Scribd Logo
Upload

Welcome to Scribd!

  • Gaseous States-Solved Examples & Exercises

    Uploaded by

    CJ DRB
    44 views24 pages

    Copyright

    © © All Rights Reserved

    Available Formats

    PDF or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    Report this Document

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
    Flag for inappropriate content
    44 views24 pages

    Gaseous States-Solved Examples & Exercises

    Uploaded by

    CJ DRB

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
    Flag for inappropriate content
    of 24
    S20 2 Sol. Sol. Sol. Physical Chemistry-l for JE (Main & Advanced) (i) hayes, hy x 1x10" = 10.33 meter What will the pressure Voom 4 hs Ordessg 76 x 13.6 x 10° iy z (i) at the bottom of the tank? Gi) at the middle of the bottom layer if two immis- cible liquids ar filled as shown in figure? P57 Pam + Pressute due to liquid (2) ~ Pressure due to liquid (1) Py= Rat OE, 5 L013 x10" * L013 x10 If} in metre o in kg/m’ and g in my/see"] or in MK.S. atm = 1.013 x 10° Pa My fas Pox Pate Tons x18 * Lors x10 Find the pressure of gas inside the container if manom- cter attached to the container shows a difference of 60 ‘mm as shown in the figure? cnt mgt 2736, we Pilate for two ideal gases 4 and B as shown in the figure. Find out the number of moles of gases 4 and B. Pr=nrt, P= SnRt { Br 1 | Je Po nF 7 Comparing by above equation, sor c (n= tan 1 RTrim tan. 1 ng=>,;mole Ra SE? 0.080 273 x eat eT *° RT tan 60° 22.4V3 5. At constant P of 0.0821 atm log V vs log T graph was plotted for three sample of ideal gases, Calculate the number of moles of each gas, Sol. Ve T Baik Tk" p log Y= log T+log K yemmene nk © ea =a“) > 7 [nega] =U" oosat For (1) C=logn 0.4771 = log n=log 3 For gas (2) 0= log =log 1 n=i For gas (3)—log += 0.30 ~ log 2=lo “los 2 m{3] 6. Radius ofa bubble atthe bottom of the tank shown be- Jow was found to be 1 em, Find the radius of the bubble atthe surface of water at same temperature, ° 10.336] snetee 10336 Poy + — 8 __ 1.013 x10° 10,336 x1x10°x9.8 Pressure at bottom, 1.013 x10° om Since tempers is constant and constant AK Bh nf Made BV, = PLY; Sol. Sol. Sol. Sol. Sra etetan 2x gat =1x Gar fm (b) If the absolute temperature at surface is 4 times to that atthe bottom. Find the radius of bubble at surface? iT AM Tq tea? idan 2. xn! 1 a T 7 2 If liter of gas A at 1.5 atm and 3 liter of gas B at 2 atm are mixed in a$ liter container find the final pressure. nym ai RI) RT RT DyVy+ P.Ve= PV 1Sx2+2%3=PxS p= 2am=1.8a1m 5 ‘Two moles of NH, and one mole of HCI gas are taken ina container of capacity 8.21 L at 300 K to produce ‘NHCL. Find total pressure ater reaction, NH + HCI—> NHC] ® @ © 201 ° 1 0 1 ig= Mygg, = 1 mole (after reaction) pate? _ «0.821300 - 821 =3atm 1. A closed container containing O, and some liquid wa- ter was found to exert 740 mm pressure at 27°C. (@) Calculate the pressure exerted by O, if aqueous tension at 27°C is 20 mm of Ha, (b) What will be the final pressure if volume is re- duced to half, assuming volume of liquid water is negligible? (©) What will be the final pressure when volume is doubled? (0) Pr=Ps+ Praresion 740 Passion Pa 720mm He Gas law applicable for gas only ©) Pay son change with temp. only) Gas law applicable for eas only PNP Gaseous State S12 = HH40= Pea, Se y= Py* Pay = 14020 1460 mmHg (Aqueous tension change with temperature only) © PM =Pr, 380 mmHg 10, An iron tank contains helium at a pressure of 3.0 atm at 27°C. The tank can withstand a maximum pressure of 10 atm. The building in which tank has been placed catches fire. Will the tank blow up frst or melt. (Melt- ing point of iron is 1835°C.) Sol, P,=30.7,=300K ALB Zh pw 3021808 300 Since at melting point, itis greater than the maximum, pressure, therefore it will blow up. AL. An open vessel a 27°C is heated until 3/5" of the airin it has been expelled. Assuming that the volume of the vessel remains constant, find (@) the temperature at which vessel was heated. (b) the air that escaped if vessel is heated to 900 K. (©) temperature at which half of the air escaped out Sol. Note the fact that on heating a gas in a vessel. the mum ber of moles of gas which go out, the volume of vessel remains constant Let initial moles of air at 300 K be ‘n". On heating 3/5 moles of air are escaped out at temperature 7. ales ofr eft at texperatue 7= (20) = 22 3 (@) Under similar conditions of P and 2n nx30= xT = 0K (B) On heating vessel to 900 K, let 7, moles be left again mT, = MoT, 1 n,x900= 300%" = m= 4" 1 n= 3 2 + moles escaped out= 1 2= Zr moles (©) Assume /2 moles are escaped at temperature T, then nT, = nels nix T= nx 300 T= 600K, 7 12, A balloon i inflated to ofits maximum volume at 27°C (a) Wil it Durst at 30°C? (BI22_—_ Physical Chemistry: for JEE (Main & Advanced) (b) Calculate the minimum temperature above which it will brost, Sol. (a) Balloon will burst if > maximum volume ‘Maximum volume = 77 1 Initial volume of balloon = °C or at 300K ar? FY x30 = 71308 © 13, An open flask contains air at 27°C. Calculate the tem= perature at which it should be heated so that (a 4 of air measured in te container at 27°C es: capes out Giy 1 ota mast in he onin i fal n- perature escapes out Sol Flint: 1, —/=n expelled Ye 3300” RT a) na 2% Ma J Vin, Sol. so, SS. Sol, Sol, 18. MV r 6 ioo=x 41 60cm A container consist of H; & O; gas having same no of moles. If the volume of H, gas is collected after half an-hour is 30 mi. Then calculate the volume of 0; collected under similar condition 2 _Ya, _ 30 2 Vo, Vo, 1n30m sal te Vo, collected Note: In any diffusion and effusion process the rate of df= fusion and effusion do not remain constant trouah- ‘out the given time interval. (Generally it decreases) However, for solving a problem, te rte is assumed to be constant during specific interval of time and this constant rate of diffusion or effusion is taken as initial rate of diffusion or effsion. A container consists of H and O, gases having same number of moles. Ifthe volume of H, gas is collected after half an-hour is 30 ml. Then calculate the volume of 0, collected in 1$ minutes taking diffusion rate con -% 2 To, 75 mL 130 minutes Vp, collecte 15 Sx 30 ‘A container consists of H, and O, in 2 : 1 molar ratio. Ifthe volume of H, gas collected after 10 minutes is 15 sa at same Pand P, What will be the volume of O; gas collected at minute and 20 minute? Pay [Ma PE rig VM, 152 4 75 mL In 15 minutes Yo, collecte ate Gaseous State 388 19, A container consists of piles of Dy gas and é soi { sy mole of His collected through a nozzle to large cou- 3 SLVs49 tainer Afer 10 minute 0.1 am of D; was collested in [ 2} the second container, dhen calculate 9 Lae. G) initial rate of diffusion of both gases. Gi). Moles of H, obtained in second container ater 10 10g 25— og 9 =Jog.0086) smite 2 1397-098: , 0.0037) Sol. (i) 1.30 240 22, Given figure shows 2 Identical 4 and B with rigid walls containing ideal gas. The pressure, volume and tem= perature in vessel 4 are 7, Vand P, whereas in second container pressure is P, voltime is V5 and temperature is Tp. Vessels second are now connected thromah a nar row tube, Show that the final ratio of ‘P" and tempera inet 4 7 Bm] PP P oa " "|| 7 r / ix thn so | 1 +E " r Leones 1414 gram ¥q=V (Same vessel) 20, A closed container having molar tatio H, and N, of 1 9. After n diffusion tis ratio changed up t0 9 1. Cal- _PY |, PY culate what is the value of n°? "nar, "Rr m= 9 =2h Rr, "8 RP (*) -(t) (eh Geng dang tng inde lng PY PV [BW | Pe 5 Jana (2 awa VM PY PY IEW , Bal ba rar (it, #5 2PV VPs, Pe T, Ts 23, Two flasks of equal volume connected by a narrow tube are at 27°C and container has 0.7 moles of H, and 0.5 atm. One of the flasks is then emeraed into a bat. kept at 127°C while the other remains at 27°C. Caleu- late the final pressure and mumber of mote of Hin each, =331 ask. _ 1.9084 « Lis after 4 diffusion, 21. A sample of UF, and “UF, is present in ratio 3 : 5 ‘motar ratio after » diffusion this ratio become 5:3 then calculate value of 7, Jn=0.3s =035 > Sam peas so. [20%] _fesve] | ae BaR 300 => POF Jeg LEU leas VME UR v-u2 a B (BIB4 Physical Chemistry: for IEE (Main & Advanced) case— x mole} 07-0] smote | Pana Voor Vas @ sok) | 400K) 4 z «i FOrA Pay V=¥-RX300 @ Forh Pra. ¥=(0.7-x)-Rx400 w x-R300=(700—x) xR x 400 300 = 280 400% 7008 = 280) L; and Z, can be calculated. 