Abstract
Temperature and magnetic field–dependent electrical and magnetic properties of La1−xCaxMnO3 (x = 0.4, 0.5) polycrystalline materials prepared by the sol-gel method are studied. An apically compressed/elongated-type distorted orthorhombic pnma-O′–phase crystallization occurs in the sample with the addition of Ca. The crystallized phases are ensured by the Rietveld refinement using the Fullprof package. Dangling bonds on the surfaces of the nanosized particles affect the vibrational features. Field emission scanning electron microscopy (FESEM) images depict the agglomeration of uniformly sized grains. With increase of Ca concentration, super-exchange (SE) interactions overcome the dominant double-exchange (DE) interactions and shift the Curie-temperature to a lower value (TC = 267 – 234K). Based on the Banerjee’s criterion, the Arrott plot confirms a second-order magnetic phase transition in the samples. Temperature-dependent evolution of the Griffiths-like phase (GP) is observed in the samples and GP% increases with Ca content. The various transitions in the different temperature ranges and magnetic field–dependent electrical transport behaviours are explained using different theoretical models. The dopant concentration influences the Mn3+/Mn4+ ratio, leading to changes in the conductivity, which is mediated by ferromagnetically (FM) ordered conduction channels, altering the metal to insulator (M-I) as well as the ferromagnetic to paramagnetic (FM-PM) as well as the ferromagnetic to antiferromagnetic (FM-AFM) transition temperatures. The electrical transport in the high temperature region is explained using variable range and small polaron hopping (VRH and SPH) models. Using Holstein’s relation, it is evident that non-adiabatic SPH (NASPH) model is the most adequate method to explain the high-temperature electrical conductivity. The half-doped samples show a higher value (~ 95%) of magnetoresistance (MR). The present study shows an increase in the Tc and TM − I towards room temperature and in the MR percentage, which may be good for different applications.
Graphical abstract
Similar content being viewed by others
Data Availability
The data will be available on request.
References
Sarkar A, Wang D, Kante MV, Eiselt L, Trouillet V, Iankevich G, Zhao Z, Bhattacharya SS, Hahn H, Kruk R (2022) High entropy approach to engineer strongly correlated functionalities in manganites. Adv Mater 2207436:1–14. https://doi.org/10.1002/adma.202207436
Salamon MB, Jaime M (2001) The physics of manganites: structure and transport. Rev Mod Phys 73:583–628. https://doi.org/10.1103/RevModPhys.73.583
Jin S, Tiefel TH, McCormack M, Fastnacht RA, Ramesh R, Chen LH (1994) Thousandfold change in resistivity in magnetoresistive La-Ca-Mn-O films. Science (80-. ) 264:413–415. https://doi.org/10.1126/science.264.5157.413
Troyanchuk IO, Trukhanov SV, Szymczak H, Przewoznik J, Bärner K (2001) Phase transitions in La1-xCaxMnO3-x/2 manganites. J Exp Theor Phys 93:161–167. https://doi.org/10.1134/1.1391533
Jithin PV, Bitla Y, Patidar MM, Ganesan V, Sankaran KJ, Kurian J (2023) Structural, magnetic and electrical transport properties of the sol-gel derived La1-xCaxMnO3 (0≤x≤0.3) nanoparticles. Mater Chem Phys 301:127651. https://doi.org/10.1016/j.matchemphys.2023.127651
