X 

NomimL values and limits from method RDLS (pCi/g) 400 

200-PW-2/200-PW-4 OU-BOreho Le Soil 


tam RAW SUF- MDA ALIQ PREP DILU- YIELD EFF COUNT FWHM DRIFT DAYS ANAL- 


Preparation batch 7060-151 2a prep error 10.0 % Reference Lab Notebook 7060 pg. 151 

R305013-01 B16W79 0.26 20.9 50 73 43 06/10/03 06/10 LSC-005 

R305013-02 B16W80 0.27 21.4 48 65 44 06/10/03 06/11 LSC-005 

R305013-03 816W81 0.26 20.9 46 80 43 06/10/03 06/11 LSC-005 

R305013-04 B16W82 0.27 20.2 50 62 43 06/10/03 06/11 LSC-005 

R305013-05 B16W83 0.37 20.7 49 38 43 06/10/03 06/11 LSC-005 

R305013-06 816W90 0.27 21.0 49 69 44 06/10/03 06/11 LSC-005 

R305013-07 LCS (QC ID=44676) 0.30 20.0 33 120 06/10/03 06/11 LSC-005 

R305013-08 BLK (OC ID=44677) 0.30 20.0 33 120 06/10/03 06/11 LSC-005 

R305013-09 Duplicate (R305013-04) 0.26 21.3 53 60 43 06/10/03 06/11 LSC-005 

(QC ID=44678) 

R305013-10 Spike (R305013-04) 0.30 20.8 53 46 43 06/10/03 06/11 LSC-005 

(OC ID=44679) 

Nominal values and limits from method 400 20.0 25 180 

Lab id EBRLNE 






Test H Matrix SOLID 

SDG 7507 


PROCEDURES REFERENCE 906.0_H3 LSC 

CP-216 Tritium in Solid Samples by Azeotropic 

Distillation, rev 6 




TRITIUM IN SOIL 





AVERAGES t 2 SD MDA 0.29 3 0.068 


Lab id EBRLNE 






Test NI L Matrix SOLID 

SDG 7507 


RESULTS 

LAB RAW SUF- 




NICKEL 63 IN SOIL 


SAMPLE ID TEST FIX PLANCHET CLIENT SAMPLE ID Nickel 63 


8305013-01 7507-001 B16W79 U 

R305013-02 7507-002 816W80 2.64 

R305013-03 7507-003 816W81 U 

R305013-04 7507-004 B16W82 14.4 

R305013-05 7507-005 B16W83 U 

R305013-06 7507-006 B16W90 U 

R305013-07 7507-007 LCS (QC ID=44676) ok 

R305013-08 7507-008 BLK (QC ID =44677) U 

R305013-09 7507-009 Duplicate (R305013-04) ok 

R305013-10 7507-010 Spike (R305013-04) ok 

Nominal values and limits from method RDLS (pCi/g) 30 






LAB RAW SUF- MDA ALIQ PREP DILU- YIELD EFF COUNT FWHN DRIFT DAYS ANAL- 

SAMPLE ID TEST FIX CLIENT SAMPLE ID pCi/g 9 FAC TION X X min keV KeV HELD PREPARED YZED DETECTOR 

Preparation batch 7060-151 20 prep error 10.0 X Reference Lab Notebook 7060 pg. 151 

R305013-01 B16W79 2.5 0.500 100 100 

8305013-02 516WBO 2.6 0.500 100 100 

R305013-03 B16W81 2.5 0.500 100 100 

R305013-04 B16W82 2.5 0.500 100 100 

R305013-05 B16W83 2.5 0.500 100 100 

R305013-06 B16W90 2.6 0.500 100 100 

R305013-07 LCS (QC ID = 44676) 2.9 0.500 100 69 

R305013-08 SLK (QC ID=44677) 2.4 0.500 100 100 

R305013-09 Duplicate (R305013-04) 2.5 0.500 100 100 

(QC ID=44678) 

R305013-10 Spike (R305013-04) 5.8 0.500 100 18 

(QC ID=44679) 

Nominal values and limits from method 30 0.500 30-105 50 180 

33 05/30/03 05/31 LSC-004 

33 05/30/03 05/31 LSC-004 

32 05/30/03 05/31 LSC-004 

32 05/30/03 05/31 LSC-004 

32 05/30/03 05/31 LSC-004 

33 05/30/03 05/31 LSC-004 

05/30/03 05/31 LSC-004 

05/30/03 05/31 LSC-004 

32 05/30/03 05/31 LSC-004 

32 05/30/03 05/31 LSC-004 

Lab id EBRLNE 






Test NI L Matrix SOLID 

SDG 7507 


PROCEDURES REFERENCE N163_LSC 





CP-071 Soil Dissolution, > 1.09 Aliquot, rev 2 

CP-281 Nickel-63 Purification By Extraction 


NICKEL 63 IN SOIL 






FOR 10 SAMPLES YIELD 100 i 0 

Lab id EBRLNE 






SDG 7507 






SAMPLE SUMMARY 

The Sample and QC Summary Reports show all samples, including QC 

samples, reported in one Sample Delivery Group (SDG). 