4 mole 27, Caleulate Ly 24, A mixture of 0.5 moles of CO and 0.5 moles of CO; Js taken in a vessel and allowed to efduse in another ig liquid 1022 g/l container which has vacuum, If total 4° moles have an effsed out in time *?, show that M4 ~ M (4) = 36 M,, Mf; are mean molar masses of mixture that are Pay effsed out and mixture still remaining a Sol. Initial mass =0.5 x 28~0.5 x44 Pa 1A) My + AM, = 36 et or MA *M, [1 -4]=36 6 0.5 mole] (ay -Atmmole)} sos 10.2 x10" x9.8 co No ‘mole ae atm ma | c LOLxI 05 mole aa to M: Mi. 25. A2L cylinder has 10 mole st 300 K. This container is connected to a 1 L-vaccm container by a narrow tube. If final temperature is remain same, then calculate the final pressure of the system Sol. PV, =mRT, é er p= 100.0821300 : 2 28, 10cm column of iris rapped by a column of Hg 8 cm. 100.0821 If capillary tube is fixed horizontally as shown in the ee pe figure at 1 atm, calculate the length of ar colurun when the tube is fixed at same temperature, or nxT (a) Vertically with open end up. = 200.0821 300 59 atm () Vertically with opened down. 3 ~ (€) At 45° from horizontal with open end up. Wom a8 ow Sol. (@) Py = Pay = Lat —— Lt the aren be 4 Py We fe a nile Lt | T00 em Caleulate Z; and Zy Sol. L, + £2=90 em (Hig does not expand) and Py=P)* Pag rxtoxas fie] ira 76 h=9.04 em V=10x4 (& P\=Latm, = 118m (© Pia latm, Y= 10x4 A=93 an 29. Mr, Gupta weights 72.15 ke and wants to fly in the sky with balloon whose weight is 20 kg and each contain- ing 50 moles of H, gas at 0.05 atm and 27°C. Density of air at given condition is 1.25 guts. How many such ‘types of balloon is needed to fly in the sky? Sol. Meninat Mag ax ~ Maine Mattoon * is] = [4g *Vistoon * Mision] = May toa var [BZ] N V [20x 10° + 100} = 75.15 x 10° 7S.asx10® [20 10° + 100] 30, Figure below shows initial conditions of a uniform cylinder with frictionless piston 4 and & held in posie tion by mechanical stoppers. ithe mechanical stoppers holding piston 4 and # are removed, (assume that tem- ‘perature remains constant) (What wil be the pressure developed in each com- partment in final state? i) What will be the final position of piston with respect to for left end of container? (iii) What will be the final position of piston B with respect to for left end of container? Gaseous Stare 335 Sol. (i) p= Mist Nar Pe 30 Py x25. 7 *A™85 ar ORT RP RF Sx 4x40 2 30 P,xAx100= 10% 25x4 + 53 Ax35+ 5 x4OxA P,x 100 = 250 + 150+ 100 sm Final postion = 80 meter 31, Few gases are filled as air in the container as shown in the figure and allowed to attain equilibrium (assuming temperature remains constant) throughout the process, Select the correct option: (@ Total moles of gas in compartinent II will be 1: (i) The moles of hydrogen in compartment I will be 2, Gif) The length of compartment containing only hy= drogen will be after equilibrium is attained? (iv) Distance of movable piston from left end is $0 em after equilibrium is attained 4 8 r 7 Lf 23m Sm i 40m He(@® Arg) New) Preauio) #307 am P52 t i u U0 ory) 40-y) en” 4am Wem He He 0 (= warm)) P=toam || P=100m pa Py Lb Pu T 1 Foed SPM. (allow only 13) 26 Physical Chemistry-l for JE (Main & Advanced) + Bag) MY yee dy v "| 3aRr Wem , 4 5 Os Pas 3.142810 am |] 0am 28314 3000314 Laon — Grl* “F001, TT Ve 28x107 F L_AtSPM. compartaent It a a4 3.14[ 282107 _ Sol, AtSPM. compartment If and I Saal 2. Sol. 33. B= P= Ph, Let (x) moles of H, are detfused from II > II (By SPM) P. Pressure of Hin I x _(0-x) wy nt At Piston in compartment [and II P= Ps IORT___xkT. @0+)R GO-W)A wx Rory H-y y=30 Calculate Vg, speed of oxygen at 300 K. BxSai4x300 Fras 32x10 . Calculate the fraction of Np molecules at 1 atm pres- sure and 300K whose speeds are in the range Of tgs = 0.005 483.12 m/sec Sol. JG ce 005 tg 005 du = final velocity — Initial velocity [egg * 0.005] ~ gg ~ 0.005] = 0.1 du=001 ‘By Maxwell distribution theory x [422et x 0.01 x 422, =8.303 x 10 Ans 34, What is the ratio of the number of molecules having speeds in the range Of 2 tig, and 2a) > du to the Num= ber of molecules having speed in the range Of tay and +du. Area of 4 Area of B Map 35. Calculate ¥jq, speed of H; molecule under the follow- ing conditions? (2 moles of H; gas at 27°C. G3 moles of H gas in 5 | container at 10° Pa, Gi) 4 moles of H, having density 1 g/mL at 10° Pa Sol. We know SRT ‘Molar mass in ke _ aPY pe “YTolmasinkg Vd Pin Pascal, Vin m?, molar mass in kg and density dor pin kein? BRP _ [xsaiaxa0o M 2x10" 3x83. we axl Fons Ome 19.34 x 10°misee. ay PRE ~ Pease? eae mY 32x10" = 500 mise to (Fo PE ors Lgiml= * kali? 107 ke 10m 36. What is the density of moist air with 90% relative h- ‘midity under the condition of 1 atm pressure and 21°C; The vapour pressure of water at 25°C is 23.7 torr and Ary air has 76% Ny and 24% Op. Also find the differ- ence in the density of dry air and moist air at the given condition. Sol. (VP. of HO at (Mavyary ait °C is 23.7 mm of Ha) (076 x 28) + (0.24 x 32) 21.28 + 7.68 = 28.96 g/mol Patil Pressure of HO VEO PMs RT Pagg = 23.7 * 0.9 = 21.33 mmblg = 0.028 atm. (Now) Moist air= (28.96 x 0.972) + (18 x0.028) 28.147 + 0.504= 28.65 sm/mol _ PMawitas 128.65 Posies ep ~ 0.0821 298 AP Pry sis~ Pas ic RH= x 100 Density (p) 17 amv P Mena, are isesic) —1 \0821 x 298) 437. Calculate the payload when a balloon of radius 10 meter mass 100 kg is filled with helium at 1.66 bar at 27°C. (Density of air 12 kent” and R = 0.083 bar dP") 28,96 — 28.65) = 0.1267 Gaseous State SBF Sol, Volume of balloon = 4190.47 x 10°L PP 4x 107ke aP Ja0# = 419047 m? Mass of the heli 1.66 x 4190.47 x 103 x 4 x10 0.083 300 Mass of balloon with helium 1117.45 + 100 = 1217.45 ke Pay load = mass of ais displaced ~ mass of filled bal- Joon = 5028.56 ~ 1217.45 = 3811 ke 38. The compressibility factor for 1 mole of a Van der Walls gas at 0°C and 100 atm pressure is found to be 0.5. Assuming thet volume of a gas molecule is ‘negli gible’, calculate the Van der Walls constant ‘a" 1117.45kg Py Sol, For I mole ofthe gas Z=F7 os = 100x¥ 00821273 = 0.2L. Nealectng, the equations (P45 = RF ta 39, Calculate the pressure exerted by 22 g of carbon diox- ide im 0.5 dm at 298 15 K using: (@) the ideal gas law and (b)_ Van der waals equation. Given: [a= 363.76 kPa din mot? ‘and b = 42,67 em? mot] 0.0821 x 298.15 or PY+ 5 = RT, a=1.251? atm mol? Sol. ‘atm =2.479 x 10°kPa 08 ( 1) xsear6 2 1,426 © (Page EMtr = esssreeusina P=222555kPa 40, The Van der waals, constants for gases 4. B and C are as follows: Gas adm*kPamol? b/d mol"! A 408.3 0.027 B 12189 0.030 c 60798 0.032 ‘Which gas has () the highest critical temperature, (Gi) the largest molecular volume, and Git). most ideal behaviour around STP? (BBB Physical Chemistry: for JEE (Main & Advanced) Sol. (@ find 7.- $4». gas.3 123228 008215200) gs, 27Rb 8 821 Gi) Large value of } «largest molecular volume. s0 volume of 0.5 mole Ny = 1.65 0.5 = 0.8251. gasC 43. The critical temperature and pressure of CO, gas are (iii) Least value of a and b ». ans. 4 304.2 K and 72.9 atm respectively. What is the radi- 41, A commercial cylinder contains 6.91 m° of Op at 15.18 us of CO, molecule assuming it to behave as Van der MPa and 21°C. The critical constants for O, are Ts Waal’s 228? =118.4°C, Pe = 50.1 atm, Determine the reduced pres- Sol, T= 304.2 K sure and reduced temperature for 0, under these condi- 8a tions. Te= saR5 Po= 72.9 atm : Resincedtemperamire ;= > = 190 Te 42, Calculate the volume occupied by 14.0 g N. foto 3 aug BY or =1 0.082 x 304 729 = 0.04277 lit mot"! = 42.77 em and 821 atm pressure i Sol 14 gNy 0.5 mole 2.77 aw? 4 Nyx Ane’ 242.77 3 © 3x 42.77 x10" " 16x 6028x314 or 24x or 62x" em radius of CO, molecule = 1.62 A 5, 380 mL ofa gas at 27°C, 800 mm of Hg weights 0.455 «Z eye 2. The molecular Weight of gas is 1. Pressure of 1g of an ideal gas A at 27° C is found to be 2 bar. When 2 g of another ideal gas B is introduced in the same flask at the same temperature, the pressure bbevomes 3 bar, Find the relationship between their mo- lecular masses, (@) My=4My (©) Mg=4My (©) Mya 2My (@ My= 2M, 2. Density of gas is found to be 5.46 g/dm? at bar pressure. What will be its density at STP? (@) Gemil (b) Sem1 (©) 3eml (4) 15 emi 3. Calculate the temperature of 4.0 mole of a gas occupy- ing § dm? at 3.32 bar. (R= 0.83 bar dm? K"! mol (@) 100K (b) SOK (©) 150K (@) 200K 4. Calculate the volume occupied by 8.8 g of CO, at 31.1°C and 1 bar pressure. & = 0.083 bar LK“'mol” (@) 10.1 © sole © 201 (@) 5.05 ie °C at 2 @ 27) 28) ©] 29 ~~) 30 At what temperature will be the rate of effusion of Ny be 1,625 times the rate of effsion of SO, at 500°C? @ 273K (b) 830K © NOK @) 173K ‘What is the ratio ofthe rat of diffusion of O, and Hy at same P and 7? @le4 WUs C6 W421 8. Equal weights of methane and oxygen are mixed in an empty container at 25°C. What is the fraction of the ‘otal pressure exerted by oxygen? 