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Synthesis and Luminescent Properties of Eu3+, Gd3+, and Tb3+ Complex Compounds with Some N-Substituted Phthalamic Acids

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Abstract

A number of europium(III), terbium(III), and gadolinium(III) coordination compounds with N-substituted phthalamic acids were synthesized. Composition and structure of the ligands and the obtained complex compounds were confirmed by NMR and IR spectroscopy and thermogravimetric analysis. It was found that terbium(III) and europium(III) coordination compounds with N-phenylphthalamic acid possess the most pronounced luminescence.

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ACKNOWLEDGMENTS

The authors express their gratitude to R.R. Khasbiullin (Frumkin Institute of physical chemistry and electrochemistry of the Russian Academy of Sciences) for the fulfillment of thermogravimetric studies. The research was carried out using the equipment of the scientific and educational center “Diagnostics of the structure and properties of nanomaterials” of the Kuban State University.

Funding

The work was carried out with the financial support of the Ministry of education and science of the Russian Federation (topic 0795-2020-0031, N.A. Aksenov).

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Authors and Affiliations

  1. Kuban State University, 350040, Krasnodar, Russia

    A. V. Chernyshova, A. A. Nikolaev & V. V. Dotsenko

  2. Mendeleev Russian University of Chemical Technology, 125047, Moscow, Russia

    F. A. Kolokolov

  3. North Caucasus Federal University, 355009, Stavropol, Russia

    V. V. Dotsenko, N. A. Aksenov & I. V. Aksenova

Authors
  1. A. V. Chernyshova
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  2. A. A. Nikolaev
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  3. F. A. Kolokolov
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  4. V. V. Dotsenko
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  5. N. A. Aksenov
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  6. I. V. Aksenova
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Corresponding author

Correspondence to V. V. Dotsenko.

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Translated from Zhurnal Obshchei Khimii, 2021, Vol. 91, No. 6, pp. 950–958 https://doi.org/10.31857/S0044460X21060123.

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Chernyshova, A.V., Nikolaev, A.A., Kolokolov, F.A. et al. Synthesis and Luminescent Properties of Eu3+, Gd3+, and Tb3+ Complex Compounds with Some N-Substituted Phthalamic Acids. Russ J Gen Chem 91, 1063–1069 (2021). https://doi.org/10.1134/S1070363221060128

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