vncnreslr oILs BY
vncnreslr oILs BY
vncnreslr oILs BY
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QUANTITATM ANALYSIS oF soME<br />
<strong>vncnreslr</strong> <strong>oILs</strong> <strong>BY</strong> t'c NMR AND<br />
CHROMATOGRAPHIC METHODS<br />
NATIONAL CENTTE Of Ef,C'I,|'D|CE<br />
rN ANALYTTCAL CITEiIISTIY<br />
trNlvERslry oF slNDll<br />
JAMSITOIO' PAKISTAN<br />
By<br />
SAYET' TUFAIL BUSSAIN SII II<br />
M sc (Goml)<br />
JUNE I'X
OUANTITATIVE ANALYSIS OF SOME<br />
i"C"tn""" otl,s <strong>BY</strong> t'c NMR AND<br />
' .-c-fn-orvr,lrocRAPulc METHoDS<br />
6y<br />
SAYED TU'AIL ||U8AA|||| 8f,AII<br />
M lc (Gond)<br />
rt.b r!bE|t|.d I Frd'l fufiL"t 'f .'l. ^r'qri 'r' ftr<br />
-ii.*-.f o-r". "t ru-"Plv lr Ar'lvlic'l cLlFv o rt'<br />
--- - f*.ft nf s.|.o.", uttttrdq of Sbd\ J'3tom<br />
ITATTONAL CEI{TIE OF IXCELLINCE<br />
IN AITALYTTCA! CIIE ETf,Y<br />
uNtvElslTY Ot stNDlt<br />
JAMStloRo, PA(ISTAN<br />
JUl{! lata
CERTIFICATE<br />
Cenificd tu s4l.!q !I4L quj!44 !!4t<br />
brr c'ried ou his<br />
rcs€lrch rd exD€rimdf.l work oo thc topic cntid.d ts'QUAiTrATrvE All^rysts<br />
ot soME t'EG!rA!L! O[!l tY |tc NMt AND Cltroil^rolcR^llllc<br />
METttot s" llnder out g0id.{Ee rnd sw€rvision in lhe labor'ton$ ofNational Cen'<br />
re of Excllldc€ in Antb4icrl Chedlarv, Utivenity of Sindlq Jaftshoro Paki$n<br />
H$ rcs.€rEh wo* is origfu! ddircr nd hi! tn sis is wodty of FB"iatiotr to tbe<br />
Universiry ofsindh for thc rwed ofd.gr.c of Doctor of Pttilosphy itr Anibriol<br />
chemsary.<br />
Protulor and Supervisor<br />
Natiodl Cefi. of frx.illdc.<br />
in AEMic.l Ch.tnify<br />
Univdsity of Sirdh, Jmhoro.<br />
ffimr !d c}$?.wiror<br />
Nrin l C.d!r ofEcclbr.<br />
ir Adyli..l Crrdrry<br />
UaEty of Sd! Jdo.o
QUANTITATIVf,<br />
<strong>BY</strong> 'JC NMR<br />
ANALYSIS OF SOME VEGETABLE OILS<br />
AND CHROMATOGRAPHIC METHODS<br />
ABSTRACT<br />
CC ,r,ni" Uo t-t €"ii out o lo v's'.rlb oil o!9|| in dd'r io<br />
"C Xm ",,a<br />
find oul qu.miritct 6. tut, eid @nF!'nn in rh€' oik sds e{inis ofs'db Aoh Shdh<br />
AgrFultui.l R6arch lsrndc Taldoi'r! P'lnur bv' bar ldfz'd in rhn tndv Oib ht<br />
b.€o *tEd.d from fi* t*ds bv 3Ltd'rd ndt@d Thc oil si'pl€! '|v' ben ul'n trom<br />
bdl d.kd Tn. 3-& wde d'o rdtad fo' 6orgi td|6' misture oil onr'nt fr4 nnv<br />
icid.nd D.oGn (Ml) @it.I gtl 'dqn| of fooign 'd6 9s grsan it @noE 'd trd<br />
liBc.d Mo6lur. us hish in cottos"4 tunno6 (HOl) rnd lis€td' Cotto6*d' iunflowd<br />
IHG|l. !i li!..r| o*d htrb oil d|an FF tutv @irL in t[ oih we h'low d' Fnsi<br />
bh lini. Ts $)d-n wi.i6 ro'd s Et-L 'd \vilin lbe'd biSh Fo&n @nE<br />
od. drcl.d.dl oh.i"d @dsc'lv €"|o dlv'd for @bu itd'( tc 6ltv<br />
rcd, iodi v.t!. (Iv) dd stoni66rio rbt (sv) Hi'n ndiE dE 6' obtd'd i'r "fno*.r<br />
.nd lro4d o'lt naih 60dcd rhMd rh' lowtr !'potrIfioton vtlu'<br />
Stin'Lri@ ELriion tine T' of@rdn"t rrc @' obt'in'd for oilt to fld th!<br />
'll<br />
1im. ..out.d for 'rC Nrfl aslFir' t!8nd Tr {hF of<br />
i' o$ of cD<br />
' l sd4e 8<br />
'ound<br />
atuo. of liB..d oil For qq|nintiw ulvtit tP'dr OoD G3? ppn w' rcqui"d tnd th' che<br />
s'liot@ of oih oro tm sm'rF s G4tv GrolP (i) ilvonEd ot t'6o6 t'n 6nc<br />
Gd o'hrddt Gt of oik b€bns.d to ctow {ii) v'ticn 4lnii'd &nb witlt tbc do{th bo'i<br />
fu66) 6 .dditio. to lh. &ids fou'i li Gtu[' (')<br />
Nat oil gnp!* wse u'd without |nv lolvat iD NMR aEltsit wing Ertdrl<br />
Der.riun t ct r3c NMR qNtiLiiv' 'dvsis showod h!! lmut of srw't'd inv ad! r
cottoB.€d ed sorab.{a oih. Acid wirh I siDsk doubt. bond (nomo.) w@ hig! u,.06..d<br />
.nd liG*d Di.ne (&id with rwo &ubh bond!) Fql.S- l@: 73 t% h sfroqr, Jl j5h<br />
@rrot6€d. 49-62./.<br />
3u'do@ wiri.., a8-j2% in orddr wirr.a ara n 6m o(<br />
'r | 2 5t% h li6...t .d | 3.5% b r.D...d oit rtu Ei.F ,.rc.fis. s tis[.n (jO4) i, d. of<br />
lia..d. NMR s.E rot l p
l-3.1 Ch.Lt M.ri.rk<br />
1,1.2 Modo lGrtu mlItaL.L<br />
REIERENCES<br />
2,2 Arh|.i ofoil Sedr<br />
TABLE OF CONTENTS<br />
C}IAPTER - I<br />
INTRODUCITON<br />
2.22 Moih.ddvol|.&x .r<br />
2,2.2,1 tGndrfrt tLrlo&<br />
2,23 Crd. Oil<br />
2.2.3.I hd@dbl M&&<br />
2.3 Popqtb ofoit*dr<br />
REIBRENCBS<br />
CHAPTER - 2<br />
ErtET DI,sCRlPrlON OF OII,SEf,DS<br />
2<br />
2<br />
3<br />
l0<br />
l0<br />
|l<br />
|l<br />
l3<br />
l4<br />
l6<br />
26
3.2 U€ ofv.lrtbb ot!<br />
3.3 EdibL F.t Coqo!@r<br />
3,4 snu.d@ ofF.tty Acidt<br />
3,5 Piopdti$ ofF.B.!d Oib<br />
3.5.1 lhdn r Prepatit<br />
3.5.1-l Dadty |rd 8D.!6. Civiy<br />
3.J.r,2 R.&tcri6ldd<br />
3.s.l3 Viro.ity<br />
3.5,t,4 Cobu<br />
r-t.2 6dn rPrltdti..<br />
3.r.2.1 Stloti.niod v.lr (SV)<br />
3.5.2.2 lodir. V.l|.<br />
3.5.2.3 F@ F.t!yA{il V.l&<br />
NEFETENCES<br />
,l.l t NMR sp&tr@!y<br />
4.1,t lfrldr.ibd<br />
4.1.2 't NMR gp..no.oopy<br />
4.1.3 R.hEtb! tis<br />
a,r.3,l Stb.SDb R.Lntir<br />
4.1.3.2 Spirldi.o lrl[tirt<br />
a.r-4 N!.lar O!d.|g Efta<br />
4.2.1 teqi|cid<br />
a.z2 C.. liFil Ct!!@bg.Dty<br />
CIIAPTER - 3<br />
vtrotTADll olts<br />
CIIAPTER - 4<br />
TIIIOR.EI'ICAL PIINCTPLES<br />
30<br />
3t<br />
35<br />
36<br />
l6<br />
33<br />
3a<br />
38<br />
39<br />
,to<br />
12<br />
43<br />
43<br />
a5<br />
lt
4.2.3 S@r.tbd .rd R..@tion Tb.ory<br />
4.2.4 Edbh.y of Col@<br />
4.2., t ohiin<br />
RSFETAnCAS<br />
t.2 N!ff, Solv.e drt R.&ae<br />
5.3 Pr.td.tid of NMR A.q'Lt<br />
,.4 NMI st!.drddd<br />
J.5 $add of SDirrLb.<br />
REFERENCES<br />
J,7.t !b(qF M.lr-<br />
CIIAPTER. 5<br />
E:X}IRIMINTAI, DtrTAII,s<br />
5,6 oil Qul',iy<br />
,.6.1 Ltty Acid coryosnb!<br />
tCt.t l{Mt Arb|i<br />
t.6.t,2 @ ADlFi.<br />
5.6.t,2,t p..F,etid of r.tu .n6<br />
5,6,1,2.2 C@ ch@awaphtc @adidN<br />
5.6.!.2.j Uedfiedd<br />
5.6.1.24 @@dds @<br />
5.6.2 cobu hdlx<br />
J.6.3 Ftu F.try A6it<br />
t.6,4 D.r@ionir! of Sediti.tin Vrr,<br />
5,5., Ldh. Vrb<br />
J.6.5.t Pt?.ndq! of wii s.r.i.<br />
to<br />
!l<br />
52<br />
t3<br />
5l<br />
62<br />
62<br />
6l<br />
65<br />
67<br />
68
5, v.!t b Ol lDryri<br />
nz.l F.w AcA (Mi.<br />
REIB&ICB8<br />
lt8<br />
6,2.1.t _c M.fi.<br />
6,21.Lt And,,d6<br />
6,2t.r2 M<br />
6.2.1.2 C^!!ri<br />
Zl.l FordanXdra<br />
CHAPTER.6<br />
r&ruLra<br />
CTIAPIER, - 7<br />
DtlqE(rN<br />
Zri Oil6d.r<br />
7.r.4 Fr!. FryAd(FA) !irb.<br />
7.1.5 ft...5 (X-D Eb.<br />
z2 v.ra.llollrlri<br />
z2l co&cb.k<br />
r22 &..86y A.il (I!FD V.r!<br />
Z2i ro.LE V.b. (rv)<br />
7.2.4 8.Dol|a.bd v.h. (gU<br />
725 krs, L&l coqo.tin<br />
?.2.J.t trtrat<br />
?.2'5.2 (L(!rdos&<br />
z2.ri .r]f-afm'dcln{.<br />
rEtarEN(|lS<br />
69<br />
o n<br />
E7<br />
9t<br />
lt!'<br />
trl<br />
uE<br />
lI9<br />
ll9<br />
tfr<br />
t2l<br />
l2l<br />
tu<br />
txt<br />
t23<br />
tu<br />
125<br />
129<br />
l30
CMPTER - 8<br />
CONCII'8TON AI{D TUTUNE PROS'ECTS<br />
Co.5rrdFtu 1n4.... l3l<br />
lr2
I r Us6 of lrious v.sd.bL otu<br />
LIST OF TAILES<br />
1.2 vroa tny eids wit[ tt n@!|m'! t'nolDE,lb.nuL<br />
6 I Adtlis of Som CoIlmn Oi&..ds<br />
62 ADb6ir of Som V.sd$Loil<br />
6l Spin lrnice Rehation T b ss h for r.lcr.
ig-<br />
LIST OF FIGURT'S<br />
(5,1) V.rio6 lti!& of D@@liA Mod.s.!.1ti.b.ppliolio6'<br />
(5.2) l80 - i- 90 ort - r- t/2 t'rh..Gqu.dco<br />
fot IR 6.to& olTr oarwn'<br />
(J.3) cordnion ofM, (t) .t v.rbd tie itt MbtbIRscq@<br />
(5.4) E@s@e of M, (r) .ird .r.n.l doc t aod n.sN. Mz (r) v.nB<br />
ro p.riiv. M' c) sh8<br />
(J.5) Pioto' NMR Sp..nlE ofsoy.Da! oil<br />
(5.6) coqL{. I'lold lr@|4Lil ltc Ntl,tR sP.
(6.10) tR $.q@ C.alc€t Pto{otr Ddlpt drrc Sp.dE.f R.p6ed Oil (K-5E6)<br />
RooE Td0a.w<br />
(6.1l) R.p@t trc "c sFcr@ ofco|4 li) Oit-.srmow on (Thor;78)<br />
d! in. C.Ed rH Dd'Dled MoL<br />
(6.12) 'rC Sp..rM orGol4 (i) Oil toE o-t? tpn in r c-ted Prero Dcouplc.l Mod' -conou..d<br />
oil (R€brb - Tudoj.o)<br />
(6.1r) R.t(6.d.tiv!'3c sFed ofcor9 (n) oi! fi@ ca? !!d h. o.t d rH<br />
D@lrLd (NNE) Mo&- sdlo€ (Co!r4&iD onNai<br />
(6-1.) r'C Sp..n@ (o-3? ppd) ir. Crt .lrH D@qLd Mod! of Nal<br />
Sd!.wOn(IIGl}<br />
(6.1t<br />
(6.16)<br />
(6.17)<br />
(6.r8)<br />
(6.r9)<br />
(6.20)<br />
(6.2r)<br />
(6.22)<br />
(6.23)<br />
(6.t41<br />
(6,25\<br />
\6. )<br />
(6.27)<br />
(6.2r)<br />
(6.29)<br />
"c<br />
St..a'n of soFh.d on ($..L) b I G.t d'll Dc6l4Ld Mod. 95<br />
crr.d Pretor[r.@'dcd 'rc Sp.rlMofSoy'hatr oi (winin) 96<br />
c't d Protos D@wLd rrc Stc.mD of soFhat Oil (cotltternD. e7<br />
'3c Orc rtot- ouo,plcO Spcao of coo ol (Comcil) Gl7 p9o 93<br />
"C Ora noto" o-,,!ta Spca- ofl-iuc.d on (Ehi90). 99<br />
G{Gd Froton D.&'DLd I'C Sr4rio orcol4 (D Pdp6..d On G_Jt6)<br />
h t!. rug! of G37 FB<br />
C.! Cnbeiosnr ofsted.td Frny Acid M.thrt Es&* (FAME)<br />
G.. ChroBtoenD of s.fbwo Ol (Ddn78).<br />
cr. Cbosbr.n ofconoaed Oil (R.ttrGT.tr&ie)<br />
c.. &oorocnmof suioE Oil(Co!t:c.it).<br />
ot choatos@ of $ulb*r o|I (Hol ),<br />
c.! ctrcDtoenn of soyrtq! Oil (steL).<br />
G.d Chloetos$n ofsoyrtc.o Oil (Wilin).<br />
c.r ctDdtoetab of soIb.r Oil (cod!@iD.<br />
C.. Cboobs.m of Cod Oil (CdMciD-<br />
a2<br />
30<br />
92<br />
94<br />
l(x,<br />
106<br />
101<br />
t07
(6.!0) o.Clndrt o of[i!..d On (8890)<br />
(6.31) O,Ck oiorEd ofx4...d Ol (rv!&)<br />
o.l) arily |. &Et.rE-.f t trd d,r..a d(r) b/frll.I.d<br />
!!.dt.a1(t'd&rtu d (.) Edw or raba C<br />
c.&oh&1, 25 ll, (I22 r, 6irs..,titl-,<br />
tir!.4!J d/ rir$iai aL I, ov..i-..&! la',4",23lt<br />
id.& q@.2t0P, d.do.l-!-r!!. r!l', totb a0 oir<br />
!|@ idirth d.Ldd.tn nr<br />
l0l<br />
l0c<br />
tu
ACKNOWLEDGEMENT<br />
I wiln to €4r* ny !hcd. tbnlc to nv supdisr Dt A W I( Kh.gib for<br />
big luhl t..bbl lrrile€, {hrt. .ug8a.b& .w @dgnls sliml'lhs dd apnitre<br />
r!ib@ ddil8 ihi cad worl"<br />
t ..b.d.deF. d.F ofg.!t!& to nv C&Sl4dvie Dr' M I En'lcd bi hn<br />
[an .a CFoDa.oo dd{}dL tllsdbc<br />
Sr.cirl ttdl' rrc du.10 Dr. Altf gl@i!. hob.l soi!di6. 066. NELI<br />
h.&tr. br AS.nule & B6losy OIAE), F!!,.ht 4 fot poudils 64L of tnldsrd &ttv<br />
aoi& E!.!yl6td !!d l@iu c&odrogt d of $re 5tr91€. His Liid h€b 3 grEtv G<br />
t tLo lh.tr Si6 Asblldl R.-.d ldlre, TD.b !d fo. pnvnn's oih'€d<br />
Tt do !rc &. b tn. Dic
DEDICATED<br />
TO<br />
MY P iENTS ANI' BROTHERS
l-1 Iniroduction<br />
CHAPTER. I<br />
INTRODUCTION<br />
veept bL oih r.6.alil !.tr! of bulru dh ltd rh6c povid. .sgtbl nutr;<br />
ar& Tb6. osr b. of seod quliy il|h6..r. Ecd .. h@tr did Quli4iw .fl1qu.orn.riw<br />
stEis aB c.d b de ilc runbol quhy of wsa.blc otu.<br />
VGg.$U. oit .d dit& nr. @qri. ofEtlycsi& DixlG wbid &€!4os<br />
or trola ido @Esli@t iny.ci& dEitrs d(g.!ri@ 0 ll. Tt relc of 6ts n .h.6mtio! of<br />
P.G|'shdnr rcAosib|. br Fb otl di!d. i . w.I lmh Not!| pria simita disovsv<br />
O tl- Pndrshdb i' d.ho!6[y bE d 6DE urdlbni rcil vnt;h b nd i . I@L.|ne of<br />
boLi: rclL Limlcio .cll i, rlcr&E rad .r E{.dil !.!ty Acit (EFA). Tbe id€1 6!@<br />
sue ofhobn .cil.r. v.sltrbL oih iLriv.d eoo runoc a..G, $vrbets EiE sm<br />
ud $fiowq s*& [t-21. vcSdrbL oiL b.v. fo*a 6ao&d .cib .nd i 3idpla niebtaid.<br />
@q6tiD $E rn n ridl6rdc !|r$. Tt* oih sldoD @i.in tiEcn d.!.in or o.ll<br />
llubd tutr.cns or uNrnr.d nfty.cil pi! f.wd rtD 16 or @c lhd 20 drboa .106.<br />
Mo$ qtty rcids d{ivc lhci a@ &on pht noD wtid ttcir on i! t.L... pabnic acid Aob<br />
p.ld phd, oLio lcil Am olivG. lituLic dd l@Ldi. .cn 6oD ID&.d ctc. V.a.trbL otu 6F<br />
tlh nimr oqo!6r of toopt@l .ad st@ls b lbc l@it of l0o0 or^s. v.a.nbL on 6tuin<br />
d rn. ms1 100 DsAs .6ohn@l Th6. uc 6w rliog' *ticb !ow.&ys @L !.sdbL oib<br />
@F sein rbr Diml ii. conou*4 di4 rdq rp**4 s6Lwd s@4 eyba! bd su.<br />
dowa t*d oih e linld.r oob l@Fnru. .!d lll o .b hi3! kvel of poblj8tmred l8<br />
6iton EFtu Dd rns brv. in*.foF .ton !t.f liG. T[ac .E D|rriny hyreogmt.n b ihcta$<br />
thei s!.f liG Il.3l. ADbtri oftbe. oil dd !..tb i .h.rcforc of i4olr.* bo.[ for<br />
'nood<br />
tlen qu|iy bd 6r ntdtr ocrqtih. ft. ndnod $'hih h|rc hd 6ed ..e si€ in onnry
3.diE horn 6r .6dt .td oiL.<br />
1.2 Amlysis of Oilsceds<br />
Th. quEy ofoibc.d d.p..& utd nt oil @!tdt The qulitv is poor irn 6n1'it<br />
dG Fr* Fttty Aoid (FFA). mietuq ii46ni4 md .doinu. .rc TL. 6idE lcft lnd effe<br />
tb! b $N tiF iqorrn tut 6iul fad Hffi dn(i is o[.d 'oil Codat' 'nd t it qpid.d<br />
n Frcong! of N of podd Il 4l. Fot .@[ s..d., . sriodng a n*d'd b'forc<br />
.,.tE.rin Th. on odar s.l @d@ b diraEnd s@ tid tv wi& InE NMR € & in 6&<br />
of sunowE 11,51 .nd r l,v @l!io! NMR b q& of nD6..d [1.6] ColniMu wlre CW<br />
drt pu&e NMR lE td s.d n Ery d.6 [1.7'l t2] Nar rtn 'RGd (NR) R'dd.e ir rn'<br />
flE krstb of ?5o b 25OO @ b..lo ba 6.d [t l3_l t5] b ddmimna of oil, mirre<br />
od Foi.n oodEts ir slt !a rDlbc .nrl rD€..d @b Di.lc.dicdbod h.s.ho b€<br />
'E€d *1 oyt6 .!d 6nd...& Il.16l. Tnc 0tb4ltirgt n oibah & @-dq t* nnv<br />
.cil 6I'a dd i4uii' rbe hrv. t@ di.r.d i! .la.ils bv RGs.n.nd P.i.6.td [r ' I tl.<br />
13 Autysis of Oils<br />
T[. frlry .qd @4o.lior of r! on i5 i! @st u.in cntui.l fatE M,nv or<br />
rbe ddi.l t gl nor on {ufty d pEity 6 t ELl.d lo thc &$v .cid @4ositi6 Edible orh<br />
ed tur oar. of trietqi.h.,.ad wbjL I!. 64o!nioD of tbc triet .1116 nt.rc is it!.r<br />
i.@s1iu, LrDwLdg. of6. |@url rld tJtd of tbc itly rcrds i. the trisb€*ids is wideb F<br />
srd.! s dr uein tli! n prnicultv s Aoh t lutrititul slddpoiol. os tLe lriglvcitt . d€<br />
b &y qso boLa doM ido d. dlrn4d fittt .cib dui.g dis6tion.<br />
M.lytds.8o, ii! udoib wd.66ilcrcd lo t 64Lx subd'lffi 6!1 6u!<br />
b. s.pdEtcd ioro 3iosLr @!F.Ml! wih difidfty. Th.y *dc r.@8dad s sesrv @lult.<br />
odi!.d h{ t[e pret&n ofB!'!n w@ 3u.h ttlt t]h.y w@ sludi.d by r htnnnn ofd.vo@<br />
dt, wt we r.e|flLrl by l!.n scilti& @[..s8 bcn s s$gbtt o@ti, ud rd .s
s|wh.r re.6itic. Tlit pir@ w$ &!Fd b $c dedop'E or tbdan ha,6sr.l<br />
l3l Ctrdcrl M.itod!<br />
CLan l |'l& br O. Acy ..il oao.ib! ulysi n@tu ih. ..r.Eaio. of<br />
rirlqitb bro 6d @qo!.d inr rci!. rt€. oatod. d.?ad rro! tt olrDil.' .!d<br />
ohit , ofiay ..nh, sblaty ofil.n .t , d boibs rob of 3n+rr .46 ofttc .cit S.p<br />
ddn of ai!E6id.. .to urba Atty .cid! t$ b6 .oq&.d !, 6rrr.[idir4 i.cidt<br />
diri[.rb!, &lv.d{lvan cxt ..rioa dftrlhd ox,&tio. .!d.&otFb! dlodi<br />
Dffi ad b 66ia ll.16l N.c |hoM lt. d.riod br lb. .a.nibo ud<br />
puitotb or[. tty..i& lbe|4i bw l.qd.@ 6r|.lbtb! ofntty.ciL. Mat oft!.<br />
o@ 6ini.d .cib c tr.ri'gt sr|bL ..d ,i! c.ytoli. tle etrib n r.dpate<br />
606 -40 'C to -70 t ra. qEdriw dacDn ii! of r[. b.h/iLl pobu!|@rcd ilty<br />
.cil by iorii's rt ir t o@d6i\,.li€ ll.lel b difrot ro.@qbL FnciDl qyn liaiii<br />
of itty .ciil Fdh.d r[. - y eortd to d.!d.r. rh.r tn b 8odl wr.6qos.d<br />
of !n d ntld rl.! siqL rbiEid.. Il t.@Brew'of Md@ wa..tL .o ioli..rd<br />
idali93.6lrt d Ei8b{€i&. bylni t .bi|E IL201.<br />
rb. bF o:dar ofitc tu si.r. or @bt& .cA. *4 dh d wib GD .r<br />
.|J4rric pr{@ ty DrE tl.2ll. Tli o.rlod w.. i4.dcd Dr Clrt &d r|ilis 1t.22-t.231.<br />
ta. @LriL.cit q@r b. dirild.r.6!9ldi. pBe. Ad.l r+o bEic oy bc didld<br />
ed- t .!E .l F*e. DaiLdb n I Eg! !t.@ *g u.d try l('6 ll,2tl dd loB<br />
I L251 $ tu h.cl r | 8tt br t!. F.til .a?.niE of O. alr&idd of |anl 1... tto*@d r!.<br />
nc lbr dt r[! sh€iL. of bq 6Ldlr silb diri||d {ibc d@!F aiD lirt d r[.<br />
e otoi t rlD&E. MoL.uLr .hnhb6 FEir diilil|ltio! of tlc tbb @hnr K{rb ste<br />
dila.. edl a |bc b€, hr a h.d &r Fond b b. ntn.o.y tu 6. 6.cb! ofeb4alhs<br />
Il.26l.<br />
Th. rlvl.r- elv.n .drcb! D..Lod 6r gbBik w @d by Firb .!d o<br />
10*6 0,4 b 19a5, Tii, rc.bilE d.ta& 'pd Ih. F.e.!dil sllhihy of 6a.n$.<br />
tyta of dr€iL. of . tu n . dv.d. S.tal rtp€ of elvrd. bd h6 ud i! tf,n &diiFr
of twd ho<br />
..& n!tutl dd coF . l l.2sl w.|ra dd MilL [l 2el i'sr'stttd ttt slrdiL'<br />
fou i.(.ir toE *bi6 dr.6iL 66gdlb! ofoil hd t@ oLr|Lr'd Tht trc|bo ofer<br />
.h.! on b. tlso t a t ?on a b enicS &.ci@ nnrtd n i'dn' {lD n6o |o' lo |73I|-301codollat<br />
oiblid' of sh,qil6 blb*d tt d'db' w" &sloptd tt<br />
r|iliA lt.3ll. ftn t. blilt Foi.4!t q4b! orll/tdiLt b' tm so'r': (D sbldit6<br />
66i'i'! 6t rlttt d ftv.cit n lt.t 6q"u!' dd (O st€iL' ir wtnh @' d @r'<br />
nry.ci| rc..aai6.d eih lltqol @k uL.r' |@rnd<br />
Th. ixlir s!, vttoL od[t r'v" !E i'di"tir of lt' Gltiw of<br />
'6u!<br />
cddnbo b &( s it!il&.d !v wi! [1 32] Ed rt.ou ll-33l TbG tutv @lcub o!<br />
'cn<br />
6. iriF {t otrrisl bt lt.6EtFo..dd i *[ Irff 'd n OG Ooland tld 'col<br />
irlb. d& {1.!al. Thc lndirl d& &r iobtior of ttirh/€iL 6'ci'a b pui6oiiD<br />
ud ..r.ntio! bw !.6 deiD.d h &..1 b dv dbill D'Fr @D!t'du Dd tr'ci"l<br />
sui&.0.3t1.391-<br />
13.2 Modcrn h ru!.rld M.tiod!<br />
Tt s!l&. .s. n de &!.hod!.,t of tt R ov'sl proo'd@ {3 l9J0r '!d<br />
t96o1 .!rt ronrd tlF ad of rh! Fi'd. gn .6toctog4!t {t 6'tbd eih d' t9'cD@<br />
Ey to F@if ! idtd.d of r4t!..d.d.d tos &r tt iiLffi'tiod '!d qt_'ni"ih of<br />
thc 6d!d! of o4ld oit|E<br />
In b5r twdv tqD rtd! bs ha . ldd of di'' t"hn'l ieovdr'dt b<br />
sr &oDtoltltt 6.1t E d!..d 6. qrbv of dlrn ua nbtrbv of tbc i'in|d'<br />
V.eus cltodbrt D[n d..to6 bs td toFd.d 6' 'bgriir th' it9 'dl @4o_<br />
!tio! ofoit / nie tl.4cl.al, Tb GGIIS &v.Lt d n G"d v*t b' bo rlo biltl 'tpli'<br />
€&n n t!. Dtib of Ein@ of lttqnd [l.'tl h tti t'6 Dlld tt'r GC_MS Oollh<br />
6tti'. dr.eciv.r..b4E<br />
b ory D'di.tiD tlc in .!d oil .F quorbtiv'lv etzod for rndr nrlv<br />
.ca 64o.aioo ty H&! Mldc u4!id cl!!dbrn!b' 0lPLc) (1 49_l Jsl AordiB<br />
to 6t p.d.d!4 r[. dacdbr b ota6 A@ 25O oA lo 3 ug,<br />
"d<br />
ih' clri! itnLrd d!v'-<br />
riF rrie n rh rulc 6oE O02 ro o2J. d.tadnE q@ lh' *Ldd odlb6 lt la b€l
suggor.d lbd indnidot tirbeid.! on b. d.r.iNiNd b i.p!t01iog Uc$ with dE lid oI<br />
HPl,c rfta botbtlion of (h. rhPL t | ,9l tt tlb qs. lb. !'ulvsis tinE ! sltonaed @Nide'_<br />
tbt, .d tn sdiivny b @lu.tiotr of tiirlvqid6 t inoRrFd wi6 ' uV ddc'ior n Eed<br />
'Witb tb. drad of highv iE d.d da..riod t..lbiqc au.[ B puhc Fount<br />
Ttu f.d GD l{M& lb! '!C hd beo@ . ptu io.l soue of quntt ric uvicJ its<br />
'rcLu<br />
6d.ir fr@ oqLx 6idG of Nt uls 6tui.i.s odotr ''c t'llt,n "poo@pv to'<br />
rn. slyqrd. @aotin ur fdt u.d by sc!@Lt v Dd .lt ov.li [t 601 n 197] S.boo|'v<br />
dd@nFd cl Dd t,u o@r n Fniuy hydresdlcd o'l wi! th..mli..tb. r'c NNn<br />
tr.d.@py ll.6ll, H. .Lo bveli!.lcd t!. lblad oil 61 6.tv.cid o.4o.ab! bv 'rC Nim<br />
lp.dor.oon Drr!.&b!y ud Eub oh.ird sd. r@ltltt qu.di iv. Usbs Mtul<br />
rto
REFERENCES<br />
Il.tl $ .Bdl'.oa B.I. slotlo.ldl R- v.F NotL Priz l,...u.. 1982<br />
ll,2l t.B. N,el, v.stuth Otb.d Fe 5 ,lalEit qlollt dt F.E @l Fattr Fodt,<br />
_ - | B Rcn.rdr.LR Frichrd Ed. El.vit Atgftn Scire l,rbr l99l<br />
tr.!l rr B. w. P.n.id (!d., , tltdtusMnd {lht' a'd oilt' Atpliqt Scioa PutlUE1<br />
Lorb .nd Nd YqL l9lt.<br />
lf.al rd'fulbDf sr.df.if OrDianira c,b.&ta.nniadq ott@n .na.! (@ tiglt<br />
Btolw .sfr4 @tld'dl .6t6t, l8O, Gad. Sr.r.bd NO, 659. l9?9<br />
ll.Jl Fcdarl Cnn l4...n Sdi.. FG|S lttetd 918'rZ USDA\,.ti'8r...<br />
D.C. 1984.<br />
tt.6f EurDd E@Dn c@ny, n4tL,td Nd 35t98a anw w, otr, EuoDo!<br />
Co@ii.. (!5 |).c.dr, tcta) L 35lrl2<br />
It,7l F.I. cot DE. Aldrk RC. rod€t.sed L SiltLs'J Aa On Cta<br />
'<br />
Soc. 4a ?Oa.( 196?)<br />
If .sl tdlruri.Drstlntiorrt[t iion oth..d4.hni8ti6 olotl<br />
st6t-l4 rstuo.t Ntd@ M.Antic Ra@@ tFtu,,t N,td'<br />
l8O. O6.v.. St t hd No. 5t | |, | 944,<br />
lf.9l Bftirl $t n66 bdiun\Oih...b Pan r, D.t nitutifiolotl bttlwLar<br />
Masrctic 8B6,@, Egl.l^tu.' Stlnrd No. 4239. 1985.<br />
(l- f Ol rdddoBl Ulir of Pe dd AopLd 6dtit y. &rt&td n thodttq b. dtdvtit<br />
ojotL l.E .,.1 d.'rrnE,7|b.d4 Bhrw.L o,rbid, M.d-d No. l. l2t, t9l7<br />
lf.rft o'ftd ArbrLlldtl|dt Vn-MMn4t 6oit i" q ITMR4PPI@dN<br />
'@tt'<br />
rpor, (}'(5d<br />
[f.f2]<br />
^lbtDl<br />
ldt@ir rnl Ati||Iloa 1984.<br />
D. Wrrfdislo!,, rr Felt ad Oib, Chdlttry a,.l T..t@logr. G.l R.r' ll.oilo! ud<br />
A. Etli Ar"[.d Sds P|alitr!, r.dD, 1930.<br />
Il.l3l D. lit itid, Ra. !|te CorD. Gt& 31. l8l (1e8.).<br />
Il. lal J. A roDqt 4 dd F.E. ai6!, J. Ai o|l Cb@ So., 61. ta! (1984)<br />
lr.rrl f,Tt 6dr, ,. A4 on cia s6' 5&819 (1981).<br />
lf.I6f lrli.l Sr.rc [tc!.rt|d of;tg]1d,tra..( tuld $.rtdldd.k6ititaoil @k l<br />
4f r,r{r@ir, T..,hi.f Bulcn 1296. O) PaN N.dt nJ6 afuiti,a oil @E l<br />
./@.rd..4 rebn lBulin I29E U$D^,w..hi$ot|. |96t<br />
{r.f4 ,. B. R.s[ r.d r.LR rncrrdF&.) ltutNi. oloitt .n', FaB dnd Fdrr Fod',<br />
!!dir ArDlid sd(e., L.&tr l99l-<br />
Il.ltl Bo*r' cld Ra,,29,333 (19'll).