1 1 2 @; OF OF ). What will be the pressure of the gaseous mixture when 0.5 L of H, at 0.8 bar and 2.0 L of dioxygen at 0.7 bar are introduced in a 1 L vessel at 27°C? (a) 4 bar (b) 18 bar (©) 0.9 bar (@ 3.6 bar 10. 4. 2. 1B M4, 16. a. 18, 19, Calculate the total pressure in a mixture of 8 g of dioxygen and 4 g of dihydrogen confined ina vessel of 1 daw’ at 27°C, & = 0.083 bar dK mot" (a) 28.5 bar (b) 56.025 bar (©) 1125 bar (@) 14.25 bar 2.9 gof ans at 95°C occupied te same volume as 0.184 2 of dihydrogen at 17°C. at the same pressure. What is ‘the molar mass of the gas? (a) 120 mot! (6) 202mot" (©) 80 mol" (@) 40 2mot* The average velocity of an ideal gas molecule at 27°C is 03 m/sec. What will be the average velocity at 927°C? (a) 0.6 msec (6) 03 msec (©) 09 msec (@) 3.0 msec The root mean square velocity of one mole ofa monoa- tomic zas having molar mass Mis Urm.s. What is the relation between the average kinetic energy (E) of the gasand Urms.? @) Meme ©) Heme = © tome @ tome 3M The compressibility of a gas is less than unity at STP, Therefore, (a) Vin > 22.4 tte (©) Vm=2244 tir (®) Vin< 224 tir (@ Vin= 448 tte . In Van der Waals equation of state for a non-ideal gas. ‘what is the term that accounts for intermolecular forc- @) (a) © (r+3) 4.0 g of argon has pressure P at temperature TK in a ‘esel_ On Eeping the sample at 80" higher tempera. thre 08g 295 as given otto maintain the presse P. ‘What was the eriainal temperate? (@) 3K (b) 100K (©) 200K @) 510K The temperature of an ideal gas is increased from 140 K to $60 fat HO K the rot mean square velocity of the gas molecules is , at $60 K it becomes: @) Su &) mu ©) wr @ wt 40 nL of mixture of, and was placed in a gas bu- Fete a 18°C and 1a. A spark was prodiced so that ‘the formation of water was complete. The remaining pe ens oda volume of 1m at 18°C and 1a tt the remaining gas was what vas the intial mole 6 oft, in mixture? (a) 75% — (b) 25% = (c) 60% (d) 45% A flask of capacity of 1 Itr contains NH, at 1 atm and 28°C. A spat is psed throug unl al the NAL, is composed into Ny and Hy Caleta the pressure of gases et at 25 ( ar @ an 20, a. 2. 23, 24. 25, 26. 21. 28. 29, 30. Gaseous State 3H G@ 2am (b) OSam © 15am (@) Tam The density of CO, at 100°C and 800 mm Hg pressure would be (@) 1212 hr? ©) 15124 gtr (©) 21124etrt @ Loe tr? Pressure remaining the same, the volume of given mass of am ideal gas increases for every degree centigrade rise in temperature by definite fraction ofits volume at @ oc () its critical temperature (6) absolute zero (@ its Boyle temperature 1£20 cm? gas at | ais expanded to 50 ent at constant T, then what is the final pressure? 1 1 (@ 20x55 © 50x55 © 1x pxso (@ None of these The volume of 1 g each of methane (CH,). ethane (CH). propane (C,H) and butane (C,H) was mea sured at 350K aud 1 atm, What is the volume of rane? @) 495 cm ©) 600 cm? (© 900em* @ 1700em* sample of gas occupies 100 mL. at 27°C and 740 man pressure, When its volume is changed to 80 mi at 740 su pressure, what will be the temperature of gas? @ 216°C & 240°C (© 33°C @ 895°C AIS.TP, the density of nitrogen monoxide is? (@) 3.0eL (b) 30h (©) 134 9L7 (@) 2.68 gL The rat of effusion ofa gas is proportional to? 2 2 a » 2 o 5 oF P & © E o> If 4 g of oxygen diffuse through a very narrow hole, how much hydrogen would have diffused under identi- cal conditions? (@ Wg () 1g © M4 @) 64g The rate of diffusion of SO, and O, are in the ratio @ 1:V2 &) 132 @12 @i4 A cylinder is filled with a gaseous mixture containing equal masses of CO and N;, The pastal pressure ratio @ Ry, =Peo (©) Peo=2 Py ©) Poo= 3 Bey (@ Pco= 12 Ry Which of the following is comect relation for root mean, square velocity?” (BIBO_ Physical Chemistry: for JEE (Main & Advanced) ar BRI eu, Ole BRT M, (0) Vos (Vrs aL a © (fr) 52, As oes 30 mi yome at 27 tempere tnd "son presse volume STi (a) 162.2 mi. (©) 362.2 mL. (@) 462.2 mL. 33. A truck having oxygen cylinders is coming from Shri- nagar. The gas in cylinder is at -23°C temperature and 3 atm pressure when truck passes from Madras. What will be the pressure of oxygen gas when temperature is 30°C? (a) 2.64 atm (©) 1.64 atm (©) Latm (@) 3.64 atm 34, Find out the density of CO, at 100°C temperature and 400 mum He pressure (a) 0.75217 (b) 25e17 (©) 05e1* (@ 02e17 38, The density ofa gas at-23°C temperature and 780 tort presse is 140 gL“, entity the gas. (@ CO, (b) S80; Cl, WN 36, Calculate the weight of CH, gas when the applied pres- sure is 16 atm, temperature is 27°C and its volume is 9 litre (2 = 0.08 L atm K*. (b) 262.2 mL (@) 96g (b) 86s) 80g (A) HE 37. The density of SO, at STP is (a) 28621" (6) 1.7621" (©) 18621" (@) None of these 38, The volume occupied by 7g N, gas at 27°C tempera- ture and 750 mm Ha pressure is @) 631r © 73 © 68 @ S3ie 39, 5 qXeF gas is filled ina 6 lr vessel at 80°C temperae ture, he applied pressure on gos is @) 021 am @) 031 atm (©) 0.11 am (@) 041 atm 40. 5.75 g of gas at SS°C temperature and 0,940 atm pres- sure occupies 3.5 It volume, Identify the molecular ‘Weight of gas, @s O47 O89 OS 41. 28 g of a N, gas occupies 10 ltr volume at 2.46 atm pressure. Identify the temperature (@) 300K () 320K (©) MOK (@) 280K 2. 48. 44. 45, 46. 47. 48. 49, Agas occupies 1 SI, volume a 75 em Fig pressure. At the same temperature, what will be the volume of gas at 50 cm, Hg pressure? (a) 1.25 Ir (b) 3.25 Ir (©) 4.25 tr @) 2.25 Ir A mixtue of gases at 760 mun Hg contains 65% N, 15% 0, and 20% CO, by volume, then patial pressure of each gas in mm is (a) 494, 114, 252 (b) 494, 224, 152 (©) 494, 114, 152 (d) None of these 0.45 g of a gas having mole weight is 60 and 0.22 of another gas has 44 mole weight. The total pressure cn these gases is 75 em Hg, then partial pressure of another 22s is (@) 30cmof Hz (0) 20cmof Hg (©) lcmofHg (@) 40cm of Hg Ifthe density of a gas Ais 1.5 times that of B then the aolecular mass of A is M. The molecular mass of B will be M @ 1sM oO © 3M @ x A certain mass of gas occupies a volune of 2 Itt at STP. Keeping the pressure constant at what tempera- ‘ure would the eas oceupy a volume of 4 In? (@) 546°C @) 2738 (©) 100°C (d@) so°c 8.2 L of an ideal gas weighs 9.0 g at 300 K and | atm pressure, The moleeilar mass of gas is f@9 (b) 27 (©) 54 (@) 81 One live of an unknown gas weighs 1.25 g at N.TP. Which ofthe following gas pertains tothe above data? @ CO, (bh) NO, © NO, If pressure of a gas contained in a closed vessel is in- creased by 0.4% when heated by 1°C, what is its initial tenuperature? (a) 250K (b) 250°C (©) 2500K @ 25°C A football bladder contains equimolar proportions of ‘H, aud O,. The composition by mass of the mixture effusing ott of punctured football is in which ratio GH, 03. (@ asd &) WF © 1:22 @ 4:1 At low pressure compressibility factor is equal to: @ (1-5) © (1355) » (: 2) @ (622) . Ifa mixture containing 3 moles of hydrogen aud 1 mole of nitrogen is converted completely into ammonia, ‘what will be the ratio of initial and final volume under the same temperature and pressure? @3 Wis O21 @ir2 53. 56. st. 59, 0. 1. $0) at STP contained in a flask was replaced by O» er identical conditions of pressure, temperature and ‘volume. Then the Weight of will be of $0; (@) halt (0) one four (©) twice (@) four times 1. According to Charles law. @ (FF) =e (¢), P a ar wv wv ola) «(a . A sample of gas at 35°C and 1 atm pressure occupies a ‘volume of 3.75 lt: At what temperature should the gas be kept if tis requited to reduce the volume to 3 It at the same pressure? (a) 266°C & orc (©) 398°C @ 28°C Equal weights of methane and hydrogen are mixed in 'm empty container at 25°C, The fraction of total pres- sure exerted by hydrogen is @12 89 @isI9 @ 19 The best vaccum so far attained in laboratory is 107° ‘mm of Fig. The number of molecules of gas remain per em at 20°C in this vaccum is (@) 3.29% 10 molecules (b) 3.29% 10° molecules (©) 3.29% 10° molecules (@) 3.29% 10" molecules .. A hydrocarbon contains 10.5 g of carbon per gm of H. One litre vapours of hydrocarbon at 127°C and 1 atm pressure weighs 2.8 g. The molecular formula of hy- drocarbon is (@) Cale (0) Cs © CH, @ Cutty AOS dar flask contains gas 4 and 1 dm flask contains sas atthe same temperature. Ifdeusity of 4=3 aid’ and that of B= 1.5 g/d! and the molar mass of 4 = 1/2 of B, the rato of pressure exerted by gases is Ps Poe oo © Bo 2 2 c) Zang ay Beng oF o# 120 g of an ideal gas of molecular weight 40 are con- fined to a volume of 20 ltr at 400 K. What is the pres sure of gas is? (@) 490 atm (&) 492 am (©) 2236 atm @ 24am A cylinder contains acetylene gas at 27°C and 4.08 M Pa, The pressure in the eylinder after half the mass of gas is used up and the temperature that has fallen t0 12°C will be (a) 405 MPa (©) 3.84MPa (b) 2.025 MPa (@ 1.92MPa 2. os 66. 