Goodenough JB, Wold A, Arnott RJ, Menyuk N (1961) Relationship between crystal symmetry and magnetic properties of ionic compounds containing Mn3+. Phys Rev 124:373–384. https://doi.org/10.1103/PhysRev.124.373
Zhumatayeva IZ, Kenzhina IE, Kozlovskiy AL, Zdorovets MV (2020) The study of the prospects for the use of Li0.15Sr0.85TiO3 ceramics. J Mater Sci Mater Electron 31:6764–6772. https://doi.org/10.1007/s10854-020-03234-9
Ade R, Singh R (2015) Disorder-driven phase transition in La0.37D0.30Ca0.33MnO3 (D = Bi, Sm) manganites. AIP Adv 5:0–12. https://doi.org/10.1063/1.4928284
Tabari T, Singh D, Calisan A, Ebadi M, Tavakkoli H, Caglar B (2017) Microwave assisted synthesis of La1−xCaxMnO3 (x = 0, 0.2 and 0.4): structural and capacitance properties. Ceram Int 43:15970–15977. https://doi.org/10.1016/j.ceramint.2017.08.182
Dutta U, Ghosh D, Haque A, Walke PS, Mordvinova NE, Lebedev OI, Pal K, Gayen A, Kundu AK, Seikh MM (2018) Influence of Ti-doping on the magnetic exchange interaction of La0.5Ca0.5MnO3 nanoparticles. J Magn Magn Mater 464:132–138. https://doi.org/10.1016/j.jmmm.2018.05.057
Najjar H, Batis H (2016) Development of Mn-based perovskite materials: chemical structure and applications. Catal Rev Sci Eng 58:371–438. https://doi.org/10.1080/01614940.2016.1198203
Kozlovskiy AL, Zdorovets MV (2021) Effect of doping of Ce4+/3+ on optical, strength and shielding properties of (0.5-x)TeO2-0.25MoO-0.25Bi2O3-xCeO2 glasses. Mater Chem Phys 263:124444. https://doi.org/10.1016/j.matchemphys.2021.124444
Khan SA, Ali I, Hussain A, Javed HMA, Turchenko VA, Trukhanov AV, Trukhanov SV (2022) synthesis and characterization of composites with Y-hexaferrites for electromagnetic interference shielding applications. Magnetochemistry 8:1–16. https://doi.org/10.3390/magnetochemistry8120186
Gaur A, Varma GD (2006) Magnetoresistance behaviour of La0.7Sr0.3MnO3/NiO composites. Solid State Commun 139:310–314. https://doi.org/10.1016/j.ssc.2006.05.018
Wu YJ, Wang ZJ, Ning XK, Wang Q, Liu W, Zhang ZD (2018) Room temperature magnetoresistance properties in self-assembled epitaxial La0.7Sr0.3MnO3 :NiO nanocomposite thin films. Mater Res Lett 6:489–494. https://doi.org/10.1080/21663831.2018.1482838
Dhieb S, Krichene A, Boudjada NC, Boujelben W (2020) Suppression of metamagnetic transitions of martensitic type by particle size reduction in charge-ordered La0.5Ca0.5MnO3. J Phys Chem C 124:17762–17771. https://doi.org/10.1021/acs.jpcc.0c04910
Trukhanov AV, Panina LV, Trukhanov SV, Kostishyn VG, Turchenko VA, Vinnik DA, Zubar TI, Yakovenko ES, Macuy LY, Trukhanova EL (2018) Critical influence of different diamagnetic ions on electromagnetic properties of BaFe12O19. Ceram Int 44:13520–13529. https://doi.org/10.1016/j.ceramint.2018.04.183
Trukhanov SV, Trukhanov AV, Kostishyn VG, Panina LV, Turchenko VA, Kazakevich IS, Trukhanov AV, Trukhanova EL, Natarov VO, Balagurov AM (2017) Thermal evolution of exchange interactions in lightly doped barium hexaferrites. J Magn Magn Mater 426:554–562. https://doi.org/10.1016/j.jmmm.2016.10.151
Sun T, Zhao S, Ji F, Liu X (2018) Enhanced room-temperature MR and TCR in polycrystalline La0.67(Ca0.33−xSrx)MnO3 ceramics by oxygen assisted sintering. Ceram Int 44:2400–2406. https://doi.org/10.1016/j.ceramint.2017.10.209
Ezaami A, Nasser NO, Cheikhrouhou A (2017) Enhancement of magnetocaloric properties in (1-x)La0.7Ca0.2Sr0.1MnO3/xLa0.7Ca0.15Sr0.15MnO3 composite system (0≤x≤1). Mater Res Bull. https://doi.org/10.1016/j.materresbull.2017.07.036
