Thermophysical Properties of Propane, National Bureau of Standars.

NATL INST OF STANDARDS & TECH R.I.C.
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All 101 9861 44
Goodwin, Robert D. (/Thermophyslcal prop
QC100 .U556 '170 1982 C.2 C.I NBS-PUB-C
NBS
PUBLICATIONS
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NBS MONOGRAPH 170
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U.S. DEPARTMENT OF COMMERCE/National Bureau of Standards
Thermophysical Properties of
Propane from 85 to 700 K
at Pressures to 70 MPa
>Q
100
No, 170
1932
C.2
NATIONAL BUREAU OF STANDARDS
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Mr aTAHXiAMBm
LOBEABT
Thermophysical Properties of Propane 29 (33?
from 85 to 700 K at Pressures to 70 MPa ^
Robert D. Goodwin and William M. Haynes
Thermophysical Properties Division

National Engineering Laboratory
National Bureau of Standards
Boulder, CO 80303
DATE DUE
Demco, Inc. 38-293
U.S. DEPARTMENT OF COMMERCE, Malcolm Baldrige, Secretary

NATIONAL BUREAU OF STANDARDS, Ernest Ambler, Director
Issued April 1982

Library of Congress Catalog Card Number: 82-6'005I4
National Bureau of Standards Monograph 170

Nat. Bur, Stand, (U.S.). Monogr. 170. 249 pages (Apr. 1982)
CODEN: NBSMA6
U.S. GOVERNMENT PRINTING OFFICE

WASHINGTON: 1982
Contents
Page
1. Introduction 1
2. Physical Properties and Their Formulation . ; . , 7.
?.l Fixed-Point Values 2
2.2 Melting Line and Vapor Pressures 3
2.3 The Orthobaric Densities 3
2.4 The Virial Equation 4
2.5 The Equation of State ..... 5
2.6 The Ideal Gas Functions 8
2.7 Thermal Loop Computations 8
2.8 The Heats of Vaporization 9
2.9 Saturated Liquid Enthalpies and Entropies 9
2.10 Dielectric Constants 10
3. Computational Methods 11
3.1 The Homogeneous Domain 11
3.2 The Saturated Liquid 12
3.3 The Compressed Liquid 13
3.4 Fugacity Coefficients 13
3.5 Simplified Computation 13
4. Tests and Comparisons 13
4.1 Specific Heats 14
4.2 Sound Velocities 14
5. Tables of Physical and Thermodynamic Properties 14
5.1 Calculated P-p-T Isochores and Isotherms 14
5.2 The Joule-Thomson Inversion Locus 15
5.3 Thermophysical Properties of the Saturated Liquid 15
5.4 Thermophysical Properties Along Selected Isobars 15
6. Acknowledgments 15
7. References 17
APPENDIX A. Symbols and Units 26
APPENDIX B. Conversion of Units 28
APPENDIX C. Fixed-Point Values for Propane 29
APPENDIX D. Propane Properties Reference Index 30
APPENDIX E. Computer Program 35
iii
List of Figures
Page
Figure 1. Density-temperature diagram of propane 54
List of Tables
Table 1. Comparisons of vapor pressure data with eq (2) 55
Table 2. Comparisons of saturated liquid density data with eq (3) . . 60
Table 3. Comparisons of saturated vapor density data with eq (4) . . 65
Table 4. Comparisons of virial coefficients with eq (5) 68
Table 5. Behavior of coefficients of equation of state for

propane (eq (6)) 71
Table 6. Calculated P(p) critical isotherm of propane 72
Table 7. Comparisons of experimental P-p-T data of propane with

eq (6) . . . . , 73
Table 8. Comparisons of data for ideal gas functions with eq (7). . . 123
Table 9. Interpolated ideal gas functions from eq (7) 125
Table 10. Comparisons of heat of vaporization data with eq (9) . . . . 126
Table 11. Enthalpies of saturated liquid propane from eq (10) .... 128
Table 12. Entropies and specific heats of saturated liquid propane

from eq (11) . 129
Table 13. Comparisons of dielectric constant data with eq (12) .... 130
Table 14. Comparisons with saturated liquid specific heats 136
Table 15. Comparisons with C and C data 139

V p
Table 16. Comparisons with velocity of sound data 143
Table 17, Calculated P(T) isochores of propane 151
Table 18. Calculated P(p) isotherms of propane 164

Table 19. The Joule-Thomson inversion locus for propane 185
Table 20. Thermophysical properties of saturated liquid propane ... 186
Table 21. Thermophysical properties of propane along isobars 188
Iv
THERMOPHYSICAL PROPERTIES OF PROPANE FROM 85 TO 700 K AT
PRESSURES TO 70 MPa
Thermophysical Properties Division
National Engineering Laboratory
Boulder, Colorado 80303
Thermophysical properties of propane are tabulated at integral

temperatures over the entire range of fluid states from 85 to 700 K
along isobars to 70 MPa by using a modified form of the nonanalytic
equation of state. These tables, along with a table for the saturated
liquid, include values for density, compressibility factor, internal
energy, enthalpy, entropy, heat capacities, fugacity, sound velocity,
dielectric constant, and isochore and isotherm derivatives. In
addition to the equation of state, equations are presented for vapor
pressures, orthobaric vapor and liquid densities, ideal gas properties,
virial coefficients, dielectric constants, heats of vaporization,
melting pressures, and orthobaric liquid specific heats, enthalpies, and
entropies. Coefficients were determined by a least squares fit of
selected experimental data, including several new sets of data not
included in previous propane correlations. Comparisons between
experimental and calculated values are given, including those for sound
velocities, heat capacities, P-p-T data, etc.
Key words: Densities; dielectric constants; enthalpies; entropies;

equation of state; fugacities; internal energies; isobars; isochores;
isotherms; Joule-Thomson inversion; latent heats of vaporization; melting
line; orthobaric densities; propane; specific heats; vapor pressures;
velocities of sound.
1. Introduction
The present work is a revision and extension of a previous provisional
report [32] from this laboratory. Since that report many new data have become
available. These include: P-p-T compressibility data [25,42,94,95,102]; some
new vapor pressure data [57,66,94,95]; new specific heats [34] and sound
velocities [107] for the saturated and compressed liquid; and new dielectric
constant data [42,45] for the saturated and compressed liquid. Other
correlations (and compilations) for propane [9,16,20,27,41,59, 83,84,86,90,106]
should be noted. However, most of these correlations are now outdated with the
availability of new and accurate data, often in regions in which data did not
previously exist.
1
In the present work a new procedure is employed for selecting the critical
density, and the nonanalytic equation of state has been modified from previous
applications [30-33,35,36,38]. Derived heats of vaporization are used to obtain
enthalpies and entropies of the saturated liquid, such that the free energy of
vaporization is zero. Thermodynamic functions for the compressed liquid then are
obtained by use of these derived properties from the triple point to the critical
point temperature.
Computations in computer programs (Appendix E) for the present work have
been conducted in units of the bar, the mol , and the liter. However, SI units
are used throughout this report in tables and equations. Pressures are given in
MPa, densities in kg/m-^, and temperatures in K. For thermal properties, the
mol is used for amounts of substance. Symbols and units used in this report
appear in Appendix A and conversion factors in Appendix B. Fixed-point values
used here are in Appendix C. References for the principal physical properties of
propane are collected in Appendix D. Computer programs for calculation of
thermophysical properties of propane are in Appendix E. The density-temperature
diagram for propane is presented in figure 1, where the upper, left-hand corner
shows the freezing liquid line.
2. Physical Properties and Their Formulation
2.1 Fixed-Point Values

These values are listed in Appendix C.
(a) The Triple Point. The temperature (T^ = 85.47 K) is adopted from
Das and Eubank [20]. The pressure is given by the present vapor-pressure eq (2).
The liquid density is assigned for consistency with data in eq (3). The vapor
density is from eq (4) for saturated vapor densities. (In recent work [70] on
the triple point temperature of propane, including an investigation of two solid
phases, a value of T^ = 85.52 K was reported.)
(b) The Boiling Point. The temperature is from vapor-pressure eq (2) at a
pressure of 1 atm = 0.101325 MPa. Liquid and vapor densities are from eqs (3)
and (4).
(c) The Critical Point. Our selected temperature was found to be the same
as reported independently by Thomas and Harrison [95]. The pressure, at first
found from the vapor-pressure equation by simultaneous fitting with P-p-T data,
fell between values obtained from two propane samples of Thomas and Harrison, and
2
thereafter the vapor pressure equation was constrained to this value. The
critical density was derived by the liquid volume fraction procedure of

Van Poolen [101] using the orthobaric densities of Thomas and Harrison [95]. It
is about one percent higher than that derived by Thomas and Harrison and is
consistent with the value selected in the correlation of Das and Eubank [20].
2.2 Melting Line and Vapor Pressures

(a) The F-lelting Line. Experimental pressures from about two to ten
kilobars were reported by Reeves, Scott, and Babb [74] as constants for the Simon
eq (1). Their extrapolation to zero pressure gave T^ = 35.3 K. As their
uncertainty in T was at least 1 K, the selected triple-point temperature from Das
and Eubank [20] is used here. Melting pressures (P^) in MPa are given by
the relation,
where P^ = 1.6895 x 10"^^ MPa, T^ = 85.47 K, P^ = 718 MPa, and c = 1.283.
(b) The Vapor Pressures. Data used for adjusting eq (2) appear in the
first part of table 1. Other data, weighted zero, appear in the continuation.
The low pressure data with ID = 80 are newly derived via thermal loops [32] by
use of new saturated liquid specific heats formulated up to 290 K by Goodwin
[34]. (See section 2.7.) Define the argument, x = "'"/T^,; then vapor pressures
(P^) in MPa are given by the relation,
£n(P^-10) = a/x + b + c -x + d-x^ + e-x^ + f-(l - x)^ , (2)
where e = 1.35 and, from least squares analysis,
a = - 8.7227 80250 d = 12.6857 90059

b = 19.2030 78280 e = - 3.8065 42924
c = -15.6106 38913 f = 1.8832 14505
The critical-point slope dP^/dT (0.08113 MPa/K) was constrained to equal the
slope of the critical isochore from the equation of state at the critical point,
(9P/3T)^.
2.3 The Orthobaric Densities

(a) The Saturated Liquid Densities. Data used for adjusting eq (3) appear
in the first part of table 2. Other data appear in the continuation. If the
3
dependent variable is defined by y(p) Pc)/(Pt "
= (p^ ^ ^'^ defined by
-
x(T) = (T^ - T)/(T^ - Tj.), then the equation for saturated liquid densities is
F ?
y = X + (x' - x) '[a + b'x + c*x"] , (3)
where z - 0.35 and, froni least squares analysis,
a = 0.7643 89673 c = -0.1 150 01817.
b = 0.0094 57047
Equation (3) is constrained to a triple-point liquid density of 16.630 mol/L, such

that the calculated densities at low temperatures are consistent with the most recent
and most reliable data sets [45,64,68,75].
(b) The Saturated Vapor Densities. Data used for adjusting eq (4) appear
in the first part of table 3. Data at ID = 1 are derived from the vapor-pressure
and virial equations. Other data, weighted zero, appear in the continuation of
table 3. The following, new formulation of the compressibility factor for
saturated vapor utilizes the vapor-pressure equation, and yields l^-'-^'X as
a behavior needed when integrating the thermodynamic equation of state.

Let ; (Z^ - 1) where is value of the compressibility factor at the
critical point, and define the arguments, n(T) = Pg(T)/P^, x(T) e T/T^, and
u(T) E (1 - x). The saturated vapor densities, e P^(T)/(Z^»R»T) , then are
given by ^
Z^(T) = 1 + A^'n-x"^-f(x) , (4)
where
f(x) E 1 + u^-[a + b'x + c-x^ + d'x"^] , (4a)
e = 0.35, and, from least squares analysis,
a = 5.439 73368 c = 23.871 0761

b = -20.029 7592 d = -10.105 1069
Column, F(Z), in table 3 gives the experimental residual,
2.4 The Virial Equation

This equation of state usually is accurate at densities up to p^/5 when
truncated as follows
4
Pv/RT = 1 + B^(T)-p^ + C^(T)-p^ + . . . (5)
The second and third coefficients, B^(T), C^(T), here are dimensionless through
use of reduced density and temperature, p^ = p/p^. x = ^^ta have been
"^/^c*
collected in two excellent monographs [24,71]. Table 4 compares selected data
with the following fitting functions developed here for propane
B^(T) = B^ + B^/x + B3/x^ , (5a)
C^(T) = (1 - Tq/T).[C^/x + yx^j , (5b)
where
T = 342.250 K B^ = -0.458 0172
0 3
B^ = 0.478 4915 = 0.215 0050
B^ = -1.230 0138 = 4.798 6166
In present work, only the second coefficient has been used: in thermal loop
computations; to synthesize P-p-T data for adjusting the equation of state;

and to obtain saturated vapor densities via the vapor-pressure equation.
2.5 The Equation of State

Appendix D and table 7 summarize P-p-T data of propane. Inclusion of the
recent data of Ely and Kobayashi [25], Thomas and Harrison [95], and of
Haynes [42] provides a dense coverage of the P(p,T) surface for propane at
3
densities up to 740 kg/m (16.8 mol/L), and at temperatures from 90 to 523 K.
The present equation of state is modified from earlier forms [30-33,35,36,
38]. It is nonanalytic, yielding a maximum in specific heats Cy(p,T) at the
critical point.
P = P^(p) + p^-R*-[T - T^(p)] + p^ R*T^-F(p,T) , (6)
where F(p,T) e B(p) •(p,T) + C(p) •*(p,T) .
For any density, obtain the coexistence temperature T^(p) by iteration

from eqs (3) or (4) for the orthobaric densities. Place this in the vapor
pressure eq (2) to obtain P^(p) = P^[T^(p)]. Densities, p^ =
P/^c' reduced
at the critical point. The gas constant for eq (6) therefore is redefined,
R* 5 (0.0083145) -p^, MPa/K.
5
The temperature-dependent functions in eq (6) are defined as follows.
Hp J) = x^.exp [b'd - T^/T)] - x^^ , (6a)
where b e - - 3)^^^^, x 5 T/T^, and x^ =

(1 3) (1
ô^^^^'^c'
^'(p,T) - ^(P,T)/^^(P) - 1 ,
(6b)
where ^^(p) is obtained from >{^(p,T) merely by replacing T with T^(p), and
Mp J) E 1 - (co - J^/r^)/{] - 1/t^) , (6c)
where a)(p,T) e [I - 0(p)/T]. A value for 3 vyas found by trial. The locus of
temperatures inside the coexistence envelope is
9(p) = T^(p)«exp[- a.f(p)] , (6d)
where
f(p) -
= IP, - ll^/((Pt)r
(P|.)^ = P^/Pq is a constant, and refers to liquid density at the triple

point. The parameter a is to be found by trial.
The density-dependent coefficients of eq (6) have been developed tediously
by trial with data for propane;
B(p) E 3^ + (6e)
Q^'pI
and
C(p) E C-,-(p^ - l)-(p^ - CQ)-exp(- Y-pJ) , (6f)
where parameters and y atê to be found by trial.
The parameters and coefficients of eq (6) for propane are
a = 1, 3 = 0.70, Y = 0.15, n = 1.1,

= 0.4565 0524 198 C^^ = 2.2
82 = 0.1582 2653 715 '

= -0.2490 4576 736
Table 5 gives behavior of coefficients B(p), C(p).

Behavior of the calculated critical isotherm near the critical density is
shown in table 6. In particular, the slope (8P/3p .)y is seen to have no
r , L \q
6
negative values. (Densities in table 5 are reduced at the liquid triple point,
= p/p^.) Table 7 gives deviations of experimental densities and pressures
from the equati on-of-state surface for most available data. Data not used for
adjusting the equation of state include those of Tonilinson [98], Deschner and
Brown [22], Teichmann [94], and of Warowny, et al . [102].
Some of the preliminary data of Thomas and Harrison [95] (for T > T^) that
were used in the fit of the equation of state were subsequently adjusted as a
result of a small air impurity (0.004 percent) in their sample gas. The maximum
change in pressure was 0.017 percent while the average change was 0.004 percent.
Such a small change has negligible effect on the equation of state. Comparisons
with the corrected data of Thomas and Harrison are given at the end of table 7.
The preliminary data, which were used in the fit but do not appear in the table,
are represented by data points 720-931 missing from the table. For temperatures
less than T^, most of the data of Thomas and Harrison (designated in table 7 as
points 1460-1988) were obtained with a different sample and they made no
adjustments to this data.
On the first page of table 7, a summary of comparisons of P-p-T data with
values calculated from the equation of state is given. For the isochores of
Thomas and Harrison, deviations in the table are those for the corrected data.
For the preliminary data the density and pressure deviations are 0.43 and 0.32
percent, respectively, or approximately the same as those for the corrected
data.
An explanation for some of the large density deviations in table 7 (e.g.,
data points 1626, 1640, etc.) that are exhibited when the data of Thomas and
Harrison [95] are compared with the equation of state should be noted. These
data points were taken extremely close to the liquid-vapor coexistence boundary.
Although the pressure deviations were relatively small (maximum of 0.15 percent)
when compared to the equation of state, the pressure deviations were of suffi-
cient magnitude in some regions of experimental data such that the calculated
density fell on the wrong side of the "dome" and gave a liquid instead of a vapor
density, or vice versa.
It should be noted that the functional form of the equation of state for
propane given here also has been used in current work on isobutane [37] and
normal butane [43]. Identical nonlinear parameters, except for small differences
in Y, have been obtained for all three fluids in optimizing this equation to
available P-p-T data.
7
2.6 The Ideal Gas Functions
Chao, et al . [13] calculated ideal gas thermodynamic properties using
spectroscopic data and compared results for the specific heat with other
sources. A plot of their c'^(T) is linear at low temperatures, changing to the
P
usual sigmoid shape at high temperatures, a behavior that we could not represent
analytically. Their enthalpies are represented by use of the arguments
1/3.
X = T/lOO and u = X
(H° - H^)/RT = 4 9xp(- £/x)- 2 A./u^

^
(7)
i=0
where R = 8.31434 J/(mol'K), e = 3, and
A.
^0
24.11012 ^3 = 980.124065
A
A„
^2
Specific heats are C^(T)

= —— 94.40550
-585.32814
= dH^/dJ, but the entropies require numerical

A.
-5
=
=
-673.64094
170.42778
integration (SUBROUTINE IDEAL, Appendix E),
.T
S°(T) = S°(300) + f C°'dT/T
P
(7a)
300
where S°(300)/R = 32.552. Table 8 presents the data used for adjusting
eq (7), and table 9 gives interpolated results from eq (7).
2.7 Thermal Loop Computations

At temperatures from the triple- to the normal boiling-point, new data have
been derived for vapor pressures, saturated vapor densities, and for heats of
vaporization by thermal loop computations including AH and AS for saturated vapor
and for saturated liquid. The procedure given by Goodwin [32], and more
generally by Yarbrough and Tsai [103], used virial eq (5), ideal gas functions
eq (7), the heat of vaporization of Kemp and Egan [53] at the normal boiling
point, and the following formulation of the specific heats of Goodwin [34] for
the saturated liquid from the triple point to 290 K. Define x = T/369.80, then
5
i-2
C^(T) = A^-x/(l - x)^ ^ E
i =2
A^ 'x (8)
i n J/(mol 'K) , where
8
;
e = 0.7 A3 = 48.U1034
A^ = - 1 .77942 A4 = -100.24355
A^ = 77 .12878 A. = 135.42504
2 b
The rms relative deviation is 0.13 percent for the 76 data points. (The
temperature, 369.80 K, was used as a reducing parameter for x in the original
thermal loop computations. Since the fit of the specific heats is independent of
the selected temperature over a wide range, it has not been changed to the
critical temperature selected in the present work.)
Results for the vapor pressures appear in table 1 at ID = 80, and for the
heats of vaporization in table 10 at ID = 40. Saturated vapor densities from the

thermal loop computations are replaced in table 3 at ID = 1 by derived data from
the fitted vapor-pressure eq (2) and the virial eq (5).
2.8 The Heats of Vaporization

Table 10 shows the "fit" of selected data. Those at ID = 40 are derived via
thermal loops (section 2.7). Those at ID = 41 are from the Clapeyron equation.
The formulation of these data in kJ/mol uses argument x(T) e (T^ - T)/(T^ - T^)
" A^-x + (x^ - x)-[A2 + A3-X + A^-x^] , (9)

^vap
where
e = 0.38 A3 = 6.252 384
A^ = 24.840 848 A^ = -12.156 857
A2 = 24.166 535
The uncertainty of at least 0.5 percent in derived data for Q^^^ at the higher
temperatures will affect compressed liquid thermofunctions at these temperatures,
because we use Q^^^ to compute AH and AS across the "dome," from saturated
vapor to liquid along isotherms.
2.9 Saturated Liquid Enthalpies and Entropies

Data for saturated liquid enthalpies and entropies have been derived at
temperatures from the triple- to the critical -poi nt by use of the ideal gas
functions, the equation of state, and the formulated heats of vaporization. The
enthalpies then have been formulated, as shown in table 11. Define the
variables
X i (T, - T)/(T^ - Tj) . y E (H^ - H^)/(H^ - H^) ,
9
when the enthalpies, H (T), are described in J/inol by
o
y = X + (x^^ - x) •
E
i = 1
A.-x'""''
^
, (10)
where e = 0.37, = 0.001 J/mol , = 33082.187 J/mol and

A. = 0.2998 57304 = -0.9494 39705
1 b
Ao = 0.3868 58687 A^ = 0.1462 98673
2 6
A3 = -0.6240 97828 A^ = 0.1113 75514
A4 = 1.0360 03301
The formulation of saturated liquid entropies in J/(mol'K) is shown in

table 12. Let x s (T^ - T)/(T^ - T^) and y = {S^ - '
^c^^^^t ^c^
8 .
-,
y = X + (x' - x)- Z
i = l
A.-x^-'
^
, (11)
where e = 0.32, S. = 82.56147 J/(mol-K), S = 234.72617 J/(inol -K) , and
A^ = 0.1263 07708 A^ = 14.0277 6880
A^ = -0.7539 54622 A. = -20.6289 4506

2 D
A3 = 1.2532 70427 A^ = 16.0117 8434
A^ = -5.9696 10330 ^8 " " 5. 4110 8275
Specific heats along the saturated liquid path follow froin the relation,
C^(T) = T*dS^/dT, in J/(molM(), as given in the last column of table 12. For
the thermal computations, these derived C^(T) values are replaced by our
formulation of experimental data, given below in section 4.1.
All of the above saturated liquid formulations for H^(T), S^.(T), and
C^(T) are used to compute thermodynamic properties for compressed liquid
states at T <
2.10 Dielectric Constants

Table 13 presents experimental and calculated dielectric constants, e, for
the saturated vapor [89] and liquid [45,89] and for the compressed liquid [42] of
propane. These data are formulated via the CI ausi us-Mossotti function,
CMF = [(e - l)/(e + 2)]/p, cm"^/mol (12a)
10
The following formulation has been used to tabulate e along isobars in table 21
at temperatures extrapolated up to 450 K, and at pressures up to 70 MPa. Define
the variables,
X ^ V\ . = P/P^ ,
where P is in MPa, when
CMF = + A2*P^ + A3-p^ + A^*£n (1 + 1/x) + A^-P/10 (12b)
A^ = 15.562 6310 A^ = 0.5107 4051

A2 = 0.385 3141 A5 = -0.0045 1412
A3 = -0.150 9977
Data at high pressures have a diminished weighting as seen in table 13. The rms
relative deviation for 260 points is 0.048 percent in the CMF, and 0.018 percent
for the dielectric constants.
Comparisons are not given in table 13 for data not used in the fit to
eq (12). The dielectric constants of Pan, Mady, and Miller [69] at temperatures
from 91 to 115 K differ from those calculated from eq (12) by approximately 0.8
to 1.0 percent while those from Thompson and Miller [96] and Luo and Miller [62]
at temperatures between 220 and 288.7 K agree v^fithin 0.1 percent with values
calculated from eq (12).
3. Computational Methods
The numerical values for E and H in this report are based on the assigned
value, E = 0 at the liquid triple-point, obtained by use of the arbitrary value,
E^ = 21,888.910 J/mol. Specific heats of Kemp and Egan [53] could be

integrated to give the solid at T = 0 as reference state.
3.1 The Homogeneous Domain

The homogeneous domain of figure 1 includes all regions which can be
attained along isotherms starting at zero density without crossing the
vapor-liquid "dome," and without passing very close to the critical point at
T > Tc.
Computations start with ideal gas thermodynamic functions at zero density,
and then continue by integrating along isotherms by use of the equation of state
in the following relations,
11
AE =
f [P - T.0P/3T)].dp/p^ , (13)
= - T- y 0^P/3T^)-dp/p^ , (14)
AS = R-£n[P°/(pRT)] +/ [R - ( 3P/9T) /p] -dp/p . (15)

0
Equation (15) is for use with initial entropies in hypothetical ideal gas states
at P^ = 1 atm (0.101325 MPa) . For all other initial states,
AS = -
y 0P/9T)-dp/p^ . (15a)
In each (p,T) state, reached by above integrations, the following are computed,
H = E + P'v , (16)
Cp = + T-(9P/3T)^/OP/9p)/p- , (17)
and
'/ = Cp.(9P/9p)/C^ . (18)
3.2 The Saturated Liquid

At temperatures from the triple point up to the critical point, thermofunc-
tions for the saturated vapor are obtained via eqs (13) through (16). Then
eq (9) is used for the heat of vaporization, Q^^p* to compute
AH = - Q , AS = AH/T , (19)
such that the free energy of vaporization, AF = AH - T'AS, is zero (see

section 2.9). Having obtained H and S for the saturated liquid, E = H - P-v is
computed.
The single-phase specific heat, Cy(p,T), at the saturated liquid boundary,
is obtained via eq (23) for C^(T), given below, and the thermodynamic relation,
C^(p,T) = C^(T) + T.(9P/9T).(dp^/dT)/p^ , (20)
where p^^
is density of the saturated liquid. Values for Cp(p,T) and W(p,T) on
this boundary follow from eqs (17) and (-18). For liquid at the normal boiling
point, the following values have been obtained,
12
= 231 .068 K, = 13135.9 J/i,iol
Ej^ = 13128.2 J/mol , = 171 .288 J/(mol- K)
3.3 The Compressed Liquid

Starting with above values for E, S, and on the saturated liquid
boundary, eqs (13), (14), and (15a) are used to integrate along isotherms, and
then H, C , and W are obtained via eqs (16), (17), and (18).
P
3.4 Fugacity Coefficients

The fugacity coefficients in table 21 were computed along isotherms relati
to properties in hypothetical ideal gas states at a pressure, P*^ = 1 atm
(0.101325 MPa)
(f/P) = (P°/P)-exp [AF/RT] . (21)
For any (P,T) point, the isothermal free energy change is
AF = (H - E°) - H° - T-(S - S°) , (22)
in which the arbitrary value of was added to tabulated values of H(P,T)

such that E(P,T) = 0 for liquid at the triple point.
3.5 Simplified Computation

Given the subroutines of Appendix E, it is necessary first to call
SUBROUTINE PVTDATA, to place constants in common statements. To obtain the
density in mol/L at a given T,i< and P,bar, it is necessary merely to write the
instruction DEN = FINDENF(T,P) for single-phase domains. Coexisting densities
are given by the functions DENG.ASF(T) and/or DENLIQF(T), and the vapor pressure
in bar by PSATF(T).
For thermodynamic properties, the subroutine SIMPLE here is an example of

how to use the general subroutine THERMO (see Appendix E)
4. Tests and Comparisons

In the provisional report, Goodwin [32] compared some enthalpy differences
and residual specific heats with derived results of independent authors, i.e.,
Kuloor, et al . [59], Eubank, et al. [27], to ensure freedom from gross errors.
These now are omitted, as present properties are comparable with the earlier
work. Following are some comparisons of experimental specific heats and speeds
of sound with calculated values.
13
4.1 Specific Heats
Table 14 gives a comparison of saturated liquid specific heats, taken from
the report by Goodwin [34]. These are formulated with coefficients revised for
the present critical temperature of 369.85 K; for the range froin T^ to T^
with X = T/T^, the saturated liquid specific heats, in J/(mol*i(), are given by
C^(T) = A^-x/d (23)

^
i=2
where
e = 0.7 8.275 839

A^ = 6.636 737 -19.926 387
A2 = 80.767 32 51 .208 621
Table 15 gives comparisons of C and C data of Ernst [26], Goodwin [34],

V p
and Yesavage [104,105] with calculated values.
4.2 Sound Veloci ties

Table 16 gives comparisons of velocity of sound data with calculated values
for the saturated liquid results of Rao [72] and of Younglove [107], and for the
single-phase measurements of Lacam [60] and of Younglove [107]. The differences
approaching 6 percent at low temperatures have required a careful scrutiny of the
calculated derivatives used in the computation of the sound velocity. The
calculated values of (3P/3p) in table 18 agree well with plots of Haynes [42]
isotherms at low temperatures, and the calculated values of ('aP/3T) in table 17
agree with plots of the Ely and Kobayashi [25] isochores. The uncertainty of up
to 3 percent in the C^(p,T) data in table 15 thus corresponds to an estimated
maximum uncertainty of about 2 percent in the calculated speeds of sound at low
temperatures. For saturated liquid, the present calculated values fall between
those of Rao [72] and Younglove [107].
5. Tables of Physical and Thermodynamic Properties
5.1 Calculated P-p-T Isochores and Isotherms

Tables 17 and 18 give a selection of isochores and isotherms computed by
equation of state (6). These are essential to examine behavior of the P(p,T)
surface. They are a useful supplement to the isobars of table 21 for
interpolating P-p-T values and their derivatives.
14
The tables of isechores show that the isochore curvatures are qualitatively
consistent with a maximum in the specific heat Cy(p,T) at the critical point.
The isotherm tables show that 8P/9p is nonnegative and that pressure increases
monotonical ly with density along isotherms.
5.2 The Joule-Thomson Inversion Locus

Table 19 gives the P-p-T locus of the JT inversion, (9T/9P)^ = 0,
obtained from equation of state (6) under the condition T»(3P/3T) = p*(9P/3p).
This table has been computed to temperatures well above those of P-p-T data, to
show approach to a maximum in P-T coordinates.
5.3 Thennophysical Properties of the Saturated Liquid

Table 20 gives physical and thermodynamic properties of the saturated liquid
computed by methods of section 3. (Properties of the saturated vapor can be
obtained from Table 21 from values given at the coexistence boundary for each
isobar.)
5.4 Thermophysical Properties Along Selected Isobars

Table 21 gives physical and thermodynamic properties on isobars, computed by
methods of section 3. These tables are extrapolated above the maximum

temperature and pressure of P-p-T data used for adjusting the equation of state.
Small discontinuities may be detected at T^ = 369.85 K along isobars at
P > P^ = 4.24746 MPa due to a change in the paths of computation (section 3).
The first line of each table refers to freezing liquid on the P(T) melting
line. Each table at P < P contains a blank line for the transition from
c
saturated liquid to vapor, as seen by the abrupt decrease of density. Dielectric
constants are extrapolated above maximum experimental temperatures and pressures
(see section 2.10 and table 13).
6. Acknowledgments
Roland H. Harrison and R. H. P. Thomas of the Department of Energy,
Bartlesville Energy Technology Center kindly communicated the results of their
extensive P-p-T measurements before publication of their data. Many staff
members of the Thermophysical Properties Division of the National Bureau of
Standards have contributed valuable suggestions, references, and documents.
Robert D. McCarty contributed the essential least-squares program, providing for
constraints. James F. Ely indicated the new numerical integration procedure, and
the simple method for obtaining fugacities. Lambert J. Van Poolen assisted with
15
the procedure for liquid volume frdctions. Neil A. Olien and the Cryogenic Oata
Center have been of invaluable assistance in supplying references and in

obtaining documents. Special thanks go to Karen A. Bowie for her diligence and
expertise in the preparation of the manuscript and tables for publication.
Finally, we express grateful appreciation for support of this work by the Gas
Research Institute.
16
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Messwerte des zweiten virialkoeffizienten einiger gesaettigter

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[96] Thompson, Jr., R. T. and Miller, R. C, Densities and dielectric constants
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24
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25
APPENDIX A. Symbols and Units
Subscripts c and t refer to critical and liquid triple points.
Subscripts g and i refer to saturated vapor and liquid.

Subscript a refers to liquid-vapor coexistence (usually the liquid).
Subscript r refers to reduced parameter.

Subscript o refers to reference state property.
Subscript m refers to melting line.
Subscript b refers to normal boiling point.
Superscript o refers to ideal gas state property,
expt refers to experimental value,

calc refers to calculated value.
(3P/9T)p isochore derivative, MPa/K
(9P/3p)-|- isotherm derivative, MPa^m^/kg
(32p/3T^)p isochore curvature, MPa/K^
a,B,Y,n nonlinear parameters in the equation of state
a,b,c,d,e,f coefficients defined in various equations
Aq Zj, - 1 in saturated vapor density equation
A^- coefficients defined in various equations

b (1 - B) + (1 - B)^''- in equation of state
B(p),C(p) density-dependent coefficients in the equation of state
B(T),C(T) second and third virial coefficients
Bp(T),C^(T) reduced second and third virial coefficients
c exponent in Simon equation
Cy(p,T) molal heat capacity at constant volume, J/(mol*K)
Cp(p,T) molal heat capacity at constant pressure, J/(molMC)
C^(T) molal heat capacity for saturated liquid, J/(mol*K)
CMF CI ausi us-Mossotti function, cm-^/mol
E(p,T) the internal energy, J/mol
E° 21,888.910 J/mol (arbitrary)
e exponent in various equations
e dielectric constant
f/P fugaci ty/pressure ratio
f(p) used in definition of 9(p)
f(x) defined in saturated vapor density equation
F(p,T) defined in the equation of state
F(Z) defined in the saturated vapor density equation
Hq enthalpy for ideal gas state at T = 0
26
APPENDIX A. (Continued)
H(p,T) the enthalpy, J/mol
J the joule, 1 N*in
JT Joule-Thomson
L the liter, 10"^
mol 44.09721 grams of propane (C^^ = 12 scale)
(jj(p,T) defined in the equation of state

P pressure, MPa
P^ melting pressure, MPa
P^(T) the vapor pressure, MPa
P^(p) P(j[T^(p)], vapor pressure as a function of density
n(T) Pa(T)/Pc
$(p,T) function in the equation of state
^(p,!) function in the equation of state
^'^^ '^^^^ vaporization, J/rnol
Qygp '^^vap'
R^^) the gas constant, 8.3145 J/(mol-K), 0.0083145 MPa-L/( mol 'K)
R* 0.0083145 -pc, MPa/K
p density, kg/m3
Pp q/Qq, density reduced at the critical point
pp ^ p/Pf density reduced at the triple point
S(p,T) the entropy, J/(mol*K)

T temperature, K
Tq constant
T|^(p) liquid-vapor coexistence temperature, K
e(p) defined locus of temperatures
u(T) defined in various equations
V 1/p, molar volume, m^/kg
W(p,T) the velocity of sound, m/s
x(T) T/Tc for the equation of state
x(T) variously defined for other equations
Xjj(p) l^{p)/J^, reduced temperature at coexistence for the equation
of state
y defined in various equations

Z compressibility factor
The gas constant is increased slightly in value from earlier work in view
of the recent report of Rowlinson and Tildesley [78].
27
APPENDIX B. Conversion of Units
In the following table the molecular v/eight oT propane is given by
mol . wt. = 44.09721 g/inol . Also, 1 cal^^ - 1 cal (thermochemi cal ) = 4.184 J
and 1 BTUj-p = 1 BTU (International Table) 1055.056 J.
To convert from To Multiply by
Pressure, MPa bar 10.
atm 9.86923
kg/ cm 10.1972
Ib/in^ 145.038
Volume, m^ liter (L) 1000.
ft^ 35.3147
Density, kg/m'- g/cm"^ 0. 001
mol/L 1 . / (mol . wt .)
^b/fV' 0.062428
Molar energy, J/mol MPa 'm^ /kg 0.001/(mol . wt.)
bar*L/mol 0.01
cal.(.|^/mol ^
0.239006
BTU j/ lb 0,429923/(mol . v/t.)
J
Molar entropy, J/(molM<) BTUjy/(lb-°F) 0.238846/ (mol . wt.)
28
APPENDIX C. Fixed-Point Values for Propa
Critical Point
4.24746 MPa
= 220.5 kg/m3 (5.00 rnol/L)
= 369.85 K
Normal Boi 1 ing Point
P = 0.101325 MPa
T = 231 .068 K
Py = 2.416 kg/m^ (0.05478 mol/L)

= 581 .04 kg/rn3 (13.176 mol/L)
Triple Point
P^ = 1 .6895 X 10"^^ MPa
= 85.47 K
Py = 1.0484 X 10"^ kg/m^ (2.3775 x 10"^^ mol/L)
p^ = 733.34 kg/m3 (16.630 mol/L)
29
APPENDIX D. Propa Properties Reference Index
Melting Line Date Pressure Range, MPa
Reeves [74] 1964 200 - 1000
Babb [1] 1970 75 - 1050
Vapor Pressures Date Temperature Ra

Burrell [8] 1916 149 229
Maass [53] 1921 230 250

Dana [19] 1926 210 323
on /I
Sage [81] '
•
1934 294 359
Beattie [3] 1935 323 348
Kemp [53] 1938 166 231
Deschner [22] 1940 302 Tc

Gill i land [29] 1940 315 358
Cherney [14] 1949 303 323
Reamer [73] 1949 313
Tickner [97] 1951 105 165
Clegg [15] 1955 323 Tc

Helgeson [46] 1967 278 361
Carruth [11,12] 1973 95 179
Mousa [66] 1977 335 Tc

Teichmann [94] 1978 325 363
Kratzke [57] 1980 312 368

Thomas [95] 1982 258 Tc
Thermal loops (This report) 1982
h 230
Saturated Liquid Densities Date Temperature Range, K
Maass [63] 1921 195 - 249
Dana [19] 1926 273 - 329

Sage [81] 1934 294 - 369
Van der Vet [100] 1937 283 - 323
Deschner [22] 1940 303 - Tc

'
Carney [10] 1942 228 - 333

NGAA [67] 1942 227 - 333
Reamer [73] 1949 313 - Tc

Clegg [15] 1955 323 - Tc
30
APPENDIX D. (Continued)
Saturated Liquid Densities Date Temperature Range,
Francis [28] 1957 293
~7
Seeman [85] 1963 278 - 299
o "7 r>
Helgeson [46] 1967 278 - 361
Klosek [56] 1968 on

89 - 1 33
1 1'\0
Shana'a [87] 1968 lUo
Jensen [48] 1969 93 - TOO

133
Sliwinski [88] 1969 ooo

coo - 309
OT O
Tomlinson [98] 1971 2/8 - 313
o ~7 n
Kahre [50] 1973 278 - 328
Rodosevich [75] 1973 91 - 115
McClune [64] 1976 93 - 173
Haynes [44] 1977 100 - 289

Ely [25] 1978 166 - 288
Orrit [68] 1978 87 - 244

Thomas [95] 1982 258 - 369
Saturated Vapor Densities Date Temperature Range,

Dana [19] 1926 290 - 323
Sage [81] 1934 294 - 369
Deschner [22] 1940 303 - Tc

Reamer [73] 1949 313 - Tc
Clegg [15] 1955 323 - Tc
Helgeson [46] 1967 278 - 361
Sliwinski [88] 1969 283 - 369
Thomas [95] 1982 323 - 369
Virial/vapor pressure equations (This 1982 90 - 330

report)
Virial Coefficients Date Temperature Range,

Sage [81] 1934 294 - 377
Beattie [2] 1937 370 - 548
Jessen [49] 1938 273 - 323
Deschner [22] 1940 303 - 609
Cherney [14] 1949 323 - 398

Reamer [73] 1949 311 - 511
31
Virial Coefficients Date Temperature Range, K
Bottornley [5] 1950 295
Kretschmer [53] 1951 303
Gunn [39] 1958 311 - 510
Dawson [21] 1960 243 - 348
McGlashan [55] 1962 295 - 413
Kapallo [52] 1963 244 - 321
Bre'wer [6] 1967 248 - 298
Strein [93] 1970 295 - 493

Hahn [40] 1974 211 - 493
Warowny [102] 1978 373 - 423
Thomas [95] 1982 323 - 523
Compressibility Data Date Range of T, K Range of P, MPa

Sage [81] 1934 294 378 0.17 - 20.7
Beattie [2] 1937 369 548 2.4 - 31.0
Burgoyne [7] 1940 243 293 0.5 - 6.0
Deschner [22] 1940 303 609 0.1 - 14.2
Cherney [14] 1949 323 398 1 .1 5.0
Reamer [73] 1949 311 511 0.1 - 69.0
Dawson [21] 1950 243 348 0.05 - 0.18
Dittmar [23] 1962 273 413 1.0 - 103.5
Kahre [51] 1964 233 350 0,9 - 9.8
Huang [47] 1966 173 273 7.0 - 35.0
Tomlinson [98] 1971 278 328 1.06 - 13.8
Ely [25] 1978 166 324 0.26 - 42.8
Teichmann [94] 1978 323 573 2.77 - 60.9
Warowny [102] 1978 373 423 0.3 - 6.3
Haynes [42] 1982 90 300 0.6 - 37.5
Thomas [95] 1982 258 623 0.6 - 40.0
Virial equation (This 1982 270 600 0.4 - 1 .0
report)
32
APPENDIX U. ( Conti nued)
specific Heats Date Type Range of T, K
Dana [19] 1926 Ca(T) 242 - 292
Sage [80] 1935 C°(T) 294 - 444

Beeck [4] 1936 273 - 573
Sage [82] 1937 Cp(T) 294 - 444
Kemp [53] 1938 Ca(T) 90 - 230
Kistiakovysky, Lacher [54] 1940 Cp°(T) 148 - 258

Kistiakov/sky, Rice [55] 1940 272 - 369
Dailey [18] 1943 CO(T) 335 - 693
Rossini [76] 1947 CO(T) 339 - 422
API 44 [110] 1952 100 - 1000
Cutler [17] 1965 Ca{T) 91 - 105
Yesavage [104,105] 1969 Cp(T,P) 116 - 422
Ernst [26] 1970 Cp(T,P) 293 - 353
Chao [13] 1973 com Spectroscopic

Goodwin [34] 1978 Ca(T) 86 - 360
Goodwin [34] 1978 Cy(T,p) 90 - 337
Heats of Vaporization Date Te mperature Range, K

Dana [19] 1926 234 - 293
Kemp [53] 1938 231
Sage [79] 1939 313 - 348
Staveley [91] 1950 185 - 213
Helgeson [46] 1967 311 - 330
Yesavage [104,105] 1969 231 - 367
Carruth [11] 1970 111 - 237
Thermal loops (This report) 1982 230
Clapeyron equation (This report) 1982 90 - 360
Sound Velocities Date Temperature Range, K
Lacam [60] 1956 293 - 498

Rao [72] 1971 140 - 230
Younglove [107] 1981 90 - 300
33
Die lectric C onstants Date Temperatur e Ran ge, K
Sliwinski [39] 1969 293 - 370
Pan [69] 1975 91 - 115
Thompson [96] 1980 228 - 230

Luo [62] 1981 220 - 289
Haynes [42,45] 1982 90 - 300
34
)
APPENDIX E. Computer Program
PROGRAM PRTHRMB INPUT OUTPUT)

{ ,
C REVISION OF PROPANE THERiMOFUNCTIONS RDG/NBS, START JAN. 26 1981.