The Sample Summary Report fully identifies client samples and gives the 

corresponding lab sample identification. The QC Summary Report shows at 

the sample level how the lab organized the samples into batches and 

generated QC samples. The Preparation Batch and Method Summary Reports 

show this at the analysis level. 

The following notes apply to these reports: 

• LAB SAMPLE ID is the lab's primary identification for a sample. 

• DEPARTMENT SAMPLE ID is an alternate lab id, for example one 

assigned by a radiochemistry department in a lab. 

• CLIENT SAMPLE ID is the client's primary identification for a 

sample. It includes any sample preparation done by the client 

that is necessary to identify the sample. 

• QC BATCH is a lab assigned code that groups samples to be 

processed and QCed together. These samples should have similar 

matrices. 

QC BATCH is not necessarily the same as SDG, which reflects 

samples received and reported together. 

* All Lab Control Samples, Method Blanks, Duplicates and Matrix 

Spikes are shown that QC any of the samples. Due to possible 

reanalyses, not all results for all these QC samples may be 

relevant to the SDG. The Lab Control Sample, Method Blank, 

Duplicate, Matrix Spike and Method Summary Reports detail these 

relationships. 

Lab id EBRLNE 


REPORT GUIDES Version Ver 1.0 

Page 1 Form DVD-RG 






FCont Melissa C. Mannion R E P O R T G U I D E Contract No. 630 


PREPARATION BATCH SUMMARY 

The Preparation Batch Summary Report shows all preparation batches in 

one Sample Delivery Group (SDG) with information necessary to check the 

completeness and consistency of the SDG. 

The following notes apply to this report: 

• The preparation batches are shown in the same order as the 

Method Summary Reports are printed. 

• Only analyses of planchets relevant to the SDG are included. 

• Each preparation batch should have at least one Method Blank 

and LCS in it to validate client sample results. 

The QUALIFIERS shown are all qualifiers other than U, J, B, L 

and H that occur on any analysis in the preparation batch. The 

Method Summary Report has these qualifiers on a per sample 

basis. 

These qualifiers should be reviewed as follows: 

X Some data has been manually entered or modified. 

Transcription errors are possible. 

P One or more results are 'preliminary'. The data is not 

ready for final reporting. 

2 There were two or more results for one analyte on one 

planchet imported at one time. The results in DVD may 

not be the same as on the raw data sheets. 

Other lab defined qualifiers may occur. In general, these 

should be addressed in the SDG narrative. 

Lab id EBRLNE 






SDG 7507 




[Contact Melissa C. Mannion R E P O R T G U I D E Contract No. 630 


WORK SUMMARY 

The Work Summary Report shows all samples, including QC samples, and all 

relevant analyses in one Sample Delivery Group (SDG). This report is 

often useful as supporting documentation for an invoice. 


* TEST is a code for the method used to measure associated 

analytes. Results and related information for each analyte 

are on the Data Sheet Report. In special cases, a test code 

used in the summary data section is not the same as in 

associated raw data. In this case, both codes are shown on the 

Work Summary. 

* SUFFIX is the lab's code to distinguish multiple analyses 

(recounts, reworks, reanalyses) of a fraction of the sample. 

The suffix indicates which result is being reported. An empty 

suffix normally identifies the first attempt to analyze the 

sample. 

* The LAB SAMPLE ID, TEST and SUFFIX uniquely identify all 

supporting data for a result. The Method Summary Report for 

each TEST has method performance data, such as yield, for each 

lab sample id and suffix and procedures used in the method. 

* PLANCHET is an alternate lab identifier for work done for one 

test. It, combined with the TEST and SUFFIX, may be the best 

link to raw data. 

* For QC samples, only analyses that directly QC some regular 

sample are shown. The Lab Control Sample, Method Blank, 

Duplicate, Matrix Spike and Method Summary Reports detail these 

relationships. 

* The SAS (Special Analytical Services) Number is a client or lab 

assigned code that reflects special processing for samples, such 

as rapid turn around. Counts of tests done are lists by SAS 

number since it is likely to affect prices. 

Lab id EBRLNE 











DATA SHEET 

The Data Sheet Report shows all results and primary supporting 

information for one client sample or Method Blank. This report 

corresponds to both the CLP Inorganics and Organics Data Sheet. 


* TEST is a code for the method used to measure an analyte. If 

the TEST is empty, no data is available; the analyte was not 

analyzed for. 

* The LAB SAMPLE ID and TEST uniquely identify work within the 

Summary Data Section of a Data Package. The Work Summary and 

Method Summary Reports further identify raw data that underlies 

this work. 

The Method Summary Report for each TEST has method performance 

data, such as yield, for each Lab Sample ID and a list of 

procedures used in the method. 

* ERRORS can be labeled TOTAL or COUNT. TOTAL implies a 

preparation (non-counting method) error has been added, as 

square root of sum of squares, to the counting error denoted by 

COUNT. The preparation errors, which may vary by preparation 

batch, are shown on the Method Summary Report. 