It.l9l Bred.nd F@L€l J- Aa Cban Soo aO' 5'l (1938)-<br />
Il.2Ol Bhn.ld RobqGo4 ltoc Chd Sci' I 5 ( 1889): AnhdgFr' 'n'6'rd! Z N'hr<br />
! 66|E@,26,65(1931)<br />
Il.2ll D}'., r. Bit. Ct@. 23, 'r4J ( l9l?)<br />
tl.22l Chrt&d Hinis;, A!s. Ofi Aar, Ct4 tl' 6!4 (1933)'<br />
Ir.23l uilig.nd cLn, J. Aec OE a8t cbdr 2r,686 (1933)<br />
Il,24l t(.o. Ba.. 1g 2034 (l87Fi ll, l4l3 (1830)<br />
fl.25l Bo@ trdB.@o,Z tddtucL N.hi. u G@wd;5197'1920: Bo@'!dEbi'\<br />
z. 'ndu.n kh@b,13,5ol (1923): Bod.idHdri& ibnl;75 1(1938).<br />
I1.261 R!w!.9!, On @d Soip, 16, 231 ( | 9!9)<br />
Il.27l<br />
Firh, Marrd, At.nou. od Tritold Oil Nd So.p,2t 3l?(r9{5)<br />
Il.28l Gbya, I'd E!8; ch@, tl{,,228 ( | 948)<br />
ll.2el Wdrd &d Milk. J S& Ch.E I!4.6t. |2J(lga2]<br />
11.30! R.inbold ud D@.. t- AD OiL Cl@ Soc , t5, | 7, l9a3<br />
ll.3ll gt|diih dd Drtto4 ,. Ar O Ctd Soc<br />
0321 \riF, Ba.3l, 7J0 Ote3).<br />
Il.33l tl&G, z. M6ut, N.re u CoEt4 4,913 (l9or)<br />
lrj4l B!|l The Bnctdirr oftbc Li,id+ Bue* Puuinilg Co , (1935), p 15-<br />
11.351 A G Vd.$cl!gi! Bb.tdir'y oflriSblst'et N.do. Mc.d ( 1930).<br />
Il.36l C!!@toclrtty, ft.ci{lAtDti.rb! of t!. M.rlFd vol I, Mn, M.@w.<br />
tl.37l<br />
Il,38l<br />
M. reB, teoldqc of Lbitob6/. I'obdoa An\/sb lnd Id.dti6otior ofl-br&.<br />
Eb@ir, ANtqdi@<br />
Mdnods hM@b!u. BioL8v, El8. PIo@Prd, Nry Yoit,L lor(l9t7).<br />
Il.39l hb.nlory suid. to dodtosnphn dd RGLI d M.lbods,<br />
voh r od 2, Mn, M6@ (1982).<br />
lr.,ol Fn6to!. D., hbotdid.. P, t. Ad Cb@ Soq,'1i,437 (1965)-<br />
Il.4tl L Nt@h.!d L s.r.D. L cledrgr,,435, 139 0 933).<br />
Il.a2l<br />
I- Gi0.$tr, Cnidtognpti, 2r, l8I (1933)<br />
Il.43l .t -Si'sFon .rd tr P.tt ., r- A!, 6.c Sc., ta, J3a ( i9a7)<br />
II.44l D.!M.dc. S.nt-M!i, ChtoDtognPhi, A 9 0987) 27 K GDb,<br />
J-Cbmtosr., 201, 233 ( l9al ).
Ir.45f B. H6bf- o Pod$. dd D. Tor8.rd. r. An. ch6! soc ,,-{861(r979J-<br />
Il.!61 F. Fredq Chtomr.sElhir, tl. 2c ( 1936).<br />
0.t4 G tohstr J- qtod!!oar.,,0a, a07 0981).<br />
[-431<br />
A. Kursa J- M]5a dd L Mrn. J. AM, Ctla Soc..5l, | $2 (r98'l)<br />
Il.49l S. Trkm,.rxl Y. K.!rlob, ,- Ad Ch@ Se,64. 38ql$7).<br />
ll.5ol B. H@rrd G. Kirb.rtq Lbilt t, 783 (1985).<br />
U.5I1 Y. rodoh .trd S. rrL,D, J. CbDdtog, 39:1, 427 ( I98?).<br />
[.52] P. Chrng $d L Riy.., J. Cbrearolr., 46!. 433 0939).<br />
ll.53l & PLnns, G Sp@d dd R. Kbi@, t. Ah. Cn d Soc.,54, 5lI (1977).<br />
u.541 c. M6rrt, Jr., M. V.ili s. G.IOysd, a,.L. r. An Chd Soc., 59, 442 (1982).<br />
It.5Jl L Ic!,pll' H. coli! rld cri,choa ArL Cnd, 56. 62 | (193,t).<br />
lt.J6l K Trrr!.!5i tI Hiu, tl. E8i.d r! Z.d. r. AD Cnd Soc..6t, 1489 (t985).<br />
11.54 A ELrLEdy !!d E- P6ti!, J- Ad Ct@ Soo. 53, 49 (t981).<br />
Il.53l v. xoer. J- K.ra..d C!i(5Fq J. Aa Ct@ S.c-. 5q 629 (1973).<br />
ll.r9l E. C€.qt nd D. D. Sd.t!€. J. llb! Rar.nreE.6, 123 (1933)<br />
0.601 J. .SolooLry .nd W.c. J.lrowri' Attlidh Not6. Qdn iwArD.d6ofc'13<br />
NMR' , vui! Ascil-, hb A!o, C/t! NMn-73-4 ( 1973).<br />
ll.6ll J. N. S.nmrry, 'AlDIic tion Nor.., u Qurli.riv. AsVi..r M€dod fo.<br />
Ddmiing th. C.qdlbr of F.tt .!d Oih', Vrid Ascitcs' hl, Alo,<br />
ca NMR-75-33 0975).<br />
Ir.62l F. E. B!tu'. D. S. H@lt ot.rd D. Budi.lq r- M!& R6o@8, rr, 167 (1975).<br />
ll.63l P. E. Pfcller, E. Ftudd, ,, Llddy. uorub .!d r.N. Sohoolat. J. Am cnd<br />
Soc., g, 380 ( 1977).<br />
[1.e] P E. Pf.&r, P. S. D.ri4 .!d ,, N, S.!ool.rr. Lt irb. 12, 369( 1977).<br />
ll,65l sod XG dd w.c r& NG .', A& CLo Soc., 60, 70 ( 1983).<br />
ll.66l s.Sh,ul,r Ali,' ''C NMR Sp.cn.6pi. Srudi$ ofAliNl d{t Vced.bL Oils for<br />
Qasiitivc Arlrn ofc.!niu.s'.lt!D.ILq!. U.iv. orsid', J.et o,<br />
11.64 S- sb!trLtr Ari A w, K KL.Ddr ed G H. Klri 'crtbG | 3 FI NMR Qunri.tivc<br />
AEt':! of F.dy Acid Coqo.iin of P.h On .nd com On ailg En@l lnctr'.<br />
Prec tLd Cnn Coot (l), |919 pp. 692-700. P..!!wa Udv6ity, P.li$o.
{l.6sl S. Sbr|Lt Ai od A. w. K Kb@d., "Frtv Ac'd Coqdnbn AubaL orsdflod'<br />
olircOil.nd cottor S..d ()|L by Crt Dl3 NMR spc.1losopy', Prec N|ll Ct@<br />
Conf.(tD.194,90. 2()9-212,lqtoliUliv P.hisl..<br />
Il.69l S, T, g, Sh@'i, A W. l( Kt @&.ad M. l, Bhlgd, 'Moii@ e.l CrtboF | 3 NM<br />
QDit!.tnc Arly'b of F.tB Aei.L b loqlt.uibbL oil sed!'.I Elvl & ArL<br />
Cho. 2. I I (1993I Pdn!<br />
ll.7ol $. thouLt Ali,.. w- ( r'lEab, $. T. s. Std.tr i rr ltlb.o.!d f. A. ru,i<br />
'SpiLnic r€Ld! It!. T. &i &bd €rb6 .$@ n Co@rcil V.!t .U.<br />
of &r Qdi* I'r.di.rh of uiDE Frty Aci&', s.,tl. U!iv., xlriDu,<br />
hri.o sliaFJodrL (b DB).<br />
ll.?ll S.St 'r'tAli s. T.Ir Shd.ziA.W.r! rh.qdr, "q!d.tt.utti ofn6r.oih<br />
tr rrc NiR .p..tm&py n hdd fit .!d p@ ehe."- Pt@ N.il ca.E C.!t (|v)<br />
192 b pr*, B.nrw.hu t,ln.. P.LirLt<br />
ll.?21 S. T. n shdi, t\ w. K Kt@d. !.1 M. I. m..e-, 'ArhBn of F.tty A.idt h<br />
SE&sg oil by Ot GodroForrr.ld Cr.hol3 i0tlR Sp.c{'dcop/,<br />
Prqdr.d .. 3nt Ndl Srq. o ]ltl', & Eeie 6@ rrtd rr N.ii(Dl CoE of<br />
AcdG n ADly. Gd U.i€ of Sidr.,.6too do.r r5-lt, 1994.
CIIAPTER . 2<br />
BRIEF DESCRIPTION OF OILSEEDS<br />
2.1 I roductiotr<br />
M6! pld...d.6dir s@ onht r[t 6@@il i4otLM ot! 3"d s e<br />
oib*d ir b!.d @ th. qulity ud oEpotni.n of ah€ tiialie'dd' pr's"r i iL lr slu' tc@<br />
rLc on olrcii i5 rLc @ti hidly pri.d 6stt!d- Tt ertE of 6iitl otl 'Oo l.erl of<br />
o!. ha.! d!'a& @ rn. LElofbrn .nd.di'fribdl id'E Wbo 'te' prear to rL'<br />
darlnlrrn @l dnor bc c.d s . fdillufl r!6 i[. vrt@ is deend'rl<br />
b br.ori.Dl lnd. $o!t 80% of .[ Oil.cdg Oih ud F ts 'E htndLd or<br />
FOSFA (Fc.ldrii6 of oir. sccd. .'d F.6 A'snid Mlrld {zll oth6 oi'r ri'd'<br />
rsiriis e r[. NSPA ( N.tinl SoFba! EoroR AFcixin} NIOP (Ntiml laG<br />
ruc ofoib..d rrodu.ts) dd NOFoTA ( Nlrtdhnd Oib' f|ls rd oib*dr T te Arsc!-<br />
wib lbci9E<br />
Ofi.G.b e sEatrvrnd.d d th. t !b of dite<br />
"d "bLnr'<br />
Ed d.ds.d s.& .ihour! thdo r. ont ildncd ptno.td oftl' gatitl bdr qi6i''<br />
aD€ly oil adat dd protli! 6!i.d. Oo tb. ood h.rd tbe distu' cdr@t tu b tuv<br />
idtrFt E ixlidtin of .$ of pmdbr.!d on quu.v<br />
2.2 Andysis of Oil Secds<br />
Tbc dn ub'ti.iliodia {Goifi.d 'rc i4uni6 m!n@ '!d whtne qn'r'<br />
oil 6fi.d .!d proid 6 d.
2.2.1 rnpuritica<br />
Adoinu.* flcis! stt6, S.U, din.!d.loct4p fc l.|ru whijb .r u'4 a<br />
.ddtiotr 10 ilorii.s, .[ of ehnh u, b. ttdt@u On rn orld h.dd i'r s@ @6!riB<br />
wt6 ,|Aig gr.la of Frrirlt ...d. ilr.y t w .liEctot ''-;s lEpuni.. dnniu.'<br />
.h.! !d dn trcim G€d n FOSFA 12. U ootndi ud i! EuoF gdnuv. *t rc t!.t hl!'<br />
l!. rc @i'g ti si6 by ISO GndIriEl Orgdzriod for sibd!'di'lbo) n l['<br />
d.6ii6 of i.eEitt F@igr Er.d .d &.tra. .rc t@ m se6lt c.d i. r!. USA<br />
Dd C.od.. Tbc USDA {Unncd Srrtd tr.r.n6Ft of Aei4u!w) d€h6 forcig! olcdl *irh<br />
. tdnl. d.G.iq tor 6.! &e( *n @ o. AOC8 ( ff_|r@ ol cndiels socicj) o|nlrd<br />
. @rhod of.t ndDi@tb! of bretn ond, bd &* mt defi!. i, dc. htb.@.of@t-<br />
Malod 61 rle it rdiotim of iquni.s u! plblitM tv ISO i! 1980 [2.21<br />
ftit o.ri.d i .bo pu!.li!h.d u Btii6 glE Ltd (BS 428+P.tt 2_ r93 l). Tt. o.tbod nw&6<br />
..r.niin bysidig.n l $ni's irio in ibE ol..g of irytti.n Gila sa|. tnE..!8n'g<br />
&oo I Oilo g 6. 6pn b 2oo s ftr lE[ &.{b $d n n!€c.d, For olna s.!ds ofit rt ditc<br />
tia 50+600 s b sTei6..r 'Itc oic.'oodi'g AOCS Matod ; cr,*V tioilt bt! .ho<br />
irrDd.l€ ln. h! ok da.<br />
2.2.2 Moirturc 3!d VohliL M.ttcr<br />
Tbe Edod d..6ib.d ii ISO 66n1977 [2.3] .ho pobl4!.d by B.nirh Srl!.hd<br />
b6d'r. (BSD u . .nd ru.Lrd [2.4), b ued by FOSFA for @d.tul eotl rd .|.&nb.<br />
6d.iEd t!.rci! ie 'tt€ lo*r b .s 4!ud 'Dd6 tbc ot4rila ondnirr lpeifidt b<br />
i6obl' wib adie to @6 .[ ttdc !r.!ho&. TIG Gl irporLd of th6. dlb& r.<br />
pEh.tly lt. o..iod! of AOCS .'d lAlC (rd6'rir.l AeoitiD or s.€d cnE[6}<br />
h rL.ISO dcloq lb. piDipL i to €try od rn ittmi{im d rt ldI<br />
Donbn ofd. @t dl s reiv.d (p@ r*d ed nrquni6), or. if r.quirc4 of in puc sed<br />
.t nq. DrlDs; sri.d o'n in r ov- .1 lo3 ] 2 "C .t ltmspi€ric pr€seu. 6ril p!.cticilly<br />
ll
eNt nt ds ir ract d. The IASC malod it ri6'hr lo I$O m.thod . ln this i$tmoe.ll .eeds<br />
.r. sreEd (or snt.d b tLc 6.c of @pn) wilour €rc.9tion AOCS o.lhod difd h dcuil fo.<br />
diEmr !-c5 bd r[ rrc ffid od uil! cr!.d etrh s..d did n u ovo d | 30 ! 3 'C<br />
6r . 6cd p.rbd. ..8- 3 t 6r $rdod !6d.d 4 n 6r €sor ba6. Moirw bae n eqL<br />
,r.?.ntin s t qric siSoi6qd 12.51, Fdi.uLrt n €rhdir8 &n.r sc
@ctroiaa with th. o@ dryine rctoo@ nqtod i, not L.s Om 0.3 .trd thc 3Lnd.rd dcvirio!<br />
m. mrc tt!! 0.2- r. .tb lDpli..rbr thc rad i. srcud for the t€fl&llnce @rhod .nd lot tn€<br />
ddcmin ab. hy NIR, Tldctru! [2.7] br 3boM tblt NIR spett ofwtol. $d stoud rtp4*d<br />
.r..n!ib, rboush sde ofrt. pak it !reu41snple.re<br />
bener rslv..l Moittu. h whole<br />
q*.d b@ ! v.ry preoixd F.l .t 1930 @ tod i n suss6t d lhr rh. rcfleLnc. vrnr.<br />
ofini pajc @r.d.d fd bcrsrodd rc0.dra .1 2l 00 to. @ b. N.d for .@utc rut$<br />
6 sDud dta..d. @fthtbr o.ftb! of o.e, vil oE Dic.r lo3 oC (lJh) .!d .<br />
rr:rd.rd dditin of 0.2G0-!0 lt! b.6 tot!.l sta @q6ri's di&..d }IIIR b.ttrenls {2 81<br />
23.3 Crudc oil<br />
Swdl D.thods lre .vrihbL fot th. d.tmiMriotr of 6dc oil h t!. v.8.r.bk<br />
oil 36&, Tn cLlsi.lud mt 6fu 6ctDd b the Soxnk €n6..bn na[od [2.9]. It<br />
6n dah.4 . sigh.d diy.rd sreud sr6il ie thc.d h. ..|nlb.. qrr.rb! diob&<br />
*nnt' n t6 ir DLc.d itu dr.diE tole I! lL. codi!46 ern 6on 4?| .lut rn. $bd<br />
n t6. frl i oltnEly ben's vrpo.nt4 Uqu.fctl b rt. 6td.@, drcDpcd 'po! trd Fscd<br />
rlrots! tb. rqb ro 6[ b.cr io t[. tb.t drryios win i .ny qlaccd dn6. Moslt<br />
i@s.!dF oL@ ch* rre u!.d.s . $!.!t br dtr.dbtr ofon b dr. Soxhlc cns.ib.<br />
d!.trd [2-10].<br />
2.t-t l lrthd..t l M.altodr<br />
TtG dl'r(tb! of iorE d.l nr.tho& in E!6n n th.t t!.y r.cun. ks<br />
opd.ro' ti@ w . po$nrliy of.rod&n, L.. .LF.d dme, e L'5 $bj.d.d to opdtor<br />
gu !d Fsftly siw ipEv.d D@iriE !d colm.cul |G!dq6 of oil @d.4,<br />
of.Ltion -irh d. slv.ir :lrn(.iiD r.&ra* Edlod nusr b. eI.blilbcd ud6 r[€<br />
bsridrd.l oahod h.r b€ {'prov.d b th. 6!lnc. For .nqL, d. .ld.mi .br of<br />
odld of rEfowd s€€d ty wilc lh. nlsL.r 6!D.ti. co!'@ (NMR) h USA is ao<br />
lppov.d D.thod 6i rlonadic &d qpon loc 12. I ! I. r,w Eolutirtr NMR i5 rbo .ppolcd fol<br />
lh. rd}1iB of @h, dd npsdd ty t[. Euopqn Eo@bic Comisior (EEC) [2. | 2l for<br />
t3
ul€dention purposd Th€ {,.leniEtion of oil. 006r@, .nd vol.til. mtrq rnd pror€in<br />
conl.nt h slab€iG by iGa-r.d r.'tl-r$e it .n otrEnl mahod of FOSfA intqnrlioEl<br />
[21]l<br />
NMR 6 th. nst wid.t ued imtrlMt l nE hod .rd !i.nd.rd ftrnod h.!<br />
bed plblithcd by ISO [2.1.1, DSI12.15], in ruPAc 12.16l. rh. ialnEn mrl *iddy u!.d<br />
n rh oldord .l0OO NMI Artr [2.I7 - 2lll. Th... i .oi&rtL drar t g..r h<br />
&pglyns poh..l NMR h r[. fo.n of t Ontr MiirE iffi b. n.u..tEn of oil<br />
@.tdr Tn.tuddB.d isa tu.lifi.d 66n of Eruld MhiFc Mo(U p20iinrr.u.s B.d<br />
for .l.|dnir|i!n of old c!&r of b. Tli i.trd i .lo b.td on wil rE bw<br />
.sbrbn NMr, u a r[. o.6.d A-lyr. tra . ti brE rb Nar n!q-.y qg5, u<br />
lpplid hI puh.d !.qu@ r..t thi. C6.iFu !y.v.. Ert Mrt {2 |9lw$@'.dost<br />
by Tisn d .l qlu . Yulo.bvi. i.'ur.d .ri a 6loe.d br rg'.i @s BruL-<br />
Mhi+.c ,2oi 12 tol.<br />
Whdd NMR s @qnd sltn rh. .dsy of Rrdio uv. ft.q@cy, th€ ner<br />
hts.d hrt uv.-Lngti. i6 ?50 lo 2t0O m .nd i i $. .!.orton of ggsJ, @r6londoe<br />
ro lh* s@krgdE wnifi drE mLo,Lr vitr.li.E. rbd!* [2 2 | I n Cdd. la .]pliad<br />
rhe MR tahmq@ to borh oil md prot in Mbsi3 of qnob.p€id l.ftb. Bdelsm [2 22]<br />
n a studv ir whih ri dfi.Nioi t.Gffi! @ilDd wD @nlFr.d ein NMR .nd Nll. usd<br />
*hot 3..dr dricd { | 0t "Ol5b for NMR elF6, .r'd st'oh t .d. tot Nl&<br />
2.2.4 Prof.ir<br />
Ar r cd.cuaE of i! ioDolEM in rt!d. .td turnioa rn 6ddion of<br />
oror.'i co.r61 hls t6r tlhid.d io c.i.ifi. mtny on . wldviL b.rs C.tbonvd..t6<br />
s.d oil co .in ft€. oh.@l dffit& qbo4 hydrog.. sd oxvgor It .ddnio. to th6.<br />
prd@ coir.b $oul 16% of ti.oS.., tosdE wnh 5rI F@ra€ of.ulphu lad<br />
pnosphoru Th. Fsqr of ctud. trc&in i! | 6'd@ ir @nvqriEl,t footd bv &.mi.ing<br />
lhe rohl nnrog.n conl.nr Nitre th. Xi.ld.hl o.{hod Nd iultiptng bv rhe 6ctot 6 2t ( | 00/16)<br />
Th. prmipb ofrhit ndl'od i' ro dd.tt d. org!& nid *in turnta &il n in Dl@ ora<br />
ehhsl. ra!.ld tt d.rbt Fodrci .&.liE, d!. d!|il.rd irt& ft llE|l.d .||@ni Nor<br />
la
.ll th€ triEo3a n! f.eding sruf, how*er. i! h lh€ fom of m€ proftnr lnd my b. Drcscd ,s<br />
.i4L dtrostrB oepou& r!.h !s rFnsiE, .6no .cnrli rtleni@ o|@o(h. ce<br />
Tb* .rc Eult Broq.d toSsi6 $ ,uids.. Tn. l]'.t in oih*d r6irtrc b 6uly qui.<br />
3@n, Tru ptui.tu n.di!or.d b hoitios o boM w€islr oflh. cidue wirh ! 6pper r{sa!<br />
rld $ cotp.r subb.te bdd !pcci6.d @ldnlru- Tn t@ prei€h i pEiribted scp.d.d<br />
ty 6htnr ..rt r!. rD'd 6rn6t d ty I[. Kiid.Lt Gtd(l Tn rdit6 .re Lf, h ([.<br />
sinnr &d irc obuLkn .ri6o.rt.[y by difid@:<br />
% sr!d. pror.h = % tu proi.n + %.Dilcs<br />