Ezaami A, Chaaba I, Cheikhrouhou-Koubaa W, Cheikhrouhou A, Hlil EK (2018) Enhancement of magnetocaloric properties around room temperature in (1-x)La0.7Ca0.25Sr0.05MnO3/xLa0.7Ca0.2Sr0.1MnO3 system (0 ≤ x ≤ 1). J Alloys Compd 735:2331–2335. https://doi.org/10.1016/j.jallcom.2017.11.353
McBride K, Cook J, Gray S, Felton S, Stella L, Poulidi D (2016) Evaluation of La1−xSrxMnO3 (0 ≤ x < 0.4) synthesised via a modified sol–gel method as mediators for magnetic fluid hyperthermia. CrystEngComm. 18:407–416. https://doi.org/10.1039/C5CE01890K
Ezaami A, Nasser NO, Cheikhrouhou-Koubaa W, Koubaa M, Cheikhrouhou A, Hlil EK (2017) Physical properties of La0.7Ca0.2Sr0.1MnO3 manganite: a comparison between sol–gel and solid state process. J Mater Sci Mater Electron 28:3648–3658. https://doi.org/10.1007/s10854-016-5969-0
Fabian FA, Pedra PP, Filho JLS, Duque JGS, Meneses CT (2015) Synthesis and characterization of La(Cr,Fe,Mn)O3 nanoparticles obtained by co-precipitation method. J Magn Magn Mater 379:80–83. https://doi.org/10.1016/j.jmmm.2014.12.004
Giannakas A, Ladavos A, Pomonis P (2004) Preparation, characterization and investigation of catalytic activity for NO+CO reaction of LaMnO3 and LaFeO3 perovskites prepared via microemulsion method. Appl Catal B Environ 49:147–158. https://doi.org/10.1016/j.apcatb.2003.12.002
Xu Y, Meier M, Das P, Koblischka MR, Hartmann U (2002) Perovskite manganites: potential materials for magnetic cooling at or near room temperature. Cryst Eng 5:383–389. https://doi.org/10.1016/S1463-0184(02)00049-7
Alami D (2013) environmental applications of rare-earth manganites as catalysts: a comparative study. Environ Eng Res 18:211–219. https://doi.org/10.4491/eer.2013.18.4.211
Dey P, Nath TK (2006) Effect of grain size modulation on the magneto- and electronic-transport properties of La0.7Ca0.3MnO3 nanoparticles: the role of spin-polarized tunneling at the enhanced grain surface. Phys Rev B 73:214425. https://doi.org/10.1103/PhysRevB.73.214425
Xia W, Pei Z, Leng K, Zhu X (2020) Research progress in rare earth-doped perovskite manganite oxide nanostructures. Nanoscale Res Lett 15:1–55. https://doi.org/10.1186/s11671-019-3243-0
Trukhanov SV, Trukhanov AV, Dang NT, Zakhvalinskii VS, Kozlenko DP, Phan T, Kichanov SE, Ovsyannikov SV, Jabarov SH, Trukhanov AV, Trukhanov EL, Vinnik DA, Gudkova SA (2018) Magnetotransport properties and phase separation in iron substituted lanthanum-calcium manganite. Mater Res Express 5:1–12. https://doi.org/10.1088/2053-1591/aad118
Trukhanov SV (2005) Peculiarities of the magnetic state in the system La0.70Sr0.30MnO(3-γ) (0≤γ≤0.25). J Exp Theor Phys 100:95–105. https://doi.org/10.1134/1.1866202
Rodríguez-Carvajal J (1993) Recent advances in magnetic structure determination by neutron powder diffraction. Phys B Condens Matter 192:55–69. https://doi.org/10.1016/0921-4526(93)90108-I
Lira-Hernández IA, Sánchez-De Jesús F, Cortés-Escobedo CA, Bolarín-Miróz AM (2010) Crystal structure analysis of calcium-doped lanthanum manganites prepared by mechanosynthesis. J Am Ceram Soc 93:3474–3477. https://doi.org/10.1111/j.1551-2916.2010.03872.x
Sultan K, Ikram M (2015) An investigation of electrical, magnetic and optical properties of La1-xCaxMnO3 (x= 0.0, 0.3, 0.5 And 0.7) system. Adv Mater Lett 6:749–755. https://doi.org/10.5185/amlett.2015.5875