, ,
COMMON GK,GKK, Bl ,B2 ,83 ,84 ,B5 C1,C2,C3, E1,E2,E3, ER, IX

,
COMMON/1 /AL BE GA D E EP ET DCRT TCRT PORT DGAT DTRP TTRP PTRP

, , , , , , , , , , , ,
C0MM0N/3/DPDT,D2P0T2,DPSDT,DPMDT,DPDD,DPDR,DTSDR,DTHDR,D0SDT
C0MM0N/4/XBl,XB2, XC1,XC2, XE1,XE2, DXBDR,DXCDR,DXEDR
COMMON/6/ TSAT, THETA, PSAT
COMMON/8/ IN, IK, P,T,DEN, E,H,S, CV,CP,CSAT, W,WK
COMMON/9/ ONG,EG,HG,SG, CVG,CPG,WG, DPGDT,DPGDD
COMMON/11/ DELS, DELCV
C0MM0N/12/ZCRT,ZCALC,D7DT, ZSAT,DZSDT, ZFX FRT,DFRTDT ,
COMMON/21/ TPS{70)
COMMON/95/ PIS, DIS, OPTIS, DPDIS
COMMON/99/ TI,EZZ, EZ,SZ,CVZ, HZ,CPZ
DIMENSION HZA(70), SZA(70), PP(99)
DATA(WM=44. 09721) ,(PA=1. 01325), {GJ=8. 3145)
C NOTE MOL. WT. HERE IS FOR PROPANE.
1 FORMATdS, 2F10.0)
2 F0RMAT(I5, 3F10.0)
3 F0RMAT(8I10)
5 FORMAT(IX)
9 F0RMAT(8F10.0)
14 FORMATdHl 13X * PROPANE ISOBAR AT P =* F10.6, 4H MPA / )
16 FORMAT{ 9X1HT 8X3HDEN 9X3HDEN 8X1HZ 5X5HDP/DT 5X5HDP/DD
2 8X1HE 8X1HH 8X1HS 6X2HCV 6X2HCP 9X3HF/P 5X1HW 4X5HDIEL. /
3 9X1HK 6X5HM0L/L 7X5HKG/M3 9X 5X5HMPA/K 1X9HMPA-M3/KG
4 4X5HJ/M0L 4X5HJ/M0L 2X7HJ/M0L/K 1X7HJ/M0L/K 1X7HJ/M0L/K
5 12X 1X5HM/SEC 4X5HC0NST )
17 FORMATdX F9.3, Ell. 4, E12.5, F9.5, F10.6, F10.5,

1 2F9.1, F9.3, 2F8.2, E12.5, 16, F9.5)
20 F0RMAT(lH116XnEST IDEAL FNCTNS*/17X 3HT,K 7X3HHZA 7X3HSZA )
21 FORMATdOX F10.2, FlO.l, F10.3)
80 CALL PVTDATA
CALL PEEK $ CALL ISOTHRM
C COMPUTE THERMOFUNCTIONS ON ISOBARS. START ON THE MELTING LINE.
C NOTE, ISOBAR P=PCRT OK, BUT ISOTHERM T=TCRT IS EXCLUDED.
C ISOBARS AT P UNDER PORT TRAVERSE THE DOME.
C NOTE USE OF QVAP ,DATA, TO CROSS THE ,DOME,.
C NOTE USE OF CSAT ,DATA, FOR SPECIFIC HEATS IN COMPRESSED LIQUID.
C NOTE TPS(IK) USED BY COMPRES.
C GET FUGACITIES, F/P, VIA H,S, HZ(T),SZ(T). (J.F.ELY).
C SAVE HZA(70), SZA(70) FROM 90 THRU 700 K.
85 DO 86 J=9,70 $ TI = 10*J $ CALL IDEAL $ HZA(J) = HZ
86 SZA(J) = SZ
87 PRINT 20 $ DO 88 J=9,70 $ T = 10*J
88 PRINT 21, T, HZA(J), SZA{J)
89 CALL JTLOCUS $ CALL TABLIQ
90 IN = 1 $ NI = 57 $ READ 9, PP( I ) ,1=1 ,NI
(
91 DO 300 I=IN,NI $ IK = I $ LS = 0
92 P = PPd) $ IF(I.EQ.28) P = PCRT
93 PK = P/10 $ PRINT 14, PK $ PRINT 16
100 T = FINDTMF(P) $ CALL COMPRLQ $ V=1/DEN $ IW=W
35
101 Z = P/OEN/GKK/T $ DIE = DIELF(DEH,T,P)
102 TI = T $ CALL IDEAL $ GIB = H-EZZ-HZ - T*(S-SZ)
103 XP = EXP(GIB/GJ/T) $ FOP = XP*PA/P $ CALL COM
104 PRINT 17, T,DEN,DIS,Z, DPTIS,DPOIS, E,H,S,CV,CP, FOP, IW, DIE
105 IT = T/10 $ IF{P.LT.PCRT) 110,180
C CASES FOR P LESS THAN PORT.
110 TPS(IK) = TS = FINOTSF(P) $ l( = L = 0
111 DO 150 J=l,99 $ T = JT = 10*(IT+J)
112 IF(T.LT.TS) 113,117
113 CALL COMPRES $ V = 1/DEN $ IW = W
114 Z = P/DEH/GKK/T $ DIE = DIELF(OEN ,T,P
M =JT/10 $ GIB = H-EZZ-HZA(M) - T*{S-SZA(M))
XP = EXP(GIB/GJ/T) $ FOP = XP*PA/P $ CALL CON
115 PRINT 17, T,DEN,DIS,Z, DPTIS,DPDIS, E,H,S,CV,CP, FOP, IW, DIE
116 GO TO 150
117 LS = LS + 1 $ IF(LS.EQ.l) 120,130
C CASE FOR SATURATED LIQUID AND VAPOR.
120 T = TS $ CALL COEXIST $ V=1/DEN $ VG=1/DNG $ IW=W $ IWG=WG
121 P/DEN/GKK/T $ ZG
Z = P/DNG/GKK/T
=
122 DIEL = OIELF(DEN,T,P) $ DIEG = DIELF(DNG,T,P)
123 TI = T $ CALL IDEAL $ GIB = H-EZZ-HZ - T*{S-SZ)
124 FOP = EXP(GIB/GJ/T)*PA/P $ CALL CON
125 PRINT 17, T,DEN,DIS,Z, DPTIS,DPDIS, E,H,S,CV,CP, FOP, IW, DIEL
126 PRINT 5 $ DIS=ONG*WM $ DPTIS=DPGDT/10 $ DPDIS = DPGDD/IO/WM
127 PRINT 17, T, DNG,DIS,ZG,DPTIS, DPDIS, EG, HG,SG,CVG,CPG, FOP, IWG, DIEG
128 T = JT
C CASES FOR THE HOMOGENEOUS DOMAIN.
130 IF(JT.GT.500) 131,132
131 K = K+1 $ T = JT = JT + 10*K $ IF( JT.GT.700) 300,132
132 CALL GENIUS $ V=1/DEN $ IW=W $ Z = P/DEN/GKK/T
133 IF(T.GT.450) 134,135
134 DIE = 0 $ GO TO 136
135 DIE = DIELF(DEN,T,P)
136 M =JT/10 $ GIB = H-EZZ-HZA(M) - T*(S-SZA(M))
137 XP = EXP(GIB/GJ/T) $ FOP = XP*PA/P $ CALL CON
141 PRINT 17, T,DEN,DIS,Z, DPTIS, DPDIS, E,H,S,CV,CP, FOP, IW, DIE
150 CONTINUE
C FOR P.GE.PCRT, CASES FOR T.LT.OR.T.GT.TCRT.
180 TPS(IK) = TCRT $ K = L = 0
181 DO 250 J=l,99 $ T = JT = 10*(IT+J)
182 IF(T.LT.TCRT) 190,210
C CASE A FOR T LESS THAN TCRT.
190 CALL COMPRES $ V = 1/DEN $ IW = W
191 Z = P/DEN/GKK/T $ DIE = DIELF(DEN,T,P)
192 M =JT/10 $ GIB = H-EZZ-HZA{M) - T*(S-SZA(M))
193 XP = EXP{GIB/GJ/T) $ FOP = XP*PA/P $ CALL CON
194 PRINT 17, T,DEN,DIS,Z, DPTIS, DPDIS, E,H,S,CV,CP, FOP, IW, DIE
195 GO TO 250
C CASE FOR T ABOVE TCRT, HOMOGENEOUS DOMAIN.
210 IF(JT.GT.500) 211,220
211 K = K+1 $ T = JT = JT + 10*K $ IF(JT.GT.700) 300,220
220 CALL GENIUS $ V=1/DEN $ IW=W $ Z = P/DEN/GKK/T
221 IF(T.GT.450) 222,223
222 DIE = 0 $ GO TO 224
36
224 M =JT/10 $ GIB = H-EZZ-HZA(M) - T*{S-SZA(M))
225 XP = EXP(GIB/GJ/T) $ FOP = XP*PA/P $ CALL CON
226 PRINT 17, T,DEN,DIS,Z, DPTIS,DPDIS, E,H,S,CV,CP, FOP, IW, DIE
250 CONTINUE
300 CONTINUE
999 STOP $ END
SUBROUTINE COEXIST
C GIVEN T AT COEXISTENCE, GET BOTH VAPOR AND LIQUID FUNCTIONS.
FOR VAPOR, GET DNG,EG,HG,SG, CVG,CPG,WG, DPGDT,DPGDD, -
C
C FOR LIQUID, GET DEN,E,H,S, CV,CP,CSAT,W. DPDT,DPDD.
C COEXIST CALLED BY COMPRLQ. P NOT USED, MUST NOT CHANGE.
C0MM0N/1/AL,BE,GA,DE,EP,ET, DCRT,TCRT,PCRT, DGAT,DTRP ,TTRP ,PTRP
C0MM0N/3/DPDT,D2PDT2,DPSDT,DPMDT,DPDD,DPDR,DTSDR,DTHDR,DDSDT
C0MM0N/9/DNG,EG,HG,SG, CVG,CPG,WG, DPGDT.DPGDD
DATA (Q=l. 01325) ,(G=0. 083145)
1 FORMATdHO 9X *T EXCEEDS TCRT IN COEXIST. * / )
2 IF(T.GT.TCRT) 3,4
3 PRINT 1 $ STOP
4 PS = PSATF(T) $ DNG = DB = DENGASF(T)
5 TI = TCALL IDEAL $
$ M=15 $ DA=L=0
6 EG EZZ=+ EZ + EDELF(L,M,T,DA,DB) $ HG = EG + 100*PS/0B
7 SG = SZ + DELS - 100*G*AL0G(Gn*DB/Q)
8 IF(T.EQ.TCRT) 9,11
9 PX = PVTF(T,DB,1) $ DPGDT = DPDT $ DPGDD = DPDD
10 CPG CVG == WG = 0 $ GO TO 15
11 CVG = CVZ + DELCV $ PX = PVTF(T,DB,1)
12 CPG = CVG + 100*T/DPDD*(DPDT/DB)**2 $ WG = SQRT( WK*CPG*DPDD/CVG)
13 DPGDT = DPDT $ DPGDD = DPDD
C NOW TRAVERSE THE ,DOME, USING QVAP ,DATA,.
15 DEN = DL = DENLIQF(T) $ DDLDT = DDSDT $ QV = QVAPXF{T)
16 H = HG - QV $ S = SG - QV/T $ E = H - 100*PS/DL
C THIS RETURN AT 16+ USED ONLY WHEN CALLING SSATFIT, HSATFIT.
17 IF(T.EQ.TCRT) 18,19
18 PX = PVTF(T,DL,1) $ CP=CV=CSAT=W=0 $ RETURN
19 CSAT = CSATXF(T) $ PX = PVTF(T,DL,1)
22 CV = CSAT + 100n*DPDT*DDLDT/DL/DL
23 CP = CV + 100*T/DPDD*(DPDT/DL)**2
30 W = SQRT(WK*CP*DPDD/CV) $ RETURN $ END
SUBROUTINE COMPRES
C SAVES COMPUTER TIME INTEGRATING COMPRLIQ AT T.LT.TCRT.
C FOR T = INTEGER MULTIPLES OF 10 K. FIRST ISOBAR USES COMPRLQ.
C FOR SUCCEEDING ISOBARS, START ON PREVIOUS ISOBAR, EXCEPT -
C AT TEMPS GE TPS(IK-l) ON PREVIOUS ISOBAR, MUST USE COMPRLQ.
C0MM0N/1/AL,BE,GA,DE,EP,ET, DCRT, TCRT, PORT, DGAT,DTRP ,TTRP ,PTRP
C0MM0N/3/DPDT,D2PDT2,DPSDT,DPMDT, DPDD, DPDR,DTSDR,DTHDR, DDSDT
COMMON/8/ IN, IK, P,T,DEN, E,H,S, CV, CP, CSAT, W,WK
37
)

C0W10N/21/ TPS(70)
DIMENSION DK(50) ,EK(50) ,SK(50) ,CK(50)
1 FORMAT (IHO 9X *! G.E. TCRT IN COMPRES. * / )
2 IF(T.GE.TCRT) 3,4
3 PRINT 1 $ STOP
4 J = T/IO $ IF(T - 10*J) 5,6
5 CALL COMPRLQ $ RETURN

6 IF(IK.EQ.IN) 7,9
7 CALL COMPRLQ
8 DK{J)=DEN S EK(J)=E $ SK(J)=S $ CK{J)=CV $ RETURN
C INTEGRATE FROM OLD DEN TO NEW DEN ON GIVEN ISOTHERM -
C EXCEPT IF T EXCEEDS OLD TMAX USE COMPRLQ.
,
9 IF(T,GE.TPS{IK-1)) GO TO 7
10 DA=DK(J) $ DK(J) = DEN = DB = FINDENF(T,P) $ N = 13
11 EK(J) = E = EK(J) + EDELF(1,NJ,DA,DB) $ H = E + 100*P/DB
12 SK(J) = S = SK(J) + DELS $ CK(J) = CV = CK(J) + DELCV
C GET NEW DP/DT, DP/DD, CP, W.
15 PX = PVTF(T,DB,1) $ CP = CV + 100*T/DP0D*( DPDT/DB)**2
30 W = SQRT(WK*CP*DPDD/CV) $ RETURN $ END
SUBROUTINE COMPRLQ
C GIVEN P,T FOR COMPR.LIQ. AT T.LT.TC, GET DEN AND FUNCTIONS.
C REVISED TO USE HSATF, SSATF, CSATXF, BUT NOT COEXIST. TIMESAVER.
C INTEGRATE ALONG ISOTHERM T FROM SATLIQ UP TO POINT (P,T).
C0MM0N/1/AL,BE,GA,DE,EP,ET, DCRT TCRT PORT, DGAT ,DTRP ,TTRP ,PTRP
, ,
1 FORHATdHO 9X *T NOT UNDER TCRT IN COMPRLQ.*/)
2 IF(T.GE.TCRT) 3,4
3 PRINT 1 $ STOP
C GET PSAT, DENLIQ, AND SATLIQ FUNCTIONS FOR START.
4 PS = PSATF(T) $ DL = DENLIQF{T) $ DDLDT = DDSDT
6 HS = HSATF(T) $ ES = HS - 100*PS/DL $ SS = SSATF{T)
C . 7 IF(T.GT.340) 8,9
C 8 CVS = CVSATF(T) S GO TO 10
9 PX=PVTF(T,DL,0) $ CVS = CSATXF{T) + 100n*DPDT*DDLDT/DL/DL
C INTEGRATE UP TO POINT (P,T).
10 DB = FINDENF(T,P) $ DX = DB - DL $ IF(DX.GT.O) 11,20
11 M = 14 $ E = ES + EDELF(1,M,T,DL,DB)
12 H = E + 100*P/DB $ S = SS + DELS $ CV = CVS + DELCV
13 PX = PVTF{T,DB,1) $ CP = CV + 100n/DPDD*(DPDT/DB)**2
14 W = SQRT(WK*CP*DPDD/CV) $ DEN = DB $ RETURN
20 DEN=DL $ E=ES $ H=HS $ S=SS $ CV=CVS $ PX = PVTF(T,DL,1)
21 CP = CV + 100*T/DPDD*{DPDT/DL)**2 $ W = SQRT( WK*CP*DPDD/CV
30 RETURN $ END
SUBROUTINE CON
C CONVERT TO SI UNITS FOR P, DEN, DP/DT, DP/DD,
C0MM0N/3/DPDT,D2PDT2, DPSDT,DPMDT,DPDD,DPDR,DTSDR,DTHDR, DDSDT
C0MM0N/8/IN,IK, P,T,DEN, E,H,S, CV,CP,CSAT, W,WK
38
COMMON/95/ PIS, DIS, OPTIS, OPOIS
DATA (WM = 44.09721)
1 PIS = P/10 $ DIS = DEN*WM
2 DPTIS = DPDT/10 $ DPDIS = DPDD/IO/WM
9 RETURN $ END
FUNCTION CSATXF(T)
PROPANE, J/MOL/K, RDG, NBS J. RES. 83(5) 449, (1978).
COEFFS, ADJUSTED FOR NEW TCRT = 369.85,
CS = A1*X/(1-X)**E + A2 + A3*X + A4*X2 + A5*X3.
DIMENSION A(5)
DATA (E=0.7) ,(TCRT=369.85)
DATA(A = 6.636737, 80.76732, 8.275839, -19.926887, 51.208621)
1 FORMATdHO 9X *CSATXF, T.GT.TCRT. * / )
2 IF(TCRT-T) 3,4,5
3 PRINT 1 $ STOP
4 CSATXF =0 $ RETURN
5 X = T/TCRT $ CS = A( 1 )*X/{ 1-X )**E $ DO 6 K=2,5
6 CS = CS + A{K)*X**(K-2) $ CSATXF = CS $ RETURN $ END
FUNCTION CUBER.T(X)
CUBE ROOT MISSING FROM 6600 COMPUTER LIBRARY.
1 E = 1.0/3.0 $ IF(X) 2,3,4
2 CUBERT = -ABS(X)**E $ RETURN
3 CUBERT =0.0 $ RETURN
4 CUBERT = X**E $ RETURN $ END
FUNCTION DELTAF(T,D)
GET (T*DP/DT - D*DP/DD) FOR THE J-T INVERSION CURVE.
C0MM0N/1/AL,BE,GA,DE,EP,ET, DCRT, TCRT, PORT, DGAT,DTRP,TTRP,PTRP
1 IF(T-TCRT) 2,4,4
2 DL = DENLIQF(T) $ IF(D-DL) 3,3,4
3 DELTAF = l.OE+100 $ RETURN
4 P = PVTF(T,D,1)
5 DELTAF = ABS (T*DPDT-D*DPDD) $ RETURN $ END
FUNCTION DENGASF(T)
PROPANE SAT. VAPOR DEN, MOL/L, (DCRT=5.00), RDG, FEB. 19, 1981.
DESIGNED FOR ZSAT = 1 AT LOW DENSITIES, 5/29/77.
USE ZSAT # PS/DS/GK/TS WITH VAPOR PRESSURES, AND ZCRT.
Z = 1 + (ZCRT-1)*PI*F(X)/X/X, X # T/TCRT, AND -
F(X) = 1 + UE*(A1 + A2*X + A3*X2 + . ),
. U = (1-X).
C0MM0N/12/ZCRT,ZCALC,DZDT, ZSAT,DZSDT,ZFX, FRT,DFRTDT
DIMENSION AV(4)
DATA (GKK = 0.083145)
DATA (EG=0.35) ,{NFG=4)
DATA(AV = 5.43973368, -20.0297592, 23.8710761, -10.1051069)
39
1 FORMATdHO 9X *T EXCEEDS TC IN DENGASF. * / )
2 IF(TCRT-T) 3,4,5
3 PRINT 1 $ STOP
4 DENGASF = DCRT $ ZFX = 1 $ DDSDT = l.OE+100 $ RETURN
5 ZN = ZCRT-1 $ PC = PCRT $ P = PSATF{T)
0 PI = P/PC $ PIT = DPSDT/PC $ TC = TCRT
7 X = T/TC $ X2=X*X $ U - 1-X $ UE=U**EG $ UEl = -EG*UE/U
8 Y = Yl = 0 $ DO 10 K=1,NFG- $ L = K-1 $ XL = X**L
9 Y = Y + AV(K)*XL S Yl = Yl + AV{K)*L*XL/X
10 CONTINUE $ ZFX = F = 1 + UE*Y $ Fl = UE*Y1 + UE1*Y
15 ZCALC = ZSAT = Z = 1 + ZN*PI*F/X2
15 DZSDT = DZDT = PI*{ F1-2*F/X ) /TC + F*PIT)*ZN/X2
(
17 DENGASF = P/T/Z/GKK
18 DDSDT = (DPSDT - P/T - P*DZDT/Z) /T/Z/GKK $ RETURN $ END
FUNCTION DENLIQF(T)
PROPANE SAT. LIQUID DEM, MOL/L, {DCRT=5.00), RDG, FEB. 19, 1981.
DEN = DCRT + YNL*{X + {XE-X)*Y), YNL # DTRP - DCRT.
Y # Al + A2*X + A3*X2 + A4*X3.
C0MM0N/3/DPDT,D2PDT2, DPSDT, DPMDT,DPDD,DPDR,DTSDR,DTHDR, DDSDT
DIMENSION AW(3)
DATA (EL=0.35) ,(NFL=3)
DATA (TTRP=35.47) TCRT=369 .85
, { ) DCRT=5.00) ,{ DTRP=16 .63)
, (
0ATA(AW = 0.764389673, 0.009457047, -0.115001817)

1 FORMATdHO 9X *DENLIQF = 0, T EXCEEDS TCRT. * / )
'
2 IF(TCRT-T) 3,4,5
3 PRINT 1 $ STOP
4 DENLIQF = DCRT $ DDSDT = -l.OE+10 $ RETURN
5 XN=TCRT-TTRP $ X={ TCRT-T) /XN $ X2 = X*X $ DXDT = -1.0/XN
6 XE = X**EL $ U = XE - X $ Ul = EL*XE/X - 1
7Y1=Y=0 $ DO 9 K=1,NFL $ L = K-1 $ XL = X**L
8 Y = Y + AW{K)*XL S Yl = Yl + AW{K)*L*XL/X
9 CONTINUE $ YNL = DTRP - DCRT
11 DENLIQF = DCRT + YNL*{X + U*Y)
12 DDSDT = YNL*{1 + U*Y1 + U1*Y)*DXDT $ RETURN $ END
FUNCTION DIELF(D,T,P)
PROPANE CONSTS., RDG, MARCH 23, 1981, VIA HAYNES DATA.
CM,RMSPCT = 0.048, E,RMSPCT = 0.018.
CM = Al + A2*R + A3*R2 + A4*LN(1+B/X) + A5*PI.
DIMENSION A(5)
DATA (8=1.0) ,{DCRT=5.00) ,(TCRT=369.85)
DATA(A = 15.562631, 0.38581410, -0.15099771,
1 0.51074051, -0.0045141181)
1 R = D/DCRT $ X = T/TCRT $ G = AL0G(1+B/X) $ PI = P/100
2 CM = A(l) + A(2)*R + A(3)*R*R + A(4)*G + A(5)*PI
3 Z = CM*D/1000 $ DIELF = (2*Z+1 ) /{ 1 .0-Z)
5 RETURN $ END
FUNCTION EDELF(L,M,T,DA,DB)
GET CHANGE OF E, S, CV WITH DENSITY ALONG ISOTHERMS.
40
. .
C GET EOELF, DELS, DELCV FROM DA TO DB OM ISOTHERM T.

C ROMBERG NUMERICAL INTEGRATION VIA -
C CARNAHAN/LUTHER/WILKES, APPLIED NUMERICAL METHODS, P. 90,
C JOHN WILEY AND SONS, INC., N.Y., 1969.
C NOTE, VALUE OF LD CONTROLS CONVERGENCE LIMITS.
C NOTE, NMAX = M, NK = FINAL, TOTAL SUBDIVISIONS OF INTERVAL DX
C0MM0N/1/AL,RE,GA,DE,EP,F.T, DCRT,TCRT,PCRT, DGAT,DTRP,TTRP,PTRP
C0MM0N/3/DPDT ,D2PDT2 DPSDT DPMDT ,DPDD ,DPDR ,DTSDR ,DTHDR DDSDT
, , ,

C0MM0N/12/ZCRT,ZCALC,DZDT, ZSAT,DZSDT, ZFX, FRT,DFRTDT
DIMENSION E(20), S(20), C(20)
DATA (LD=2) ,(01=0.00001) ,(G=0. 083145)
1 F0RMAT{1H09X*EDELF L =*I2,5H, N =13, 5H, T = F8.3,6H, DA =E10.4,
1 6H, DB =E10.4, 6H, LD =12//
2 lOX IHN 7X5HEDELF 8X4HDELS 7X5HDELCV )
2 FORMATdHO 9X 6HEDIF =F10.3, 8H, SDIF =F10.5, 9H, CVDIF =F10.3)
3 F0RMAT(6X 15, F12.3, F12.5, F12.3)
4 FORMATdHO 9X *EDELF NG AT TCRT FOR CV AT DEN NEAR OR GT CP.*/)
C FOR DA=0 AND DB.LE.DI, IDEAL GAS, EDELF=DELS=DELCV=0
C FOR DA=0 AND DB.GT.DI, START ROMBERG WITH DA = DI, -
C TO AVOID INFINITIES IN ORDINATE FUNCTIONS AT DA = 0.
5 NK = 1 $ DM = DCRT/2 $ DZ = 0.98*DCRT
9 ZK = 1.0 - 1/ZCRT $ RK = 100*G*TCRT/DCRT
10 IF(L.EQ.O) 11,14
11 IF(DB.LE.DI) 12,13
12 EDELF = DELS = DELCV =0 $ RETURN
13 DA = DI
C GET FIRST TRAPEZOID AREA, E(l) ETC., FROM DA TO DB.
14 DX = DB - DA $ P = PVTF(T,DA,0) $ IF(DA.LT.DM) 16,17
16 EA = RK*(ZK*ZSAT*ZFX + FRT - T*DFRTDT) $ GO TO 18
17 EA = 100*(P-T*DPDT)/DA/DA
18 IF(L.EQ.O) 19,20
19 SA = -RK*DFRTDT $ GO TO 21
20 SA = -100*DPDT/DA/DA
21 CA = -100n*D2PDT2/DA/DA
22 P = PVTF(T,DB,0) $ IF{DB.LT.DM) 23,24
23 EB = RK*( ZK*ZSAT*ZFX + FRT - T*DFRTDT) $ GO TO 25
24 EB = 100*{P-T*DPDT)/DB/DB
25 IF(L.EQ.O) 26,27
26 SB = -RK*DFRTDT $ GO TO 28
27 SB = -100*DPDT/DB/DB
28 CB = -100n*D2PDT2/DB/DB
29 E{l)=(EA+EB)*DX/2 $ S(l)={SA+SB)*DX/2 $ C(l)=(CA+CB)*DX/2
C INTERVAL HALVING, GET E{N+1), ETC.
30 DO 60 N=1,M $ K = N + 1
31 JM = 2**N - 1 $ DXN = DX/2**N $ E(K) = S(!<) = C(K) = 0
33 DO 45 J=1,JM,2 $ NK = NK+1 $ DN = DA + J*DXN
34 P = PVTF(T,DN,0) $ IF(DN.LT.DM) 35,36
35 EB = RK*(ZK*ZSAT*ZFX + FRT - T*DFRTDT) $ GO TO 37
36 EB = 100*(P-T*DPDT)/DN/DN
37 IF(L.EQ.O) 38,39
38 SB = -RK*DFRTDT $ GO TO 40
39 SB = -100*DPDT/DN/DN
40 CB = -100n*D2PDT2/DN/DN
41
41 E{K) = E(K) + EB $ S(!<) = S(K) + SB $ C(K) = C(K) + CB
45 CONTINUE $ E{K) = E(N)/2 + E{K)*DXN
46 S(!<) = S(N)/2 + S(K)*DXIJ $ C(K) = C(N)/2 + C(K)*DXN
TEST FOR CONVERGENCE.

50 ED=ABS(E(K)-E(N)) $ SD=ABS(S(K)-S(N)) $ CD=ABS(C(K)-C(N))
53 IF(ED.LT.0.4/LD) 54,60
54 IF(SD.LT.0.002/LD) 55,60
55 IF(T.EO.TCRT.AND.DB.GT.DZ) GO TO 57
56 IF(CD.LT.0.04/LD) 57,60
57 EDELF = E(K) S DELS = S{K) $ DELCV = C(K) RETURN
60 CONTINUE $ N = M $ NM = N-1 $ NP = N+1
61 PRINT 1, L, N, T, DA, DB, LD
62 PRINT 3, NM,E(NM) ,S(NM) ,C(NM) PRINT 3, N,E(N),S(N),C(N)
64 PRINT 3, NP,E(NP) ,S(NP) ,C(NP) PRINT 2, ED, SD, CD
99 STOP $ END
FUNCTION FINDENF(T,P)
C ON ISOTHERM T, FIND DEN, MOL/L, TO MINIMIZE (P-PC) VIA EQNSTATE.
C0MM0N/1/AL,BE,GA,DE,EP,ET, DCRT ,TCRT ,PCRT, DGAT ,DTRP ,TTRP ,PTRP
DATA (GKK = 0.083145)
41 FORMATdHO 9X *FINDENF = 0, FAILS TO CONVERGE. * / )
42 FORMATdHO 9X *FINDENF = DCRT, DP/DR ZERO OR NEG. * / )
43 FORMATdHO 9X *FINDENF = 0, DOUBLE-VALUED AT P = PSAT. * / )
DM = 1.05*DTRP
IF(P.GT.O) 1,35
1 IF(T-TCRT) 2,5,8
2 DG=DENGASF(T) $ DL=DENLIQF(T) $ PS=PSATF(T) $ IF(P-PS) 3,32,4
3 D = DG/2 $ GO TO 11
4 0= {DL+DTRP)/2 $ GO TO 11
5 DG=DL=DCRT $ PS=PCRT $ IF(P-PS) 6,33,7
6 D = DCRT/2 $ GO TO 11
7 D = 2*DCRT $ GO TO 11
8 IF(T,LT. 450.0) 9,10
9 PC = PVTF{T,DCRT,0) $ IF{P-PC) 6,33,7
10 0 = DCRT
11 DO 30 J=l,50 S DP=P-PVTF{T,D,1) $ IF{ABS (DP/P)-1.0E-7) 31,31,12
12 IF(DPDD.GT.O) 13,34
13 DD = DP/DPDD $ IF{ABS DD/D)-1 .OE-7 31,31,14
( )
14 n = D + DD $ IF{D.GT.O.O) 16,15
15 D = P/GKK/T $ GO TO 30
.. 16 IF(D.GT.DM) 17,18
17 D = DM $ GO TO 30
18 IF(T-TCRT) 19,24,30
19 IF(P.LT.PS) 20,22
20 IF(D.GT.DG) 21,30
21 D = DG $ GO TO 30
22 IF(D.LT.DL) 23,30
23 D = DL $ GO TO 30
24 IF{P.LT.PCRT) 25,27
25 IF(D.LT.DCRT) 30,26
26 D = DCRT - 0.02 $ GO TO 30
42
27 IF{D.GT.DCRT) 30,28
28 OCRT + 0.02
D =
30 CONTINUE $ PRINT 41 $ STOP
31 FINDENF = D $ RETURN
32 PRINT 43 $ STOP
33 FIMDENF = DCRT $ RETURN
34 FINDENF = DCRT $ PRINT 42 $ RETURN
35 FINDENF=0PDT=D2PDT2=0 $ DPDD=GKK*T $ DPDR=DPDD*DTRP
36 RETURN $ END
FUNCTION FINDTMF{P)
C GIVEN P ON THE MELTING LINE, FIND T FOR PROPANE.
C0MM0N/1/AL,BE,GA,DE,EP,ET, DCRT,TCRT ,PCRT, DGAT ,DTRP ,TTRP ,PTRP
DATA (A=7180.0) ,(E=1.283)
1 X = (P-PTRP)/A + 1 $ FINDTMF = TTRP*X**(1 .0/E) $ RETURN $ END
FUNCTION FINDTSF(P)
C GIVEN VAPOR PRESSURE P, ITERATE T TO MINIMIZE (P-PC).
1 FORMATdHO 9X *FINDTSF = 0, FAILS TO CONVERGE. * / )
2 FORMATdHO 9X *FINDTSF = 0, P EXCEEDS PORT. * / )

3 IF(P-PCRT) 4,11,12
4 T = 300 $ DO 9 J=l,50 $ DP = P - PSATF(T) $ ADP = ABS (DP)
5 IF(ADP/P-l,0E-7) 10,6,6
6 IF(ADP/DPSDT/T-1.0E-7) 10,7,7
7 T = T + DP/DPSDT $ IF(T-TCRT) 9,9,8
8 T = TCRT
9 CONTINUE $ PRINT 1 $ STOP
10 FINDTSF = T $ RETURN
11 FINDTSF = TCRT $ RETURN
12 PRINT 2 $ STOP $ END
SUBROUTINE GENEOUS
C GIVEN P,T FOR THE HOMOGENEOUS DOMAIN -
C GET DEN AND FUNCTIONS AT ANY TEMPERATURE.
C0MM0N/3/DPDT,D2PDT2,DPSDT,DPMDT,DPDD,DPDR,DTSDR,DTHDR,D0SDT
COMMON/8/ IN, IK, P,T,0EN, E,H,S, CV,CP,CSAT, W,WK
DATA (0=1.01325) ,(G=0. 083145)
3 TI = T $ CALL IDEAL $ IF(P.GT.O) 4,10
4 DEN = DB = FINDENF{T,P) $ M=15 $ DA=L=0
5 E = EZZ + EZ + EnELF(L,M,T,DA,DB) $ H = E + 100*P/DB
6 S = SZ + DELS - 100*G*AL0G(G*T*DB/Q)
7 CV = CVZ + DELCV $ PX = PVTF(T,DB,1)
8 CP = CV + 100n/DPDD*(DPDT/DB)**2
9 W = SQRT(WK*CP*DPDD/CV) $ RETURN
10 DEN=S=0 $ E = EZZ + EZ $ H = E + 100*Gn $ CV=CVZ $ CP=CPZ
12 W = SQRT{WK*CP*G*T/CV) $ RETURN $ END
43
SUBROUTINE GENIUS
C VALID ONLY FOR THE HOMOGENEOUS [30MAIN.
C SAVES COMPUTER TIME WHEN TABULATING FUNCTIONS ALONG ISOBARS.
C SAVES D£N,E,S,CV ALONG ISOBARS FOR USE IN INTEGRATING TO NEXT
C HIGHER ISOBAR. VALID ONLY FOR MONOTONICALLY INCREASING ISOBAR
C PRESSURES, AND AT TEMPS. T = INTEGER MULTIPLES OF 10 K.
C0MM0N/3/DPDT,D2PDT;?,DPSDT,DPMDT,DPDD,DPDR,0TSDR,DTHDR,DDSDT
DIMENSION DK(70) ,EK(70) ,S:<(70) ,CK(70)
1 FORMATdHO 9X *GENIUS T NOT INTEGRAL. * / )
2 J = T/10 $ IF(T - 10*J) 3,4
3 CALL GENEOUS $ RETURN
4 IF(IK.EQ.IN) 5,9
5 CALL GENEOUS
6 OK(J) = DEN $ EK(J) = E $ SK(J) = S $ CK(J)=CV $ RETURN
C INTEGRATE FROM OLD DEN UP TO NEW DEN ON GIVEN ISOTHERM.
9 DA = DK(J) $ OK{J) = DEN = DB = FINDENF(T,P) $ N = 14
11 E1({J) = E = EK(J) + EDELF(1,N,T,DA,DB) $ H = E + 100*P/DB
13 SK{J) = S = SK(J) + DELS $ CK(J) = CV = CK{J) + DELCV
C NOW GET NEW DP/DT, DP/OD, CP, W.
15 PX = PVTF(T,DB,1) $ CP = CV + 100*T/DPDD*(DPDT/0B)**2
30 W = SQRT(lfK*C?*DPDD/CV) $ RETURN $ END
FUNCTION HSATF(T)
C PROPANE SATLIQ ENTHALPY, J/MOL.
C DEFINE YH # (H-HC) /( HT-HC), X # (TC-T)/{TC-TT) , WHEN -
C YH = X + (XE-X)*(A1 + A2*X + A3*X2 + . .)
.
DIMENSION AH(7)
DATA (NFH=7) ,(EH=0.37) ,(TTRP=85.47) ,(TCRT=369.85)
DATA (HTRP = 0.001),(HCRT = 33082.187)
DATA(AH = 0.2998573044, 0.3868586865, -0.6240978276,
1 1.036003301, -0.9494397054, 0.1462986734, 0.1113755135)
1 FORMATdHO 9X 3HT =F10.5, * IN HSATF{T).*/)

2 IF(T.GT.TCRT) 3,4
3 PRINT 1, T $ STOP
4 X = (TCRT-T)/(TCRT-TTRP) $ IF(X.LE.O) 5,5
5 HSATF = HCRT $ RETURN
5 V = X**EH -X $ FX=X $ DO 7 K=1,NFH
7 FX = FX + V*AH(K)*X**(K-1)
8 HSATF = HCRT - (HCRT-HTRP)*FX $ RETURN $ END
SUBROUTINE IDEAL
C PROPANE IDEAL GAS (1 ATM) THERMOFUNCTIONS VIA CHAO (1973).
C (HZ-HZZ)/RT = 4.0 + (A + B/Q + C/Q2 + D/X)*EXP(-E/X) , WHERE -
C X # T/lOO, Q # CUBERT(X).
COMMON/99/ TI, EZZ, EZ,SZ,CVZ, HZ,CPZ
DIMENSION A(6)
DATA (E=3.0) ,(R=8. 31434) ,(SI=32. 552)
DATA(A = 24.11012, 94.40550, -585.32814,
1 980.124065, -678.64094, 170.42778)
1 X=TI/100 $ Q=CUBERT(X) $ DQDX=Q/3/X $ XP=EXP(-E/X)
2 H = 4.0 $ SUM = SMI =0 S DO 7 K=l,6
44
. ) .
3 H = H + A(K)*XP*Q**(1-K) $ L = 4-K $ QL = Q**L

4 SUM = SUM + A(K)*QL $ SMI = SMI + A(K)*L*QL*DQDX/Q
7 CONTINUE $ CP = 4.0 + {E*SUM/X/X + SM1)*XP
C S = S(300) + INTEGRAL(CD/X)*DX FROM T=300 UP TO TI
10 N = ABS(TI-300)/4 +4 $ DX = (X-3)/N $ S = SI
12 DO 20 J=1,H $ X = 3.0 + (J-0.5)*DX $ Q = CUBERT{X)
14 DQDX = Q/3/X $ XP = EXP(-E/X) $ SUM = SMI = 0
15 DO 19 K=l,6 $ L=4-K $ QL= Q**L
16 SUM = SUM + A(K)*QL $ SMI = SMI + A(K )*L*QL*DQDX/Q
19 CONTINUE $ CPX = 4.0 + (E*SUM/X/X + SM1)*XP
20 S = S + CPX*DX/X
C CONVERT TO DIMENSIONED RESULTS, JOULES, MOLES, KELVINS.
22 CPZ = R*CP $ SZ = R*S $ HZ = R*TI*H
23 CVZ = CPZ - R $ EZ = HZ - Rni $ RETURN $ END
SUBROUTINE ISOTHRM
C PRINTOUT THE CRITICAL ISOTHERM.
C0MM0N/1/AL,BE,GA,DE,EP,ET, OCRT,TCRT,PCRT, DGAT,DTRP,TTRP,PTRP
C0MM0N/3/DPDT,n2PDT2,DPSDT,DPMDT,DPDD,DPDR,DTSDR,DTHDR,DDSDT
DATA (WM = 44.09721)
1 FORMATdHl 14X *THE CRITICAL ISOTHERM, PROPANE* //
1 6X6HTC,K = F7.2, 12H, DC,KG/M3 = F9.4, lOH, PC,MPA = F10.7/ 6X
2 *AT THE CP., DPS/DT =*F9.6, 9H, OP/DT =F9.6, * MPA/K.* //
3 6X4HD/DC 9X5HTS/TC 9X5HPS/PC 10X4HP/PC 9X5HDP/DR 4X6HDTS/DR
4 4X6H0TH/DR 4X6HDPS/DR 4X6HDXB/DR 4X6HDXC/DR )
2 F0RMAT(2X F8.3, 3F14.10, F14.9, 5F10.5)

3 PC = PVTF(TCRT,DCRT,0) $ PCS = PCRT/10 $ DCS = DCRT*WM
DPST = DPSDT/10 $ DPT = DPDT/10
4 PRINT 1, TCRT, DCS, PCS, DPST, DPT $ DO 8 J=l,41
5 DR = 0.895 + 0.005*J $ DN = DR*DCRT
6 PR = PVTF(TCRT,DN,1)/PCRT $ DPSDR = DPSDT*DTSDR
7 TSN = TSAT/TCRT $ PSN = PSAT/PCRT
DPDR = DPDR/10 $ DPSDR = DPSDR/10
8 PRINT 2, DR, TSN, PSN, PR, DPDR, DTSDR ,DTHDR DPSDR, DXBDR,DXEDR
,
9 RETURN $ END
SUBROUTINE JTLOCUS
C THE JOULE-THOMSON P-V-T LOCUS FOR PROPANE.
C DERIVE THE J-T INVERSION CURVE. USE ROUTINE DELTAF( T ,DI )
DIMENSION DK(60) ,DN{60) ,TT(60) ,PP(60)
DATA {A=2. 77755) ,( 8=0.60625) ,( TZ=500 .0) ,( WM=44 .09721
1 FORMATdHl 16X nHE JOULE-THOMSON INVERSION LOCUS FOR PROPANE* //
2 17X 3HT,K 8X2HDI 5X5HKG/M3 5X5HP,MPA
3 7X 3HT,K 8X2HDI 5X5HKG/M3 5X5HP,MPA )
2 FORMATCIOX 110, 2F10.1, F10.3, 110, 2F10.1, F10.3)
C SAVE INITIAL, TRIAL DENSITY, DK(I) = DI.
5 TA = 290 $ NP = 52
6 PRINT 1 $ DO 25 1=1, NP $ DX = 0.8
7 T = TA + 10*1 $ U = T/TZ S DK(I) = DI = EXP(A-B*U)
45
.
10 IF(T-TCRT) 11,12,12
11 iU = DENLIQFd) $ IF(DI.LT.DL) 23,12
12 SS =DELTAF(T,DI) $ DO 20 IT=1,14
14 D=DI-DX $ SL=DELTAF(T,D) $ D=DI+OX S SP=DELTAF(T,D)
15 IF(SS-SL) 18,16,16
16 IF(SP-SL) 19,17,17
17 SS = SL $ DI = DI - OX $ GO TO 20
18 IF(SS-SP) 20,20,19
19 SS = SP $ DI = DI DX
20 DX = DX/2 TT(I) T $ ON(I) = DI S ?P(I) = PVTF(T,DI,0)
21 GO TO 25
23 TT(I) = T DK(I) = DN{I) = PP(I) = 0
25 CONTINUE $ N = NP/2
26 DO 35 J=1,N $ K = J + N
27 IT = TT{J) S ITT = TT(K)
28 DKJ = WM*DK(J) $ DMJ = WM*DN{J)
29 DKK - WM*DK{K) $ DNK = WM*DN{K)
30 PPJ = PP{J)/10 $ PPK = PP(K)/10
35 PRINT 2 IT, DKJ,DNJ, PPJ, ITT, DKK, DNK, PPK
40 RETURN $ END
SUBROUTINE PEEK
EXAMINE BEHAVIOR OF THE PVT COEFFICIENTS,
B(S) # Bl + B2*S2, E(S) # El*( S-1)*(S-ER)*EXP(-GA*S**IX)
WHERE, R # DEN/DTRP, S # DEN/DCRT.
COMMON GK,GKK, Bl ,B2,B3,B4,B5, C1,C2,C3, E1,E2,E3, ER,IX
C0MM0N/1/AL,BE,GA,DE,EP,ET, DCRT,TCRT,PCRT, DGAT ,DTRP ,TTRP ,PTRP
DATA (WM = 44.09721) (EX = 1.10)
,
4 FORMATdHl 14X ÊQUATION OF STATE COEFFS., PROPANE * //

1 15X 6HTTRP =F7.3, 8H, TBLP =F9.4, 8H, TCRT =F8.3, * K* /
2 15X 6HPTRP =E12.6, 8H, PBLP =F8.6, 8H, PORT =F9.6, * MPA* /
3 15X 6HDTRP =E11.5, 8H, DLBP =E11.5, 8H, DCRT =E11.5, * KG/M3* /
3 15X 6HDGAT =E11.5, 8H, DGBP =E11.5, * KG/M3* /
3 15X *DPS/DTB,MPA/K =* Ell. 5, QVAPB,KJ/MOL =* F7.3//
4 15X 4HIX =12, 6H, EX =F5.2, 6H, ER =F5.2, *, S # DEN/DCRT* /
5 15X 4HAL =F10.7, 6H, BE =F10.7, 6H, GA =F10.7/
6 15X 4HDE =F10,7, 6H, EP =F10.7, 6H, ET =F10.7//
7 15X 4HB1 =F14.11, 6H, B2 =F14.11, 6H, B3 =F14.11/
8 15X 4HC1 =F14.11, 6H, C2 =F14.11, 6H, C3 =F14.11/ )
5 FORMATdSX 4HD/DC 6X4HTSAT 5X5HTHETA 4X6HPS,MPA 9X1HB 9X1HC )
6 F0RMAT(9X F10.2, 2F10.3, F10.4, 2F10.5)

8 TB=FINDTSF(1. 01325) $ DGB=DENGASF( TB) $ DLB=DENLIQF( TB)
9 QB = TB*DPSDT*(1/DGB - 1/DLB)/10.0
PTR = PTRP/10 $ PBLP = 0.101325 $ PCR = PCRT/10
DTR = DTRP*WM $ OLBI = DLB*WM $ OCR = DCRT*WM
DGA = DGAT*WM $ DGBI = DGB*WM $ DPSB = DPSDT/10
10 PRINT 4, TTRP,TB, TCRT, PTR, PBLP, PCR, DTR, DLBI,DCR, DGA, DGBI, DPSB, QB,
1 IX,EX,ER, AL,BE,GA,DE,EP,ET, B1,B2,B3, E1,E2,E3
11 PRINT 5 $ N = 10*DTRP/DCRT + 1
12 DO 20 J=1,N $ S = 0.1*J
13 DN = S*DCRT $ S2=S*S $ SN=S-1 $ SX = S**IX
46
)
14 SR = 1 $IF(ER.GT.O) SR = S-ER
16 B = Bl + B2*S2
17 E = (El + E2*S)*SN*5R*EXP(-GA*SX)
19 TSAT=TS=TSATF{ON) $ TH=THETAF{ DN) $ PS=PSATF(TS) $ PIS=PS/10
20 PRINT 6, S, TS,TH,PIS, B,E $ RETURN $ END
FUNCTION PMELTF(T)
C PROPANE MELTING LINE, BAR, VIA REEVES, SCOTT, AND BABB(JR),
C J. CHEM. PHYS. 40(12), 3662 (1964).
DATA (A = 7180.0) ,(E = 1.283)
1 X = T/TTRP $ XE = X**E $ PMELTF = PTRP + A*(XE-1)
2 DPMDT = A*E*XE/X/TTRP $ RETURN $ END
FUNCTION PSATF(T)
C PROPANE VAPOR PRESSURE, BAR, RDG, FEB. 19, 1981. (DCRT=5.00).
C LN{P) = Pl/X + P2 + P3*X + P4*X2 + P5*X3 + P6*(1-X)**EPP.
C0MM0N/3/DPDT,D2PDT2,DPSDT,DPMDT,DPDD,DPDR,DTSDR,DTHDR,D0SDT
DIMENSION PJ(6)
DATA (EPP = 1.35)
DATA TTRP=85 .47 ) TCRT=369 .85 ) DCRT=5 .00) DTRP=16 .63
( , ( , ( , (
DATA(PJ = -8.722780250, 19.203078280, -15.610638913,

1 12.685790059, -3.806542924, 1.883214505)
1 FORMATdHO 9X *T ABOVE TCRT IN PSATF(T). * / )
4 X = T/TCRT $ V = 1.0 - X $ IF(V) 7,8,9
7 PRINT 1 $ STOP
8 Z = Zl = 0 $ GO TO 10
9 Z = V**EPP $ Zl = -EPP*Z/V
10 PL = PJ(6)*Z $ PLl = PJ(6)*Z1
11 DO 13 K=l,5 $ L = K-2 $ XL = X**L
12 PL = PL + PJ(K)*XL $ PLl = PLl + PJ(K)*L*XL/X
13 CONTINUE $ PSATF = EXP(PL)
15 DPSDT = PL1*PSATF/TCRT $ RETURN $ END
SUBROUTINE PVTDATA
C PROPANE EOS CONSTANTS, RDG/NBS, FEB. 19, 1981. (DCRT=5.00).
COMMON GK,GKK, Bl ,B2 ,B3 ,B4 ,B5 C1,C2,C3, E1,E2,E3, ER, IX
,
C0MM0N/1/AL,BE,GA,DE,EP,ET, DCRT, TCRT, PORT, DGAT, DTRP,TTRP, PTRP

C0MM0N/12/ZCRT,ZCALC,DZDT, ZSAT,DZSDT, ZFX, FRT,DFRTDT
10 WM = 44.09721 $ TTRP = 85.47 $ TCRT = 369.85
12 DCRT = 5.000 $ DTRP = 16.630
13 PTRP = PSATF(TTRP) $ PORT = PSATF(TCRT)
20 GKK = 0.083145 $ GK = GKK*DCRT $ ZCRT = PCRT/DCRT/GKK/TCRT
21 IX = 2 $ AL = 1.0 $ BE = 0.7 $ GA = 0.15 $ DE = 0
22 EP = 0 $ ER = 2.20 $ ET = 1.1
23 Bl = 0.45650524198 $ B2 = 0.15822653715
24 El =-0.24904576736 $ B3=B4=E2=E3=0
25 DGAT = DENGASF(TTRP) $ WK = 100000/WM $ EZZ = 21888.910
47
.
99 RETURN $ END
FUNCTION PVTF(T,D,M)
PROPANE EQNSTATE, PVTF = P,BAR. SIMPLIFIED, FEB. 12, 1931.
NOTE, M=0 RETURNS DP/DT, D2P/DT2. n=l RETURNS ALSO DP/DD.
P-PSAT = S*GK*(T-TSAT) + S*S*GK*TCRT*F( S ,T) , WHERE -
F{S,T) # B(S)*XBF(S,T) + £( S)*XEF( S ,T) , AND -
B(S) # Bl + B2*S2, E{S) # El*( S-1 )*{ S-ER)*EXP( -GA*S**IX)

WHERE, R # DEN/DTRP, S # DEN/DCRT.
COMMON GK,GKK, Bl ,B2,B3,B4,B5 C1,C2,C3, E1,E2,E3, ER,IX
,

C0MM0N/3/DP0T,D2PDT2,0PSDT,DPMDT,DPDD,DPDR,DTSDR,DTHDR,DDS0T
C0MM0N/4/XBl,XB2, XC1,XC2, XE1,XE2, DXBDR ,DXCDR ,DXEDR
C0MM0N/12/ZCRT,ZCALC,0ZDT, ZSAT,DZSDT,ZFX FRT,DFRTDT
,
1 S = 0/DCRT $ S2=S*S $ SN=S-1 $ SR=S-ER $ SX=S**IX

5 GK = DCRT*Gi<K $ TC = TCRT $ DSDR = DTRP/DCRT
6 RG = S*GK $ GKT = GK*TC
7 TSAT=TS=TSATF{D) $ PSAT=PS=PSATF( TS) $ THETA=THETAF(D)
8 XB = XBF(T,D) $ XE = XEF{T,D)
9 B = B1*S2 + B2*S2*S2
10 XP = EXP(-GA*SX) $ SM = S2*SN*SR $ E = E1*SM*XP
12 F = B*XB + E*XE $ Fl = B*XB1 + E*XE1 $ F2 = B*XB2 + E*XE2
13 PVTF = PS + RG*(T-TS) + GKT*F $ FRT=F/S2 $ DFRT0T=F1/S2/TC
14 DPDT = RG + G!<*F1 $ D2PDT2 = GK*F2/TC $ IF(M) 15,30
15 BD = (2*B1 + 4*B2*S2)*S*DSDR
16 XPl = -IX*GA*SX/S $ SMI = (SN+SR)*S2 + 2*S*SN*SR
18 ED = E1*(SM*XP1 + SM1)*XP*DSDR
20 Fl = B*DXBDR + BD*XB + E*DXEDR + ED*XE
26 DPDR = {DPSDT"RG)*DTSDR + (T-TS)*GK*DSDR + GI<T*F1
27 DPDD = DPDR/DTRP
30 RETURN $ END
FUNCTION QVAPXF{T)
PROPANE QVAP, J/MOL, RDG/NBS, FEB. 20, 1981.
QVAP = A1*X + (XE-X)*(A2 + A3*X + A4*X2 + . ). .
X # {TC-T)/(TC-TT), XE # X**E.
DIMENSION AQ(4)
DATA (NFQ=4) ,(EQ=0.38) ,(TTRP=85.47) ,(TCRT=369.85)
DATA(AQ = 24.840848, 24.166535, 6.252384, -12.156857)
1 FORMATdHO 9X *1 EXCEEDS TCRT IN QVAPXF(T). * / )
2 IF(TCRT-T) 3,4,5
3 PRINT 1 $ STOP
4 QVAPXF = 0 $ RETURN
5 XN = TCRT - TTRP $ X = (TCRT-T)/XN $ XE = X**EQ
6 F = 0 $ DO 7 K=2,NFQ
7 F = F + AQ(K)*X**{K-2) $ Q = AQ(1)*X + (XE-X)*F
10 QVAPXF = g*1000 $ RETURN $ END
SUBROUTINE SIMPLE
FOR ANY GIVEN T,K AND P,MPA, CONVERT TO P,BAR, AND USE SUBROUTINE
48
.
C THERMO (OR ENTRIES THEREIM) TO GET THERMOPHYSICAL PROPERTIES.