Tb. sdi-llnout.d e1nod whih j.. nplt v€Bi6 of rtr. Kjeld.U $.r[o{<br />
salg 6 uDn d!..d dig..in ti@ of 9 mi\ ! i! wit6pEd e. Ttc dig6.id binuc b rut-<br />
nric .ci
@l (c c@d.d ro rdfll prer.ir wh6 u.d n $i@l foodrlu$ $d olrihrd @adl<br />
dtribb Dd v{ricty rc ih. h|n! dni Tbc @6ry of mtry @uri6 d€pads. ro &e<br />
sdot @ ortMtioa proo*its or ogon of v.slotL oibc..li A! rn .r4L, ir l!. UK b<br />
rsr y6B indstriB Nhs predlclt $apli.d by th. t*d mlbilg trd oil pre4snE industv<br />
.@rD..d for 5@ 2270 of br.l €qby|al b @lun(tuir&<br />
Thc plryl&.Icl'ncldinl, ofibe s!.& v.ry eiLly, po8l$ly @r.30 @w.&vs rb! nr<br />
rbe prsi *it! s itr.gsins ont ib'riF &oo the DLlr glddnin. Fo. {t4L rn rc.nrc.d hul<br />
@rid ofsdlbsd s.qL wtnb h$ droppcd to t*. ih.! 20'6 by veiSh nont*.Lof42%<br />
T[. on @ ol LB i!6as.d.@.di4t n d 25-32 lo it0-4996 In rhb iosrd@ .n€ hd n<br />
6!.i 6idla rd ligln€r i't wcigh. Atotba d4L b wtitb th. oitu of dr. !.d i ct ngd<br />
to6 blcl or reddih bmm is n 6. dev.loDoa of<br />
'tllow<br />
lol|.d vrbtie of C$oh, Inis<br />
.Lv.lopEar i ro tad6 ![n p.rticdr cloilin np€*d {icy m@ 6l4.trvc sith<br />
$r.tds bt r.duchs t[. 6bd oltd of @l q|.tE nom I l% clo!.r .o t!.t ol s]rba!<br />
ch@ic.lly t!. oils..& 'r hirlt @4Lr .!d thc cl'ed.do! of tLi,<br />
coqkrny n r oo nui.s fi.ld rst6. Th. djor o4daL ofitr€ s.cd. rc lblL of wnicl<br />
@.. ioFtu .r. Lisbccdde,, w.r€s dd t[c @41€x pbdpno'ipids !d 8b€lieils. Notr<br />
lpil 6qomE rrc ibc For.tos, €r!oty&.te, cdtL 6hr., oir@ ud notSttic @nd.<br />
Mor 6hd @qordl! rr. pilDots, vitrdiB, .nbxldlrt , aulEs ed .lrhutrnb@l<br />
&@r.. dl of rni6 s d@ae . oaior ef.(. or r!. FDKio! .td tbc s of t!. ...d Dd nr<br />
s@o&d @nrporot* Ir s@61t.r&!oE rh. hdl oBits tu8rv oforbo[yftta dd orud.<br />
6b.. $i& Er ir Diot prord dd on.<br />
2.4 Common Oilseed!<br />
CASTER BEANST R4irs CoMub Lid.a<br />
S.ed is ovlL !riq![y llnacd nd ofvaritbL Lngrh. 3-20 @<br />
orrE n nritL. eib dbtiFnc @di.g of3*dl @b@
6DD rtic, bron p'rtL or rcd S..d w's|! 0.3s<br />
COnN/MAIZE OERM!<br />
H l 25-35%. ldcl 6J-7J%, oil aGJ2t6, misru. 3,c?.0ra.<br />
peteb l t-2J%. conrlb ! loxic Dror.iF{ich ( l.5% of oil tc<br />
reitu ) .! .&rloi!-@iriE .nd . Fr@r .|lrsd.<br />
A lqdl oil d.t bderl @ t !.d or dr. hig! kv.l or<br />
ft. @. rit t gtom di..y b €lhd D6! y.Iow d bdrn<br />
od Tb. l.ftl ii tootb [L. n rn p. wirn f hddtbr rr thc<br />
rop ofdr. nun, Th! tm.l 6rbrl offou mirr @qo!dlr:<br />
*Ich (549%), nb€. prct io Gldo) dd s.m dd @ii.io 4.G<br />
4.8% oiL Tt. pw 8@ (3% tryGirh of rtuD srriB 5G<br />
5,1% ol Tb. ..D.nicd aol b @!.d b snatb rhi.l h8 llc<br />
.pDad@ &d ,!rpc ofe ir..d wirE- Ir b ligh to &rr boh<br />
d @bu d.odding o! th. &ybg Dre€r aed<br />
Cdo n...f.rt.d br+redd &oo wq E iaof@n6r<br />
s.rd dd &y orfu br b.*6 oi ut srir. It tE6r<br />
@'l!'@il gd is &oD wd Eillia ud b t$i.& 42-J0% oil<br />
5% h, Moin@, 8% Dx. r..idul !t rch. The Ml r*idw,<br />
€m t@ 8l@ .iB 20.G24.0% trorciA Tt &y Di[.d<br />
gdmt (rbn o b. 2G2J%oI or ltl79a oi d.podi'g @ O.<br />
A rchncv n tL l&tri onhsh b roh@t@r.d lcidi.<br />
Oil non S016 Afi6n *tit. @h is l* @tu!Ld. CoII@<br />
cbl @m b/6rnr .1 6-7% on b.v. t€ dev.bp€d nr USA [2.2?].<br />
!.c€ditrs 6. lbil oqo3iir a .bo h.-3 6ftid o|r 12.281.<br />
l1
COTTONSEEDT<br />
GROU DNUTS.<br />
USA. A'rsrnli. C[i!. Wd Ani., Bn,il<br />
cono4*d i, lxom<br />
for irs li'tl (ee&@ [.6) The led of<br />
@ uully rcril $c lid rd i, -U..1wt\Yhae<br />
(;l2* tid) d bbclq vitt Gdul don hriE, liord o! tuz. lt b<br />
Dqr .be.4 lD to 12@ b!8, 5m wi.L, slou.d tnor4 red or<br />
tlctst6bE nrl6dd i@h{iA fh.6 35-4046 W.iih<br />
Avdslvlts br US cotroE..d [2.29] @!1u. e.9%, oil<br />
l9.Jt( pmcn l9-a%. q!d. 6tr. 226%. .ti 4.7%. Oil 6t*a.<br />
|5-2,t%. Ma$ @ rb l-2% by v€ie[t oapigmot gtlds wniol!<br />
6itu.b, @ i6 rdb*.oxic pirF.d losyDol r Lv.b of 0.4<br />
-1.79a.Ir;dnto FF@idlts. Th. ml r6d€ n E d6r<br />
Cnrd. on @db 0.l-l.3% cltbptupaoil nny.ciL. qBitra !<br />
potnnc grbha t d. wniS & d.eor.d @ Fo6iE. Usld .t<br />
d cdbL oil Cot@cil vfiaiB of gl&dl*, Bos.t?ol fr€e o1o.o!...dn<br />
v. b@ &Ebp.d dd sr.M n sisni6q!. tril<br />
quiii.. n USA 12.30 - 2,31l.<br />
Andi. lrrDqrs tibd<br />
USA 6j , Arg.diu, Wd Ani6, Broil<br />
Tb. pod (sld: sbrU sun, n6t) whi! urlG dd6aou4 j.<br />
dls 6bdd l.Foj6 ro 6.G 2.5@.!tl odn rm oi abr@<br />
!..$. E&h .6d (td.l, dn) odi! tw etyledos, taw6<br />
*ni.t li.. r!. r.d. .rd wtFk ! 6v€r€d by. lietn r!! or Gd srh<br />
Cd o. db|.), 2-.r% ofd. ...d hy rcisl!. Thc 16!, ehnh<br />
wic 0.t2.08, r!!c AoD 3ph@ql io cridni..l with .<br />
lln@d , o@rH or pont.d ad. Th. LrEd n'nl ..& Vnsin<br />
nri*y n ih. USA. .@ s.k..cd &r €dL pqpos- Sh.U weish<br />
l3
LmSEED!<br />
MUSTARD SEEDr<br />
it 25-35% oftlE wt LFd.<br />
TIE l.ful o.iii. 4G52% oil 4.G6.07o milrE , 25-30%<br />
pret ir .nd 2.t3-0% .Cr 12.32 - 2.331- Tb€ .lb @dr..<br />
r.di! &d is .@v€d tu -4 foo.l uB b.oq. of itl bincr<br />
rn.- Tbc @l sii& i. B.d 6r .nidl fe.d<br />
A &n iq'n
OLIVET<br />
(d) Sniit .ry@i &nu@) Chrrbc* o' *ild mnt r4<br />
EuoDc uSA. t di.. Chn (pnic.od tLck): lndir. r.t E$r<br />
Co.h (t{oM)r Euopq UsA (chrrlock)<br />
Th. ied ! brc t obb6g sttdic.l ot 3lirltly 6$a.d Ll@lt,<br />
wil . pttd o. rti?Ld .un€, Bom rur.rd (.) it tphaa.l<br />
r.9rm.lid6, !d Flbs c-d rdiaia db. n bdi, Bbcr<br />
Nd..d (b) dllld b lpndi.L rddi|6 t om nd rj@<br />
dnD.tq, It. wln. spdi6 (o) i! tutrdcd br@[y, 2.5m lo.g<br />
ud ir 6@!t '€lbw-<br />
C[rib.L i. .ibilr io r.p€*d 6d ir<br />
di66l ro .t n|c &on n. \t i!h. of IOO sdd B 0,37a.<br />
On 6rr.d 2/H0t6 Prftn . ml €iiE ,tli%- C.tt b3<br />
girsnob&s .!d rbc ptge of .!yl .Dd Fnty&oxyb.nzyl<br />
nollioc]{Et. B rBposibL lbr th. pu8.d sftlL wih mininD<br />
|bn of0-70% (.) .!d l% (6) or rM D.l 2j% (c) of Ar.hy<br />
&orrtoE r iltliprDt. giv6 nr 6. ISO speif€tiD [3t1.<br />
Th.l4ud on b id|r io @ao3tid b tie! tu. t.p6€d<br />
oil Ir n s.d & u dibL pu.poc. p.ni.uLrt h bdi.<br />
Ot ENp.. Li@.u<br />
Tb. ftn of! oliw b d cee 3t p.( .b.!rt d rh,p., 2-3 m<br />
bq; ofta adiig ii I Doitr. Thc @bE v.rib 6on gt@ or<br />
wlic bfrtG, purpL, r.d !trd bhc&. Il 64ri'B !3 ordd sldn<br />
(1.!3.J% by w.i$o, ffituD or pub (6J-83% hy w.is!.) ud<br />
u arl,qrD o. ir@ ( | 3-3O% ty wish) w[nh 6dn o@ red<br />
(3% tr w.i!h oft[. &4.).<br />
The wboL s.d @qri.s ,|{!50% vrrf,20.25% oll nd 2s-<br />
40% $lil rdidw, TlE on distr<iotr nlio b 96-93% G.ri{rp)<br />
.!d 2-r% G..d). Oltc poac." 6. r6i&& @trtaioiog thc dloB<br />
.nq dniq; i 6.d n .dol f..ds brr !.r ! tlv f..dina unr<br />
z0
.rd @y .lF b. usd $ fiEl .nd fcniliF. At.mtirct ftc oil<br />
@y b. dr.d.d wi! $lvat fot inddri.l le<br />
A hunl cdibh oil wrb muult lid @nIdt of olei. .cid.<br />
lLe o'DDdlid of t[. tdd oil i. riEilr .o th froF h. rub.<br />
Tn urna gnd.. ofthc mq6,.d oliv. oil ohr.iEd nod ih.<br />
D{b .rc !.n tu d cdibL or p!.d€dihl pu.Dose So@<br />
sr.ds ofr.fr.d .xh.r.d on rr. 6r .dibL u." b*d Bn&t<br />
Eh.i g!i@i N. t J&quil<br />
Wei Mr|yli, S.t !,I Lci. Nigdi<br />
Tte prh 6d r &l4c &d b smur b hrs. hbcb* *lh frun<br />
rcproatins 60-65% ofth€ budr w.t!r, Ar€ns. hucb woigb.<br />
i l02o k! b M.hysi., wi! |J00 tli uch. Thc nrn is osl<br />
3h.p€( 1t56 b!9, 2.5h i' didd rd hd6 ir rciahr<br />
6om 3 to !|)!. CobE i! d @ilbd .od v.tis toD d..p oEgc<br />
ro rcddi,n bloM or bb.L Thc 9ub ocb.6 in 3ed or ldd<br />
whid! witt b lmundiig brd itGl, h qlcd the nu. T[.<br />
en ln w ! ory gcyil whn. fl6h *ith. hld hroM @.t od<br />
o@3idlt rh*.G tm Fr nu. W.islt of I0o td.l i,<br />
8!r2oa .od ..?r6.dr .hod l0% (*Giih) of r[. nui. It<br />
M.hr.i h ia.d ya6 Fh Ldd Dio<ior n lbom 27%<br />
of6. p.h on ouer! Oy w6ish).<br />
9.lo oil oflar of pob .vasa 56%. Ma @ryosiri,! of<br />
Mrhyli! Fh oil tqacl is: oil 48.6% (a6.+50 E tuirw<br />
6j% (J.98.r%). 6t a c7% 12.16l. Prer.itr 6d6t of.nnc.d<br />
p.loLd.l@lh |7-19" rdport d nnor @oDoemr tr.tn€<br />
m.di& pqat h th. Dub ldl h p.b oil .r !ve! of 100-<br />
A 6ai{|i| .dt& oil 6d.i'ins . nisi ke.l ofp.tniia .cir<br />
zl
RAPE SEEI'T<br />
RICE:<br />
M.bV .dftL @e Dd 6tr b. ticrb@t€d to provi.l€ ! @@!<br />
A @ieEd.diblc oil @Dina. bisb LwlofLub.od<br />
M.l6 d lowa l.4dtu. tun trb on .Dd .l$.t Edblc 6<br />
od! on n o@oslin Ur.d rr b .ditL or httufil oil OE<br />
$bliydd f6ai'epotgri.. oflu;.cil !. |!nt d h<br />
CdL rrrc.. Itomd! PoL!4 UK tldi ctiE<br />
T[. ..iBi'L boM .6d .rc .lbdsl 'pbai..l or .tslrt<br />
f|ttocd ln6dv, .bo'n 2@ diDta. Th. Lu[ ( 15-20% of34d<br />
w.irr) i ratuh.d ed i. n !.!E i| 4n ibdSis &.tu.<br />
bav€idnndt t t$i.. .d edpn saei6. woeh of l(|0<br />
Alase v.bd rF 3q5% oil 6-99n minlq 2496 pior.o<br />
I37|. rob*ilrE 6€d(t rn l{h6) .rc ac5ota.rld<br />
o(nd [381. Cr.dio 'a.d (q!oL md nF*d) ovd . ftc ya'<br />
!6irt,lt7-1t82,.edrFil4r.q72%<br />
oil( &y t ri) Ed 39.2-<br />
aJ.6ta Fol.n (ol ne &r hrir) llel. Th. ..d odn ![si<br />
@ln6 d ldll dgiaA@ 76 (da6td) 1o 123 (upa)<br />
ldL /A di.d oil dn ccd @l rhlhl @!rdr 36% fih.a<br />
26* ortoh,rt ta.!d@ hial nFt4tlot-<br />
A [Auil .diblc o0 nith E6 Lt d o! l[. tui. .cll Mt d. On<br />
witb Lish Isv.L ofqun .oid (gatd tlrn 40ela) i @3rlt u.d<br />
ibily wirq!, n |}. wd@ wl4 on tu GdibL e i<br />
odDn d ty letlo@ .r . Lv.l of5% dlid|e<br />
A mh @l coA the ri@ gni! i! acLFd in ! hrd brom<br />
22
SAFFLOWER SEEDST<br />
lr ir ofotb.B st pc .bou Em lon& Miniba itwlv. 'lehulling lo<br />
sivc tiam rie, Brn !d slm .r. rbd r.mv.d lnd politltd<br />
DilLd rn ir c.d 6rt@! food<br />
tlo! 207. L€r.l J29t n tl l5%. br.! l0%. Ri.. t D iE|ud.<br />
sdD, sm hdb. pdinrp Dd eft @&sp.m. lr @r!is oil<br />
,23A\ preEi^1-rzqq tu . ('27%. .s! &22%. Tbe lbcc<br />
azyB tr-d<br />
ph.nE. rpi.l.i* idrnc FFA.bd oxn .lF of<br />
o! dnits. C@.qudt tlE t .tr is €illd 6d io oiotl &.d<br />
d rh. e*inci.d on wdn,r e.P '@ufrde.<br />
A hun on di'iiing vitmh E .trd witb lt8. lordri.l votG<br />
C.n!r@ tieloia Li@cB<br />
Mdiq lndi. USA UssR Sp.@ PonusrL Aus[1 cb{<br />
Th. nri b E .cl@ ( diy, des..dd wd . Ob h!I). rt<br />
r@b&. I ordowd s*! @lou.d crab, whic or erey. It i!<br />
incgulrly DqFblp.d sort ot shiry md 'p ro loDD Ltg.<br />
Tb. bll ir i[i:l.!d 6LoE.!d 6 ery n prepon@ro rb.<br />
qr { 43% h bdi. a0% UIA). Wcishl of I OO r.cd rr 7g.<br />
oil 254w6.ctor.i2o-22%li @l Giduo), 60% (h 6nt<br />
d6ni{.d @l 6itE}<br />
A [t],ly |4turld lhrld .d$lc on wih ! lth 6dd of oLic<br />
.cid Tm trt6 of .rc stoM-lir! limleic .6owd on ( Cr8: I /<br />
lrTq Cl8:2/ 77%),Iodnc V.lE 133'145: ht! ol€b lmowa<br />
on wth Lv.l pE3€d ( Cl8: lt7% ). SFnitl Dd AEir.|ntr b3<br />
L.r tld 7a% ofliml€ic rcil shcl6 cbit..c b$ Dr. lt|d<br />
80%. orignit rn indEtri,l oil botb tlT6 .c @* N€n for
SaSAMESEEDS! Sdd@itdidt!@.s<br />
Sos4r Cti!, Mqico, Sutl4|ndi<br />
Ddoinion: TL. pa-$!p.d *.ds 2 5-3.0m htrg" l 5@ wrd..nd 6ltwd<br />
hlolq t omdrntos*drsld!nrb. Alim @ftci'r<br />
'T hid', n h.!cd on 6hu. Hqe lbc .ppaus oftb. gio@d<br />
wlL ted oir.it with rugtt ! pr.&ft.I rh. hill b 15 20%<br />
v.idt oftl. Gd ad 6ddB 6Li@ orbtc orv.lt w.L!'r<br />
of loo Gd n 030 g<br />
64ositbd- on 53% ({r"60), bicns hv.k 6Dd srilda losd ld.L froo<br />
hdi [.!01. PFt io 2F2t%. 6tt. l2%, tul 6,6% (&v b..i'),<br />
C.nrir vqy bili Lrtl otEte dd.ft ed Lis! levcb of<br />
po.isns o8!*i@ ptlol. Mql r6id@ B.d b siDtl f..dr<br />
Sd@ oil- A li blc liqlid..n:!b oil rid' i oli &d bobn.ciiL-<br />
SOIA}IANSI Gt,tt@l4 Lids(8Ei[,<br />
So@- USA B..tl, Atgric, Cbir<br />
Deeorsiimr ltc s€d i5 obi( @rt .pndica! up |o 12 @ bng; sinilr<br />
n ti& lo . sI pa lt i !@lt v.[N hr . o@Da of<br />
@ldGd wi:ti.&sr!co, t@q!. bL.L, di* rlc @t osisrs or<br />
r*o 6tir.dont 6cbc.d by . liqh !!! (8% b, wGief.) Wci8!<br />
of l0o 8ed! 8.J &<br />
Ca4o.itDc- oil t7-21%, Moinu. l3Tq preteh 35% Dd, ibG 4 8% Od.nd<br />
tna.ir Lv.b v..y iw.t b l[. USA .tq.a. v.titv<br />
di&@€ of3.9% on, 5% trcteh rrc fo@d. Cod.i$ E<br />
@rE-liDrr4e p|ldDng D-rv f.vou bv oxid.lb! of<br />
tb. oil md ! irrtsin bhftnot ir a dal rdidc Mal cnw 6cd<br />
n 6iD.r &.n ot bobi6 foi hljlfu bod<br />
soldla! oi!- an lsMld lhuil.d,tL oil M.iiV.d$L !c wnn sc<br />
hdutlil !a,!o.aoc.<br />
24
SUN'IIIWER SEEDS. Hdidu.dN Lin.4<br />
Ar&dr Fnc, UsA, hrSrry<br />
Tb. tl&! (.ondd or s.d of co@.) .r. orrwo u.itne<br />
14! r..d.d tEd t)r @!&ctbsv (2t'3t% oil) .!d 5@[<br />
.6.Ld tp6 nr oU c.L (4tl5ora oD. T!. LrsG t .d.d tv!€<br />
b.!. blri'di.l .trbiry r.lSitg Aon blok to wbita The s@ds<br />
dt<br />
''to lt@k g; Doildldrh.b.G odit d$dEioD<br />
&d Dluiv bwilql I|F o,t5..ib e lAcL ot.L* t oM.!d<br />
.@ia ofs ort6 bBls 23'36% ht rci8la (a3% 6 rrg.<br />
...d.d ttT.L acbi8 d. @! *nnh h.! lm @tvllrd.a<br />
qr.igtn of loo .a& 5.7-6.7 &<br />
oil 4G5o%. @i!@ Gl3%. For.n l6.tn9 6%. 6br. 13 2_<br />
l r.?t(.d 2.e3,9t( Th. tulh .E tili b fl'...!d on n<br />
*rio whijh e...tDdd wi! O. on [al], Th. @t @d.ia<br />
L5-2.0% dloro!!.i. .oil ehi.h 6u6 &it@itg b @rtu of<br />
6. @l6ih. rbr oxili..r<br />
Arl@turt d lhuid€di .oilodlhbg [ir! Lv.b of lirolcF<br />
eil Ur.d 6r .diU. Dupo6.