Roy C, Budhani RC (1999) Raman, infrared and x-ray diffraction study of phase stability in La1−xBaxMnO3 doped manganites. J Appl Phys 85:3124–3131. https://doi.org/10.1063/1.369651
Keshri S, Joshi L, Rout SK (2009) Influence of BTO phase on structural, magnetic and electrical properties of LCMO. J Alloys Compd 485:501–506. https://doi.org/10.1016/j.jallcom.2009.06.006
Li G, Zhou H-D, Feng SJ, Fan X-J, Li X-G, Wang ZD (2002) Competition between ferromagnetic metallic and paramagnetic insulating phases in manganites. J Appl Phys 92:1406–1410. https://doi.org/10.1063/1.1490153
Altintas SP, Amira A, Mahamdioua N, Varilci A, Terzioglu C (2011) Effect of Eu doping on structural and magneto-electrical properties of La0.7Ca0.3MnO3 manganites. J Alloys Compd 509:4510–4515. https://doi.org/10.1016/j.jallcom.2011.01.008
Tiwari A, Rajeev KP (1999) Low-temperature electrical transport in La0.7A0.3MnO3, (A: Ca, Sr, Ba). Solid State Commun 111:33–37. https://doi.org/10.1016/S0038-1098(99)00148-9
Zener C (1951) Interaction between the d-shells in the transition metals. II. Ferromagnetic compounds of manganese with perovskite structure. Phys Rev 82:403–405. https://doi.org/10.1103/PhysRev.82.403
Channagoudra G, Gupta S, Dayal V (2021) Study of structural, transport and magneto-crystalline anisotropy in La1-xSrxMnO3 (0.30 ≤ x ≤ 0.40) perovskite manganites. AIP Adv 11:1–5. https://doi.org/10.1063/9.0000119
Krichene A, Solanki PS, Rayaprol S, Ganesan V, Boujelben W, Kuberkar DG (2015) B-site bismuth doping effect on structural, magnetic and magnetotransport properties of La0.5Ca0.5Mn1-xBixO3. Ceram Int 41:2637–2647. https://doi.org/10.1016/j.ceramint.2014.10.163
Jaime M, Salamon MB, Rubinstein M, Treece RE, Horwitz JS, Chrisey DB (1996) High temperature thermopower in La2/3Ca1/3MnO3 films: evidence for polaronic transport. Phys Rev B 54:11914–11917. https://doi.org/10.1103/PhysRevB.54.11914
Dhahri A, Jemmali M, Dhahri E, Hlil EK (2015) Electrical transport and giant magnetoresistance in La0.75Sr0.25Mn1−xCrxO3 (0.15, 0.20 and 0.25) manganite oxide. Dalt Trans 44:5620–5627. https://doi.org/10.1039/C4DT03662J
Sen V, Panwar N, Bhalla GL, Agarwal SK (2007) Structural, magnetotransport and morphological studies of Sb-doped La2/3Ba1/3MnO3 ceramic perovskites. J Phys Chem Solids 68:1685–1691. https://doi.org/10.1016/j.jpcs.2007.04.012
Jeffrey Snyder G, Hiskes R, Dicarolis S (1996) Intrinsic electrical transport and magnetic properties of La0.67Ca0.33MnO3 and La0.67Sr0.33MnO3 MOCVD thin films and bulk material. Phys Rev B 53:434–444. https://doi.org/10.1103/PhysRevB.53.14434
Urushibara A, Moritomo Y, Arima T, Asamitsu A, Kido G, Tokura Y (1995) Insulator-metal transition and giant magnetoresistance in La1-xSrxMnO3. Phys Rev B 51:14103–14109. https://doi.org/10.1103/PhysRevB.51.14103
Mott NF, Davis EA (1979) Electronic process in non-crystalline materials, Second Edi edn. Clarendon Press, Oxford, New York
Emin D, Holstein T (1969) Studies of small-polaron motion IV. Adiabatic theory of the Hall effect. Ann Phys (N Y) 53:439–520. https://doi.org/10.1016/0003-4916(69)90034-7
Debnath JC, Wang J (2017) Magnetic and electrical response of Co-doped La0.7Ca0.3MnO3 manganites/insulator system. Phys B Condens Matter 504:58–62. https://doi.org/10.1016/j.physb.2016.10.017