* A RESULT can be 'N.R.' (Not Reported). This means the lab did 

this work but chooses not to report it now, possibly because it 

was reported at another time. 

* When reporting a Method Blank, a RESULT can be -N.A.- (Not 

Applicable). This means there is no reported client sample work 

in the same preparation batch as the Blank's result. This is 

likely to occur when the Method Blank is associated with 

reanalyses of selected work for a few samples in the SDG. 

The following qualifiers are defined by the DVD system: 

U The RESULT is less than the MDA (Minimum Detectable Activity). 

Lab id EBRLNE 









Contact Melissa C. Mannion G U I D E c u n t Contract No. 630 


DATA SHEET 

If the MDA is blank, the ERROR is used as the limit. 

J The RESULT is less than the RDL (Required Detection Limit) and 

no U qualifier is assigned. 

B A Method Blank associated with this sample had a result without 

a U flag and, after correcting for possibly different aliquots, 

that result is greater than or equal to the MDA for this sample. 

Normally, B is not assigned if U is. When method blank 

subtraction is shown on this report, B flags are assigned based 

on the unsubtracted values while U's are assigned based on the 

subtracted ones. Both flags can be assigned in this case. 

For each sample result, all Method Blank results in the same 

preparation batch are compared. The Method Summary Report 

documents this and other QC relationships. 

L Some Lab Control Sample that QC's this sample had a low 

recovery. The lab can disable assignment of this qualifier. 

H Similar to 'L' except the recovery was high. 

P The RESULT is 'preliminary'. 

X Some data necessary to compute the RESULT, ERROR or MDA was 

manually entered or modified. 

2 There were two or more results available for this analyte. The 

reported result may not be the same as in the raw data. 

Other qualifiers are lab defined. Definitions should be in the 

SDG narrative. 

The following values are underlined to indicate possible problems: 

* An MDA is underlined if it is bigger than its RDL. 

Lab id EBRLNE 











DATA SHEET 

* An ERROR is underlined if the 1.645 sigma counting error is 

bigger than both the MDA and the RESULT, implying that the MDA 

may not be a good estimate of the 'real' minimum detectable 

activity. 

* A negative RESULT is underlined if it is less than the negative 

of its 2 sigma counting ERROR. 

* When reporting a Method Blank, a RESULT is underlined if 

greater than its MDA. If the MDA is blank, the 2 sigma counting 

error is used in the comparison. 

Lab id EBRLNE 




SUMNARY DATA SECTION Version 3.06 


SDG7507 






LAB CO N TROL SAMPL E 

The Lab Control Sample Report shows all results, recoveries and primary 

supporting information for one Lab Control Sample. 


• All fields in common with the Data Sheet Report have similar 

usage. Refer to its Report Guide for details. 

• An amount ADDED is the lab's value for the actual amount spiked 

into this sample with its ERROR an estimate of the error of this 

amount. 

An amount added is underlined if its ratio to the corresponding 

RDL is outside protocol specified limits. 

* REC (Recovery) is RESULT divided by ADDED expressed as a 

percent. 

* The first, computed limits for the recovery reflect: 

1. The error of RESULT, including that introduced by 

rounding the result prior to printing. 

If the limits are labeled (TOTAL), they include 

preparation error in the result. If labeled (COUNT), 

they do not. 

2. The error of ADDED. 

3. A lab specified, per analyte bias. The bias changes the 

center of the computed limits. 

* The second limits are protocol defined upper and lower QC limits 

for the recovery. 

* The recovery is underlined if it is outside either of these 

ranges. 

Lab id EBRLNE 






SDG 7507 



1Client Hanford 



DUPLICATE 

The Duplicate Report shows all results, differences and primary 

supporting information for one Duplicate and associated Original sample. 


* All fields in common with the Data Sheet Report have similar 

usage. This applies both to the Duplicate and Original sample 

data. Refer to the Data Sheet Report Guide for details. 

If the Duplicate has data for a TEST and the lab did not do this 

test to the Original, the Original's RESULTS are underlined. 

* The RPD (Relative Percent Difference) is the absolute value of 

the difference of the RESULTS divided by their average expressed 

as a percent. 

If both RESULTS are less than their MDAs, no RPD is computed and 

a '-' is printed. 

For an analyte, if the lab did work for both samples but has 

data for only one, the MDA from the sample with data is used as 

the other's result in the RPD. 

* The first, computed limit is the sum, as square root of sum of 

squares, of the errors of the results divided by the average 

result as a percent, hence the relative error of the difference 

rather than the error of the relative difference. The errors 

include those introduced by rounding the RESULTS prior to 

printing. 

If this limit is labeled TOT, it includes the preparation error 

in the RESULTS. If labeled CNT, it does not. 

This value reported for this limit is at most 999. 

* The second limit for the RPD is the larger of: 

1. A fixed percentage specified in the protocol. 

Lab id EBRLNE 











DUPLICATE 

2. A protocol factor (typically 2) times the average MDA as 

a percent of the average result. This limit applies 

when the results are close to the MDAs. 