REFERENCES<br />
12.ll J. R, Pnc6.d.l. An Chm S.c.,60,322-32 (1933).<br />
[2.2] ldl iiul Sr.librd o'SDn.ti,4 Oib..ns: D.bmi@tid oJ InPrnti$ CdE t,lSO.<br />
cad., sIrdrd No. 658. 1980.<br />
12.31 rdddb.l $.rAr& O4tl .tio4 OiLc€d.,<br />
ttt nitut 6 oJ tuxttt drd voletil, cda. SurAnl No. 665, ISO- Go4, I97.<br />
12.41 Br&'bst nd.rd. b.tndio!. Oih.ldr Pm 3-<br />
Ir).dttudd dMoit@ a,,.1 raLdr. Cattr, BSI, bnilo!' Std.htd No. ,1289, | 97&<br />
l2.Jl P. c, wiUn@.!d J.T- Sr8q.Lo4 c@l ctd, !5, 214 ( I978).<br />
12.61 W.rr lld.rd M.lI Nesd,l. Alq OE AaL C!4, tt 757 0966).<br />
[2.7] ILr. Tbcbul! r, Ae ct@ Soc,, sq 819 (l98 | ).<br />
I2,3l r.t ridkbutd, r. AE cl.d soc., 9, 33&{ (1982)<br />
12.91 IIJPACE&attd.r.l Methdt Ftm.ltulttitoldk, Fdt and lLdwtb.s.<br />
Si.I Erhno. Pd8.mo ft83 ( | c/8) F.g<br />
[2.10] LA, roh@a r lE.w. Llu, J. AE chm soo,,60,219 (1983).<br />
I2lll Fcdd.l Cr.n l!4.db! Sdn G(fS) iErru€bt 9l3-3t, USD,I, W$hn8to4<br />
DC, 1984.<br />
I2.lzl EqoFr E@@ob C.@iy, R4lltn No.35r5/8a Ada. VIl. Otr J. EEopa<br />
co't6Eii* ( | 5 D@ibq l9t t) uJ&t 2.<br />
12. l3l J.A" Robdt'on |!d F.E. Drno4 J. A& Cb@ So.., 61, 543 ( r$4).<br />
I2.l4l rd@rbuf Si&.frr.t OrS&iatia\Oils..dt-D.t tuinand oJoil C@t ,Llb<br />
Rttaluti@ Ntcl.ar Mogn.d. Rsdue spettutu bic M.tho.l. 1SO. Gada, Snndtrd<br />
12.<br />
f 5l Biiidb St&
12.f?l Orlord Arvic.f b^rrF,ltltd,MMt ofoil in 5...b h) tMR-ADCli{'tion<br />
R€ro( Oxford Axtd..l bltrul@ls lrd, Abinsdoq | 984.<br />
[2. r3l D. w.ddiBlon., h: Fe6 & Oil, Ch itnt & Tehnolog/, .d. R. ''. tLDjlrob !trd<br />
Bhi Ar4'[.d Sci@ Plbli3[ar! LodbD, 1980.<br />
^-<br />
[2, !9] P.N. Tiwrl t,N. G.dn, T.S- Rrj.!, t, Aa C1.6 Soo. 5r,104. 1974.<br />
[2.20!<br />
P.N- Tiwrd &d W.,- BdL. t. An Cnd Soo.. 57. | 19. 1930.<br />
[t.2U Rr. T.c,bul! r, Aa Ctd Soo.,3a.8lq 1931,<br />
12.221 L D6g!co4 F.,ite scif@ Autti:b, 07. 262, 1935.<br />
[223] F.&rtior of Oihe& ud ft. as.nibE, trd (FOSFA lriqutbDl),<br />
Muul, FOS!4. Iltcdrbu! ld.bA 1932, P 2?7.<br />
[2.2] AOCS Unif.(EMcbod Co@in.., J. AD Ch@ S@.,64, 1516. 1947.<br />
I2.2Jl D. Rr-h.illir Dd M.F. M.vict, Rd. t &. @rp6 gr.r. 31,I al, | 934.<br />
[2,26]<br />
B.A. CoLr, t. An Cn E, Soc,. 47,202, 1980.<br />
12.271 B. J. Fit t l|t@Dr J. AD Ctm Soc..62. 1524. l9aJ.<br />
[2.28] E.t. Wctd!!d D.E. Alou&]€r, J. Ad Chd Soc,. 52. 370, l9?5.<br />
lZ29f WIr Tbtt. h: Cl'fuddt t Cotldt d Prductt,d- AE B.iLy,ld@i.6<br />
hrl,bhat, Nd Ydlq p. I28. 1948.<br />
[2.30] E. W Lss od C. M, lividcd,.,. Aa CLm Soc.. 64$9, r93?.<br />
I2.3ll Urild St &6 Dqd@! ofAsri u., Eo€.dit8s of C@ftrae @ Gtot!.rs<br />
Conoa A.RS, Aefsu[., Md I9??.<br />
[2.32] GD. Ror6, I!: P/,|j'@.d Ph"t P@lin Fodl'n!n', 4. LM. Abohul Aq&di<br />
Pl6., a YorL t ,125. 195&<br />
[2.33] g,r, Tri[ Ae Ct€d Soe, 5t, 69, I 98J.<br />
[2.34] AG q..!, t. An Cn@ S@-, 6r, /!0l, 1936,<br />
12.351 ldmrbrl Srdit'd Ors.dEtior DBbrd *.4.p.ci6edor. lSO, Gqdr. Srild.rd<br />
No. rr7,l98l.<br />
21
12.361 T.s. f.!8.nd P K T6n. L An. cto loa, 6|,25d l9!5.<br />
Et4 ]t" tloc. ol lrr! N.xr. !r.1. lga?.<br />
[2.!al ,. rr@Li lcl. sei6o Airi.\ L,{6l t9a4<br />
[2jrl ,. x- Dr. Cdl Food lrih.I|l ,. atl,lgL.<br />
12./Ol D. x. Y@r S. tta|r6. w.s.L.Ldc, lL Ara.,<br />
t aa cl@ 8oa,. at- 20. 19t2.<br />
. [2.all w. rI Xottar J. AE Ore &c. aE, 1064 1916<br />
?t
J.l Introduction<br />
CHAPTER-3<br />
VEGETABLE OILS<br />
Ib b.m. .xl.rd (o' lish p6oLm .xrtc) i ald lt. 'ol .odd'. fti &ei<br />
rir of t!. ld.uriool Srdd.rd O4Ei.tbn (ISO) i.lr..d.pl.d it tb. F.dd.tin of Oih<br />
s.Gdr.rd F{i Al*irir GostA) I'rd..irl o6cil d}od I!. u. Il€ EEtritr EoDEI<br />
Co@ity (EtC) .dopls . sioih .l€6ntlD hn rdtias tb. e of l[. @lv.d n.r& o t [3.2-<br />
3.31. tt. dbd of t[. rdantiDl ADciia. of s..d cindt (t sc) .dao . .i!r'<br />
ditoiiD b IEO .!d POSFA dqDridl 13.41.<br />
Ofi & !i!/€t d't of fry .cil n r5.r tbE ndv rcid 6Ld6 d da;<br />
ftn w|! ocd sbedl oL.dq . g:<br />
nl*<br />
rr-c-qr<br />
o I<br />
ll,....c€<br />
o I<br />
i 3lom[ rF--.C-il]g + t f,rO<br />
o<br />
I<br />
F.tay si.h oit
F.rs ! l oih r. 3ut!nnc6 of tiniht c[q!i"t 'tf,ene hvhs th' !.m<br />
n i.bolis h ih..nmlbodv F.B @ eIt 'I ddirtv tanp*'rt'' -n..'s d8 !' l4ud'<br />
oah ue thc rdt @'i.rrt tC $dE of 69 &'d b tt' dit turdi|. ' li'tL<br />
mr. ihn lwic. u @nv qlonc p. unn *id{ ! N6olri/dt$' d ptu|.i|! (td'boli4ble<br />
cGst h qhd.5 t gd:frl! 91, rrotriral oboltvlrr.' l)<br />
Ahtous! th. Prim.v frnktrl finctioi ofoib it io t{CPt tt' b'dv wih ' eu@<br />
of gEA,, oih t. .ho inFfi.trt in oitt ac"t! loc oib rt v"nin oti'6 rh v'rc'bL<br />
oih r. ol @$i!a.d irF.n.r $|.o of vibnii di 6t a'tlid of bs oi\ b' 6t!pL<br />
,alnoilIl5l<br />
J.2 Uscr of vctrldh (Xb<br />
Th. iG strd oiL h.v€.lw'v' u *'rti|| reL ! 6'd fd mdind ln 'tunio4<br />
ho*tg, ou tEdo i'd!.rd.l 9trld l$ n"v iipond 'Dglioti@ fot lhoi Tttrc !' tm<br />
b.ord cl*ifdtbE fd rn irt td oiL: 'diuc td it'diblo It' oE@rfid of aa udoil n<br />
ed'bl. products t.PB.nis .bo!r ?Op?6 oftl u6 oftlE t ti'L Th' nriN 'dibL oik'<br />
@non ..4 olivc eF!-a dtr' dc, .s 'Abv'd b' tld &-i!g* orlt t'$' 86 rdl<br />
fo. @ori.g puto.6 Th. hvdrcgdi'd ntt nt co'lila td t'lng mv iEutL ' Pi'h wi"v<br />
of v.eetabk oik, sucn s cottoN..4 Ftu! and ev'hqa tir th' nvdtogimLd pt@s<br />
imdov6 ttE @lour, 0.vou, .t'.1o&u of tlE dtiil qd' Pddrc'r s su $ tnt rdpna<br />
lo
Ahour 20% of id€dibk oib .r. a.d b sp indGty. ircMhg t.Iow. @mnu..<br />
r.h oil .nd c.nan sras6. so@ .rs sltlt b/droe€uted to @t 1b@ suitrbL ro.<br />
opqLiB. Tl& dryn's on hdBtd6 (inoludi.S p3ilr .Dd hmish$) coslm 90% of the<br />
h.dtu. oih, aitl| 0$6 qior @surp.ion of lin!G.d. tus. $)nb€rG md ecior oil in smller<br />
dd!4 Tbe rlrybg oib .e 6..dblb u@rEld ud produe 6nD. or @.ti.8s upoo dryins.<br />
TIE rr..L. cqhrql eitb rrDthaL Bbs.!d @[ut8. dan|tiv6 to 8iv. !p*il rttc of<br />
6b. Cea liE..r|. !o).baa -p6..rl .d 6rioE .d oil.rc h.iq 6d lo $@ *id .s<br />
pldniai tor Lcq|B dd Ftrl6. Oind oi*L@ uc imhtL rLG on cbdt .nd<br />
liDlau intnry. r!. c|r@i:l bddry for th. EoA.rrc of 9r .!d oil ddihit6. 6e<br />
'uuAdu. of btiisrs lrd g6s. r[c pidtios idGr'y. dd lbe lb-plr. bdunry, A wit.<br />
uri.ty ofoib lo@ m ii€salD.n oflrb8 polirh.!, oqtrE,..d tuubioB, tra. qu nns<br />
of.ufoolcd gbldik" dd rdiid fitly rl@hoh !trd ddildivc s.fr. s wcnba rsd.. !.d<br />
(i....!!d.. Tbc da.il le e si@ io T.bt. 3. t.<br />
33 Edible Frt Compotrcrt<br />
Co|l]@il edibl its !r. @Ept r bidEe of ristcaid.. Dd 'd[.our of<br />
olld.uhdd.6 o@uia stdly in Dhdr ed !dD!16ts or daivcd tbrouC pe€3ids .nd<br />
stoEgo of th. ftts. In s@.1, the !uhd!n6 ehjoh Ey 6qris6 6Eeroi.t.diblc frts !d<br />
oiL irFludc llc fouoeibc-<br />
Tri$En a dielEll€, @.8llrdidc., tuty rcid& .l@1, ptorphobid!<br />
DigD4 h. shbk vimnl' bdqtbo'& Hrd. orid.rin ploiluds ud tr.€ of Dc.k.<br />
Tt liElFai6 mb W 6. hdr otr[. ni dd @s.quarry.rc of satc..<br />
rc.hirl i!torr.@ llo*fld !h. sdu .o@r3 of .scbr.d subleG .c .h. iqoti.nt b<br />
t!. 6od oldjlt !d t.{hoL8isl. C6i.b of r!6e suh6tuc6 .rc .Grposibt for lh.<br />
d.nd*iltio $.re, o
T.Dl.l.l<br />
U!., of v.rktu Vca.t bL oils<br />
Cd$ciEy.ld iqi€r: rw.c fniEs n b.ol.d 36dt, tuty<br />
.Lo[o\ eD. .!d darr.dr<br />
Srhd dd @ti'g oil 6tr.dE Dd 3tondng .t6 p.nil<br />
con@cd on s.Ld5d ooria oil otgriF 6d ebort@ig lno p.ni.l<br />
tldoge4rir4 dp .od .Ltrs@ls.<br />
Pri!., {oi!.& tloor @v.rn$, htriQrrs 6d i!ls,<br />
Ahlralon ir.4a.ie<br />
liL4r.iE.t nai'8 .na Fnil hrdrcsdri.a 6!&
!..tiutrd d.ry tury slt re6 & &r batisl.d. Th€ sluted rcnrs, W to .nd hcbdrg<br />
qpryucr rrc liqlidr .r ordi.iry r@pdr@i rbov. qprylic th€ acids tre $lih,<br />
The l@tnied 6tty.cids !r. foud widet .lbtibded as gbcdido in th. fts of<br />
diDh. Dt ! &d @inc 6iEL. Itc u@tu|.d !.i& f. mrc .hdn lt uctn. tun<br />
naqt d rlL ed rbe!&tc of stana |. tlobsi.l i4ornsa Md1 of rt. lD$lnrcd .cils<br />
..dil. rff.ly trv. l,r @li'g poi6 ..d @.q!.dly .rc liqdd. .r otdiory r.4.n'<br />
Ea. Tn ttgae of I dodu. tond pdrt! .ddiin 6.ins: .!!dibo of \ibo86 tw tlc<br />
@nc.!o!dia simi.d rcil:.ddiioo of itb$i pdoang d €*iEtbD of i!. lmba of<br />
&uU. bolib Fd.in<br />
(i'dnc nh!):.nd l!. tddniE orox],so to oq. oxi&tiv. d.nionrbn<br />
b .dru. its or "di'.rg" itr thc dtyiA oih, t bL 3.2 li.t! v.ri,u itty .cidi wlh rhci fodu&s<br />
T.bl.3'2'<br />
Vrrioo! f.aty Nckb rith lbcir conroq rFa.malic orm.r, forruh!<br />
lad connon lofici.<br />
I. NORMAL SATTJRATED FATTY ACIDS<br />
cH, (cH, ), coon<br />
crl, (cs, I cooq<br />
cI\ (clr, ), cooH<br />
cg! (cH, ). cooH<br />
cHr (cH, )ro cooH
Mrr6ric FTa.&oFi(l.io) ClIr(c.It,),,cooH Codd.ndFlrtur<br />
o'q m$ltMl.d<br />
P.lm'tE cHMd.dma(t6:0) CHr (CH1)ri COOH A[ einl.nd,td irs<br />
srarc Fodrdd@ic(18r0) Cll(cIr,),6COOII Addnrsud.hr<br />
@ftpoEn ofDLnr f.r<br />
Archdic n-EEo$noic (2oro) CHr (crl )rr COos pdur oit, mll.nout of<br />
odrr pbd dd .niDl f.rs.<br />
sdrdc GDo@.(22:0) cH1(clr,),cooE H*,ff--<br />
Lignocqic FT6n@$idc (2.:o) Ctr, (CH, )r, COOH StrU momt in p.._<br />
nur o4 .trd Mt rrull 6ts<br />
I, UNIIATUIATXI' IATTY ACIIIS<br />
OLt e-Ocniled.:(rE:r) CDH$C@H ptnrdmidia<br />
Erlcic llr-Do@ma(20:l) CTIHTCOOH M6r.d !d rF..d oil<br />
(T) D'ENE<br />
Ldolac g,I2-Octtld (lE:2) Cr?Hj,C@H lrodr..d tu1 niFr<br />
Ci.Dio @'trEoMt of<br />
(ct rttENE<br />
L@l.n( a.l2,tt-OcL t l3.Jl CTiHTCOOH Lc..d rrd otb.r<br />
d.disi 5..d oA.
J.a Strrcarr. .f Fr[y Aci-<br />
1s-.dlt/|r<br />
Ibi$rr- dt y r- rt -. o.-..N rd i { tr* or n lb<br />
o<br />
lt 2-rt ra<br />
(Il{-{ ol )i-cr,<br />
o ar L-t1 la<br />
(n) S&ii. (1,r0) Oll--{-( ClI, ),.---4\<br />
r. u.a..nll Frlr' a.|l<br />
(i) ok& (ll:l)<br />
(4 Lb.lic(18r2)<br />
lt 2 i-r 9 to tr r2-r7 ra<br />
ro-c..{H,-< cll, ).---{r|
3.5 Propertics ofFets rod Oils<br />
ftrn l rd ch@i.l pDDqtb .r mt 6dt* btn ury enhh tdi! s dDm<br />
nr TrtL 3. t. V.ruriotr Bd. nod tddl ou*:<br />
(l)plliftt n de.ived 60r @ry vltili6 ot.p@i6 8rc6 id dif'6r loqhns !d<br />
(2) un-l it ay uty *ih trEd .td f..4<br />
(3) .! Ao id!a..d 0y Edod. of rcfti|!, pt!6-e; .s. dd trm8! @ldiira<br />
soc i4or..r !trytn dd .5dicl prpglis of |nG tur .!d oib 'F the<br />
3.5,1 Ptwic.l Pmp€rai€s<br />
Th. ih.iryof srt..oB ilh.ntb olits |lsb i. she tht rheior'<br />
s!!.r.e{riuwi[r. 4d.w Fotnr!udoili i..atestdnsEstd6 ilittc<br />
Spoi6. sDvity b dc!rcd.c rhc !B of. tutd.tr!€ tt t'Crhiv. to thc N or<br />
r.qulvoiE ofw.tdrtt'c<br />
ttdltti@l ldpo4le cf d.nity Mrt t !L:<br />
Spei& sEvty 6t@ ilo 6t v..y gratt bd*d $. dntd A$ ttd oih<br />
hd. rhi .t nadim. n of hL thE h damnis tbe i.hitv d pdtv of . nt D@'Y<br />
'<br />
of @sildru. lrl5 towq, h ..tiDti|g lle sBlilod r.!io b offi'irl tui<br />
ArrDugi rt. .l@iix of sB ot liqun tu r. qui. dr..d. thac . gld derda<br />
baw6 th. .l&tii. of sfd rd liquid de di. .xD.$bo in 8ti!s noo @ tttt' to u orh6'<br />
Thb dp@in is lh. b.si, for €sti@tioS elih itr ! plnitnv ml.d &t Sp@i6c 3tlvitv vill<br />
and $dl dqsse<br />
id.de wi|l u iN@cios proporlb! of w.lu.t d 6ltv acid Sbaqid6<br />
wtl .o imrd.iog rrorortio! ofb.s ctrb nq &idlgt@da ir r[. frt OxlLrb! offrt wil<br />
.Lo iFar. b ipeift sxvny Da.iy .nd .94i6c sDvitv m t€ dacnniEd !v @ of<br />
36
t5.l.2 t Ediv! l.d.!<br />
Th. r.n crre hdq of a ncdiun is rh. 6to ofde sr6d of liah .l a d.fmn€<br />
wavelds.h h v.c!o to 'li sp*d il the m.diun<br />
,1tultri@l lh/tnah@:-<br />
Th. lrbc fta .nd oi& h.v. ch..rdinic r€fncirc irdiB. hsE rhn<br />
detmiDtbn a v.hubL fo. id€'.ifidbn ud ! .n indq of runy. h B .ls ur.tut h foUow-<br />
dtg tn. progrse of hydros'dbn of m oil Ti. r.tu iiv. hd.r !c..g enh iicrsi,ts<br />
.nounl of lons-ch.h 4u6i.d tury &'d glyGidd a wll a win inc@iis mouirs of usrur.Ld<br />
sbldidd ll .&o icles with lh. oxidtion of ht<br />
Th. 3nrd.rd n ajod! for ..&rdiw ii.Lr (RD e A06 tup C Mahod 2 102,<br />
Bs 634 S.6ion l:2..d AOCS rdbd Cc ?-2J. tdds.d Ny orlE risnic h.E<br />
dadn d !h. '.A..ri6 ili! oftu trd oi8 rir Att r.tdo'fu [3 c!.I.<br />
tttj t'tSglx||rY<br />
P446,<br />
TIE vi.riy c.n h. d.fi.d . rr. 6tE i..o ir.d iisio 'Hr vigc<br />
mft. otrdr d@ to d.6m!s folE, nq r 6ir.F b tt-. or ltor.<br />
V.ry linl. ddr !.e fourd b fic lit.f.tu.. on 6c vEcoiity of iB n.l ort. Thit<br />
chara&rirlE rhould. hovws, h. ur.frl ro iopoldsl odE ptr!f,.1 16r]r. Ir sqel<br />
visny will dd*. *ith ino*ig .lrin lds ' .trd dqs. with i@ina !.$ru.!Fr<br />
of tlE @Eiiir6r itty .cils. Vis@sily nba ol. tuDlq of Ars ..d o'& u. siH bt<br />
R.grL .nd Cotuhi [3<br />
8]. The vi@sity of tu .d oih o h. dffiii.d .ithd by th.
Onqld vbodd d M.cMidh..l vio'd.r'<br />
!.il.a colruR<br />
T@ u.nn B;w ot6bu d.Eadi.t tt R.@l [3 61 ud N'ltlt ud<br />
S.dh& t3.71- P.ot bt th. @. wid.lt B.d d of 6bs E dogrc i ih' t'lihotrd<br />
"t<br />
Tbobca. Th. @61 voion of tb btt|@t |e . rid@dtic 3r!ro of obu€d 8ls<br />
616 ofsrybs d.d!. of 6loE: th.v .rc F4 rlo{ .nd tl&: Ed tdbw 6!6 b'<br />
'!d 'G<br />
e@t d iod oI dlt ro tO El, &d tle ios o| to'l0 Th. ui!.r.ddiiw. ic' 20<br />
ydb*.lid. hr. ..G d.Fh of @bu r !td6 lO + 9 + l. itttd @r' r[' 6'ld freb ttnt<br />
rlid... F{ ydb* rod bl'. ofcqtll sls a sr.t- Tha! i | .ko . *t of e'r''l 31116 whi6<br />
.E oqlil b t!. t.4L lbh Fn b o4d.tc tu h.tht d Th' oil d'9adia @ It<br />
F6of6bu. bsd b€ll h.vi's D.ti lo€t! of U4 nr t/'2 i'. I ia2ir5l/4hor6bi<br />
2.t @. J d! tO'4 20@c,|o@<br />
Th.6bE ofdF on uda r.r i dd.tti'.t! bv fleh i!8 n nD6 tLldrd<br />
'<br />
lisb $|@. A .4t i ont i.d b €! of .t'!@F.B FO<br />
|.oSd! wNc! @t b' q6r'd<br />
wtE 16!! i d.ch.cd Th. [ch t th sc lLreoC rt oil md 6bu 6lGB be ru of<br />
.!SLd niM, it. two obE 6.1& !n !i.w.d.id. tv !id. trmo$. l.L..oDC cv.pis<br />
Mddnsof r!.tso 6bu 61.1& i doE ty6.tublltilalt 6bu m@. aiig onlv O.<br />
cd ed Flow if Fsiblc<br />
Tbc 6u! add h. d..l6d for @4L a 5 R 50 Y i!<br />
c.tr G.a ti'r!6 &oo. .y, cuooDty[ siilE wi! &.d. ht& @qo@r b tt. En<br />
IUPAC GLd 2.lo, i d..ig!.d to !i€ e oli.civc qtu.d of on 6b6<br />
3.5.2 Cf,EMICAL PNOPERTIES<br />
" l/t b<br />
3.!.2.r SAAON|FTCATION VALUE (Sv)<br />
Wilq- Tb. nponlh.fto ur! i d.ft.d r t d]|tnd of Dousid hvderlt<br />
EquiEd |o spori' I srm of. ht<br />
38
AMbrial i-pttur<br />
Th. eoooift.in. v.lu a s ind oftlE E! tuhod.r *igt ofdE<br />
r.rslyqd6 @rcritos. nl If dF tutr E(L pr.an b ft dlEiL e of bw @hal'<br />
*irht Ghd-ch.in rib), mE slt€ib mtclL. siu t tqri.d to d|F& | sm of n<br />
lh.r rlt.ci& .rc of hisn mLotlr rdsh (lotg cnu &'&) S.roni6di.o v.i@ (Sv) b<br />
ths.for. inrdet proponbcl ro dE '|w noh.ub seh ofdE eb6id€s of. f..<br />
To ddmir tt!6 spoiifqrion rh., . sbM @cb orthc 6r i! red wnh .<br />
rosured volune ol aboholi. potasliw hydrorid. $luti6r trd s.ponifi.d by hsdrg The<br />
excss of polesstum hydroxid€ d b.cldht.d wrth sr.n.ii.d 0 5 N mid $lulion A bhnl<br />
d€tsnindion 6 on linun!@uly wfi lh. sDl. to d.tsnirc th6 coMlt rion oa the<br />
.l@holh pol!$id hydoxido $ln@i. FM th. Fidn of spL ad fie dftlon vdu6 on<br />
rh. bLnt rnd the ed0l6, th. rFnifiotion v.lu. Dy b. qkuh.d 13 9l lol<br />
3.5.'.2 TODINE VALUE<br />
The iodile valu. ii ddr.d a tl* nunb. qrigt|m of idire !tM6.d by one<br />
Aryt 'tj@J tnwduer<br />
1@<br />
doubl. boidd in a f.r Sine the uMtuBl.d iny ei.k @mnly ocd.6g B @hpor6t3 of<br />
.dibl. frts r. liqud !r rem lanDdtrG, th. iodim $1u.6 b. nh€d b th. @!irg poirn<br />
or hrdrE of r flt For dn'CL, rn MrDn CibL oib r. cdFii.d of ! fun prcponion<br />
of uBlur.d Arry &il siEn-. Thd n .b sD riLE dr. dtandy h.rd tus<br />
(pGdoni.'rly brsdi' d|!dl !tsb) e oi da3.a io dE le d.sc ii rh.<br />
body s oir ia 6n ilR d .t' 6$. &qrr of nl!|l.d glreil. To sm<br />
d.sre rtE. 3 . rAiili t tul & rFL. (ll. b qidn .ra-idi.. .rd id-.<br />
nuna.r of . tu. Tlt .F hilr G|||ad rlyo.n .r$i.i t tt &ib d[ 2 or ]
douu. boi.ls @ hig4t su$(ltibL to oxibriv. &rdbnrion :lh. oLt si.l gtdd.. win<br />
oft doobl. bonds e€ muoh L6s 3septrbl.: .nd lh. stuEt€d &id altqile re no1 tl .ll<br />
s@.ptibk to tnis type of sPoibge<br />
Trc of dE olda r.tho& rsilrbL for th. bdiE ddqnirrion @ dE w1i!<br />
Il I ll .nd HdG [3.12] naho& Th. ont ditr.@ d th6. d.nod! i rrF of bbscd'E<br />
.sdr !r.d BaG. bdnF il3.r 6 'Di aci@ c$gn to .dd qElrtrrivet to tll<br />
uMr.d lbt!s6,ICI or lDr ol!.itn.c u!.d Tiu rhhougl it it E tr|llICIorIBr<br />
dd to th€ doubL bond. b th. B.do4 tlE br.l h.loi@ ltld.d b atr..r.d B 'odne Th'<br />
W|l3 rdhod mrhtt kdie turc.]btd. !d th. H.M ndn d iodi@ b.on'd. a lh'<br />
h.brdllB rsgr. It Wt ohti[ oa ind ood&riL ttouLl b. nwhr tM'<br />
Edn rlu ih. ltx6 i.tdi, ditiuiiL $rtio! Co!.qtdt' rulr ot'oiEd 6v dE<br />
wu. n6hod se . t .rr .sci..*, Fni*hrt f.. o- ,rh hai b
lL t- ftry.dild i. tdor !rf!.t h.. qit.ftd o t! h.l v.iuot<br />
rff ol, ts da.ritu&r i of FiF i{db. *....[ 0q 6ts d.i !d t<br />
qdno of q.r+ v,tiA iv t &...i.l{b., v,tdr i 6..@6.. of .tlat|d of<br />
pon .i6 @D*ido rqrnld to qrt b. oh. ..iliy of I |tto ofit. or $ lt! pro.dr€! or<br />
t . ttry..aFrd.ILi-a.q|cU {r! i.ro otd.dbv Co& ddVu Ld. F.131
REFERENCES<br />
t3.U rdq[tbol Suqhrd OrlDn rib- Oih.
CHAPTER - 4<br />
THF',OR"ETICAL PRINCIPLES<br />
4.1 rrc NMR SpcctrGcopy<br />
4.1,1 Intmduction<br />
NMR is ! @- d!6!rutiv. t ol fo. {uli.tivo e s[ c for qulit ivc ub8i!<br />
[4.]-4.J]. 116 qusnrdve $D.c i. w[ boM bot! for polm ud lb' 'rC [4 Jl Prero! ind<br />
fs.iE NMR hrs wd.lyta u.d flr qudi.tiv..EhEii 3ne b'a [4 c-r.10].<br />
Pr.to! NMR ofv.ati.tL oil .t o4l* .d lLd.&r. . Sood qudn rivc<br />
Elj/ti i.or Dosihlc. Ho*dd rtu?tio t t 4d PMR n @ of ligib [aq hn r.@i<br />
olt drL io qutLtie. ildiEstin No qu!.trtivc @t/!n n$ h.6 &e.<br />
For quff.tivc etdi . qu.dty loow r d@t{l ahin siv6 bt Eq (a.l) !<br />
(4. t)<br />
s/ia! vs ud !r e @tl.4 n!$di.. bt t 4L dd r&a* 6D.ci6t Cb@bl<br />
.Lii, & tla.forc srrE n pdt F oilli'o d t'9E rlli* to 3m ondut T.f.4rtt&;<br />
lE or TMS lu ta u.d s . std.il for poro! t.d I'c 14 5l- 'nc cbdn l shin tus6 for<br />
'H rF o to t o ppb (i! $@ *6 'pio 20 ppo) Dd bt rrc lli! me! ! uE[t uFo 2to pto.
4.1.2 t'c NMR sp..tro.copy<br />
rrc NleN i r rpb L? lslqr wth . Eiul .butL@ of r.lo8 lnd r.ltiw<br />
r..lpdvny Dr wit! @ped ro pot6 b 1.7 r lor t4.51. tt b ttc@forc v6y h!.d to oh*d. uld<br />
my 3r.dn .r. llLa dd rv@sad ed I hir[ @n6 r.lid of *qL b r.qun.d.<br />
Wi! rh..dvd ofDrt d Ft NMR rrc srql.hrdre i!@l'. .tc to$itb<br />
i! . @A la! ti@. "C pat! rr. *![ l@hrcd .od e(a.r|.d &oB ac6 or[d md rt6. .rc mt<br />
@4Ln ud elssrd m oo. rid. Mi{ucruba6 ! thdcforc DosibL q!'Jy [4,4-4.t tl.']C<br />
tP.dn n @tt @rdcd ir | oalady pEtd .L.coqLd @d.. Ihc liB .E l[s.&E<br />
eltbk$ 6a Sii* rrc i . be.t@d.!€ nstq4. . bish otrc
slErc 6H is i!. lire si&h. tC lit. wi(tth !r. uuUv tumw . $a'foic thl'3 @Lrtlbn do6 ml<br />
phy tir oL n q@ii.tir ub'|i [4 5]<br />
,11.3.2 SD!-lrtda idudo<br />
Tbn i I pEcd tt stih ilc dittub€d !Eb'.v6t@ @E b 'qolibna b iF<br />
1. acti!8 wih ns sEo@dilg rrom .t 'bni4' Thi! it ! fit$ ordd rcLhrbtr pr@8 crrEc<br />
rsiz.d br . tiE olr !r T. bom r .pn|di4 rLntjoo d bqil'niul rcb{iib ri6' ri<br />
nrb tlD IOl lo lO'.. b ou Es 6i tte. d'fl8!.ic @led!. of oi!' ini dv n4!<br />
ton l-los.Thc robuiim whicb w. Nte L givo tt<br />
tl<br />
wxd. Tr ! ot6d.d t.hribn d@ eil TIDD n dbolcdbok cb{rion . Trsr it rabsrio!<br />
dE to .piFb$tb. iddctid rd Tr' n t.Lrtb. d!. io o&d m'tdls5. YlftL @v bc<br />
cldn l.nin xioaoty (CSA), stt @|4li's GC).id qungoh' ac ln ou oE lo*r<br />
.ns. ofT. b olt !c@$ry dd oohrdss rre nol inpon.nr. T1 b ! big 6otor in tht ris'<br />
lra for d!t/.i' ty rrc .p.dbrPY<br />
4,1.4 Nuclerr Ov.rhtutcr Efrect<br />
(r.3)<br />
For t@td d@'{liE; iritub. of preid .Pb i !|6cIrv D& b rnis irdj.tih<br />
protor spiB qc!&ge tb.n @drv *itt rr C qtbo bd't'd lo ih@ or rq o@ Tna<br />
sn6 ri. i, .dt&ed ofrrc De.t i4its dE lo !Eh.r Ovdb'6a andcd'd (NOE)<br />
r+11 =r--L ' r<br />
(4{)<br />
w[4 ], ! iitony of 3isat b 6qL..t pmto. d@l{Ld N& tnd I,i i6 fiG itr'4iv of
.iarl i,-{.ad.dD&<br />
t,P =<br />
sna! r = F-t ditb|tc|@<br />
,r. = {3 ' r.r.r<br />
e'nd.1H..d tc D Dsnaoorn dio of rH ltd 'tc E9div.lv<br />
(a.r)<br />
(4.6)<br />
c.qL. F.- aotra dd Pa I'c ld. h o' '6n' of Dc<br />
!.r. I. d.b b I@ td !. r..ltdn . Fra t-!'t' ria $q<br />
Edl To |sd 'o "c r*. r locrr ad.ii, b$ |. tc &ooqr'a i<br />
..a L|b r-b l a..rl l-..1fr lD--ai.at- dtA Ib<br />
x(E i .t-.a Br lt - b. . d I llt, l... d,i. i-a la. t 'cd<br />
s* rrl* ..*rit-Ll, ra-..rt<br />
a.2 CrnrqttF<br />
(2.1 h.*<br />
ft.d.rrqrb..f.a d.tdc || D. tillr '..d i Liy'r !_<br />
biid lbrerr, rb 's - Drr.ly b i || td tr n sbr i?e .&s t<br />
.DL n. ri.&&lvd io be llqNf I of- fria I dirtv rf...' tr..t n'<br />
tb. @'r?'.&'r lo tt.o..i of .Nei- r.aF o@'. CLodlt Ci. doe o b.<br />
.Lli.d.@rdi!g to t)4- of Dlib.d ..t'@ty FB .d !r. .bn ofry Fnnull<br />
r.cliqr dtd 'fa ||.rr!!of rq] lt*g dtl,.d
d2"2 G$ Lhuid Chronriogr.phy<br />
Crs cnF6to8Dthy (CC) i on. of th. Dd wid.ly aqbycd Nbric.l reb-<br />
.48 lo&y, lt n 6.d h .oddic ud rd.rch Lbontori.6 B w.l! .s in iddNtry. C
whq. vc = @t@ t d wt@ rnd<br />
i - t,[b ti. of th. D.tib lL.<br />
rae @ne imld n t rbd wla Vo td iold" wn 4'€ d! b<br />
iti...or dd dacao. i.d srt*<br />
Th. .diu.i.tl t rdio. whm vr .d tiF |r 6. r soh. i] d_'6oa<br />
Vr =Vr-Vo dd tr =rr-lo<br />
(r.r0)<br />
L CC. vr t!5t b @r@td tu ll. o4d.lirv of rt' a.@a !5& d& ro<br />
rh. ffire dint6ail.b.s t ot|e PBle g..lir tcc J @!r t' u'd liitg ln'<br />
6 ft.ltir Eh. V, 6.. ai@ tdFd. !d ia.rF{|c .|:<br />
K=Cs/CM<br />
(4.r l)<br />
lta ob.a.d !.aatbd cbt.ldbtic fot . ohl. dlpad' |4o! it'<br />
'litrihtiD<br />
hal@ .!. dliL.!d tr.ri.rty le.d dd rt. Errirc.Ev lostt -'f TID rcL'ia<br />
.mu! of thc olln. b 6.h pb.c ! !t\d bv<br />
(4. | 2)<br />
*t@ K = Fnitbn o.ftcar<br />
C. - c4detr it tl. driir.Y pl.e<br />
c = d..d.i. i|}.l.a-<br />
I!.loul cratito Eb t( ! tivi' 'L i lD' v! wit li' oh d'l<br />
f. vs i d..-ClYt trit- idr ti.db<br />
vr - vr + xv.<br />
,o<br />
(a-13)<br />
(r.r.)