67. 68. 09. 0. m1. 2. 74, Gaseous State 31S The weight of 350 mL ofa diatomic gas at O°C and 2 am pressures 1g. The weight ing of one atom at NTP G@) 264x10%~¢ (2.641 © S28x10% gD) 0821 Oxygen is present ina line flask ata pressure of 7.6 x 10° nm of Hg. The number of oxygen molecules in the Mask a 0°C is (@) 27% 10° motecutes (b) 2.7 x 10"? molecules (©) 27x10" molecules (@) 2.7 10" molecules The rms. velocity of hytiogen at 27°C, R= 8314 3 mol" Kis (@) 1934 m/s () 1934 mvs (© 1934's (@) 1934 ms Tennperatre at which RMS. speed of O, is equal to that of neon at 300 Kis @) 280K () 480K (©) 680K @ 180K The most probable velocity of a neutron at 20°C is neaby (@) 220 ms () 2200ms (©) 22200 m/s (@) 2ms The RMS. speed of the molecules ofa gas of density 44 kg nr” and pressure 1.2 x 10° Nur is @ 120ms* () 300ms" (© 600ms* (@ 200ms" The RMS, velocity of a gas whose each molecule weighs 107? g and at temperature 27°C is (@) 0.70 cms () 035 cm/s (©) 0.35 ms (@) 0.70ms The average speed ofan ideal gas molecule at 27°C is 0.3 m sec", The average speed at 927°C is (@) 0.15 msec () 06 msec (© 12msect (@) 06 cmseet The temperature at which CO; has the same RMS. speed to that of Oat STP. sire (@) 37538K (@) 102.38°C (© 27538K (@20238°C The temperatize at which the most probable speed of CO, molectles be twice as that of $0°C is (@) 200°C ) 292K © 100°C @ 66K What isthe total translational and rotational cuetay of | mole of oxygen at 300 K? 314 Tmo: (@) 623553 () 623.255 (© 623253 (@ 625255 '. The kinetie energy of N molecules of O, is x Joule at 123°C, Another sample of O, at 27°C has a kinetic energy of 2x. The later sample contains ‘male ecules of 0; @N WN2 ©2N W3N The average kinetic energy in joules of molecules in 8.0 gm of methan at 27°C is isa 75, 16. 1. 78. 79. 80. 81. 82, 83. 84, 85. Physical Chemistry-l for JE (Main & Advanced) (@) 3.1% 10 Jimolecile The ratio of rates of diffusion of CO, and SO, at the same pressnre and temperature is @ 4:0 (ust (@) 1:4 (d) 1:6 20 L of SO, diffs throng a pocons partion in 60 Seconds. Volume of O; dffse nner similar conditions in 30 seconds will be (a) 12.14L, (b) 14.14L (©) 18.14L, (@) 28.14L The footballs are respectively filed with nitrogen, lnydrogen and hicitn, If the leaking ofthe wns occurs ‘wt time from the filling hole, then the ratio ofthe rate of leaking of gases (7s, : Fiz :Tze) from three footballs (im equal time interval) is (@) OVI) ©) WFD @ a:N7-Ni4) © OTN) NH, and SO, gases are being prepared in two comers ofa laboratory. The gas that wil be detected fst in the middle ofthe laboratory is (@) NH; (b) SO, (¢) Both at the same time(d) Cannot determine 10 mL of gaseous hydrocarbon on combustion gives 40 an of CO; aud $0 mil of H,O. The hydrocarbon is () CAH ©) Gill © City @) Cathy The volume of oxygen required for complete oxidation of 2 Itr of methane at NTP is (a) 12.25L, (b) 4L (IL (@ 3L LPG isa mixtuce of n-butane and iso-butane. The vole ume of oxygen needed to bum 1 kg of LPG at NTP would be (@) 22401, (b) 25101 (©) 10001, (@ S001. The viscosity of a which liquid is the maxinmm? (@) Water (b) Glycol (©) Acetone (@) Ethanol Equal masses of methane and oxygen are mixed in an empty container at 25°C. The fraction ofthe total pres- sure exerted by methane is (@) 13 ® 12 © 23 (@ (3) 273/298) Helium atom is two times heavier than @ hydrogen molecule, At 298 K, the average kinetic energy of a helium atom is (@) Two times that of a hydrogen molecules (b) Same as that of a hydrogen molecules (©) Four times that of a hydrogen molecules (@) Half that of @ hydrogen molecules The compressibility of a gas is more than unity at STP, Therefore, 86. 87. 88, 89, 90. o1. 92, 93, 94, 96. (0) V2 2247 ) %,.<224L © V=24L @ V2 4487 Ifpwo moles ofan ideal gas at 546 K occupiesa volume of 4.8 It, the pressure must be (@ 2atm (b) 3am (©) 4am @) Latm [At STP, the order of root mean square velocity of mol- ecules of H,, N,,O, and HBr is G@) H,>N,>0,>HBr (b) HBr>O,>N,>H, (©) Hisr>H,>0,>N, (4) N,>0,>H,> HBF The density ofa gas at 37°C and 1 atm is d. Pressure remaining constant at which ofthe following tempera- tures wil its density become 0.75 d? (@) 20°C (b) 30°C © 400K @ 300K At 27°C the ratio of RMS velocities of ozone to ox senis @ fs ©) © i @ 0.25 teal gas most closely approaches the behaviour of an ideal gas at G@) 15 atmand200K — (b) 1 atm and 273K (©) 015 atm and 500K (@) 15 atm and 500K At STP, 28 ltr of hydrogen sulphide were mixed with 1.6 It of sulphur dioxide and the reaction occurred ac= cording to the equation, 2HLS (g) + $0; (g) —+ 2H,0 ()) +38.) ‘Which of the following shows the volume of the gas ‘remaining after the reaction? G@) 0.2 Ir ofSO;(@) — @) 0.4 In of Fs (@) (©) 12Mtrof 8 (@) —_@) 1.2 ltr of $0, (e) The rates of diffusion of SOs, CO3, PCI; and SO, are in the following order: (@) PCly> 80, > SO, > CO, (b) CO,» $0, > PCI, > $0, (©) SO;>80; > PCL, > CO, (4) CO,» $0, > $0, > PC, Acclosed vessel contains equal mumber of nitrogen and oxygen molecules at pressure of P mm. If nitrogen is, removed from the system, then the pressure will be @P &2P ©P2 @P The rate of diffusion of methane at a given temperature is twice that of gas X. The molecule weight of X is @ 640) 320 40 @) 80 RMS velocity of SO, , RMS velocity of $0, i The rio. ENT Salty oF He * OF MD lone and helium gases at 30°C is equal to @4 (025 @aw @s A certain volume of argon gas (Mol. Wt. 40) requires 45 sto affse through a hole at a certain pressure and temperature, The same volume of another gas of un- Jnown molecular weight requires 60 s to pass through the same hole under the same couslitions of tempera ture and pressure, The molecular weight of the gas is @3 35 © @ 120 97, A chemist has synthesised a greenish yellow gaseous compound of chlorine and oxygen and finds that its density is 7.71 g/L at 36°C and 2.88 atm. Then the mo- lecular formula of the compound will be (@ ClO; (b) ClO; © ClO @ C1,0) 98. When a gas is expanded at constant temperature. (a) the pressure decreases (b) the Kinetic energy of the molecules remains the (©) the kinetic energy of the molecules decreases. (@) the number of molecules ofthe gas decreases. 99, At what temperature will the total KE. of 0.3 mol of He be the same as the total KE. of 0.40 mol of Ar at 400 K (a) 533K (6) 400K (©) 346K (@) 300K If molecules ofthe gas are sphcrical of radius 1 A, the ‘volume occupied by the molecules in 1 mol ofa as is: (a) 22400 mt. @) 2247 (©) 252mL (@) 422m. , The volume of O» and CO, at atm and at body temperature of 37°C, assum- {ng 10 Ir blood in human body. would be (9) 2 ber, Ir (b) Stir 45 tte (© 159,462 Ie (A) 3.82 te, 4.62 I ‘When 2 g of a gas "is introduced into an evacuated flask kept at 25°C, the pressure is found to be I atin. If 3 g of another gas ‘B" is then added to the same flask, the total pressure becomes 1.5 atm. Assuming ideal 20s ‘behaviour, calculate the ratio of molar masses M, : My @i3 Wl4 Ol O31 S mL of a gaseous hydrocarbon was exposed to 30 ml of ©}. The resultant gas, on cooling is fomnd to mea- sure 25 mL, of which 10 mL was absorbed by NaOH and the remainder by pyrogallol. All measurements are made at constant pressure and temperature. The mo- lecular formula of the hydrocarbon is, @ Gh W Cie © CH @ CH A gaseous compound X contained 44.4% C, 51.9% N and 3.7% H. Under like conditions 30 cm’ of X dif fused through a pinhole in 25 sec and the same volume of Fh, diffused in 4,81 sec, The molecular formula of X is (@) CHIN @) GH © CHN, (@ CNA The density of the gsseow mise (He and N) ew at NTP, What is the percentage composition of Fie and N, by volume in this mixture respectively? (@) 75%, 25% (b) 25%, 75% (©) 30%, 70% (@ 40%, 60% ‘A gas bulb containing air is connected to an open limb manometer at 27°C and at 750 mm Hg. Assuming that initially the level of Hg in the both limbs were same. ‘The bulb was heated to 77°C, what will be difference in the levels of Ha in two limbs? (Assuming the volume difference of the gas produced is negligible at higher ‘emperarure). (@ 7.5 cmHg (&) ScmBg (© 6cmHs @ 125 cme In the following graph of Maxwell-Boltzmann distri« bution of molecular velocities n olecules Velocity [BIB4 Physical Chemistry: for IEE (Main & Advanced) M4 16. a. 18. 