* The RPD is underlined if it is greater than either limit. 

* If specified by the lab, the second limit column is replaced by 

the Difference Error Ratio (DER), which is the absolute value 

of the difference of the results divided by the quadratic sum of 

their one sigma errors, the same errors as used in the first 

limit. 

Except for differences due to rounding, the DER is the 

same as the RPD divided by the first RPD limit with the 

limit scaled to 1 sigma. 

* The DER is underlined if it is greater than the sigma factor, 

typically 2 or 3, shown in the header for the first RPD limit. 

Lab id EBRLNE 






E BERLIN E SERVICES/RICHMOND 





MATRIX SPIKE 

The Matrix Spike Report shows all results, recoveries and primary 

supporting information for one Matrix Spike and associated Original 

sample. 


* All fields in common with the Data Sheet Report have similar 

usage. This applies both to the Spiked and Original sample 

data. Refer to the Data Sheet Report Guide for details. 

If the Spike has data for a TEST and the lab did not do this 

test to the Original, the Originals RESULTS are underlined. 

* An amount ADDED is the lab's value for the actual amount spiked 

into the Spike sample with its ERROR an estimate of the error of 

this amount. 

An amount is underlined if its ratio to the corresponding RDL is 

outside protocol specified limits. 

* REC (Recovery) is the Spike RESULT minus the Original RESULT 

divided by ADDED expressed as a percent. 

* The first, computed limits for the recovery reflect: 

1. The errors of the two RESULTS, including those 

introduced by rounding them prior to printing. 

If the limits are labeled (TOTAL), they include 

preparation error in the result. If labeled (COUNT), 

they do not. 

2. The error of ADDED. 

3. A lab specified, per analyte bias. The bias changes the 

center of the computed limits. 

* The second limits are protocol defined upper and lower QC limits 

Lab id EBRLNE 






EBERLINE SERVI CES /RI CHMOND 





for the recovery. 

MATRIX SPIKE 

These limits are left blank if the Original RESULT is more than 

a protocol defined factor (typically 4) times ADDED. This is a 

way of accounting for that when the spike is small compared to 

the amount in the original sample, the recovery is unreliable. 

+ The recovery is underlined (out of spec) if it is outside either 

of these ranges. 

Lab id EBRLNE 






SDG 7507 






METHOD SUMMARY 

The Method Summary Report has two tables. One shows up to five results 

measured using one method. The other has performance data for the 

method. There is one report for each TEST, as used on the Data Sheet 

Report. 


* Each table is subdivided into sections, one for each preparation 

batch. A preparation batch is a group of aliquots prepared at 

roughly the same time in one work area of the lab using the same 

method. 

There should be Lab Control Sample and Method Blank results in 

each preparation batch since this close correspondence makes the 

QC meaningful. Depending on lab policy, Duplicates need not 

occur in each batch since they QC sample dependencies such as 

matrix effects. 

* The RAW TEST column shows the test code used in the raw data to 

identify a particular analysis if it is different than the test 

code in the header of the report. This occurs in special cases 

due to method specific details about how the lab labels work. 

The Lab Sample or Planchet ID combined with the (Raw) Test Code 

and Suffix uniquely identify the raw data for each analysis. 

* If a result is less than both its MDA and RDL, it is replaced by 

just 'U' on this report. If it is greater than or equal to the 

RDL but less than the MDA, the result is shown with a 'U' flag. 

The J and X flags are as on the data sheet. 

* Non-U results for Method Blanks are underlined to indicate 

possible contamination of other samples in the preparation 

batch. The Method Blank Report has supporting data. 

* Lab Control Sample and Matrix Spike results are shown as: ok, No 

data, LOW or HIGH, with the last two underlined. 'No data' 

Lab id EBRLNE 






EBE RLIK E SE RVI CES / RI C HM O ND 


SDG 7507 

Contact Melissa C. Mannion G U I D E, C O n t 


Contract No 630 



means no amount ADDED was specified. 'LOW' and 'HIGH' 

correspond to when the recovery is underlined on the Lab Control 

Sample or Matrix Spike Report. See these reports for supporting 

data. 

* Duplicate sample results are shown as: ok, No data, or OUT, with 

the last two underlined. 'No data' means there was no original 

sample data found for this duplicate. 'OUT' corresponds to when 

the RPD is underlined on the Duplicate Report. See this report 

for supporting data. 

* If the MDA column is labeled 'MAX MDA', there was more than one 

result measured by the reported method and the MDA shown is the 

largest MDA. If not all these results have the same RDL, the 

MAX MDA reflects only those results with RDL equal to the 

smallest one. 

MDAs are underlined if greater than the printed RDL. 

• Aliquots are underlined if less than the nominal value specified 

for the method. 

• Prepareation factors are underlined if greater than the nominal 

value specified for the method. 

• Dilution factors are underlined if greater than the nominal 

value specified for the method. 

• Residues are underlined if outside the range specified for the 

method. Residues are not printed if yields are. 