Thc blu@ Vr My b. ohlt dbydr.flow . oJ rh. mbile phrle<br />
V =F t<br />
{na. to i, !h. rai|r ris otrrt @biL pt $.<br />
TID rcLrivc rcdih o of t!. tN oqo@u A Dd B i!<br />
rc.pdiw Fnii[ cbndainir, K^ od \<br />
{,2.4 Efncicoc} of Coh|lo<br />
& tli. spei6c .cdbd wt@. Fq .<br />
Tt. op.ciy ntu K i. | @rG Dr.cric.l<br />
I - to ., --.o, uo*<br />
(4.tt<br />
(4_r6)<br />
14.r7t<br />
thc eficituy of . otm d..ohc r!. ote .r *Li,I' Dt*!&. u.vct rt oush .<br />
oh@ [4.12]. This !olr. d.po& r4u 6.n p.rtirio! 6.6ci'n$ Ed th. Gulr.lr prcflo of<br />
l[. otr. b!.h .pDrorb.ts ro r nord Osi! .lilt$dnn pftne or owc rbc par 'ui6.<br />
r.FB6d 6. K v.h..fdd erq@6t ud rpptoximr. to inc .vdgc nt. ofrlv€l of<br />
rlE &lr.. @brna Pat einn L b r Bue of @tm c6i.iolcr.!d b (&c.d nr th.<br />
luDhs of tbr€n l .4t!:liDri@ .r.Es 6.1 hrE oo@d witli! tt€ @tm Tlc @nm .tr-<br />
n@ .4riv.kd to ad n.! or rl. inarcri.rl pLie H i, livd hy:<br />
(4.18)
Lrc L ie rn. oltm kr8!b. tw i<br />
tirc. Th. .fe{.iv. nMb.r ofplt4<br />
(4.r9)<br />
N, i! . mrc .cMt. tlBe of lh. 3eprnriu powd of ! 6lt@. Aho pbte t !h H i. dF<br />
dElEcof ollm c&iacr 3irc i daabis ttE nnts of .q!itLim n('6 .r!d b<br />
nd.p6dd ot@h@ L6srL Th. !h.+!d ofr pot Gd.d. rl. pht. h.{rhi<br />
4.2.5 Rcrolulion<br />
N,=L/H=16(rrr/Ur<br />
Tnn i. d.&.d c t!. e{d of s@nrih of rumiv. sl6. b.!xb or D-t!.<br />
Fd G.@iu Fb th. ..p.nrba i eiva !y rh. nrb of rtrG t-t &xiD. b rlc h.o.d!-i of<br />
.L. lab i., rt. E! D-l ,itt&<br />
R5 = (rE-rk,/lh(!^-rvJ (4.20)<br />
A{i€r ears *ti.b.e !uri6..odf @&.4 o t iqod ry iF.a&<br />
ia t!. r.eutiln ofpak or by cdeina $. wi&t ofrb€ F.b ia by rc
REFERENCES<br />
l1.rl G. D. a.da, Eigh Raofutid /vr,a/R. bd E t, A€.|.oi) ItB6, N. Y-,l98O-<br />
14.21 G C. L.q, R, L, Licbrq tndB. L. N.b\Cd.b@- 13 Nrclar MaEn ti. R.@ne<br />
.qFdta@pr, 2od AL , WiLy, N. Y,. 1930.<br />
14.31 M. L Mrni! G. ,. M.nn .!d raF,lcqu D.bucrl<br />
Ptuctiql NMR Spcctwopy,H.y.ko. tm.bl! t980,<br />
14-41 F. r- Bovly L J.lblibd L A-min\ NEL* M.gn n A.M<br />
,&dru@p/,2nd E.l. Aoibbn prd." N. y, tt8&<br />
14.51 t,W-.I NMRdtd cl6&r,,lrd Ed., CtryM.od t||[, t nrb., t99t.<br />
14.61 C. Y- riopiiq J, AE Cn@ 8e, jt, 664 (t 96 t).<br />
[a.4 t r Aoha.rd W D. CooL. Art a,nd, i6, r?t!. t32t (1964).<br />
14.31 n F. L llo, R R' K.6ld, ADr cll@ /t5, l3O2 (1974).<br />
l49l B.Itriu!.od M. Mq$da Ois Mrgtr R.@a,7_ J75 (197j).<br />
ll.tol S. L MerL G' D. Kt@.!d N. A. Ktriri M.atr R.&@.Caa, 23.20? 09s51,<br />
lit,l l l A.T-J.ardA",, P M.ni! Bb.!@.t, SO,679.ndAEbd.77.915 (t952)<br />
I4.r4 A. Brihsi..rxl F.r. Sottr<br />
Ch@atoAtuphic M.thodt, Ch,p@ .nd tLI, Na yort , p, t4-21 ( | 985)<br />
5t
5.1 M.terids<br />
CHAPTER.5<br />
EXPERIMENTAL DETAILS<br />
Th.6lbwi's v.8...bt oit .dt oihe& t v. D.a 6.d rnelebod rhi r€€!.t<br />
(.) v.a...u. ofl.<br />
(t s'dovd on (6|ll@it)<br />
(D s.y.t€! oi (6!IE.it)<br />
(iO Como! (@@nt)<br />
(iv) Cd.uS6dotl {Retri - T.doj.a)<br />
(v) tbfrE ol GloriT8)<br />
(tO Sr&doffi Oil (Hol)<br />
(vn) sol.baloil (&!elc)<br />
(vin) SoFtaloit (wi[ji6)<br />
(n) tiMldoil (EFeo)<br />
(x) R pq..d Oil (K-5r6)<br />
S.!ok (0 to (iii) wd. oh!i!.d tln r'd @tr. otHyddra4 Sid! hLir&<br />
rd h.! h6 u.d s sua si6o|n fry rornEr or Dufiqiln Wtit tu $qk aon (n)<br />
ro (r), oit .& e* ot ri'Gd nd thc SinL Asrtulu. R€,c! Cdq T.!doiD! p.t-<br />
ilt r, oils wd. qre.ted 6on rh* s64 Bhs rrd.rd ndtro& ourli!.d in ndr serior.<br />
Tn. v.rink of v.aa.bL oih$'h rE gi6 h.to*:<br />
52
(D) v...!.01. Oilr...l!<br />
(i) c.ttoD..d G6n n- Tm
5.4 NMR Spcdrometcr<br />
Tn spe.*rooca 6Gd n rn6. .rt .in ,i. b ,EOL m- 9oQ Fr NMR spetod_<br />
ad. For trrotr rnd rrc r*o lirk otpsbd .r. BdL-<br />
(i) c/H dul obc.flrld pret .<br />
(ii) MuhrcL.r or l@tL Preto<br />
For (,H ud T@bL Prch., tlE lroton ot d.tiotr i.qMcy a 89.J5 MlIz, brn<br />
tur lrc 6c ob.d.rbn n qEaq 6r C/Fl i! 22.J Mtlz @d for t@bL l. b 22.49 MAz.<br />
Tte ftld B i zl l T6L b. rH t $s.y of89.55 Mttz ItlG.!..trotutd 66<br />
Digal Qod{@ Da.dior (I,QD) oalod 6r &r.diE th. rbEr Lisln Pa Cdrel Sysro<br />
(LI'cs), !d AuTo STACIqNG &nw.r. reordd on c.sFn. Maeldis Trt. (cMI) it<br />
Md d u old T.nr bctu.d TI 9aoD @q!td 3)aLn. For tublc protq ! coqdct<br />
@r.olLd (frE TI 93OA Co4uq SFtd) W.vddlRodhd tcqEcy irdl€ia Mo.t l<br />
561G25 ! u..I Thi .Fihcia E!.dta t qwi. 600 0 .o l0o MH, o.edd for<br />
rwbl. .ob€. En.ml '?D bcl i, ued n! .[ o6.<br />
For 'rC |lauc@is ! hc.@@L.r wi&h.!d dis€ d€@uplilg '3C-lrH) is<br />
q.d Ot d d@|plig @d. a 6cd n @rdiB t!. pal ir.@iy nr mda|pld md6-<br />
Vun6 tit of .b@'pliB m.r{.r.l tt i Ec.E dou b Fis (5.r). la. ooputs hls r<br />
|!d!ry of 24L A l2 hn AD/DA orvald i u.d C.s.n. M4naic lipc (CMT) md .<br />
Dridd it u.d E iautourP'n d.viL hh6 .F s@l.d &oo . riqle PG l0 DUls. s6erubr<br />
Thir 8oa.!or .to 8.|a16 pufc .quc br inditb! .!d shnrin ric<br />
'lqutEa. Tn |Fvini 0r4ut of rdb Fequcy (RF) F€ .4Ed ir 15 w.!r3.<br />
Mrgla i! a.&dro6g!(. powwd noo a AC Al'bilhd sd@ of220v.nd 4.3lrVA
6<br />
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it
5.5 Measuremetrt of Spitr-Lattice Relaxatioo Time T.<br />
To @.d. !pcln.. &b.rion dm,ltrEiotr l@vqy(lR) 'nalDd hf b.ol<br />
Md I! rbis !€!hod. (l3Gt-90- T) pul& leqrd@ x 3nown in Fis(5.2) b u.4 H€r. 1n<br />
rn€ tid b..r6 Dlla Dd T ir qiig tirc br | l@.d s.q@ 10 h. .r!lii- D5T, for<br />
.o@t Tr Fsd.r.d' ! ir rh. nut6 6r pur. !.qwe 1o bG r€p6r.d .!d r!.uld b.<br />
sar6 tlrn @. wh6 !p.r.@ b @iy. TL @@rpi. drn.tizrtid Mz (t) b adiEci.r<br />
6Bts E{ (5.1) .na @{l of d&uli's pu}c 15.21.<br />
Mo-Mz()<br />
(5.t)<br />
-ia! l,lo i cquilit iu 'F!.t;-ri- .nq . btrs rir r- h.sr.abn ofdc Eq (5. | ) siv€<br />
Mo - Mz (t) = A dp (-r /Tr)<br />
For IR Fq@@ tb. 3q (5.1) sivd Mz (1) =. - Mo.t r = 0 ed A h@c Gaul<br />
10 2Mo. TtE 6rc Eq (5-2) h.6G<br />
Mo ' Mz(r) = 2Moe,a(-r'Tr)<br />
Rauu8i8 @d rltiie b ofhotl .Ae Eq (5.]) b€@E6<br />
2Mo<br />
(5 2)<br />
(J.3)<br />
(5.)<br />
Aph'r of hR @6 t sn6 r Ntr.tir liF sirb 3brc = -llrr. Fis (5.3).to* i6e 6(hin<br />
of Mz (t) .l urbs iotdrl r .nrl Fig (r.4) shows @rsqoe orMz (t) .g.inlt de r non<br />
e8.tiv. ro F.inG M2 (t) {lq. ln JEoL Fx-90Q FI NM& .n AUI(},STAC(IiIC
Fig(s.4)<br />
Fl (s.2)<br />
r-3-F- rrtit r',2F R _<br />
+l'n## -.* * s6sroc. ra IR d6fod or<br />
"':+, ,.+,<br />
i "'v't'* i<br />
,+"-::-*,+".<br />
.+, "",.+'<br />
,+,.-:::*,+'<br />
Fig (5.3) Condition ofMz (t) sr vadous tonc inr.ft"ls r in<br />
Emcrgcnce_of Mz (t) signat againn r|mc I from nlgative Vz rr, \atucs<br />
!0 posrl'vc Mz() vrlues.<br />
IR
5.6 Oil Quelity<br />
To cie.l rt! quhy of oih folbeiB dsd idlio.t hG bd €tEd oul<br />
F.tty Acill Congo.itnn (F.AC)<br />
s.podfd&! v.l'& (sU<br />
5.C1 Frtty Acid Conpos ion<br />
F*ry&n @qolitin of lcscrhL oib Lt t o ddmid.d by -C NMR rd @<br />
5.6.1.I NMR A!.lyi.<br />
PFrs NMR i tur $ c.tul for quliiliw .!d qddi.tire dh/rb !t lh. *o<br />
riu ii 6qLx low fttd NMR $.ctrotut6. a r.pq6nliv. pretotr NMR tp.crru of<br />
slrb.e oil b sbom ir fig (5.5). "C NMR .p.ctF ofves.ttblc o& !rc *.lt re|led md r[.<br />
!.f. .F d!p. Tld.bc i'iadJiqrbn .!d tu€en'd tr. b.a drid o'n winour sy di6<br />
c{ry. For Fr idldii6lb4 totr rrc Nt\|R stdu tr. h.6 @rd€d nt rL. @Dp!r. (E<br />
@l4Ld Dde. a r.prc@t tire 6qLi. trolon &@wkn 3pers or $riba! (@mi.l)<br />
on n shoM in lis (5.6). Vdou 'rC p*k! e id@tificd a@ordine to ShooLry 15.41 rtrd<br />
rn.i .nin re siva b d. T.Ue Ll .id @di6..tir for th. Fql€ s.! in th€ Fsr<br />
For qunittne @rj/sn. @[ poniE of sp.s@ non 0.o 37 Ppb i5..quit d<br />
I ti, lddl tt"e of dpdd.d sp€dlu i! omnlis(J7).<br />
5a
g::i$;: !:ji !! !.<br />
'E:l*i::::g?!:::#<br />
E;s!!i4iqiq4liq<br />
i€a:r:istii:::'<br />
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5<br />
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ti<br />
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6 tl<br />
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it !<br />
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I
Nor oil snpLs Itlvins ligh rmb nv of trFl'o'ld *nh bml et<br />
ljzcd. siie d!u!;iM 'x!'dl locl1ecl'nil!' Priortoq'u hdi!' 'nllvsie<br />
or$e oils r'bx'<br />
.- r* ", t* ** *b ntv' t'a ddmined lnvdtbr R@!"v nrdhod $'s<br />
h@ 6..1ro d.d. r.Lntin tic Tr' To ga n 'ccMr' i!t'sr'l of rtt pats rbe spain<br />
bE ta @t&d h |h. Ctr'd D@qlirg (r'I E) drle Gttcd d@uDlilg ' Ecd b onro<br />
" rUV -,eU .p.s- *m" cidultn@slv Glibilrne ftc itrdasc in tissl doe bv th'<br />
N*rq. O"obruo eoitno@t (NOE) Thb i! posibl€ b'dNt th' de@wlhg of spid lh't<br />
0@6 6aInl' i@l!s'@B rh' Nu'k'r Ovqh!@r EntD@6or (NoE) howdd de<br />
oJ - * * .bw< FLriir of @Li ah6 irrtc d'6lDld it 6'll tic wb@<br />
lhn e bGiA 6lLaG4 rnt NOE vil br]d 'p IfdE ddl4ld b ina ru*d of' wliL ih'<br />
&ta rrc h.iog @l|.cr.il. l!' {"tM b@@ @4rereV 6tPlG4 th'rc b i$r6ci'r dc<br />
ro bs dc NoE. Dv uilg rbis tFrnod of '!.dLV 16ins on 'od of (cntiq) tht d6ol9Lr<br />
b pmpd s.ql@a *. htve otr'in'd ih' 6p'cl6 rh" onbin dxims iridsrt rld hulti-<br />
16.r.2 GC An.ltit<br />
Fot da.didrioo of t!' frltv loil 64osnb! b GC !h' oih s se oNdbd i4ro<br />
i[. rdi 6td Tha the ne'6tt atan ofvcg't'nb oitr rnd ih' tb't'rd nelhvt ctde of$'<br />
tuty r.i& *@ it ..€d b c' bt qudi'tiv' dlsn<br />
t.6LtI P.4...ti.n ol ^Attl at6<br />
M.thvl .ei€s wdc prcp'tud Oob oits bv h'sFqirlvz'd insndnvlltion l5 5l<br />
5.0 s of oih *rs r.Os'rl vilh s[dbt ot"ined bv rqdirs o 2 8<br />
' of nr 40 dl of !o_<br />
'odi@<br />
nydros oat dL Aftcr 20 ni!r!6 r|i' toldiod ss @Ld wil loo nl ofd'd[cd mt'r'<br />
'nd lh. dd$vl ..16 E oddcd lvit vin |o0 nl6f hde Th' ndnvl 'dG $[nbo<br />
w.s dii.d ovd rnnvdtou edin '!|nt' d @pmt'd ro d'@s h r d6o of lroad'<br />
6'
t61.22 G.t cttontqr.*b @.ltt s<br />
rruns EbEi 5[owi'8 6dtiE wft d ].rn br tb. -qlc<br />
Fbw nlc of Nitogpr er!<br />
2Dx2@(i..1) Fc&dwi!20%<br />
&odoibAV/ lGr0O n d<br />
l5o-5-250t<br />
Dc!.... r.4€.r@<br />
bjc..dr6F.@<br />
:<br />
:<br />
:<br />
I9o 'C<br />
20ot<br />
frG tolni.i(h D...'d (rD)<br />
: 50 DriE (a(xl 6YdnL)<br />
laioc(d@he : 0.2 pl<br />
: mp!i8(40Elbid)<br />
DBGS d<br />
&d tunnh<br />
t Ldlt&lx<br />
'.cl.t<br />
in &.bi|E di5 nr t€ r.d for rt ild€tir of rL. nity .ciL i, rt<br />
@q.rio ofi!. .nrin dG of EeLt o.rb,l dd wil rh.t ottbc c.!d.!d3 d rle<br />
'.@<br />
@t@ Ed.r l[. !@ @dtbr of 0os nL Ed t qc.te.<br />
5.6. 1,2,1 Qtar'tra1t'. .db&<br />
Qunn tive @!di b. b6 mi.d oa b ln. id.8rtor, hdld h fic itrld<br />
E d, lti.h nt€ lh. .q oltt D6b. GC &o@sa of ll. Dlrtt Gi4 of la v€eaiL<br />
oil *ft t ta Chndoln! 016. raltd o.tyt .ddr otwb! nty &i.L w<br />
.!o r.to to bD{ tb. r..din ti6 ofwin! 6tty .cit<br />
5,6.2 Colou lnder<br />
Ttc 6bu ofth. vcsabL oil tN6 b..n E$u€d b t[. Lvihond Tilori€..r<br />
[5.6] rh. dtrul 6t'! of l[. ie|@t !g . ttidlodic .1/nd of obed As ft@<br />
63
of wyi|g dsrlE of 6bd:lf,.y.c tqL y![ow ftd blE: r.d.nd tclthv 616 .r€ inc<br />
ddt o0.1 rd$to70uirs.'rdt{rnor0.I io40. Tt.di3.E.ddaiv.. ic. 20}tl<br />
l,e slid. ls r@ d€ort of@lou r. .lik3 l0 + 9 + l. nfibs Dr. th. ftld tDb thr€<br />
s|idd, rc{ }dbw !!d bhre of€qul vrlud i. !r.r. Ti@ i. . .$o ! s.t of tr.u.nl .lid6 whrch<br />
.rc ovsUid n d. &qk lietu ptrh ro @n'pdete for tr€lds. Th. oil depadina otr its<br />
Drth of obu. b r.d n e& h.virS D.O lagtbl of t4 a l/2 it. I !. 2 io. J l/4 it or 6 t<br />
t5@5@lO@20@ot,t0@<br />
Ttc olo! of rt oil udd i.r br bo .kdnEd t'y il@iItila rlaD don .<br />
d.!d..d lirhr our. A s4L s od.b.d n cd of I itr h Frt lrlth. Thc [!ln Ftt g06<br />
lbough tl. on .!d @bu ftq by IqD ofegLd bnrcE rhc leo @bw fi.ldi .e y&ved<br />
!i.L ty rib &ougi I telesope ryrpi.4, M.rdiog of in tM @L,q fi.ltt wu dotr€ by l[€<br />
@truLtios lh. @lou 6Ld, uinr o!ry l!. rcd. colou tulex of vc8.bbl. oib brve b@ de<br />
tdbcd b tL fo&vns 6nuL<br />
\rb@ R. i for rd .nd Y n f.. t low @bu.<br />
5,6.3 F r. F.tty Acid<br />
o.t<br />
r@ n&y &in GFA) t . ba d*qfln d b th. slld.rd IUPAC n O.d [5.4-<br />
5s of th. r.4L h.5 h.d *qelcd iro . 30od Erld.)q ei|( 2ool of 6cbLi.d spid<br />
.nd &w dot of tta.b[d.Lnr idioror eh|tin ,a ..Llcd T!. d.tt *s shtcd ro<br />
dislv. rbc {ql @qld.t- rha lf,. r4lc a tini.d $i} tnltLrd O. I N NIOH l4to<br />
r[. dd poid. Tle FFA lE lH qbuLl.rl by r!. blbeira foEuh :<br />
Dl or rc'd scd x Nod|ny of tcid t 23.2
5,6.4 DeterniElion of SrDonificrtion Value<br />
Ir the veas.bl. oib rponiicrrion v!lu. (SV) hs bai d€l@iocd br dr. 1Lr<br />
&'d IUPAC rErhod 15.31 5s ofenpb e.s nl@ ido rn. 10061Erkdncy.r ILsl.nd 50Dl<br />
oflLoholic poi,sim hrdrxlL elutio! r.s rr.6f€red. An t @dc46 Mr at&ded ro<br />
rlE bp of ft31 .d reou.d 61 30 Dnuq. Tt tbt wls tba mk4 lbl otptdbhirLin<br />
i.dio.lor sohnim wls ..ld.d. ed q6 of pot $i@ iqdroride prclcDr ei6 tilitd win the<br />
tud.rd 0-5 N .cid sldin la. bht dnmilrin trs .ho h.@ rib!&.@at va! th.<br />
sql.- T1E bLnt damiutio! 6rt iN rh. sm vo[!E of rlonotc porr$iu hydroxtla<br />
$htin @ed n r[. !E wry.nd rdir.! for in r@ Irgr! of tim.s r[€ s@ks.<br />
FroD in. w.ieht of $qL md th. tir.rbo v!t6 on tbe blrt !trd lb. eqb, fi€ sponi6or-<br />
rion v.b. hrs bd olculied by rtc b[owitrs 6tmL :<br />
5.6.5 lodio. Vrlu.<br />
Bbt ritu $.ql Tidr@ x No@|ny of Acd r 16,<br />
S.qL *oilbt nt cnN<br />
(5.?)<br />
For rtc dsr.minriD of iodiF rtu. (rv), wij, n .!.d l5.el n8 &q u€t! 0.25<br />
sD of rr ..li!b hs b.a tufd.d inro |!c 3oOEt sh$ sroppa€d bdirc dfL Tn. oit us<br />
dielvcd n l5ml ofctbrf.@ Anq ..tdi!s rlc 2jDt ofvb i6dn snrioa the ,t ,[ v.s<br />
doppd.d ,nd dlt d ganly to Eix rL sol'nio4 .d pt ccd i! l[€ drrt 61 30 Dinut.s. Ar rhe<br />
ad of t[i tic. rhe sropF u3 bosrt .nd {sbd hb rh. 0.sL *i[ 2oot of rh. t5%<br />
porssid bdid. etllih folbwd hy 100 nt ot wrcr. Iodi& .olurho w.. rtu.rd *i!<br />
3tu&rd o.IN sdi@ rbbrulfit ehdb! dn rhc r€[.* iodid. @bu dtu@s,.d. Fd<br />
&!pl of lnrc,h in.lirror eldion yls r.tdld .nd !g!h tirnred b tne disppar.@e of<br />
bhE @bu. Tm 6lrt d*mi!.rio! wd. m 3iEd,n@6t *nh ihe {EeLs Thc sn<br />
qMndy of 6( rqs€nrs *ft u.d $ nr 6. srpLs &d votw mlr€d wjrh rhe ee volulft.pptnls.<br />
Thc Ndge v.hG oh.ircd for in. bL.l damiM.ioE is ucd b rsdh<br />
ib. b.los@ @nodhti.n of lh. i.db. &t'rior todh. v.lE hls bd olcubled by the
BbrTidb!. SrqLTih.bn r Nodli$ oa<br />
SrqL e.illl in sts<br />
(r.8)<br />
t6.5.1 PEDr.dd ol Wft Solod@<br />
13! of.nbli'rlrl idb. sntb. Ms dielv.d b I i6 ofahcil rcan .cA citl<br />
ta!. T6.sll.idws@Ld.!d. 20nlp.niBof itmtliE i.dwi!!t nd.td0,lN $dim<br />
rhi.ulfrL eltb( r00olofitdn snnb! w$.ntd.r.d bo r h-la. WUhd 5!d di€d<br />
cbbrb. gI wc pl$.d tuo tlc dh ponbo ofettin unil Oe oriliMl li bn 6slrc w.3<br />
doubk4 TL m[ poniD of rn. oi4rn l iodn€ E[nir v!31tu&n.d do thc .nbiul.d<br />
$hrbr rho wh eludor w.s slor.d ; . ghs. doDpaed .Ebd honlc.<br />
5.7 Oilsccd Qodity<br />
ro det in quliy of oih6.b blrrwit! dcmi|riE bs td €nin ou<br />
Th. preedrc for lh. d.d.miEtior of tn @i!rr .!d oil @lrdrs lrc dc<br />
sFib.d ir d...c.ir (5,D of lti d.a.-. To da@iE rt. F@ig! dt 6.!d proi.i! rh.<br />
folbwhg peed@ wqc lihptql<br />
5.7.1 IorclgD Mrtt r<br />
Thc Dclhoil $tih w.s Ned 10 .b6l rtc Foreig' Mttd b rh. r@mr.l€d pro-<br />
c.d!! of ldd!.liul Sn!d.!d Orgniztin (ISO) IJ.l0l. I5g of dh sryL ec w.igh€d<br />
All illpuilie. i, the ss.ls ws! s.Fr.rc.L Ispuiair* *d. Eie!.d.nd For.ig mttq h,s<br />
ba qlcunt.d hy thc fo[oviog foduh
5.7.2 PROTEIN<br />
Wds[r ot.+dii.s r l0o<br />
(5. ro)<br />
fte (hl&hrs bdho.l fo $. dermbrliotr oftoul oitroga w$ perfornDd otr r<br />
Kirt rF.ntE by rt. n&lh.d p.oqlu. [J.l l]. Tobl c.uL proGb a dami.d ty<br />
nulbtbr t[. psdr drcsd by rh€ hcror 6.25.<br />
Rdid8 of oib€€{b (ED w$ wcig!.d dd rn6 truftrr€d ilro . di3-tbr ftsL<br />
AD|!)d{u sdim lulbr. (158) rnd ruh'ic .oid (2J.0 ml) wd. lEo !&.d to tt db€$iod<br />
t iL Ib. bttuc {s hotcd gdrv unil frdng !' €3.d. Tt. btuqa w* th6 botLd<br />
h.illr lO th. digdbn @ 6qlc€ .nd dr aoluin b€@ 6buL.! o. F ly e- Tin<br />
uult equn6 two 1o th@ hous. The flrsL Ms thd @ol.d to roob tdpfrtdc rnd d6-<br />
dLd a(. (200.0 ! ) 98 r.!Ld ro Oc mif@ th. $ttb. Hs m& llolgt.trliE by<br />
todlg a5% sodim hrd.oxi& !ohi@ (90,0 6l). A pinch ofribc dlal w.. !dd.d 10 prry@r<br />
bqi'a rd r€lE notnng Tb. t 5L *$ Mtlcd virh rt @n.t46 ru.tr tlrt tt tb of<br />
tL €orbd .n@4t b€bv tlc rufre of . *rdtcd boG rcil $tnir b rue t@is. Tb.<br />
€.rdr wdc thdoo! y En.d by sbrlinB. kilbtbi *!s ontnru€d @til r[ orthc rmni!<br />
t3 p.$.d ova ito rn. hori .on T[. fir.t 6.din ( I J0.0 bl) of rh. dinilL@ sadlt 6F<br />
bioed rU th€ !!@d, io lhc fom of rmoni@ b.htc. ftc i@ir plr tha titrded di-<br />
r.db wt! ![.!d.!d .cil uig dt rcd $ u iidn tor. A ttd de.@irtiD {s .ho @<br />
win rh. !|@ .@rd of pg.dr, P.otcin h|! h.6 .Lrmiocd by th€ folowios tuEuL:<br />
(r.r)
RtrFERENCES<br />
I5.rl ltJl,,. &.ndzrd M.bod J@ k. AMbsit of Oik Faa and Denwtiw.<br />
Sid Eiiin Pas.ld Pra P. e ( 1973).<br />
[5.2] M, L, Mrnio, G t, Mtnn.!d JaF J.cq@ D.bwh. Pd.r,e/ tMR<br />
Sp.ctacqpr, n rdql' t rd.q 1980,<br />
I5,!t AUTosTAcKNGPRoGRAnt JEOL LTD, Tohp. J.F!. hblit tir No I'Y022<br />
I5.al t. N- Slolqy'C-tJ rvMX a Ogndbttv Aefuet M.ttd Fq D.tdntng th.<br />
cMqtisa 4 Fat aa alf NifAri@ Nd. NMx.-7t!, aDrn O tJ) v.litr<br />
Asoitd P.lo. Alo. CA. U. S. A.<br />
I5,rl F. F. lddy rld R A. Brr&t4 t, A4 Ctd Se. 37. ,L? ( 1960)<br />
tt,61 Aa Oif Cnm Soe, orLral6d T.nbtiv Methdt, C.l3B-45 11946,<br />
O.n InI'PAC,Sb,thdt M.tho.k FeTh. Aobtir {Oitt. FdE ad Dcnwtiw-<br />
Silth Ed., Pdsldtr Pr*, Odor4 | 979, p,52,<br />
15.81 'IrPAC.Sht<br />
b,tl M.thdt Fu fh. rultais 4Ah,<br />
Sid! Ed., Pqgrmn Pt€r oldor{ | 979, p.56.<br />
FaE d,.l D.riNttB,<br />
ls.9l IUPAC Stat bd M.ttdt Fn lrt ,rndwb {Ak, Faaod Dctivaaw,<br />
Sint Ed., Paa.'m P6., Nor(l979, p. 66,<br />
IJ.lo] L Bbu.!d S, Ftut L ,, An CIR Soc.- 60, 54 (193E)<br />
I5.frl tdl@tioDr sr&d'(fs orsniatbr,A"indtJe.tns tt4f - D.t tuttuti@ olnttmse"<br />
dtd @!al4rd dcrtlL pdein d,ar, ISO G6.v., Snrdrrd No. 59a3, 1979.