C THEN CONVERT TO MPA, AND KG/M3 IN PRESENT ROUTINE.
C0MM0N/3/DPDT,D2PDT2,DPSDT,DPMDT, DPDD ,DPDR ,DTSDR,DTHDR,DDSnT
DATA (R=0. 083145) ,(GJ=8. 3145) ,(PA=1. 01325) ,(WM=44. 09721)
14 FORMATdHl 18X *TEST OF THERMO AT P,MPA =* F8.5/
1 19X ^DENSITIES KG/M3, HEATS J/MOL. * / )
16 F0RMAT{6X4HPMPA 9X1HT 6X3HDEN 8X1HZ 5X5HDP/DT 5X5HDP/DD
1 8X1HE 8X1HH 8X1HS 6X2HCV 6X2HCP 5X1HW 9X3HF/P 5X4HDIEL )
17 FORMATdX F9.4, F10.3, F9.2, F9.5, F10.5, F10.6, 2F9.1, F9.3,

1 2F8.2, 16, E12.5, F9.5)
C LET US EXAMINE A SUBCRITICAL ISOBAR.
19 PMPA = 3.5
20 P = 10*PMPA $ PRINT 14, PMPA $ PRINT 16
21 DO 90 J=l,39 $ TIK = T = 110 + 10*J
22 CALL THERMO $ IW = W $ Z = P/OEN/R/T
C GET DIEL. CONST., AND FUGACITIES.
25 GIB = H-EZZ-HZ -T*{S-SZ) $ FOP = EXP(GIB/GJ/T)'*^PA/P
26 IF(T.GT.450) 27,28
27 DIE = 0 $ GO TO 30
C CONVERT PRESSURES, DENSITIES, AND DERIVATIVES.
30 PMPA=P/10 $ DEN=DEN*WM $ DPDT=DPDT/10 $ DPDD=DPDD/10/WM
31 DPMDT = DPMDT/10 $ DPSDT = DPSDT/10 $ DDSDT = DDSDT*WM
40 PRINT 17, PMPA, T, DEN, Z, DPDT,DP0D, E,H,S, CV,CP,IW, FOP, DIE
90 CONTINUE $ RETURN $ END
FUNCTION SSATF(T)
C PROPANE SATLIQ ENTROPY, J/MOL/K.
C CONSTRAINED AT TRIPLE AND CRITICAL POINTS.
C Y # (S-SCRT)/(STRP-SCRT), X # (TC-T)/( TC-TT)
C Y = X + (XE-X)*(A1 + A2*X + A3*X2 + . ).. .
DIMENSION AS(8)
DATA (NFS=8) ,(ES=0.32) ,( TTRP=85.47) TCRT=369 .85)
, (
DATA (STRP = 82.56147) (SORT = 234.72617)

,
DATA(AS = 0.1263077082, -0.7539546213, 1.253270427, -5.96961033,

1 14.0277688, -20.62894506, 16.01178434, -5.411082748)
1 FORMATdHO 9X 3HT =F10.5, * IN SSATF(T). * / )
2 IF(TCRT-T) 3,4,5
3 PRINT 1, T $ STOP
4 SSATF = SORT $ RETURN
5 YN = STRP-SCRT $ XN = TCRT-TTRP
. 6 X = (TCRT-T)/XN $ XE = X**ES $ V = XE - X
7 Y = X $ DO 8 K=1,NFS
8 Y = Y + V*AS(K)*X**{K-1)
9 SSATF = SORT + YN*Y $ RETURN $ END
SUBROUTINE TABLIQ
C0MM0N/1/AL,BE,GA,DE,EP,ET, DCRT,TCRT,PCRT, DGAT,DTRP ,TTRP ,PTRP
C0MM0N/3/DPDT,D2PDT2, DPSDT, DPMDT, DPDD, DPDR,DTSDR,DTHDR, DDSDT
49
COMKiON/8/ IN, IK, P,T,DEN, F.,H,S, CV,CP,CSAT, W,WK
C0MM0N/9/DNG,EG,HG,SG, CVG,CPG,WG, DPGDT,DPGDD
C0MM0M/12/ZCRT,ZCALC,DZDT, ZSAT,DZSDT,ZFX FRT,DFRTDT
,

DIHEMSION DSA(60) ,TSA(60) ,PSA(60) ,DLT(60) ,DPT(60) ,DP0(60)
DATA G=0. 083145) ,(WM=44. 09721)
(
-.4 FORMATdHl 13X ^PROPERTIES OF SATURATED LIQUID PROPANE* //

1 14X IHT IIXIHP 3X5HDEN,L 7X5HDEN,G 5X3HZ,L 5X3HZ,G
5X6HDPS/DT 3X6HDDL/DT 3X5HDP/DT 6X5HDP/DD /
?.
3 14X IHK 9X3HMPA 3X5HKG/M3 7X5HKG/M3 16X

4 5X5HMPA/K 2X7HKG/M3/K 3X5HMPA/K 2X9HMPA-M3/KG )
5 F0RMAT{5XF10.3, E12.5, F8.2, E12.5, 2F8.5, E11.4,F9.4,F8.4,E11 .4)

11 FORMATdHl 13X ^PROPERTIES OF SATURATED LIQUID PROPANE * //
1 14X IHT 4X5HQ,VAP 8X1HE 8X1HH 8X1HS
2 6X2HCV 6X2HCS 6X2HCP 6X3HF/P 6X1HW 4X5HDIEL. /

3 14X IHK 4X5HJ/M0L 4X5HJ/M0L 4X5HJ/M0L 2X7HJ/M0L/K
4 1X7HJ/M0L/K 1X7HJ/M0L/K 1X7HJ/MQL/K IIX 5HM/SEC 4X5HC0NST )
12 F0RMAT(5X F10.3, 3F9.1, F9.3, 3F8.2, F9.5, 17, F9.5)

C FOR PAGE ONE OF TABLIQ.
C REPLACE T = 230 BY B.P. AT J = 30.
120 NP = 58 $ PRINT 4
121 DO 150 J=1,NP $ IF(J.EQ.l) 122,123
122 T = TTRP $ GO TO 139
123 IF(J.EQ.30) 124,125
124 T = FIN0TSF( 1.01325) $ GO TO 139
125 IF(J.EQ.NP) 126,128
126 T = TCRT $ DSA(J)=DG=DL=DCRT $ DLT{J) = DDLDT = 0
127 VG = VL = 1.0/DCRT $ ZG = ZCRT $ GO TO 141
128 T = 80 + 5*J
139 DSA(J) = DL = DENLIQF(T) $ DLT(J) = DDLDT = DDSDT
140 DG = DENGASF(T) $ ZG = ZSAT $ VG = 1/DG $ VL = 1/DL
141 TSA(J) = T $ PX = PVTF(T,DL,1) $ DPT(J)=DPDT $ DPD{J)=DPDD
147 PSA(J) = PS = PSAT $ Z = PS/DL/G/T
148 PS=PS/10 $ DPSDT=DPSDT/10 $ DPDT=DPDT/10 $ DPDD=DPD0/10
149 DL=DL*WM $ DG=DG*WM $ DDLDT=DDLDT*WM $ DPDD = DPDD/WM
150 PRINT 5, T,PS, DL,DG, Z,ZG, DPSDT, DDLDT, DPDT,DPDD
C PAGE 2, TABLIQ. AVOID COEXIST, TIMESAVER.
C USE COEXIST AT ALL TEMPERATURES.
150 PRINT 11 $ DO 180 J=1,NP $ T = TSA(J) $ P = PSA(J)
161 CALL COEXIST $ DL = DEN $ IV/ = W
162 DIEL = DIELF{DL,T,P) $ QX = QVAPXF(T)

C GET FUGACITY COEF., (F/P), VIA HZ, SZ, HG, SG.
C NOTE, 01 = 0.00001 MOL/L IN EDELF.
170 GIBS = HG-EZZ-HZ - T*(SG-SZ)
171 GJ = 100*G $ XP = EXP(GIBS/GJ/T) $ FOP = XPn.01325/P
172 IF(DNG.LE. 0.00001) FOP = 1.0
180 PRINT 12, T,QX, E,H,S, CV,CSAT,CP, FOP, IW, DIEL
999 RETURN $ END
SUBROUTINE THERMO
C FOR COMPUTATION AT ANY (T,P) POINT.
c ASSUMES AN ISOTHERM IH SINGLE-PHASE ONLY.
c CASES FOR ISOTHERMS BELOW, EQ., ABOVE TCRT.
50
C GIVEN (T,P), RETURNS DEN, E,H,S, CV,CP,W, DPDT, DPOD.
C ENTRIES BELOW FOR PHASE BOUNDARIES ASSUME A GIVEN ISOBAR P, OR -
C ENTRIES BELOW FOR PHASE BOUNDARIES ASSUME A GIVEN ISOTHERM, T.
COMMON/l/AL ,BE ,GA,nE ,EP ,ET, DCRT TCRT ,PCRT, DGAT ,DTRP ,TTRP ,PTRP
,
C0MM0H/3/DPDT,D2PDT2,DPSDT,DPMDT,DPDD,DPDR,DTSDR,DTHDR,DDSDT
COMMON/8/ IN, IK, P,T,DEN, E,H,S, CV,CP,CSAT. W,WK
COMMOH/9/ ONG,EG,HG,SG, CVG,CPG,WG, OPGDT,DPGDD
1 FORMAT! IHO 9X ^THERMO, P.GE.PMELT. * / )
2 FORMATdHO 9X *THERMO DOUBLE-VALUED AT P = PSAT. * / )

3 FORMATdHO 9X *THERMO, DEN GE. DCRT AT T = TCRT. * / )
10 IF{T-TCRT) 11,20,25
C SUBCRITICAL ISOTHERMS.
11 PM = PMELTF(T) $ IF(P.GE.PM) 12,13
12 PRINT 1 $ CALL COMPRLQ $ TI=T $ CALL IDEAL $ RETURN
13 PS = PSATF(T) $ IF(P-PS) 14,15,16
15 PRINT 2 $ RETURN
16 CALL COMPRLQ $ TI = T $ CALL IDEAL $ RETURN
C THE CRITICAL ISOTHERM.
20 CALL GENEOUS $ IF(DEN.LT.DCRT) RETURN
21 CP = CV = W = 0 $ PRINT 3 $ RETURN
C ISOTHERMS AT T ABOVE TCRT.
C THERMOM FOR GIVEN ISOBAR AT THE MELTING LINE, GET T.
C RETURNS T,DEN, E,H,S, CV,CP,W, DPMDT,DPDT,DPDD.
ENTRY THERMOM
40 T = FINDTMF(P) $ PM = PMELTF(T) $ CALL COMPRLQ
41 TI = T $ CALL IDEAL $ RETURN
C THERMOL FOR GIVEN ISOBAR AT SATURATED LIQUID LINE, GET T.
C RETURNS T,DEN, E,H,S, CV ,CP ,CSAT ,W, DPSDT,DDSDT, DPDT,DPDD.
ENTRY THERMOL
43 T = FINDTSF{P) $ CALL COEXIST $ RETURN
C THERMOV FOR GIVEN ISOBAR AT THE SATURATED VAPOR LINE, GET T.
C RETURNS T,DEN, E,H,S, CV,CP,W, DPSDT,DDSDT, DPDT,DPDD.
ENTRY THERMOV
45 T = FINDTSF(P) $ CALL COEXIST $ DEN=DNG $ E=EG $ H=HG $ S=SG
47 CV=CVG $ CP=CPG $ W=WG $ DPDT=DPGDT $ DPDD=DPGDD $ RETURN
C THRMM FOR ISOTHERM AT THE MELTING LINE, GET P.
C RETURNS P,DEN, E,H,S, CV,CP,W, DPMDT, DPDT, DPDD.
ENTRY THRMM
50 P = PMELTF(T) $ CALL COMPRLQ $ TI=T $ CALL IDEAL $ RETURN
C THRML FOR ISOTHERM AT SAT. LIQ. LINE, GET P.
C RETURNS P,DEN, E,H,S, CV,CP,CSAT,W, DPSDT,DDSDT, DPDT, DPDD.
ENTRY THRML
55 P = PSATF(T) $ CALL COEXIST $ RETURN
C THRMV FOR ISOTHERM AT SAT. VAPOR LINE, GET P.
C RETURNS P,DEN, E,H,S, CV,CP,W, DPSDT,DDSDT, DPDT, DPDD
ENTRY THRMV
60 P = PSATF{T) $ CALL COEXIST
61 DEN=DNG $ E=EG $ H=HG $ S=SG $ CV=CVG
62 CP=CPG $ W=WG $ DPDT=DPGDT $ DPDD=DPGDD
99 RETURN $ END
51
.
FUNCTION THETAF(DEN)
THETA = TSAT*EXP(U(S))
LET Q = {S-1)/(ST-1) WHERE ST = OTRP/OCRT,
, THEN -
IF S < 1, U = AL*Q**3, IF S > 1, U = -AL*Q**3,
C0MM0N/1/AL,BE,GA,DE,EP,ET, OCRT,TCRT,PCRT, DGAT,DTRP,TTRP,PTRP
C0MM0N/3/DPDT,02PDT2,0PSDT,DPMDT,DPDD,DPDR,DTSDR,DTHDR,DDSDT
1 S = DEN/DCRT $ DSOR = DTRP/DCRT $ C = DSOR-1
2 Q = (S-l)/C $ Q2 = Q*Q $ U = AL*Q*Q2
3 Ul = AL*3*Q2*DS0R/C $ IF(Q) 5,9,4
4 U = -U $ Ul = -Ul
5 XP = EXP(U) $ THETAF = TSAT*XP
6 DTHDR = (TSAT*U1 + DTSDR)*XP $ RETURN
9 THETAF = TCRT $ DTHDR =0 $ RETURN $ END
FUNCTION TSATF(DEN)
ITERATE T TO MINIMIZE (DEN-DCALC) VIA DENGASF(T), DENLIQF(T).
IF ITERATION FAILS, PRINTOUT ONCE ONLY AND STOP AT K = 2.
C0MM0N/3/DPDT,02PDT2,DPSDT,DPMDT,DPDD,DPDR,DTSDR, DTHDR, DOSDT
DATA (0=2. 0),(FN=6. 3890561)
NOTE, FN # EXP{Q) - 1.0.
1 FORMATdHl 14X *TSATF(DEN) FAILS AT DEN =* E15.7//
1 15X 5HDCALC 13X2HDD 10X5HDDSDT 13X2HDT 12X3HT,K )
2 F0RMAT(5X 5E15.7)
3 K = 0 $ D = DEN
4 S = D/DCRT $ YN = TCRT/TTRP-1 $ IF(D-DCRT) 5,30,6
5 ST=DGAT/DCRT $ F=AL0G( S)/ALOG( ST)*{ 1-S) /( 1-ST) )**2 $ GO TO 7
(
6 ST=DTRP/DCRT $ U={ S-1 /( ST-1 ) )**3 $ F=(EXP(Q*U)-1)/FN

( )
7 T = TCRT/(YN*F+1)
8 DO 20 J=l,50 $ IF{D-DCRT) 9,30,10
9 DC = DENGASF(T) $ GO TO 11
10 DC = DENLIQF(T)
11 DD = D - DC $ IF(ABS(DD/D) .LT.l.OE-7) 25,12
12 DT = DD/DDSDT $ IF( ABS{DT/T) .LT.l .OE-7) 25,13
13 T = T + DT $ IF(T) 14,14,15
14 T = TTRP $ GO TO 18
15 IF{T.LT.TCRT) 18,16
16 T = TCRT - 0.05
18 IF(K.EQ.l) PRINT 2, DC, DD, DDSDT, DT, T
20 CONTINUE $ K = K+1 $ IF{K.NE.l) STOP
21 PRINT 1, DEN $ GO TO 4
25 TSATF = T $ DTSDR = DTRP/DDSDT $ RETURN
30 TSATF = TCRT $ DTSDR = 0 $ RETURN $ END
FUNCTION XBF(T,D)
XBF(R,T) # (X**BE)*EXP{A*(1-TS/T)) - XS**BE, WHERE -
X # T/TC, XS # TS/TC, A # (1-BE) + SQRT(l-BE),
X3F = U*EXP(A*V) - US, U # X**B, US # XS**B, V # (1-TS/T).
C0MM0N/3/DPDT,D2PDT2,DPSDT,DPMDT,DPDD,DPDR, DTSDR, DTHDR, DDSDT
52
1 B = BE $ BN = 1-B $ A = BN + SQRT{BN)
2 TC=TCRT $ TS=TSAT $ X=T/TC $ XS=TS/TC $ XS1=DTSDR/TC
3 U = X**B $ Ul = B*U/X $ U2 = -BN*U1/X
4 US = XS**B $ USl = B*US*XS1/XS
5 V = 1-TS/T $ VIR = -DTSDR/T $ VIX = TS/T/X $ V2X = -2*V1X/X
6 P = EXP(A*V) $ PI = A*P $ P2 = A*P1
7 PIR = P1*V1R $ PIX = P1*V1X $ P2X = P1*V2X + P2*V1X*V1X
8 XBF = U*P - US $ XBl = U*P1X + U1*P
9 XB2 = U*P2X + 2*U1*P1X + U2*P $ DXBDR = U*P1R - USl
10 RETURN $ END
FUNCTION XEF(T,D)
C ULTRA REVISION, MARCH 29, 1981.
C XEF = H(R,T)/HS(R) - 1.0,
C H{R,T) # 1 - (W-WE/E)/(1-1/E), E = ET.
C X#T/TC, F#TS/T, W#(1-TH/T), WE#W**E
C A = DE B = 1-A C = EP E = ET.
C0MM0N/1/AL,BE,GA,DE,EP,ET, DCRT,TCRT,PCRT, DGAT,DTRP,TTRP,PTRP
C0MM0N/4/XBl,XB2, XC1,XC2, XE1,XE2, DXBDR, DXCDR,DXEDR
E = ET $ EK = E/(E-1) $ TC = TCRT
TS = TSAT $ TH = THETA $ X = T/TC
W = 1.0 - TH/T $ IF(W) 30,30,4
CONTINUE
WIR = -DTHDR/T $ WIX = TH/T/X $ W2X = -2*W1X/X
WE = W**E $ WEI = E*WE/W $ WEIR = WEI^WIR
7 WEIX = WE1*W1X $ WE2X = WE1*W2X + (E-1)*WE1*W1X*W1X/W
8 H = 1 - EK*(W-WE/E) $ HIR = -EK*(W1R-WE1R/E)
9 HIX = -EK*(W1X-WE1X/E) $ H2X = -EK*(W2X-WE2X/E)
10 WS = 1.0 - TH/TS $ IF(WS) 11,11,12
11 HS = 1 $ HSl = 0 $ GO TO 16
12 WSl = (TH*DTSDR/TS - DTHDR)/TS
13 WSE = WS**E $ WSEl = E*WSE*WS1/WS
14 HS = 1 - EK*(WS-WSE/E) $ HSl = -EK*( WSl-WSEl/E)
16 U = 1.0/HS $ UlR = -U*HS1/HS
17 P = H*U $ DXEDR = H*U1R + H1R*U
18 XEl = H1X*U $ XE2 = H2X*U $ XEF = P - 1 $ RETURN
30 XEF = XEl = XE2 = DXEDR =0 $ RETURN $ END
53
ooooooooo
oooooooo
54
Table 1. Comparisons of vapor pressure data with eq (2).
Data sources and ID numbers: (l)Tickner, (2)Carruth, (3)Maass, (4)Dana, (e))Saqe, 7 ) Beatt e.i
(9) Kemp, (11 )Deschner, (12)Reamer, ( 13)Cherney, (14)C egg, ( 7)Helgeson , 19)611 1 ( 1 i 1 and
(20)Burrel (25)Thomas, (30)Mousa, (35)Kratzke, (78)Teichmann, (80)Therma Loop s
1
1 D We ight Temp. T/Tc Pa(expt) Pa(oalc) Oiff. dPa/dT

K MPa MPa % MPa/K
80 .053 OP. 4 /(J
O T AA 1
.
ItZOAOC
1
AA
6808t-09 .
IÔACI" AA
689DE-09
1 -. 52 .688E-1
80 .059 yu.uuu •z43j4 A A "70 n
.96721 AA
b-09 1 A occ AA
^'
.958D5t-09 r"
-. 14 .353E-09
80 .066 95.000 .25686 .54 72E-08 1 .54 Z3E-08 1 . 09?
u . 176E-08
80 .073 1 00 .000 .27038 .25 185E-07 .25 139E-07 1 ft . 730E-08

A C AAA .28390 AAOA~7C~ A "7 AAÂTI" AT ?n
80 .081 1
.9989 /t-07 .99697E-07 . Au .260E-07
80 .088 t
1
1
ouo
1u • AAA
A O A*7/4Z
.zy O yl A CnAC AtT
~Z
.3451 E-06 1 . 17 .814E-07
lie AAA lAÎOC AC
80 .097 .J uy4 1 . 051oE-0d . 1 3 .227E-06
80 .105 1OA AAA . jz44d
OACA^tr ACT
•Z9504L-05 OA/IOICT
. 2948
AC
E-05 1 .08 .574E-06
80 .1 14 1O AAA Z"Z7n7
.3j /y / T/C'Z'ZC AC ~7>10AyiC" AC
.74804t-05 .04 . 133E-05
80 .124 1 AAAA
"Z. zc A 1 yt
. 1 7534 E-04 .00 .286E-05
C AAA T^ CA1
80 .133 1
.38308L-04 .38316E-04 -.02 .574E-05
A AAA
80 . 143 140.000
1 >1
.37853 , 78644t-04 .IQol E-04 1 . 09E-04
1
80 .154 14D.U(JU .39205 . Dz74 L-03

1 .
ICOTAH
15279E-03 AT -.04 .195E-04
c:n Ann 9Q99ACr A'Z 009"Zi::C AZ
80 .164 1
15U. UUU •4U DD .ZOZ3DE-U3 -.03 .334E-04
AO ylAOOAC C\X A no A7C AT
80 .176 1DP . UUU .4 Q
yuy
<1 1
1 o4yooOt--UD .4yoy /E-U3 -. 02 .547E-04
80 . 187 1
1 uU. nnn
An UUU .4j)Zfc) 1 •
Q/1 AO C A'Z
o4Dy t-Uj 1
I
OA 7AAF A'Z
. 04 /UUt-Uj -.01 .865E-04
80 .199 1
1 OJ nnn
R . UUU .440 J 1 . JODDt-UZ
1 .
1
1
"^QA/ F A9
JO04t-UZ .00 . 132E-03
on QTyl R/i Q nr n9 F A9
9 .202 1
1DD
f^f^
. yu 1
1 .44yj4
yt yj
. D4oUt-UZ
1
1 .
1
DD 9
1
c^ c: 1
Zt-UZ 1 -.21 . 145E-03
80 .21 1
i7n
1
nnn
/ U. UUU .4 DyOD 91QAXC
. z yODt— n9
1 uz 9 Q ROF n9
• z lyDyt-uz
1
.02 .195E-03
A AO A9 90T'^nP A9 9Q'^nQF n9 .249E-03
9 .220 1 /-). J^:U .4DODZ .zy_)_)Ut-uz . zyjuot-uz .08
80 .224 17R
1
nnn
/ -).UUU yl7'^ 1 A ';'^7A'iF_n9
.J J / ODt— UZ '^^7RAF n9
. J> J / DO t— UZ .02 .281E-03
9 .236 17Q Pj19 .
O
HODZU
/I 4QRRnF-n9
.^yoDuc-uz . 4Qft7RF-n9
Hy O / O u— UZ -.06 .390E-03
80 .237 iftn
1OU nnn
.UUU • H OODO o DU J H C— UZ 1 .
c;A/Q7p_n9
ju'+y / F— UZ .03 .394E-03
9 .257 1Q7 T/17 . DUODD .0s79^nF_n9
/ZDUt— UZ .
Q79QAF_n9
0 / zyo t— UZ -.05 .621E-03
80 .264 ion
1
nnn
yu .UUU •D D /Z 1 .
AK AF_n
UD
1
1 DC— U 1
I . 1
1
n
UDR 9 F_ n
ZF— U 1
1
1
.04 .724E-03
80 .278 iQR m nnn
UUU . •i979/l
DZ Zh . HOy JU— U
1 1 . 1
1
d(^ft7F-n
HDO / F— U 1
.04 .954E-03
9 .278 1Q C IT 1 . DZ / Dy «
A
1
1
QA"^F_n
4oU Jt— U 1
1 .
ylfl
1
1
9F_n
40 Zt— U 1
1
1
-.06 .960E-03
80 .292 9nn nnn
zuu. UUU • D4U n7A
/O 9n nF n
. ZU 4Ut-U
1 /I
1
1 9n '^TF n
. ZU Jjt-U
1
1
1
.03 . 123E-02
9 .301 9n9
zuz . Qy 1
1
<=iy1PA"^
. D400 .z jyo /t— u 9"^QQ'^F — n
.ZDyyjt— u 1
-.02 .142E-02
80 .307 ZUP . nnn
9nR UUU . DD4ZO
97 Z
• Z /
97F_nl
/ t— U
1
1
97
s z /
11 QF
1 y c— n
1 u .03 . i57E-02
9 .322 onQ oo^; R A7 An

• DO /OU
7 c~7 1 A 1
• DO /4 1
n
F -U 1 '^c:70QF
._>D /yot-u ni 1 -.07 .196E-02
80 .322 o n
z U.UUU
1
1
nnn .Do /oU
z c A COET A
.DDyDZt-U 1
.
z cr CiA AC n 1
jDy44t-U .02 . 197E-02
9 .338 z 4 . no
o 1
yoz
1
o >!
.Dol z / ylAOOylC A1
.4Doo4b-Ul jIAOAZir A1
.45oyDt-U -.02 .244E-02
80 .338 o J.
Z c: nnn
UUU
1
1 .
cQ
Do JZ 1
1
-zn A AOyl F A
.40y44t-U y1 1 A AQ'Z7F A
. 4oyj / t-u
1
.02 .244E-02
80 .354 oon nnn
ZzU.UUU CO O^
.Dy4o4 y1 Anyi AAC A
.DU4oUt-U 1 AAylCCC A1
.bU4DDE-U .01 .298E-02
o on o cn A O OC A AITZIET A1
9 .355 ZZU.ZDy . 59554 .512 1
lzt-01 1 1
.5 z3 E-01
1 1 -.03 .301 E-02
80 .370 ZZP. UUU AO C
iC
.OOODD "Z
.7588zt-01 *7AOQ/l[r A1
. /5oo4h-(Jl -.00 .360E-02
9 .370 90(^ AOQ
zz 5. uyy AAQ A9
. dUodz
"771~7nC
. / /
A1
/yt-ui1
779"ZQF A
. / /zjot-U
1
-.08 .362E-02
9 .383 zzo.oUo A 1 OA C
.0 lOOD .yAIÔ^C A1
4o4h-Ul
1 .y
A1CAZC
1
A1
Dy3E-ui -. 12 .413E-02
80 .387 TZ A AAA
230.000 .62 187 .96624E-01 .96633E-01 -.01 .431 E-02
9 .392 231 .462 .62583 .
1
1
AA
A"2AOC"
030zE+00 1
.
lATIACiAA
031 OE+00
1 -.08 .453E-02
25 O CQ . C A 1 A AT AA OA "7AC_i_AA OA CIC-LAA
.487 ZDO 5U 1 .by /yy 1 1
.09 . 101E-01
"2/1 C/IAET lAA A COOC lAA
25 1 .000 zo3 . 50 1 .7 50 1 1 .34549t+00 "Z
.3452zE+<jO .08 .1 14E-01
25 1 .000 268. 50 1 .72502 .40623E+00 .40601 E+00 .05 . 129E-01
25 1 .000 273. 50 1 .73854 .47462E+00 .47447E+00 •U .145E-01

25 1 .000 0~70 CA
z /o . DO 1
1 .75206 .55125t+00 CC
.551 O AA
18E+00 1 1 [T 1
• 01 . 162E-01
/""I/^TI CiAA
25 1.000 283. 1 50 .76558 .63672E+00 .53671 E+00 .00 .180E-01
OOO CA lAA
25 1 .000 288. 1
1 50 .77910 .73159E+00 .731 67E+00
1
. U I .200E-01
Ct T d ^ Cr~ lAA
25 1 .000 293. 1 50 .79262 .83650E+00 .83665E+00 -.02 .220E-01
25 1 .000 OOO
zyo. 1
1
CA
DO oAA
.80514 1 y1 ACOAOCj AA
.9D20zh+00 A COOAC_i_AA
.9d2z9E+00 -.03 .242E-01
A"70AC A A"? AO C* A
25 1 .000 303. 50 1 .8 966 1 .
1
1 0789E+0 1 1
. 0792
1
1 E+O 1 1
-. 03 .266E-01
ÔI~ lAI
"71
35 1 .000 3 .974
1 1 .84351 .
1
13318E+01 . 3327E+01
1 -.07 .310E-01
T A A C lAI r"
35 1.000 312.360 .84456 .
^
1 3446E+0 . 3447E+0
1 -.01 .312E-01
25 1.000
"7
J J.
1-7
1
1
1
CA
DU o» A An
.o4D0y .
A A9F_1_A
ijoyzb+ui
1 "Z 1
.
"ZAAC^F J.A
joyDt+u
1
1
1
-.03 .316E-01
35 1 .000 317.143 .85749 .14993E+01 .15000E+01 -.05 .338E-01
35 1 .000 322. 120 .87095 . 16743E+01 . 16751E+01 -.05 .366E-01
7 1.000 323.150 .87373 .17122E+01 .17131E+01 -.05 .372E-01
25 1.000 323.150 .87373 .17130E+01 .17131E+01 -.00 .372E-01
35 1.000 327.660 .88593 .18861E+01 .18870E+01 -.05 .399E-01
25 1.000 333. 150 .90077 .21164E+01 .21 158E+01 .03 .435E-01
35 1.000 333 . 545 .90184 .21331E+01 .21330E+01 .00 .437E-01
35 1.000 337.944 .91373 .23309E+01 .23318E-f01 -.04 .467E-01
35 1.000 342.679 .92654 .25606E+01 .25609E+01 -.01 .501E-01
25 1.000 343.150 .92781 .25862E+01 .25846E+01 .06 .504E-01
55
1 1 . 11 0
1 1
Table 1. (Continued)
Data sources and ID numbers: (l)Tickner, (2)Carruth, (3)Maass, (4)Dana, (6)Sage, (7)Beattie,
(9)Kemp, ( )Deschner, (12)Reafner, (13)Cherney, (14)Clegg, ( 17) He geson , ( 19)Gi
1 1 land, I I I i
(20)Burrei (25)Thomas, (30)Mousa, (35)Kratzke, (78)Teichmann , (80)Thermal Loops.

I
,
1
1
n
u Wo (T K +
I
nt? y
1 n 1 Tsfnp • 1 / 1
C ni f f riP /rIT
r\ MPa MPa MPa /K
35 1.000 347,773 .94031 .28265E+01 .28259E+01 .02 ,540E-01

7 1.000 348.150 .94133 .28485E+01 .28463E+01 .08 ,543E-01
25 1.000 348 . 50 1 .94133 .28486E+01 .28463E+01 .08 ,543E-01
25 1.000 353. 150 .95485 .31309E+01 .31281E+01 .09 ,585E-01
35 1.000 353.423 ,95558 .31451E-K)1 .31441E+01 .03 ,587E-01
35 1.000 357.564 .96678 ,33962E+01 .33948E+01 .04 ,625E-01
7/I'2
25 1.000 358. 1 50 .96837 .34352t+01 .343 16t-K)
1 . 1 .630E-0
35 1.000 369.876 .98 01 1 .37371E+01 . 37373E+01 -.01 ,679E-01
1.000 363. 50 1 .981 88 -37633E+0 .37594E+n . 1
25 1.000 365. 50 1 .98729 . 390 8E+ni

1 .38983E+01 .09 .707E-01
35 1.000 366- 30 1 .98994 .39665E+01 .39681 E+0 -.04 .720E-0
25 1.000 367. 50 1 .99270 .40450E+01 .40423E+01 ,07 .734E-01
35 1.000 357. 583 .99387 ,40727E+01 .40742E+01 -,04 .741 E-01
25 1.000 368. 150 .99540 .41 185E+01 .41 165E+01 ,05 .751E-01
25 1.000 369. 50 1 .9981 .4 1935E+01 .41926E-K) 1 .02 .772E-01
25 1.000 369.650 .99946 .42316E+01 .42316E+01 .00 .788 E-01
1.000 369.750 .99973 -423Q3E+0 .42395E+0 -.00 .794E-0
1 0.000 105.350 .28485 ,13330E-06 .10921E-06 22.06 .283E-07
1 0.000 108.250 .29269 ,26660E-06 .22667E-06 17.61 .554 £-07
1 0.000 112.450 .30404 ,66660E-06 .60685E-06 9.85 .136E-06
1 0.000 115.750 ,31296 ,13330E-05 ,12453E-05 7.04 ,263E-06
1 0.000 119.250 .32243 ,26660E-05 .25447E-05 4.77 .503E-06
1 0.000 124.350 .33622 ,66660E-05 ,66588E-05 .11 .120E-05
1 0.000 128.350 .34703 ,13330E-04 .13346E-04 -. 12 .224E-05
1 0.000 132.850 .35920 .26660E-04 ,27600E-04 -3.40 .429E-05
1 0.000 139.150 .37623 .66660E-04 .69900E-04 -4.64 .979E-05
1 0.000 144.350 .39029 , 13330E-03 , 14057E-03 -5.17 .181E-04
1 0.000 149.950 .40543 ,26660E-03 .28069E-03 -5.02 .332E-04
1 0.000 158,150 .42761 ,66660E-03 .69949E-03 -4.70 .733E-04
1 0.000 164.750 .44545 .13330E-02 .13538E-02 -1.54 .129E-03
2 0.000 94,540 .25562 .68500E-08 .46579E-08 47.06 .153E-08
2 0.000 99,780 .26979 .30650E-07 .23579E-07 29.99 .688E-08
2 0.000 105,150 .28430 , 12190E-06 . 10368E-06 17.58 .270E-07
2 0.000 110,650 ,29918 .43650E-06 .40193E-06 8.60 .936E-07
2 0.000 117.420 ,31748 .17800E-05 . 17616E-05 1.05 .360E-06
2 0.000 127.720 ,34533 .1 1360E-04 ,12000E-04 -5.33 .204E-05
2 0.000 134.150 ,36271 .31250E-04 ,33703E-04 -7.28 ,512E-05
2 0.000 143.740 ,38864 .1 1960E-03 ,12989E-03 -7.92 ,169E-04
2 0.000 155.720 .42104 .50660E-03 ,53976E-03 -6. 14 ,586E-04
2 0.000 162,450 ,43923 ,10390E-02 .10830E-02 -4.06 .107E-03
2 0.000 173,580 .46933 .29920E-02 .29962E-02 -.14 ,254E-03
2 0^000 178.650 .48303 .45700E-02 .45409E-02 .64 .360E-03
3 0.000 229.750 .62120 ,11426E+00 .95561E-01 19.57 .427E-02
3 0.000 230,250 ,62255 .11599E+00 .97716E-01 18.70 ,435E-02
3 0.000 230,850 .62417 .1 1919E+00 .10035E-K)0 18.77 .444E-02
3 0.000 234,750 .63472 .13999E+00 .1 1887E4O0 17.77 .506E-02
3 0.000 242.300 .65513 . 18238E+00 .16214E+00 12.48 .644E-02
3 0.000 250.050 .67608 .26944E+00 .21824E+00 23.46 .808E-02
4 0.000 210.330 , 56869 ,36837E-01 .36599E-01 .65 .200E-02
4 0.000 216.410 .58513 .50689E-01 .50477E-01 .42 .258E-02
4 0.000 216,470 .58529 ,50822E-01 .50632E-01 ,37 .259E-02
4 0.000 221.640 .59927 .65835E-01 .65504E-01 .51 .318E-02
4 0.000 227.250 .61444 .85753E-01 .85335E-01 .49 .391E-02
4 0.000 231.080 .62479 .10181E+00 .10138E+00 .42 ,447E-02
4 0.000 235.040 .63550 .12050E+00 . 12034E+00 .13 .5nE-02
4 0.000 235.090 .63564 .12082E+00 .12060E+00 ,18 ,512E-02
4 0.000 242.730 ,65629 .16520E+00 . 16493E+00 ,16 .652E-02
4 0.000 249.070 .67344 .21041E+00 .21043E+00 -.01 .786E-02
4 0.000 256,290 .69296 .27238E+00 .27326E+00 -.32 .958E-02
4 0.000 267.280 .72267 .39303E+00 .39490E+00 -.47 ,126E-01
4 0.000 272.120 .73576 ,45903E+00 .45972E+00 -, 15 ,142E-01
4 0.000 275.630 .74525 .50529E+00 .51 145E+00 -1 ,21 ,153E-01
4 0.000 282.670 .76428 .62542E+00 .62810E+00 -,43 .178E-01
56
Table 1. (Continued).
Data sources and ID numbers: (l)Tickner, (2)Carruth, (3)Maass, (4)0ana, (6)Sage, (7)Beattie,
(9)Kemp, (IDDeschner, (12)Reamer, (13)Cherney, (14)Clegg, 17 )Hei geson 19)Gi 11 land,( , ( I
(20)Burrell, (25)Thomas, (30)Mousa, (35)Kratzke, (78)Te ichmann (80)Thermal Loops. ,
u Wiis
Wfc;
I nK
y *t*
T©rnp • / c P 1 1 r \ ni ff HP /rIT
1 1 1 1 1 1
0
MPa MPa t
p lira/ i\
4 0.000 283.300 .76599 .63648E+00 .63942E+00 -.46 .181E-01

4 0.000 291.080 .78702 .78607E+00 .79193E+00 -.74 .212E-01
4 0.000 298.080 .80595 .94352E+00 .95059E+00 -.74 .242E-01
4 0.000 307.090 .83031 . 1644E+01
1 . 1876E+01
1 -1.95 .285E-01
4 0.000 315.210 .85226 .14232E+01 .14358E+01 -.87 .327E-01
4 0.000 323.490 .87465 .17023E+01 .17258E+01 -1.36 .374E-01
4 0.000 323.490 .87465 .17065E+01 .17258E+01 -1.12 .374E-01
6 0.000 293.930 .79473 ,86180E+00 . 85398 E+00 .92 .224E-01
6 0.000 301 .090 .81409 .10352E+01 . 10255E+01 .94 .256E-01
6 0.000 307.480 .83136 . 12066E+01 . 1987E+01
1 .66 .287E-01
6 0.000 313.320 .84715 .13790E+01 . 13749E+01 .30 .317E-01
6 0.000 318.590 .86140 .15513E+01 .15494E+01 .12 .345E-01
6 0.000 323.370 .87433 . 17237E+01 .17213E+01 .14 .373E-01
6 0.000 327.930 .88666 . 18961E+01 . 18978E+01 -.09 .401E-01
6 0.000 332.090 .89790 .20684E+01 .20701 E+01 -.08 .428E-01
6 0.000 336.090 .90872 .22408E+01 .22464E+01 -.25 .454E-01
6 0.000 339.870 .91894 .24132E+01 .24231 E+01 -.41 .481E-01
6 0.000 343.480 .92870 .25855E+01 .26013E+01 -.61 .507E-01
6 0.000 346.930 .93803 .27579E+01 .27807E+01 -.82 .533E-01
6 0.000 350.090 .94657 .29303E+01 .29532E+01 -.78 .559E-01
6 0.000 353.090 .95468 .31026E+01 .31246E+01 -.70 .584E-01
6 0.000 355.870 .96220 .32750E+01 .32903E+01 -.47 .609E-01
6 0.000 358.590 .96956 .34474 E+01 .34594E+01 -.35 .635E-01
6 0.000 361.260 .97677 .36197E+01 .36324E+01 -.35 .662E-01
6 0.000 363.760 .98353 .37921 E+01 .38012E+01 -.24 .690E-01
6 0.000 366.260 .99029 .39645E+01 ,39775E+01 -.33 .721E-01
6 0.000 368.760 .99705 .41369E+01 .41627E+01 -.62 .763E-01
1 0.000 301.950 .61641 .10536E+01 . 10477E+01 .56 .260E-01
1 0.000 302.950 .81912 .10807E+01 .10739E+01 .63 .265E-01
1 0.000 304.610 .82360 . 1248E+01
1 . 185E+01
1 1 .56 .273E-01
1 0.000 306.680 .82920 .n829E+01 .1 1760E+01 .59 .283E-01
1 0.000 308.350 .83372 . 12317E+01 .12239E+01 ,64 .291E-01
1 0.000 31 1.490 .84221 .13246E+01 .13178E+01 .52 .307E-01
1 0.000 311.490 .84221 . 13249E+01 . 13178E+01 .54 .307E-01
1 0.000 315.480 .85299 .14500E+01 .14446E+01 .37 .329E-01
1 0.000 318. 150 .86021 .15471E+01 . 15343E+01 .84 .343E-01
1 0.000 318.280 .86057 .15474E+01 .1 5388E+01 .56 .344E-01
1 0.000 324.940 .87857 .17798E+01 .17806E+01 -.05 .383E-01
1 0.000 330.600 .89388 .20098E+01 .20071 E+01 ,13 .418E-01
1 0.000 330,600 .89388 .20107E+01 .20071 E+01 . 18 .418E-01
1 0.000 333.960 .90296 .21596E+01 .21512E+01 .39 .440E-01
1 0.000 336.650 .91023 .22749E+01 .22720E+01 .13 .458E-01
1 0.000 340.120 .91962 .24561E+01 .24351 E-i-01 .86 .482E-01
1 0.000 340.120 .91962 .24539E+01 .24351E+01 .77 .482E-01
1 0.000 344.640 .93184 .26778E+01 .26606E+01 .65 .516E-01
1 0.000 348.240 .94157 .28709E+01 .28512E+01 .69 .544E-01
1 0.000 351 .640 .95076 .30683E+01 .30408E+01 .90 .572E-01
1 0.000 358.010 .96799 .34289E+01 .34227E+01 .18 .629E-01
1 0.000 361.120 .97640 .36292E+01 .36231 E+01 .17 .660E-01
1 0.000 361. 120 .97640 .36320E+01 .36231E+01 .24 .660E-01
1 0.000 363.200 .98202 .37687E+01 .37628E+01 .16 .683E-01
1 0.000 363.450 .98270 .37828E+01 .37799E+01 .08 .686E-01
1 0.000 365.470 .98816 .39048E+01 .39209E+01 -.41 .71 lE-01
1 0.000 368.850 .99730 ,41585E+01 .41696E+01 -.27 .765E-01
0.000 368.970 .99762 .41813E+01 .41787E+01 .06 .767E-01
2 0.000 313.483 .84759 .13790E+01 . 13801E+01 -.08 .318E-01
2 0.000 332.039 .89777 .20684E+01 .20679E+01 .02 .427E-01
2 0.000 339.594 .91819 .24132E+01 .24098E+01 .14 .479E-01
2 0.000 346.428 .93667 .27579E+01 .27540E+01 .14 .529E-01
2 0.000 352.706 .95365 .31026E+01 .31022E+01 .01 .581E-01
2 0.000 358.261 .96867 .34474E+01 .34386E+01 .26 .631E-01
2 0.000 363.594 .98309 .37921 E+01 .37898E+01 .06 .688E-01
2 0.000 368.372 .99600 .41369E+01 .41332E+01 .09 .755E-01
3 0.000 303.150 .81966 .10801E+01 . 10792E+01 .08 .266E-01
57
D ) .
(9)Kemp, ( )Deschner , (12)Reamer, (13)Cherney, (14)Clegg, ( 17)Helgeson, ( 19)Gi
1 1 land, I I i
(20)Burrell , (25)Thomas, (30)Mousa, (35)Kratzke, (78)Teichmann, (80)Thermal Loops.