Belkahla A, Cherif K, Belmabrouk H, Bajahzar A, Dhahri J, Hlil EK (2019) Influence of non-magnetic ion In3+ on the magneto-transport properties in La0.7Bi0.05Sr0.15Ca0.1Mn1-xInxO3 (0 ≤ x ≤ 0.3) perovskite. Solid State Commun 294:16–22. https://doi.org/10.1016/j.ssc.2019.03.004
Pal S, Banerjee A, Rozenberg E, Chaudhuri BK (2001) Polaron hopping conduction and thermoelectric power in LaMnO3+δ. J Appl Phys 89:4955–4961. https://doi.org/10.1063/1.1362411
Liu GD, Che GC, Zhao ZX, Jia SL, Guo SQ, Zhang YZ, Chen H, Wu F, Dong C (1998) Electronic and magnetic properties of La4BaCu5−xMnxO13+δ. J Phys Condens Matter 10:8477–8484. https://doi.org/10.1088/0953-8984/10/38/008
Ravi S, Kar M (2004) Study of magneto-resistivity in La1-xAgxMnO3 compounds. Phys B Condens Matter 348:169–176. https://doi.org/10.1016/j.physb.2003.11.087
Ziese M, Srinitiwarawong C (1998) Polaronic effects on the resistivity of manganite thin films. Phys Rev B - Condens Matter Mater Phys 58:11519–11525. https://doi.org/10.1103/PhysRevB.58.11519
Holstein T (1959) Studies of polaron motion. Part I. The molecular-crystal model. Ann Phys (NY) 8:325–342. https://doi.org/10.1016/0003-4916(59)90002-8
Das K, Dasgupta P, Poddar A, Das I (2016) Significant enhancement of magnetoresistance with the reduction of particle size in nanometer scale. Sci Rep 6:20351. https://doi.org/10.1038/srep20351
Zhou Y, Zhu X, Li S (2015) Effect of particle size on electric and magnetic transport properties of La0.67Sr0.33MnO3 coatings. PCCP 17:31161–31169. https://doi.org/10.1039/x0xx00000x
Reshi HA, Pillai S, Bhuwal D, Shelke V (2013) Nanostructure induced metal-insulator transition and enhanced low-field magnetoresistance in La0.7Sr0.3MnO3 systems. J Nanosci Nanotechnol 13:4608–4615. https://doi.org/10.1166/jnn.2013.7136
Coey JMD (1999) Powder magnetoresistance (invited). J Appl Phys 85:5576–5581. https://doi.org/10.1063/1.369899
Ziese M (2002) Extrinsic magnetotransport phenomena in ferromagnetic oxides. Rep Prog Phys 65:143–249. https://doi.org/10.1088/0034-4885/65/2/202
Hwang HY, Cheong S-W, Ong NP, Batlogg B (1996) Spin-polarized intergrain tunneling in La2/3Sr1/3MnO3. Phys Rev Lett 77:2041–2044. https://doi.org/10.1103/PhysRevLett.77.2041
Peng HB, Zhao BR, Xie Z, Lin Y, Zhu BY, Hao Z, Ni YM, Tao HJ, Dong XL, Xu B (1999) Surface pattern and large low-field magnetoresistance in La0.5Ca0.5MnO3 films. Appl Phys Lett 74:1606–1608. https://doi.org/10.1063/1.123631
Troyanchuk IO, Khalyavin DD, Trukhanov SV, Chobot GN, Szymczak H (1999) Effect of oxygen content on the magnetic state of La0.5Ca0.5MnO3-γ perovskites. JETP Lett 70:590–594. https://doi.org/10.1134/1.568220
Abdallah-Ben Ammar A, Cheikhrouhou-Koubaa W, Koubaa M, Nowak S, Lecoq H, Sicard L, Ammar S, Cheikhrouhou A (2014) Effect of sodium substitution on the physical properties of solegel made La0.65Ca0.35MnO3 ceramics. Mater Chem Phys 148:751–758. https://doi.org/10.1016/j.matchemphys.2014.08.044
Singh NK, Suresh KG, Nigam AK (2003) Itinerant electron metamagnetism and magnetocaloric effect in Dy(Co,Si)2. Solid State Commun 127:373–377. https://doi.org/10.1016/S0038-1098(03)00441-1
Banerjee BK (1964) On a generalised approach to first and second order magnetic transitions. Phys Lett 12:16–17. https://doi.org/10.1016/0031-9163(64)91158-8
Zhang H, Zeng D, Liu Z (2010) The law of approach to saturation in ferromagnets originating from the magnetocrystalline anisotropy. J Magn Magn Mater 322:2375–2380. https://doi.org/10.1016/j.jmmm.2010.02.040