* Yields, which may be gravimetric, radiometric or some type of 

recovery depending on the method, are underlined if outside the 

range specified for the method. 

REPORT GUIDES 

Page 13 


Page 47 

* Efficiencies are underlined if outside the range specified for 

the method. Efficiencies are detector and geometry dependent so 

this test is only approximate. 

Lab id EBRLNE 



Form DVD-RG 

Version 3.06 




SDG 7507 





• Count times are underlined if less than the nominal value 

specified for the method. 

• Resolutions (as FWHM; Full Width at Half Max) are underlined if 

greater than the method specified limit. 

• Tracer drifts are underlined if their absolute values are 

greater than the method specified limit. Tracer drifts are 

not printed if percent moistures are. 

• Days Held are underlined if greater than the holding time 

specified in the protocol. 

• Analysis dates are underlined if before their planchet's 

preparation date or, if a limit is specified, too far after 

it. 

For some methods, ratios as percentages and error estimates for them are 

computed for pairs of results. A ratio column header like '1+3' means 

the ratio of the first result column and the third result column. 

Ratios are not computed for Lab Control Sample, Method Blank or 

Matrix Spike results since their matrices are not necessarily 

similar to client samples'. 

The error estimate for a ratio of results from one planchet reflects 

only counting errors since other errors should be correlated. For a 

ratio involving different planchets, if QC limits are computed based on 

total errors, the error for the ratio allows for the preparation errors 

for the planchets. 

The ratio is underlined (out of spec) if the absolute value of its 

difference from the nominal value is greater than its error estimate. 

If no nominal value is specified, this test is not done. 

For Gross Alpha or Gross Beta results, there may be a column showing the 

sum of other Alpha or Beta emitters. This sum includes all relevant 

REPORT GUIDES 

Page 14 


Page 48 

Lab id EBRLNE 



Form DVD-RG 

Version 3.06 








results in the DVD database, whether reported or not. Results in the 

sum are weighted by a particles/decay value specified by the lab for 

each relevant analyte. Results less than their MDA are not included. 

No sums are computed for Lab Control, Method Blank or Matrix Spike 

samples since their various planchets may not be physically related. 

If a ratio of total isotopic to Gross Alpha or Beta is shown, the error 

for the ratio reflects both the error in the Gross result and the sum, 

as square root of sum of squares, of the errors in the isotopic results. 

For total elemental uranium or thorium results, there may be a column 

showing the total weight computed from associated isotopic results. 

Ignoring results less than their MDAs, this is a weighted sum of the 

isotopic results. The weights dependon the molecular weight and 

half-life of each isotope so as to convert activities (decays) to weight 

(atoms). 

If a ratio of total computed to measured elemental uranium or thorium is 

shown, the error for the ratio reflects the errors in all the 

measurements. 

Lab id EBRLNE 






C 

FH-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST I F03-006-62 Pea` '- °t1 


Joharmilpope/Pfister LC Hulstrom 373-3928 TRENT, S] 

Project Designation Sampling Loca tion 

SAN No. 

200-PW-2/200-PW-4 OU -Borehole Soil Sampling 216-A-37 (C4106); (12.5'-15 JÎ/t. ROtl^^ ` rJb^) F03-006 

iFx,Ghat No. 

^ 7 


C- 6 [ ^ HNF-N-3361 117504ES 10 Federal Exp ress 

Price Code 8N Data Tnrnaround 

Air Quality 

Shipped To - Otfid Property No. ^ O I r C/ Bill of Lading/Air Will No. .,- 0^'e) 

EBERLM SERVICES (Formerly TMA) /tC/ 7 0 

POSSIBLE SAMPLE ELA ARDS/REMARKS 



Preservation 



Volume 


B161N79 SOIL Lg Oj 

Cod aC Cod dC Cod Now Noce 

aG 

aG G aG aG 

I 1 1 1 

120ML 60mL 120ML 60ml, 60mI- 

01. xa- oil&Caeee- sm ilam (1)e Tritium-In 

rtes-7196 413A spend 

P5130, 

E] 

45 Days 

OF POSSESSION Sign/Print Names SPECIAL INSTRUCTIONS 

Matrix e 

` e The is to m achieve a detection limit of 50 .0 pCi/g for Carbon-14. e` 

s-adt 

^ 1A '>'72$- q=CS 0.5- 

Af` Y/z cj ^sam. 

soseti. 