1 Weight Temp, T/Tc Pg ( expt) Pg ( ca c
1 D 1 1 1 dP(j/dT
K MPa MPa % MPa/K
13 0.000 323.150 .87373 .17154E+01 .17131E+01 .14 ,372E-01
14 0.000 323.150 .87373 .17154E+01 .17131E+01 . 14 ,372E-01
14 0.000 333.150 .90077 .21 197E+01 .21 158E+01 .18 .435E-01
14 0.000 343.150 .92781 .25909E+01 .25846E+01 .24 .504E-01
14 0.000 348. 150 .94133 .28533E+01 .28463E+01 .24 .543E-01
-
14 0.000 353. 150 .95485 ,31390E+01 .31281E+01 .35 .585E-01
14 0.000 358.150 .96837 .34400E+01 .34316E+01 .25 .630E-01
14 0.000 363.150 .98188 .37683E+01 .37594E+01 .24 .683E-01
14 0.000 368.150 .99540 .41239E+01 .41 165E+01 ,18 .751E-01
17 0.000 277.594 .75056 .54470E+00 .54223E+00 .46 . 160E-01
17 0.000 283.150 .76558 .63980E+00 ,63671 E+00 .48 .180E-01

17 0.000 288.706 .78060 .74330E+00 .74284E+00 .06 .202E-01
17 0.000 294.261 .79562 .86180E+00 .86141E+00 .05 .225E-01
17 0.000 299.817 .81064 .99350E+00 .99332E+00 .02 .250E-01
17 0.000 305.372 .82566 .1 1397E-K)1 .1 1394E+01 .03 .276E-01
17 0.000 310.928 .84069 .13010E+01 .13006E+01 .03 .304E-01
17 0.000 316.483 .85571 .14789E+01 .14778E+01 .07 .334E-01
17 0.000 322.039 .87073 . 16734E+01 . 16721E+01 .08 .366E-01
17 0.000 327.594 .88575 .18857E+01 .18844 E+01 ,07 .399E-01
17 0.000 333.150 .90077 .21 188E+01 .21158E+01 , 14 ,435E-01
17 0.000 338.706 .91579 .23718E+01 .23676E+01 .18 .472E-01
17 0.000 344.261 .93081 .26462E+01 .2641 lE+01 .19 .513E-01
17 0.000 349.817 .94583 .29434E+01 ,29380E+01 .18 .556E-01
17 0.000 355.372 .96085 .32654E+01 .32601E+01 .16 .604E-01
17 0.000 360.928 .97588 .36184E+01 .36105E+01 .22 .658E-01
19 0.000 314.817 .85120 .14065E+01 . 14229E+01 -1. 16 .325E-01
19 0.000 330.372 .89326 .20271 E+01 .19976E+01 1.48 ,416E-01
19 0.000 34 5.372 .93382 .27441E+01 .26985E+01 1.69 ,521E-01
19 0.000 357.594 .96686 .34060E+01 .33967E+01 .27 ,625E-01
20 0.000 148.950 .40273 .40000E-03 .24915E-03 60.54 ,299E-04
20 0.000 154.850 .41868 .80000E-03 .49082E-03 62.99 .540E-04
20 0.000 163.950 .44329 .20000E-02 .12537E-02 59.53 .121E-03
20 0.000 172.650 .46681 .40000E-02 .27678E-02 44.52 .237E-03
20 0.000 179.850 .48628 .66660E-02 .49909E-02 33.56 .390E-03
20 0.000 190.350 .51467 .13332E-01 .10768E-01 23.81 .739E-03
20 0.000 196. d50 . 53224 . 19998E-01 . 16540E-01 20.91 .105E-02
20 0.000 202.050 .54630 .26664E-01 .22794E-01 16.98 .136E-02
20 0.000 210.250 .56847 .39997E-01 .36439E-01 9.76 . 199E-02
20 0.000 215.450 .582 53 .53329E-01 .48044E-01 1 ,00

1 .248E-02
20 0.000 219.950 .59470 .66661E-01 .60306E-01 10.54 .298E-02
20 0.000 223,750 .60497 .79993E-01 .72482E-01 10.36 .344E-02
20 0.000 225.550 .60984 .86660E-01 ,78886E-01 9.85 .368E-02
20 0.000 227.050 .61390 .93326E-01 .84556E-01 10.37 .388E-02
20 0.000 228.050 .61660 .97325E-01 ,88509E-01 9.96 ,402E-02
20 o.ooc 229.050 .61931 .10133E+00 .92606E-01 9.42 ,417E-02
30 0.000 334.780 .90518 .22001E+01 .21875E+01 .58 ,445E-01
30 0.000 337.360 .91215 .23186E+01 ,23047E+01 .60 .463E-01
30 0.000 340.510 .92067 .24651E+01 .24540E+01 .45 .485E-01
30 0.000 346.730 .93749 .27883E+01 ,27700E+01 .66 .532E-01
30 0.000 350.470 .94760 .29955E+01 .29745E+01 .71 .562E-01
30 0.000 353.620 .95612 .31652E+01 .31556E+01 .30 .589E-01
30 0.000 357.820 .96747 .34242E+01 ,34108E+01 .39 .627E-01
30 0.000 362.280 .97953 .37296E+01 .37004E+01 .79 ,673E-01
30 0.000 365.570 .98843 .39541E+01 .39281 E+01 .66 ,712E-01
30 0.000 367.850 .99459 .4T159E+01 .40941 E+01 .53 ,746E-01
30 0.000 369.740 .99970 .42537E+01 .42387E+01 ,36 .793E-01
78 0.000 324.754 .87807 .17728E+01 .17735E+01 -.04 .382E-01
78 0.000 328.078 .88706 .19041 E+01 .19037E+01 .02 .402E-01
78 0.000 331.356 .89592 ,20393E+01 .20389E+01 .02 .423E-01
78 0.000 333.900 .90280 ,21496E+01 .21486E+01 .05 .439E-01
78 0.000 335.669 .90758 .22278E+01 .22274E+01 .02 .451E-01
78 0.000 337.878 .91355 .23285E+01 .23288E+01 -.01 .467E-01
78 0.000 340,292 .92008 .24433E+01 .24434 E+01 -.01 .484E-01
78 0.000 342.939 .92724 .25742E+01 .25740E+01 ,01 .503E-01
58
D . .
(9)Kemp, ( ) Deschner ,
1 1 (12)Reamer, (13)Cherney, (14)Clegg, ( 17 ) Hel geson , ( 19)Gi land, I I i
(20)Burrell, (25)Thomas, {30)Mousa, (35)Kratzke, (78)Teichmann, (80)Thermal Loops.

1 We ight Temp, T/Tc P^( expt) P(j(cal c) Di f f dP(j/dT
K MP a MPa % MPa/K
1R
10 u» uuu lit;
. yDD 1 £. . jL do
/ UHTU 1 •ZOO DZ ctu 1
on
78 0.000 348.087 .94116 .28434E+01 .28429E+01 .02 .542E-01
78 0.000 350.680 .94817 .29866E+01 .29863E+01 .01 .564E-01
78 0.000 352.559 .95325 .30930E+01 .30937E+01 -.02 .579E-01
78 0.000 354.824 .95937 .32279E+01 .32271E+01 .02 .599E-01
78 0.000 358. Ml .96834 .34310E+01 .34310E+01 .00 .630E-01
78 0.000 353.426 .98263 .37776E+01 .37783E+01 -.02 .686E-01
Number of data points used in fit = 81; rms pressure deviation = 0.056^.
59
1 0
n 1 1 0
5/1
1 C
1 . 0
R/
P
1 . 0
R11
111 U
0. , R/1
11
Table 2. Comparisons of saturated liquid density data with eq (3).
Data sources and ID numbers: (l)Maass, (2)Van der Vet, (3)NGAA, (4)Sage, (5)Reamer, (7)Clegg,
{8)Francis, (ll)Seeman, ( 2)Hel geson , (13)Klosek, {14)Shana'a, (15)Jensen, ( 16)S iwinski
1 I
( 17)Toml inson, (18)Kahre, ( 19)Rodosevich, (20)Haynes, (2 Deschner , (22)0rrit, (23)McClune, 1 )
(24)Ely, (25)Thomas, (34)Carney, (36)Dana.
ID Weight Temp. (VT)/(Tc-Tt) Dens ty (expt) i Density (calc) Di f f dP£/dT

IN mo / L 1
kn/ C m3.K' ^
1 finn 1 6 .607 . \)D -1 1 . n"^ni

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Q
11 2/ 1 nnn 91 nin .98052 16.485 726.96 727.64 -.09 - 1 .0265
23 1 .000 93 . 50 1 .97299 16.442 725.05 725.44 -. 05 -1 .0250
22 1 .000 96.040 .96283 15.385 722. 52 722.48 .01 -1 .0230
23 1 .000 98 . 1 50 .9554 16.331 720. 17 720.33 -.02 -1 .02 16
19 1 .000 no.
\J\J % 01 \J
1\ \ .94887 16.291 718.41 7 8.43
1 -.00 -1 .0205
£-\J 1 nnn inn n7s .94864 16.307 719.07 718.36 . 1 -1 .0205
1 nnn 1nn QRn . 94546 16.272 7 1 7 . 54 7 7.44
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22 1.000 182.340 .65936 14.385 634.33 634.40 -.01 -U0475
24 1.000 184.294 .65249 14.340 632.34 532.35 -.00 -K0503
22 1.000 187.800 .64016 14.254 628.55 528.66 -.02 -K0556
24 1.000 191.936 .62562 14.155 624.21 524.28 -.01 -K0623
22 1.000 193.300 .62082 14.120 622.57 622.83 -.03 -U0647
24 1.000 198.748 .60167 13.991 516.96 517.00 -.01 -K0747
22 1.000 198.890 .601 17 13.986 616.72 616.85 -.02 -1 ^0750
20 1.000 200.000 .59726 13.955 61 5.42 61 5.66 -•04 -1.0771
24 1.000 204.329 .58204 13.857 611.05 510.97 .01 -1 ^0860
22 1.000 204.540 .58130 13.847 610.62 610.75 -•02 -1.0865
60
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(8)Francis, (IDSeeman, (12)Helgeson, (13)Klosek, (14)Shana'a, (15)Jensen, ( 6)S w nski 1 I i i
( 17)Toml inson, (18)Kahre, 19) Rodosev Ich , (20)Haynes, (21 )Deschner , (22)0rrit, (23)McClune,
(
ID Weight Temp. (Tc-T)/(Tc-Tt) Density (expt) Density (calc) Diff. dp„/dT

K mo /L 1 kg/m3 kg/ rn3 kfi/ f m3.K ^
22 1 .000 210.020 .56203 13.710 604.59 604.75 -.03 - 1 .0989

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22 1 .000 2 6.020
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25 1.000 367.150 .00949 5.756 297.92 298.45 -.18 -10.3851
16 1.000 368.100 .00615 6.488 286. 10 287.23 -.39 -13.6269
25 1.000 368. 150 .00598 6.485 285.97 285.54 -.20 -13.8779
16 0.000 369.100 .00254 6.080 268.10 269.86 -.65 -23.3214
25 1.000 369. 150 .00246 6.082 268.20 268.67 -.18 -24.3714
16 0.000 369.600 .00088 5.669 250.00 253.99 -1 .57 -47.1839
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Data sources and ID numbers; (l)Maass, (2)Van der Vet, (3)NGAA, (4)Sage, (6)Reanier, (7)Clegg,
{8)Francis, (ll)Seeman, ( 12)Helgeson, (13)Klosek, (14)Shana'a, (15)Jensen, ( 16)S wl nski I i
( 17)Toml inson, (18)Kahre, ( 19)Rodosev ich , (20)Haynes, (21 )Deschner , (22)Orrit, (23)McClune,
ID We ight Temp. (Tc-T)/(Tc-Tt) Dens ty i ( expt) Density (calc) Di ff. dPn/dT

X,
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2.43 -3.4624
4 0.000 355.872 .04915 8.456 372.87 353.02 2.71 -3.8440
4 0.000 358.594 .03958 8.228 362.82 351.89 3.10 -4.3522
4 0.000 361.261 .03020 7.973 351.59 339.33 3.61 -5. 1 198
4 0.000 363.761 .02141 7.708 339.88 325.19 4.52 -5.2966
4 0.000 366.261 .01262 7.406 326.58 306.88 5.42 -8.7034
4 0,000 368.761 .00383 7.009 309,06 276.85 n.63 -18.3934
6 0.000 313.480 .19822 10.609 467.82 466.43 .30 -1.7822
6 0.000 324.480 .15954 10.141 447.20 445.71 .33 -1.9973
6 0.000 332.040 ,13296 9.778 431 .19 429.87 .31 -2.2015
6 0.000 339.590 . 054
1 9.395 414.31 412.25 .50 -2.4850
6 0.000 346.430 .08235 8.975 395.75 394.04 .43 -2.8542
6 0.000 352.710 .06027 8.524 375.88 374.46 .38 -3.4178
62
(8)Francis, (ll)Seeman, ( 2)He geson , (13)Klosek, (14)Shana'a, (15)Jensen, ( 6) S li w nski
1
I
1 I
( 17)Tomi inson, (18)Kahre, ( 19)Rodosevich, (20)Haynes, (21 Deschner , (22)0rrit, (23)McClune, )
ID We ght
i Temp ^ '
C ' ' ^ c T Dens ty i ( expt) Dens ty
1 ( ca c
1 Di f f d Pj^/d T
K mol/L kg/m3 kg/m3 $ kg/(m3.K)
6 0.000 358.260 .04076 8.036 354.37 353.34 .29 -4.2880

6 0.000 363.590 .02201 7.471 329.46 326.26 .98 -6. 1918
6 0.000 368.370 .00520 6.632 292.45 283.35 3.21 -15.1457
7 0.000 323. 150 .16422 10.150 447.59 448.34 -. 17 -1.9670
7 0.000 333. 150 .12905 9.550 421.13 427.41 -1.47 -2.2373
7 0.000 343.150 .09389 8.980 395.99 403.09 -1 .76 -2.6626
7 0.000 348. 150 .07631 8.630 380.56 389.01 -2. 17 -2.9894
7 0.000 353.150 .05872 8.300 366.01 372.95 -1 .86 -3.4691
7 0.000 358. 150 .041 14 7.860 346.60 353.81 -2.04 -4.2643
7 0.000 363. 150 .02356 7.320 322.79 328.93 -1.87 -5.9427
7 0.000 368. 150 .00598 6.410 282.66 286.54 -1 .35 -13.8779
8 0.000 293. 150 .26971 11.350 500.50 499.81 .14 -1 .5232
1 0.000 278. 160 .32242 1 1 .851 522.60 521.63 . 19 -1 .3953
1 0.000 283. 140 .30491 1 1.686 51 5.30 514.59 .14 -1 .4336
1 0.000 285. 150 .29432 1 1.586 51 0.90 51 0.24 . 13 -1 .4587
1 0.000 289.160 .28374 1 1.482 506.30 505.81 .10 -1.4853
1 0.000 293. 1 50 .26971 1 1.342 500. 15 499.81 .07 -1 .5232
1 0.000 295.150 .26268 1 1.271 497.00 496.74 .05 -1 .5435
1 0.000 297. 150 .25564 1 1.200 493.90 493.63 .05 -1 .5647
1 0.000 299.180 .24851 1 1.125 490.60 490.43 .03 -1 .5872
12 0.000 277.594 .32441 1 1 .891 524.34 522.42 .37 -1 .391
12 0.000 283. 1 50 .30487 11.718 516.73 514.57 .42 -1.4337
12 0.000 288.706 .28534 1 1.532 508.52 506.48 .40 -1.4812
12 0.000 294.261 .26580 11.345 500.27 498.1 .43 -1.5344
12 0.000 299.817 .24627 n. 1 39 491.21 489.42 .37 -1 .5945
12 0.000 305.372 .22673 10.935 482.19 480.37 .38 -1 .6630
12 0.000 310.928 .20719 10.722 472.80 470.92 .40 -1 .7418
12 0.000 316.483 .18766 10.484 462.29 461.00 .28 -1 .8338
12 0.000 322.039 .16812 10.241 451 .60 450.52 .24 -1.9427
12 0.000 327.594 .14859 9.985 440.31 439.37 .21 -2.0742
12 0.000 333. 150 .12905 9.713 428.30 427.41 .21 -2.2373
12 0.000 338.706 .10952 9.423 415.52 414.43 .27 -2.4461
12 0.000 344.261 .08998 9.095 401.06 400.10 .24 -2.7261
12 0.000 349.817 .07044 8.697 383.49 383.91 -.11 -3.1274
12 0.000 355.372 .05091 8.235 363.15 364.92 -.49 -3.7665
12 0.000 360.928 .03137 7.757 342.06 341.01 .31 -5.0051
13 0.000 88.706 .98862 16.542 729.45 730.00 -.08 -1.0284
13 0.000 94.261 .96909 16.420 724.07 724.30 -.03 -1 .0242
13 0.000 99.817 .94955 16.296 718.61 718.62 -.00 -1.0206
13 0.000 105.372 .93002 16.168 712.95 712.96 -.00 -1.0176
13 0.000 110.928 .91048 16.042 707.39 707.32 .01 -1 .0153
13 0.000 116.483 .89095 15.914 701.76 701 .68 .01 -1 .0136
13 0.000 122.039 .87141 15.787 696. 16 696.05 .02 -1 .0125
13 0.000 127.594 .85187 15.656 690.37 690.43 -.01 -1 .0121
13 0.000 133. 150 .83234 15.525 684.62 684.81 -.03 -1.0123
15 0.000 93 . 50 1 .97299 16.446 725.20 725.44 -.03 -1 .0250
15 0.000 103. 150 .93783 16.212 714.90 71 5.22 -.05 -1 .0188
1 0.000 113. 150 .90267 15.967 704.10 705.06 -. 14 -1 .0145
15 0.000 123. 150 .86750 15.743 694.20 694.93 -.10 -1 .0123
15 0.000 133. 50 1 .83234 15.516 684.20 684.81 -.09 -1 .0123
17 0.000 278,150 .32246 11.835 521 .90 521 .65 .05 -1 .3952
17 0.000 283.150 .30487 11.679 515.00 514.57 .08 -1 .4337
17 0.000 288. 150 .28729 11.513 507.70 507.30 .08 -1.4762
17 0.000 293.150 .26971 11.345 500.30 499.81 .10 -1 .5232
17 0.000 298. 150 .25213 11.171 492.60 492.06 .11 -1.5757
17 0.000 303.150 .23455 10.989 484.60 484.04 .12 -1 .6345
17 0.000 308.150 .21696 10.803 476.40 475.70 .15 -1.7010
17 0.000 313.150 .19938 10.608 467.80 467.01 .17 -1 .7769
18 0.000 277.550 .32457 1 1.850 522.55 522.48 .01 -1.3908
18 0.000 288.750 .28518 11.491 506.70 506.41 .06 -1 .4816
18 0.000 299.850 .24615 11.110 489.90 489.37 .11 -1 .5949
18 0.000 310.950 .20712 10.696 471.65 470.88 .16 -1.7422
63
Tabl e 2. (Continued)
Data sources and ID numbers: (l)Maass, (2)Van der Vet, (3)NGAA, (4)Sage, (6)Reamer, (7)Clegg
(8)Francis, (ll)Seeman, ( 2)Hel geson , (13)Kiosek, ( 14) Sliana' a, (15)Jensen, ( 16) S wi nski
1 I i
( 17)Toml inson, (18)Kahre, ( 19)Rodosevich, (20)Haynes, ( 21 ) Deschner , (22)0rrit, (23)McClune,

(24)Ely, (25)Thomas, (34)Carney, (3&)Dana.
ID We g ht
i Temp (T -T)/(T^-T+) Dens ty i ( expt) Density (calc) Di f f dPj^/dT
K mol /L kg/m3 kg/m3 % kg/(m3.K)
18 0.000 327,550 . 14874 9.941 438.35 439.46 -.25 -2.0731

20 0.000 288.706 .28534 1 .479
1 506. 19 506.48 -.06 -1 .4812
21 0.000 303» 150 .23455 1 .017
1 485.82 484.04 .37 -1 .6345
21 0.000 308. 150 .21696 10.851 478.50 475.70 .59 -1 .7010
21 0.000 313. 150 . 19938 10.692 471 .49 467.01 .96 -1 .7769
21 0.000 318. 150 .18180 10.500 463.02 457.91 1.12 -1 .864 5
21 0.000 323. 150 . 16422 10.302 454,29 448.34 1.33 -1 .9670
21 0.000 328. 150 .14663 10.075 444.28 438.21 1.38 -2.0890
21 0.000 333. 150 .12905 9.842 434,00 427.41 1.54 -2.2373
21 0.000 338.150 .1 1 147 9.570 422.00 415.78 1.50 -2 .4226
21 0.000 543. 150 .09389 9.252 408.00 403.09 1.22 -2.6626
21 0.000 348.150 .07631 8.896 392.30 389.01 .85 -2.9894
2! 0.000 353. 150 ,05872 8.527 376,00 372.95 .82 -3.4691
21 0.000 358.150 .04114 8.078 356.20 353.81 .68 -4.2643
21 0.000 363.150 .02356 7.529 332.00 328.93 .93 -5.9427
21 0.000 368.150 .00598 6.644 293.00 286.54 2.25 -13.8779
34 0.000 227.594 .50023 13.284 585.80 585.04 ,13 -1,1471
34 0.000 233, 150 ,48069 13.139 579.40 578.62 .14 -1 ,1655
34 0.000 238,706 .461 16 12.990 572.80 572.09 .12 -1, 1856
34 0,000 244.261 ,44162 12.835 566.00 565.44 .10 -1,2075
34 0.000 249.817 .42209 12.681 559.20 558.67 .10 -1,2315
34 0.000 255.372 .40255 12.522 552.20 551.76 .08 -1.2577
34 0.000 266.483 .36348 12.209 538.40 537.46 .18 -1.3180
34 0.000 277. 150 .32597 11.883 524.00 523.04 .18 -1.3879
34 0.000 288,706 .28534 11.504 507.30 506.48 . 16 -1.4812
34 0.000 310.928 .20719 10.708 472.20 470.92 .27 -1 .7418
34 0.000 322,039 . 16812 10.273 453.00 450.52 .55 -1.9427
34 0.000 333.150 .12905 9.783 431.40 427,41 .93 -2.2373
JO 1
1
7 . yj-jj
£, n'^'^ ^ JU , ou
36 0.000 278.150 .32246 11.878 523,80 521,65 .41 -1 .3952
36 0.000 283. 150 .30487 1 . 720
1 516,80 514,57 .43 -1.4337
36 0.000 290. 150 .28026 1 .482
1 506,30 504.33 .39 -1 .4944
36 0,000 293.150 .26971 11.389 502,20 499.81 .48 -1 .5232
36 0.000 297.150 ,25564 11.248 496,00 493.63 .48 -1,5647
36 0.000 300.150 ,24509 1 1 . 1 53 491.80 488.89 .60 -1.5984
36 0.000 315.150 .19235 10.577 466.40 463.43 .64 -1.8103
36 0.000 321.150 .17125 10,091 445.00 452.23 -1 .60 -1.9239
36 0.000 323.150 .16422 10.232 451 .20 448.34 .64 -1.9670
36 0.000 327.150 .15015 10.046 443.00 440.29 .62 -2.0627
36 0.000 329.150 .14312 9.958 439. 10 436.1 .69 -2.1 163
Number of data points used in f it = 120; rms dens ty deviation = 0,074^.

i
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67
. .
Table 4. Comparisons of virial coefficients with eq (5).
Second virial coefficients of propane
Data sources and ID numbers )McGI ashan (2)Kapallo, (3)Dymond/Smith (4)Strein, (5)Hahn
( I , ,
(7)Gunn, (8)Brewer, (9)Beattie, 10) Bottom ley, (ll)Cherney,

( 12)Deschner (13)Jessen, ( ,
(14)Kretschmer {15)Reamer, (16)Sage.

,
ID Weight Temp. T/Tc B Bp(expt) Buccal c) Di ff Diff

K cm3/mo 1
%
5 .146 21 1.300 .5713 -844.00 -4.2200 -4. 1843 -.0357 -.85

5 .464 231 .200 .6251 -680.00 -3.4000 -3.4051 .0051 .15
2 .095 244.000 .6597 -610.00 -3.0500 -3.0159 -.0341 -1.13
8 .418 248. 150 .6709 -579.00 -2.8950 -2.9043 .0093 .32
5 .332 251.500 .6800 -567.00 -2.8350 -2.8188 -.0162 -.58
3 .470 260.000 .7030 -526,00 -2.6300 -2.6184 -.01 16 -.44
3 .209 270.000 .7300 -478.00 -2.3900 -2.4093 ,0193 .80
2 .082 273.000 .7381 -477.00 -2.3850 -2.3516 -.0334 -1.42
8 ,574 273. 150 .7385 -468.00 -2.3400 -2.3488 .0088 .37
13 .976 273. 160 .7386 -470.00 -2.3500 -2.3486 -.0014 -.06
5 .224 273.800 .7403 -471 .00 -2.3550 -2.3366 -.0184 -.79
3 .206 285.000 .7706 -424.00 -2. 1200 -2.1406 .0206 .96
16 .012 294.270 .7956 -4 17.56 -2.0878 -1 .9966 -.0912 -4.57
10 .029 295.210 .7982 -407.90 -2.0395 -1.9828 -.0567 -2.86
1 .274 295.400 .7987 399.00 -1 .9950 -1 .9801 -.0149 -.75
4 .434 296. 100 .8006 -396.00 -1 .9800 -1.9699 -.0101 -.51
2 .326 297.000 .8030 -394.00 -1 .9700 -1.9570 -.0130 -.66
8 .995 298 . 1 50 .8061 -388.00 -1.9400 -1.9407 .0007 .04
3 .359 300.000 .8111 -380.00 -1.9000 -1 .9149 -0149 .78
12 .059 303. 160 .8197 -382.04 -1.9102 -1.8719 -.0383 -2.05
12 .039 303.160 .8197 -384.00 -1 .9200 -1.8719 -.0481 -2.57
14 .009 303.160 ,8197 -395.00 -1.9750 -1.8719 -.1031 -5.51
1 .225 306.500 .8287 -369.00 -1.8450 -1 .8281 -.0169 -.93
4 .818 308.000 ,8328 -360.50 -1.8025 -1 ,8089 .0064 .35
7 .012 310.900 .8406 -335.80 1.6790 -1 ,7727 .0937 5.28
15 .011 310.940 .8407 -335,49 -1,6775 -1.7722 .0947 5,34
15 .007 310.940 .8407 -330,00 -1 .6500 -1 .7722 .1222 6.89
16 .005 310.940 .8407 -381,80 -1.9090 -1.7722 -.1368 -7.72
3 .270 315.000 .8517 -341.00 -1 .7050 -1 .7232 .0182 1.06
1 .870 317.600 .8587 -339,00 -1.6950 -1.6930 -.0020 -.12
2 .043 321.000 .8679 -340,00 1.7000 -1 .6546 -.0454 -2.75
11 .214 323. 160 ,8738 -329,62 -1.6481 -1.6308 -.0173 -1.06
13 .866 323. 160 ,8738 -325,00 -1.6250 -1 .6308 ,0058 .36
1 .064 327.600 .8858 -324.00 -1.6200 -1.5836 -.0364 -2.30
15 .033 327.600 .8858 -305.44 -1 .5272 -1 .5836 ,0564 5.56
15 .036 327.600 .8858 -306.00 -1.5300 -1.5836 .0536 3.39
16 .003 327.600 .8858 -353.45 -1.7673 -1 .5836 -.1836 -1 1 .60
3 .671 330.000 .8923 -310.00 -1 .5500 -1.5589 .0089 .57
4 .255 332.900 .9001 -309.00 -1 .5450 -1 .5298 -.0152 -.99
1 .325 337.800 .9133 -299.00 -1.4950 -1.4825 -,0125 -.84
15 .191 344.270 .9308 -280. 15 -1 .4008 -1 .4232 .0224 1.58
15 .230 344.270 .9308 -280.60 -1.4030 -1 .4232 .0202 1.42
16 .004 344.270 .9308 -316,71 -1.5836 -1 .4232 -.1604 -1 1.27
7 .216 344.300 .9309 -280.40 -1.4020 -1.4229 .0209 1.47
1 .207 347.900 .9407 -274.00 -1.3700 -1 .3914 .0214 1.54
12 .029 348. 160 .9414 -289. 13 -1.4457 -1.3892 -.0564 -4.06
12 .016 348. 160 .9414 -293.00 -1 .4650 -1.3892 -.0758 -5.46
3 .901 350.000 .9463 -275.00 -1.3750 -1.3735 -.0015 -.11
4 .285 353.800 .9566 -271.20 -1 .3560 -1.3420 -.0140 -1 .05
1 .242 357.900 .9677 -265.00 . -1.3250 -1.3091 -.0159 -1.22
15 .897 360.940 .9759 -256.06 -1 .2803 -1.2854 .0051 .40
15 .999 360.940 .9759 -256.80 -1.2840 -1.2854 .0014 .11
16 .005 360.940 .9759 -283.74 1 .4187 -1.2854 -. 1333 -10.37
1 .513 368.200 .9955 -244.00 -1.2200 -1.2314 .01 14 .92
9 .461 369.970 1.0003 -245.58 -1 .2279 -1.2187 -.0092 -.76
9 .014 369.970 1.0003 -260.00 -1.3000 -1.2187 -.0813 -6.67
9 .326 373. 160 1.0089 -241.82 -1 .2091 -1 .1963 -.0128 -1 .07
9 .058 373.160 1.0089 -247.00 -1.2350 -1. 1963 -.0387 -3.24
11 .734 373. 160 1.0089 -240. 15 -1 .2008 -1 .1963 -.0045 -.37
12 .075 373. 160 1.0089 -245.98 -1 .2299 -1.1963 -.0336 -2.81
12 .014 373.160 1.0089 -256.00 -1.2800 -1 . 1963 -.0837 -7.00
4 .248 373.400 1,0096 -242. 10 -1.2105 -1 . 1 946 -.0159 -1.33
68
1 .
Second virial coefficients of propane
Data sources and ID numbers; ( )McGI ashan , (2)Kapallo, ( 3)Dymond/Sm th , (4)Strein, (5)Hahn,
1 i
(7)Gunn, (8)Brewer, (9)Beattie, 10)Bottomley, (IDCherney, ( 12)Deschner , (13)Jessen,

(
( 14)Kretschmer (15)Reamer, (16)Sage.

,
ID We ight Temp. T/Tc B Br(expt) Br.(cal

r
c) Di ff Diff.
K cm3/mol %
3 .923 375.000 1.0139 -237.00 -1.1850 -1 .1836 -.0014 -.12

7 .310 377.600 1.0210 -235-90 -1.1795 -1. 1661 -.0134 -1. 15
15 .492 377.600 1.0210 -234.95 -1.1748 -1. 1661 -.0087 -.74
15 .586 377.600 1.0210 -234.60 -1.1730 -1. 1661 -.0069 -.59
16 .008 377.600 1.0210 -254.72 -1 .2736 -1 .1661 -.1075 -9.22
1 .218 377.700 1.0212 -229.00 -1.1450 -1. 1654 .0204 1.75
12 .266 380.960 1.0300 -225. 18 -1 .1259 -1 .1439 .0180 1.57
1 . 100 388.500 1.0504 -213.00 -1.0650 -1 .0963 .0313 2.85
4 .709 394.000 1.0653 -213.70 -1 .0685 -1 .0633 -.0052 -.49
9 .908 398. 160 1.0765 -208.26 -1.0413 -1.0392 -.0021 -.20
9 .260 398. 160 1.0765 -21 1.00 -1 .0550 -1.0392 -.0158 -1 .52
11 .959 398.160 1.0765 -207.21 -1.0361 -1.0392 .0031 .30
12 .460 398. 160 1.0765 -209.79 -1 .0490 -1 .0392 -.0098 -.94
12 .015 398. 160 1.0765 -224.00 -1.1200 -1.0392 -.0808 -7.78
3 .952 400.000 1.0815 -206.00 -1.0300 -1 .0288 -.0012 -.12
1 . 169 400. 100 1.0818 -201.00 -1.0050 -1 .0282 .0232 2.26
15 .125 410.940 1.1111 -199.07 -.9954 -.9697 -.0256 -2.64
15 .106 410.940 1.1111 -199.60 -.9980 -.9697 -.0283 -2.92
4 .987 413.800 1.1188 -191.10 -.9555 -.9551 -.0004 -.05
9 .987 423. 160 1. 1441 -181.48 -.9074 -.9090 .0016 .16
9 .706 423. 160 1.1441 -183.00 -.9150 -.9090 -.0060 -.65
12 .111 423. 160 1.1441 -187.36 -.9368 -.9090 -.0278 -3.05
12 .017 423.160 1. 1441 -197.00 -.9850 -.9090 -.0760 -8.36
3 .914 430.000 1 626
. 1 -176.00 -.8800 -.8773 -.0027 -.31
4 1 .000 433.100 1.1710 -172.60 -.8630 -.8633 .0003 .04
15 .147 444.270 1.2012 -167.93 -.8397 -.8155 -.0241 -2.96
15 .125 444.270 1.2012 -168.40 -.8420 -.8155 -.0265 -3.25
7 .207 444.300 1.2013 -167.00 -.8350 -.8154 -.0196 -2.41
9 .903 448.160 1.21 17 -159.30 -.7965 -.7996 .0031 .39
9 .999 448.160 1.21 17 -160.00 -.8000 -.7996 -.0004 -.04
4 .953 453.500 1.2262 -156.20 -.7810 -.7785 -.0025 -.32
3 .909 470.000 1.2708 -143.00 -.7150 -.7175 .0025 .35
9 .669 473.160 1.2793 -140.04 -.7002 -.7065 .0063 .89
9 .400 473. 160 1.2793 -139.00 -.6950 -.7065 .0115 1.62
12 .100 473. 160 1.2793 -147.44 -.7372 -.7065 -.0307 -4.35
12 .021 473. 160 1.2793 -155.00 -.7750 -.7065 -.0685 -9.70
4 .983 474.900 1. 2840 -140.00 -.7000 -.7005 .0005 .07
15 .315 477.600 1.2913 141 .40 -.7070 -.6914 -.0156 -2.26
15 .241 477.600 1.2913 -142.00 -.7100 -.6914 -.0186 -2.70
4 .971 493.300 1. 3338 -128.10 -.6405 -.6410 .0005 .07
9 .297 498. 160 1.3469 -122.45 -.6123 -.6262 .0140 2.23
9 .163 498.160 1.3469 -121 .00 -.6050 -.6262 .0212 3.39
3 .658 500.000 1.3519 -123.00 -.6150 -.6208 .0058 .93
7 .787 510.900 1.3814 -1 17.20 -.5860 -.5895 .0035 .59
15 1.000 510.940 1.3815 -1 18.19 -.5910 -.5894 -.0016 -.27
15 .868 510.940 1.3815 -1 19.00 -.5950 -.5894 -.0056 -.95
9 .471 523. 160 1.4145 -109.57 -.5479 -.5564 .0086 1 .54
9 .356 523. 160 1.4145 -109.00 -.5450 -.5564 .01 14 2.05
12 .902 526.380 1.4232 -110.70 -.5535 -.5481 -.0054 -.99
12 .490 526.380 1.4232 -108.00 -.5400 -.5481 .0081 1.48
9 .498 548 . 60
1 1.4821 -97.55 -.4878 -.4952 .0074 1.50
9 .240 548. 160 1.4821 -96.00 -.4800 -.4952 .0152 3.06
3 .574 550.000 1.4871 -97.00 -.4850 -.4910 .0060 1.21
12 .51 570.460 1.5424 -91 .89 -.4595 -.4465 -.0129 -2.90
12 .821 570.460 1. 5424 -89.00 -.4450 -.4465 .0015 .34
12 .040 609.320 1.6475 -85. 19 -.4260 -.3728 -.0532 -14.26
Number of data points = 118; rms deviation = 1.20^.
69
1 52 2 1 50.
Table 4, (Continued).
Third virial coefficients of propane
Data sources and ID numbers: (1 )McGlashan, (2)Kapal lo. (3)Dymond/Smith, (4)Strein, (5)Hahn
(7)Gunn, (8)Brewer, (9)Beattie 10)Bottomley, (IDCherney, (12)Deschner
( (13)Jessen, ,
(14)Kretschmer, (5)Reamer
1 (1 6 )Sage.
,
ID Wei gilt Temp. T/T_ C Cr.(expt) Cp(cal c) Dif f

K ( cm3 /mo 1
)
16 .002 294.270 .7956 -10510. -.2628 -2.4978 2.2350

12 .163 303.160 .8197 -62760. -1 .5690 -1 .7060 .1370
15 .469 310.940 .8407 -54120. -1 .3530 -1 .1762 -.1768
15 .065 310.940 .8407 -65000. -1 .6250 -1.1762 -.4488
16 .006 310.940 .8407 861. .0215 -1. 762
1 1.1977
11 .755 323.160 .8738 -22470. -.5618 -.571 .0094
15 .329 327,600 .8858 -23530. -.5883 -.4044 -.1838
15 .523 327.600 .8858 -14000. -.3500 -.4044 .0544
16 .003 327.600 .8858 59710. 1.4928 -.4044 1 .8972
15 .722 344.270 .9308 -1 725. -.0431 .0416 -.0848
15 .912 344.270 .9308 2000. .0500 .0416 .0084
16 .009 344.270 .9308 42550. 1.0638 .0416 1 .0221
12 .023 348.160 .9414 29980. .7495 .1 141 .6354
15 .523 360.940 .9759 741 3. .1853 .2921 -.1068
15 .837 360.940 .9759 13000. .3250 .2921 .0329
16 .052 360.940 .9759 28280. .7070 .2921 .4149
9 .41 7 369.970 1.0003 19450. .4863 .3751 .1112
9 .997 373.160 1,0089 15890, .3973 .3978 -.0006
11 .576 373. 160 1.0089 191 20, .4780 .3978 .0802
12 .556 373.160 1.0089 19260, .481 5 .3978 .0837
15 .453 377.600 1.0210 12430, .3108 .4247 -.1 140
15 .207 377.600 1.0210 90 00. .2250 .4247 -.1997
16 .751 377.600 1.0210 14520. .3630 .4247 -.0617
12 .967 380.960 1.0300 18290. .4573 .4417 .01 55
9 .469 398.160 1.0765 15550. .3888 .4940 -.1053
1 .658 398.160 1.0765 16920. .4230 .4940 -.071
12 .696 398.160 1.0765 17160. .4290 .4940 -.0650
15 .992 410.940 1.1111 20000. .5000 .5060 -.0060
15_ .426 410.940 1.1111 25000. .6250 .5060 .1190
9 .357 423.160 1.1441 14960. .3740 .5039 -.1299
12 .563 423.160 1.1441 16800. .4200 .5039 -.0839
15 .995 444.270 1 .201 191 90. .4798 .4817 -.0020
15 .564 444.270 1 .2012 23000. .5750 .4817 .0933
9 .425 448.160 1 .21 17 1461 0. .3653 .4760 -.1108
9 .607 473.160 1.2793 14370. .3593 .4339 -.0747
12 .774 473.160 1.2793 15430. .3858 .4339 -.0482
15 .957 477.600 1.2913 181 20. .4530 .4259 .0271
15 .535 477.600 1.2913 21000. .5250 .4259 .0991
9 .689 498.160 1.3469 13090. .3273 .3887 -.061
15 .877 510.940 1.3815 16365. .4091 .3662 .0429
15 .195 510.940 1 .381 23000, .5750 .3662 .2088
9 .910 523.160 1 .4145 12780. .3195 .3456 -.0261
12 1 .000 526.380 1 ,4232 13840. .3460 .3403 .0057
9 .998 548.160 1 .4821 12630. .3158 .3065 .0092
12 .900 570.460 1 .5424 12540. .3135 .2757 .0378
12 1 .000 609.320 1 .6475 9373. .2343 .2305 .0038
Number of data points = 46.
70
8 5
1 6
2 9
3
4
Table 5. Behavior of coefficients of equation of stafe for

propane (eq (6)).
d/d ^ '
a 0 ~o B(p) C(p)
K K i^Pa
.10 300.609 283.690 1 .01 33 .45809 -.46999

.20 328.350 31 5 .259 1 .91 47 .46283 -.39609
.30 344.408 335.148 2.6487 „ 47075 -.32679
.40 354.668 348.633 3.21 78 .481 82 -.26259
.50 361 .308 357. 737 3.635f .49606 -.20390
.60 365 .501 363.647 3.923'. .51 347 -. 1 51 01
.70 367.994 367.205 4. 1 0'''8 .53404 -.1 041
.80 369.291 369.056 4, 2033 .55777 -.06335
.90 369.780 369.750 4.2^1 8 .58467 -.02867
1 .00 369. 850 369. 850 4.247 .61 473 0.00000
1.10 369.774 369.745 4*24! .64796 .02285
1 .20 369.305 369.071 4.2046 .68435 .0401
1 .30 368.1 43 367.354 4. 1 1 60 .72391 .0521
1 .40 366.050 364.193 3.9624 .76663 .05939
1 .50 362.843 359.257 3.7385 .81 251 .06220
1 .60 358.390 352.291 3.4467 .861 57 .061 07
1 .70 352.604 343.1 23 3.0963 .91 378 .05650
1 .80 345.429 331 .657 2.701 .9691 .04902
1 .90 336.837 31 7.879 2.2806 1 .02770 .0391
2.00 326.818 301 .853 1.8536 1 .08941 .02734
2.10 31 5.374 283.721 1 .441 1 .15428 .01 41
2.20 302.51 263.703 1 .0625 1 .22232 .00000
2.30 288.274 242.095 .7342 1 .29352 -.01464
2.40 272.683 219.261 .4677 1 .36789 -.02939
2.50 255.802 1 95.627 .2686 1 .44542 -.04389
2.60 237.713 171 .671 .1346 1 .5261 -.05782
2.70 218.534 147.900 .0562 1.60998 -.07092
2.80 198.415 124.827 .0183 1.69700 -.08298
2.90 177.545 102.943 .0042 1.78719 -.09381
3.00 156.139 82.685 .0006 1.88054 -.10330
3.10 134.434 64.403 .0000 1.97706 -.1 1135
3.20 112.662 48.340 .0000 2.07674 -.11793
3.30 91 .042 34.622 .0000 2.17959 -.12302
3.40 69.762 23.256 .0000 2.28560 -.12665
71
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72
1 ) 1
Table 7. Comparisons of experimental P-p-T data of propane

with eq (6).
Summary of P-P-T data comparisons.
R ange of Data No. of Deviations

Authors T(K) P(MPa) p ( kg/m3 Po nts
i Ap/p, rms AP/P,mean
(.%) (%)
Beattie [21 369-548 2.4 - 31.0 44-441 106 0.46 0.36

Deschner [221 303-609 0.1 - 14.2 1-418 236 1.28 0.92
Cherney [141 323-398 1.1 - 5.0 17-1 14 25 0.27 0. 17
Reamer 73 [ 1 31 1-51 1 0- 169.0
- 1-576 306 0.32 0.82
Dawson 21 [ 243-348 0.05- 0.18 1-3 18 0.20 0. 18
Dittmar [231 273-413 1.0 -103.5 320-590 325 0.21 1.41
TomI inson [981 278-328 1.06- 13.8 452-530 40 0.11 4.01
Ely [251 166-324 0.26- 42.8 508-651 222 0.06 4.62
Teichmann [94] 323-573 2.77- 60.9 108-461 148 0.69 0.83
Warowny [1021 373-423 0.3 - 6.4 5-170 51 0.83 0.24
Haynes [42] 90-300 0.6 - 37.5 493-741 196 0.07 8.27
Thomas [951
i sochores 370-623 2.0 - 40.0 35-486 215 0.43 0.32
i sotherms 258-370 0.6 - 35.7 35-549 51 1.41 2.24
Virial equation
(this report) 270-600 0.4 - 1.0 8.8 34 0.20 0.18
Total number of points used in fit = 1946

Overall rms density deviation = 0.76$
Overall mean pressure deviation = 2.41$
73
1. . 9
4
7
.
1 7 0.
8
Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)Beattie, (4)Deschner, (5)Reamer,
(13)Cherney, 7)Toml nson , (24)Ely, (26)Dittmar, (XXXX)Haynes, ( 51 , 52 )Thomas, (78)Teichmann,
( 1 i
(79)Warowny.
ID Data Ternp Dens ty

i De n s ty i L/O -J
p P ,
f^p Co
C^Cl CU
o 1 1
1 1 1 )
y •êxpt ca c 1
1 1
Point expt ca c 1 D i ff D 1 f f
No K nv-, 1 /I Kg/ irr rsy/ Ml MPa MP a p
1 . 00
1 270.000 9nn 8.82 -.05 .4057 .4055 .04
2 .1 00 9R0 .000 oon C5 •OZ 8. 82 -.06 .4242 .4240 .05
3 . 00
1 990.000 9 no o « oz 8.83 -.08 .4425 .4422 .08
4 . 00
1 300.000 . 9nn
zuu O • DZ 8.83 -. 1 .4607 .4602 . 1
5 . 00
1 31 0.000 9nn
. zuu o • oz 8.83 -. 1 .4787 .4781 .13
5 .1 00 390.000 9 no
. zuu O R9
R • OZ 8.83 -. 1 .4967 .4959 .16
7 , 00
1 330.000 9on R R9 8.84 -.1 . 51 45 .51 36 . 1
8 .100 340.000 9 no R R9 8.84 -. 21 .5323 .5313 .20

9 . 00
1 350.000 'JOO Q oz
o» Q9 8.84 -.22 .5500 .5489 .21
1 n . 00
1 o» OZ 8.84 -. 24 .5677 .5664 .22
1 on
1 "^7n onn . ÛU O • OZ R R4 - . 94
Z.H
9"^
1 9 on
1 -'OU . uw onn O • OZ -.25 .601 4 .94
• i. H
\ 3 • 00
1 390.000 oon O Q9
Q •OZ 8.84 -.25 .6203 .6188 .24
1 4 . 00
1 400.000 . ZUU 0» OZ 8. 84 -. 26 .6378 .6362 .25
idin nnn O AA O • OZ O . 0*T .o^ ^— . U ^ -JO
nn 47n nnn O AA
zUU 0« OZ R. R4 9^ .6726 .fi71 0 .94
1
1 D 1 . . /O1 u • ^H
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R . OH - 9S fiQOO
.u ûu .OOOJ • 94
ZH
1
1
S
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/ u / . /u ô • 94
ZH
nn A^c\ nnn o oo
1 Q 1
• 200 O.OZ 0 . 04 - . 9/1
ZH . 794ft
/ Z*+D . /Z 9Q
79 Z . ZJ)
90
^.\J no1 4f^n nnn O AA
.zuu Q QO
CS« OZ R R4 -.Z 9"^ --J • 74
/H Q
^ 1
1 . 7409
H UZ.
/ .
9"^
Z-J
21 . 001 470. ono O AA O QO
Q . OZ 8.84 -.93 . 7591 .7574 . 22
no 4Rn nnn O AA Q QO _ . oo • 774
9? 1 . ZUU O.OZ O. R4
fl OH z^ • 77fi4
/ / VJH /H7 / / * 99
z z
9"^ nn1 4Qn nnn O AA Q . QO
O OZ O . 9A
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Z 1
24 . 001 ^nn.nnn OAA

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O.OZ 8.84 -.21 .8108 .8092 .20
25 . 001 sin. nnn .200 8.82 R.R4
O . OH -.90 .8280 .8264 . 9 1
26 .100 520.000 .200 8.82 8.84 -.19 .8452 .8436 .19

27 ,100 530.000 .200 8.82 8.84 -.18 .8623 .8608 .18
28 .100 540.000 .200 8.82 8.83 -.17 .8795 .8780 .17
29 .100 550.000 .200 8.82 8.83 -.17 .8966 .8952 .16
30 .100 560.000 .200 8.82 8.83 -.16 .9138 .91 24 .15
31 .100 570.000 .200 8.82 8.83 -.15 .9309 .9295 .15
32 .100 580.000 .200 8.82 8.83 -.14 .9480 .9467 .14
33 .100 590.000 .200 8.82 8.83 -.13 .9651 .9638 .13
34 .100 600.000 .200 8.82 8.83 -.12 .9822 .9810 .12
74
1 .
( 3)Chern8y, (1 7)Toml Inson, (24)Ely, ( 26 )D ttinar , (XXXX)Haynes,
1 i 51 , 52 )Thomas, (78)Teichmann,
(
(79)Warowny.
ID Data Weight Temp, Dens ty

i Dens tyI Dens tyI
Pexpt Pcah Pressure
Point expt calc Diff. Di ff
No. K mol/L kg/irr kg/m^ MPa I'â %
2 35 1 .000 243.150 .045 1 .99 1 .99 -. 1 .0887 .0886 .10

2 36 1 .000 243.150 .060 2.63 2.63 -.02 .1 161 .1 160 .02
2 37 1 .000 258.150 .060 2.62 2.63 -.09 .1237 .1236 .09
2 38 1 .000 258.150 .045 1 .99 1.99 -.11 .0945 .0944 .11
2 39 1 .000 273.150 .071 3.12 3.12 -.16 .1 552 .1550 .15
2 40 1 .000 273.150 .045 1.99 1.99 -.19 .1003 .1001 .19
2 41 1 .000 273.150 .060 2.63 2.63 -.14 .1316 .1314 .14
2 42 1 .000 288.150 .059 2.62 2.62 -.16 .1386 .1383 .16
2 43 1 .000 288.150 .021 .91 .91 -.26 .0490 .0489 .26
2 44 1 .000 288.150 .045 1 .99 1 .99 -.18 .1060 .1058 .18
2 45 1 .000 288.150 .071 3.12 3.12 -.19 .1643 .1640 .19
2 46 1 .000 288.150 .037 1 .63 1 .64 -.28 .0874 .0872 .27
2 47 1 .000 323.1 50 .037 1 .63 1 .64 -.22 .0983 .0981 .22
2 48 1 .000 323.150 .070 3.09 3.10 -.25 .1838 .1834 .24
2 49 1 .000 323,1 50 .021 .91 .91 -.12 .0551 .0551 .12
2 50 1 .000 323.150 .045 1 .99 1.99 -.25 .1 193 .1 190 .25
2 51 1 .000 348.150 .060 2.62 2.63 -.27 .1694 .1690 .27
2 52 1 .000 348.150 .045 1 .99 2.00 -.34 .1290 .1286 .34
75
3 , .
Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)Beattie, (4)Dsschner, (5)Reainer,
(l3)Cherney, 7 )Tom inson
( 1 I (24)Ely, (26)0 ittmar
, (XXXX)Haynes, (51 ,52 )rhomas,
, 78 )Te ichmann (
(79)Warowny.
ID Data Weight Temp. .