6.1 Oilseed Amlvsis<br />
CHAPTER - 6<br />
RESULTS<br />
Oib.o& *crc @bed for @ietde forcis! @nd, oit coslab. fr.e f.l1y rcid<br />
rd pbr.-r (|El). Ilc Ec!.& otddmi!.riD of rte 4onriis w.,c odli!.d b Sd;n<br />
J,? ofct pts 5- T[e rauXs ob!.ii.d ubg $de nanods aE sild i! TrbL 6,l,<br />
Frcn T.tt 6.1,iilck r rlltl for.bb o$q(FM) @dtu or@rron$qb od<br />
lise& lre bish. The nrg* of br.is! und for ortE s.eds li€ betke! 1.4 ,nd 2.2 %.<br />
Moirtu. @dar oforton s.ed i O. high6r. ortq tie[ qr.Sory .r sbtbwd (ttc l) Dd<br />
linseed (EL;90). Moilre oal@r ofrbe rcst ofr6. oils€erl, lie. i! rhe rlse of+5 %. The<br />
htn oil 616r. i6 olx.rvc.t b *c of nt6€ed (K-5s6). li@.ir (Eb!9o) &d su!fi,wd<br />
(Hol) Tt niAcofoilco atsof olha sceds Ucs betw@ t7 lnd 2tolo. Fr€e f.t1y rcid<br />
(FFA) @at€ds ofo$@ 3..d is l[. hishqr (0.9 %), rn. odlds Ev.. nra! or0.4 ro 0.6 %.<br />
Pdci. (M.lD @rrcors of $yrb... (siab) aod sortba! (w n@) .re erly equt hd<br />
tbhs( wbsc fi. orhr r&dr siw . rrs. of2? b 3s %.<br />
6.2 Vcgetrble Oit AralFis<br />
Vcsd.tb oiL ftcd nod oi sc.ds or €tl4rci y oh.ix{t yde.Et&d<br />
for Colou tld€x (CI), Fr* F try Acil (ITA), roilhq V!lu. (rv) .!d s,po!i66rb! V!l,E<br />
(S9. rlc.ld.ib ofrha. dlods sqe givo i. S..rion J.6 ofct r.d 5. Tb. r6!tr! ob_<br />
tlined qins thos hdnod! .rc siva i! T!bl. 6.2.<br />
lr i! ct r 6c T.bt 6-2 ri.. .n 6bE ibrLr ofnp€e{ ono6e.d.nd tiF<br />
s*d rr. hi8n (3 | ro 34. Tn. obu ird€x o{od.r oib lic h.tw6 | 5 and 27. Fr.c Fany Acid<br />
(ITA) @Ird b rlte bw.r ; q$ of 6E aon€rciit slrbqq $r.ban (S.Gek) .nd
TABLE6.I<br />
A!.ly!i! of Som. Connotr Oibc€ds<br />
SAMPLE FOREIoN MOISTUSE OIL FI.EE FATTY PROTETN<br />
MATTER<br />
Sdb€ 1.6 5.t 2l-t O.5 37 4<br />
(Thori'?3)<br />
C.nod..d 1.5 1-6 17.5 09 432<br />
So0owd 2.1 6.1 402 O 5 27.4<br />
(HGD<br />
Soy.bqn l.A 4-2 193 04 445<br />
soyftan 2,2 4.3 18,4 0.6 44 4<br />
Lie.d 4.2 6.1 1r.1 O.t 33,t<br />
(Ehi9o)<br />
t.4 5.2 12.5 0.6 3J-a<br />
(K-516)<br />
@dfuil lulbw6 oI (0.02), wbiL t ir 6. ljshdl h 8€ of 6n G€( ti6*d rd<br />
np6..d (0.06). h othd *e n L$ . v.lu. of 0.0r. lo.liG ulu. (ry) ntrE6 non t47 ro I j2<br />
n @ of litr €{ elnowd &d 6mil s}.har. T[. Diddlc tule i! toD l3l ro t38.<br />
whiL lo*cl nnse it 103 to lO4. S.Foain..na v.tE (SD tug€ tDn I9I (ru0owd) ro<br />
195 (@.rll@irlsr.ba! on).lt odq {lu6 6n8c Aod l?6 (np6.c
2.<br />
t.<br />
5<br />
3.<br />
(Ihori-78)<br />
(HGr)<br />
(Ebn90)<br />
(K-586)<br />
AnrlFi! of Somc Vcg..ablc Oil!<br />
25<br />
21<br />
t8<br />
I5<br />
3l<br />
0,02<br />
0.02<br />
0.02<br />
0.06<br />
Iodn. S.D6if6rid<br />
t49<br />
(r35-t50)<br />
t03<br />
( 99-t 19)<br />
128<br />
(l r0.t13)<br />
t38<br />
(r2(lt43)<br />
t31<br />
t52<br />
tll<br />
{r03.t23)<br />
(155-205)<br />
(94-l20l<br />
) 'c froE co.t r AliedadB sdDd.r{r 161,.<br />
7l<br />
192<br />
(r36-t98)<br />
t89<br />
(t39-t98)<br />
t83<br />
( r3&r9!)<br />
t9l<br />
I39<br />
(l3a-t9J)<br />
t93<br />
t95<br />
t8a<br />
(r3?-t9J)<br />
(r3&t96)<br />
{r63-r8l
6.2,1 FstS Acid Compsition<br />
Th. rjor p.rli of ln6it b @nc@ed with dt' dci.diM'in otf'tty aoid oqc<br />
snioi. n is th€eforc eto in deLil Th. ddetbiErioo of fdtv lcil oortosniotr iD v'adtble<br />
oih b l!. F6d worl i. b.sed ot Dc Ni/t +*lrempv $d Cns Chmdtognplio !Dt-<br />
ds of@lhyl6t6s of 6tty tcide pr6d nr dt oil The !6dts otioided 6on 1b6' @lhodr<br />
e siv6 i. rhe folo*irs 8.dia<br />
For i[. idad8orntr ofvari,s r]c lats $..f, of vcgabk oib b.vc bd<br />
eerd.d i. @dpl4.V ptoloD do@l4led mde Thi! eNc r6es b ..h!Den d of rrc psl<br />
'<br />
indni.s dle ro NoE n.ror rt 16.21. Sld spdn t. sctul for qulitttiv. dlysis .Dd id4<br />
i6€1bn of p€rks duc to vrriou sonps and &ny t.id ospordrs. Th€ a$i8@l of pals<br />
n b..d o! thc tudis of SclooLry [6-31. Coryld. on .Fe $. r@rdcd ioD 0 to 20o<br />
ppn qnrS ! spccltll widU of 5000 IIz .t I i€q@cy of 22 50 Mllz Son. of rtes€ sp€cE<br />
br difiad oih re shou in Fig (6.1)ro Fls (6.5). Th* spe.rn blvc b.a @.ded i.<br />
M. *|te sins €xtml ddndiu bct. No d€d.nr.d or orLd mh€nr n.. b.a u.d. there.<br />
f.rc Frr ntd6* .6 ahlkl Tb* s?..rn .rc th.rcftJrc Di etul for qurinivc<br />
sdbab. Ir ir s.6 non tb*€ sp6fi th,1 rhe r.8ion of 40 - 200 ppb is s!D. nr !U of th6e<br />
+.dn. nE sctul dd i.fotflrPc egin lis 6€rw@ 0 10 37 ppa .!d i i6 the rcgnn vbic[<br />
is u.d in qu@drive .u\,sb. Quddiv. expr cd speclra hlve b.d reord€d b eit€d dc<br />
@lpkd m.L s rlrr NOE Acto. rl sbodd t s'pptscd [6.3], To |@rd r.t€d
E<br />
E<br />
4<br />
-€:t€:en;:n:;Eit:E:<br />
! !:d ii j j :ij ji!i i ii* i j<br />
i:i::3;::3;*t33t;;:<br />
: ; ;..:,:i.:.: i;;.j.j.; ji; ; i<br />
3=E'!:*?:t:::586;;<br />
u T{{;;Sii;;;E<br />
"t<br />
e
t<br />
2<br />
E<br />
!<br />
it<br />
;:;;:i!!it:<br />
;ililiiirii<br />
.r
n<br />
:;:€::::i*;;!;i gs g<br />
= i': .? i .;.: 1.: ": 1 .:<br />
!nininqin:-c<br />
;:cgi3g3*:::<br />
E
!<br />
,t<br />
a<br />
.D<br />
&<br />
:;;i:gE::i!a<br />
=; i:!;;::; i i<br />
aa;!;a3!a::e<br />
EisEi;!Ei!{:<br />
!;;:5;::i:!.<br />
ii!qiiiii4E<br />
:EFiEE!*::'<br />
iiiiqtn:nqi<br />
::g:a3::::-<br />
'€<br />
:<br />
,<br />
,2.
E<br />
a<br />
:<br />
.x<br />
t<br />
.n<br />
3
t<br />
1a<br />
I d<br />
.I 9l<br />
.E<br />
,t -5<br />
E'<br />
Ed<br />
E:<br />
TP<br />
dE
t<br />
:<br />
79<br />
'c<br />
F<br />
n I<br />
a<br />
I<br />
.E!<br />
Y><br />
!E<br />
.E.!<br />
Ir<br />
!t ,E<br />
i.<br />
'9
80<br />
!<br />
I !!l<br />
n<br />
a<br />
a<br />
,P
8l<br />
e,<br />
.t<br />
E<br />
tf
_]<br />
1<br />
I<br />
32<br />
o+<br />
36<br />
a<br />
i:
h b s.m Aon Tlbk 6,3 tbrl th. hiS!.st T, h qs€ ofslmowd &d @tton-<br />
3c.d oil is 0.34 s. A E r€d decol4Ld sp€cM ofth@ oih tr*ds onv 3.4 E ro lcceuUi. on.<br />
sp€t@ &r Dirsn- H{rlat rcbr.itn ri@ i! 4,08 . foi Cr? D6L nr Bs of liE.d, Fony<br />
@ !!coo& (.al s) & a[.r.&E ...(|.t| tu @ .e@!hin ot liEed 3p.6u *bi.t i,<br />
' od t[. t.rn of nry rcid @q..nb! .!d Fl .*t"-d. bav€ 0-3? DpE,<br />
th. oib n v. bea cl$si6.d hto r$! 8reip3.<br />
(n)<br />
oils wbic! comlid di@ (wo &ubl€ bonds). tutuae (one &!blc bood)<br />
oib $tnh 6drb ni(G (r!le doublc bondr) n ..iirbn ro di[.,<br />
Go'a (t o[.i! strowa rd @tto. s.d oik. Th. .sislMt of wbu<br />
DaL .r. e'v6 i'r tlbk 6.it. TrDlc 6.4 rL. lirt lirid @@oMt8 n rn fotu of stbtc4<br />
b&@ r'd di@ fom. R.r.6adn. tD.
TABLE 6.3<br />
Spin kttic€ Relararion T, in rcconds for rclectcd 13C rtoo. oftom.<br />
v.g.trblc oils<br />
Crno .ld .robd i! ct.i!<br />
c, c, c..,, €,, cr. c,. cn<br />
6(ppd 249 2!.? tl3 tLI 316 3r'0 n6<br />
S.6ow6 0.16 0,29 0,12 013 O-41 o34<br />
Gt ri78)<br />
Cottons.d 0.18 0,31 O.lt 062 038 0.34<br />
S'Etbw6 O.2o 0.43 0.38 r'02 0,95 109 3,41<br />
Surovg o.la 0.45 0,41 0.7a I OI l.l2 321<br />
(HOl)<br />
SoFta! O.l7 O.47 0,39 0.79 r4 1.21 316<br />
Soy.bao 0.29 0.52 O !5 0 82 r.54 1.31 1.31<br />
SoFtd! 0.29 0,59 O.3l 1.54 t13 l.l0 t<br />
CoE o31 oA5 0,33 2-11 L5a otl 4.20<br />
Liu.d 0.6A \23 O4l r'93 \r7 r.tz /t.01<br />
(Eti90)<br />
&F..d 0.41 o5l oal 0.85 |23 264<br />
(K-r16)<br />
T!€ cheBiol sbin 6 ppD b witl rcry..t to TMS wd !s d i cml liud.rd
.bb Ga<br />
AdF..ot of O.Dh.l 8llito .f GrdD 0) O&<br />
(8.fr€ldoono...do- )<br />
ADCDI'.LPID<br />
@r|roxElT<br />
c, c! Cr, C,.o sAIlrs-IlS<br />
3a.O 25,0 2a l'' l A !F<br />
c. c". c, cD ctr I|[(,NOENa<br />
3:f-O n3 - 25.0 tLA l4.l 6 !|l[<br />
c, c,.,. c,, c, cu ctr DIENE<br />
3a,O /1.3 8.7 25tr Za l4.l 6 Fo<br />
ltr d4t tilclnb Pdlii..oid (Cl6ro) od Stqb roid(ClE:o)<br />
rb@i.tlbolao|.il (crtt l)!d Etuio.oiil dry b r.Er..d(C?2: l)<br />
ll.dididr|..rolio.dl Gr&2)<br />
lLt ir.bdd..lrbb.dil (Cltl)
c,<br />
ABC<br />
3a.o<br />
c2<br />
c.<br />
IAELE 6.!<br />
ASSICNMf,NT OFCf,EMICIl- SEIFTS OT CROIJP(ii) OILS<br />
c<br />
32.O<br />
32.0<br />
( SEfowd, Sor.bda cota LiB..drdR.Psad Oib)<br />
31.6 u.3<br />
C,,<br />
25.7<br />
E F<br />
25.O<br />
c-<br />
u.0<br />
c,<br />
25.0<br />
25.1 25.O<br />
c,,<br />
22.4<br />
cn<br />
u.a<br />
1r,a<br />
c<br />
LITID<br />
qoxtoNErar<br />
EATUTATED<br />
SEI'B<br />
DTETE<br />
c,, TTIENE<br />
tt ..r@t6 iEr& rthia ei (cl6:o) .'d &qneil(clt:0)<br />
'ii"<br />
It --* .ti@ iDbd.. Lokn.oid (cl8:2)<br />
Tt tiEE n b.L. rtbi. ..il (Cl8:3)<br />
atr,a." Oti"."ia (cls:l) od ENi"cil' o'lv b r'[d'd (C22:l)
Qddi.tiv€ u|l6n of hoth srorp of oils bs b€ dd. tr t[c follovbs alob-<br />
62.1.1.t C.taLtion 4 Gdp O Olk<br />
Foi qudttive @tdi . rd! ponho of rp*1l@ Wro 37 ppb b r.quircd T[is<br />
so@l tr?. of .xt!trdcd 3p4t@ 6oD 0 to 37 ppb wr sbom b Fig (6,1l). Ditrercol A.e<br />
ibn ofnty &i&.rc oLoh&d uiu iL &lbwqs bmuLs [6.3,6.6].<br />
Sb@ ach n$yeid @ rid. c, dbon dm md i. rcbniD tim Tr io<br />
ttirbqidd i GLriwV shorr. Itr .q of C j r.l@@.r 6 = 25,0 ppo i! tulLrcd ore<br />
olbo! tu i[ rlbbrtb c&!i@. A! ri.n. i nor pra@t io thjs 6q th. urq@ rcsmc !t 6<br />
= 25,7 ppo r@B@ts olt CI br did chrid. By divdila llc pc* r6oM4 rl 6 = 25.7<br />
pts ty C- couM pat d6 Civ6 r!. t cd.n br di6e o[.D i! Oc tul*uk.<br />
C| (6'25.tFa) Flt.F<br />
cr (6 - 25.0 !'r) pat.F<br />
(6. t)<br />
RsD,@ liF, i = 2t.3 ppd r.pH.ds tle ra of C!.[ &r @e@ !d<br />
C!,ra b. da.q Dieiliog 6 = 27.3 r.iodE@ by two w sive tbc 16 for .ithd of th. tM<br />
qlboE ot @@4 .!d dte Tta!&r., rhdr.dirs this lE 6oh th. .a ofoe psl fot<br />
M artoo of C .,r, * v ga.d br @re otriE Divilia t[ir.6 6n tr@-.<br />
.d|n by rn lg of Cj w. w 8a A.cai.D br t|.ee d.ir Tf,e dlcDl'rinc .ft<br />
Ard 6r Do@G ohrin =<br />
Cr,I - C.,ra (6 =27.3ppD)pdl rq<br />
AF tur @ Erto/mm@ cbn - c!.!t (5 = 27.3) pal 'E - c! G = 25.7) p€L &a<br />
a7<br />
2<br />
(6.2)
I Clrbor / Mo@* cllit<br />
%Mo@m. = -- -------------- x 100<br />
q Pol !'6<br />
ft. Fcd -hte Dy orib ota.i.d ty de.* n@ l0O (siE re h.v.<br />
.ba.ly qlo&tqlllc @Dc rtl diaE) o.6y t qblbt il ty otd.di'8 in E of<br />
r!. c,6 G 32.0) aFoird win l|.d@ ed &tutq rh. g!!it8 @ ril i.prodt l[.<br />
rq ofda 6rbon p.r !.tnt.d clia DiviliB try the Ca a@. 8iv.u l[. tldin of s|lut6.<br />
c..(dod+dut )F1.6- | €'bor,bd.c c!.i<br />
100 - (M@4. + Dkoc)<br />
-x<br />
Forrpil€lollriE.n .boE .$miB o b. etto u [6.1]:.<br />
= D (C, 6 25.0pDD)<br />
N@b.r of ohtuio o!.i6 = B (c!.I C!.,a 627.3 ppE)<br />
Nr&ofobi.cbn = C (Ctt 6 2J.7mn)<br />
Fr.
t9<br />
,<br />
I<br />
a<br />
6<br />
F<br />
o<br />
IE<br />
.3tr<br />
IF<br />
Eg<br />
ta<br />
I
90<br />
ii.tSir.'4;<br />
![<br />
{<br />
:<br />
.I t<br />
T<br />
!<br />
E<br />
I<br />
63.<br />
8T<br />
si<br />
}H<br />
F
62LL2 c.tst tiN 4 G@p (4 oi,.<br />
TrEo. rwe .6ndanrn qol|!@ .r 6 - 20 6 prd for C,, .toD, Tibh 6 5<br />
rn! 16 otFf i dddlf byG qtb!.1@c, i! c@d b -hnr.d ud ldtu.t d<br />
6.iL L.. tL .d ofc, .ro b. B<br />
Cr? (6 = 20.6 ppd) pal 16<br />
Cr(6=25.oFo)Fr!u<br />
lm<br />
(6.n)<br />
(O oi*<br />
DiF gi6 d..cqi*b r4!ee .t 6 =3!.6!0m6rCGFt*t rL..E<br />
Cr6(6- 31.6 pFd)paL ra<br />
Cr(6 = 25.o<br />
''o ) Fr .B<br />
(6.12)<br />
M@. 6qo.tbddt dadd.dt@Frc.ddl.ryt\tu. 6.J.<br />
Tt lor C in Ft (6.13).f.* @dhbd.n of l@oo., dcEodni.o..I-a$. @ of<br />
o.5 t^q(qr - cr,.)- ^€ (cJl<br />
0.5 [ A16 (c..I, cir. cJl<br />
9l<br />
r 100 (6.ll)<br />
(6.14)
t2<br />
3l<br />
,!<br />
Ir<br />
5z<br />
q6<br />
Tfl<br />
II<br />
t"t<br />
:e<br />
TI<br />
!l<br />
t?<br />
lt<br />
:;g<br />
It<br />
!x<br />
6g<br />
'f
(iv) s.tur6<br />
96slnr$- = lo0 -(ri6E + DirE + Itoda.) (6.t5)<br />
Ttc .how .[ otlhiE d b. tl,'t'@ird u t bw tu quicl tufd@.<br />
TotrlDnDdofcliN - E (cr 0 2d9p!6)<br />
N6lqof.trF.5!a - B (C..6 3t.7Dto)<br />
NC of liaE .t i'. - C (C,, 6 2r,6 r)<br />
Nr&of@ediq - C (C,r.6 27.3prD)<br />
(Cut 6 20.6 !Dd)<br />
(q 6 316PPr)<br />
o<br />
Fndiolofiria€ (R) = ---- x 100<br />
B<br />
F-Grb.of.lic@ (Q) - -- x Io0<br />
E<br />
c-G-28<br />
FndiEofD'D@ (P) =<br />
d (P) -<br />
-<br />
-<br />
E<br />
y2C<br />
E<br />
(6.r6)<br />
(6.t?)<br />
r 100 (6.18)<br />
r l0o (6.19)<br />
Fndiolof.rnlg (s)- loo-(P + Q + R) (6.20)<br />
Rtr*mdv. ItC sn d d.ooryt d .p€dn of go+ (iD h.vc ba stoM i! Fg<br />
(6.14) to Fi8 (6.20). ft... .r..tr. b!v. ta cddd b t! ruse ofG3? !'pd lor.girl vr!<br />
G ofri Flt bre ba t.ra.rd 6c t E ha u.d nr l|l. qlcrbrid of tacds.<br />
@4o.ib! oflrmtcd. Ddd., diF ud eie oit@.r@.<br />
ca
I<br />
I<br />
I<br />
:<br />
rt<br />
I<br />
'& t<br />
E<br />
aa<br />
!oE<br />
t
i<br />
'I<br />
rt<br />
I<br />
T<br />
.€<br />
- t6 6<br />
t cE<br />
I<br />
9
l<br />
96<br />
1<br />
1<br />
I<br />
-l<br />
E<br />
,! 1<br />
t9<br />
t!<br />
- rs<br />
I I<br />
t<br />
.t<br />
c<br />
Io €'<br />
!