19, 20. 21, 2. 23, ‘Which of the following is the correct order of tempera~ ‘ure? @ T. 7.) then what will be the final pressure? @ o 2h T+h 2h © TE A balloon containing 1 mole air at 1 atm initially is filled further with ai til pressure increases to 4 atm. The inital diameter ofthe balloon is 1 m and the pres- sre at each stage is proportion to diameter of the balloon. How many number of moles of air added to change the pressure fom I atm to 4 atm? (a) 80 (b) 287) 255d) 256 What isthe density of wet air with 75% relative humid dty at 1 atm and 300 K2 Given : vapour pressure of 0 30 torr and average molar mass of air is 29 ¢ mot? (@) 1614 g1. (©) 0.96 gi. © 10681. (@) 1264 gt. Calculate minimum number of balloons each of vol- une 82.1 L required to lift a mass of 1 ke to a height of 831 m. Given : molar mass of air = 29 gino, tem- _petature is constant at 290 K and mass of each balloons is 40 g, [Use e®4 = 069, pressure at sea level = I atm, acceleration due to gravity (g) = 10 m/s"}, @ 10 20 © 25 Onn @ 50 Gaseous State 3188 $0, > CH, > CO, 9. The critical compressibility factor Ze for O> is 0.308, and its critical pressure and critical volume are $0.1 aim and 7.8 x 107 ltr mot respectively. The Boyle temperature of O) is (in dex K) @) 348.6 (b) 2154 (©) 1545 (@) S214 10, At extremely low pressures, the Van der Waals equa- tion for one mole of a gas may be expressed as (BBE Physical Chemistry: for IEE (Main & Advanced) uu. 2. 1B 14. 16. a. 18. 19, &) Ar-5) srr & @) Prot S T © @+a(v-b) Integer-Types Questions Td) PY=1.2RT One mole of nitrogen gas at 0.8 atm takes 38 seconds, to diffuse through a pinhole, witereas one mole of an ‘unknown compound of xenon with fluorine XeFx at 1.6 atm takes $7 seconds to diffuse through the same hole. Find out the value of x. 9 mL of a gaseous mixture consisting of a gaseous compound A and just sufficient amount of oxygen re- «quired for complete combustion, yielded on burning. 4 mL of CO,, 6 mL of water vapour and 2 mL of N,, all ‘volumes measured at the same temperature and pres- sure, If compound a contained only C, H and N, how ‘many volumes of oxygen ate required for complete combustion, 0.9 smn of an onsanie compound (Mol. wt = 90) con- tains carbon, hydrogen and oxygen requires 224 mL of oxygen at STP for complete combustion. After the combustion, the gases occupy 556 ml. at STP. On pass- ing it through KOH solution, the volume reduced to 112 mL. If the compound has formula CyFHyOzx. then find out the value of X ‘At 400 K, the root mean square (rms) speed of a gas X° (Mol. wt. = 40) is equal to the most probable speed of 2as Vat 60 K. What is the molecular weight of the ans Yn . Two flasks 4 and B have equal volumes. A is main- tained at 300 K and B at 600 K. While 4 contains H gas, B has an equal mass of CH, gas. Assuming ideal behaviour for the both gases find the rato of (uav)4 (wav. ‘A lask of capacity of 1 L containing NH, at Latm and 25°C. A spatk is passed lurough wnt all the NH, is de- composed in Ny and FH, Caleulate the pressure of gases left at 25°C after the reaction, A compound exists in the gaseous phase both as mono- ‘mer (A) and dimer (A,). The atomic weight of Ais 48. In an experiment 96 g of compound was confined in ‘vessel of volume 33.6 Land heated to 273°C. Caleulate the pressure developed ifthe compound exists as dimer to the extent of $0% by weight under these conditions. ‘The compressibility factor for nitrogen at 330 K and 800 atm is 1.90 and at $70 K and 200 atm is 1.10.A certain mass of Ny occupies @ Volume of 1 dim? at 330 K and 800 atm. Volume occupied by same quantity of [N, gas at 750 K and 200 atm in ite is If the slope of Z (compressibility factor ) vis p curve is constant (slope = w/492.6 atmr*) ata particular tem- perature (300 k) and very high pressure then calculate diamter of the molecules in A, (Given N= 6.0% 10". R= 0.0821 atin lit ol") 20, Twomoles ofa gas are confined to a $I flask at 27°C. Caleulate its pressure using Van der Waals equation, For ammonia, atm it™® mot and &=0.037 litmiol”, 21, What will be the temperature difference needed in a hot air balloon to lift 1.0 kg weight? Assume that the ‘volume of balloon is 100 m, the temperature of atmo- sphere is 25°C and pressure is 1.0 atm. Average molar mass of air is 29 amu. 22, 4 gf anideal ans was introduced into a bulb of volume of 0.821 dm at certain pressure, P and temperature 7. The above bulb was placed in a thermostat maintained at temperature (7+ 125) K of 0.8 am of the gas was left off to keep the original pressure. Calculate the pressure in atmospheres, [Molecular weight of the gas is 40 a ‘mole and R value is 0.0821 litatm-K"! mol. 23, Pressure in a bulb dropped from 2000 to 1500 mum in 7 minte when the oxygen leaked through a small hole. The bulb was then completely evacuated. A mix- ture of oxygen and another gas of molecular weight 79 {in molar ratio 1-1 ata total pressure of 4000 mm was {ntroduced, Find the motar ratio of two gases remain ing in the bulb after a period of 74 minute, 24, The composition of the equilibrium mixture, (Cl, = 2C)) which is attained at 1200°C, is determined by measuring the rate of effusion through a pinhole It is observed that at 1.80 mm Hg pressure, the mix- ‘are effuses 1.16 times as fast krypton effuses under ‘the same conditions. Calculate the fraction of chlorine molecules dissociated info atoms. (At. wt. of Kr = 84) 25, A mixture of ethane and ethene occupies 40 Ir at 1.00 atm and at 400 K. The mixture reacts completely with 130 gm of O, to produce CO, and HO. Assuming ideal behavior, calculate the mole fraction of C,H, and CH, in the mixture? 26, The total pressure of a mixture of H, and O, is 1.00 bar. The mixture is allowed to react to form water which is completely removed to leave only pure a a pressure of 0.35 bar. Assuming ideal gas behavior and that all pres- sture meastrements we made under the same conditions of tenaperanure and volume, calculate the composition of the original mixture 27, The degree of dissociation is 0.4 at 400 K and 1.0 atm for the gaseous reaction PCL(g) —* PCIe) + Cle). Assuming ideal behavior of all gases, calculate the den- sity of equilibrium mixture at 400 K and 1.0 atm. ( 31, C1=35.5) 28. The pressure exerted by 12 om of an ideal gas at °C in a vessel of volume ¥'Itr is one atm. When the tem- perature is increased by 10°C at the same volume the pressure increased by 10%. Calculate the temperature ¢ and volume v? (Mol. Wt. = 120) 20, The density of the vapour of a substance at 1 atm pres- sure and 500 K is 0.36 kg mr, The vapour effuses through a small hole at arate of 1.33 times faster than oxygen under the same condition 30. aL 32, 33. MM. 36. 37 38, 39. 40. ‘Determine (i) molecular weight, (ii) molar volume, (iii) compression factor (Z) of the vapour and (iv) which forces among the gas molecules are dominating: the at- tractive ofthe repulsive? [AT27°C, H, gasis leaked through a tny hoe into aves- sel for 20 nits. Another tnknown aos. atthe same tent pernmire and presse, as that of Fis leaked through the same hole for 20 mts. ter the effusion ofthe ans- es the mixmare exerts presnre of 6 atm. I His 0.7 mol and volume of vessel is 3 It, calculate molecular ‘weight ofthe unknown gs. 1 ltr flask contains O, at 0°C and 7.6 x 10~!° mm Hg. Calculate the numberof molectles of O* present. ‘Assuming that N2 molecules is sphcrical and its radius is 2 x 10° metre, calculate the empty space in one sole of N2 gas at NTP A class bulb of 1 lr contains 2 x 1021 molecules of nitrogen exerting pressure of 7.57 x 103 Nm. Calcu- late (a) the root mean square velocity and temperature of the gas molecules and (b) Umpv of gas molecules at this temperature ‘Two grams of gas A are introduced in an evacuated flask at 25°C, The pressure of the gas is 1 atm, Now 3 g of another gas B is introduced in the same flask, the {otal pressure becomes 15 atm, Calelate (a) the ratio of molectlar mass MA and Mi and (b) volume of the vesel ifs 0" 1 ltr O° and 1 Its H? are taken in a vessel of 2 ltr at STP, “These gases are made to react to form water, Calculate (@) moles and weight of water formed (b) amount of gas left in the vessel and (¢) total pressure of the gas at 10 A long rectangular box is filled with chlorine (at.wt. 35.45) which is known to contain only *°C] and °7C1. If the box cau be divided by a partition and the two types of chlorine molecules putin the two compari- ments respectively, calcualte where shou the partition ‘be made if the pressure on both side are to be equal. 