Chitra Devi E, Soibam I (2019) Law of approach to saturation in Mn–Zn ferrite nanoparticles. J Supercond Nov Magn 32:1293–1298. https://doi.org/10.1007/s10948-018-4823-4
Lal G, Joshi J, Bhoi H, Punia K, Dolia SN, Choudhary BL, Barbar SK, Kumar S (2021) Impact of hydrogenation on the structural, dielectric and magnetic properties of La0.5Ca0.5MnO3. Appl Phys A Mater Sci Process 127:1–11. https://doi.org/10.1007/s00339-020-04206-w
Zhang P, Lampen P, Phan TL, Yu SC, Thanh TD, Dan NH, Lam VD, Srikanth H, Phan MH (2013) Influence of magnetic field on critical behavior near a first order transition in optimally doped manganites: the case of La1−xCaxMnO3 (0.2≤x≤0.4). J Magn Magn Mater 348:146–153. https://doi.org/10.1016/j.jmmm.2013.08.025
Zhang H, Li Q, Li Y, Liu H, Dong X, Chen K, Hou Q, Huang Y (2012) Griffiths phase and reduced magnetization of La0.5Ca0.5MnO3 with different annealing temperature. J Supercond Nov Magn 25:1707–1712. https://doi.org/10.1007/s10948-012-1505-5
Jiang W, Zhou X, Williams G, Mukovskii Y, Privezentsev R (2009) The evolution of Griffiths-phase-like features and colossal magnetoresistance in La1−xCaxMnO3 (0.18 ≤ x ≤ 0.27) across the compositional metal–insulator boundary. J Phys Condens Matter 21. https://doi.org/10.1088/0953-8984/21/41/415603
Pramanik AK, Banerjee A (2016) Finite-size effect on evolution of Griffiths phase in manganite nanoparticles. J Phys Condens Matter 28. https://doi.org/10.1088/0953-8984/28/35/35LT02
Salamon MB, Lin P, Chun SH (2002) Colossal magnetoresistance is a Griffiths singularity. Phys Rev Lett 88:1972031–1972034. https://doi.org/10.1103/PhysRevLett.88.197203
Deisenhofer J, Braak D, Krug von Nidda H-A, Hemberger J, Eremina RM, Ivanshin VA, Balbashov AM, Jug G, Loidl A, Kimura T, Tokura Y (2005) Observation of a Griffiths phase in paramagnetic La1-xSrxMnO3. Phys Rev Lett 95:257202. https://doi.org/10.1103/PhysRevLett.95.257202
Riahi K, Messaoui I, Cheikhrouhou-Koubaa W, Mercone S, Leridon B, Koubaa M, Cheikhrouhou A (2016) Effect of synthesis route on the structural, magnetic and magnetocaloric properties of La0.78Dy0.02Ca0.2MnO3 manganite: a comparison between sol-gel, high-energy ball-milling and solid state process. J Alloys Compd 688:1028–1038. https://doi.org/10.1016/j.jallcom.2016.07.043
Kim D, Revaz B, Zink BL, Hellman F, Rhyne JJ, Mitchell JF (2002) Tricritical point and the doping dependence of the order of the ferromagnetic phase transition of La1-xCaxMnO3. Phys Rev Lett 89. https://doi.org/10.1103/PhysRevLett.89.227202
Nasri M, Triki M, Dhahri E, Hlil EK (2013) Critical behavior in Sr-doped manganites La0.6Ca0.4-xSrxMnO3. J Alloys Compd 546:84–91. https://doi.org/10.1016/j.jallcom.2012.08.018
Andrade VM, Vivas RJC, Pedro SS, Tedesco JCG, Rossi AL, Coelho AA, Rocco DL, Reis MS (2016) Magnetic and magnetocaloric properties of La0.6Ca0.4MnO3 tunable by particle size and dimensionality. Acta Mater 102:49–55. https://doi.org/10.1016/j.actamat.2015.08.080
Amri N, Nasri M, Triki M, Dhahri E (2019) Synthesis and characterization of (1− x)(La0.6Ca0.4MnO3)/x(Sb2O3) ceramic composites. Phase Transit 92:52–64. https://doi.org/10.1080/01411594.2018.1550637
Nasri A, Zouari S, Ellouze M, Hlil EK, Elhalouani F (2014) X-ray diffraction, magnetic and magnetocaloric properties of La0.6Ca0.4Mn1−xFexO3 (0 ≤ x ≤ 0.3) manganites prepared by the sol-gel method. Eur Phys J Plus 129:0–10. https://doi.org/10.1140/epjp/i2014-14180-5