B7At,/ n^nosed Fmm ^ - By/Stared ^^^ 

(1)7er8netiruo-99; 5hmim ti-E9.90-TohI Sr, Iaatopic7Lomm ('(Corium-232); Carbon -14; Iodine- Iodine- sra +a: 

kej^ f'>- '577—t S) 03 1160 1166 129; Nickel-63; Nephmiuo>-237 w- Wru 

oou 

By/Itemo F Dateltme B a-aa 

in Datdrm 

Relut"slied /Removed From ®e. ^l / Rw4tvd By/Stomd In DaWfime 

^^ Ds m 

oUO^ uy m 

M 

'.. _:•..., - ,By Fmm Datdfime By in 

w wp 

em Pers onnel not 

Datdf®e 

available to 

Ref 

om 

p Lon the 3728 

Datdrmre ^. /d 

Received By/Stored In Datdrmre 

elioquished By/Removed F rom DavlCime eceived By/stared in relinquish samples fr 

hpuished By/Remuved From 

LABORATORY Received By TitleDau Time 

SECTION 

F IN AL. SAMPLE Disposal Method Disposed By Datdrare 

DISPOSITION 

BHI-EE-0 11 (03/01/2002) 

V-V 

v-vegum 

x-oor,

C 

F11-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS RE UEST F03-006-63 Pan- 1 of 1 

Collector Company Contact Telephone No. Proj ect Coordinator 

Johanseo/Pope/Plister LC Hulstrom 373-3928 TRENT, S7 

Project Designation Sampling LerA tion ^ ^^ nr(/ 

200-PW-2 /200-PW-0 OU - Borehole Sod Sampling 21 6-A-37 (C4106); ( 17.5'-20) 9 (k1 Ì T L 

Iee Chat No. 017 FielNF-N-361No. 

1177504ESIO 

SAF No 

F03-006 

MFoeral Exp^sent 

Prim Code $]v Data Turnaround 


Shipped To Offshe P ro perty No. 

A O 3 

/7 

u P/ 

-1 

Bill of Lading/Air Bi ll EBPRLINE SERVICES (Formerly TMA) 

POSSIBLE SAMPLE DA7-ARDS/AEMARKS 

0 

No. p,^^ 

U 

p ^_ 

l 

Preaervadon 

CcW 4C C.W Cod Noce Nape 





Volume 

aG aG aG aG 

1 1 t 1 1 

"ou" 60mL 120mL Wet, 60mL 

t3mmaea OU&Graae- seeaa0)m T,6.40 

nee-7196 53.2 413.1 spew 

WAI 

^4e oa. 


816W80' SOIL 6 D x 

PrIA-ZZA 

45 Days 


Y/g^p^d F 

/R®n3

FH-Central Plateau P roject CHAIN OF CUSTODY/SAMPLE ANALYSIS RE UEST F03-006-64 J P8P I Of ! 

Collector 

Project Dei igna tion 

200; PW-2200-PW-4 OU - Borehole Soil Sampling 


LC Hulst rom 


216-A-37 (C4106); (27.5'-30) 

Telephone No. 

373-3928 

S C qa l^ tf ^ ^.^ 

O r 


TRENT, SJ 

1 SAE No. 

J F03-006 

Price Code $]1i 

Air Quality q 


45 Days 

IccCtie3e^NO. Field Logbook No. COA Method of Shipment 

G 0 / 0/ HNF-N-3361 117504ES I O Federal Express 

Shipped To 

EBERLINE SERVICES (Formerly TMA) 


Ofrd Properly No. '\ 

V 

t/ Q 

7 0 


Prpwatloo 



Volume 

SAMPLE ANALYSIS v,Ati 


B16W81 SOIL d 01 

cod C Codk Cad 4C Nom Noce 

aG 

aG aG aG 

1 1 1 1 1 

120mL 60mL 120ml, 60m1, 60ml, 

Chomum N O sera - smna ra (1)m Trhwm -]n 

3 -7196 33.2 413.1 spcdd 

Bill of Lading/Air Bill No. C O S 

J rJ 


B m 


BY/Stored In ^,ÌO-^^ ®e 


re The labo ratory is to achieve a d etection limit of 50.0 pLVg for Carbon-14. " 

9 yea 

a to 

3 

By/Removed Fr m 

IL 

I yCp ReceivW BY in ine ' (1) Tadme-99; du Str ontium-89,90 — Total Sr, Isotopic Thorimm (Thoriom-232); Carb on-14; lodme- 

1 .G C Lt - 2-1. 129; Nick"3;Nepamium-237 

` / 

ed From 

57L .5 t 0 

me 

//00 

Received By/Stned In 

DaWrzac 

//00 

Refiraquishod By 

B 

F DatNl'®e 

^/O 

v V 

vedF 

"ved By/Startd Date/tune 


relinquis sa mples from the 3728 

Ref# / 

rom Datdlme torad In 5^2.^'m9^^ 

on 

Relinquasherl By/Removed F JDatefr 

ro m DaWrime By/Stored In ®e 

LABORATORY Received B)' Title Datefrime 

SECTION 

FINAL SAMPLE Disp osal Method Disposed BY DatNPme 

DISPOSITION 

BHI-EE-011 (03101/2002) 

Matra 

= 

so-sd'd 

si-m * 

W.W. 

oau 

A-" 

M-wyc 

r^r'a'u 

v-vawa

FH-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-65 Pam 1 a i 

Collector 



200-PW-]1200-PW4 OU - Borehole Soil Sampling 

Ice Chest No. G O O 

Shipped To 

EBERLAIE SERVICES (Formerly TMA) 





LC HuWMm 373-3928 

Sampling Location 0 G 1 r q 'r,1 ^7tn1 

216-A-37 (C4106); (37.5'-40) 4! °I pt l T ^.^ V T 


HNF-N-3361 

Offsite Property No. 