3.6 g of an ideal gas was injected into a bulb of internal volume of 8 L at pressure P atm and temp 7K. The ‘bulb was then placed in a thermostat maintained at (7 + 15)K 0.6 g of the gas was let off to keep the original pressure. Find P and Tif molecular weight of is 44. A toy balloon originally held 1.0 g of He gas and had a radius 10 em, During the night, 0.25 ofthe aas ef fused from the balloon, Assuming ideal as behaviou tinder these constant? and T conditions, what was the ‘dis ofthe balloon the next morning?” If scuba diver isto remain submerged for 1 hr. what pressure must be applied to force sufficient air into the tank to be used. Assume 0.5 dm’ of air per breath at standard atmospheric pressure, a respiration rate of 38 breaths per minute, and a tank capacity of 30 dm’. While resting, the average human male uses 0.2 dm’ of , per hour at STP for each kg of body mass. Assume 41. 2. 8. 44. 45, 46. 47. 48. 49. Gaseous State 3187 that all this ©, is used to produce energy by oxidis- ing glucose in the body. What is the mass of glucose required per hour by a resting male having mass 60 kg. What volume. at STP of CO, would be produced? 12.@Ns, 4 gH, and 9 gO, are put into a 1 ltr container at 27°C, What isthe total pressure? 1.0 x 107 kg of hydrogen and 6.4 x 10" kg of oxygen, are contained in a 10 x 10" m? flask at 473 K. Caleu late the total pressure of the mixture. Ifa spank ignities the mixture, what will be the final pressure? At room temperature, NH; gas at one atm and HCI gas at "P* atm are allowed to effuse throuah identical pin holes to the opposite ends of a alass tube I'm long and ‘uniform cross section, A white deposit is observed at a distance of 60 em from the HCI end. What is P. A gas mixture contains equal number of molecules of ‘Nz and SF, some of it i passed through a gaseous ef- fusion apparatus. Calculate how many molecules of Ny arc present in the product gas for every 100 molecules of SF 5 ‘Two gases NO and O; were introduced atthe two ends of a I mtr long tube simultaneously (tube of uniform cross section). At what distance ftom NO gas end, brown fiames will be seen? ‘At 20°C tivo balloons of equal volume and porosity are filled to a pressure of 2 atm, one with 14 kg Np and other with 1 kg H, The Ny balloon leaks to a pressure of 2 atm in one hour. How long will i tke for H, bale 2 Joon to leak toa pressure of 2 arm? Pure O diffuses through an aperture in 224 see, where a mixture of Oy and another gas containing 80% O» diffuses fiom the same in 234 sec. What is molecular weight of the gas? A space capsule is filled with neon gas 1.00 atm and 200 K. The gas effases through a pin - hole into outer space at such arate that the pressure drops by 0.3 torr/ (@) If the capsule were filled with ammonia at the same temperature and pressure, what will be the rate of pressure drop? If the capsule were filled with 30.0 mol % heli- ‘un, 20.0 mol%6 oxygen and $0.0 mols nitrogen ata total pressure of 1.00 atm and a temperature of 290 K. what will be the corresponding rate of pressure drop? ‘Show that the height at which the atmospheric pressure 0.69327 is reduced to haf ts value is given by /i= ‘given by Me Calculate the pressure of a barometer on an aeroplane which is a an altitude of 10 km. Assume the pressure to be 101.325 kPa at sea level and the mean temperature 243 K. Use the average molar mass of air (80% N, 20% 0). © (BIBS Physical Chemistry: for JEE (Main & Advanced) 51. An iron cylinder contains helium at a pressure of 250 kPa and 27°C. The cylinder can withstand a pressure of 1 x 10° Pa, The room in which cylinder is placed catches fire. Predict whether the eylinder will blow ‘up before it metls or not, [Melting point of eylinder = 1800 K] 52. Determine the molar mass of a gas if its pressure is to fall to one-half of its value in a vertical distance of one metre at 298 K. 53. The time taken for a given volume of gas E to effuse through a hole is 75 sec. Under identical conditions, the same volume of a mix of CO and N; (containing 40% of Np by volume) is effsed in 70 see. Caleulare G) the relative molecular mass of E, and (i) the RMS velocity (in ms“ units) of Eat 0°C. 54, At what temperature in °C, the Ums of SO, is equal to the average velocity of O, at 27°C? 55. The density of CO at273 K and | atm is 1.2504 ke mr, Cafeulate (a) root mean square speed, (b) the average speed and (c) most probable speed. $6. Calculate the temperature values at which the mol- ecules of the fist two members of the homologous se- ties C,Hog.o Will have the same RIMS speed as CO, gas at 770K, The normal bp. of n-butane is 273 K. Assuming ideal gas behaviour of r-butane up to this ‘temperature, calculate the mean velocity ans the most probable velocity ofits molecules at this temperature, 57. Calculate the temperature at which the root mean square velocity. average velocity and most probable velocity of oxygen gas are all equal to 1500 ms"! 58, The compressibility factor for Np at -50°C and $00 atm presse is 1.95 and at 100°C and 200 atm, it is 1.10. ‘A certain mass of nitrogen occupied 1 Itrat-S0°C and 800 atm. Calculate the volume occupied by the same quantity of N; at 100°C and 200 atm, 59, At 273.15 K aud under a pressure of 10.1325 MPa, the compressibility factor of O, is 0.927. Calculate the mass of O, necessary to fill a gas cylinder of 100 dm? capacity under the given conditions (60. The Van det Waals constant for 0, are a= 1.36 atm 1? ‘mot and 6 = 0.0318 L mot". Calculate the tempera- ture at which O, gas behaves, ideally for longer range of pressure. 61. Show that at low densities, the Van der Waals equation (>-g.)on-o-ar and the Dieterici's equation P{V,, - 5) = RT exp CalRTV,) given essential the same value of p. (62, Calculate from the Van der Waat's equation, the tem- perature at which 192 g of SO; will oceupy a volume of 10 dav? at 15 atm pressure. [4 = 6.7 atm L? mol”, }=0.0564 L mot”) (63, Calculate the pressure of 15 mol neon at 30°C in a 12 ltr container sing @ the ideal gas equation (ii) the Vander Waals equation {a= 0.2107 atm L? mol, b= 0.0171 L mol) 64, What wll be the temperature difference needed in a hot air balloon to lif 1.0 kg of mass? Assume thatthe vol- ‘une of balloons is 100 mi’, the temperature of ambient air is 25°C, the pressure is I bar, and air isan ideal gas ‘with an average molar mass of29 g mol" (hot and cold both. 65. One mole of a non-linear tiatomic gas is heatted in a closed rigid container from S00°C to 1500°C. Calew Jate the amount of energy required if vibrational degree of freedom become effective only above 1000°C. 66, Therespiration ofa suspension of yeast cells was miea- sured by determining the decrease in pressure of the aas above the cell suspension. The apparatus was ar- ranged so that the aas was confined to a constant vol- lume, 16 cin and the entire pressure change was caused by uptake of oxygen by the cells. The pressure was rieasured in a monometer, the Muid of which had den- sity of 034 g/cm’. The entire apparatus was immersed {na thermostat at 37°C. Ina 30-mis observation period, the fuid in the open side of the manometer dropped 37 mm. Neglecting the solubility of oxygen in the yeast suspension, compute the rate oxygen consumption by the cells in mms of O, (STP) per how. 67. Ina basal metabolism measurement timed at 6 mts, a patient exhaled $2.5 L of air measured over water at 20°C. The vapour pressure of water at 20°C is 17.$ tor: Tie barometric pressure was 750 tor. The exhaled air analysed 16.75 volume % oxygen and the inhald air 20,32 volume % oxygen. Both om a dry basis nealect- ing any solubility ofthe gases in water and any differ- ence in the total volumes of inhaled and exhaled ai, calculate the rate of oxygen consumption by the patient in mt (STP) pet minute 68. The temperature and the relative humidity of air are 20°C and 80% on a certain day. Find the fraction ofthe ‘mass of water vapour that will condense ifthe tempera- ture falls to $°C. Saturation vapour pressures at 20°C and $°C are 17.5 mm and 6.5 mmm of Hg respectively 69, 6.0 a of He having average velocity 4 x 10° ms" is mixed with 12.0 g of Ne” having the same average ‘velocity. What isthe average kinetic enersy per mole inthe mixture? 