,Co,
Silica (SiO,)is insoluble in water and acts asa very
‘weak acid
‘SnO, is amphoteric as itreacts with both acid and base,
‘SnO, + 2H,S0,—> Sn(S0,), + HO
Sn0, + 2KOH———> K,$n0, + H,0
Incoming electrons occupies the smaller
also negative charge on oxygen (O°) is another factor
due to which incoming electron feel repulsion,
Hence electron repulsion outweigh the stability gained
by achieving noble gas configuration.
In the isoelectronic species, all isoelectronic anions
belong to the same period and cations to the next
perio.
T represents Li, I represents K
represents Br, IV represents 1
V represents He
So, amongst these, II represents most reactive metal
‘and V represents least reactive non-metal
Helium (He) 1s? ~ Highest ionisation
energy due to noble gas
innature.
Fluorine (F) 1s?,2s?2p? —> High electronegativity in
nature dueto small size
and -1 oxidation state.
Rubidium Rb) > Most electronegative
element due tolarge
atomic size
Lithium, > Strongest reducing
agent due to small size
and positive oxidation
state (+1)
GP_3371 5.
DAILY PRACTICE
PROBLEMS
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x
ce
A
COF Its structure is
Greater the difference in electronegativity between the
‘wo atoms, larger will be polarity and hence dipole
‘moment. Thus (a) has maximum dipole moment,
a HC UH
fe ¥
:
H.C H.C’ Sc
Symmetrical molecules (= 0)
[NH undergoes H-bonding and hence has the highest
bp. Among the remaining hydrides i.e, PH ASH and
SbH, as we move from PH, to BiH, the molecular
‘mass increases, Asa result the van der waal's forces of
attraction increases and the boiling point increases
regularly from PH, to BiH
A
Bich, CI=BiC(, sp? Hybridisation
(Trigonl planar geometry), Bond angle= 120"
gp
we
InPCl; (Pyramidal
Tere geome | pond angie
yp telow 103
Tasch, av Pyne | 22 Sereates fom
GET mein) |PCHIPBIC
Bic, SA” ceyramidat
ENG somes)
In these, order of bond angle
BCI,>PCL,>AsC, > BiCl,
In NH, the atomic dipole (orbital dipole due to lone
pir) and bond dipole arein the same direction whereas
in NF, these are in opposite direction so in the former
case they are added up whereas in the later case net
CHEMISTRY
SOLUTIONS
i)
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Nyrottoris? oaora? {
@
phd
results reduction of dipole moment. Ithas been shown
inthe following figure
:
: K
4» 4
i }
Molecular orbital configuration of
wl
293
‘Te correct onderis = NP -You might also like