Dens ty i Dens ty
i Dens ty i
Pexpt Pcalc Pressui
Point expt calc Di ff. Dif f
No. K mol/L kg/in^ kg/m-^ % MPa MPa %
13 53 1.000 323.150 .474 20.88 20.91 -.15 1 .0801 1 .0788 .13

13 54 1.000 323.150 .494 21 .79 21 .82 -.16 1 .1 186 1 .1171 .13
13 55 1.000 323.150 .5 33 23.48 23.54 -.25 1 . 1 896 1.1872 .20
13 56 1.000 323.150 .559 24.63 24.65 -.08 1 .2341 1.2334 .06
13 57 1.000 323.150 .577 25.46 25.53 -.26 1 .2686 1.2660 .20
13 58 1.000 323.150 .608 26.82 26.88 -.21 1 .3203 1 .3181 .16
13 59 1.000 323.150 .631 27.81 27.88 -.25 1 .3578 1.3552 .19
13 60 1.000 323.150 .695 30.63 30.74 -.34 1 .4601 1.4565 .25
13 61 1.000 323.150 .773 34.10 34.21 -.34 1 .5756 1.5719 .23
13 62 1.000 323.150 .872 38.44 38.66 -.57 1 . 7094 1 .7031 .37
13 63 1.000 373.1 50 .383 16.90 16.95 -.27 1 .0832 1 .0805 .24
13 64 1.000 373.1 50 .406 17.92 17.97 -.28 1 .1419 1 .1390 .26
13 65 1.000 373.150 .462 20.36 20.41 -.25 1 .2797 1 .2769 .22
13 66 1.000 373.150 .534 23.57 23.60 -.15 1 .4540 1 .4521 .13
13 67 1.000 373.150 .634 27.98 28.02 -.15 1 .6840 1.6819 .13
13 68 1.000 373.150 .781 34.42 34.45 -.09 1 .9971 1.9956 .08
13 69 1.000 373.150 1 .014 44.71 44.67 .09 2.4429 2.4446 -.07
13 70 1.000 373.150 1 .447 63.79 63.58 .34 3.1 127 3.1192 -.21
13 71 1.000 373.150 2.520 111.11 110.91 .18 4.0733 4.0757 -.06
13 72 1.000 398.150 .535 23.61 23.67 -.24 1.5847 1 .581 .22
13 73 1.000 398.150 .636 28.06 28.10 -.15 1 .8431 1 .8407 .13
13 74 1.000 398.150 .784 34.58 34.60 -.06 2.2018 2.2007 .05
13 75 1.000 398.150 1 .021 45.04 44.98 .13 2.7267 2.7295 -.11
13 76 1.000 398.150 1 .464 64.57 64.25 .50 3.5565 3.5688 -.34
13 77 1.000 398.150 2.580 113.79 113.26 .47 4.9781 4.9893 -.22
76
. 7 ,
Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)Beattie, (4)Deschner, (5)Reanier,
(13)Cherney, 7 )Tom II nson , (24)Ely, (26)Dittmar,
( 1 (XXXX )Haynes, (51 , 52 )Thomas, 78 )Te ichmann
(
(79) Warowny
Data Weight Temp. Dens ty

i Dens ty
I Dens ty i
expt cal c Pressur
Point expt calc Diff. Diff.
No. K mol/L kg/nr kg/rrr MPa
3 78 1 .000 369.960 .999 44.06 43.62 1 .02 2.3659 2.3838 -.75

3 79 1 .000 373.150 .999 44.06 43.83 .53 2.4085 2.4131 -.40
3 80 1 .000 398.150 .999 44.06 43.95 .26 2.6770 2.6826 -.21
3 81 1 .000 423.150 .999 44.06 43.97 .22 2.9354 2.9408 -.18
3 82 1.000 448.150 .999 44.06 43.97 .21 3.1887 3.1945 -.18
3 83 1 .000 473.150 .999 44.06 43.99 .16 3.4400 3.4448 -.14
3 84 1 .000 498.150 .999 44.06 44.02 .10 3.6892 3.6927 -.09
3 85 1 .000 523.150 .999 44.06 43.94 .28 3.9284 3.9385 -.26
3 86 1.000 548.150 .999 44.06 44.01 .13 4.1 776 4.1826 -.12
3 87 1 .000 369.960 1.499 66.09 65.33 1.17 3.1087 3.1302 -.69
3 88 1 .000 373.150 1.499 66.09 65.54 .85 3.1 715 3.1877 -.51
3 89 1 .000 398.150 1.499 66.09 65.68 .62 3.61 12 3.6257 -.43
3 90 1 .000 423.150 1.499 66.09 65.68 .62 4.0317 4.0505 -.46
3 91 1 .000 448.150 1.499 66.09 65.72 .57 4.4441 4.4642 -.45
3 92 1 .000 473.150 1.499 66.09 65.76 .50 4.8504 4.8706 -.41
3 93 1 .000 498.150 1.499 66.09 65.80 .44 5.251 5.2716 -.38
3 94 1 .000 523.150 1.499 66.09 65.68 .63 5.6367 5.6682 -.55
3 95 1 .000 548.150 1.499 66.09 65.87 .33 6.0430 6.0613 -.30
3 96 1 .000 369.960 1.998 88.12 87.76 .41 3.6295 3.6361 -.18
3 97 1 .000 373.150 1.998 88.12 87.33 .91 3.7044 3.7201 -.42
3 98 1 .000 398.150 1.998 88.12 87.44 .78 4.3357 4.3554 -.45
3 99 1 .000 423.150 1.998 88.12 87.45 .77 4.9386 4.9640 -.51
3 1 00 1 .000 448.150 1.998 88.12 87.55 .66 5.5293 5.5559 -.48
3 101 1 .000 473.150 1.998 88.12 87.61 .59 6.1079 6.1361 -.46
3 102 1 .000 498.150 1.998 88.12 87.71 .48 6.6314 6.7074 -.39
3 103 1 .000 523.150 1.998 88.12 87.78 .39 7.2478 7.2719 -.33
3 104 1 .000 548.150 1.998 88.12 87.86 .30 7.8101 7.8308 -.26
3 105 1 .000 373.150 2.498 110.16 109.65 .46 4.0581 4.0642 -.15
3 106 1 .000 398.150 2.498 110.16 109.38 .71 4.8940 4.9111 -.35
3 107 1 .000 423.150 2.498 110.16 109.46 .63 5.6975 5.7193 -.38
3 108 1 .000 448.150 2.498 110.16 109.59 .52 6.4818 6.5048 -.35
3 109 1 .000 473.150 2.498 110.16 109.70 .42 7.2518 7.2746 -.31
3 110 1 .000 498.150 2.498 110.16 109.31 .31 8.0128 8.0328 -.25
3 111 1 .000 523.150 2.498 110.16 109.94 .19 8.7677 8.7813 -.16
3 112 1 .000 548.150 2.498 110.16 110.05 .10 9.5154 9.5235 -.08
3 113 1 .000 369.960 2.998 132.19 132.47 -.22 4.1300 4.1284 .04
3 114 1 .000 373.150 2.993 132.19 132.13 .05 4.2708 4.2713 -.01
3 115 1 .000 398.150 2.998 132.19 131.61 .44 5.3287 5.3386 -.19
3 116 1 .000 423.150 2.998 132.19 131.62 .43 6.3429 6.3583 -.24
3 117 1 .000 448.150 2.998 132.19 131.82 .28 7.3380 7.3516 -.19
3 118 1 .000 473.150 2.998 132.19 132.63 -.33 8.3472 8.3268 .24
3 119 1 .000 498.150 2.998 132.19 132.17 .02 9.2874 9.2886 -.01
3 120 1 .000 523.150 2.998 132.19 132.31 -.09 10.2480 10.2398 .08
3 121 1 .000 548.150 2.998 132.19 132.43 -.18 1 .2005
1 11.1822 .16
3 122 1 .000 373.150 3.497 154.22 154.49 -.17 4.3884 4.3874 .02
3 123 1 .000 398.150 3.497 154.22 153.87 .23 5.6752 5.6802 -.09
3 124 1 .000 423.150 3.497 154.22 153.87 .23 6.9144 6.9230 -.12
3 125 1 .000 448.150 3.497 154.22 154.14 .05 8.1364 8.1392 -.03
3 126 1 .000 473.150 3.497 154.22 154.35 -.09 9.3432 9.3372 .06
3 127 1 .000 498.150 3.497 154.22 154.55 -.21 10.5398 10.5214 .18
3 128 1 .000 523.150 3.497 154.22 154.71 -.32 1 .7274
1 11.6944 .28
3 129 1 .000 548.150 3.497 154.22 154.85 -.41 12.9068 12.8582 .38
3 130 1 .000 369.960 3.997 176.25 178.48 -1 .25 4.2486 4.2470 .04
3 131 1 .000 373.150 3.997 176.25 176.55 -.17 4.4502 4.4496- .01
3 132 1 .000 398.150 3.997 176.25 175.63 .35 5.9650 5.9729 -.13
3 133 1 .000 423.150 3.997 176.^5 175.88 .21 7.4443 7.4531 -.12
77
; 6
11 0
5 02
1 3
(13)Cherney, 7 )Tom nson, (24)Ely, (26)D ittinar, (XXXX )Haynes, (51 ,52)Thomas, (78)Teichmann,
( 1 I i
(79)Warowny.
ID Data Weight Temp. Dens ty

i Dens tyI Dens ty i
expt ca c
I
Pressure
Po nti expt ca Ic Diff. Diff.
No. K mot/L kg/nr kg/nr MPa MPa %
134 1 .000 448.150 3.997 176.25 176.27 - .01 8.91 15 8.9107 .01
155 1 .000 473.150 3.997 176.25 176.53 -. 1 1 0.3655 1 0. 3522 . 1
136 1 .000 498.1 50 3.997 176.25 176.78 -.30 1 1.81 25 1 1 .781 .27
137 1 .000 523.150 3.997 176.25 177.00 -.42 1 3. 2523 13,1 996 .40
138 1 ,000 548.150 3.997 176.25 177.29 -.59 1 4.6942 1 4.6087 .59
139 1 .000 373.150 4.496 198.28 196.07 1.13 4.4826 4,4857 -.07
140 1 .000 398.150 4.496 198.28 196.75 .78 6.2305 6.2498 -.31
141 1 .000 423.150 4.496 198.28 197.39 .45 7.9652 7.9874 -.28
142 1 .000 448.1 50 4.496 198.28 198.01 .14 9.6998 9.7101 -.11
143 1 .000 473.150 4.496 198.28 198.43 -.07 1 1.4284 1 1.421 .06
144 1 .000 498.150 4.496 198.28 198.73 -.23 13.1 510 1 3.1 221 .22
145 1 .000 523.150 4.496 198.28 199.00 -.36 14.8694 14.8140 .37
146 1 .000 548.1 50 4.496 198.28 1 99.21 -.47 16.5808 16.4973 .51
147 0.000 373.150 4.996 220.31 212.79 3.54 4.5049 4.51 49 -.22
148 0.000 398.1 50 4.996 220.31 217.08 1 .49 6.4959 6.5403 -.68
149 1 .000 423.150 4.996 220,31 218.50 .83 8.5133 8.5629 -.58
150 1 .000 448.150 4.996 220.31 219,42 .41 10.5439 10.5812 -.35
151 1 .000 473.150 4.996 220.31 220.00 .14 12.5765 1 2.5940 -.14
152 1 .000 498.150 4.996 220.31 219.04 .58 14.5108 14.6004 -.51
153 1.000 523.150 4.996 220.31 219.56 .34 16.5352 16.5999 -.39
154 1 .000 548.150 4.996 220.31 221 .08 -.35 18.6691 18.5919 .42
155 1 .000 369.960 5.995 264.37 264.89 -.19 4.2708 4.2702 .01
156 0.000 373.150 5.995 264.37 256.35 3.13 4.5758 4.5980 -.48
157 0.000 398.150 5.995 264.37 259.68 1 .81 7. 1657 7.2565 -1 .25
158 1 .000 423.150 5.995 264.37 261 .66 1.04 9.8680 9.9698 -1 .02
159 1 .000 448. 150 5.995 264.37 262.81 .60 12.61 70 12.7048 -.69
160 1.000 473.150 5.995 264.37 263.54 .32 1 5.3862 1 5.4493 -.41
161 1 .000 498.150 5.995 264.37 264.01 .14 18. 1 61 18. 1961 -.19
162 1 .000 523.150 5.995 264.37 264.37 .00 20.9408 20.9410 -.00
163 1 ,000 548.150 5,995 264.37 264.65 -.1 23.71 82 23.681 .16
164 1 .000 369.960 6.994 308.44 307.03 .46 4.4725 4.4878 -.34
165 1 .000 373.150 6.994 308.44 305.84 .85 4.891 4.9268 -.73
166 1 .000 398.150 6.994 308.44 305.85 .85 8.3826 8.4810 -1.16
167 1 .000 423.150 6.994 308.44 306.68 .57 1 2.01 92 12.1 299 -.91
168 1 .000 448.150 6.994 308.44 307.34 .36 15.7246 15.8219 -.61
169 1 .000 473.150 6.994 308.44 307.98 .1 5 19.4328 19.5351 -.27
170 1 .000 498.1 50 6.994 308.44 308.11 , 1 23.21 15 23.2569 -.19
171 1 .000 523.150 6.994 308.44 308.31 .04 26.9585 26.9794 -.08
172 1 .000 548.1 50 6.994 308.44 308.48 -.01 30.7045 30.6972 .02
173 1 .000 369.960 7.994 352.50 351 .48 .29 5.5587 5.6039 -.81
174 1 .000 373.1 50 7.994 352.50 351 .23 .36 6.1504 6.2121 -.99
175 1 .000 398.150 7.994 352.50 351 .03 .42 10.9472 1 1 .0694 -1.10
176 1 .000 423.150 7.994 352.50 351 .51 .23 15.9019 16.0195 -.73
177 1 .000 448.150 7.994 352.50 351 .78 .20 20.9044 21 .01 44 -.52
178 1 .000 473.150 7.994 352.50 352.07 .12 25.9493 26.0295 -.31
179 1 .000 493.150 7.994 352.50 352.20 .09 30.9832 31 .0500 -.22
180 1 .000 369.960 8.993 396.56 395.92 .16 9.0068 9.0845 -.86
181 1 .000 373,150 8.993 396.56 395.64 .23 9.81 23 9.9297 -1.18
182 1 .000 398.1 50 8.993 396.56 395.74 .21 16.4623 16.6064 -.87
183 1 .000 423.150 8.993 396.56 395.85 .18 23.1301 23.3383 -.68
184 1 .000 448.150 8.993 396.56 395.72 .21 29.8676 30.0913 -.74
185 1 .000 369.960 9.992 440.62 440.44 .04 17.3357 17.3862 -.29
186 1 .000 373.150 9.992 440.62 440.03 .14 18.3824 1 8.5461 -.88
187 1 .000 398.150 9.992 440.62 439.81 .19 27.3699 27.6442 -.99
78
1 ,
Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)Beattie, (4)Deschner, (5)Reanner
(13)Cherney, ( 17)Toml inson, (24)Ely, (26)0ittmar, (XXXX)Haynes ( 51 , 52)Thomas
, (78 )Te ichmann
(79)Warowny.
D Data Weight Temp. Dens ty

i Dens ty i Dens ty i
expt cal c Pressure
Point expt ca c
I Diff. Diff.
No. K mol/L kg/m- kg/m^ MPa MPa %
26 188 0.000 373. 150 7.257 320.00 331.01 -3.33 5.3937 5. 1269 5.20
26 189 0.000 383. 150 7.257 320.00 326.39 -1 .96 6.8647 6.6492 3.24
26 190 0.000 393. 150 7.257 320.00 325.33 -1 .64 8.4337 8.1975 2.88
26 191 0.000 403. 150 7.257 320.00 324.36 -1 .34 10.0028 9.7631 2.45
26 192 0.000 413. 150 7.257 320.00 323.52 -1 .09 1 1.5718 11.3411 2.03
26 193 0.000 363. 150 7.710 340.00 349.40 -2.69 4.2169 3.9629 6.41
26 194 0.000 373.150 7.710 340.00 347.56 -2. 18 5.9821 5.6812 5.30
26 195 0.000 38 3.150 7.710 340.00 345.91 -1.71 7.7473 7.4395 4. 14
26 196 0.000 393.150 7.710 340.00 345.96 -1.72 9.6105 9.2223 4.21
26 197 0.000 403. 150 7.71 0 340.00 343.35 -.97 11.2776 1 .0223
1 2.32
26 198 0.000 413. 150 7.710 340.00 343.43 -1.00 13. 1409 12.8350 2.38
26 199 1.000 363. 150 8. 164 360.00 366.03 -1 .65 4.9033 4.6147 6.25
26 200 1.000 373.150 8.164 360.00 363.96 -1.09 6.8647 6.6189 3.71
26 201 1.000 383. 150 8. 164 360.00 363.50 -.96 8.9241 8.6547 3.1 1
26 202 1.000 393. 150 8. 164 360.00 364.00 -1.10 11.0815 10.7121 3.45
26 203 1.000 403. 150 8. 164 360.00 363.34 -.92 13. 1409 12.7852 2.78
26 204 1.000 413. 150 8. 164 360.00 362.74 -.75 15.2003 14.8699 2.22
26 205 1.000 353. 150 8.617 380.00 380.82 -.22 3,5304 3.4836 1.34
26 206 1.000 363. 150 8.617 380.00 381.36 -.36 5.8840 5.7809 1.78
26 207 1.000 373.150 8.617 380.00 381 .32 -.35 8.2376 8. 1 146 1.52
26 208 1.000 383 . 50
1 8.617 380.00 381 .94 -.51 10.6892 10.4727 2.07
26 209 1.000 393. 150 8.617 380.00 382.27 -.59 13.1409 12.8483 2.28
26 210 1.000 403. 150 8.617 380.00 381.77 -.46 15.4945 15.2369 1.69
26 211 1.000 413.150 8.617 380.00 381 .91 -.50 17.9462 17.6352 1.76
26 212 1.000 353. 150 9.071 400.00 400.11 -.03 5.0014 4.9903 .22
26 213 1.000 363. 150 9.071 400.00 401 .42 -.35 7.8453 7.6760 2.21
26 214 1.000 373. 150 9.071 400.00 401.47 -.37 10.5912 10.3864 1.97
26 215 1.000 383.150 9.071 400.00 401 .40 -.35 13.3370 13. 1 144 1.70
26 216 1.000 393. 150 9.071 400.00 401.28 -.32 16.0829 15.8552 1.44
26 217 1.000 403.150 9.071 400.00 401 .13 -.28 18.8288 18.6054 1.20
26 218 1.000 413. 150 9.071 400.00 400.98 -.24 21 .5746 21.3622 .99
26 219 1.000 343.150 9.298 410.00 409.26 .18 3. 1381 3.2105 -2.25
26 220 1.000 353.150 9.298 410.00 410.01 -.00 6.0801 6.0794 .01
26 221 1.000 363. 150 9.298 410.00 410.99 -.24 9.1202 8.9770 1.60
26 222 1.000 373.150 9.298 410.00 41 1.01 -.25 12.0622 11.8944 1.41
26 223 1.000 383.150 9.298 410.00 410.95 -.23 15.0042 14.8261 1.20
26 224 1.000 393. 150 9.298 410.00 410.86 -.21 17.9462 17.7681 1.00
26 225 1.000 403. 150 9.298 410.00 410.75 -.18 20.8882 20.7174 .82
26 226 1.000 413.150 9.298 410.00 411 .03 -.25 23.9282 23.6714 1 .08
26 227 1.000 343. 150 9.524 420.00 419.02 .23 4.2169 4.3406 -2.85
26 228 1.000 353.150 9.524 420.00 420.08 -.02 7.4531 7.4407 .17
26 229 1.000 363.150 9.524 420.00 420.16 -.04 10.5912 10.5627 .27
26 230 1.000 373.150 9.524 420.00 420.15 -.04 13.7293 13.7002 .21
26 231 1.000 383.150 9.524 420.00 420.53 -.13 16.9655 16.8486 .69
26 232 1.000 393.150 9.524 420.00 420.41 -.10 20. 1036 20.0047 .49
26 233 1.000 403.150 9.524 420.00 420.29 -.07 23.2418 23. 1657 .33
26 234 1.000 413. 150 9.524 420.00 420.52 -.12 26.4780 26.3296 .56
26 235 1.000 343. 150 9.751 430.00 430.09 -.02 5.7859 5.771 .26
26 236 1.000 353.150 9.751 430.00 430.03 -.01 9. 1202 9.1 145 .06
26 237 1.000 363.150 9.751 430.00 429.91 .02 12.4544 12.4742 -. 16
26 238 1.000 373.150 9.751 430.00 430. 18 -.04 15.8868 15.8451 .26
26 239 1.000 383. 150 9.751 430.00 430.37 -.09 19.3191 19.2237 .50
26 240 1.000 393. 150 9.751 430.00 430. 17 -.04 22.6534 22.6071 .20
26 241 1.000 403. 150 9.751 430.00 429.98 .00 25.9876 25.9931 -.02
26 242 1.000 413.150 9.751 430.00 430.42 -.10 29.5180 29.3797 .47
26 243 1.000 333.150 9.978 440.00 439.77 .05 3.9227 3.9617 -.99
79
. . 4
6
C
1 1 3
7 63 , .
Data sources and ID numbers: (l)Virlal Equafion, (2)Dawson, (3)Bedhtie, (4)Deschner, (5)ReaiTier,
(I.5)Cherney, 7 ) Tom nson (24)Ely, (26 )D t htiar
( 1 I i (XXXX)Haynes, ( 51 , 52 )Tho(nas,
,
i78 fa ichmann
,
( )
(79)Warowny
1 D Data We ght i Temp Dens ity Dens ty i Dens tyi

expt Pcalc Pressure
'ô i nt expt ca cI iff. D i f f
No • I\ mo /Li kg/ in kg/m^ MP a To
26 244 1 .000 343. 1 50 9.978 440 .00 440.03 .Ul 7 1 1 A 13

.(Jo
11
26 245 1 .000 353. 1 50 9.978 440.00 440. 15 11.1/ yo 1 jI
.J 1
7t^<^0 •7 1
26 246 1 .000 363.1 50 9.973 440.00 439.31 4 . / UU
1 1
1
1 4A • ID^dL
26 247 1 .000 373.1 50 9.978 440.00 439.87 .Uj 1
o 1
XXO A
O . jjo4
26 243 1 .000 383. 1 50 9.978 440.00 439.90 .02 21 .9669 21 .9969 -.1 4
249 393 . 50 9.978 440 .00 439.62 .09 o c:
z5.4yA Ci~t~t
25 .62 A O
-.48
26 1 .000 1 /j 1
26 250 1 .000 403. 50 1 9.973 440c 00 439.37 • 4A1

1 29.0277 29.2457 -.75
26 251 1 .000 41 3. 50 1 9.978 440.00 439.43 . 3 1 32.6561 32.8586 -.65
26 252 1 .000 333.1 50 10.205 450.00 449.22 .17 5.6879 5 .8507 -2.78
26 253 1 .000 343.150 10.205 450.00 449.53 .09 9.61 05 9.71 06 -1 .03
26 254 1 .000 353.150 10.205 450.00 449.45 .1 2 13.4351 1 3.5808 -1 .07
26 255 1 .000 363.150 10.205 450.00 449.32 .1 5 17 .2597 1 7 . 4572 -1.13
26 256 1 .000 373.1 50 10.205 450.00 449.20 .1 8 21 .0843 21 .3369 -1.13
26 257 1 .000 383.150 10.205 450.00 449.39 .14 25.0070 25.21 75 -.84
26 253 1 .000 393. 50 1 10.205 450.00 449.02 .22 28. 7335 29.0970 -1 .25
26 259 1 .000 403.1 50 10.205 450.00 449.45 .1 2 32. 7542 32.9739 -.57
26 260 1 .000 41 3.1 50 10.205 450.00 449.13 .19 36.4307 36.8466 -.99
26 261 1 . 000 323. 150 10.431 450.00 459.54 .10 3.9227 4.0265 -2.53
26 262 1 .000 333. 50 1 10.431 460.00 459.89 .02 3.1 395 8. 1683 -.35
26 263 1 .000 543.150 10.431 460.00 459.44 .12 1 2. 1602 1 2.31 35 -1 .29
26 264 1 .000 353. 50 1 10.431 460.00 459.38 . 1 16.2790 16.4734 -1.18
26 265 1 .000 363.150 10.431 460.00 459.61 .09 20.4959 20.6299 -.65
26 266 1 .000 373. 50 1 10.431 460.00 459.27 . 1 24.5166 24. 7857 -1 .09
26 267 1 .000 383. 50 1 1 0. 431 460.00 458.74 .28 28.4393 28.9390 -1 .73
26 263 1 .000 393. 50 1 1 0.431 460.00 459.21 . 1 7 32. 7542 33.0881 -1 .01
26 269 1 .000 403 . 1 50 1 0.431 480.00 453.99 .22 36. 7749 37.231 -1 .23
-.91A1
26 270 1 .000 41 3.1 50 1 0.431 460.00 459.21 . 1 / 40.9:^1 0 41 .3686
26 271 1 .000 313.150 10.658 470.00 469.55 . 1 1 .961 2.0694 -5 . 22
26 272 1 .000 323. 50 1 10.658 470.00 469.48 . 1 6.3743 6.5168 -2.19
26 273 1 .000 333. 50 1 10.658 470.00 469.03 .zO 1 u • Doyz 1 A CSC AO -Z .5o
26' 274 1 .000 343. 50 1 10.658 470.00 469.33 • 4A1
1 1 ^ • ZUUJ 1 D • 4z4o -11 .4d
26 275 1 .000 353. 50 1 10.658 470.00 469.00 1 y • ^1 1
1
A
9. o AO
O /yz "7 1
26 276 1 .000 363. 50 1 10.658 470.00 468.98 . 22 23. 9282 24 .3309 -1 .55
26 277 1 .000 373 . 50 1 10.658 470.00 463.97 Zo . j4 Z Zo t 1 1 1^ -1 1 .
RO
Dz
AC\
26 278 1 .000 383. 50 1 10.658 470.00 463.98 •ZZ jZ . /y4Z J J. Z\ oo -\1 .4U
26 279 1 .000 393. 50 1 10.658 470.00 468.79 .26 j/.Ooyl J 1 .o5z4 -1 . DO
A
26 280 1 .000 403. 50 1 10.658 470.00 463.84 .25 41 .4821 42 .0775 -1.41
1 ^
26 281 1 .000 41 3. 50 1 10.658 470.00 469.08 .20 45.9932 46. 4932 -1 .08
26 282 1 .000 313.1 50 10.885 480.00 478.83 .24 4. 41 30 4 . 7554 -7.20
26 283 1 .000 323.1 50 10.885 480.00 479.03 .20 9.21 83 9.5356 -3 .33
26 234 1 .000 333.150 10.885 480.00 473.92 .23 13.9254 1 4.31 44 -2.72
26 285 1 .000 343.150 10.885 480.00 478.84 .24 13.6326 19.0895 -2.39
26 286 1 .000 353.1 50 10.885 480.00 479.01 .21 23.4379 23.8590 -1 .77
26 287 1 .000 363 . 50 1 10.885 480.00 478.96 .22 28.1451 23.6213 -1 .66
26 283 1.000 373.150 10.385 480.00 473.93 .22 32.8523 33.3751 -1 .57
26 289 1 .000 383.150 10.835 480.00 478.92 .22 37.5595 33.1 191 -1 .47
26 290 1 .000 393.1 50 10.835 480.00 479.29 .15 42.4623 42.3525 -.91
26 291 1 .000 403.150 10.885 480.00 479.14 .18 47.0719 47.5743 -1 .06
26 292 1 .000 413.150 10.885 430.00 479.17 .17 51 .7791 52.2839 -.97
26 293 1 .000 303.150 11.112 490 . 00 488.63 .28 2.451 2.8842 -15.00
26 294 1 .000 313.150 11.112 490.00 483.96 .21 7.6492 8.0183 -4.60
26 295 1 .000 323.150 11.112 490.00 439.23 .16 12.3467 13.1463 -2.28
26 296 1 .000 333.150 11.112 490.00 489.25 .15 17.9462 18.2665 -1 .75
26 297 1 .000 343.150 11.112 490.00 439.23 .15 23.0456 23.3776 -1 .42
26 298 1 .000 353.150 11.112 490.00 489.33 .14 28.1451 28.4782 -1.17
26 299 1 .000 363.150 11.112 490.00 439.20 .16 33.1465 33.5671 -1 .25
80
. 1. 1 .
Data sources and ID numbers: (l)VIrlal Equation, (2)Dawson, (3)Beattie, (4)Deschner, (5)Reainer,
(13)Cherney, ( 7)Tom 11 nson, (24)Ely, (26)Dittmar, (XXXX)Haynes, (51 ,52 )Thomas, (78)Teichrnann,
1
(79) Warowny
ID Data Weight Temp. Dens ity Density Dens ty Pressure

I
expt cal c
Point expt ca Ic DIff Diff
No. K mol/L kg/m-' kg/rrr % MPa IvPa %
26 300 1.000 373.150 1 .1 12 490.00 489.29 .15 38.2459 38.6436 -1 .03

26 301 1.000 383.1 50 1.112 490.00 489.22 .16 43.2473 43.7066 -1 .05
26 302 1.000 393.150 1.112 490.00 489.03 .20 48. 1507 48.7555 -1.24
26 303 1.000 403.150 1.112 490.00 489.18 .17 53.2501 53.7898 -1 .00
26 304 1.000 413.150 1 .112 490.00 489.19 .17 58.2515 58.8087 -.95
26 305 1.000 303.150 1.339 500.00 498.86 .23 5.9821 6.4211 -6.84
26 306 1.000 313.150 1.339 500.00 498.93 .21 1 .4738
1 1 .9256
1 -3.79
26 307 1.000 323.150 1.339 500.00 499.02 .20 16.9655 17.4172 -2.59
26 308 1.000 333.1 50 1.339 500.00 499.12 .18 22.4572 22.8951 -1 .91
26 309 1.000 343.150 1.339 500.00 499.04 .19 27.8509 28.3586 -1 .79
26 310 1.000 353.1 50 1.339 500.00 499.01 .20 33.2445 33.8068 -1 .66
26 31 1 1.000 363.1 50 1.339 500.00 499.00 .20 38.6382 39.2389 -1 .53
26 312 1.000 373.150 1.339 500.00 499.18 .16 44.1299 44.6545 -1.17
26 313 1.000 383.150 1.339 500.00 499.07 .19 49.4255 50.0528 -1 .25
26 314 1.000 393.1 50 1.339 500.00 499.13 .17 54.81 92 55.4335 -1 .11
26 315 1.000 403.150 1.339 500.00 499.08 .18 60.1 148 60.7962 -1.12
26 316 1.000 413.150 1.339 500.00 498 . 93 .22 65.3123 66.1405 -1 .25
26 31 7 1.000 293.150 1.452 505.00 503.73 .25 2.2555 2.7362 -17.57
26 318 1.000 303.150 1.452 505.00 503.80 .24 7.9434 8.4476 -5.97
26 319 1.000 313.150 1.452 505.00 504.10 .18 13.7293 14.1433 -2.93
26 320 1.000 323.150 1.452 505.00 504.18 .16 19.41 72 19.8230 -2.05
26 321 1.000 333. 150 1.452 505.00 504.10 .18 25.0070 25.4861 -1 .88
26 322 1.000 343.150 1.452 505.00 504.06 .19 30.5967 31 .1321 -1 .72
26 323 1.000 353.150 1.452 505.00 504.22 .16 36.2846 36.7604 -1 .29
26 324 1.000 363.150 1.452 505.00 504.08 .18 41.7763 42.3705 -1 .40
26 325 1.000 373.150 1.452 505.00 504.12 .17 47.3661 47.9619 -1 .24
26 326 1.000 383.150 1.452 505.00 504.19 .16 52.9559 53.5342 -1 .08
26 327 1.000 393.150 1.452 505.00 504.15 .17 58.4476 59.0870 -1 .08
26 328 1.000 403.150 1.452 505.00 504.13 .17 63.9394 64.6201 -1 .05
26 329 1.000 413.150 1.452 505.00 503.90 .22 69.2349 70.1331 -1 .28
26 330 1.000 293.150 1.565 510.00 508.96 .20 4.3149 4.7483 -9.13
26 331 1.000 303.150 1.565 510.00 509.21 .16 10.2970 10.6587 -3.39
26 332 1.000 313.150 1 .565 510.00 509.26 .15 16.1 810 16.5498 -2.23
26 333 1.000 323.150 1 .565 510.00 509.34 .13 22.0650 22.4218 -1 .59
26 334 1.000 333.150 1 .565 510.00 509.26 .14 27.8509 28.2744 -1 .50
26 335 1.000 343.150 1 .565 510.00 509.07 .18 33.5387 34.1073 -1 .67
26 336 1.000 353.150 1.565 510.00 509.23 .15 39.4227 39.9200 -1.25
26 337 1.000 363.150 1 .565 510.00 509.27 .1 4 45.2087 45.7124 -1.10
26 338 1.000 373.150 1 .565 510.00 509.19 .16 50.8965 51 .4839 -1.14
26 339 1.000 383.150 1 .565 510.00 509.27 .14 56.6824 57.2344 -.96
26 340 1.000 393.150 1.565 510.00 509.25 .15 62.3703 62 . 9636 -.94
26 341 1.000 403.150 1 .565 510.00 509.14 .17 67.9601 68.671 2 -1 .04
26 342 1.000 413.150 1 .565 510.00 509.18 .16 73.6479 74.3572 -.95
26 343 1.000 293.150 1 .679 515.00 513.95 .20 6.4724 6.9507 -6.88
26 344 1.000 303.150 1 .679 515.00 514.17 .16 12.6506 13.0641 -3.17
26 345 1.000 31 3.150 1 .679 51 5.00 514.21 .15 18.7307 19. 1550 -2.21
26 345 1.000 323.150 1 .679 51 5.00 514.29 .14 24.8108 25.2236 -1 .64
26 347 1.000 333.150 1 .679 51 5.00 514.39 .12 30.8909 31 .2701 -1 .21
26 348 1.000 343.150 1 .679 515.00 514.21 .15 36.7749 37.2942 -1 .39
26 349 1.000 353.150 1 .679 51 5.00 514.37 .12 42.8551 43.2959 -1 .02
26 350 1.hoo 363.150 1 .679 515.00 514.27 .14 48.7391 49.2748 -1 .09
26 351 1.000 373.150 1 .679 51 5.00 514.34 .13 54.721 55.2308 -.92
26 352 1.000 383.150 1 .679 51 5.00 514.43 .11 60.7032 61 .1638 -.75
26 353 1.000 393.150 1 .679 51 5.00 514.42 .1 66.5872 67.0736 -.73
26 354 1.000 403.150 1 .679 51 5.00 514.33 .13 72.3731 72.9601 -.80
26 355 1.000 413.150 1 .679 51 5.00 514.27 .14 78.1590 78.8232 -.84
81
1 . 0 .
Data sources and ID numbers: (HVirial Equation, (2)Dawson, (3)Beattie, (4)Deschner, (5)Reamer,
(13)Cherney, 7)Tomli nson, (24)Ely, (26)0ithnar,
( 1 (XXXX)Haynes. (51 , 52 )Thomas, (78)Teichmann,
(79)Warowny.
ID Data We ght
i Temp. Dens ty i Dens ty
i Dens ty
i
expt ca c
I
Pressure
Point expt calc Dtff Dif f
No. K moi/L kg/m'^ kg/m-^ MP a MPa
26 356 1.000 283.150 11 .792 520.00 51 9.00 .19 2.5497 3.0055 -15.16
26 357 1 .000 293.150 11 .792 520.00 519.14 .17 8.9241 9.3532 -4.59
26 358 1 .000 303.150 1 .792
1 520.00 519.12 .17 15.2003 15.6740 -3.02
26 359 1 .000 313.150 1 .792
1 520,00 519.32 .13 21.5746 21 .9690 -1 .80
26 360 1 .000 323.150 1 .792
1 520.00 519.38 .12 27.8509 28.2388 -1 .37
26 361 1 .000 333.150 11 .792 520.00 519.31 .13 34.0291 34.4836 -1 .32
26 362 1 .000 343.150 1 1.792 520.00 519.29 .14 40.2073 40.7035 -1 .22
26 363 1 .000 353.150 1 .792
1 520.00 519.44 .11 46.4835 46.8984 -.88
26 364 1 .000 363.150 1 1 .792 520.00 519.48 .10 52.6617 53.0684 -.77
26 365 1 .000 373.150 1 .792
1 520.00 519.42 .11 58.7413 59.21 33 -.80
26 365 1 .000 383.1 50 11 .792 520.00 519.52 .09 64.9200 65.3332 -.63
26 367 1 .000 393.150 11 ,792 520.00 519.41 .11 70.9021 71 .4279 -.74
26 368 1 .000 403.150 11 .792 520.00 519.45 .11 76.9822 77.4975 -.66
26 369 1 .000 413.150 1 .792 520.00 51 9.40 .12 82.9643 83.5420 -.69
26 370 1 .000 283.150 1 ,906 525.00 524.59 .08 5.1 975 5.4033 -3.81
26 371 ] oOOO 293.1 50 1 1 .906 525.00 524.45 .10 1 1.6699 1 1 .9662 -2.48
26 372 1 .000 303.150 1 1 .906 525.00 524.73 .05 18.3384 18.4989 -.87
26 373 1 .000 313.150 1 1 .906 525.00 524.69 .06 24.81 08 25.0026 -.77
26 374 1 .000 323.150 1 1 . 906 525.00 524.71 .06 31 .2832 31 .4780 -.62
26 375 1 .000 333.150 1 1 .906 525.00 524.62 .07 37.6575 37.9257 -.71
26 376 1 .000 343.150 1 1 .906 525.00 524.71 .05 44 .1 299 44 .3459 -.49
26 377 1 .000 353.150 1 1 .906 525.00 524.83 .03 50.6023 50.7386 -.27
26 378 1 .000 363.150 1 1 .906 525.00 524.85 .03 56.9766 57. 1041 -.22
26 379 1 .000 373.150 1 1 .906 525.00 524.90 .02 63.351 63.4424 -.14
26 380 1 .000 383.150 1 1 .906 525.00 524.86 .03 69.6272 69.7536 -.18
26 381 1 .000 393.1 50 1 1 .906 525.00 524.86 .03 75.5035 76.0377 -.18
26 382 1 .000 403.150 1 1 .906 525.00 524.78 .04 82.0817 82.2948 -.26
26 383 1 .000 413.1 50 1 .906
1 525.00 524.74 .05 88.2598 88.5250 -.30
26 384 1 .000 273.150 12.019 530.00 529.56 .08 .9807 . 990
1 1 -18.21
26 385 1 .000 283.150 12.019 530.00 529.50 .09 7.7473 8.01 79 -3.38
26 386 1 .000 293.150 12.019 530.00 529.68 .06 14.61 19 14.8006 -1.27
26 387 1 .000 303.150 12.019 530.00 529.73 .05 21.3785 21 .5497 -.79
26 388 1 .000 313.150 12.019 530.00 529.67 .06 28.0470 28.2666 -.78
26 389 1 .000 323.1 50 12.019 530.00 529.81 .04 34.8136 34.9523 -.40
26 390 1 .000 333.150 12.019 530.00 529.84 .03 41 .4821 41 .6075 -.30
26 391 1 .000 343.150 12.019 530.00 529.78 .04 43.0526 48.2325 -.37
26 392 1 .000 353.150 12.019 530.00 529.76 .05 54.6230 54.8277 -.37
26 393 1 .000 363.150 12.019 530.00 529.77 .04 61 .1935 61 .3933 -.33
26 394 1 .000 373.150 12.019 530.00 529.82 .03 67.7640 67.9295 -.24
26 395 1 .000 383.150 12.019 530.00 529.69 .06 74.1383 74.4364 -.40
26 396 1 .000 393.150 12.019 530.00 529.79 .04 80.7087 80.9143 -.25
26 397 1 .000 403.1 50 12.019 530.00 529.73 .05 87.0831 87.3633 -.32
26 398 1 .000 413.150 12.019 530.00 529.70 .06 93.4574 93.7836 -.35
26 399 1 .000 273.150 12.132 535.00 534.84 .03 3.7265 3.81 35 -2.28
26 400 1 .000 283.150 1 2 . 1 32 535.00 534.88 .02 10.7873 10.8602 -.67
26 401 1 .000 293.150 12.132 535.00 534.82 .03 17.7500 17.8674 -.66
26 402 1 .000 303.150 12.132 535.00 534.82 .03 24.7128 24.8375 -.50
26 403 1 .000 313.150 12.1 32 535.00 534.73 .05 31 .5774 31 .7724 -.61
26 404 1 .000 323.150 12 . 32 1 535.00 534.83 .03 38.5401 38.6731 -.34
26 405 1 .000 333.150 12.132 535.00 534.95 .01 45.5029 45.5404 -.08
26 406 1.000 343.150 12.132 535.00 534.99 .00 52.3675 52.3750 -.01
26 407 1 .000 353.150 12.132 535.00 535.06 -.01 59.2322 59.1773 .09
26 408 1.000 363.1 50 12.132 535.00 535.16 -.03 66.0968 65.9476 .23
26 409 1 .000 373.150 12.132 535.00 535.08 -.02 72.7653 72.6862 .11
26 410 1 .000 383.150 12.132 535.00 535.04 -.01 79.4339 79.3935 .05
26 41 1 1 .000 393.150 12.132 535.00 535.03 -.01 86.1024 86.0697 .04
82
. + . ^ . 11 m49
2
0/
7 0
1 69
3 3
11 8
2
0
Data sources and ID numbers: (l)Vlrial Equation, (2)Dawson, (3)Beattle, (4)Deschner, (5)Rearner,
(13)Cherney, 7 )Tom nson (24)£ly, (26)Dithnar, (XXXX )Haynes, (51 52 )Thomas , ( 78 )Te Ichmann,
( 1 I i
, ,
( 79)V/arowny
U Da+a We g h i Temp Densi ty Dens ty i Dens ty 1

expt '
ca c 1
Pressur
0*-v
rO nt+ T
1
1-1
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1
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26 420 1
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.000 333 • 50 1 1 2. 246 540 .00 539.98 .00 49. 71 97 49. 7363 -.03
26 421 1 .000 343. 50 1 1 2.246 540.00 540. 1 -.02 56.8786 56. 7852 .16
26 422 1 .000 353 . 50 1 1 2.246 540.00 540.04 -.01 63. 841 63.7993 .07
26 423 1 .000 363. 50 1 1 2.246 540.00 540. 1 -.02 70.9021 70.7789 .17
26 424 1 .000 373. 50 1 1 2.246 540.00 540. 1 -.03 77 .8648 77 . 7247 . 1
26 425 1 .000 383. 50 1 1 2.246 540.00 540.27 -.05 84 .9256 84 .6369 .34
26 426 1 .000 393 . 50 1 1 2.246 540.00 540.25 - .05 91 .7902 9 . 5 60
1 1 .30
26 427 1 . 000 403. 50 1 1 2.246 540.00 540.1 -.03 98.5568 98 .3623 .20
26 428 1 .000 273. 50 1 1 2.359 545 .00 545.08 -.01 9.8067 9.7575 .50
26 429 1 .000 283. 150 12.359 545.00 545.12 -.02 17.3578 17.2741 .48
26 430 1 .000 293. 150 1 2.359 545.00 545.09 -.02 24.81 08 24 .7444 .27
26 431 1 .000 303. 50 1 1 2.359 545.00 545.1 -.02 32.2639 32.1 71 .29
26 432 1 .000 31 3. 50 1 1 2.359 545.00 545. 19 -.04 39.7169 39.5562 .41
26 433 1 .000 323. 50 1 1 2.359 545 .00 545. 1 -.04 47.071 46.901 .36
26 434 1 .000 333 . 50 1 1 2.359 545.00 545.24 -.04 54.4269 54.2074 .41
26 435 1 .000 343. 50 1 1 2.359 545 .00 545.32 -.06 61 .781 9 61 .4753 .50
26 436 1 .000 353. 50 1 1 2.359 545.00 545.23 -.04 68.9407 68.7059 .34
26 437 1 .000 363.1 50 1 2.359 545.00 545. 1 -.03 76.0996 75. 8998 .26
26 438 1 .000 373. 50 1 1 2.359 545 .00 545.27 -.05 83.3565 83.0573 .36
26 439 1 . 000 383.1 50 1 2.359 545 .00 545 .30 -.05 90 .51 54 90.1 792 .37
ZD 440 1
1
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.000 393. 50 1 1 2. 359 545 .00 545 .35 -.06 97.6742 97. 2658 .42
ZD 441 1
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.oou OTZ
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1
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50 12.586 555.00 555 .53 -. 1
1
A
0 33. 465 1
zo .5933
3Z X AZ Z ZA
.3y
1
1
26 456 1 .000 303.150 12.586 555.00 555.55 -.10 41 .0899 40.5964 1 .22
26 457 1 .000 313.150 12.586 555.00 555.61 -.11 49.0333 48.4516 .201
26 458 1 .000 323.150 12.586 555.00 555.62 -.11 56.8786 56.2607 1.10
26 459 1 .000 333. 150 12.586 555.00 555.67 -.12 64.7239 64.0252 1.09
26 460 1 .000 343.150 12.586 555.00 555.57 -.10 72.3731 71 .7461 .87
26 461 1 .000 353.150 12.586 555.00 555.53 -.09 80.0223 79.4244 .75
26 462 1.000 363.150 12.586 555.00 555.60 -.11 87.7695 87.0609 .81
26 463 1 .000 373.150 12.586 555.00 555.62 -.11 95.4187 94.6565 .81
26 464 1 .000 383.150 12.586 555.00 555.60 -.11 102.9698 102.21 18 .74
26 465 1 .000 273.150 12.699 560.00 560.67 -.12 21.1824 20.6403 2.63
26 466 1 .000 283.150 12.699 560.00 560.60 -.11 29.4200 28.8991 1 .80
26 467 1 .000 293.150 12.699 560.00 560.71 -.13 37.7556 37.1014 1 .76
83
. 3 1 1 40 ,
(13)Cherney, 7)Toml inson, (24)Ely, (26 )D ttrnar , (XXXX)Haynes,
( 1 51 , 52 )Thomas,
i 78 fe Ichmann ( ( )
(79) Warowny
D Data Weight Temp. Dens ty I DensI ty Dens ty I