70. Molar volume of He at 10.1325 MPa and 273 K is 6.011075 times its molar volume at 101.325 kPa. Cal- culate radius of He atom assuming negligible 7A. The vital equation for ethane gas is given by PY= RT. + BP_At °C, B=-0.1814 Limol. Calculate volume of cone mole of ethane at 10 atm, anda! 72. Pressure of He gas confined in a stel chamber drops from 4.0 to 1.0 atmosphere in 4 hrs due to diffusion through a pin hole in the steel chamber. If an equimolar mixture of He and methane gas at 20 stmmosphere and the same temperature are confined in the same cham- n. 4 76. 1. 78. ber, what will be the partal pressure of He and methane after In, Assume rate of diffusion tobe linear function of gas pressure and inverse fiction of square 100t of ‘molar masses, ‘A [Ite flask containing NH (g) at 2.0 atmoshpere and 300 K is connected to another 800 mi. flask containing HCI (g) at £0 atmosphere and 300 K by means of a narrow tube of negligible volume and gases were al- lowed to react quantitatively as NA, (@) + HCl (g) —+ NH,CI (6) ; DH =~ 43 kmol Itheat capacity of HCl (g) CV is 20 JK‘ mol“, deter- ‘mine final pressure inside the flask assuming negligible heat capacity of flask and negligible volume of solid NH,CL. Calculate the value of . 4 Z, and Z, for nitrogen mol- cules at 25°C and at pressure of 10° mm Hs. Given that 6 for nitrogen is 39.1 cm? mol". . The mean free path of the molecule of a certain gas at 300 K is 2.6 x 10° m, The collision diameter of the ‘molecule is 0.26 nm. Calculate (a) pressure of the gas, and (b) number of molecules per unit volume of the gas. There are two vessels of sante consisting same number of moles of two different gases at same temperatute One of the gas is CH, and the other is unknown X. As suming that all the molecules of X are under random ‘motion whereas in CH, except one all are stationary. Caleulate Z, for Vin terms of Z, of CH,. Given that the collision diameter for both gases are same and (U,,)8 FU est A mixture of CH, and O, is used as an optimal fel if is preseat in thrice the amount required theoretically for combustion of CH,, Calculate number of effusion steps required te convert a mixture containing one part of CH, in 193 parts mixture (parts by volume. If calo- rifie value (heat evolved when I mole is burt) of CR is 100 cal'mole and if after each effusion 90% of CH, is collected, find out what initial mole of each gas in ini- tial mixture required for producing 1000 eal of energy after processing? {Given 0.9)°= 0.6] A closed vessel of known volume containing known amount of ideal gaseous substance A’ was observed for variation of pressure with temperature. The expected raph was to be like (i) However actual observations evealed the araph to be like. (i) The deviation was attributed to polymerisation of gas molecules as ‘BA(g) = Ang). If itis known thatthe above reac- tion gave only 50% yield a (@) calculate the ratio of "= (here nexp= Mo * Total munter of gaseous mole actually prescat ticoritcal= Total munberofinole risa taken) Pam) 79. 80. SI. 82. Gaseous State 3189 (b) Find the valne of » to which the gas A is being ‘polymerised int. 32, + 10) t =| Teo) @ Expected During one of his adventures, Chacha Chaudhary got trapped in an underground eave which was sealed 200, yrs back. The air inside the cave was poisonous, hav ing some amount of carbon monoxide in addition t0 ©, and N;, Sabu, being huge could not enter into the cave, so in order to save Chacha Choudhary he started sucking the poisonous air ont of the cave by mouth Each time, he filled his Innge with cave air and exhaled it out in the surroundings. In the mean time, fresh air fiom surrounding effused into the cave till the pressure ‘was again one atmosphere. Each time Sabu sucked out some ait, the pressure in the cave dropped to half of its initial value of one atmosphere If the intial sample of air from the cave contained 5% by volume CO. If the safe level of CO in the atmo- sphere is less than 0.001% by volume, how many tines does Sabu need to such out air in order to save Chacha Choudhary. Acclosed vertical eylinder is divided into two parts by a ftictionless piston, each part contains 1 mole of air. At 27°C, the volume of the upper partis four times than that of the lower part. Calculate the temperature when. volume of the upper part will be three times that of the lower part. Awater gas mixture has the composition by volume of | 50% H,, 40% CO and 5% CO, (@ Calenlate the volume in litres at STP of the mix ture which on treatment with excess steam will contain 5 ltrs of H,. The stoichiometry for the wae ter gas shift reaction is CO+H,0 + C0, +H, Find the density of the water gas mixture in @ (iii) Calculate the moles of the absorbants KOH, Ca(OH), aud ethanolamine. HO ~ CH, ~ CH, ~ NH, required respectively to collect the CO, gas obtained, A gas present in a container connected to fiietionless, weightless piston operating always at one atmosphere ‘pressure such that it permits flow of gas outside (with ‘no adding of gas). The graph of m vs T (Kelvin) was plotted and was found to be a straight line with coordi- nates of extreme points as (300, 2) and (200, 3). Cal late (BO Physical Chemistry: for JEE (Main & Advanced) (i) relationship between 7 and T (i) relationship between Vand 7 (ii) Maxima or minima value of '* 83. Find the critical constant (Pe, Ve and Te) in terms of A and B. Also find compressibility factor (=) for the fol- lowing equation of state: where 4 and B are constant, P = pressure and = molar volume. 84, Calculate the mass of mercwy in a uniform column 760 mum high and 1.00 cm* in cross-sectional area. Is, there any change in (a) mass and) (b) pressure of column of same height but with 2.00 cm! cross-sectional area is taken? (Density of He = 13.6 gicm’) 85. The diameters of a bubble at the surface of a lake is 4mm and at the bottom of the lake is 1 mm. If atmo- spheric pressure is 1 atm and the temperature of the lake water and the atmosphere are equal, what is the depth of the lake? (The density of lake water and He are 1 guviml. and 13.6 guviml. respectively. Also ne lect the contsibution of pressure due to surface tene sion) 86. At room temperature, following reaction goes to com- pletion: 2NO+0,—>2N0, —>N.0, Dimer NO, at 262 K is solid. A 250 mL flask and a 100 ml flask are separated by a stop cock. At 300 K, the nitric oxide in the large flask exerts a pressure of | 11083 atm and the smaller one contains O, at 0.789 at, The gases are mixed by opening the stop cock and afer the ead of the reaction, the flasks are cooled to 220 K. Neglecting the vapour pressure of dimer. Find out the pressure and composition of gas remaining at 220 K (Assume gases behave ideally). 87. 1 mole of N, and 3 moles of Hy are mixed in 8.21 It container at 300 K to form NE. If equilibrium average molecular mass was found to be 34/3 gram thea find partial pressure of each component. 88. One litre Hask contains ait, water vapour and a small amount of liquid water at a pressure of 200 mm-Hg. If ‘his is connected fo another 1 Ir evacuated flask, what will be the final pressure of the gas misture at equi- librium? Assunne the temperature to be SO°C. Aqueous tension at S0°C = 93 mm-Hig. 89. A500 mi bull is filed with CH, ata pressure of J atm and oxygen ata pressure of 4 atm at 27°C. The mixture 's then exploded, when the reaction CH, + 20, —> CO, = 2H,0 (1) occurs. Calculate the pressure if the final temperature is 27°C. Aqueous tension at 27°C is 26.7 mm, 90. o1 92. 93. 94, 94, 95. 96. 