vl<br />
,[;<br />
I<br />
I<br />
5<br />
I<br />
!<br />
I ,<br />
, I<br />
I
98<br />
!<br />
I<br />
l5<br />
.E 6<br />
]E<br />
IF<br />
P $'r.<br />
I<br />
lt<br />
'E II<br />
e<br />
.t
lL<br />
lD<br />
a<br />
!! E<br />
'I<br />
,2 .Ig.<br />
5<br />
t<br />
6<br />
t
i$irl{<br />
l,l j<br />
l<br />
I<br />
t9<br />
!<br />
3<br />
o<br />
ria<br />
i<br />
Ig<br />
g
Th. 16r|13 of p@tige @nD@nion of toth Aolps b!v. bee. rc@rdld in T.blc<br />
6.6. lt i ot6.d.d noD T.U. 6.6 tt r opq..d oil t e low.d .d'Dl of srur6. High<br />
.mui of nMt. ir ohld.d h on@.Gd .nd sr.b.n oih. nighdi .mu! of tu6a. h<br />
okd.d n s. of np*!d b! l[€ uruc of m@@ ir nor hom O$d high wlu.s of<br />
tua rc ot aad h s6tuG.!d li'*.d oib. t wv.t6ot@lmc.rc'anqe<br />
of s$toa sunowd ud @no4ed oib, Higt di@ @opo@! i 3@ io osc of $fiL,wd<br />
!d iurowa oil* I! nitriy of o6 e.vds. {lE of J0% dih. is.6. ft. bwer<br />
dLE @qonaI i ot qv.d b lirad.!d rFed oih. LiB6d.ho rhou bbld rio.<br />
@qoodt' (30%). fte !.n bpa ra|n. n cd in o.. of nF4..d (t6%). The orhe oib<br />
[wa t4 Fst s. of EiE tlr 2 to lO<br />
nF !v.r.a. Euts oftle 6E .p..tn of*5 on 6qL by uitrs ib. .toE cqu-<br />
tia .r. .loM h T.hL 6.6.<br />
tot
T.tlG 6.6<br />
Percentrge Frtty Acid Conposilion of Some Vcgetabl€ Oib by<br />
t3c Nln spectroscopy<br />
OILSAMPLE SATUIIATES MONOENE DIENE TRIEIIE<br />
(Ttori?3)<br />
12.6 + 0.6 t4,3 a0.a 1t,l+ 0.4<br />
2. Condsd 28.3 4 0-J 20,1!0.4 51.!+0.4<br />
(so-r)<br />
(Eri9o)<br />
(K-J36)<br />
16.8 40.4 32.2_t !O7. 43,3*0.' 2.2 +O.2<br />
lca*0,6 t9.7 40,5 62.2tO-4 t,? *0.2<br />
25,7 +0.4 t9,4+0.6 47.5*0,3 7.4+0_3<br />
20,6 + 0.5 2!.t *0.4 49.4*0.6 7,9!0.4<br />
18.I j 0.6 20.3 +o.7 51,640_3 9.9403<br />
rr.7+ 0.J 26,9 +0.7 4a.7 ! 0.4 8,?*0.4<br />
f&4 +0.3 392!n1 r2-5 +0.2 29.9t0.2<br />
8j 4 0.r 62.0+0.5 l3.j + 0.4 t6.2+ 0.2<br />
Th.eturdircnd. P.hiric.cid (Cl6jo).id Si6n.cid(Cts:o)<br />
T[.ma iFtlks Olcia.cn (C!8:t).!d Erei. rci! oot i. R ]€..d {c22: t )<br />
Ttcdic hoird* r@Lic.cA (ClB:2)<br />
nFrrircirclds ra.ldic icid (Cl8:3t<br />
tot
For GC. th€ lesa.bL oil ynrpLs wse @N.n.d nno rhen 'esp*rilc nElhyl a$<br />
16 16,61. Ile oalod of pct nriotr w.s outbed i! Seri,n J.6.l.2lof C1nDrd 5 Tt.<br />
ned.rd De.hyl on6 of rlE frny rci& ind @rlryt 6t6 of dc v.s.r.bt oil smples ws.<br />
id.ld 1o G C in rhc suc 6hlm &d Dd6 rh. !io&r @s.tirioB. The €,rhbn ot cC<br />
vq. ol'liEl n Serir 5.6.1.2.2of ChtFd 5. Tt.8$ c!reoro8nD of !ru(h(l ddryl<br />
€nds oflt. f.!!y.cidr is stoM nr Fig(6.21). Tnc rcldtion tin. ofdF *rndrrd trEthyl.$<br />
te of mr oltllh 6try.ci4 dich iic fotbd ii rU m$ .[ of rte oi! in lpp@irbtc<br />
amut!, @s foudin6. o.g.of 6 s(achyt€r.Fof p.bnicdcids) b 2O.J s (@tlyt d.<br />
t* of lioleric rcid). Tl€ lilty .oiG wbich !e co@nly foud in .hon rt v€scLbt oib<br />
.r.!.btnacil { ct6:0), Gi.cil cl3:o),(obia.!id(cl3:t). hoLicAcid (crsj2}lnd<br />
liMLnic.cid (CI3r3).Tle r.tarb. ti@ of6e wrbu 6tty rcids lic sbou in Tabt.6?.<br />
R9r6al|riv€ olb@rogrn ofv$iou oatyl ers ofso@ v€sebL oib !,e sbou in<br />
Fig (6.22) b Fig (6.31).<br />
T.bL 6.3 ti* pc!€fuse nfiy .cit 6bpo.nio, or efibwa .nd onon sed oiL<br />
&b6.d ty @. Il i 3€ noa Trh& 6.8 .h.r edo*d onbs v.ry low.@ur of od.ejc_<br />
d€..eio, dod€Mob ..d bFnic .cid itec w@ nol !e@ io NMR Majo, amul of srtu_<br />
6rc is i ttc Ld ofp.hnic .cn (Ct5:O) r.l s6ic.cid (Crs:o). Th€ tont.tud oferu-<br />
nt. s 13.49 %. 1!. maoac pd€n&s. b thc tom of oLio.oid (Cl s:t) ! I 2,{t o/o whilc<br />
di@ h lhe fom of kdohio .cid (C l3:2) is 73.02 7c lD qs€ of @non se€
pl<br />
II<br />
il:<br />
LI :<br />
-'t t: :<br />
-1 :<br />
*t!;<br />
tii:<br />
,:'1" i.<br />
I l'is: i<br />
i I t':<br />
iri ;<br />
t :<br />
L{t =<br />
It-<br />
ill;r::-<br />
i I l- - .<br />
I i- ! .<br />
1"t... :. -<br />
i r_ -<br />
Ln - I<br />
L pr:<br />
o<br />
I r<br />
T.bl. 6?<br />
P.tk tu{r, fi.ighr of P..li! Dd Conc.ltrtio! olErch P.!k in F.ttt<br />
EJr6 (F ME) sr.ndrd s.EC. .i C.l.ul.(.d by GC CoDp!!.i<br />
CALCULATION REPORT ..<br />
PXNO<br />
I<br />
!<br />
;<br />
TIIIE<br />
0.7t2<br />
.0:96i<br />
l. 413<br />
AREA<br />
| 216087<br />
i07997<br />
944761<br />
.l 1.71<br />
2.)83<br />
19888<br />
t3325p22<br />
8<br />
2.936<br />
3.6<br />
4.669<br />
3381I<br />
t9t]8t0<br />
79;89<br />
9<br />
l0<br />
tl<br />
l!<br />
ll<br />
)a<br />
1?<br />
l8<br />
6, 0t6<br />
7. 909<br />
9.2t!<br />
t0. i77<br />
I1.996<br />
15.008<br />
17.86;<br />
20.376<br />
23.841<br />
5817264<br />
76tra7<br />
r8136<br />
43620r4<br />
83{9602<br />
t42t6ltr<br />
1062414<br />
31r792<br />
fi2205<br />
4\295<br />
I9<br />
!0<br />
!l<br />
8450<br />
r3r803?<br />
?61t<br />
23.<br />
7693<br />
r0288<br />
:l'l<br />
146715<br />
t9?496<br />
l8t?t<br />
782i62<br />
31.0t4<br />
';i.392<br />
39.812<br />
40.81I<br />
45.tt4<br />
48.04{<br />
t0.898<br />
tJ. 18<br />
TOTAL<br />
5l134.r08<br />
t05<br />
HE IGHT<br />
287337<br />
1t3089<br />
157358<br />
3t27<br />
1159599<br />
3i7a<br />
426it3<br />
3€08.<br />
268165'<br />
30920<br />
i?170<br />
218269<br />
le9ot3<br />
28859<br />
18054.<br />
3756<br />
,lr49<br />
54?<br />
t12<br />
I t622<br />
I fJ6<br />
171<br />
fa5<br />
l:30<br />
.34<br />
4..37<br />
3004203 100<br />
, co;\c<br />
2, )742<br />
t, 3846<br />
1.8175<br />
0.0389<br />
26, 059<br />
0, 0661<br />
11.61t6<br />
I L.r51?<br />
' t. 493 r<br />
0,l137<br />
t6.t )2<br />
16,3288<br />
2.07ii<br />
,0.6.189<br />
0, ! l9{<br />
0,0808<br />
0,0165<br />
2,5776<br />
0.00;l<br />
0,01;<br />
0.0201<br />
o,247<br />
0.ta52<br />
t. t308<br />
--c5<br />
--c E<br />
--cr 0<br />
--ct6<br />
-- cl8<br />
--c18<br />
--cr8<br />
--c20<br />
--cl8<br />
:0<br />
:1<br />
t2<br />
:0<br />
:3<br />
--c22t0<br />
--C24:0
:t AI<br />
IA<br />
5!<br />
i!<br />
t- EC<br />
E!<br />
ol<br />
^t<br />
8E<br />
f<br />
1...::=-_<br />
,2'<br />
I<br />
E<br />
fi<br />
t.!<br />
3I<br />
!o<br />
(,!<br />
^a
- g-.<br />
a- :!<br />
ct<br />
u3<br />
F3<br />
F;<br />
I<br />
I<br />
f<br />
I<br />
i<br />
I<br />
i'<br />
I<br />
Lr<br />
:r<br />
a!<br />
nt<br />
E<br />
$a<br />
;<br />
x<br />
I I<br />
5 6<br />
1<br />
I I<br />
T<br />
L<br />
;<br />
T<br />
t0a<br />
6<br />
Lt<br />
6<br />
E<br />
t I
TAII 6.'<br />
P.rc.ot gr Frtty Acid CooD..ldetr of grmo{€r' .nd Cottooteed<br />
(!b It GC<br />
c6<br />
ca<br />
clo<br />
ct2<br />
ct4<br />
cr6<br />
crlJ<br />
Or-|.ta)<br />
oat<br />
(L06<br />
O'1,<br />
q35<br />
qa6<br />
zzt<br />
13.t9<br />
Cll:l l2-al<br />
clt2 fi.@,<br />
oJl<br />
o.8<br />
oz,<br />
0.91t<br />
u.g<br />
zd,<br />
30.75<br />
l!.9<br />
19.4
TlbL 6.9 givcs pdc@llge @npolition offrxy rci& @trtlhhs C6 !o C22 c.rh.n<br />
!ro@ d ldtower orL Tte @!tor! of $ru.icd fi 1ty rcds noD C6 10 Cl4 0nd C20 to C22<br />
i.low. P.hitn roid (Cl6:0) dd itqi. rci (Cl8:0).re h poc..t aa ola.l2 rnd 4.94 h<br />
@@Ecil v.ri.ty aDd 9.30 ud 5-99 % b HOI uri.iy i6pediv.t. Tbe lmbt ofm@a.<br />
b 6. bd ofoLio.cid (Cl8:0) b hiSi (30.6J %) nouErc v.ndy.rdb*htlGl v.-<br />
riry (17.t9 %). Tbe di6e Fc.d.s. ir rs.h hid i! @mrcil sriry rd bw i. HGI v.-<br />
rhr. ft. lD'rt of E@ n Oc bE of ld.oi..cnl (Cl&3) n tlEs -E<br />
r.Dl. 6.9<br />
Icrcenfige Fatty Acid Coo polilion of Sunllower Oib by CC<br />
c6<br />
c-3<br />
cr0<br />
cl2<br />
cl4<br />
c16<br />
Cla:0<br />
C20:0<br />
C2t:O<br />
Cla:l<br />
Cl8:2<br />
Cla:3<br />
STJNTI,OWEI<br />
0.37<br />
0,36<br />
3.12<br />
0.88<br />
t5,21<br />
30.65<br />
48.?0<br />
It0<br />
SUNFT-oWER<br />
(I|O-1)<br />
0.23<br />
0.13<br />
5.99<br />
0.73<br />
0,13<br />
t8.29<br />
60.62<br />
t.1a<br />
b rh. no.h
T.t{.6.10 gic.6ob of tb. rtre. utilrix of !or6b6! oih. CoBFcit oit<br />
h.r.lishvhigh @ff.dr.rior of(c8:0) ud (Cr6:0).cib.rt quriry orc6 to Ct4 ed<br />
C2O i.i& !r. bw h in v!ridi,* qo.!r (Cl3ro) ii clfudll sr{b€!!. Co@qchl oil hls<br />
high pdoel.g. of stut6- P.rcldrs. of 4@@ is @r€ or le$ sG in .[ uri.ri.s. S.@<br />
dc b witl t!. di@ lloea6 tii.o. lEt€t ic it Lls h @ of @@rcirl uil &eb s+<br />
..y (6 ro 7 *) dd i i tigb n €e wilid v.riry (9_6 %}<br />
3.<br />
T.U.6.10<br />
P.rcertigc Fatty Acld CoDPolition of Soyab€rn Oll. by GC<br />
c6<br />
ct<br />
cl0<br />
ct2<br />
cl4<br />
cl6<br />
Cl8:O<br />
C2O:0<br />
ClErl<br />
Cl3r2<br />
Cl8:3<br />
SOYADEAN $O]A'EAN SOYADIAN<br />
:"'<br />
3.18<br />
0.32<br />
15.01<br />
1.31<br />
0.33<br />
26.@ 21.52<br />
t9.8t<br />
|ll<br />
21,01<br />
50,31<br />
0,2,<br />
o,l l<br />
0.29<br />
13.23<br />
2,12<br />
0.tJ<br />
t1.71<br />
18,95
.bL 6.1I lir $. GC.ob.b of@n|. lis..d &d nF..d oih. Ar uql rh.<br />
r@rd of c6 ro cl4 ud c20 b c2a ! bw.rc.4. (cl0:0).m@r in q& ofnp6ed oil<br />
(4-JI 9l). ft.npced.106el6 .hprtnlblcil(C|6:0).trdthe.nbdof lr.ric..id i!<br />
.h. be b q* of dDes{L Sligt'aly tiah p.rcal|ge rrc .bo otadld for (C20:0) Dd<br />
(C22:o) b o!. of r.p6*al oil IlE ovsrl srdr. pdcfug€ b bw i! np6.d .. oq.re.l<br />
to @n &d li6@d vhere r@6t oJ {tE.r* ii mr. or Lss sG€. Tlt rmui of nono@e is<br />
ldytial b a. of 6p6*
Trblc 6.t2 to 6.rJ br @q.nriv. c!|. otoir.d by "C NMR ud GC.<br />
T.t& 6.12 lit! lhc Fu!! d otroea &d @fton $.d oiL. Nl|R siv6.lirhly low pftmt-<br />
.Bq of lrtMt€. lrd rlirht nigh t@ougd i! q.e of @mtr dd di@. Tt r.NLs lre<br />
howdd @qrnbL with i'! ei4di@tll m$ of boll tuthoib<br />
TtU' 612<br />
P.rc.ot g. F{ty Acid Conpo.ldor of S.mo*.r .nd Cotto&"d Olb bv<br />
Gcend rrc lnm<br />
c6c8<br />
0.85<br />
clo 0.06<br />
ct2 0.49<br />
cl4 0.35<br />
cl6 9,36<br />
Cl8r0 2,24<br />
SAiILOWER<br />
(Itdi-71)<br />
cc "cNta cc<br />
Ior.l 13.a9 12.61<br />
ctEt 12.11 11.21<br />
Cl8:2 13.02 73.12<br />
3<br />
o.25<br />
o.21<br />
26,30<br />
2.62<br />
J0.75<br />
COTTONSEtrD<br />
"cNtdn<br />
13.99 20,36
TrU.6.13 lks. c.@dit 6!! of "C NMR !.d @ ot sutl.rc oib Th. te<br />
rdi & @q.Et|. cGiktiA ln qpqiMltl @qrdi6 oftor! d..ho&. NMR il e<br />
.bbro.li&(ari't ta*a wbu bD tuiy.ci&-<br />
Trhl. Cl3<br />
P.rc.nt g. Frity Acid CoDpoclfioo of Sunllowcl Oils by GC<br />
c,c<br />
c6<br />
c8<br />
clo 0(a<br />
ctz o.a7<br />
cr4 0.36<br />
cl6 a,l2<br />
Cl8:0 4.94<br />
C2O:0 0.46<br />
C72:0 0.88<br />
SIJNtrlOWER<br />
(Comncrchl)<br />
ttcNt'R<br />
Tot l 15,21 16,11<br />
Cl3:1 30.6J 32,!9<br />
Cla:2 1a.7O ,13,U)<br />
cla:3 1.90 2,24<br />
rnd "c NMR<br />
I l/t<br />
@<br />
0.23<br />
0_J4<br />
0.I3<br />
o.73<br />
18.29<br />
t1_19<br />
1.78<br />
SI]NiLOWER<br />
(EO-l)<br />
t"cNr&<br />
16.35<br />
l9_65<br />
62.22<br />
t.71
T.bk 6.14 lbts th. onprtltirc 3tudy ofrllc strhsn vdietics Bi.8 "C NMR<br />
.!d GC d!o&. As.nr th. r6ul5 .E ooprobh to aod or[d NMR is @blc ro dtf.rc n<br />
r& ha*€ wbu fds ncy.cid& Ih. d@t6 .rc low ir qutliitv &oD C5 !o Cl2 Ed<br />
C22, S.@ @ilE tL qE .ty of (Cl8:0) i .ho pcd n .&nbt b Di,r qu.li, of<br />
(Cl6:0).<br />
T$lc 6'14<br />
P.rccotrgc Fatty Acid Conpolilion of Soyrbern Oib by GC rnd rrc NMR<br />
SOYAtrEAN SOYABEAN SOYAAE{N<br />
(co@d.i.l) (sido)<br />
c5 0.32<br />
c3 1.97<br />
ct0<br />
crz 0.41<br />
cr4 0.79<br />
cr6 20.46<br />
Cl8:0 3-Ia<br />
C22:O<br />
cc ttcNMx cc t'cNr,iR Gc "cN!'R<br />
oa5<br />
0.40<br />
020<br />
15.01<br />
4,31<br />
o.25<br />
on<br />
0.lt<br />
13.23<br />
2.12<br />
0.1,<br />
Tot.r 26.37 25.12 2112 20.55 11.32 18.12<br />
Cla:l l9.al !9,16 2l Ot 2313 ta95 ,0.35<br />
cl&2 16.15 47.s1 to,3l 49.40 4966 5r'61<br />
Cla:3 711 66a 1.92 960 99t<br />
lt5
T.bt 6 t 5 8iv6 t!. @4.nliv' dudv of rrc NMR dd Gc on @c li@'4 dd<br />
nps*.d o&. Agir rb. {tuts uc et ditrac'iirEd hv NMR tlow@ one dFr {tifiit'<br />
ec i! s€ it os of mpi4.t wLdG Nlvtrr ! @bL ro h€r*'o two tlDG of m'<br />
'li&dir'<br />
md. (clsl).td (C22:I) (C22:!) it totv i4ond ot'd s Eruic aoid dd is ldM<br />
'crd<br />
to 6@ nafth Drebl@r'<br />
T.blc 6'15<br />
Pcrcennge Frtty Acid conporition of-Corn' Linseed rnd Rrp'secd Oik bv<br />
GC .!d "CNMn<br />
CORN<br />
,.la&rr!rd cc "cNM cc ocll\,n cc "cNia<br />
c6 o-22 o. t5<br />
C3 - 0.02<br />
clo 0@ ' o,l3 4 5l<br />
ct2 o.17 - 0,06<br />
Cl4 0.t,1 - 0.ll<br />
ct6 12.00 10.21<br />
cr8:o 3ia - 6.27 2r3<br />
CzO:O O,O3 -<br />
099<br />
CZr.o o.lJ - Ot3 .-al<br />
cz40 0.21<br />
LTNSIED<br />
(t,lli.90)<br />
RAPESEED<br />
(K-2lO<br />
To!.f - ro.sg lr.rz v.22 184' 9ll 82t<br />
cr8:t 25,66 26,94 tl3aa 39.22 15 30<br />
c22.r<br />
Aohl 25,26 26.9a 38 83 39.22 60 44 62 oo<br />
Cr8:2 46.55 4869 ll lT 1245 1t22 l3t3<br />
cl8:3 a,97 a.65 217a 2992 15'93 1622<br />
6
REFERENCES<br />
l6.U C.dd Ari!.dliu C.|@i.i[ sblt ldtdt !q.'d,bh !.6.td oih, t9e2,<br />
(8aiql 1987, C.dd Alim 87t ?). L.u.d tr 6.i'in PAqWHO f@d sl.lnrdt<br />
Presr@., vi d.& rcD di C.noll lx)loo. Ror ftrV<br />
I6.2f G C, rdy, R L ri.hr edE L N&., Ctbd-rJ ,v!41@ NzgNnD Rtw<br />
,S.drurtt, 2rd E r. , WiLr, N. Y,, l9Eo.<br />
(cal J.N. shoohry. sd!. gl@trdrE ,ttpl@d$ "!"c NMR SPccnucop n Pasa"<br />
tn NMR $@au.qt ll (lqn t9. ?*93. Prlrdo tt6., Frrbir<br />
I6.al rr. L M.n!, G t. M.nb !d teLoqq D.b@\<br />
Pwn@l NMR spcaacoo,llay.b. Ltu, l9N<br />
(6.J1 AUIO STACI'ING I'LOqAM, JDOL LTD, TolOo.,.p.4 Putlcliot No. l'Y022<br />
16.61 Soo NG !d We LD NG, L Ao. Ci@ S& , 60, 70 ( l9t3)<br />
tt7
7.1 Oikeed A.nrlysis<br />
CHAPTER - 7<br />
DISCUSSION<br />
Tbc oi!..& slris ** otr.iE
Prot bly str ofth6. t.v€ inctas.d th. pacot.s. ofb.eign fltl.r' In thc p'cet vtndv or<br />
@t on s€.d n ws mst sh .nd dur p.nioL. plu $ft lid 6rbn Li6G€d E a sflf sed<br />
od n mnb.d iEquiis of ornq sdde. tr4. did .td tttr * E$n thtl rbc pqcotrec or<br />
fmigr dfi6 ss iiS! in €F of lit!..d (Ebi9O) vd€t' \v.!ri.s 6oltv r@ve ilitt .nd<br />
d.c. Tlc othq r.€dr @ lE Imd.d by !i4.s .!d Dropq sqedins [? 4]<br />
7.1.2 Moillulc<br />
Thc rcfd@ ndlod for @i]|rt da@iltid ie d.sdit d i. ISO 66tlt7<br />
17.5t. Th. rqt n dridto llt3a2 "C b t! .@.r.tuspndic trdu. iilt r cctud @s it<br />
rad€d AOCS D.rhod i! slcfot ditr r.d dd b n &:Es b ,r dri.d oln .r 130 + 3"c ft)r !<br />
6x.d Frid c,g. 3h for su0ow@ed [?,3]. rsrl Filchd tnEtion ndlod ir rlso @d 17.6l Spa<br />
oifio mbtuc d.rds !!d NIR r.fl.d,@ oanod are llso E.d [7 3], but thc mst a@u.rc<br />
ddnod i! lh. dtyiq one. The Dml .vd!F tu8c aor @ittue it 3% Hirl| d!rd' c'ful.<br />
@B s..d nons. t.ohLor Mnm.groiuD dc@l,D i! s.ed Hr8[ minw @nrd tko "n<br />
.16 srirdns utl ru[i.s Droum b ndcrty. Fot abit .tic .!d Lar.E .!c !G!d€d $'hiot @F<br />
sw! |ot ofcL.triol6dsy, r[u qaliogli8!oilproddin@tt5. rt ofthee oile'€ns, rlc<br />
d4r& @rrht ts lowq rhd 3% A tvtiol !ih. for s@dowd s4& Biv.! mist!ft @d61<br />
Aom 5 to 13% [?,3], Tlt sunowq s..d Gql) b.s sljs v hiSh p@ml.gc tob th' lowdr<br />
o!€ (J%), nowdd ib rn of th6e, rn tuistu. @d.d n w !! th. noml Udn'<br />
7.13 Oil Co cnr<br />
Th. on @!td pLlt @3t i4otult roL in d€idiu rn or of oihed rth' oil<br />
@!niN mrc irtt icids. ns v.lc is sril. i!..{ Tlc on onrdt lati.t toD 3e€d to sed tnd<br />
vlrietr ro vri.ty On iha b.sis of oil olrott, w. dividc lbe presdt oil5"ds inlo 1*o ero'4s<br />
0)<br />
Hie! oil @ra. v.set U. oibddc e40%)<br />
rnv oil mrd wscntL oikc..* (
Tt Dr6cd cul id&.i. hit! oil Pdcot 96 h sufitrq (HGl). liE .d oil<br />
(ELi9O) .!d npd.€d on (K-536), l[! oth6 lhov . b* Pa€t sG tlD rB ro 21.<br />
'Ia.rc e rm widi.. of&vrt-o !..{t. Sovrbqr (St.D nf bi3h oil 6 alt<br />
(19.3%) .'d k€s 6&a! Dtt{ (1.8%), *hlc t y.tdn (wili6) hls L,w oi @dat (r8.4%)<br />
tde oftigl c.d.d of tu.ir! oltd (2.2%). It i oL.r $.t hish psFggc or 6'.tD dnc<br />
.nrl miet@ rctn|s oil c.m@t of rc.d .!tl bdoc rL @@v ulre A tuge of on Fr@r.g. is<br />
eivo ty hddd t3l ud ilec ...:<br />
$.flowd 36d<br />
Coltotsed<br />
Srdota c..d<br />
SoJdtd !..r1<br />
rsliA .r rn.. fts n<br />
EA be (a5%) ed ttsdlF i | |<br />
O. bw6r p6€lr!F. Li@Gd (Ebn90)<br />
oil6r'..rn n n hrg! r:r's..<br />
7.1.4 Frer FotS Acid (FFA) vrlu.<br />
i .@ th .&wd s..d (tlD;73) hr. on @!rcm<br />
r@. v.ri.ty. Thc oahqr ltrc on 6fr.dr bi3!a rb!<br />
.!d np*.d ((-J86) trc 3od witi.. b...u. r!.n<br />
Frce e$y .cnl FIA or .oidiry !.hb oft tu ! r @tue ofde ed@. to wii.h hr<br />
drotDb hE [h.Ft€d tbt tuty rca nDE tlci atd bbg. vilh p.rd lrtt6i& @bcuL O!<br />
rc!d6 a b e iquity- A hctt6 w.y t to d!6!. tlit .. .cil vtiE ie l[e t@b.r ofng ofKOH<br />
..qd!dt F|n..li,e 6e &@ nity.oi.b h lA ofoil<br />
AciLy n dd.b.d dEiig 3..d dddionrb! Thb dv be dG ro r''"rh& noF<br />
.s!, trb-dndis ore@Ls. th. s4d dv t dms.d bv kunins, did* tiabs .!d 0r!6<br />
t20
.1rds Scrors. Co ir nim{rseisN &grdc tn€ 61 This dcet.&tbi b otrl}6ed bv an d_<br />
,ytr loos $ q8. wbic[ qt t|36 lhc hy&oh6b of &t to lrA [3]-<br />
Tn @@l el'! of ne 6tty .cil (FFA) i9 0.5% r. rh. Dt6ar sludv hiEh6l<br />
FFA s oh.md nr qF of @nodcd (0,9%} Slight tish v.!u6 of 0 6% r. ot8d€d in os<br />
ofloy.bd (r,VUlbE). nDs*d lti tbc b.!oh rcffning proc* ofotu, l6c is lbout doubL the<br />
!D@r ofFFA. Abos 1,8% Io$ of oil b .xpeted ih {sc of @tton sccd dd 1.2% in ese of<br />
srltan (wi[i8) ud 606..d<br />
7.r5 Protcir (M.tl) vrluc<br />
Tbc oqt idpotut thilg rnd oil coit@r is grotei! or 6qtl r6rd@ Th€ oil on-<br />
bibn@ dqsy &d eani.l 6tty !oit! 10 hudn diet. vesd.bte prl.io whic[ re let in residul<br />
on et6 dd @b.rc u..d !v diuh.. EG&tu6. ltN th*.r. onv6&d ro lnidil pre_<br />
reic .nd lni ollrihn Mtirt n'!tri.r[r !d v.rity to Ll@ di.t. Th.E rt. mE toxic @E<br />
pou& n rci
7.2.r Cobur lrder<br />
t lih.nd liitooclo s $. m wrd.t ued istllllMt for @lou h43u'Ml's<br />
I?.4. Tln bls b.a Ed haq nish obu h&x b ot6ded in Ep6ccd libsed !d otroNe'd'<br />
Th. @!ru ir&x ixli..la tt€.@ ofibor.dld ofpiBrdt! ot tne Dd.rt c'ttE in&x<br />
.!o r€dls 6ds. of r.6i.g pr6@6 ia tlq.cnns dd dot oft.rb! lnd rhis ic €['d 6lou<br />
pa*D n ldibL oib t7.3!, C .'rettrylt nici|.l cd.tropbvn soPLx givc olou 'o oiIJ Da<br />
odornliion somdidc tdult itr ddrucrioo of oot@oils ud tLi! r.!uh b 6I of @lou or il<br />
dy h. cn lss b loophmb dttu(tft. C.loor tLo cb.lee de to dp6rc io ltbl dd 'n<br />
dditrs doEsF. C!@rcil otu hw€ b* obu hds, h.c!c. rn6. scre rc6n'd dd dddoF<br />
7.a2 rre€ Fatty Actd (FFA) Value<br />
A!.@Er ot&e 6tty.ci.l trl@ [$ bd ia b.6t i'r sedin 7 l-4 Frc'<br />
irlt rcil mtat ir . ncor qlicl t s dir .6ca @ rnc htl fcld of cto d on IB dadiM-<br />
rion is of Fi@ iaon !@, Rosl I?.?l br @i.wd its iqon6@ ad . D€rbod ro {lul. n'<br />
c.rd. oils hlve I .o 5% ofFFA 6l' ttc r.6!od oils blve Gs tdodrSq<br />
Frcsblv rched md de<br />
o&riz.d oib !.v. FFA v.t@ of0 03% bl, s t[. sronse tim ed @ldtioa lrt ctdgc4 thi!<br />
{h€ oy rie. A ut! oto.os% s.e?l!bL lioir' I! the pr6.d 6sc.l oih h'v' FFA !th'<br />
Lrs tb.n o.os%. FFA v.hD bi a rcLtir witb @ithre odo. ll t!. oil bts much Nduq<br />
nFA nhE i.rn@iic.lb itrm.d This h4 t@ rLc qs. hd So@ mistue ton led tt!<br />
@t@.1h1o lhc oil duilg Gxrrtdiot pre@. Co!l@!.sl ludns hvc l* tm6l of FFA<br />
qluq prcb.bb b.{u. of b.nd m.rhod of r.fitilc l[e or<br />
?.L} rodir. Vdu.0V)<br />
lodb. shc (Iv) is ! o*3uic of .trul ulr$rio! o' nuDber of doubL ttds<br />
p6al ir ! fri Th. ftl.s !!c d&oy.d d!. ro oxtd id tnd n6o. thcn bdbe val@ i' r'du@d<br />
todir. unr€ or l{7-lr2 i. ese of liB*4 tunows dd $}th4a (o@dcitl) rdp'clivet<br />
t22
6hos hrs! d.sice of lNtulbn in rn6€ oiE Most ofbdnE ube.rc wibin d. repon.d linF<br />
is ofco.Lx Alidarlriou St!ffbrd 17.31 qo.pt fio!. of lis4{ $t6tsn (St*le) shere ulud<br />
!rc L*d thd BirioM v.lw 6d $t{ha! (@nlffidtl) shd. vilo. i! hiehd 1n!D n|ximm<br />
v.h.. Itlb By ds lo dDdinqn l @a i @ru.@lrs b.o@ rhc @xinm dor it 6%<br />
sti5 ! losihk b 6it ndlotl<br />
7.2.4 S.potritic.rion V.lue (Sv)<br />
stpo.i6..tbr vrbe ie th. i.tL' of !!m ml*rh' w.isb oflrlctv'dide @d9ris_<br />
i.s the ir Hish $tditctiE rtE ot l9t i ot .dcd itr €s of .ut wa GlCl), t@nowa<br />
(192), $rbar *ilid (leJ), liG€.d (ltl) eFban 6mil (leJ). nE oib conr'in cn<br />
tbd lth adld of di.dB (ts ibublc to!.L), tia.' (3 dolbL hon&) or oillrc ofbot\ *-<br />
c.pr smowa wbion hls hish6l .@@t of di@ rha v!l@ .r. wihin t[' tbns of Co'!*<br />
Ali@l:riu srln
?:.5.1 "c NMR<br />
'rc Nrltr h.s b6 dore i! 1*o wts i. 64krct pblon dslphd (coM)<br />
md€ rnrl sted d.@uPled or NNE @de in hlgus. of JEoL FX-90Q Fr NMi COM mde<br />
otrt siv6 quhirivc lspccr .d sisDred of FLs b.t.d otr dlyEi; of Shmkrv I? l0l COM<br />
md€ d!o6 "c pal tu6iri6 b.qe of Nuler Ovant@ Enntboodr (NoE) 6otor<br />
1.ln @qld. epcct@ ofG20{ lprq ltr chDcrdi,rb tatl li. i! 6' r'sion ofG4O pp8 For<br />
oudn tvc Dltrb. sD.c@ *n@ NOD fiaor ! a'sltit'L i rcqrird Thi! ir 'cheircd n<br />
g..d d.@'ptiu (NNE) Eod. rvblv sp€dn n€ @rLd for r g@d siSrl b mb' s/N r'lio<br />
The @ndnio! in s|lcd d@|4lhs b drt r!. wdlins dnc b.t*d '€uuhiou Sould h' I 0Tl<br />
whq. T, a tE dxi'm r.Ltti@ liE ot€d.4 ofrn' pat *hich s involved nr rht qu fitivc<br />
dbais. a l@wleds. .f s"iFtnic. r.Lutio. Tr i! 'hd'foE nmrry rnvdbn i@v'ry<br />
tR seq@e oelhod bts b.a ed od n is rh. msr .@u't' D'rhod The b461 reltnii'!<br />
rioe or4.1 s is oh.ded b * of l6ad oi! 6i cr7 pa\ ftqcfo" for oG teuullbn '<br />
snibg ri'!. of4l 3 i! r.{uircd Ahod I O .@@ulttioN wde t'quied lot ! sood siSol in qse<br />
of liE€d oil ? nhln6 li@ st tpqn ia ra@ultlio! td 'bou 3 Dbut6 wrc !*n'd nr<br />
rMrdids rnit int8ration of3p.drm Thu I |o din'rr. tid€ ue requt'd for rnlvsis Exl'ml<br />
d.u{i@ bcl u3 s.