êxpt '^ca ! c Pressu
Point expt calc DIff. DIff.
No. K mol/L kg/m^ kg/m-^ % MPa MPa %
26 468 1 .000 303.150 12.699 560.00 560.77 -.14 45.9932 45.2503 1.64
26 469 1 .000 313.150 12.699 560.00 560.68 -.12 54.0346 53.3482 1.29
26 470 1 ,000 323.150 12.699 560.00 560.82 -.15 62.2722 61 .3970 1.43
26 471 1 .000 333.150 12.699 560.00 560.74 -.13 70.2156 69.3981 1.18
26 472 1 .000 343.1 50 12.699 560.00 560.70 -.12 78.1590 77.3530 1.04
26 473 1 .000 353.150 12.699 560.00 560.70 -.12 86.1024 85.2625 .99
26 474 1 .000 363.150 12.699 560.00 560.66 -.12 93.9477^ 93.1278 .88
26 475 1 .000 373.1 50 12.699 560.00 560.73 -.13 101 .891 100.9497 .93
26 476 1 .000 273.150 12.813 565.00 565.75 -.13 25.4973 24.8429 2.63
26 477 1 .000 283.150 12.813 565.00 565.62 -.11 33.9310 33.3595 1 .71
26 478 1 .000 293.150 12.813 565.00 565.66 -.12 42.4628 41 .8162 1 .55
26 479 1 .000 303.150 1 2.81 565.00 565.66 -.12 50.3965 50.2161 1 .35
26 480 1 .000 313.150 12.813 565.00 565.71 -.13 59.3302 58.5619 1.31
26 481 1 .000 323.150 12.813 565.00 565.63 -.1 1 67.5678 66.8554 1 .07
26 482 1 .000 333.150 12.813 565.00 565.60 -.11 75.8054 75.0984 .94
26 483 1 .000 343.1 50 12.81 565.00 565.61 -.1 84.0430 83.2923 .90
26 484 1 .000 353.150 12.813 565.00 565.58 -.10 92.1 825 91 .4381 .31
26 485 1 .000 363 . 50 1 1 2.81 565 .00 565.59 -. 1 1 00.3220 99.5371 .79
26 486 1 .000 273.1 50 12.926 570.00 5 70.80 -.14 30.1064 29.3552 2.56
26 487 1 .000 283.150 12.926 570.00 570.70 -.12 38.8343 38 . 349
1 1 .83
26 488 1 .000 293.1 50 12.926 570.00 570.68 -.12 47.5623 46.8513 1 .52
26 489 1 .000 303.1 50 12.926 570.00 570.62 -.11 56.1921 55.5076 1 .23
26 490 1 .000 313.150 12.926 570.00 570.62 -.11 64.8220 64.1065 1 .12
26 491 1 .000 323.150 12.926 570.00 570.59 -.10 73.3537 72.6501 .97
26 492 1 .000 333.150 12.926 570.00 570.60 -.10 81.8855 81 .1401 .92
26 493 1 .000 343. 150 12.926 570.00 570.50 -.09 90.2212 89.5780 .72
26 494 1.000 353.150 12.926 570.00 570.51 -.09 98.6549 97.9653 .70
26 495 1 .000 273.150 13.039 575.00 575.81 -.14 35.0097 34.191 2.39
26 496 1 .000 283.150 13.039 575.00 575.75 -.13 44.0319 43.2393 1 .83
26 497 1 .000 293.1 50 13.039 575.00 575.66 -.11 52.9559 52.2208 1 .41
26 498 1 .000 303.150 13.039 575.00 575.55 -.10 61 .7319 61 .1389 1 .05
26 499 1 .000 313.150 13.039 575.00 575.50 -.09 70.6079 69.9962 .87
26 500 1 .000 323.150 13.039 575.00 575.50 -.09 79.4339 78.7951 .81
26 501 1 .000 333.150 13.039 575.00 575.47 -.08 88.1618 87.5373 .71
26 502 1 .000 343.150 13.039 575.00 575.41 -.07 96.7916 96.2246 .59
26 503 1 .000 273.150 13.153 580.00 580.69 -.12 40.1092 39.3645 1 .89
26 504 1 .000 283.150 13.153 580.00 580.57 -.10 49.3274 48.6870 1 .32
26 505 1 .000 293.150 13.153 580.00 580.51 -.09 58.5457 57.9391 1 .05
26 506 1 .000 303.150 13.153 580.00 580.36 -.06 67.5678 67.1244 .66
26 507 1 .000 313.150 13.153 580.00 580.34 -.06 76.6880 76.2456 .58
26 508 1 .000 323.150 13.153 580.00 580.30 -.05 35.7101 85.3051 .47
26 509 1 .000 333.150 13.153 580.00 580.24 -.04 94.6342 94.3049 .35
26 510 1 .000 343.150 13.153 580.00 580.15 -.03 103.4602 103.2468 .21
26 51 1 1 .000 273.150 13.266 585.00 585.53 -.09 45.5029 44.8904 1 .36
26 512 1 .000 283.150 13.266 585.00 585.44 -.07 55.0153 54.4927 .96
26 51 3 1 .000 293.150 13.266 585.00 585.33 -.06 64.4297 64.0210 .64
26 514 1 .000 303.150 13.266 585.00 585.20 -.03 73.7460 73.4790 .36
26 515 1 .000 313.150 13.266 585.00 585.21 -.04 83.1604 82.8696 .35
26 516 1 .000 323.150 13.266 585.00 585.13 -.02 92.3786 92.1951 .20
26 51 7 1 .000 333.150 13.266 585.00 585.03 -.00 101 .4988 101 .4579 .04
26 51 8 1 .000 273.150 13.380 590.00 590.09 -.02 50.8965 50.7836 .22
26 519 1 .000 283 . 1 50 13.380 590.00 590.02 -.00 60.7032 60.671 .05
26 520 1 .000 293.150 13.380 590.00 589.95 .01 70.41 17 70.4816 -.10
26 521 1 .000 303 . 1 50 13.380 590.00 589.93 .01 80.1203 80.21 79 -.12
26 522 1 .000 313.150 13.380 590.00 589.83 .03 89.6328 89.8833 -.28
26 523 1 .000 323.150 13.380 590.00 589.71 .05 99.0472 99.4805 -.44
84
. . 0 1 23
9
0
J
4
1 8
5
A
1
Data sources and ID numbers: (l)VIrlal Equation, (2)Dawson, (3)BeattIe, (4)Deschner, (5)Rea(ner,
(13)Cherney, ( 7)Toml inson, (24)Ely, (26)Dittmar, (XXXX)Haynes, (51 ,52 )Thomas, (78)TeIchmann,
1
(79)Warowny
ID Data We ight Temp. Density Density Density expt cal c Pressure

Point expt calc DIff DIff.
Noo K mol/L kg/rrr kg/m-^ 1 Mra Mra el
f> P
524 .000 90.000 16.799 740.78 739.91 "7 t;A 1 c;

-
1201 1 j4 . /zl / .DD
525 .000 90.000 16.775 739.73 738.86 t: 1 o T0 t A 1 O AA -8.33
1202 1 .1 ^ 31 . z /ol 34. 1 zOO
1203 526 1 .000 90.000 16.751 738.67 737.79 1 o z / . j4d .D /yb A . ZO T/

-9
1204 527 1 .000 90.000 16.726 737.59 736.71 .1
1 o
I z4. jy 1
0"7
z / .
1
1
O
ol
1 1 A O
1205 528 1 .000 90.000 16.701 736.48 735.62 .
1
1
o
z zU. 94 /9 23 .6556 -1 1 .45
1206 529 1 .000 90.000 16.675 735.31 734.52 .
1
1
1
1 1 / .D04O 1A AOA C
19.9806 -1 2 .39
1207 530 1 .000 90.000 16.648 734.15 733.40 1 r\ ^ A A(C1 c; 1<^
b. JO 1/4
1
1 A f\Ci
1208 531 1 .000 90.000 16.621 732.96 732.26 .(jy 1 A ^ 1O

z. "70
/zUo
1
AQ -10.53
1209 532 1 .000 90.000 16.594 731 .76 731 .12 .09
"7
/ .
1
1
*7C
/34 >1 A
9 . AA/^
096 1
1 -21 .23
1210 533 1 .000 90.000 16.567 730.57 729.95 .08 3.7326 5.5597 -32.86
1001 534 1 .000 100.000 16.594 731 .74 730.90 . 1 1 35 . 7539 38.3478 -6.76
1002 535 1 .000 100.000 16.561 730.23 729.55 .10 31 .621 33.8520 -6.59
1003 536 1 .000 100.000 16.530 728.94 728.29 .09 27.8341 29.8013 -6.60
1004 537 1 .000 100.000 16.503 727.74 727.13 .08 24.391 26. 1906 -6.87
1005 538 1 .000 100.000 16.476 726.53 725.95 .08 20.9477 22 .6289 -7.43
1006 539 1 .000 100.000 16.448 725.29 724.76 .07 7.5047
1 19.0268 -8.00
1007 540 1 .000 100.000 16.420 724.05 723.55 .07 14.0615 1 5.4877 -9.21
1008 541 1 .000 100.000 16.397 723.04 722.57 .07 1 1.3072 1 2.6299 -1 0.47
1009 542 1 .000 100.000 16.374 722.03 721 .58 .06 8.5527 9.8048 -1 2 .77
1010 543 1 .000 100.000 16.356 721 .24 720.58 .09 5.7985 7.6069 -23.77
1011 544 1 .000 100.000 16.338 720.46 719.82 .09 3.7328 5.4530 -31 .55
1012 545 1 .000 100.000 16.321 719.70 719.06 .09 1.6670 3.3899 -50.82
501 546 1 .000 110.000 16.376 722.15 721 .41 .10 34.9955 37.1324 -5.75
502 547 1 .000 110.000 16.347 720.84 720.10 .10 31 .2768 33.3625 -6.25
503 548 1 .000 110.000 16.318 719.57 718.88 .10 27.8332 29.7598 -6.47
504 549 1 .000 110.000 16.288 718.26 71 7.63 .09 24. 3900 26. 237 1 -6.64
505 550 1 .000 110.000 16.259 716.96 716.37 .08 20.9466 22 .5535 -7.12
506 551 1 .000 110.000 16.229 71 5.67 71 5.14 .07 1 7 .641 1 9.0598 -7.44
507 552 1 .000 110.000 16.201 714.41 713.97 .06 1 4 .5424 15 .6992 -7.37
508 553 1 .000 110.000 16.178 713.39 712.97 .06 1 1 .9258 13.031 -8.49
509 554 1 .000 110.000 16.155 712.39 71 1 .93 .07 9.2401 10.441 -1 1 .50
510 555 1 .000 110.000 16.131 71 1 .35 710.85 • 07 6. 4857 7.7448 -16.26
511 556 1 .000 110.000 16.1 14 710.60 710.09 .07 4 .5578 5 .8500 -22.09
512 557 1 .000 110.000 16.098 709.89 709.35 .08 2.6985 4.0601 -33.54
513 558 1 .000 110.000 16.087 709.40 708.85 .08 1 .4591 2. 8237 -48.33
514 559 1 .000 110.000 16.082 709.18 708.61 .08 .8761 2.2849 -61 .66
601 560 1 .000 120.000 16.180 713.50 712.77 .10 36.3748 38.3563 -5.17
602 561 1 .000 120.000 16.141 71 1 .78 71 1 .12 .09 31 .9673 33.7323 -5.23
603 562 1 .000 120.000 16.104 710.16 709.54 .09 27.8350 29.4408 -5.45
604 563 1 .000 120.000 16.073 708.76 708.21 .08 24.391 9 25 .8077 -5.49
605 564 1 .000 120.000 16.041 707.36 706.86 .07 20.9485 22.2216 -5.73
606 565 1 .000 120.000 16.008 705.91 705.48 .06 17.5053 18.5722 -5.74
607 566 1 .000 120.000 15.977 704.54 704.14 .06 14.1999 15.1895 -6.52
608 567 1 .000 120.000 15.952 703.45 703.06 .06 1 .5833 1 12.5220 -7.50
609 568 1 .000 120.000 15.923 702.18 701 .79 .05 8.5533 9.4667 -9.65
610 569 1 .000 120.000 15.897 701 .02 700.63 .06 5.7991 6.7266 -13.79
611 570 1 .000 120.000 15.878 700.17 699.74 .06 3.7334 4.7320 -21 .10
612 571 1 .000 120.000 15.862 699.45 699.00 .06 2.0118 3.0527 -34.10
613 572 1 .000 120.000 15.853 699.08 698.62 .07 1 .151 2.2083 -47.37
614 573 1 .000 120.000 15.848 698.84 698.39 .07 .6141 1 .6608 -63.02
401 574 1 .000 130.000 15.958 703.72 703.31 .06 35.3418 36.3798 -2.85
402 575 1 .000 130.000 15.922 702.13 701 .74 .06 31 .4162 32.3954 -3.02
85
0
1 0
4
1 . . «
"/ • ^
1 11 1 9/7/
11 71J
1// D.
1
Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)3eattie, (4)Deschner, (5)Reainer,
(13)Cherney, ( 7)Tom nson, (24)Ely, (26)Dittinar, (XXXX)Haynes, ( 51 , 52 )Thomas, (78)Teichrnann,
1 I i
(79)Warowny
u Data We g n r Temp Dens ty Dens ty Dens ty p Pressur

1
1
i i
n î
i
expt '^cal c
Po n t i expt ca c 1 U I
1 tt • D i f f
No • K mol/L kg/m-" % MPa MPa %
403 575 1 .000 130.000 IK OO A "7

/UU CO
A A •DO 700.34 .05 27.9727 28.8070 -2.90
577 .000 130.000 1 c oci":
mODJ £!AA 1 698.85 -2.94
404 1 1 0 .04 24.391 25.1302
40P 0 fo ] •UUU 1
1
'Zr\ AAA
* UU'J
1 £^ QO1 £ A"7 glQ
by / •DO £f\~I /A
69 / .40 • 04
AA r\ A aA
21 .6014 -3.02
A r\r\f\ "Â AAA iUdA 10 A "Z ^ t c 1
0 /y 1 1
1 J»U« UUU 1 D • /4D oy4 • J) / •Oj 1 3.5 13 1
1
"z
1 3.9329 -3.03
hU I DoU 1
1
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•UU'J 1 "Â AAA
jUÛUU
i
1 c "71 A
oy--> • 1 o AO •
A"?
U^ 1
1
A ~T C A
u» /9Dy 11.11 AAO
11
99z -3 .95
A HQ Q1 1
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•UUU 1 XC\ AAA
J>U«
1 UUU 1 D •oyu oyt «00 oyi .D? ,
A
•U^ / .oo4 / 0. JDO
ll
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.Oz
A AO Doz 1
1
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-->U 9 UUU
1 ! 0 •ODD OA • oz
oyu QO 690 .55 A>1
• U4
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y A AO Cl C A 1 1
O.U41 >! A . T71
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Dvu AR Doy. /5 •U4 3» /333 4. J /yu A
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Doy A1 •
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eUUJ 1 "Â UUU
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"7A AAA <CQO OA 7R97
4 JO UUU J)U • UUU ftPR DOO • AR • OZ / /
1
(-'•DID U00 .zy U . jjZ / —J J .DU
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1 ! • 1 9 ft/1
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1 nnn HU • UUU
t 15.769 695.36 fiQ4
D . Q1
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00 ^7/ . RS74
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1 15.727 693.50 fiQ^
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t •ns
UJ "^9 ft'îftn
JZ • D JDU 44'=iQ
JJ . ^'t jy -9
Z . JD
^fi
703 590 1 .000 140.000 1 (SR4 u" 1 . u_/ 691 .37 .04 28.5239 29. 11 91 -2.04
704 591 1 .000 140.000 ^RQ 77 689.55 .03 24.3920 24.8962 -2.03
140 000 fiRR . J
000 1
1
f^RR 00
ooo. UU • 09
uz 90
z u . Q4R7
y+o / z 9RR7
91 . zoo 1
-1 .OU
fiO 1
/VJD 1 non 1
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000
40 . UUU DOO . 000 41
(=;Rf=. . H . 09
uz 1 7 SOSfi 1 7 7^04 -1 1
"^R
.JO
707 H U » 000
140 1 UUU U Q ^ •.00
fiRS UU fiR4
D OH .
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1 4 ^^7R 1 4 Alfî.
7nfl
/ uo Jy J 1 onn 1
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OOO
40 . UUU 1 ^ ^04 u 0^
fifl'^ . / 70
u D OJ
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1 1 fiR9 1 1 7409 — . 7R
/ J
7nQ 1 nno 140 1

000
H U . UUU IS 4 74 îR9 "^4
DOZ . JZ • 00
UU 0 RQ77
R .o^ / R . Q'^ftl
0 )7JO 1 • *t J
71 n "107 1 000 1
Û 1
000
40 . UUU 1 44QR !=,fl1 97 QO . Z91
fiRI 1
01
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71
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uz 4 4991
4 «HZZ 4 fiS74 J . OS
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71 O jyy 1 AAA 4U.
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0 / y .4z D /y . ZP A"^
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0 /UUP J.U4^ — 1
1
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A UUU D . jy
1 D / o . yp A 7Q
D /O . 79
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9 . 11 yz 1 1
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4U 1 UUU 5 . joy
1 D /O .0 ^;7« "^7
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— JZ 1
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Â .UUU 15.354 677.06 e^^c
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Xii; —•J 1
802 603 1 .000 160.000 1

1
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5 "Â/ 0 /4 . 00 674.82 .01 31 .9674 32.0922 -.39
803 604 1 .000 160.000 1
1
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5 .z5o D /Z.OZ 672.78 .01 27.8352 27.9097 -.27
oU4 1
1
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A oUUU 1 5 . z1 0 c "7 1 A£:
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805 606 1 .000 1
160.000 1 5 . 1 78 669.31 669. 26 .01 zU. y4o Z 1U4U3
•
y1
A AAA
160.000 667 .48 667 .45 A 7 .5056
IT/ TAA C; T
-.37 -7
806 607 1 .000 1
1 5. 1 37 .01 1 1 •!? /OU
807 608 1 .000 1 60 .000 1 5 .094 665.60 665.59 .00 1 4.0623

1
1
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4A .0805 -.13
-.00 0
808 609 1 .000 1 60 .000 1 5.059 654.06 664.07 1 .3080
1 1 1 . 2808 .24 >i
809 1 A AA ^ -.00 8.5534 8. 5273

61 1 .000 1 60 .000 1 5 .024 652.51 662.52 .31
-.00 0A
81 61 1 .000 160.000 1 4-988 660.92 660.94 5.7992 5. 751 .84
81 612 1 .000 160.000 1 4.960 659. 70 659.74 -.01 3. 7335 3.6738 1
1
^0
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81 2 61 3 1 .000 160.000 1 4.938 658.72 658. 72 -.00 2.01 1 2.0056 .32
813 61 1 .000 160 . 000 1 4.924 658.08 658. 10 - .00 .9791 .951 2 .88
901 61 5 1 .000 180.000 14.963 659.84 659.89 -.01 37.4764 37.3754 .27
A AO AAA O A AAA 14.912 657.56 A1
-.01 7 A AX
-7
J J. j44j
"7 TKA 1^0
yoz 61 6
1
1 .UUU 1
1oO.UUU 65 / .DD
~z.
JJ . 1
1 /j4 .5z
903 61 7 1 .000 180.000 14,858 655.21 655.36 -.02 29.2121 28.9623 .86
904 618 1 .000 180.000 14.804 652.80 652.99 -.03 25.0803 24.7507 1 .33
905 619 1 .000 180.000 14.749 650.40 650.55 -.02 20.9483 20.6943 1 .23
906 620 1 .000 180.000 14.701 648.28 648.46 -.03 1 7.5052 17.2164 1 .68
907 621 1 .000 180.000 14.653 646.17 646.35 -.03 14.1308 13.8317 2.16
908 622 1 .000 180.000 14.613 644.37 644.55 -.03 1 1.3076 1 1 .0336 2.48
909 623 1 .000 180.000 14.571 642.53 642.74 -.03 8.5530 8.2277 3.95
910 624 1 .000 180.000 14.528 640.64 '640.90 -.04 5.7988 5.41 82 7.03
91 625 1 .000 180.000 14.495 639.19 639.48 -.05 3.7330 3.3175 12.52
912 626 1 .000 180.000 14.462 637.75 638.03 -.04 1 .6671 1.2636 31 .93
913 621 1 .000 180.000 14.452 637.28 637.55 -.04 .9786 .6002 63.04
85
. . .
Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)8eattle, (4)Deschner, (5)Rearner,
(13)Cherney, (1 7)Tom! inson, (24)Ely, (26)0 ittmar, (XXXX)Hayne3, (51 , 52 )Thomas, (78)Teichmann,
(79)Warowny
10 Oata Vie i ght Temp. Dens ty

i Dens tyi Dens ty
I
expt cal c
Pressure
Point expt calc DIff Dif f
No. K mo /L kg/m^ kg/nr MPa iMPa
2901 628 1 .000 200.000 14.535 640.95 640.72 .04 34. 7203 35.0966 -1 .07
2902 629 1 .000 200.000 14.484 638.70 633.57 .02 31.2770 31.4860 -.66
2903 630 1 .000 200.000 14.431 636.38 636 .36 .00 27.8334 27.3681 -.12
2904 631 1 .000 200.000 14.378 634.02 634.09 -.01 24.3903 24.2837 .44
2905 632 1 .000 200.000 14.322 631 .57 631.74 -.03 20.9469 20.6993 1.20
2906 633 1 .000 200.000 14.265 629.04 629.33 -.05 17.5038 17.0986 2.37
2907 634 1 .000 200.000 14.206 626.45 626.83 -.06 14.0606 13.5460 3.80
2908 635 1 .000 200.000 14.158 624,33 624.77 -.07 1 1 .3062 10.7260 5.41
2909 636 1 .000 200.000 14.109 622.19 622.65 -.07 8.5516 7.9584 7.45
2910 637 1 .000 200.000 14.060 619.99 620.47 -.08 5.7974 5.21 18 1 1.24
2911 638 1 .000 200.000 14.022 618.32 618.73 -.08 3.7317 3.1679 1 7.80
2912 639 1 .000 200.000 13.984 616.64 61 7.06 -.07 1 .6657 1 .1720 42.13
3001 640 1 .000 220.000 14.129 623.05 623.03 .00 34 . 7208 34.7474 -.08
3002 641 1 .000 220.000 14.070 620.46 620.58 .02 31 .2774 31 .1005 .57
3003 642 1 .000 220.000 14.010 617.82 618.06 .04 27.8339 27.5096 1.18
3004 643 1 .000 220.000 13.950 61 5.17 61 5.44 .04 24.3908 24.0357 1 .48
3005 644 1 .000 220.000 13.889 612.48 612.74 .04 20.9474 20.6331 1 .52
3006 645 1 .000 220.000 13.826 609.70 609.93 .04 17.5043 17.2305 .59
1
3007 646 1 .000 220.000 13.761 606.82 607.00 .03 14.0610 13.8545 .49
1
3008 647 1 .000 220.000 13.704 604.30 604.57 .04 11 .3067 1 1 .0074 2.72
3009 648 1 .000 220.000 13.645 601 .69 602.06 .06 8.5521 8.1566 4.85
3010 649 1 .000 220.000 13.584 599.00 599.45 .07 5.7979 5.3387 8.60
3011 650 1 .000 220.000 13.537 596.96 597.42 .08 3.7321 3.2695 14.15
3012 651 1 .000 220.000 13.490 594.38 595.34 .08 1.6662 1 .2194 36.64
3101 652 1 .000 240.000 13.738 605.80 605.27 .09 34.7217 35.3947 -1 .90
3102 653 1 .000 240.000 13.669 602.75 602.48 .05 31 .2784 31 .61 1 4 -1 .05
3103 654 1 .000 240.000 13.598 599.65 599.58 .01 27.8348 27.9215 -.31
3104 655 1 .000 240.000 13.527 596.51 596.56 .01 24.3916 24.3384 .22
3105 656 1 .000 240.000 13.454 593.28 593.41 .02 20.9432 20.8073 .68
3106 657 1 .000 240.000 13.379 589.95 590.12 .03 17.5052 17.3376 .97
3107 658 1 .000 240.000 13.301 586.54 586.66 .02 14.0619 13.9383 .89
3108 659 1 .000 240.000 13.236 583.65 583.77 .02 1 .3076
1 11 .1980 .98
3109 660 1 .000 240.000 13.166 580.56 580.75 .03 8.5530 8.3877 1.97
3110 661 1 .000 240.000 13.093 577.36 577.58 .04 5.7983 5.6033 3.40
3111 662 1 .000 240.000 13.035 574.82 575.10 .05 3.7331 3.5014 6.62
31 12 663 1 .000 240.000 12.976 572.21 572.52 .05 1 .6672 1 .4215 17.28
3201 664 1 .000 260.000 13.320 587.38 537.38 .00 34.7213 34.7204 .00
3202 665 1 .000 260.000 13.245 534.05 584.13 .02 31 .2780 31 .1370 .45
3203 666 1 .000 260.000 13.166 580.60 580.34 .04 27.3346 27.5377 .89
3204 667 1 .000 260.000 13.101 577.73 573.05 .06 25.0301 24.7671 1 .26
3205 668 1 .000 260.000 13.034 574.75 575.15 .07 22.3253 21 .9556 1 .63
3206 669 1 .000 260.000 12.964 571 .69 572.13 .03 19.5709 19.1867 2.00
3207 670 1 .000 260.000 12.393 563.52 568.96 .08 16.8163 16.4449 2.26
3208 671 1 .000 260.000 12.818 565.25 565.64 .07 14.0619 13.7433 2.32
3209 672 1 .000 260.000 12.739 561 ,75 562.15 .07 1 .3076
1 11 .0035 2.76
3210 673 1 .000 260.000 12.676 558.98 559.40 .08 9.2417 8.9328 3.46
321 1 674 1 .000 260.000 12.611 556.09 556.52 .03 7.1760 6.3732 4.41
3212 675 1 .000 260.000 12.543 553.12 553.51 .07 5.1 103 4.3477 5.42
3213 676 1 .000 260.000 12.472 549.98 550.35 .07 3.0445 2.8122 8.26
3214 677 1 .000 260.000 12.422 547.77 543.14 .07 1 .6673 1.4397 15.31
3301 673 1 .000 275.000 13.01 7 574.00 573.35 .03 34.7209 34.8709 -.43
3302 679 1 .000 275.000 12.934 570.35 570.31 .01 31 .2776 31 .3188 -.13
87
1 . 7
1 / 0
3
2
Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)38attle, (4)Deschner, (5)Reainer,
(13)Cherney, ( 7)TomI inson, (24)Ely, (26 )0 ttinar , (XXXX)Haynes, (51 ,52 )Thoinas, ( 78 )Te Ichmann,
1 i
( 79) 'Warov/ny
ID Data Weight Temp. Dens ity Dens ty

i Dens ty i p expt P—ca c^
1
1
Pressu
No. K .noi/L kg/m-' kg/m-^ % MPa MPa %
3303 680 1 .000 275.000 12.846 566.49 566.58 -.02 27.8341 27.7497 .30
-"lie /^/^
3304 681 1 .000 275 .000
/"N
12.774 563.28 563 .46 -.03 25.0796 24.9305 .60
3305 682 1 .000 2 75.000 12.697 559.89 560.19 -.05 22.3248 22.0817 1 .10
3306 683 1 .000 275.000 12.61 556.39 556.75 -.07 19.5704 19.2874 1 .47
3307 684 1 .000 275.000 12.536 552.80 553.13 -.06 16.8157 16.5724 1 .47
3308 685 1 .000 275.000 12.451 549.05 549.31 -.05 14.061 13.8837 1 .28
3309 686 1 .000 275.000 12.361 545.09 545.24 -.03 1 .3070
1 1 1 .2077 .89
3310 ,687 1 .000 275.000 12.288 541 .88 542.01 -.02 9.2410 9.1659 .82
3311 688 1 .000 2 75.000 12.210 538.43 533.59 -.03 7.1752 7.0791 1 .36
3312 689 1 .000 275.000 12.127 534.74 534.98 -.04 5.1095 4.9791 2.62
3313 690 1 .000 275.000 12.051 531 .43 531 .79 -.07 3.3880 3.2015 5.82
3314 691 •
1.000 275.000 11 .974 528.01 528.41 -.08 1 .6665 1.4695 13.41
3401 692 1.000 290.000 12.702 560.13 560.22 -.02 34.7213 34.6376 .24
3402 693 1.000 290.000 1
1
O fÔQ
^.DUO Ojy . y 556.29 -.06 31 .2781 31 .0094 .87
3403 694 1.000 290.000 12.511 551 .69 552.12 -.08 27.8346 27.4860 1 .27
j4U4 oy? !©UUU ^yj •UUU 12.428 548.06 •"• 1 u 1
3405 696 1.000 290.000 12.342 544.25 544.90 -.12 22.3255 21.8570 2.14
3406 697 1.000 290.000 12.251 540.24 540.99 -.14 19.571 19.0643 2.66
3407 698 1.000 290.000 12.156 536.06 536.82 -.14 16.8164 16.3323 2.96
3408 699 1 .000 290.000 12.057 531 .66 532.38 -.13 14.0622 13.6379 3.11
3409 700 1 .000 290.000 1 1 .949 526.92 527.59 -.13 1 .3077
1 10.9363 3.40
3410 701 1 .000 290.000 1 1 .864 523.17 523.74 -.11 9,2418 8.9475 3.29
3411 702 1 .000 290.000 1 1 .773 519.15 519.63 -.09 7.1761 6.9438 3.34
3412 703 1 .000 290,000 1 1 .672 514.71 515.20 -.10 5.1104 4.8915 4.47
3413 -704 1 .000 290.000 1 1 .581 510.69 511 .23 -.10 3.3888 3.1678 6.98
3414 705 1 .000 290.000 1 1 .486 506.50 506.94 -.09 1.6674 .4977
1 11 .33
2801 706 1 .000 300.000 12.493 550.92 551 .07 -.03 34.7209 34.6014 .35
2802 707 1 .000 300.000 12.395 546.57 546.84 -.05 31.2776 31 .0625 .69
2803 708 1 .000 300.000 12.288 541 .86 542.36 -.09 27.8341 27.4645 1 ,35
2804 709 1 .000 300.000 12.201 538.02 538.55 -.10 25.0795 24.7096 1 .50
2805 710 1 .000 300.000 12.109 533.99 534.52 -.10 22.3248 21 .9737 1 .60
2806 711 1 .000 300.000 12.01 529.64 530.23 -.11 19.5703 19.2037 1 .91
2807 712 1 .000 300.000 1 . 904
1 524.93 525.64 -.14 16.8157 16.4035 2.51
2808 713 1 .000 300.000 1 .790
1 519.92 520.70 -.15 14.061 13.6454 3.05
2809 714 1 .000 300.000 1 1 .670 514,61 515.34 -.14 1 1 .3070 10.9489 3.27
2810 715 1 .000 300.000 11.573 510.32 510.98 -.13 9.2410 8.9427 3.34
281 716 1 .000 300.000 1 .462
1 505,42 506.26 -.17 7.1 752 6.8236 5.15
2812 717 1 .000 300.000 11.348 500.42 501 .12 -.14 5.1095 4.8428 5.51
2813 718 1 .000 300.000 1 .265
1 496.73 497.40 -.13 3.7324 3.4948 6.80
2814 719 1 .000 300.000 11.174 492.75 493.40 -.13 2.3551 2.1398 10.06
88
. 8
1 5 . 51 .
Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)Beattle, (4)Deschner, (5)Reainer,
(13)Cherney, 7 )Toml inson
( 1 (24)Ely, 26 )D ttinar , (XXXX )Haynes, (51 ,52 )Thomas, ( 78) Telchmann,
,
( I
(79) Warowny
D Data Weight Temp. Dens ty i Dens ty Dens ty P Pr essui

i I
©xpi" ^ca c
1
Point expt calc DIff Dif f

No. K mol/L kgArr' kg/wr % MPa f4â %
24 932 1 .000 288.263 11 .518 507.93 507.82 .02 .9950 1.0384 -4.18
24 933 1 .000 288.981 1 .518
1 507.92 507.80 .02 1 .4087 1.4541 -3.12
24 934 1 .000 291 .393 1 .518
1 507.91 507.76 .03 2.7986 2.8591 -2.12
24 935 1 .000 293.489 1 .518
1 507.89 507.72 .03 4.0067 4.0744 -1 .66
24 936 1 .000 296.555 1 .517
1 507.87 507.68 .04 5.7744 5.8539 -1 .36
24 937 1 .000 300 . 1 04 11 .516 507.84 507.64 .04 7.8212 7.9082 -1.10
24 938 1 .000 303.696 1 1.516 507.82 507.61 .04 9.8936 9.9888 -.95
24 939 1 .000 307.131 1 1 .51 507.79 507.58 .04 1 .8760
1 1 1.9708 -.79
24 940 1 .000 310.771 1 1.515 507.77 507.57 .04 13.9780 1 4.0735 -.68
24 941 1 .000 314.179 11 .514 507.74 507.56 .04 15.9460 16.0341 -.55
24 942 1 .000 317.799 1 .514
1 507.72 507.56 .03 18.0380 1 8.1 195 -.45
24 943 1 .000 321 .470 11 .513 507.69 507.56 .03 20.1600 20.2263 -.33
24 944 1 .000 277.973 1 .837
1 521 .97 521 .90 .01 .5517 .5835 -5.45
24 945 1 .000 278.268 1 .837
1 521 .97 521 .90 .01 .7419 .7741 -4.16
24 946 1 .000 280.501 1 .836
1 521 .95 521 .89 .01 2.1805 2.2070 -1 .20
24 947 1 .000 283.701 11 .836 521 .93 521 .88 .01 4.2392 4.261 -.51
24 948 1 .000 288.949 11.835 521 .88 521 .87 .00 7.6082 7.6135 -.07
24 949 1 .000 294.597 1 .834
1 521 .84 521 .85 -.00 11 .2241 1 .2173
1 .06
24 950 1 .000 299.983 1 .833
1 521 .80 521 .84 -.01 14.6620 14.6428 .13
24 951 1 .000 308.342 1 .832
1 521 .74 521 .80 -.01 19.9780 19.9412 .18
24 952 1 .000 319.913 1 .830
1 521 .65 521 .76 -.02 27.3000 27.2340 .24
24 953 1 .000 267.752 12.155 536.01 535.79 .04 .4041 .5227 -22.69
24 954 1 .000 268.361 12.155 536.00 535.78 .04 .8370 .9521 -12.09
24 955 1 .000 269.31 12.155 536.00 535.78 .04 1 .5169 1.6348 -7.21
24 956 1 .000 270.036 1 2.155 535.99 535.78 .04 2.0268 2.1413 -5.35
24 957 1 .000 271 .190 12.155 535.98 535.77 .04 2.8457 2.9581 -3.80
24 958 1 .000 273.224 12.154 535.96 535.77 .04 4.2877 4.3946 -2.43
24 959 1 .000 275.321 12.154 535.95 535.76 .04 5.7722 5.8794 -1 .82
24 960 1 .000 277.531 12.153 535.93 535.75 .03 7.3345 7.4365 -1 .37
24 961 1 .000 280.521 12.153 535.90 535.74 .03 9.4447 9.5375 -.97
24 962 1 .000 283.740 1 2 . 1 52 535.88 535.73 .03 1 1 .7120 1 .8018
1 -.76
24 963 1 .000 287.984 12.151 535.84 535.71 .02 14.6930 14.7714 -.53
24 964 1 .000 293.573 12.150 535.80 535.69 .02 18.6070 18.6775 -.38
24 965 1 .000 299.091 12.149 535.75 535.67 .02 22.4570 22.51 34 -.25
24 966 1 .000 304.757 12.148 535.70 535.64 .01 26.3950 26.4392 -.17
24 967 1 .000 312.701 12.147 535.64 535.59 .01 31 .8910 31.9273 -.11
24 968 1 .000 323.740 12.145 535.55 535.52 .01 39.4790 39.5054 -.07
24 969 1 .000 258.574 12.446 548.83 548.46 .07 .7550 .9794 -22.91
24 970 1 .000 260.283 12.446 548.82 548.47 .06 2.0907 2.3072 -9.38
24 971 1 .000 264.687 12.445 548.78 548.49 .05 5.5231 5.7107 -3.29
24 972 1 .000 269.204 12.444 548.74 548.50 .04 9.0289 9.1889 -1 .74
24 973 1 .000 273.221 12.443 548.70 548.50 .04 12.1340 12.2680 -1 .09
24 974 1 .000 278.846 12.442 548.65 548.50 .03 16.4630 16.5672 -.63
24 975 1 .000 283.771 12.441 548.61 548.50 .02 20.2350 20.3188 -.41
24 976 1 .000 288.215 12.440 548.57 548.48 .02 23.6230 23.6893 -.28
24 977 1 .000 293.359 12.439 548.53 548.46 .01 27.5270 27.5819 -.20
24 978 1 .000 297.819 12.438 548.49 548.43 .01 30.8960 30.9413 -.15
24 979 1 .000 300.501 12.438 548.46 548.42 .01 32.9150 32.951 -.11
24 980 1 .000 305.386 12.437 548.42 548.38 .01 36.5800 36.6151 -.10
24 981 1 .000 310.827 12.435 548.37 548.33 .01 40.6410 40.6767 -.09
24 982 1 .000 250.200 12.689 559.53 559.02 .09 .7767 1 .1235 -30.87
24 983 1 .000 251 .067 12.688 559.52 559.04 .09 1 .5143 1 .8463 -1 7.98
24 984 1 .000 251 .924 12.688 559.51 559.05 .08 2.2426 2.5600 -1 2.40
24 985 i .000 253.890 12.688 559.49 559.08 .07 3.9104 4.1969 -6.83
24 986 1 .000 258.31 12.687 559.45 559.14 .06 7.6451 7.8699 -2.86
24 987 1 .000 263.206 12.686 559.40 559.19 .04 1 1.7550 11.9142 -1 .34
89
0 . 9
0
8
4 1 1 1 0
4 4
7
1 ,
Data sources and ID numbers: (l)Virial Equati on, (2)Dawson, (3)BeattIe, (4)Deschner, (5)Reamer,
(13)Cherney, ( 1 7 )Tom nson , (24)£ly, (26)Dittm ar, (XXXX)Haynes,
I i 51 ,52 )Thomas, ( 78 )Te Ichmann (
(79)Warowny.
D Data Weight Temp Dens ty I Density Density 'êxot ^calc Pressure

Point expt caic Diff. ^ Diff.
No. K mol /L kg/m^ Wq/w? % MPa MPa %
24 988 1 .000 263.259 1 2.686 559.40 559. 19 .04 1 .7830

1 1 1 .9417 -1 .33
24 989 1 .000 268.01 1 2.685 559.36 559.22 .03 15.7660 15.8760 -.69
24 990 1 .000 276.292 1 2.683 559.28 559.23 .01 22.61 20 22.6495 -.17
24 991 1 .000 283.434 1 2.681 559.21 559.21 -.00 28.4990 28.4958 .01
24 992 1 .000 294.455 1 2.679 559. 1 559.13 -.00 37.3690 37.3553 .04
24 993 1 .000 247.621 1 2.742 561 .87 561 .45 .08 .2571 .5525 -53.47
24 994 1 .000 247. 734 1 2.742 561 .87 561 .45 .08 .3546 .6493 -45.39
24 995 1 .000 248.490 1 2 .742 561 .87 561 .46 .07 1 .0065 1 .2965 -22 .37
24 995 1 .000 248.673 1 2. 741 561 .86 561 .46 .07 1 . 6421 1 .4460 -1 9.49
c it 1 *7 1 ZA"7 1 1 Z Ait
24 997 1 .000 249.31 1 2 . 74 561 .86 yi
.0 / 1 . / 30 I 1 .yyoy -1 3.96
24 998 1 .000 250.333 1 2.741 561 . 85 561 .48 .07 2.5934 2 .8580 -9.26
24 999 1 . 000 251 .088 1 2. 741 561 . 84 561 .49 .06 3.2424 3.4955 -7 .24
C A 0 AZ A AQ
24 1 000 1 .000 252 .974 1 2. /40 561 .oZ 561 .51 .06 4.O6I I 5.0693
0
-2 CA
24 1 001 1 .000 255 . 995 1 2. 740 561 . 79 561 . 53 .05 1 .4466 /.63/4 . 50
IT Q
24 1002 1 .000 258. 548 1 2 739
. 561 .77 561 .55 .04 y .6241 9.7889 -11 .60
24 1003 1 .000 263 .440 1 2 738
. 561 .72 561 . 58 .02 1 3. 781 1 3. 8879 -.11
24 1004 1 .000 268. 97 1 1 2 . 737 561 .68 561 . 59 .0^ 1 930
/ . / 1 /. ooZ^) -.39
24 1005 1 .000 273.360 1 2.736 561 .63 561 .60 .01 22. 1 250 22. 530 1 -.13
24 1006 1 .000 278.376 1 2. 735 561 .58 561 . 59 - .00 26 .3070 26 .301 .02
24 1007 1 .000 283.231 1 2. 734 551 .53 561 .57 -.01 30.3300 30. 2986 . 0 1
24 1008 1 .000 288.691 1 2.733 561 .48 561 .53 -.01 34.8260 34.7805 . 1 3
24 1009 1 .000 293.107 1 2. 732 561 .44 561 .49 -.01 38.4390 38.391 .1 2
24 1 01 1 .000 297.847 1 2.731 561 .40 561 .44 -.01 42. 2950 42.2569 .09
24 101 1 1 .000 247.820 1 2.773 563.26 563.03 .04 .5453
1 1 .7064 -9.44
24 1012 1 .000 248.646 12.773 563.26 563.04 .04 2.261 2.41 96 -6.54
24 1013 1 .000 250.345 12.773 563.24 563.05 .03 3.7322 3.8702 -3.57
24 1014 1 .000 252.1 31 12.772 563.22 563.06 .03 5 .2754 5.3930 -2.18
24 101 5 1 .000 254.247 12.772 563.20 563 .07 .02 7.0999 7.1 962 -1 .34
24 1 016 1 . 000 256.785 12.771 563.18 563.08 .02 9.2327 9.3570 -.79
24 101 7 1 .000 259.61 12.771 563.15 563.09 .01 1 1 . 7 1 30 1 1.7576 -.38
24 101 8 1 .000 262.510 12.770 563.12 563.10 .00 14.1 840 1 4 .2002 -. 1 1
24 1 01 9 1 .000 265.495 12.769 563.09 563.10 -.00 16.7280 16.71 60 .07

24 1 020 1 .000 268.1 71 12. 769 563.07 563.1 -.01 1 9.0010 1 8.971 .16
24 1021 1 .000 271 .181 12.768 563.04 563.1 -.01 21 .5500 21 .4952 .25
24 1022 1 .000 276.240 12.767 562.99 563.10 -.02 25.8150 25.7229 .36
24 1023 1 .000 281 .440 12.766 562.94 563.08 -.02 30. 730 1 30.0506 .41
24 1024 1 .000 286.945 1 2 . 765 562.89 563.05 -.03 34.7600 34.61 46 .42
24 1025 1 .000 286.968 12.765 562.89 563.05 -.03 34.7790 34.6338 .42
24 1026 1 .000 291 .062 12.764 562.85 563.02 -.03 38.1 720 38.01 22 .42
24 1027 1 .000 296.653 12.763 562 .80 562 .97 -.03 42.7790 42.61 27 .39
24 1028 1 .000 235.542 13.073 576.47 576.24 .04 .4570 .6449 -29. 1 3
24 1029 1 .000 236. 63 1 13.072 576.46 576.25 .04 1 .0563 .2257
1 -13.82
24 1030 1 .000 237.1 16 13.072 576.45 576.27 .03 1 .9745 2.1205 -6.89
24 1 031 1 .000 237.986 13.072 576.44 576.29 .03 2.81 12 2.9358 -4.24
24 1032 1 .000 239.626 13.072 576.43 576.32 .02 4.3844 4.4775 -2.08
24 1033 1 .000 242.193 13.071 576.40 576.36 .01 6.8363 6.8728 -.53
24 1034 1 .000 245.592 13.070 576.37 576.39 -.00 10.0630 10.0417 .21
24 1035 1 .000 249.203 13.070 576.33 576.42 -.02 13.4660 13.3880 .58
24 1036 1 .000 252.921 13.069 576.29 576.43 -.02 16.9440 16.8206 .73
24 1037 1 .000 256.51 13.068 576.25 576.42 -.03 20.2830 20.1276 .77
24 1038 1 .000 260.718 13.067 576.21 575.39 -.03 24.1490 23.9797 .71
24 1039 1 .000 264.442 13.066 576.17 576.35 -.03 27.5490 27.3777 .63
24 1040 1 .000 267.990 13.065 576.13 576.29 -.03 30.7630 30.6017 .53
24 1041 1 .000 232.965 13.169 580.70 580.12 .10 1.1792 .6707
1 -29.42
24 1042 1 .000 234.603 13.168 580.69 580.14 .09 2.7885 3.2595 -14.45
24 1043 1 .000 234.672 13.168 580.69 580.14 .09 2.8562 3.3267 -14.14
90
. . 8 3
1 5 0
4 0
Table 7. (ConMnued)
Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)BeattIe, (4)Deschner, (5)Rearner,
(13)Cherney, ( 7 )Tom nson
1 I (24)Ely, (26)Dittmar, (XXXX )Haynes, ( 51 , 52 )Thomas, (78)Teichmann,
I
,
(79) Warowny
D Data Weight Temp Dens ty I Dens ty I Dens ty p Pressur

1
expt ca c
1
Point expt ca Ic DIff. DIff.