97. ‘What is the difference in the density of dry air at 1 atm and 25°C and moist air with $0% relative humidity un der the same condition? The vapour pressure of wa ter at 25°C is 23.7 Tom and dry air has 75.5% N; and 24.596 0, ‘A sample of butane gas C,Hy9 of unknown mass is con- tained in a vessel of unknown volume V at 25°C and a pressure of 760 mi-Hg. To this vessel, 8.6787 ¢ of neon gas is added in such a way that no butane i lost, from the vessel. The final pressure inthe vessel is 1920 ‘mm-Hu at the same temperature. Calculate the volume of the vessel and the mass of butane. Amixture of CO and COs is found to have a density of 1.50 gtr at 30°C and 730 mm. Calculate the composi- tion of mixture. ‘The pressure in a bulb dropped from 2000 to 1500 mm. cof meteury in 47 minutes when the contained oxygen leaked through a small hole, The bulb was then com- pletely evacuated, A mixture of oxygen and another gas of molecular weight 79 in the molar ratio of 1: 1 at a total pressure of 4000 mm of mercury was introduced. Find the molar ratio of the two gases remaining in the bulb after period of 74 minutes. L mole of CCl, vapours at 77°C oceupies @ volume of 35.01. Ifvander waal’s constants are a= 20.39 L? atm mol and 5 = 0.1383 L mol", calculate compressibil- ity factor Z under, (a) ow pressure region and (b) high pressure region, One mole of nitrogen gas at 0.8 atm takes 38 sce to diffuse through a pinhole, whereas one mole of an un- known compound of xenon with fluorine at 1.6 atm takes 57 sec to diffuse through the same hole. Deter- ‘mine the molecular formula of the compound Which of the following statements is correct? (@) He diffuses a arate of 8.65 times as much as CO does (b) He escapes at a rate of 2.65 times as fast as CO does (6) He escapes ata rate of 4 times as CO; does (@) He escapes at a rate 4 times as fast as SO, does The pressure of an ideal gas is increased isothermally at 298 K ina SL vessal from 1 bat to 2 bar, The comect, option (s)is fare (@) AG=2.7 kVimol © AS, <0 @ MS gers One mofe triatomie vapours of an tinknown substance 4 effses = times faster than] mole Oy nde same con- ditions. if the density of uiknown vapours at pressure ‘and temperature Tis d, which of the following holds true forthe unknown substance? (@) deze = 0.8035 1 ©) Zatomic number) =6 (© Zcompress ibility factor) = 18 aRT (@ Vapour density = 9 PREVIOUS YEARS’ QUESTIONS: OF JEE (MAIN & ADVANCED) |. The number of moles per litre in the equation PI ok is expressed by [AIEEE -02] P Pv O ar O a RT © a (@) None of these >. The correct value of Ris [AIEEE-02] (082 litre atm 314 10” erg K+ mot 1K mor" (@) None of the above . As the temperature is raised from 20°C to 40°C, the average kinetic energy of neon atoms changes by factor of which of the following ? [AIERE-04] @ 12 &) YORI (©) 3132293 @2 In Van der Waal’s equation of state of the gas law, the constant bis measure of IATEFE-04] (a) intermolecular repulsions (b) intermotecular atraction (©) volume occupied by the molecules (@) intermolecular collisions per unit volume The ratio between the RMS. velocity of Hh at 50K and that of Oat $00 K is EE 1996] wt 2 ©1 @ v4 5. X mL H, gas effuses through a hole in a container in S see. The time taken for the effusion of the same volume of the gas specified below under identical conditions is [IEE 1996}, (a) 10sec, He (b) 20sec, 0, (©) 25sec. CO (@) 55sec, CO, 1. One mole of N,O, (a) at 300 K is kept ina closed con- tainer under 1 atm, It is heated to 600 K when 20% by mass of NO, (a) decomposes to NO; (g). The resultant ‘pressure is WEE 1996] (a) 12am (b) 24am (c) 20am @ 10am 3. One way of writing the equation for state for real gases ws praat[tben] whos i con [JE 1997] Derive an approximate expression for 'B' in tems of ‘Van der Waals constant‘ and According to Graham's law, ata given temperature the ratio of the rates of diffision 7 of pases 4 and B is (SEE 1997] o (GF siven by @ a) - 10, u. 2. 4 15, 16. 1. 18, 19, A gas will approach ideal behaviour at al Gaseous Sate BMY" 34 (2 © Had © Zhe An evacuated alas vessel weighs $0.0 g when empsy, 148.0 then filled with a liguid of density 0.98 mt and 405g when filed with an ideal gas at 760 nn 11 300 K.Deterin the molecular weight of the zs. Using Vin der Waals equation calculate the constant ‘at when 2 moles ofa gn coutined in a4 Ir Mask ex- extsa pressure of 1.0 atm a temperate of 300 K- The valuc of "b" is 0.05 Itr mol!, [JEE 1998) One mole of N; gas at 0 atm takes 38 se fo diffse ‘through a pin hole, whereas one mole of an unknown compotnd of Xenon with Fat 6 atm takes $7 se 1 Gis through the sme hole Calculate the molecular formula of the compound. [JEE 1999] [JEE 1999} (a) low temperature and low pressure ()) low temperature and high pressure (©) low pressure and high temperature (@) high temperature and high pressuse The compressibility ofa gas i less than unity at STP. Therefore [SEE 2000} @) V>24L () ¥,<224L © V,=224L @ Vi=48L The RMS. velocity of hydrogen is V7 times the RMS. velocity of nitrogen. 1f Tis the temperature of the gas, IJEE 2000) (@) TH)=T) ——(B) TH)> TH) © TH)<7N) — ) TH= V7TN) Calculate the pressure exerted by one mole of CO, gas at 273 K, if the Van der Waals constant a = 3.592 dm® atm mol”, Assume that the volume occupied by CO, molecules is negligible. [EE 2000) The compression factor (compressibility factor) for cone mole of a Van det Waals gas at 0°C and 100 atmo- sphere pressure is found to be 0.5. Assuming thatthe volume of a gas molecule is nealisibe, calculate the Van der waals constant “a SEE 2001] The density ofthe vapour ofa substance at 1 atm pres- sure and 500 K is 0.36 Kg mr. The vapour effuse through a small hole a arate of 1.33 times faster than oxygen under the same condition. [SEE 2002} (@) Determine (@ Molecular weight : (ii) Molar volume ; (iii) com- pressibility factor (z) of the vapour (iv) Which forces among the gas molecules are domi- nating the attractive or the repulsive? (b) If the vapour behaves ideally at 1000 K, deter- nine the average translational KE. of a molecule. The average velocity of gas molecules is 400 m/sec. Calculate its (R.M.S) velocity at the same temperature. [JEE 2003] (BIE2_— Physical Chemistry- for JEE (Main & Advanced) 20, Positive deviation from ideal behaviour takes place be- cause of [JEE 2003] (a) molecular interaction between atoms and PY PE oy RT (©) molecularinteractionbetweenatomsand - < RT : an (©) finite size of atoms and ">= v (@) finite size of atoms and “>= <1 21, For areal gas obeying Van der Waal's equation a graph is plotted between PY, (»-axis) and P(x-axis) where V,, is molar volume, Find y-intercept of the graph, [SEE 2005] 22, The ratio ofthe rate of diffusion of hetium and methane inder identical condition of pressure and temperature will be [JEE 2005] @4 2 ol @ 05 ® 4@ Sm 6 © 4) 1. @ 16 @ 2E %@ 2% @ 34 @) 35 @ 36 © 4 @ 4.0) 46 @ 34 @) 38. @ 56 &) 64. @) 65.) 66, @ 40) 7% @ 76 © 84.) 8 @ 86, © Aa 95.) 96 L@ 2@ 3@ 4@ 5@ 6 L@® 2@ Be MW@ 160 16 2.@ 2@ 23.0) 4 %@ 2% <8 Lever m 1 A342 B sO 340 2 (A >¢B) 35 © >7.5D) spar 4 @ 6% 720 8@ 9@ 10 2) 16, Qatm)17, atm) 18. 4) 19. (SA) 20. (Keay =0.66) 26. (Ny, =0.78) 27. G46 gL) (i) (AF= 18.1}, Gi) [50.27 x 10° me], Git) [1.225], Gv) [Z> 1 repulsive] c ! eA a Py. 23, Site i 2 a oy Ls, ‘a= Van der Waal's constant for pressure correction ‘b= Van der Waal's constant for volume correction Pick the incorrect statement only. [IEE 2006] (a) For gas A, if a = 0, the compressibility factor is, directly proportional to pressure, (b) For gas B, if b = 0, the compressibility factor is directly proportional to pressure, (©) For gas C, a #0, 50, itcan be used to calculate a and b by giving lowest P value and its intercept with Z=1. (@ Slope for all three gases at high pressure (not shown in graph) is positive | Answer Key (] ® 7@ 8&§@ © 1 w © 70 B@ 9 2 @ 270) 8 @ 2% 300) @ 3.@ 8@ 9 4.0) © 40 8 © 9 @ 50 @ © 3 © BH 92 © 6. oH @ 6) 68) 6 @) 70. @ & 7. @ 7% @ 7% @ 80. &) @ 8 @ 8 © 9% © © © 97.) 98. @_—-9% 100. &) © 720 8&@ %®@ Le ® 7@ B@ BO 2@ © 27.@ B@ 2») As B)>5© +p.GO p40 A) >5 BPC) 50) 34 @ © 127m) 3.@) 14. a) ©) 2G) 22, Gatm)23. (1.236) 24. 0.138) 28. (100K and 0.82 L) 30. (Af= 1033 g Mor) Gaseous State 38 |. (2.68 x 10°) 32. (99.9%) 33. (494.2 msec. and 405.26 m/sec.) 34. (a) 1/3 (b) (1.53 lit.) (a) [0.803 gram], (b) [0.71 gram], (c) [1.02 atm] 36. [3.4421] 37, [0.062 atm, 75 K] [r=90886em) 39. [P=38aim] 40. [11.9991] 41, [66.74 1m] 42. [19.66 x 10° Nim] [P=21979a1m) 44. [x=228] 45. [50.8 cm] 46. (16min) 47. [466] (a) [3.25 torn/sec. } (b) [0.3387 torr/see.] 49. [Conceptual] 50. [25.027 kPa] 1. [Blow Up] 52. [M=175.133 ke mole") 53. (i [2.1428 gm/mole}, (i) [460.28 ms] 54. [236.29°C] (a) [493.03 m/s] (b) [454.259356] (c) [403 m/s] 56, [Conceptual] [2886 K, 3399 K.4330 K for mis, average, most probable] . B.77L] 59. [1540kgm) 60. (Conceptual) 61. (Detivation] 62. T= 350. (@ 31.1 am] (i (31.4 atm] 64. [Conceptual] 65. [4500 R] 66. [0.104 em?/m] [280 mL/min] 68. [0.509] 69. [80784] 70. [134 pa} [a= 3.77 bar L’mot~ [s4 atm] 73. [10.3 atmosphere] [314 pm, 7.05 em, 6739-4 sec“!, 1.09 x 10!7 mr? see] 75. [530.3 Pa, 1.281 x 10 mr] (2) = Z(CH,) 77. [5333.3 mole O, and 28.78 mole CH,] 78. (a) [0.625] (0) [a= 4] 79. [n= 13] [219K] 81. () [P= 5.263 L], Gi) [p= 0.7 gL}. (it) [0.2349 Mole] 82. @ [» ae] w lr ws [ax 1088" 84. (i) [2067.2 g] (ii) This mass would rest on twice the area and exert the same pressure] 85. [65116.8 cum] 86. [Pyo (left) = 0.221 atm] 87. [Pyq= 1.5 atta, Pry = 4.5 atta] 88. [146.5 mmHg] 89. [3.0513 atm] 90. [0.007 kg m=] 91. [6.85 L and 6.24 g] 92. [mole % of CO, CO= 67.81%, 32.19%] 93. [1.2361] 94. (a) [0.98]. (6) [1.004] 95. (bd) 96. (a, ¢, d) 97. (a,c, d)

    You might also like