Yadav K, Singh HK, Varma GD (2012) Effect of La-doping on magnetic properties of Bi0.6-xLaxCa0.4MnO3 (0.0≤x≤0.6) perovskite manganites. Phys Scr 85. https://doi.org/10.1088/0031-8949/85/04/045704
Jeddi M, Gharsallah H, Bekri M, Dhahri E, Hlil EK (2020) Improvement of magnetocaloric properties around room temperature in (1−x) La0.6Ca0.4MnO3/(x) La0.6Sr0.4MnO3 (0 ≤ x ≤ 1) composite system. Phase Transit 93:311–322. https://doi.org/10.1080/01411594.2020.1720678
Nasri M, Khelifi J, Triki M, Dhahri E, Hlil EK (2016) Impact of CuO phase on magnetocaloric and magnetotransport properties of La0.6Ca0.4MnO3 ceramic composites. J Alloys Compd 678:427–433. https://doi.org/10.1016/j.jallcom.2016.04.020
Walha I, Dhahri E (2017) Magnetic and electrical properties induced by the silver in the lanthanum sites of La0.6Ca0.4MnO3 compound. J Alloys Compd 690:497–502. https://doi.org/10.1016/j.jallcom.2016.08.132
El Boukili A, Mounkachi O, Hamedoun M, Lachkar P, Hlil EK, Benyoussef A, Balli M, Ez-Zahraouy H (2021) A study of structural, magnetic and magnetocaloric properties of (1−x)La0.6Ca0.4MnO3/xMn2O3 composite materials. J Alloys Compd 859:158392. https://doi.org/10.1016/j.jallcom.2020.158392
Gharsallah H, Souissi A, Bejar M, Dhahri E, Hlil EK (2016) Magnetic anisotropy and superparamagnetism in La0.6Ca0.4MnO3, La0.6Sr0.4MnO3 and their mixed composition 0.875 La0.6Ca0.4MnO3/0.125 La0.6Sr0.4MnO3, agglomerated at different temperatures. Mater Chem Phys 182:429–438. https://doi.org/10.1016/j.matchemphys.2016.07.051
Anwar MS, Ahmed F, Koo BH (2014) Dimensionality dependent magnetic and magnetocaloric response of La0.6Ca0.4MnO3 manganite. J Nanosci Nanotechnol 14:8745–8749. https://doi.org/10.1166/jnn.2014.9994
Ho TA, Thanh TD, Ho TO, Phan MH, Phan TL, Yu SC (2015) Magnetic properties and magnetocaloric effect in Fe-doped La0.6Ca0.4MnO3 with short-range ferromagnetic order. J Appl Phys 117. https://doi.org/10.1063/1.4915103
Das A, Chakraborty KR, Gupta SS, Kulshreshtha SK, Paranjpe SK (2001) Structural and magnetic ordering in La0.6Ca0.4MnO3. J Magn Magn Mater 237:41–46. https://doi.org/10.1016/S0304-8853(01)00495-4
Gharsallah H, Jeddi M, Bejar M, Dhahri E, Hlil EK (2019) Prediction of magnetocaloric effect using a phenomenological model in (x) La0.6Ca0.4MnO3/(1−x) La0.6Sr0.4MnO3 composites. Appl Phys A Mater Sci Process 125. https://doi.org/10.1007/s00339-019-2851-y
Walha I, Dhahri E (2016) Magnetic and electrical properties induced by the substitution of divalent by monovalent in the La0.6Ca0.4MnO3 compound. J Supercond Nov Magn 29:3001–3007. https://doi.org/10.1007/s10948-016-3744-3
Hamad MA (2013) Magnetocaloric properties of La0.6Ca0.4MnO3. J Therm Anal Calorim 113:609–613. https://doi.org/10.1007/s10973-012-2723-6
Krichene A, Boujelben W, Cheikhrouhou A (2013) Structural, magnetic and magnetocaloric properties in La0.5-xRexCa0.5MnO3 manganites (x = 0; 0.1 and Re = Gd, Eu and Dy). J Alloys Compd 550:75–82. https://doi.org/10.1016/j.jallcom.2012.09.036
Wang H, Su K, Huang S, Ge J, Tan W, Huo D (2019) Magnetic properties and charge ordering in polycrystalline La1-xCaxMnO3 (x= 0.2, 0.5) manganite. J Supercond Nov Magn 32:3887–3891. https://doi.org/10.1007/s10948-019-05152-2
Rozenberg E, Tsindlekht MI, Felner I, Sominski E, Gedanken A, Mukovskii YM, Lee CE (2009) Size and nonstoichiometry effects on magnetic properties La0.5Ca0.5MnO3 manganite. IEEE Trans Magn 45:2576–2579. https://doi.org/10.1109/TMAG.2009.2018894