/ , 

Preservation 


3 O Z 

COA 

117504ES10 


TRENT, S7 

SAP No. 

F03-006 


Federal Eximm; 

Cod M: Cod IC Nape Nape 

aG 

No. of Contaiaer(s) I 1 

Volume 

- a 

Sample No. Ma tr ne • Sample Daft Sample Time 

B16IN82 SOIL O1} 

aG 

aG aG aG 

I 1 1 

120mL 67 120mL 60ML Wool, 

cema:oo N621HO3 . aanrent. S iU.(I) m Tdtk. -In 

Hax- 7196 3532 

4 13.1 

Special 

^', 

â 

tamaaam. 

•.CBAIN OF POSSESSION AR 

Sign/Print Nam" SPECIAL INSTRUCTIONS 

- B Reeeiwd By/SOmed la E^►G.L DaWT 

eriG^J' 1 

kdmqmsw By From 

e QLA 

l It tad 

it , EQ 

veal Byrs 

$ ^L 

Z 

®e I 

y 

Reliar ved From 

F7z SI 03 

Datdr= 

eezved By/Slomd In 

Datdf®e 

1160 C^ ^ e C" _ "V 

Relioqmshed By/Removed From I)atdrime Received By/Stomd In Date/fine 

LABORATORY 

SECTION 

price Code $N 


B01 of Lading/Air Bi ll No.sO, 

. 

/I -- 

I u 

r 


45 Days 

t 

C/ 

CD 

•• ILe labmmory is to achieve a detection I®it of 50.0 pCi/g f br Cart o 14. *4^ b/ j 

La. G 

()) 7echaetium-99; Strwtmn-99,90 - Tolel Sr, Lmtopic 1Lrxiom ('ILoriam-732); Cazbm-14; Iodise- 

129; Nickel-63; Neptunium-237 



Ref # 

Reaived By - Tide Datefrime 

FINAL SAMPLE Dnponl Mtrhod Disposed By Dardrane 

DISPOSITION 

BHI-EE-011 (031012002) 

M atrix 

sa^,ar 

so-sda 

9-seas 

W.W. 

a 

vmwye 

u am3 

v-v.w+m 

x^

.r 

F71-Central Plateau P roject CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST F03-006-66 Paae I of 1 

Collector Company Contact Telephone No. Project Coordinator price Code $N Data Turnaround 

Johanseo/Pope/P&ster LC Huls trom 373-3928 TRENT, SJ 

Project Designation Sampling London ' I (/ Sso SAF No. 

200-PW-2200-PW-4 OU - Borehole Soil Sampling - 216-A-37 (C4106); (47.5'-50, Sn ^. V a ` q / 

F03-006 

Ice Clint No.^y Field Logbook No. COA Method of Shipm en t 

(i^l c 0/., e / BNF-N-3361 117504FSIO Federal Exp ress 

Shipped To Offsite P ro perty No. n X2 a y , ice/ Bill of Lading/Air Bill No. C 

EBERLINE SERVICES (Formerly TMA) /TV J C/ GL/ Zj 


Special Handling and/or Sto ra ge 


Preservation 



Volume 

Sample No. matrix • Sample Dare Sample Time 

Cod 4C Cod 4C cod Nine rove 

aG aG vG aG 

I 1 I I I 

120mL 12OWL 60ML 60ir 1, 

13mid. NAM3- altsnrm- Si (I) ie Tm:m-M 

Ha .7196 357.2 413.1 Spedal 

01 

bamatiom. 

Air Qua lity E] 

A a\ Tt 

B16W83 SOIL / 9 


g 

Sigm/Print Names 

Received By/Staed In 

Q-^'rtl 

pat a 

SPECIAL INSTRUCnONS 

•• The labommry is to achieve a detective lilt of 50.0 pCi /8 for Ceiban-14. •• 21alabenthryi -to 

- is. JPî^ y/Ls`0) 

% dpi D 

4 

'yd By 

Z •e a f - 

(1) Ter u d.-99; Shonthw-89,90 — ToW Sr, Isotopic Thmimo (Thoriam-232); Cmb.14; Iod'i 

129; Nickel-63; Neptuxn -237 

By Feom ece ved By/Sbmed in Da dl me 

.574,5_ // ^/© 

ehn,imsbedBy/ReonvedF 

By/ Faun 

Rdmqwshed Ey/Renoved Frain 

DNelrime 

S1 0 7 11,06 

DaWrmc 

Datdl'i 1111, 

Received By/S 

rsoaea In 

Roodved By/Stowd Wr 

5 

Datetrune 

- 

Date(rune 

1= 

personnel not available to 

3728 

relinqu sampi^/ 

Ref # 

° 

- 

LABORATORY Receved By Tide DaterTime 

SECIION 

FINAL SAMPLE Dispos al Method Disposed By Daterrime 

DISPOSITION 

BHI-EE-011 (03 1012002) 

45 Days 

matrix 

ss^.r 

so-sa 

srs ma, 

W- Wm 

nap 

a-• 

ma wm sdtl 

m. uem 

r3 W 

» 

x^^

F11-Central Plateau Project CHAIN OF CUSTODY/SAMPLE ANALYSIS REQUEST 

collector 



LC Hulstrom 

Telephone No. 

