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Effect of metal oxide nanoparticles on thermal behavior of polyvinyl alcohol

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Abstract

Polymers reinforced with metal oxide nanoparticles exhibit interesting possibilities from an application point of view due to the homogeneous distribution of nanoparticles and superior thermal and mechanical properties. In the present work, silicon dioxide (SiO2), zirconium dioxide (ZrO2), and zinc oxide (ZnO) nanoparticles were prepared by the microwave hydrothermal method, and polymer nanocomposites based on them were processed in polyvinyl alcohol (PVA) matrix. The size of the SiO2, ZrO2, and ZnO nanoparticles is around 80 nm, 44 nm, and 95.71 nm, respectively. The thermal decomposition behavior of pure PVA and nanocomposites was studied using thermal gravimetric analysis (TGA) and differential scanning calorimetry (DSC). In the case, of nanocomposites, at 50% weight loss, the temperature was shifted by nearly 80°C compared to the pure PVA. Furthermore, the SiO2 doped nanocomposites showed a three-stage temperature decomposition in the DSC spectra.

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Acknowledgements

Authors sincerely thank Nanotechnology Research Center, SRM University, India, and the sophisticated analytical instrument facility (SAIF) at Indian Institute of Technology Madras (IITM), India, for providing HRSEM-EDX images and XRD patterns for nanoparticles and nanocomposites. We would also like to thank the Director of High Energy Materials Research Laboratory (HEMRL), Pune, for the thermal analysis of various samples. Finally, the authors are grateful to Dr. P. K. Khanna, Head, Department of Applied Chemistry, for valuable discussions and to the Vice Chancellor, Defence Institute of Advance Technology, for the permission to publish this work.

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Authors and Affiliations

  1. Department of Nanotechnology, SRM University, Kattankulathur, 603203, India

    Shrikant S. Channe

  2. Defence Institute of Advanced Technology, Girinagar, Pune, 411025, India

    Ranjana Singh & Suresh G. Kulkarni

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  1. Shrikant S. Channe
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Contributions

All authors contributed to the study conception and design. Material preparation, data collection, and analysis were performed by SSC. The work was supervised by RS and SGK. The first draft of the manuscript was written by SSC, and all authors commented on previous versions of the manuscript. All authors read and approved the final manuscript.

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Correspondence to Suresh G. Kulkarni.

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Channe, S.S., Singh, R. & Kulkarni, S.G. Effect of metal oxide nanoparticles on thermal behavior of polyvinyl alcohol. Polym. Bull. 81, 3403–3438 (2024). https://doi.org/10.1007/s00289-023-04858-7

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