Sarkar T, Ghosh B, Raychaudhuri AK, Chatterji T (2008) Crystal structure and physical properties of half-doped manganite nanocrystals with size< 100nm. Phys Rev B - Condens Matter Mater Phys 77. https://doi.org/10.1103/PhysRevB.77.235112
Giri SK, Nath TK (2011) Suppression of charge and antiferromagnetic ordering in La0.5Ca0.5MnO3 nanoparticles. J Nanosci Nanotechnol 11:4806–4814
Das A, Babu PD, Chatterjee S, Nigam AK (2004) Ionic size effect in charge-ordered La0.5Ca0.5MnO3. Phys Rev B - Condens Matter Mater Phys 70:1–7. https://doi.org/10.1103/PhysRevB.70.224404
Xia W, Li L, Wu H, Xue P, Zhu X (2017) Molten salt route of La1−xCaxMnO3 nanoparticles: Microstructural characterization, magnetic and electrical transport properties. Mater Charact 131:128–134. https://doi.org/10.1016/j.matchar.2017.07.002
Chen X, Wang Z, Li R, Shen B, Zhan W, Sun J, Chen J, Yan C (2000) The magnetic and transport properties of Fe doped La0.5Ca0.5MnO3. J Appl Phys 87:5594–5596. https://doi.org/10.1063/1.372461
Wang KY, Song WH, Dai JM, Ye SL, Wang SG, Sun YP, Du JJ (2001) The influence of Cu doping on the charge-ordering of La0.5Ca0.5MnO3. Phys Status Solidi Appl Res 184:515–522. https://doi.org/10.1002/1521-396X(200104)184:2<515::AID-PSSA515>3.0.CO;2-S
Rubi D, Duhalde S, Terzzoli MC, Villafuerte M (2002) Correlation between structural and transport properties of La0.5Ca0.5MnO3 thin films grown by PLD. Appl Surf Sci 197–198:536–541. https://doi.org/10.1016/S0169-4332(02)00337-9
Smari M, Hamouda R, Walha I, Dhahri E, Mompeán FJ, García-Hernández M (2015) Magnetic and magnetoresistance in half-doped manganite La0.5Ca0.5MnO3 and La0.5Ca0.4Ag0.1MnO3. J Alloys Compd 644:632–637. https://doi.org/10.1016/j.jallcom.2015.05.026
Wang KF, Xiao Q, Yu H, Zeng M, Zhang MF, Liu JM (2005) Magneto-transport and specific heat behavior of Cd-doped La0.5Ca0.5MnO3. J Magn Magn Mater 285:130–137. https://doi.org/10.1016/j.jmmm.2004.07.026
Gonzalez-Calbet JM, Herrero E, Rangavittal N, Alonso JM, Martinez JL, Vallet-Regi M (1999) Ordering of oxygen vacancies and magnetic properties in La0.5 Ca0.5MnO3-δ (0≤δ≤0.5). J Solid State Chem 148:158–168. https://doi.org/10.1006/jssc.1999.8441
Li R-W, Sun J-R, Wang Z-H, Zhang S-Y, Shen B-G (2000) Magnetic and transport properties of Sn-doped La0.5Ca0.5MnO3, J. Phys. D. Appl Phys 33:1982–1984. https://doi.org/10.1088/0022-3727/33/16/308
Awana VPS, Tripathi R, Balamurugan S, Kumar A, Dogra A, Kishan H (2009) Thermal hysteresis in electrical transport of charge ordered La0.5Ca0.5MnO3 manganites. J Alloys Compd 475:L13–L16. https://doi.org/10.1016/j.jallcom.2008.07.077
Funding
1. University Grants Commission via the Innovative Program
2. Department of Science and Technology, India via the FIST scheme
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
The authors declare that they have no conflict of interest.
Additional information
Publisher’s Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Supplementary information
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Jithin, P., Bitla, Y., Patidar, M.M. et al. Enhanced magnetoresistance and evolution of Griffiths-like phase in La1−xCaxMnO3 (x = 0.4, 0.5) nanoparticles. J Nanopart Res 25, 207 (2023). https://doi.org/10.1007/s11051-023-05847-7
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s11051-023-05847-7