! 3a ptr It io clar rt t iios @npLl.ly pdon &@(plc! (COM) .p.ctn ihr. rh. r.ain @v-<br />
diE 4G2m !9$ b @L. br qu.dniv. Putpos6<br />
v€s.N.ti. oib 6nt in itn. dcLi i.. Dlotoa ItO dd r3c Proto! si,6. oc<br />
plex !p..am s {! 3toM in Fig (5.5). ftis tp{t@ bs ttod tols . uide.tiied bnli_<br />
!lt!. Iltcgdrim of tro.d pqL! t.d dit oiif.d dultiPlel gt6 wbna r*u!s. Fi.U<br />
ito@gacity ir.bo . DtubLd Hoqar t'g! f.ld tblon NMR av Sivc b.ttd sp.da ed<br />
ha@ h.n6 qudntrivc su!t. Bqu. of @{!.iLtiliv of hiSn 6!U NM& llis optbb i mt<br />
iri.4 '?O erv6. sblbD.r* ht.llty!6 of.ci&. ftnp-tbttqd.rdn@€mio6@tDn<br />
b ot't iled aob "o 16ot!.@ lt. olt !@Ls o
7.2.5.2 GAS CHROM TOCRAPTIY<br />
A4t'|i! ofitty !ctl, i! v.gsrblo oils tbroud d.rilrltitiotr b fom Flttv acid<br />
M.ttyl Estd (!AME ), .d .!h..qrdt 8|3 ch'oErognphy bN rdin€d @e of th. mst<br />
wnn Ddlbd of dl}l6. I1 b gdatlt !9..d lbtl tL. lhsid ph.e. of rh. c!re@to3r.pbic<br />
oll@ i. rn prbciprl &ctor Sovcoing tlrc s@mliot of FAME' Ttc sEdnd t€l:t lUovs t<br />
wid. ruee of tqud tht6 ituludiog poljr'oBtd! ruot s pob.tbylde glrol .dip.le (PEc{)<br />
Dovdi.thyhrc cbsol swot€ (DEGS) rnd oFs.Iioon. P!'s. Howd6, io tnc F6€or<br />
wdh DECa wss foud to bc c.tul fo. tbc 3lornton ofttDd ![ lh. FAME s ruailg &oo C-<br />
6 t C-21. ANt rebdve .ra @sud@r 61 6. pdc.o!a. @nposnid ofth. &try .c'ds<br />
we d@ ty d.droni. iotosrtor. Idcotifiotb, ofr[. Pats !!d olibr.tbr of ih. iBtuDdr<br />
rs rcli*d by u!,"ig of ituLrd Einw of talyl .5rq!. Coqltte GC s@D.ib of rn<br />
O. nay rcid Ddty d6 (FAr,Es) &oo v.rbu v.sd.blc oil $4ts w.s oh.n d n lle<br />
pr6at mrL The s.s .&odro!r.s oa .Lt.htd firiy .cid et[yl €tr6 is slom ir<br />
Fig(6.21). Tb. tod ulFi ri@ oft!* FAMI€ E lcr lb. dislng Ca ondibtu m fo6d<br />
to !. 22 snd4. E .i D.rlqd 5ra w$ id.ldftd .Dd qmti6ed b, . @rylriF! of rbe<br />
d.di6 ti@ wt! rb.r of @@c.lt t,.9|rcd D@ .'rtdft snntLtd s4L' A. is thc @<br />
Buly, rh. FAME w. ..?.nt d b ord.i of ns4irs @le!|t eogh on in DECS<br />
!r.d@!y !e.e i'|i,i 640@& of rcglubL oil wq. plhni. rcil (Cl6:0I ud lh. the<br />
C-las (..n , oLrcsd |noLic rcid) qbnb .h!cd i. ru..dtr orda.<br />
ExmiDib! otrlc rdub of itty .cd. oh.io.d tt GC ldh/sit re@t t!.1 @t-<br />
los*d oilh! th. nighdt.@ul oftold ntut 1.! (26,08 %) {tiL np€4d onnts lh. bwst<br />
(9.rr % ). Cas clroDtoFptic r4bliqu. h.s .n .dv.nr8. in lti] utab rlll riD* .x rhc<br />
FAME! .r. oonplelely relollcd 3o ihcy cu b. D..cur.d dep.r.tely .v.n whm rhc<br />
@ndr.lio of the en.r i6 too low to bc da.orcd by NMR. TlbL 6.15 sivB lh.64!6riv.<br />
srudy oI IrC NMR ..d CC on @h, li.!*d snd hp.rc.d o't. Th€ r.tutl€s .r€ Dol<br />
dmodtued by NMR ADd nom rhie lb. heunoic, ootrroic, dqroio .trd dod€cmi lcils<br />
w@ d,cdt€d dd quni6.d br CC 6'! de 1o rh.n bw r@dr d.r 6uld e1b. oli6.d !y<br />
6. NMR T.hl. 6.15 .Lo thow6 tblt trr@.d oil @!niN cmic roil . m l@tuterl 22<br />
srtd roid (c-22:1. D-9. .n) |4ro 45.14 %. Tbis rcid wr .nes€d ro 6Ge nuiritirul<br />
126
ootld .rd wB regridcd $ . h6ln h..rd rnd bt eu! .cid nDsee! srniB wq.<br />
htods.rl ty ph tr.cdinrt [?,lll, T[€ ENpan E@moic Comunv (EEC) popo*d<br />
Etua Acil n F@d Resrhbn l9?9 nih. U.K [?-12] *hit 6Erd.d.h. @cio.cid ofia|r<br />
ro 5 % . Thdeforc h tbe pr.sdr wo.l n st foEd ttrt !i4h CC ofFAME provlts. lrpid<br />
s@bs ..d Uy eli.6 n i! 6Itt ti.d thrr rll t!. !.rclbl€ oi&, qc.ot nps.€4 lrc Ae fiob<br />
Ap.rl Aod llc p..ld ol!@ sD dioetognthy ol FAIvtEs. I o4!!ieD<br />
ws rl. dor. uiig ! qpflty @he e$ .nmdlognDty. Altou€! .hc tchiq@ of aDnlry<br />
@ t r b.6 Llou for l@y rq6 brr srs tui et! ed owi.8 ro tlc .b6@e ol .<br />
sufi.iort srrbL d€t€.-ror. Crpilbry sls chro@logr.pby ir mw b4oDbs widely c.d<br />
6p*i[r ci@ 1!r iobodudior of rclibt s@niv., liuar, tuG ioli in deic.ior !d fi!.d<br />
silid opirr.y 6nm witt cndialy tod.d srbrry ptrB. Th. Giaril fatue of .<br />
dpilLry ol@! 1b!t di$ilguirlE I nod rb. prctcd @ll@, is rnrt n is opa tobuht. tt€<br />
srltiDrr pt * &ing o.ld ! . i[il fl6 oo th. Bit qll of tb. olt|m ft.lc.gih of I<br />
opillry oh@ is mtult 2J to 60 etdc wirL 0.2 - 0.8 M n .ful dirn rd. ln thi! 6ltm<br />
opdii.lbtr 6fr|!c oo* nt orth. Frir r.6 ir m iqorlll Fuln.lmr..h. preue<br />
drep8 .lorg 6! @lu@ oc. 6t.Bbn oflh. orier s!s, aod ircomd U.ar vclocity rowrids<br />
tlc 6d of rh. @Ll@ To lirioiF .hi! dgonb. rrs6 of be viroray sbould b. u$4<br />
hrdrc8d bcids th. hdt, foL,w.d by hcli@ od l[d nnro8d, Th. !dv!.rrs. of oDitb.y<br />
6nm n nr nbb @lvirg to*6 wba. n d t6h€ c! rld hc i{!6 of 6t.n nny<br />
.ci&. thie is rot posibL by Fctod anm .tuodloFoy- A nmb.r of rditu on @pillry<br />
@n@ ss d|.dto3nDty trrc rbo.rDar.d b bdte [7.13, ?.14]. Ii& (7.t) shoys rhc<br />
..9r.tin of d.rd.rd 6tty tcid ncthy .lrd, Btd fiob . v.sdlbL on ud 6tft ton<br />
hdolErtd oil Eis qpfl.ry @l!@ h 6 bc !@ th.t i. oqnno! ro dt prolcd ol<br />
'@, qpilhry @hm ir mr dly t nE i rc.olvirs in FAMES hn .ho is bls lim 66@<br />
A omlt ovdboled &ctor duia thi! .d)€is n t[.t 1n. rsuL! ohried by<br />
sD dmdtognplry.re sffilt t 6I ih. oqdnbn of tlF .furnu61 f.ny rcil sdhyl<br />
dd. Tt rrigbs'dc. in 6. oil 6.bi. sto.bl .nd @!v6io! ro FAME involv. a<br />
ml@u|rr raFrnsc@l [?.1J1. h rddnin d onor fri @y @nLir uspmin.bL mer (- 3<br />
t27
l-:,<br />
c<br />
t28<br />
I f i E!<br />
9?<br />
gEsE F;<br />
g5 g:<br />
iei:E<br />
i5!i<br />
Er F:<br />
E?C-[<br />
!t:€<br />
S .= E Y<br />
€ii!<br />
E A3F<br />
Fe d;<br />
EE iE<br />
2 P'E 9<br />
4E;F<br />
;'E IT E<br />
!tE'cl<br />
Fi d'. i<br />
Xe.i's E<br />
F;:!E
%), For lld. ro$6, tlo @ncd id of . t nnrk .ci4 qv liDLi., n m oil {4L ev<br />
e! .lr!B h6 .qo.r b t Fc.d4e oeihrnd b O. tutv tcid o4oib! G .hldiEd B<br />
GC. h 6dd h..liSht lo@ r!.! rL !..u1uh!. Wha i i r**.rv to Lloe rb. &rql<br />
d, of m rcil n d o( ny for udnidl or Lb.nfu PuDo6, llo E itdl 'l|rdtd sld<br />
.. q.!F ic .ci.l (Clt:o) lnodd D. ..U.4 Ed it o!..!e iF n th. ftd nttv t.il cda<br />
u.d b dlo&tc ttr. .crul o!6t.rid of tle hrtivirnDl rcnb it O. otigb.l !.4L.<br />
Exdi.d..r otrl. TrbL 6.!2 to Ltlc C t J |los drn r!. slb ols4 nr.y !ij. n n@<br />
e vdy.l'€}lv lovg (l-2 %) th.n ltn ofNMR Eowad,.i@c rti ndd it el @itod 30<br />
&i n*ns nlrta .h.iL.l ilt€.brbr to .i9hb 6. pbo@, if i ooca Ldc<br />
.3.3 C.ipri@ orNMR0d CC R{lr.<br />
T.tL 6.t2 stdr r6d. of itry roi& @4oetutr of rm oitt Deet {Sowd sd<br />
old,..d oil EiA GC bd NMR t .biCe Ar iLds.d dia rhrr @ 'nlil. NMR 6r.<br />
cL.rly idatii.d FAI n o c.5 to C-13, Tb. rc qurilrtiva r-d ofthe ..ids ty 6. lwo<br />
&.hn{& i! & vqy clo.e A vdy hl .liftroe td€ rh. ttu i wftb rn fDirt of<br />
.rp.ri@Ll nor gbe t!. h6rn ofd. two t clnlld i3 ldy ooch difrGrdr. Sls i rh€ *.<br />
ellrtr @F6 !d dic T.!L 5.13 ed 6 14 .[ow . 6q.iq h
REFERENCES<br />
I?-r1 FodariE of OiL, Sddr & F.6 |&iti'n rrd, lvLtul, FOSFA ldq[tibl.<br />
Loltloa 1982 o. 283.<br />
I?.21 lltld*El sintt&h o.groj,!tb\ oiheeds: d.Emi8ti@ of ihpunn' c$tatt<br />
ISq C'F,., Sh.Lrd No. 65& 1980,<br />
l7.3l r.LR. fticls4,{etdrr ei., pnp.tti$ ol Oib...lt. i 'lMltttt oJole.dt, Fe a".l<br />
F41y FoaL.Ed" J.B. Roe.l.nd J.LL ttch!4 Bbaia ,r!Dli.! sci@., r,ndo.,<br />
17.41<br />
M. A!&a, Rl rLnildedIB. R@$l<br />
F.t! wirsdch!ft T..hobsica, 89, 7 ( | 987).<br />
17 5l ldlDtiDf Sr.ldn L OrgEirtiti\ Oit.4rt: d.t mitud@ o! noane and nlatiL<br />
SLld4d No. 665. ISO- C6{. 1977.<br />
F.6l J. Mtd€[ dd D,M, S6itL,/lg@.rry, t r@i.!@. N.Y., |948.<br />
Q.1l t.B. Nos{ AMW 4 oib dd r'.4 Ed Rr. tLDiln.rd.l.B. Rll*ll Arpli.d<br />
SciE Prui$dr, hndo!. 1986, p l-90.<br />
[7.8] Codd Ali@t .ic Co@ilriD s'.ndrd! 6r .dru.6ts !d onq 1982 (Rai.d 198?.<br />
Cod.i AlbDd 87/t?. I!s!d by rl. Ftu FAO THO F@d SLrdlrd! Pog'!@, !t<br />
.lc& T@ di Cs€[. OOl00, Rd. , lt ly.<br />
17.91 M.r, CNr nm. nL qtkE in hwu nutritiq, Ed F.B. PdLy.nd J. Podnor., Elb<br />
Holred, cni.h*rd, 1983, p 23.<br />
l7.r0l ,.N. Sboof.ry, sd'. pfo,tr"a Appli@nM o! 'C NMR spccaapt i Prott*<br />
tt ttMR Sp4baqtt ll (lEll) pp. 7*93. Parr@r Pr6., ElstdL<br />
fr.ltl Food.!dfuri.u!@Olluiz ia\ DLirJaLt M.l oilt d htu nuhrto, - R.port oJan<br />
.4..r 4dt8i@, EAo, tJNo, Ro6., Ibt 1980.<br />
lzl2l fi. Eruic.cil ir Fod R.grhiE 1977, snruo.y b'b@r No,69I. 1977.<br />
[t.13] AcLdA RG.. ''. An Oil Ch@ Soc.66,293. 1989.<br />
[?.14] ACl@. &G Ia Axlj.ie of t!l5.!d Oi&,.d Lr. srnild rql J.B. n6el. Ehai&<br />
Atdi.d Soinc., Iedo., p, t37, 19E6.<br />
17.l5l !.w'rl.ll@!4A!.lrii!of!.4.!doili,Ed.RJ.tLmild.n1,,.8, Rosl,Eldnr<br />
Atpli.ds.i..." bn&o. 1985,p. 122<br />
[7,16] J,B. Ros.l ud ,,L.R Ph.ilrd in lnltttt ofoilnak, Fait ada Fdq Foodt,<br />
Eb@id Apphd sci..rcc, Loldoa 199 | .
CHAPTER - 8<br />
CONCLUSION AND FUTURE PROSPECTS<br />
n wr. rncy<br />
v.ga.U. oit @rin oalil p!tu of O. tm di4 sd ptuvit dd !ul,i. s.<br />
's b. of s@d qEtiy if O., rc b tuEt rL n Fotq otc n rhe b@n dir.<br />
ArrFi! of 6try.oid gdd. !r iqonet ro 4E tut egcobL oib u. of sood qu[ty.<br />
Tbu d@d&bL.!d vlM.cd @ltods e @d.d if r!! i.quiE.t qu&y io ids of .o@!cy is<br />
to Dc €c6€d Tlc iity .cit oqosibn .!d ro €,tsn .nat oftd quriy ndoc [Le e*<br />
turr..ib. Di*uq iaEii+ rhin@ de .rc n .d.d &r 6. vrtu. of v.sdbL oih ir! th.<br />
Mry of d. cttaic.t ter. for oil ida&y or pEiy tu t rdr.d to tnc finy rcir<br />
@pdrin v.gcrtt oib @qri. or dirbqi.Ln .d wht rh. @qo.iib of rhe. .e<br />
i.ia61ius, lnowLdSc of inc .mEr dd t ?6 of e$y ..id i. 6c 'rislrwite b wi.t€b<br />
r.ard.d a @. B.6ll noo ih. afiiiDt p.il of vid. TtG ncy.cid @qo.irb, of Oc<br />
!.g...bL oib atr.d by rte rw l..hiqE via "c NMR rd cL tlEL r!.r bo6 r!.<br />
t .hirB rF @ecinc ai& rh. r..rb obdod ne ,a$sbb do* ro och o$d wnbi, rnc<br />
llorbL libtu of @r. It NMR @rbod ! GmoEt .n!CL, npid rd @_det !.rive<br />
.!no!gh i i. 6 aaqiw tc&i|e to h. rd.prcd hy idE itii! n ou 6ldy. Il h.. .tr<br />
.dq!t!s. rlrr I &. mt r.qdrc &y sr.!d.r.i itry.cit {qt. fo. @Dp.rie rnt i, rhu b<br />
!b.olt. n Ntod O;6€ oilr te4 cLc reqund pr@.ErD. orbdhyl6r@ offfny.cirts bul<br />
i ii[..iipL.d ir.'panrc t.cbtlE Wirb 6...hd otqp,Lry @ll|6 ed r[. ct creni<br />
&oano-ilr.gm|.t, 6. hig[ r@ttrb, &d h.nd roMq of tbe nry rci,t @eo,nb! i!<br />
@rl.dt .di.v..l A[ tn6. prop.niq. @tc rbb te.lliqu. poput r in r!. qutily @ntlol<br />
r.
t E s qoi' ttigh 6ne t'trq'
APPENDIX. 1<br />
(P.rk A,3lgrn.lo rtrd othcr d.btlt)<br />
t33
'-C P..L ArrlpmrEnt ol Snt!:<br />
cattoN No. cu.lltl<br />
cl<br />
c9.D<br />
,c9,t0<br />
cl0.t2<br />
ct.!.1<br />
ct6<br />
cl6<br />
c!-t I<br />
rc4t.t2.l5<br />
cl4. t5<br />
c3.l.l<br />
ct.t I<br />
cl1<br />
ctt<br />
clE<br />
TMS<br />
a)<br />
o)<br />
(b.cd)<br />
(..c)<br />
(b)<br />
(b)<br />
(c)<br />
(d)<br />
(b)<br />
(c)<br />
(b)<br />
(b...d)<br />
O..d)<br />
la: O sr-i. *ld r.tnuc..ld<br />
t!a<br />
.$cr Olt (Thorl?8)<br />
PPM(!) 9E^ris<br />
t 72"235<br />
r:9.!rit6<br />
128.t!6<br />
l2t t!6<br />
69lrl<br />
6: t99<br />
34.9t7<br />
12 t8l<br />
11750<br />
t00r5<br />
a 5az<br />
29 542<br />
17 !61<br />
:t.361<br />
25 790<br />
:5oll<br />
:!Et0<br />
14 t95<br />
.8<br />
,B<br />
F<br />
G<br />
H<br />
I<br />
K<br />
L<br />
tl<br />
t\<br />
o<br />
TME
cAtBola No CHAN PPM (I) PEAXS<br />
cl<br />
:'c9.tl<br />
c9,lo<br />
'clo.r2<br />
cl.t,t<br />
ct6<br />
,g!6<br />
cr7.r5<br />
c,1-7.12.15<br />
cta.t5<br />
. ct,14<br />
cl.t I<br />
'ctl<br />
cl7<br />
cr6<br />
G)<br />
O,.d)<br />
(c,d)<br />
o)<br />
G)<br />
(d)<br />
(b)<br />
(c)<br />
(b)<br />
o.cO<br />
Sl.d. ..1.1 Prlhilic rcld<br />
t35<br />
l'l9t4<br />
l7l.tE5<br />
t29.ta9<br />
I t9 t69<br />
r:t otr<br />
69.1t9<br />
aQi03?<br />
l:l162<br />
t2937<br />
It.750<br />
30.0tt<br />
29 616<br />
:9 420<br />
2?.!6t<br />
2?.!61<br />
ls r9o<br />
:5 0I<br />
22,$0<br />
la l9J<br />
I<br />
c<br />
D<br />
E<br />
ic<br />
I<br />
I<br />
,K i<br />
t(<br />
L<br />
\l<br />
o<br />
TM'
)C lcrtr eggnnurr ot soy.b.rn ()il (Stcclc)<br />
c It0(,N No, CIIAIN' PPM (S) PEAKS<br />
cl<br />
ct6<br />
C9:C9.l3rc9il0<br />
c9.tt<br />
Cl0,l1l3r tql2<br />
cl5<br />
c1.2.3<br />
ct6<br />
cl6<br />
c4-1<br />
q-7,tt<br />
ca7,t2-15<br />
c4n t<br />
C8,8,l4ill<br />
cl I,t4<br />
c<br />
c3<br />
ct7<br />
ct7<br />
crl<br />
TMS<br />
(t)<br />
(b)<br />
(rb)<br />
G)<br />
({b.c),<br />
(..d)<br />
o)<br />
(.)<br />
(b)<br />
(.)<br />
(d)<br />
G)<br />
((\qi)<br />
(1,.d)<br />
t16<br />
t7l.9la<br />
l?l.Jtl<br />
t3l.@<br />
t29.926<br />
| 29:926r<br />
r:99!6<br />
l:8.t,6<br />
'l21.tn<br />
69.U3<br />
6?.@t<br />
33 9r?<br />
3r Eorl<br />
30.070<br />
29.907<br />
29.6'6..<br />
15 844<br />
25.&ta<br />
25,0t5<br />
22_r72<br />
21l5zl<br />
:0 tso<br />
t.r.t95<br />
oo.oott<br />
H<br />
I<br />
JI<br />
x<br />
L<br />
M<br />
N'<br />
o<br />
rMs
(] l'..k A$tgntrfrr ot !ioJ!b..n oit (\r.[I!E)<br />
CARBON NO CHAIN PPM (S)<br />
cl<br />
ct6<br />
c9,to<br />
c9.r!<br />
c9<br />
cl0.rltt. t0.t2<br />
cl5<br />
c2<br />
ct6<br />
cl6<br />
Ca-tt4.7.t t<br />
c+7,t5<br />
c4-t,t 2nt<br />
c4.t5<br />
C,l8.lal,.l.l<br />
cl r.ta<br />
c|l<br />
clt<br />
ct?<br />
cr3<br />
rus<br />
tl<br />
ll :l<br />
tl rl<br />
lt<br />
(.)<br />
o)<br />
(.)<br />
(ab.cd)<br />
(qd)<br />
(b)<br />
(!<br />
(b)<br />
(.)<br />
(d)<br />
(r)<br />
(b)<br />
rD.@o IMS<br />
L37<br />
r7t 64'<br />
|ll660<br />
tr9.r7E<br />
lu9.t7r<br />
l29,9tE<br />
l:t.loo<br />
l:7?97<br />
69.2n<br />
62.14J<br />
l!.9r7<br />
tl !45<br />
!1966<br />
:r0 | t.l<br />
30,11:l<br />
!0,t24<br />
79.745<br />
29.52a<br />
l?5!J<br />
:7 5tl<br />
tJ,085<br />
t2.9f2<br />
t2 864<br />
zo 19<br />
r4195<br />
c<br />
D<br />
E<br />
F<br />
c H<br />
I<br />
t2<br />
,3<br />
L<br />
M<br />
N<br />
N
, ':C P.rk: A$bnrrd |of ,SoJ'.|b.m (Conrrrlctal)<br />
c^laoN No, cHAI PPM (6) PEARS<br />
cl<br />
ct6<br />
:cr.t0<br />
c9,r:<br />
cto.|l.r]. t0.l:<br />
ctt<br />
ct,2,!<br />
cl6<br />
cl6<br />
qLt..r.r.t5<br />
c+t,lJ<br />
:cr.?,t2n,<br />
: aa.l5<br />
: Cli *.la: 8J I<br />
cll.l.r<br />
.ctr<br />
c!<br />
cl?<br />
ctE<br />
TMS<br />
(r)<br />
(c)<br />
G)<br />
(.)<br />
(\b,c,il)<br />
h.b,!d)<br />
G.d)<br />
{b)<br />
(b)<br />
(c)<br />
(d)<br />
o)<br />
(b)<br />
(.,b,cd)<br />
G,cd)<br />
(.) '<br />
|ll<br />
r7156J<br />
lll.65t)<br />
t29.96<br />
tz9jra<br />
t29926<br />
l2i B6<br />
t!137'<br />
60.2.3<br />
6it.09l<br />
33.9t?<br />
t2 237<br />
30.90?<br />
30.90t<br />
,9.6:t5<br />
t74!5<br />
25.0t5<br />
22.912<br />
n.Ea<br />
20130<br />
B<br />
c<br />
c<br />
D<br />
E<br />
T<br />
F<br />
H<br />
I<br />
l1<br />
,3<br />
t(<br />
L<br />
L<br />
M<br />
ll<br />
N<br />
o
'iOf..f f.g"-r,nf .con)Ol (.otrel.L! corou)<br />
cAlBoN NO. ' CHATN. PPM (l)l '' PEAKI<br />
cl6<br />
c9.10<br />
c9.t!<br />
c9<br />
ctt.t:<br />
clql2.l!<br />
ctt<br />
c:<br />
ct6<br />
cl6<br />
- c*l<br />
'cat.tt :<br />
c+r.t2.tt<br />
Cr. la,8; ll<br />
cI.ta<br />
'an<br />
'clt<br />
cl7<br />
ctr<br />
rua<br />
(.)<br />
(c,<br />
o)<br />
G)<br />
(.)<br />
(.)<br />
(*"'cl<br />
(c.d)<br />
(b)<br />
(.)<br />
o)<br />
(c)<br />
{d)<br />
(.)<br />
o),.<br />
($aal'<br />
1L.d)<br />
(r)<br />
la,<br />
ltt ttil<br />
l7t.5t5<br />
t!r.6ao<br />
l2tall<br />
rz9.ul<br />
l!tatt<br />
t:r I36<br />
tl3,t!5<br />
tzl.tu<br />
at ||9<br />
5i1.00?<br />
!19t7<br />
n ztl<br />
3t.lo.<br />
30i0lt<br />
29.n36<br />
29,tt:16<br />
!t 420<br />
:7415<br />
25.?90<br />
?!.r90<br />
,5.0t1<br />
t2.9n<br />
l?t6.<br />
:0.696<br />
t4t9t<br />
@.0<br />
a<br />
t)<br />
o<br />
H<br />
I<br />
JI<br />
n<br />
'L<br />
L<br />
M<br />
N,<br />
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CAREON NO. CHAIN PPM(S) PEAIiS<br />
(:l<br />
ct6<br />
c9.t0<br />
c9.t3<br />
c9<br />
cl0.r2.t!<br />
cl0.t2<br />
ct5<br />
cl,2J<br />
cl<br />
cl6<br />
cl6<br />
@7.1t<br />
caT.trlJ<br />
a.|.lS<br />
C!; la.8; ll<br />
c .t4<br />
ctl<br />
c3<br />
cl7<br />
(17<br />
clt<br />
TMS<br />
(.)<br />
(c)<br />
G)<br />
(.)<br />
(..b)<br />
G)<br />
(.)<br />
(.,\c)<br />
(c.c)<br />
(b)<br />
(.)<br />
o)<br />
(.)<br />
ad)<br />
(.)<br />
(b) ,<br />
o..d)'<br />
l/o<br />
r'n.69t<br />
t31.629<br />
t29,t0t<br />
t29.109<br />
| !9.?oe<br />
D8 2lt<br />
ll7,9t9<br />
t2?,!25<br />
6D.t06<br />
62.06!<br />
3t 362<br />
12 l8l<br />
I t.4?l<br />
29.153<br />
29J21<br />
t9 t:l<br />
:9166<br />
:7 761<br />
25.654<br />
25.654<br />
2t.ooa<br />
?:.9tt<br />
zo ae,<br />
t:r I9t<br />
c<br />
DI<br />
D]<br />
o<br />
I<br />
ta<br />
li L<br />
L<br />
M<br />
o
'--.' PCrrf rd:m-* fCsBlroli (5si)<br />
c^R0r)N No .HAIN PPV(6) PEAI.iS<br />
cl<br />
ct6<br />
c!.to<br />
(t tI<br />
ct0.l2<br />
cl0,t2.l!<br />
ct5<br />
ct.2,3<br />
ct6<br />
cl6<br />
c,7<br />
c4.t.r<br />
.::l.t.l l.l J<br />
4tt<br />
Cq la||l I I<br />
c .ta<br />
cll<br />
c!<br />
cl?<br />
ctt<br />
Tl.S<br />
dr<br />
[!<br />
ll:2<br />
ll: t<br />
ll:O<br />
Oli. ..J<br />
(dcd)<br />
(.)<br />
(.)<br />
o)<br />
(.)<br />
(b) .<br />
(.)<br />
(.)<br />
(c.d)<br />
o,<br />
(r) ,<br />
o)<br />
lc)<br />
(d)<br />
(..\6)<br />
(.)<br />
o)<br />
(t!e.d)<br />
(r) l<br />
l,il<br />
t rta<br />
t'|.ttt<br />
!:t.ri60<br />
rzt.lt!<br />
r29l|t<br />
t!8_lll<br />
r2t.t36<br />
!2t.l16<br />
r21.t2t<br />
69.1t9<br />
62 0!t<br />
t! '|?<br />
!l.tor<br />
rqort<br />
29.6t6 t<br />
:9 5!a<br />
t9 420<br />
21.alt-<br />
25.7m<br />
,5.'l0<br />
tt0!t<br />
::9r2<br />
t2-l6a<br />
20.696<br />
l,tt9t<br />
0qo0..-.'<br />
c<br />
c<br />
I<br />
,l<br />
L<br />
.L<br />
N<br />
o<br />
P
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