No. K mol/L kg/rr' kg/fn-^ i MPa MPa %
24 1044 1 .000 236.343 13.168 580.67 580.16 .09 4.4938 4.9357 -8.95
24 1045 1 .000 238.154 13.167 530.65 580.18 .08 6.2641 5.6770 -6.18
24 1046 1 .000 239.793 13.167 580.63 580.19 .08 7.8622 8.2479 -4.68
24 1047 1 .000 242.380 13.166 580.60 580.22 .07 10.3770 10.7225 -3.22
24 1048 1 .000 245.001 13.166 580.58 580.23 .05 12.9150 13.2315 -2.39
24 1049 1 .000 249.556 13.165 580.53 580.26 .05 17.3020 17.5603 -1 .47
24 1050 1 .000 254.065 1 3 . 1 64 580.48 580.26 .04 21 .6150 21 .8236 -.96
24 1051 1 .000 258.913 13.163 580.43 580.26 .03 26.221 26.3885 -.63
24 1052 1 .000 263.566 13.151 580.38 580.25 .02 30.6100 30.7468 -.44
24 1053 1 .000 268.61 13.160 580.33 580.21 .02 35.3390 35.4606 -.34
24 1054 1 .000 273.058 13.159 580.28 580.18 .02 39.4660 39.5783 -.28
24 1055 1 .000 226.866 13.315 587.16 587.03 .02 1.1 092 1 .2271 -9.60
24 1056 1 .000 228.670 13.315 587.14 587.05 .01 2.9726 3.0503 -2.55
24 1057 1 .000 230.980 13.314 587.12 587.09 .01 5.351 5.3837 -.50
24 1058 1 .000 234.058 13.313 587.08 587.12 -.01 8.5084 8.4694 .45
24 1059 1 .000 237.362 13.313 587.06 587.1 -.02 11.8810 1 .7900
1 .77
24 1060 1 .000 242.108 1 3.31 587.00 587.19 -.03 16.6960 16.5067 1.15
24 1 061 1 .000 247.394 13.310 586.94 587.22 -.05 22.01 90 21 .7355 1 .30
24 1062 1 .000 250.1 51 13.309 586.91 587.23 -.05 24.7790 24.4515 1 .34
24 1063 1 .000 254.663 13.308 586.86 587.23 -.06 29.2690 28.8779 1 .35
24 1064 1 .000 258.294 13.307 586.82 587.22 -.07 32.8600 32.4248 1 .34
24 1065 1 .000 261 .963 13.306 586.76 587.21 -.08 36.4690 35.9737 1 .38
24 1066 1 .000 265.574 13.306 586.74 587.19 -.08 40.0010 39.4955 1 .28
24 1067 1 .000 21 8.855 13.516 596.03 595.70 .06 .7779 1 . 101 4 -29.37
24 1068 1 .000 219.585 13.516 596.02 595.71 .05 1 .5821 1 .8853 -16.08
24 1069 1 .000 221 .230 13.516 596.00 595.74 .04 3.3908 3.551 -7.13
24 1070 1 .000 223.680 13.515 595.98 595.77 .03 6.0763 6.2828 -3.29
24 1071 1 .000 226.125 13.514 595.95 595.81 .02 8.7463 8.8900 -1 .62
24 1072 1 .000 227.750 13.514 595.93 595.83 .02 10.5150 10.6179 -.97
24 1073 1 .000 228.861 13.514 595.92 595.84 .01 1 .7220
1 1 .8008
1 -.67
24 1074 1 .000 229.601 13.514 595.91 595.85 .01 12.5250 12.5842 -.47
24 1075 1 .000 231 .940 13.51 595.88 595.88 .00 15.0560 15.0571 -.01
24 1076 1.000 234.664 13.512 595.85 595.91 -.01 17.9930 17.9328 .34
24 1077 1 .000 238.083 13.51 1 595.81 595.93 -.02 21 .6610 21 .5256 .63
24 1078 1 .000 242.385 13.510 595.76 595.96 -.03 26.2480 26.0254 .86
24 1079 1 .000 246.702 13.509 595.71 595.97 -.04 30.8200 30.5180 .99
24 1080 1 .000 251 .325 13.508 595.66 595.98 -.05 35.5820 35.3086 1 .06
24 1081 1 .000 256.596 13.507 595.60 595.97 -.06 41 .1820 40.7376 1 .09
24 1082 1 .000 21 1 .641 13.696 603.95 603.33 .10 .4075 .0574

1 -51 .47
24 1083 1 .000 212.694 13.696 603.94 603.35 .10 .5320
1 2.2571 -27.70
24 1084 1 .000 214.101 13.695 603.92 603.37 .09 3.2652 3.8500 -1 5.19
24 1085 1 .000 21 7.902 13.694 603.87 603.43 .07 7.6602 8. 1 396 -5.89
24 1086 1 .000 222.089 13.693 603.82 603.49 .05 12.4730 12.8420 -2.87
24 1087 1 .000 225.450 13.692 603.78 603.53 .04 16.3140 16.5964 -1 .70
24 1088 1 .000 230.231 13.691 603.72 603.61 .02 21 .7740 21 .9035 -.59
24 1089 1 .000 235.520 13.689 603.66 603.63 .01 27.7060 27.7432 -.13
24 1090 1 .000 241 .297 13.688 603.59 603.66 -.01 34.1 620 34.0721 .25
24 1091 1 .000 244.776 13.687 603.55 503.57 -.02 38.0220 37.8649 .41
24 1092 1 .000 247.542 13.586 603.51 603.58 -.03 41 .0760 40.8589 .53
24 1093 1 .000 205.755 13.857 61 .05
1 61 0.99 .01 1 .7549 .8348
1 -3.81
24 1094 1 .000 207.297 13.856 61 1 .03 51 1 .02 .00 3.6605 3.5728 -.33
24 1095 1 .000 209.435 13.856 61 1 .01 61 1 .06 -.01 6.2801 6.2222 .93
24 1096 1 .000 212.526 13.855 610.97 61 1 .11 -.02 10.0490 9.8797 1 .71
24 1097 1 .000 216.578 13.854 610.91 51 1 .18 -.04 14.9560 14.6384 2.17
24 1098 1 .000 220.157 13.853 610.87 61 1 .22 -.06 19.2590 18.8327 2.26
24 1099 1 .000 225.334 13.851 610.80 61 1 .27 -.08 25.4320 24.8468 2.36
91
. 7
5 8 4
0
2
. 0 7 ,
Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)8eattie; (4)Deschner, (5)Rea(ner,
(13)Cherney, (1 7)Toml inson, (24)Ely, (26 )D ttmar, (XXXX)Haynes, (51 ,52 )Thomas,
i 78 )Te ichrnann (
(79)V/arowny
ID Data Wei ght Temp. Dens ty i Dens ty i Dens tyi

expt cal c Pressure
Po nt I expt calc Diff Diff.
No. K mol/L kg/nr kg/m^ MPa MPa
24 11 00 1.000 227.547 13.851 610.78 61 .28

1 -.08 28.0520 27.4169 2.32
24 1 101 1 .000 230.819 13.850 610.73 61 .29
1 -.09 31 .9060 31 . 1 770 2.34
24 1102 1 .000 235.224 13.848 610.68 61 .30
1 -.10 37.0550 36.2358 2.26
24 I103 1 .000 237.320 13.848 610.65 61 .30
1 -.11 39.4890 38.6247 2.24
24 1104 1 .000 199.157 13.991 616.96 61 7.01 -.01 .5378 .4838 11.16
24 1105 1 .000 200.472 13.990 616.94 61 7.04 -,02 2.2353 2.1 78 1 5.55
24 1106 1 .000 202.81 13.990 616.91 61 7.08 -.03 5.2383 5.0287 4,1 7
24 1107 1 .000 206.391 13.989 61 6.86 61 7.16 -.05 9,7993 9.4371 3.84
24 1108 1 .000 210.980 13.987 616.80 61 7.23 -.07 1 5.6020 15 .0640 3.57
24 1109 1 .000 216.347 13.986 616.73 61 7.29 -.09 22.3260 21 .5934 3.39
24 1110 1 .000 21 6.464 13.985 616.72 61 7.26 -.09 22.4300 21 .7241 3.25
24 1111 1 .000 221 .205 13.984 616.66 61 7.10 -.07 28.031 27.4494 2.12
24 1112 1 .000 225.885 13.983 616.60 61 7.32 -.12 34.0430 33.0622 2.97
24 1113 1 .000 231 .094 13.981 616.53 61 7.32 -.13 40.3660 39.2628 2.81
24 1114 1 .000 192.61 14.155 624.19 624.28 -.01 .9162 .8001 1 4.52
24 1115 1 .000 193.111 14.155 624.19 624.29 -.02 1.5904 1.4585 9.05
24 1116 1 .000 195.904 14.154 624.15 624.36 -.03 5.3735 5,1041 5.28
24 1117 1 .000 197.140 14.154 624.13 624.39 -.04 7.0407 6.7082 4.96
24 1118 1 .000 199.390 14.153 624.10 624.44 -.05 1 0.0650 9.6273 4.55
24 1119 1 .000 202.609 14.152 624.05 624.50 -.07 1 4.3660 13.7738 4.30
24 1120 1 .000 205.926 14.151 624.01 624.55 -.09 1 8.7680 18.0378 4.05
24 1121 1 .000 209.500 14.150 623.96 624.60 -. 1 23.4770 22.5969 3.89
24 1122 1 .000 213.137 14.149 623.91 624.64 -. 1 28.2320 27.2110 3.75
24 1123 1 .000 215.014 14.148 623.88 624.65 -, 1 2 30-6720 29. 5762 3. 71
24 1124 1 .000 21 7.285 14.147 623.85 624.67 -.13 33.6100 32.4378 3.61
24 1125 1 .000 220.119 14.146 623.81 624.68 -. 1 37 .2570 35.991 3,52
24 1126 1 .000 184.715 14.340 632.34 632,36 - .00 .61 63 .5835 5 .63
24 1127 1 .000 185.973 14.339 632.32 632.40 -.01 2.4300 2.3255 4.49
24 I 23I 1 .000 187.723 14.339 632.30 631 .97 .05 4.2992 4.7519 -9.53
24 1129 1 .000 189.954 14.338 632.26 632.49 ft 1 'M^ 7 fli "^0 4 1
24 1130 1 .000 194.865 14.336 632.19 632.60 IS 1 1 1 n 4 .01
24 1 131 1 .000 198.151 14.335 632.14 632.66 - 09. \ y• 1 ^ j\j 1ft QR41
24 1132 1 .000 204.051 14.333 632.05 632.75 - 1 1 ^- 1 * ^ J j\j 26 .91 83 3 .85

24 1133 1 .000 208.548 14.332 631 .99 632.79 "^4 470 1 ^ 71
24 1134 1 .000 213.736 14.330 631 .91 632,82 -.14 41 . 2 40 1 39 .7878 3.58
24 1135 1 ,000 177.351 14.524 640.48 640.55 -.01 1 ,3550 .2502
1 8.38
24 1136 1 .000 179.819 14.523 640.44 640.62 5.1 580 4.8634 5.44
24 1137 1 .000 181 .543 14.523 640.41 640.67 -.04 7.7509 7.3727 5.13
24 1138 1 .000 183.330 14.522 640.39 640.71 -.05 1 0.4590 9.9802 4 .80
24 1139 1 .000 187.888 14.521 640.32 640.81 -.08 17.3130 16.5602 4.55
24 1140 1 .000 190.854 14.520 640.27 640.87 -.09 21 .7350 20.8033 4.48
24 1141 1 .000 194.795 14.51 640.21 640.94 -.11 27.5610 26.4145 4.34
24 1142 1 .000 198.915 14.517 640.15 640.99 -.13 33.5930 32.2424 4.19
24 1143 1 .000 201 .433 14.516 640.11 641 .01 -.14 37.2500 35.7785 4.11
24 1144 1 .000 204.618 14.515 640.06 641 .03 -.15 41 .8440 40.2308 4.01
24 1145 1 .000 166.227 14.776 651 .60 651 .57 .01 .7033 .7554 -6.91
24 1 146 1 .000 167.461 14.776 651 .58 651 .61 -.00 2.7642 2.7174 1.72
24 1147 1 .000 168.747 14.776 651 .56 651 .65 -.01 4.9045 4.7569 3. 10
24 1 148 1 .000 171 .053 14.775 651 ,52 651 .73 -.03 8.7235 8.3916 3.95
24 1149 1 .000 174.434 14.773 651 .46 651 .82 -.06 14.2790 13.6830 4.36
24 11 50 1 .000 178.373 14.772 651 .39 651 .92 -.08 20.6850 19.7969 4.49
24 1 151 1 .000 182.557 14.770 651 .32 652.00 -.10 27.41 10 26.2425 4.45
24 1152 1 .000 187.796 14.768 651 .24 652.08 -.13 35.7200 34.2506 4.29
24 1153 1 .000 189.817 14.768 651 .21 652.10 -.14 38.8920 37.3200 4.21
92
A1 .. • U
I1 1 y
U
D
1
1! J. D
1 / A
4
J
9
/
I , 1
Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)8eattie, {4)Deschner, (5)Reainer,
(13)Cherney, 7 )Tom nson , (24)Ely, ( 26)D ttmar
( 1 I (XXXX)Haynes. (51 ,52 )Thomas, ( 78 )Te Ichmann
i i
,
(79)Warowny.
ID Data We ght i Temp. Dens ty i Dens ity Dens ty i

expt ca c I
Pressure
Point expt ca c I Diff Diff.
No. K mol /L k Q/m 1 11 a MPa
l^lr a f>
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5 1196 1 .000 327.594 .356 15.68 15.72 -.29 .8618 .8597 .25
5 1197 1 .000 327.594 .440 19.38 19.42 -.16 1 .0342 1 .0328 .14
5 1198 1 .000 327.594 .629 27.72 27.67 .20 1 .3790 1.3811 -.15
5 1199 1 .000 327.594 10.018 441 .76 440.57 .27 2.0684 2.2573 -8.37
5 1200 1 .000 327.594 10.1 15 446.03 444.77 .28 2.7579 2.9769 -7.36
5 1201 1 .000 327.594 10.198 449.71 448.61 .25 3.4474 3.6568 -5.73
5 1202 1 .000 32 7.594 10.275 453.12 452.14 .22 4 . 369 1 4.3365 -4.60
5 1203 1 .000 327.594 10.416 459.33 458.51 .18 5.51 58 5.7086 -3.38
5 1204 1 .000 327.594 10.538 464.69 464.14 .12 6.8948 7.0363 -2.01
5 1205 1 .000 327.594 10.675 470.73 470.42 .06 8.6184 8.7062 -1 .01
5 1206 1 .000 327.594 10.805 476.46 476.05 .09 10.3421 10.4741 -1 .26
5 1207 1 .000 327.594 10.905 480.88 481 .16 -.06 12.0658 1 .9649 1 .84
5 1208 1 .000 327.594 1 1 .015 485.72 485.86 -.03 13.7895 13.7346 .40
5 1209 1 .000 327.594 1 1 . 06 1 489.75 490.22 -.10 15.5132 15.3191 1 .27
93
2
1 . . 1 8 35 1 6
4 2
/
1 4
Data sources and ID numbers: (l)VIrial Equation, (2)Dawson, (3)3eattie, (4)Deschner, (5)Reamer,
(13)Cherney, 7 )Tom nson (24)Ely, (26 )D ttinar, (XXXX)Haynes, (51 ,52)Thomas, (78)Teichmann,
( 1 I i
, i
(79) Warowny
) Data We a h tI Temp Dens ty

i D^^n o I np^
l-'O n c + \/
Hot i p .
P 1 1^ r* cc 1 1 r~ o
1 1 ( 1
y y 1
•êxpt '
ca! c
Point expt ca c 1 iff. D i f f •
No • K moi /L kg/irr k g/ m"^ MPa MPa t
5 1 210 1 cOOO 327.594 11.212 494,41 494 .29 .02 17.2369 1 7.291 -.31
5 1 21 1 .000 327 .594 1 .300
1 498.30 498.1 .04 18.9606 19.0484 -.46
5 1 21 1 .000 327.594 1 .388
1 502.18 501 .71 .09 20.6843 20.91 63 -1.11
5 1 21 3 1 .000 327.594 1 .532
1 508.54 508.38 .03 24.1316 24. 2238 -.38
5 1214 1 .000 327.594 1 .662
1 514.25 514,44 -.04 27.5790 27.4680 .40
5 1 21 5 1 .000 327.594 1 .768
1 518.94 520,01 -.21 31 .0264 30.341 2,26
5 1 21 6 1 .000 327.594 1 .906
1 525.02 525,18 -.03 34.4738 34.3580 ,34
5 121 7 1 .000 327.594 12.150 535.77 534.54 .23 41 .3685 42.3382 -2,29
5 1 21 8 1 .000 327.594 12.315 543.04 542.87 .03 48.2633 48.41 70 -,32
5 1219 1 .000 327.594 12.475 550.12 550.39 -.05 55.1581 54.8964 .48
5 1220 1 .000 327.594 12.623 556.64 557.27 -.11 62.0528 61 .3997 1 .06
5 1221 1 .000 327.594 12.805 564.67 563.61 .19 68.9476 70.1477 -1 .71
5 1222 1 .000 344.261 .036 1 .58 1 .58 -.25 .1013 .101 .25
5 1 223 1 .000 344.261 .049 2.15 2.16 -.27 .1379 .1375 .27
5 1224 1 .000 344.261 .074 3.25 3.26 -.31 .2068 .2062 .30
5 1 225 1 .000 344.261 .099 4.37 4.38 -.32 .2758 .2749 .32
5 1226 1 .000 344.261 .125 5.50 5.52 -.34 .3447 .3436 .33
5 1 227 1 .000 344.261 .151 6.65 6.68 -.33 ,41 37 ,41 24 ,32
5 1 228 1 .000 344.261 .204 9.01 9.04 -.33 ,5516 ,5499 .31
5 1 229 1 .000 344.261 .260 1 1.45 1 .49
1 -.30 .6895 .6875 ,28
5 1 230 1 .000 344.261 . 332 14,63 1 4.67 -.24 .861 8 .8600 ,22
5 1 231 1 .000 344.261 .408 17.98 18.01 -.1 1.0342 1 .0327 ,14
5 1 232 1 .000 344 .261 .573 25.25 25. 24 .06 1,3790 1 .3797 -,05
5 1 233 1 .000 344.261 .986 43.47 43.09 ,89 2,0684 2.0808 -,59
5 1 734 1 .000 344.261 9. 1 41 403.09 401 .57 ,38 2,7579 2. 8840 -4,37
R 1 93'5 1 .000 344 .9fi1 9.293 409. 78 409.21 , 1 3.4474 3.5050 -1 ,64
J 1( P'^fi
^_>o 1 non 344 9fi1 9. 433 41 5.98 41 ^ ^1 1 n 4 1 3ftQ 4 1 ftS4 -1 1 , D
1ft1
R
J 1 9'S7 1 nnn 344 . 9fi1 9.659 425 . 92 49S Oft "SI ^9. 5. "5081 1 4
R
J 1 1 nnn 344 9fi1 9. 847 434 .24 434 43 - n4 D , O ^HO ft ftftnQ . 4Q
H^
R
J 1 'J'^Q 1 nnn 344 9ft 1 0.049 443. 1
443 9R - n3 O w ft4
ft , ftl OH 1
ft SQ1 Q , J \
R
J 1
1
94.n
Z M-W 1 nnn 344 9ft1 1 0. 229 451 .08 4Rn P3 , DD
nfi in 3491 1
1 D , 4n33
n HU_?_J - RQ
R
J 1t 941
ZH 1
1 nnn 344 9ft1 1 0.374 457.48 4S7 47 nn 11 9 , nfti^ft
Z ^w/D^ O 1 9 n7nQ - . DH
n4
R
J 1 949 1 nnn 344 9fi1 1
1
n • 'i9n
U _^ZD HD^ . Q9
4ft3 7Z 4ft3 4n ,
1
1
1
1
1 3 7flQR 13
1J . Q4fl1
^H O t
-1 1 . 1
1
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H
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J 1 94"^ 1 nnn 344 . 9ft1
ZD 1
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^ . DH^
11 ft43 4ftQ
HD 33
^ • -J J 4AR , OU
HDO Rn .
1
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R1 _JZ
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R 1 944 1 nnn 344 9ft1 in 7S7 474 34 4 7^^ 7R •
1 T
1 ^ 1 7 9'^ftQ 1 7 4R"^7 -1 I . 94
ZH
R 1 94R 1
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J^HH 9ft1 1
in R71 470 3q A19. "^3
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1
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4ft9
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ZU «ic\i
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J 1 947 1 nnn 344 . 9ft1
-JHM- ZD 1 11 .141 491 .28 4Qn 4n 1 R 94
ZH . 31 Dft 1
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ZH R4ftft -1 1 D^
. ftQ
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J 1 943 1 nnn 344 9fi1 1 .282
1 497.49 4Q7 3R . n9
DZ Z . ^ 7 Qn
97 ^D
/ 'i / 97
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D_-'UD
/ . Z 1
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J 11 Z.94Q
H^ 1 nnn 344 a 9fi1
^'+'+ ZD t 1 1 .407 503.02 Sn3 79 - 1 4 31 n9ft4 30 . DZ. D
ft9ft1 1
1 31
R
J 1 9sn 1 nnn 344 9fi1 11 .551 509 ,37 RnQ "i"! - n3 34 473R 34H . 3ft 74
_^ H / . J 1
R
J 11 9^11
^ V 1
1 nnn 344 . ZD
^HH 9ft1 1 1 1 .81 521 . 1 SI Q 07 e 99
Z Z 41 3fiftS 49 . QQn
HZ " J'D 1
1
-1 .Q7
R
J 19S9 1 nnn 344H . 9fi1
Z. D t 12.009 529.56 S9Q 19 na HO.
4ft 9fi33
Z. D_-'_^ HO . ft19ft
4ft D ^D 1
- 79
5 1253 1 .000 344 .261 12.182 537.18 537 ,32 -.n3 55 , 1 581 55 .0349 ,22
5 1254 1 .000 344.261 12.344 544.32 544.77 -.08 62,0528 61 .6206 ,70
5 1255 1 .000 344.261 12.518 551 .99 551 .59 .07 68.9476 69,3690 -.61
5 1256 1.000 360.928 .034 1 .50 1 .51 -.23 .1013 ,1011 .23
5 1257 1 .000 360.928 .047 2.05 2.06 -.26 .1379 ,1375 .26
5 1258 1 .000 360.928 .070 3.09 3.10 -.30 .2068 .2062 ,29
5 1259 1 .000 360.928 .094 4.15 4.17 -.30 .2758 .2750 .30
5 1260 1 .000 360.928 .118 5.22- 5.24 -.32 .3447 .3437 .31
5 1261 1 .000 360.928 .143 6.31 6,33 -.31 .41 37 .4124 .30
5 1262 1,000 360.928 .193 8.52 8,55 -.30 .5516 ,5500 .29
5 1263 1 .000 360.928 .245 10.80 10,83 -.29 .6895 ,6876 .27
5 1264 1 .000 360.928 .312 13.75 13,78 -.24 .8618 ,8600 .22
5 1265 1 .000 360.928 .381 16.82 16,84 -.16 1 .0342 1 ,0327 .15
94
Data sources and ID numbers: (l)Virlal Equation, (2)Dawson, (3)BeattIe, {4)Deschner, (5)Reamer,
(13)Cherney, ( 7 )Toml nson , (24)Ely, (26 )D ttrnar, (XXXX)Haynes, (51 ,52 )Thomas, ( 78 )Teichmann
1 i i
( 79) Warowny
ID Data Weight Temp. Dens ty i Dens ty i Dens tyi

expt cal c
Pressure
Point expt calc Dif f Diff
No. K mol/L kg/rrr kg/in-' MPa MPa
1266 1 .000 360.928 .530 23.36 23.36 .01 1.3790 1 .3790 -.01
1267 1 .000 360.928 .877 38.69 38.49 .53 2.0684 2.0768 -.40
1268 1.000 360.928 1 .342 59.16 58.33 1 .33 2.7579 2.7802 -.80
1269 1 .000 360.926 2.103 92.74 92.13 .67 3.4474 3.4552 -.23
1270 1 .000 360.928 8.1 71 360.32 359.03 .36 4.1369 4.1884 -1 .23
1271 1 .000 360.928 8.731 385.03 383.38 .43 5.51 58 5.5444 -2.28
1272 1 .000 360.928 9.063 399.64 398.36 .32 6.8948 7.0368 -2.02
1273 1 .000 360.928 9.363 412.90 412.03 .21 8.6184 8.7463 -1 .46
1274 1 .000 360.928 9.602 423.42 422.74 .16 10,3421 10.4644 -1.17
1275 1 .000 360.928 9.792 431 .79 431 .64 .03 12.0658 12.0953 -.25
1276 1 .000 360.928 9.971 439.71 439.32 .09 13.7895 13.8835 -.68
1277 1 .000 360.928 10.114 445.99 445.10 -.02 15.5132 15.4835 .19
1278 1 .000 360.928 10.262 452.52 452.20 .07 1 7.2369 17.3327 -.55
1279 1 .000 360.928 10.398 458.53 457.74 .17 18.9606 19.2171 -1 .33
1280 1 .000 360.928 10.492 462.67 462.84 -.04 20.6843 20.6241 .29
1 281 1 .000 360.928 10.71 472.59 471 .99 .13 24.1316 24.3768 -1 .01
1282 1 .000 360.928 10.886 480.03 480.03 -.00 27.5790 27.5764 .01
1283 1 .000 360.928 1 1 .062 487.80 487.25 .1 31 .0264 31 .3039 -.39
1284 1 .000 360.928 1 1 .1 91 493.47 493.80 -.07 34.4738 34.2948 .52
1285 1 .000 360.928 1 1 .501 507.14 505.38 .35 41 .3685 42.51 30 -2.59
1286 1 .000 360.928 1 1 .696 515.76 515.43 .06 48.2633 48.5028 -.49
1287 1 .000 360.928 1 1 .883 524.01 524.35 -.07 55.1581 54.8780 .51
1288 1 .000 350.928 12.056 531 .66 532.38 -.14 62.0528 61 .3999 1 .06
1289 1 .000 360.928 12.248 540.09 539.71 .07 68.9476 69.3186 -.54
1290 1 .000 377.594 .033 1 .43 1 .44 -.21 .1013 .1011 .21
1291 1 .000 377.594 .044 1 .96 1 .96 -.25 .1379 .1376 .24
1292 1 .000 377.594 .067 2.95 2.96 -.30 .2068 .2062 .30
1293 1 .000 377.594 .090 3.96 3.97 -.29 .2758 .2750 .28
1294 1.000 377.594 .113 4.97 4.99 -.29 .3447 .3438 .28
1295 1 .000 377.594 .136 6.00 6.02 -.29 .4137 .4125 .28
1296 1 .000 377.594 .184 8.09 8.12 -.27 .5516 .5502 .26
1297 1 .000 377.594 .232 10.23 10.26 -.26 .6895 .6878 .24
1298 1.000 377.594 .295 12.99 13.02 -.21 .8618 .8601 .20
1299 1 .000 377.594 .359 15.83 15.86 -.16 1 .0342 1.0327 .15
1300 1 .000 377.594 .495 21 .83 21 .83 -.02 1 .3790 1.3788 .01
1301 1 .000 377.594 .801 35.34 35.21 .38 2.0684 2.0747 -.30
1302 1 .000 377.594 1 .1 73 51 .74 51 .31 .82 2.7579 2.7741 -.58
1303 1 .000 377.594 .658
1 73.13 72.24 1 .23 3.4474 3.4720 -.71
1304 1 .000 377.594 2.397 105.72 104.58 1.08 4.1369 4.1543 -.42
1305 1 .000 377.594 7.050 310.88 306.76 1.34 5.51 58 5.5936 -1.39
1306 1 .000 377.594 7.951 350.61 349.34 .36 6.8948 5.9618 -.95
1307 1 .000 377.594 8.509 375.23 374.26 .26 8.61 84 8.7052 -1 .00
1308 1 .000 377.594 8.886 391 .85 390.65 .31 10.3421 10.4912 -1 .42
1309 1 .000 377.594 9.152 403.59 403.12 .12 12.0658 12.1383 -.60
1310 1 .000 377.594 9.385 413.84 413.31 .13 13.7895 13.8880 -.71
131 1 .000 377.594 9.568 421 .93 421 .97 -.01 15.5132 15.5044 .06
1312 1 .000 377.594 9.746 429.78 429.55 .05 17.2369 17.2926 -.32
1313 1 .000 377.594 9.908 436.92 436.30 .14 18.9606 19.1280 -.88
1314 1 .000 377.594 10.021 441 .91 442.41 -.11 20.6843 20.5376 .71
1315 1 .000 377.594 10.281 453.36 453.15 .05 24.1316 24.2044 -.30
1316 1.000 377.594 10.475 461 .90 462.43 -.11 27.5790 27.3723 .76
1317 1 .000 377.594 10.649 469.58 470.62 -.22 31 .0264 30.5683 1 .50
1318 1 .000 377.594 10.827 477.46 477.97 -.11 34.4738 34.2206 .74
1319 1 .000 377.594 1 .144
1 491 .44 490.82 .13 41 .3685 41 .7344 -.88
1320 1 .000 377.594 1 .385
1 502.05 501 .82 .05 48.2633 48.4178 -.32
1321 1 .000 377.594 1 .595
1 51 1 .32 51 1 .49 -.03 55.1581 55.0327 .23
95
. . 1\ 1 y 4
2 . 6
0 71/ ! , 81
Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)Bedttie, (4)Deschner, (5)Reamer,
(13)Cherney, (1 7)Toml inson, (24)Ely, (26)Dittmar, (XXXX )Haynes, ( 51 , 52 Thomas, ( 78)Telchmann
)
(79)Warowny.
Data WeigPit Temp Dens Ity Dens ty i Dens ty i

'êxpt '^ca 1 c Pressu
Point expt calc Diff Diff.
No. K mol /L % MPa MPa %
-.14 0 n CT 0 0
5 1 322 1 .000 377.594 1 1 . 779 519.43 520 . 1 62.0528 61 .4565 .97
5 1 323 1 .000 377 . 594 1 1 .969 COT
52 / . 01
oi 52 7 .98 -.03 68.9476 68.7931 .22
324 .000 41 0.928 A 7A
.030 1 TO
.3/ TO
1
• 32 -.20 .1013 .1011 .20
5 1 1 1 1
5 1 325 1 .000 riA

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0.928 7.625 336.26 335.49 .23 1 2.0658 12.1 259
5 1 344 1 .000 41 0.928 8.072 355 .93 354.40 .43 1 3.7895 1 3.9524 -1.17
5 1 345 1 .000 it1 n noo
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346 .000 410.928 381 .77 .24 .2369 1 7.3822
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5 1 351 1 .000 41 0.928 9.892 436.19 437. 1 -. 21 31 .0264 30. 7001 1 .06
5 1 352 1 .000 41 0.928 10.114 445.98 446.30 -.07 34.4738 34.3495 .36
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5 1 355 1 .000 410.928 1 .032
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5 1 356 1 .000 41 0.928 1 .249
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1
'Xe^^
S>OD 1
1
AAA
. UUU
AAA
444 Zo 1
.193 8.50 0. CO
Q jZ 0
-.Z4 >1
.Doy5 .00 /y OT
.Zj
5 1366 1 .000 444.261 .243 10.71 10.73 -.21 .8518 .8501 .20
5 1367 1 .000 444.261 .294 12.96 12.99 -.18 1 .0342 1 .0325 .17
5 1368 1 .000 444.261 .399 17.58 17.60 -.09 1 .3790 1 .3778 .08
5 1369 1 .000 444.261 .620 27.32 27.30 .10 2.0584 2.0702 -.09
5 1370 1 .000 444.261 .857 37.81 37.70 .29 2.7579 2.7649 -.25
5 1371 1 .000 444.261 1.115 49.16 48.93 .48 3.4474 3.461 1 -.40
5 1372 1 .000 444.261 1.395 61 .51- 61 .13 .61 4 . 359 1 4.1571 -.49
5 1373 1 .000 4U.26] 2.040 89.95 89.27 .76 5.51 58 5.5460 -.54
5 1374 1 .000 444.261 2.816 124.20 123.71 .39 6.8948 6.9124 -.25
5 1375 1 .000 444.261 3.956 174.44 174.26 .10 8.5184 8.6244 -.07
5 1376 1 .000 444.261 5.069 223.54 222.19 .61 10.3421 10.3962 -.52
5 1377 1 .000 444.261 5.91 5 260.84 260.34 .19 12.0658 12.0919 -.22
96
0
6
8
2 . . 1 1. 01 9
4.
Data sources and ID numbers: (l)VIrial Equation, (2)Dawson, (3)Beattie, (4)Descliner, (5)Reainer,
(13)Cherney, (1 7)Toml inson, (24)Ely, (26 )D ttinar , I (XXXX)Haynes, C?! ,52 )Thotnas, (78)Teichmann,
(79)Warowny
) Data We ght i Temp DensI ty Dens ty i Dens ty i

'êxpt ""calc Pressure
Point expt ca c 1 D i ff DIf f
/ T
kg/m^
1
No. K mol/L kg/m-^ % MPa r-lPa %
5 1378 1 .000 444.261 6.603 291 .20 289.35 .64 13.7895 1 3.9169 -.92
5 1379 1 .000 444.261 7.106 313.35 31 1 .52 .59 15.5132 15.6761 -1 .04
5 1380 1 .000 444.261 7.471 329.44 329.04 .12 1 7.2369 1 7.2809 -.25
5 1381 1 .000 444.261 7.803 344.09 343.37 .21 18.9606 19.0553 -.50
5 1382 1 .000 444.261 8.061 355.48 355.47 .00 20.6843 20.6365 -.01
5 1383 1 .000 444.261 8.51 4 375.44 375.12 .08 24.1315 24. 1949 -.26
5 1384 1 .000 444.261 8.856 390.54 390.77 -.06 27.5790 27.5233 .20
5 1385 1 .000 444.261 9.1 41 403.1 403.81 -.17 31 ,0264 30.8279 .64
5 1386 1 .000 444.261 9.407 414.81 41 5.00 -.05 34.4738 34.4100 .19
5 1387 1 .000 444.261 9.854 434.53 433.61 .21 41 .3685 41 .7488 -.91
5 1388 1 .000 444.261 10.195 449.55 448.81 .17 48.2633 48.6333 -.76
5 1389 1 .000 444.261 10.431 462.20 461 .70 .11 55.1581 55.4449 -.52
5 1390 1 .000 444.261 10.724 472.90 472.94 -.01 62.0528 62.0301 .04
5 1391 1 .000 444.261 10.975 483.96 482.92 .22 68.9476 69.7098 -1 .09
5 1392 1 .000 477.594 .026 1.13 1.13 -.17 .1013 .1012 .17
5 1393 1 .000 477.594 .035 1.54 1.54 -.19 .1379 .1376 .19
5 1 394 1 .000 477.594 .052 2.31 2.32 -.22 .2068 .2064 .22
5 1 395 1 .000 477.594 .070 3.09 3.10 -.24 .2758 .2751 .24
5 1396 1 .000 477.594 .088 3.88 3.89 -.25 .3447 .3439 .25
5 1 397 1 .000 477.594 .106 4.66 4.67 -.25 .4137 .41 27 .25
5 1 398 1 .000 477.594 .1 42 6.25 6.26 -.25 .5516 .5502 .25
5 1 399 1 .000 477.594 .1 78 7.85 7.87 -.25 .6395 .6878 .24
5 1 400 1 .000 477.594 .224 9.87 9.90 -.22 .861 8 .3600 .22
5 1 401 1 .000 477 .594 .270 1 1 .92 1 1 .95 -. 21 1 .0342 1 .0321 .21
5 1 402 1 .000 477.594 .365 16.10 16.13 -.1 5 1 .3790 1.3770 . 1
5 1 403 1 .000 477 .594 .562 24.80 24. 79 .03 2 .0684 2.0690 -.03
5 1 404 1 .000 477.594 . 770 33.96 33 .89 . 21 2.7579 2 .7631 -. 1
5 1 405 1 .000 477 .594 .990 43.64 43.47 .40 3.4474 3 .4595 -.35
5 1 406 1 .000 477 .594 1 .221 53 .83 53.56 .49 4.1 369 4, 544
1 -.42
5 1 407 1 .000 477.594 1.724 76.01 75 .55 .62 5.51 58 5.5433 -.50
5 1 408 1 .000 477.594 2.284 1 00 .74 1 00.22 .51 6.8948 6.9220 -.39
5 1 409 1 .000 477 . 594 3.058 134.83 1 34 .68 . 1 8.61 84 8.6258 -. 08
5 1 41 1 .000 477.594 3.864 170.39 1 70. 81 -.24 1 0.3421 1 0.3220 .20
5 1 41 1 1 .000 477.594 4.636 204.43 204.66 -. 1 1 2.0658 1 2.0535 .10
5 1 41 1 .000 477.594 5.31 8 234.49 234.00 .21 1 3.7895 1 3.821 -.23
5 1 41 3 1 .000 477.594 5.881 259.32 258.88 .1 7 15.51 32 15.5464 -.21
5 1 414 1 .000 477.594 6.381 281 .39 279.81 .57 17.2369 17.3807 -.83
5 1 41 5 1 .000 477.594 6.774 298.73 297.44 .43 18.9606 19.0983 -.72
5 1 41 1 .000 477.594 7.090 31 2.67 312.46 .07 20.6843 20.7106 -.1 3
5 141 7 1 .000 477.594 7.652 337.45 336.75 .21 24.1316 24.2444 -.46
5 1 41 1 .000 477.594 8.076 356.14 355.83 .09 27.5790 27.6426 -.23
5 1 41 9 1 .000 477.594 8.416 371 .14 371 .46 -.09 31 .0264 30.9486 .25
5 1 420 1 .000 477.594 8.728 384.89 384.70 .05 34.4738 34.5272 -.15
5 1 421 1 .000 477.594 9.247 407.79 406.32 .36 41.3635 41 .901 -1 .27
5 1422 1 .000 477.594 9.635 424.87 423.66 .29 48.2633 48.7981 -1 .10
5 1423 1 .000 477.594 9.961 439.25 438. 18 .25 55.1581 55.71 55 -1 .00
5 1424 1 .000 477.594 10.234 451 .31 450.69 .14 62.0528 62.4160 -.58
5 1425 1 .000 477.594 10.505 463.25 461 .72 .33 68.9476 69.972 7 -1 .47
5 1426 1 .000 510.928 .024 1 .05 1 .06 -.16 .1013 .1012 .16
5 1427 1 .000 510.928 .033 1 .44 1 .44 -.19 .1379 .1376 .19
5 1428 1 .000 510.928 .049 2.16 2.16 -.21 .2068 .2064 .21
5 1429 1 .000 510.928 .065 2.88 2.89 -.24 .2758 .2751 .23
5 1430 1 .000 510.928 .082 3.61 3.62 -.25 .3447 .3439 .25
5 1431 1 .000 51 0.928 .099 4.34 4.36 -.26 .4137 .4126 .26
5 1432 1 .000 510.928 .132 5.81 5.83 -.27 .5516 .5501 .27
5 1433 1 .000 510.928 .165 7.30 7.32 -.27 .6895 .6876 .27
97
. . m /
1 4 ,
Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)Beattie, (4)Deschner, (5)Reainer,
(13)Cherney, ( 7 )Tom nson, (24)Ely, (26)Dittmar,
1 1 i (XXXX)Haynes, ( 51 , 52 )Thomas, ( 78 )Te ichmann
( 79) Warowny
1
UaTa we 191)1 Temp Dens ty i De n s 1 y 1 Density êxpt cal c Pressui
rO ni 1 expt ca c 1 U 1 T T . D i f f .
if
No • t\ mo /l_i kg/ kg/ in To Mi-'a Mra P
1
4 j4 •UUU CIA QOQ OHQ
ZUO Q
y. D y. y -.zo ox 1 Q0
.001 0c
1
yl
f •
1
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1
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r\C\r\
D u.1 yzo 1
1
1
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1
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1 4•y Q1 1
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1.9/ OA
^7 yu 1
1
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• J fO\
1 01
c;
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1
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r\c\r\
• SI
J I
A
0 99Z . 7ft
Z Q /
99 . 7R
zz /o 9 . riftR4
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uy9 4R . zy
40 9Q An . 1 9S
40 1 . 9U A ^ftQ
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1
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1 0 9
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. Z R ftl 04
0.01 R4 —. Z91 1
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CIA 1
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u . yzo 9SQ
9 .Z9o 149 .Dy 14
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1 440 1
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©UUU sin Q9R 4.413 194.61 1
1
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44 49• 1
19./7RQS
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• UUU 4.951 218.31 Z R0Q
91 0I^ 1
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97 /
1 S S ^9 1
. 9U
5 1448 1 .000 510.928 5.431 239.43 239.72 -.10 1 7.2369 1 7.2163 .12
5 1449 1 .000 510.928 5.865 258.62 258.12 .19 13.9606 19.0108 -.26
5 1450 1 .000 510.928 6.223 274.41 274.36 .02 20.6843 20.6903 -.03
5 1451 1 .000 510.928 6.845 301 .86 301 .48 .13 24.1316 24.1857 -.22
5 1452 1 .000 510.928 7.331 323.28 323.17 .04 27.5790 27.6000 -.08
5 1453 1 .000 510.928 7.725 340.65 340.99 -.10 31 .0264 30.9551 .23
5 1454 1 .000 510.928 8.076 356.13 356.03 .03 34.4738 34.4973 -.07
5 1455 1 .000 510.928 8.650 381 .45 380.42 .27 41 .3685 41 .7036 -.80
5 1456 1 .000 510.928 9.095 401 .06 399.76 .33 48.2633 48.7816 -1 .06
5 1457 1 .000 510.928 9.462 417.27 41 5.80 .35 55.1581 55.8480 -1 .24
5 1458 1 .000 510.928 9.771 430.87 429.53 .31 62.0528 62.7765 -1.15
5 1459 1 .000 510.928 10.054 443.36 441 .55 .41 63.9476 70.061 -1 .59
98
1 . . 7
1 . 5 7 , 1
Data sources and ID numbers: (I)Vlrial Equation, (2)Dawson, (3)BeattIe, (4)Deschner, (5)Reamer,
(13)Cherney, 7 )Tom nson , (24)Ely, (26)0 ittrnar,
( 1 I I (XXXX)Haynes, 51 52 )Thomas, (78 )TeIchmann
( ,
(79)Warowny
ID Data Wei ght Temp Dens ty i Density Dens ty

i
'"êxpt ^cal c Pressure
No. K mol/L kg/m^ kg/m^ MPa MPa
51 1460 1 .000 258.150 12.435 548.33 549.02 -.13 .7657 .3440 122.57
51 1461 1 .000 258.150 12.440 548.57 549.23 -.12 .8954 .4888 83.19
51 1462 1 .000 258.150 12.446 548.82 549.39 -.10 .9944 .6426 54.75
51 1463 1 .000 258.150 12.451 549.06 549.66 -.11 1 .1605 .7888 47.1
51 1464 1 .000 263.150 12.289 541 .91 542.52 -.11 .7452 .3962 88.10
51 1465 1 .000 263.150 12.294 542.13 542.77 -.12 .8841 .5206 69.82
51 1466 1 .000 263.150 12.299 542.35 543.00 -.12 1 .0164 .6456 57.42
51 1467 1 .000 263.150 12.310 542.82 543.47 -.12 1 .2898 .91 27 41 .32
51 1468 1 .000 268.150 12.139 535.30 535.75 -.08 .6689 .4297 55.66
51 1469 1 .000 268.150 12.144 535.52 536.00 -.09 .8035 .5495 46.24
51 1470 1 .000 268.150 12.150 535.78 536.21 -.08 .9160 .6337 33.99
51 1471 1 .000 268.150 12.156 536.05 536.41 -.07 1 .0203 .8290 23.08
51 1472 1 .000 268.150 I 2 . 1 62 536.31 536.64 -.06 1 .1464 .9681 18.41
51 1473 1 .000 268.150 12.173 536.78 537.13 -.07 1 .4105 1.2206 15.55
51 1474 1 .000 273.150 I .989
I 528.69 528.79 -.02 .6027 .5528 9.03
51 1475 1 .000 273.150 12.000 529.18 529.27 -.02 .8360 .7925 5.49
51 1476 1 .000 273.150 12.012 529.70 529.72 -.00 1 .0585 1.0475 1 .05
51 1477 1 .000 273.150 12.01 529.91 530.01 -.02 1 .201 1.1554 4.00
51 1478 1.000 273.150 12.017 529.93 529.99 -.01 1 .1917 1.1649 2.30
51 1479 1 .000 273.150 12.023 530.16 530.26 -.02 1 .3303 1.2797 3.95
51 1480 1 .000 273.150 12.028 530.42 530.49 -.01 1 .4442 1.4080 2.57
51 1481 1 .000 273.150 12.034 530.65 530.77 -.02 1 .5876 1.5240 4.17
51 1482 1 .000 273.150 12.039 530.87 531 .00 -.02 1 .7040 1.6374 4.07
51 1483 1 .000 273.150 12.049 531 .32 531 .55 -.04 1 .9843 1.8690 6.17
51 1484 1 .000 273.150 12.050 531 .37 531 .50 -.02 1 .9581 1.8920 3.49
51 1485 1 .000 273.150 12.097 533.45 533.83 -.07 3.1820 2.9791 6.81
51 1486 1 .000 273.150 12.1 96 537.81 538.32 -.09 5.6784 5.3852 5.44
51 1487 1 .000 273.150 12.299 542.35 542.94 -.11 8.4537 8.0844 4.57
51 1488 1 .000 278.1 50 1 1 .831 521 .73 521 .77 -.01 .6083 .5897 3.16
51 1489 1 .000 278.150 1 1 .838 522.02 522.01 .00 .7163 .7210 -.66
51 1490 1 .000 278.150 1 1 .843 522.26 522.25 ,00 .8239 .8306 -.81
51 1491 1 .000 278.150 1 1 .849 522.52 522.50 .00 .9378 .9494 -1 .22
51 1492 1 .000 278.150 1 1 .855 522.76 522.76 .00 1 .0579 1.0602 -.22
51 1493 1 .000 278.150 1 1 .860 523.01 523.02 -.00 1 .1764 1 .171 .40
51 1494 1 .000 278.1 50 11 .865 523.22 523.29 -.01 1 .3027 1 .2722 2.40
51 1495 1 .000 283.150 1 1 .675 514.82 51 4.75 .01 .7093 .7402 -4.18
51 1496 1 .000 283.150 1 1 .681 515.08 514.99 .02 .8100 .8483 -4.52
51 1497 1 .000 283.150 1 1 .687 51 5.35 51 5.24 .02 .9146 .9596 -4.69
51 1498 1 .000 283.150 1 1 .692 515.59 515.48 .02 1 .0168 1 .0639 -4.42
51 1499 1 .000 283.150 1 1 .698 -51 5.86 515.75 .02 1 .1283 1 .1764 -4.09
51 1500 1 .000 288.150 1 1 .51 507.59 507.46 .03 .7919 .8432 -6.08
51 1501 1 .000 288.150 1 1 .51 507.86 507.72 .03 .8901 .9464 -5.95
51 1502 1 .000 288.150 1 1 .517 507.87 507.70 .03 .8835 .9486 -6.87
51 1503 1 .000 288.150 11 .523 508.13 507.96 .03 .9827 1 .0480 -6.23
51 1504 1 .000 288.150 1 1 .529 508.38 508.22 .03 1 .0851 1 .1457 -5.29
51 1505 1 .000 288.150 1 1 .529 508.38 508.23 .03 1 .0873 1 .1479 -5.28
51 1 506 1.000 288.150 1 1 .534 508.63 508.48 .03 1 .1866 1 .2439 -4.61
51 1507 1 .000 293.150 1 1 .343 500.20 500.04 .03 .9185 .9747 -5.77
51 1508 1 .000 293.1 50 1 1 .348 500.42 500.35 .01 1 .0261 1 .0504 -2.32
51 1509 1 .000 293.150 11 .354 500.68 500.62 .01 1 .1206 1 .1446 -2.10
51 1510 1 .000 293.1 50 1 1 .360 500.95 500.92 .01 1 .2290 1 .2394 -.84
51 1 51 1 .000 293.150 1 1 .366 501 .19 501 .19 .00 1 .3234 1 .3246 -.09
51 1512 1 .000 298.1 50 1 1 .169 492.54 492.27 .06 1 .0177 1 .1047 -7.88
51 1513 1 .000 298.150 1 1 . 701 492.55 492.20 .07 .9958 1 .1082 -10.15
51 1514 1 .000 298.150 11 . 1 75 492.81 492.52 .06 1 .0975 1 .1892 -7.71
51 1515 1 .000 298.150 1 1 . 1 76 492.83 492.45 .08 1 .0742 1 .1980 -1 0.33
99
5 7
11 0 4 1 3/ , 5
Data sources and ID numbers: (l)Viriat Equation, (2)Dawson, (3)Beattie, (4)Deschner, (5)Rea(ner,
(13)Cherney, 7)Tomi inson, (24)Ely, (26 )0 ttrnar , (XXXX )Haynes, (51 ,52 )Thomas,
( 1 i 78 fe ichmann ( )
(79)Warowny.
ID Data We ght
i Temp. Dens ty i Dens ty i Dens tyi
expt ca c I
Pressure
No. K mol/L kg/iir kg/ nr MPa MPa
51 1516 1 .000 298.150 11 .177 492-.85 492.44 .08 1 .0729 1 .2050 -1 0.97
51 1517 1 .000 298.150 1 1 .181 493.05 492.85 .04 1 .2035 1 ,2670 -5 .01
51 1513 1 .000 298.150 I 1 . 821 493.08 492.79 .06 1 . 1 851 1 .2777 -7.24
51 1519 1 .000 298.1 50 1 1 . 1 88 493.35 493 . 1 .05 1 .282 3 1 .3632 -5.93
51 1520 1 .000 298.150 I I . 1 94 493.64 493.30 .07 1 .3494 1 .4601 -7.58
51 1521 1 .000 298.150 1 1 . 94
1 493.64 493.32 .07 1 .3546 1 .4601 -7.23
51 1522 1 .000 298.150 1 1 .249 496.03 495.77 .05 2. 1679 2.2565 -3.92
51 1523 1 .000 298.150 11 ,302 498.39 498.14 .05 2.9922 3.0789 -2,81
51 1524 1 .000 298.1 50 1 1 .423 503.71 503.50 .04 4.9970 5.0808 -1 ,65
51 1525 1 .000 298.150 1 1 . 500 507.12 507.01 .02 6.41 83 6. 4669 -.75
51 1526 1 .000 298.150 11 .523 508.14 508.00 .03 8399
6. 6 .8973 -.83
51 1527 1 .000 298.150 1 1 .592 51 1 .19 51 1 .15 .01 8.2207 8.2388 -.22
51 1528 ,000 298.150 11.679 515.00 515.00 -.00 1A A AT
10.010/ 1
0.0092
1 1 • 01
51 1529 1 .000 303.150 10.984 434.35 484.11 .OD A
1.1011
1 1 1 1 1 C ~7A
.16/0 ^
-5 ^65
1
51 1530 1.000 303.150 10.989 484.59 484.40 r\A