373-3928 


TRENT, SJ 

Project Designa tion Sampling Loca ti on ^'a ^^ SAF No. 

200-PW-21200-PW-4 OU -Borehole Soil Sampling 216-A-37 (C4I06); (17.5'-201 -Sod F03-006 

Iee Chest No. n,G 0' 

017 


HNF-N-3361 

S hi pped To 

EBERLINE SERVICES (Formed TMA) 

POSSIBLE SAMPLE HAZARDS/BEMARKS 

OHsite Proper ty No.,ll ., 

/-^ 

b Z 

Special Handling and/or Sto rage 

Preservation 



Volume 

COA 

I17504FS 10 



Cod 4C Cod 4C Nom Nua 

a0 

t 

aG aG aG aG 

I 1 1 1 

120mL IZOmL 60m1, Wall, 

N 3- Oiltcae.ee- Smitea 0) m T^ - w 

7196 351.2 413.1 spec) 

SAMPLE ANALYSISIl 

lvrmimon. 

Sample No. Matti, • Sample Date Sample Time 

B1 6W90 SOIL. 2^ 03 0 x 

i 

A 

I F03-006-73 J Pw t of s 



Bill of Ladiog/Air Bi ll No. 5 ^--^ ^J 

CHAIN OF POSSESSION Sign/Print Names SPECIAL INSTRUCTIONS 

C 

F 

By/Ramoved irod 

^ 

44 S 

DaddT®e 

DttrJimc 

J I OU 

Received By/Stood Io Drtdf®e 

^PFF /ft 3^2X yz$v, 645 

Received ByMood In DatJf® e 

The laboratory is to achim a detection limit of 50.0 pCU9 for Carbou-14. ' ay u 

q N/0:1. 

- ^ 

(1) Tecbnafi r 99; Shoutium-59,90 – Total Sr, Isotop ic Thorium (T6aimo-232); Cuboo-I4; Iod ine 

(Cp 129; Nickd-63; Neptwom-277 

Lqu,shed By p Dat5 

eceived /Stored In Da[dCuae 

. By From Dmdf®e 

'P 

BY/Stomd 

to 

D ^ 

.5• Lfi^ 

RebRuaslacd By/P—wd From Daadr= Becdved Wslowl. Datdhoe 

. By/Removed Fran 

Personnel not 

available to 

R squish sa 

mples from the 3728 

LABORATORY 

SECTION 

Rmeav'ed By - Title 

Datdrime 

FINAL SAMPLE 

DISPOSITION 

Disposal Medved Disposed By Drtd line 

BHI-EE-011 (03/01!2002) 

^^^ 

By/Stond In Da

a 

E la != R ^^ r^ r 

Gr(P} 

IFT 

ANALYTICAL SERVICES GROUP 

Richmond, CA Laborato ry 


Client: DeteMme received 

coo No.F0 -0 0 6 —0 1 6 3 r t 6St 4 6 4 —743 

S ^` a3 

Container I.D. No. -Requested TAT (Days) 1S P.O. Received Yes [ ] No [ ] 

INSPECTION 

1 . Custody seals on shipping container intact? Yes [ ^ No [ 1 NIA [ 1 

2. Custody seals on shipping container dated & signed? Yes [ y No [ 1 N/A [ ] 

3. Custody seals on sample containers intact? Yes [L,J- No [ 1 N/A [ ] 

4. Custody seals on sample containers dated & signed? Yes [^ No [ 1 N/A [ 1 

6. Packing material is: Wet [ 1 Dry [ ^^ 

6. Number of samples in shipping container: 

7. Number of containers per sample: (Or see CoCC i 

S. Paperwork agrees with samples? Yes [ ` L+_ ^ No [ ] 

9. Samples have: Tape [ 1 Hazard labels ( ] Red labels 

[ kp,_Proprlate sample labels [ 

10. Samples are: In good condition !" 1 Leaking [ ] Broken Container[ 1 Missing [ ] 

ill Samples are: Preserved [ I Not preserved ( Preservative 

12. Describe any anomalies: 

13. Was P.M. not! ' o any anomalies? Yes[ 1 No ( ] Date 

14. Received by Date: S^ Time: (bb 

Customer Sample Customer Sample 

No. cpm mR/hr wipe No. cpm mR/hr wipe 

ion Chamber Ser. No. q .5 Calibration date t 2 2 ^^3 

Alpha Meter Ser, No. 

Calibration date 

Beta/Gamma Meter Ser. No. reitti.ett..,, eta+o 3 z"^•.3 

Form SCP-01'.2, 02-11-03 

,,over 50 years of quallty nuclear services"

RECEIVED RX929!

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