.U4 1 1 O 1 1
1 »15 It
"i'X.
15 -4^38
51 1531 1 .000 303.150 10.995 484.35 434,68 .U4 1 T1 OT -3. /y
51 1532 1 .000 303.150 1 1 .001 485.1 484,97 1 .J>40D 1 . JO / 1
o • oo
-z yz
51 1533 1 .000 303.150 1 .007
1 485.38 485.24 • Uj 1
1 .
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51 1534 1 .000 303.150 1 .008

1 485.42 485.12 »Ub 1 Al "7c: c oo
-5 •o /
51 1535 1 .000 303 . 50
1 1 .020
1 485.96 485.66 .UD 1 . 54oo 1 .DJO -5.3/
O QC:^Q -1 . 1A
_
51 1536 1 .000 303 . 50
1 11.110 489.91 489.82 Z . ODDO u1 1
51 1537 1 .000 303.150 1 .252

1 496 . 1 496.03 .U-> 4. y JD4 -I AA
— 1 .uu
51 1538 1 .000 303.1 50 11 .353 500.65 500.58 • Ul D •d4DD A A"^
O .D /4j -.41
51 1539 1 .000 303.150 1 1 .441 504.50 504.51 — , nn
uu O • Z4UO O . Z JOO «U J
51 1540 1 .000 303.150 1 .527
1 508.31 508.41 y QQQn
Q .ooyu • 4!3
52 1541 1 .000 303.150 10.983 484.33 484.24 1 • 1 J /D 1
1 .
1 iCO
oZ4 y1 O
-Z 1 T
1 J .
1542 303.150 10.939 484.60 434.55 Al 1 O O CO 1 O/A

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-11 .ZZ
52 1 .000 .01 1
y1
A "Z AO OA oo
52 1543 1 .000 303.150 10.996 484.87 484.34 1 1
1 .3Uol 1 1
1 . 3 by
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52 1544 1 .000 303.1 50 1 1 .007 485.40 485.36 •
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yl
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1 -•D /
52 1545 1 .000 303.150 1 1 .01 485.73 485.65 AO
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.45
52 1546 1 .000 303.150 1 1 .137 491 .10 491 .07 •
A
01
1
3.231 3 ,2407 -.29
52 1547 1 .000 303.150 1 1 . 801 492.99 492.94 .01 3.8543 3,8736 -. 50
52 I548 1 .000 303.1 50 1 1 .260 496.52 496.54 -.00 5 . 1 231 5. 1 157 . 1
52 1549 1 .000 303.150 1 1 .302 498.38 498.45 -.01 5.8301 5,8027 .47
52 1550 1 .000 303.150 1 1 .362 501 .05 501 .03 .00 6.8244 6.8309 -.10
52 1551 1 .000 303.150 1 1 .537 508.77 508.96 -.04 1 0. 807 1 1 0.0949 • 85
51 1552 1 .000 313.150 10.596 467,27 467.38 -.02 1 .4533 1 .4281 1 ^77
51 1553 1 .000 313.150 10.602 467.54 467.65 -.02 1 .5149 1 .4892 1 ^72
51 1554 1 .000 313.150 10.609 467,81 467.92 -.02 1 .5776 1 .5520 1 ^65
51 1555 1 .000 313.150 10.61 5 468.08 468.17 -.02 1 .6349 1 .61 52 1 .22
51 1556 1 .000 313.150 10.621 468.38 468.45 -.02 1 .7015 1 .6835 1 .07
51 1557 1 .000 313.150 10.628 468.69 463.60 .02 1 .7347 1 .7559 -1 .20
51 1558 1 .000 313.150 10.634 468.91 468.94 -.01 1 .3153 1 .8099 .32
51 1559 1 .000 323. 150 .800 35.28 35.39 -.33 1 .61 27 1 .6091 .22
51 1560 1 .000 323.150 .820 36.16 36.30 -.37 1 .6402 1 .6361 .25
51 1561 1 .000 323.150 .840 37.04 37.19 -.40 1 .6668 1 .6625 .26
51 1562 1 .000 323.1 50 .850 37.48 37.64 -.41 1 .6799 1 .6754 .27
51 1563 1 .000 323.150 .860 37.92 38.08 -.42 1 .6928 1 .6882 .27
51 1564 1 .000 323.150 .870 38.36 38.53 -.43 1 .7056 1 .7009 .28
51 1565 1 .000 323.150 .875 38.59 38.75 -•42 1 .71 13 1 .7071 .27
51 1566 1 .000 323,150 .876 38.61 38.76 -.40 1 .7122 1 .7078 .26
51 1567 1 .000 323.150 10.1 79 448.85 448.65 .04 1 .7664 1 .8014 -1 ^94
51 1568 1 .000 323.1 50 10.179 448.85 443,73 .03 1 .7307 1 .8014 -1.15
51 1569 1 .000 323.150 10.179 448.86 443,60 .06 1 .7575 1 .3038 -2.57
51 1570 1 .000 323.150 10.185 449.1 449,01 .02 1 .8238 1 .8473 -1 .00
51 1571 1 .000 323.150 10.185 449.13 448.87 .06 1 .3046 1 .851 -2.52
100
1 7 1 0.
9 7
Data sources and ID numbers: (l)Virlal Equation, (2)Dawson, (3)Beattie, (4)Deschner, (5)Reamer,
(13)Cherney, (1 7)Toml Inson, (24)Ely, (26)Dittmar, (XXXX )Haynes, ( 51 , 52 )Thomas, (78)TeIchmann,
(79)Warowny.
ID Data Weight Temp. Den si ty Dens ty

i Dens tyi
"expt cal c Pressure
No. K mol/L kg/nr kg/m MPa MPa t
n
51 1572 1 .000 323.150 10.186 449.1 448.82 .08 1 .7970 1 .8586 -3.32
51 1573 1 .000 323.150 10.191 449.39 449.16 .05 1 .8570 1 .8976 -2.14
51 1574 1 .000 323.150 10.191 449.40 449.15 .06 1 .8544 1 .8992 -2.36
51 1575 1 .000 323.150 10.197 449.65 449.48 .04 1 .91 33 1 .9434 -1 .55
51 1576 1 .000 323.150 10.197 449.66 449.45 .05 1 .9083 1 . 9458 -1 .93
51 1577 1 .000 323.150 10.203 449.91 449.78 .03 1 .9660 1 .9895 -1.18
51 1578 1 .000 323.150 10.203 449.93 449.70 .05 1 .9525 1 .9944 -2.11
51 1579 1 .000 323.150 10.209 450.17 450.06 .03 2.01 71 2.0376 -1 .00
51 1580 1 .000 323.1 50 10.209 450.21 449.94 .06 1 .9952 2 .0434 -2.36
51 1581 1 .000 323. 150 10.210 450.22 449.89 .07 1.9867 2.0459 -2.89
51 1582 1 .000 323.150 10.250 452.00 451 .73 .06 2. 3253 2 .3746 -2 .08
51 1583 1 .000 323.150 10.500 463.02 462.85 .04 4.6856 4.7256 -.85
51 1584 1 .000 323.150 10.750 474.04 473.96 .02 7.6467 7 .6697 -.30
52 1585 1 .000 323.150 .800 35.28 35.40 -.35 1 .61 29 1 .6091 .24
52 1585 1 .000 323.150 .800 35.28 35.40 1 fiOQI .73
52 1587 1 .000 323.150 .820 36.16 36.29 -.37 1 .6402
52 1588 1 .000 323.150 .840 37.04 37.19 1 fi69S
52 1589 1 .000 323.150 .850 37.48 37.63 -.40 1 .6799 .96
52 1590 1 .000 323.150 .860 37.92 38.08 1 fiRR9 97
52 1591 1 .000 323.150 .870 38.36 38.53 -.43 1 ,7056 1 .7009 .98
52 1592 1 .000 323.1 50 10.182 448.99 448.55 1 1 .7489 1 R9'iS -4 94
52 1593 1 .000 323.150 1 0 . 1 88 449.26 448.87 . ^" 11 . RDS'i
OvJ ^ J 1 R740 -"^ fill
52 1594 1 .000 323.150 10.194 449.53 449.18 . OR

uo 1 Q991 -^ 9'i
52 1595 1 .000 323.150 10.200 449.79 449.46 n? 1 Q1 nn 1 QftRQ -9 QQ
52 1596 1 .000 323.150 10.206 450.07 449.74 01
• \j 1 1 .QSR7 9 01 RS -9 Qft
52 1597 1 .000 323.150 10.498 462.92 462.82 • n?

u^ A
H . ft7RR
D OO /
52 1598 1 .000 323.150 1 1.034 486.58 485.57 91 1 1 /IfiQI 1 1 R494

52 1599 1 .000 323.150 11 .504 507.29 507.86 - 1 1 91 9RfiS i-\J * QRRR
90 -70CJ0 49
1 .HZ
1
52 1600 1 .000 323.150 1 .998

1 529.09 530.13 - .20 35.0469 34.2992 2.18
51 1601 1 .000 333.150 .800 35.28 35.34 -. 1 1 .7004 1 -fiQRI .1
51 1602 1.000 333.1 50 .900 39.69 39.77 . zz 11 R44Q

. OH- Hi' 1 R499 . 4 1
51 1603 1 .000 333.150 1 .000 44.10 44.22 -.28 1 .9755 1 .9720 .18
51 1604 1 .000 333.150 1 .050 46.30 46.48 -.33 2.0358 2.031 .20
51 1605 1 .000 333.150 1 .060 46.74 46.91 -.35 2.0475 2.0432 .21
51 1606 1 .000 333.150 1 .075 47.40 47.58 -.36 2.0646 2.0602 .21
51 1607 1 .000 333.150 1 .100 48.51 48.70 -.39 2.0925 2.0878 .22
51 1608 1 .000 333.150 1 .120 49.39 49.59 -.41 2.1 42 1 2.1093 .23
51 1609 1 .000 333.150 1 .122 49.48 49.66 -.37 2. 1 58 1 2.1114 .21
51 1610 1 .000 333.150 9.699 427.69 427.51 .04 2.1 278 2.1 508 -1 .07
51 161 1 .000 333.150 9.704 427.92 427.76 .04 2.1 595 2.1 807 -.97
51 1612 1 .000 333.1 50 9.710 428.19 428.04 .03 2.1 955 2.21 46 -.86
51 1613 1 .000 333.150 9.716 428.44 428.30 .03 2.2288 2.2471 -.81
51 1614 1 .000 333.150 9.722 428.71 428.53 .04 2.2577 2.2810 -1 .02
51 1615 1 .000 333.150 9.728 428.97 428.82 .03 2.2961 2.31 51 -.82
51 1616 1 .000 333.150 9.734 429.23 429.08 .03 2.3301 2.3495 -.82
51 1617 1 .000 333.150 9.740 429.50 429.33 .04 2.3625 2.3841 -.91
51 1618 1 .000 333.150 9.746 429.76 429.59 .04 2.3966 2.4185 -.91
51 1619 1 .000 343.150 .800 35.28 35.31 -.09 1.7859 1.7847 .07
51 1620 1 .000 343.150 1 .000 44.10 44.13 -.07 2.0890 2.0881 .04
51 1621 1 .000 343.150 1 .200 52.92 52.98 -.11 2.3408 2.3393 .06
51 1622 1 .000 343.1 50 1 .300 57.33 57.43 -.18 2.4484 2.4461 .09
51 1623 1 .000 343.150 1 .350 59.53 59.66 -.22 2.4977 2.4949 .11
51 1624 1 .000 343.150 1 .400 61 .74 61 .91 -.28 2.5442 2.5407 .14
51 1625 1 .000 343.150 1 .425 62.84 63.04 -.32 2.5663 2.5625 .15
51 1626 0.000 343.1 50 1 .448 63.85 403.1 84.16 2.5856 2.5818 .14
51 1627 1 .000 343.150 9.149 403.44 403.35 .02 2.6054 2.6132 -.30
101
1 .
(13)Cherney, (1 7)Toml Inson, (24)Ely, (26)Dittmar, (XXXX )Haynes, (51 ,52 )Thomas, (78)Teichmann,
(79)Warowny.
ID Data Weight Temp. Density Densi ty Dens ty

i
expt cal c Pressure
Point expt calc DIff. Dif f
No. K mol/L kg/nr kg/m^ MPa MPa
51 1623 1.000 343.150 9.155 403.69 403.58 .03 2.6247 2.6341 -.36
51 1629 1.000 343.150 9.160 403.94 403.82 .03 2.6445 2.6546 -.38
51 1630 1.000 343.1 50 9.165 404.17 404,06 .03 2.6651 2.6746 -.36
51 1631 1.000 343.150 9.171 404.42 404.32 .02 2.6868 2.6954 -.32
51 1632 1.000 343.150 9.1 77 404.67 404.56 .03 2.7077 2.7170 -.34
51 1633 1.000 343.150 9.182 404.92 404.81 .03 2.7290 2.7385 -.35
51 1634 1.000 343.150 9.188 405.15 405.03 .03 2.7479 2.7589 -.40
51 1635 1.000 343.150 9.193 405.40 405.26 .04 2.7680 2.7807 -.46
52 1636 1.000 343.150 1.300 57.33 57.42 -.17 2.4483 2.4461 .09
52 1637 1.000 343.150 1.350 59.53 59.66 -.21 2.4976 2.4949 .11
52 1638 1.000 343.150 1.400 61 .74 61 .90 -.26 2.5440 2.5407 .13
52 1639 1.000 343.150 1.425 62.84 63.05 -.33 2.5665 2.5625 .16
52 1640 0.000 343.150 1.448 63.85 403.11 -84.16 2.5856 2.5818 .15
52 1641 1 .000 343.150 9.147 403.34 403.13 .05 2.5880 2.6049 -.65
52 1642 1 .000 343.150 9.152 403.60 403.41 .05 2,6108 2.6261 -.58
52 1643 1 ,000 343.150 9.158 403,84 403.64 .05 2.6294 2.6462 -.63
52 1644 1 .000 343.150 9.164 404.09 403.89 .05 2.6504 2.6677 -.65
52 1645 1 .000 343.150 9.169 404.33 404.16 .04 2.6732 2.6882 -.56
52 1646 1 .000 343.150 9.1 75 404.59 404.37 .05 2.6914 2.7100 -.69
51 1647 1 .000 348.150 .800 35.28 35.30 -.06 1 .8282 1.8273 .05
51 1648 1 .000 343.150 1 .000 44.10 44.09 .01 2.1447 2.1448 -.01
51 1649 1 .000 348.150 1 .400 61 .74 61 .76 -.03 2.6310 2.6305 .02
51 1650 1 .000 348.150 1 .500 66.15 66.21 -.10 2.7241 2.7227 .05
51 1651 1 .000 348.150 1 .550 68.35 68.45 -.15 2.7666 2.7647 .07
51 1652 1 .000 348.150 1 .600 70.56 70.71 -.21 2.8065 2.8039 .09
51 1653 1 .000 348.150 1 .625 .66
71 71 .84 -.25 2.8255 2.8225 .11
51 1654 1 .000 348.150 1 .650 72.76 72.97 -.28 2.8438 2.8405 .12
51 1655 1 .000 348.150 8.829 389.33 389.23 .03 2.8604 2.8668 -.23
51 1656 1 .000 348.150 8.834 389.57 389,46 .03 2.8745 2.8815 -.24
51 1657 1 .000 348.150 8.840 389.81 389.71 .02 2.8907 2.8969 -.21
51 1658 1 .000 343.150 8.844 390.01 389.93 .02 2.9048 2.9100 -.18
51 1659 1 .000 348.150 8.850 390.25 390.16 .02 2.9200 2.9257 -.20
51 1660 1 .000 348.150 8.855 390.47 390.39 .02 2.9348 2.9402 -.18
51 1661 1 .000 348.150 8.860 390.71 390.61 .02 2.9496 2.9557 -.21
51 1662 1 .000 348.150 8.865 390.94 390.84 .03 2.9642 2.9713 -.24
51 1663 1 .000 348.150 9.000 396.88 396.55 .08 3.3770 3.4025 -.75
51 1664 1 .000 348.150 9.500 41 8.92 418.51 .10 5.6828 5.7387 -.98
52 1665 1 .000 348.150 .800 35.28 35.30 -.06 1 .8281 1.8273 .04
52 1666 1 .000 348.150 9.001 396.94 396.48 .12 3.3717 3.4076 -1 .05
52 1667 1 .000 348.150 9.501 41 8.96 413.53 .10 5.6861 5.7436 -1 .00
52 1663 1 .000 348.150 9.999 440.91 440.79 .03 9.5096 9.5358 -.28
52 1669 1 .000 348.150 10.499 462.97 463.09 -.03 15.3466 15.3066 .26
52 1670 1 .000 348.150 1 .000
1 485.05 485.48 -.09 23.8349 23.6406 .82
52 1671 1 .000 348.150 1 1 .500 507.1 507.89 -.15 35.6945 35.2172 1 .36
51 1672 1 .000 353.150 .800 35.28 35.29 -.04 1 .8701 1.8696 .03
51 1673 1 .000 353.150 1 .000 44.10 44.07 .06 2.2000 2.2009 -.04
51 1674 1 .000 353.150 1 .500 66.15 66.07 .12 2.8177 2.3194 -.06
51 1675 1 .000 353.150 1 .700 74.97 74.97 -.00 2.9904 2.9903 .00
51 1676 1 .000 353.150 1 .800 79.37 79.45 -.10 3.0621 3.0609 .04
51 1677 1 .000 353.150 1 .850 81 .58 81 .72 -.17 3.0945 3.0926 .06
51 1678 1 .000 353.150 1 .900 83.78 83.99 -.25 3.1246 3.1219 .09
51 1679 1 .000 353.150 8.462 373.14- 373.14 0.00 3.1365 3.1365 .00
51 1680 1 .000 353.150 8.467 373.35 373.35 .00 3.1462 3.1463 -.01
51 1681 1 .000 353.150 8.472 373.58 373.57 .00 3.1561 3.1564 -.01
51 1682 1 .000 353.150 8.477 373.79 373.80 -.00 3.1667 3.1665 .01
51 1683 1 .000 353.150 8.481 374.01 374.00 .00 3.1760 3.1763 -.01
102
1 . . 7
1 1 ,
Data sources and ID numbers: (l)VIrlai Equation, (2)Dawson, (3)8eattie, (4)Deschner, (5)Reamer,
(13)Cherney, ( 7)Tom 11 nson, (24)Ely, (26 )0 ttrnar , (XXXX)Haynes, (51 , 52 )Thomas, ( 78)re ichmann
1 i
(79)V/arowny
ID Data We ght i Temp. Dens ty i Density Dens ty

I Pressure
'"êxpt cal c
Point expt ca Ic Diff Diff.
No. K mol/L kg/m kg/m^ MPa MPa
51 1684 1 .000 353.150 8.486 374.23 374.22 .00 3.1865 3.1865 -.00
51 1685 1 .000 353.150 8.491 374.44 374.44 .00 3.1964 3.1967 -.01
51 1686 1 .000 353.150 8.496 374.66 374.63 .01 3.2056 3.2072 -.05
51 1687 1 .000 358.150 .800 35.28 35.28 -.02 1 .91 1 1 .91 15 .01
51 1688 1 .000 353.150 1 .000 44.10 44.05 .10 2.2547 2.2563 -.07
51 1689 1 .000 358.150 1 .500 66.15 65.98 .25 2.9101 2.91 41 -.14
51 1690 1 .000 358.150 1 .900 83.78 83.68 .13 3.2525 3.2541 -.05
51 1691 1 .000 358.150 2.000 88.19 88.16 .04 3.3162 3.3166 -.01
51 1692 1 .000 358.1 50 2.100 92.60 92.68 -.08 3.3717 3.3708 .03
51 1693 1 .000 358.150 2.200 97.01 97.26 -.25 3.4196 3.41 72 .07
51 1694 1 .000 358.1 50 2.225 98,12 98-42 -.31 3.4304 3.4277 .08
51 1695 1 .000 358.150 8.025 353.88 354.13 -.07 3.4408 3.4336 .21
51 1696 1 .000 358.150 8.030 354.08 354.31 -.06 3.4461 3.4394 .19
51 1697 1 .000 358.150 8.034 354.28 354.52 -.07 3.4521 3.4452 .20
51 1698 1 .000 358.150 8.039 354.48 354.70 -.06 3.4574 3.4509 .19
51 1699 1 .000 358.150 8.043 354.68 354.88 -.05 3.4627 3.4569 .17
51 1700 1 .000 358.150 8.048 354.88 355.06 -.05 3.4682 3.4628 .16
51 1701 1 .000 358.150 8.052 355.08 355.25 -.05 3.4738 3.4688 .15
51 1 702 1 .000 363.1 50 .800 35.28 35.28 -.01 1.9532 1.9531 .00
51 1703 1 .000 363.150 1 .000 44.10 43.97 .29 2.3062 2.31 1 -.21
51 1704 1 .000 363.150 1 .500 66.15 65.91 .36 3.0010 3.0071 -.20
51 1705 1 .000 363.150 2.000 88.19 87.93 .30 3.4504 3.4545 -.12
51 1706 1 .000 363.1 50 2.500 no. 24 110.44 -.18 3.7063 3.7048 .04
51 1707 1 .000 363.150 2.550 1 2.45
1 112.74 -.26 3.7231 3.7210 .05
51 1708 1 .000 363.1 50 2.600 114.65 115.06 -.35 3.7385 3.7359 .07
51 1709 1 .000 363.150 2.630 115.98 116.46 -.41 3.7470 3.7441 .08
51 1710 1 .000 363.1 50 2.650 116.86 1 7.39
1 -.45 3.7524 3.7493 .08
51 171 1 .000 363 . 50
1 7.467 329.29 329.89 -.18 3.7735 3.7645 .24
51 1712 1 .000 363.150 7.476 329.66 330.23 -.17 3.7787 3.7700 .23
51 1713 1 .000 363.150 7.483 330.00 330.85 -.26 3.7882 3.7751 .35
51 1714 1 .000 363.150 7.500 330.71 331 .19 -.14 3.7935 3.7860 .20
51 1715 1 .000 363.150 7.507 331 .05 331 .50 -.13 3.7985 3.7914 .19
52 1716 1.000 363.150 2.000 88.19 87.92 .31 3.4504 3.4545 -.12
52 1717 1 .000 363.150 2.500 110.24 1 10.45 -.19 3.7064 3.7048 .04
52 1718 1 .000 363.150 2.550 112.45 112.76 -.27 3.7232 3.7210 .06
52 1719 1 .000 363.150 2.600 114.65 1 15.08 -.37 3.7386 3.7359 .07
52 1720 1 .000 363.1 50 2.630 115.98 1 16.49 -.44 3.7472 3.7441 .08
52 1721 1 .000 363.150 2.650 116.86 117.45 -.50 3.7527 3.7493 .09
52 1722 1 .000 363.1 50 7.462 329.05 329.50 -.14 3.7676 3.761 .17
52 1723 1 .000 363.1 50 7.466 329.25 329.70 -.14 3.7707 3.7640 .18
52 1724 1 .000 363.150 7.470 329.42 329.83 -.13 3.7726 3.7664 .16
51 1725 1 .000 365.150 .800 35.28 35.28 -.00 1.9697 1.9697 .00
51 1726 1 .000 365.150 1.000 44.10 44.04 .14 2.3306 2.3330 -.10
51 1727 1 .000 365.150 1 .500 66.15 65.58 .87 3.0289 3.0439 -.49
51 1728 1 .000 365.150 2.000 88.19 87.87 .37 3.5035 3.5088 -.15
51 1729 1 .000 365.150 2.000 88.19 87.85 .39 3.5032 3.5088 -.16
51 1730 1 .000 365.150 2.500 110.24 1 10.1 7 .07 3.7780 3.7787 -.02
51 1731 1 .000 365.150 2.500 110.24 110.10 .13 3.7774 3.7787 -.03
51 1732 1 .000 365.150 2.700 119.06 119.32 -.21 3.8456 3.8440 .04
51 1733 1 .000 365.150 2.700 119.06 119.22 -.13 3.8450 3.8440 .03
51 1734 1.000 365.150 2.750 121.27 121 .63 -.30 3.8593 3.8572 .05
51 1735 1 .000 365.150 2.750 121 .27 1 21 .52 -.21 3.8587 3.8572 .04
51 1736 1 .000 365.150 2.800 123.47 123.95 -.39 3.8717 3.8693 .06
51 1737 1 .000 365.150 2.800 123.47 123.82 -.28 3.871 3.8693 .05
51 1738 1.000 365.150 2.850 125.68 126.31 -.50 3.8831 3.8801 .08
51 1739 1 .000 365.150 2.850 125.68 126.16 -.38 3.8824 3.8801 .06
103
. 1 . 1 5 ,
Data sources and ID numbers: (1)Virial Equation, (2)Dawson, {3)8eattie, (4)Deschner, (5)Reaffler,
(13)Cherney, (1 7) TomI nson, (24)Ely, (26 )0 ttinar ,
i i (XXXX )Haynes, (51 ,52)Thomas, ( 78 ) Te ichmann
(79 )Warowny
ID Data Weight Temp. Dens tyi Dens ty i Dens i ty '

expt ^cal c Pressure
No. K mol/L kg/m-' kg/m-^ MPa MPa
51 1740 1 .000 365.150 2.900 127.83 128.63 -.58 3.8930 3,8899 .08
51 1 741 1 .000 365 . 1 50 2.900 127.88 128.49 -.47 3.8925 3,8899 .06
51 1 742 1 .000 365.150 7.163 315.86 316.61 -.24 3.9065 3.8993 .18
51 1743 1 .000 365.150 7.167 316.03 316.82 -.25 3.9085 3.9009 .20
51 1744 1 .000 365.150 7.1 70 316.18 316.88 -.22 3.9091 3.9023 .17
51 1745 1 .000 365.150 7.170 316.18 316.87 -.22 3.9090 3.9023 ,17
51 1 746 1 .000 365.150 7,184 316.80 317.42 -.20 3.9146 3.9083 .16
51 1747 1 .000 365.150 7.184 316.80 31 7.40 -.19 3.9143 3.9083 .15
51 1 748 1 .000 365.150 7.192 317.15 31 7.76 -.19 3.9180 3.9118 .16
51 1749 1 .000 365 . 1 50 7.192 31 7.16 31 7.77 -.19 3.9182 3.91 19 .16
51 1 750 1 .000 365.150 7.200 317.48 318.01 -.17 3.9206 3.9151 .14
51 1 751 1 .000 365.150 7.200 31 7.48 318.06 -.18 3.921 3.91 51 .15
51 1752 1 .000 365.150 7.207 31 7.80 318.31 -.16 3.9237 3.9184 .14
51 1753 1 .000 365 . 50 1 7.207 31 7.80 318.36 -.17 3.9243 3.9185 .15
51 1754 1 .000 365.1 50 7.214 31 8.13 318.66 -.17 3.9275 3.9218 .14
51 1755 1 .000 367.150 2.500 110,24 110.06 .16 3.8498 3.851 -.04
51 1755 1 .000 367.150 3.000 132.29 132,76 -.36 4.0024 4.0004 .05
51 1757 1 .000 367.150 3.100 136,70 137.39 -.50 4.0201 4.01 77 .06
51 1758 1 .000 367.150 3.200 141 .11 142.08 -.69 4.0343 4.031 7 .07
51 1759 1 .000 367.150 3.250 143.32 144,47 -.80 4.0403 4.0375 .07
51 1760 0.000 367.150 3.270 144.20 298.47 -51 .69 4.0424 4.0396 .07
51 1761 0.000 367.150 3.290 145.08 298,89 -51 ,46 4.0444 4.0416 .07
51 1762 1 .000 367.150 6.769 298.47 299,47 -,33 4.0473 4.0424 .12
51 1763 1 .000 367.150 6.772 298.62 299.59 -.33 4.0480 4.0431 .12
51 1764 1 .000 367.150 6.775 298.76 299.73 -.32 4.0487 4.0438 .12
51 1765 1 .000 367.150 6.798 299.78 300.51 -.24 4.0529 4.0489 .10
51 1766 1 .000 368.150 .800 35.28 35,28 .00 1 .9944 1 .9944 -.00
51 1767 1 .000 368.150 .000
1 44.10 44.03 .15 2.3629 2.3656 -.11
51 1763 1 .000 368.150 .500
1 66.15 65.86 .43 3.0910 3.0987 -.25
51 1769 1 .000 368.150 2.000 88.19 87.77 ,48 3.581 8 3.5392 -.21
51 1770 1 .000 368.150 2.500 110.24 110.00 ,22 3.8852 3.8876 -.06
51 1771 1 .000 368.150 3.000 132.29 132.55 -,20 4.0478 4.0465 .03
51 1772 1 .000 368.1 50 3.200 141 .11 141 .71 -.42 4.0840 4.0820 .05
51 1773 1 .000 368.150 3.300 145,52 146.35 -.57 4.0973 4.0952 .05
51 1774 1 .000 368.150 3.350 147.73 148.68 -.64 4.1029 4.1007 .05
51 1775 1 .000 368.150 3.400 149.93 151 .03 -.73 4.1079 4.1056 .05
51 1776 1 .000 368.150 3.450 152.14 153.36 -.80 4.1 121 4.1099 .05
51 1777 1 .000 368.150 3.500 154.34 155.75 -.91 4.1 158 4.1137 .05
51 1778 1 .000 368.150 6.499 286.57 287.68 -.39 4.1 199 4.1 166 .08
51 1779 1 .000 368.150 6.502 286.70 287.81 -.38 4.1203 4.1170 .08
51 1780 1 .000 368.150 6.505 286.84 287.89 -.37 4,1205 4 . 1 1 74 .08
51 1781 1.000 368.150 6.508 286.97 288.04 -,37 4,1210 4.1177 .08
51 1782 i .000 368.1 50 6.51 287.10 288.15 -.36 4,1213 4.1 181 .08
51 1783 1 .000 369.150 2.500 110.24 109.91 .31 3,9199 3.9234 -.09
51 1784 1 .000 369.150 2.500 110.24 109.95 .27 3,9204 3.9234 -.08
51 1785 1 .000 369.150 3.000 132.29 132.41 -.09 4.0928 4.0922 .02
51 1786 1 .000 369.150 3.500 154.34 155.14 -.51 4.1 713 4.1697 .04
51 1787 1 .000 369.150 3.700 163.16 164.54 -.84 4,1857 4.1841 .04
51 1788 1 .000 369.1 50 3.750 165.36 166.47 -,67 4,1877 4.1866 .03
51 1789 1 .000 369.150 3.800 167.57 168.79 -.72 4,1898 4.1887 ,02
51 1790 1 .000 369.150 3.850 169.77 1 71 .11 -.78 4.1915 4.1 906 ,02
51 1791 0.000 369.150 3.900 171 .98 268.91 -36,05 4.1929 4.1921 ,02
51 1792 0.000 369.150 3.920 172.86 269.38 -35.83 4,1934 4.1926 .02
51 1793 1 .000 369.150 6.1 12 269.54 270,58 -.39 4.1947 4.1935 .03
51 1794 1 .000 369.150 6.115 269.66 270,61 -.35 4,1948 4.1 937 .03
51 1795 1 .000 369.150 6.1 18 269.78 270,75 -.36 4.1949 4.1938 .03
104
Data sources and ID numbers: (l)Viria' Equation, (2)Dawson, (3)BedttIe, <4)Deschner, {5)Reainer,
(13)Cherney, (1 7)Toml inson (24)Ely, ( 26 )D ttmar
, i
,
(XXXX)Haynes, 51 52 )Thomas, ( 78 )Te iciimann
( ,
{79)Warowny.
Data Weight Temp. Densi ty Dens ty i Density 'êxpt '^cal c Pressure

No. K mol/L kg/rrr kg/m-^ MPa
51 1796 1 .000 369.150 6.121 269.90 270.78 -.32 4.1950 4.1939 .02
51 1797 1 .000 369.1 50 6.1 23 270.02 270.89 -.32 4.1951 4.1941 .02
51 1798 1 .000 369.150 6.126 270.14 271 .01 -.32 4.1 953 4.1942 .03
51 1799 1 .000 369.150 6.129 270.26 271 .02 -.28 4.1953 4.1943 .02
51 1800 1 .000 369.150 6.129 270.26 271 .03 -.28 4.1953 4.1 943 .02
51 1801 1 .000 369.1 50 6.134 270.49 271 .25 -.28 4.1956 4.1946 .02
51 1802 1 .000 369.150 6.139 270.73 271 .42 -.25 4.1 958 4.1 949 .02
51 1803 1 .000 369.1 50 6.145 270.97 271 .59 -.23 4.1960 4.1952 .02
51 1804 1 .000 369.150 6.199 273.37 273.51 -.05 4.1988 4.1 985 .01
51 1805 1 .000 369.150 6.251 275.65 275,36 .10 4.201 4.2024 -.01
51 1806 1 .000 369.150 6.500 286.63 285.43 .42 4.2277 4.2320 -.10
51 1807 1 .000 369.650 3.000 132.29 132.39 -.07 4.1155 4.1 149 .01
51 1808 1 .000 369.650 3.250 143.32 143.67 -.24 4.1662 4.1649 .03
51 1809 1 .000 369.650 3.500 154.34 154.97 -.41 4.1988 4.1974 .03
51 1810 1 .000 369.650 3.750 165.36 166.13 -.46 4.2178 4.2168 .02
51 181 1 .000 369.650 3.800 167.57 168.32 -.45 4.2203 4.2195 .02
51 1812 1 .000 369.650 3.850 169.77 170.49 -.42 4.2225 4.2218 .02
51 1813 1 .000 369.650 3.900 171 .98 172.66 -.39 4.2244 4.2238 .01
51 1814 1 .000 369.650 3.950 174.18 174.99 -.46 4.2261 4.2255 .01
51 1815 1 .000 369.650 4.000 176.39 177.26 -.49 4.2275 4.2270 .01
51 1816 1 .000 369.650 5 703
. 251 .49 252.54 -.42 4.2319 4.2316 .01
51 1817 1 .000 369.650 5.733 252.82 253.38 -.22 4.2321 4.2319 .00
51 1818 1 .000 369.650 5,757 253.86 254.02 -.07 4.2323 4.2323 .00
51 1819 1 .000 369.650 5.781 254.90 254.73 .07 4.2326 4.2327 -.00
51 1820 1 .000 369.650 5.781 254.91 254.88 .01 4.2327 4,2327 -.00
51 1821 1 .000 369.650 5.792 255.43 255.1 .13 4.2328 4.2329 -.00
51 1822 1 .000 369.650 5.805 255.96 255.52 .17 4.2329 4.2331 -.00
51 1823 1 .000 369.650 5.829 257.03 256.33 .27 4.2333 4.2336 -.01
51 1824 1 .000 369.750 3.950 174.13 174.86 -.38 4.2324 4.2319 .01
51 1825 1 .000 369.750 4.000 176.39 177.24 -.48 4.2340 4.2335 .01
51 1826 1 .000 369.750 4.050 178.59 179.03 -.24 4.2351 4.2348 .01
51 1827 1 .000 369.750 4.100 180.30 181 .47 -.37 4.2363 4.2359 .01
51 1828 1 .000 369.750 4.150 183.00 183.67 -.36 4.2371 4.2369 .01
51 1829 1 .000 369.750 4.200 185.21 185.37 -.09 4.2377 4.2376 .00
51 1830 1 .000 369.750 4.300 189.62 191 .27 -.86 4.2390 4.2387 .01
51 1831 1 .000 369.750 5.574 245.80 245.14 .27 4.2395 4.2396 -.00
51 1832 1 .000 369.750 5.608 247.23 246.41 .35 4.2397 4.2398 -.00
51 1833 1 .000 369.750 5.623 247.97 246.22 .71 4.2397 4.2400 -.01
51 1834 1 .000 369.750 5.623 247.98 246.22 .72 4.2397 4.2400 -.01
51 1835 1 .000 369.750 5.642 248.78 248.48 .12 4.2401 4.2401 -.00
51 1836 1 .000 369.750 5.669 249.98 249.24 .30 4.2403 4.2404 -.00
51 1837 1 .000 369.750 5.699 251 .31 250.27 .41 4.2405 4.2408 -.01
51 1838 1 .000 369.750 5.758 253.89 251 .92 .78 4.2410 4.2417 -.02
52 1839 1 .000 369.750 4.000 176.39 177.65 -.71 4.2343 4.2335 .02
52 1840 1 .000 369.750 4.300 189.62 191 .61 -1 .04 4.2390 4.2387 .01
52 1841 1 .000 369.750 5.554 244.92 248.98 -1 .63 4.2402 4.2395 .02
52 1842 1.000 369.750 5.565 245.42 248.98 -1 .43 4.2402 4.2396 .01
52 1843 1 .000 369.750 5.577 245.91 249.1 -1 .29 4.2402 4.2396 .01
52 1844 1 .000 369.750 5.588 246.41 249.11 -1 .09 4.2402 4.2397 .01
52 1845 1 .000 369.750 5.633 248.42 250.53 -.84 4.2406 4.2401 .01
52 1846 1 .000 369.750 5.680 250.46 251 .54 -.43 4.2409 4.2406 .01
52 1847 1 .000 369.770 4.000 176.39 177.70 -.74 4.2356 4.2348 .02
52 1848 1 .000 369.770 4.150 183.00 184.61 -.87 4.2388 4.2382 .01
52 1849 1 .000 369.770 4.200 185.21 186.88 -.89 4.2395 4.2390 .01
52 1850 1 .000 369.770 4.250 187.41 189.21 -.95 4.2400 4.2396 .01
52 1851 1 .000 369.770 4.300 189.62 191 .74 -1.11 4.2405 4.2401 .01
105
1 . 0
n / 8
71 7 Z/3 Z H
/
1/
Data sources and ID numbers: (l)Vlrial Equation, (2)Dawson, (3)Beattie, (4)Deschner, (5)Reamer,
(13)Cherney, ( 7 )Torn nson, (24)Ely, (26)Dittinar, (XXXX )Haynes, (51 ,52 )Tho(Ttas, (78)Teichmann,
1 I i
(79)Warowny.
j1 Ud a W(3 I nh + Tenip Dens ty

i L/C no
rio M c T ^v/
y L/ytlc? y
p , p Pressur
) 1 1 1 1
"êxpt
rCJ I
1 M+
n r expt ca c 1
n i -f -f
U 1 TT .
Ntj • K
i\ mo /L1 k y/fTi k m t
A" r\ra i^B a
s? 1 852 1 .000 369. 770 4.350 191 .82 1 94. 08 -1.16 A 94nR A 94n'i n1
\ JJ 4.440 195 . 79 244 .56 -11
Q . Q4
-? ^H 4 941 9 4
H 94nQ
. ni
.U 1
1 nnn "SfiQ 7 7n 5.544 244 .46 947 ^^7 -1I.I/

1 4 9417
H.z H / 1
4 .Z
H 9419
H Z 1
n1
J £- 1 855 1 .000 369. 770 5. 566 245.43 94R 1 1 -1 nR 4 9 41 R 4 941
H. ZH 4 1
ni
•\j 1
1 Q55 1 .000 "^ftQ. 77n 5.611 247.42 94Q 9 1 - fiR 4 9491 4 . 9417
H ZH / 1 . ni
\j 1
1 ftS7 1 nnn ^fiQ 77n 5.655 249.37 9'in 4R . HH 4.Z 9494

HZ ^4- H . 949
4 Z fZ 1
ni
52 1 858 1 .000 359, 770 5 .703 251 .50 251 .77 . 1
1
1
1
4+ . 949R
<1 H Z O 4.Z
H 9497
HZ nn
52 1 859 1 . 000 369.790 4.020 1 77 .29 178.58 _, 73 4.Z
H 9"^^ 7R
/J 4.9
H ^fi 7
ZÛ . n9
^z
52 1 860 1 .000 369. 790 4.221 1 86 . 1 5 187.72 - .R4 A
H . 9411
ZH I 1
4
H.Z 94n7
Hw / ni
52 1 861 1 .000 369. 790 4.272 188.37 -.16
. o 1 4. 241 4 941
H.Z H ^ 1
nn
52 1862 1 .000 369.790 4.322 190.59 1 92.14 -.81 4.2420 4.2417 ni
52 1863 1 .000 369.790 4.372 192 .80 1 94.92 -1 .09 4.2423 4.2421 .01
52 1864 1 .000 369.790 4.423 195.02 1 96.99 -1 .00 4.2425 4 .2423 .00
52 1865 0.000 369. 790 4.486 197.83 242 .23 -1 8. 33 4,2428 4.2426 .00
52 1866 1 .000 369. 790 5.51 9 243.38 246.00 -1 .07 4.2433 4.2429 .01
52 1867 1 .000 369.790 5.563 245.32 247.10 -.72 4.2435 4.2431 .01
52 1868 1 .000 369.790 5.609 247.32 247.93 -.24 4.2436 4 .2435 .00
52 1869 1 .000 369.790 5.654 249.34 249.46 -.05 4.2440 4.2440 .00
52 1870 1 .000 369.790 5.701 251 .40 251 .08 .13 4.2445 4.2446 -.00
52 1871 1 .000 369.810 4.000 1 76.39 1 77.64 -.71 4.2382 4.2374 .02
52 1 872 1 .000 369.81 4.200 1 85.21 1 86.38 -.63 4.2421 4.2417 .01
52 1873 1 .000 369.81 4.300 189.62 191 .02 -.74 4.2432 4.2429 .01
52 1 874 1 .000 369.810 4.350 1 91 .82 193.07 -.64 4.2436 4.2434 .00
52 1875 1 .000 369.81 4.400 1 94 . 03 195.65 -.83 4.2439 4.2437 .00
52 1 876 1 .000 369. 81 4.450 196.23 198.52 -1 .15 4.2441 4.2439 .00
52 1 877 0.000 369.81 4.530 199.76 241 . 1 -17.15 4. 2444 4.2442 .01
52 1 878 1.000 369.810 5.473 241 .35 244.37 -1 .24 4.2448 4.2445 .01
52 1 879 1.000 369.81 5.517 243 .27 244. 78 -.51 4.2449 4.2447 .00
52 1 880 1 .000 369.810 5.561 245.24 246. 1 -.38 4 .2451 4.2449 .00
52 1 88 1 .000 369.81 5.629 248.23 248. 1 .02 4.2455 4.2455 -.00
52 1 882 1 .000 369. 81 5.699 251 .30 250.54 .30 4.2462 4.2464 -.01
52 1 883 1 .000 369.830 4. 000 1 76. 39 1 77.79 -.79 4.2396 4. 2387 .02
52 1 884 1 ,000 369. s'sn 4 . 200 1 85. 21 1 86 .45 -.66 4.2435 4.2431 .01
52 1 385 1 .000 A "snn 1 RQ fO 1 Qi nR - 7fi 4.Z
H 9447
HH / 4,2444 .01
52 1 886 1 .000 369. R^n 4 .400 1 94 .03 1 95 ,57 - . 84 4.9453
H . ZH 4 .2451 .00
Ju too /
1 nnn A 4sn 1I
9"^
Qfi •S.J 1QR 1 n - . Q4
^H H. ZH 4 94S4 nn
J 1 RRf! 1 nnn A snn 1 QH AA 9nn Ri -1 n4 4 94'i7 A
H lA'^fk
ZH-JD
. nn
-/ 11 SRQ
007 n nnn 4,572 201 .61 9"=;^ n7 -1 4 fin 4 94'iQ 4 94'i7
H . ZH ^ nn
1 RQO 1 nnn 5 .351 941 97 -9 Q 1 4
H • 94fi9
ZHDZ 4 94RO ni
1 nnn 47^ 949 RiS - fi'^ 4
H . 94fi4
Z HUH 4
H.9 Z 4fi9
HUZ nn
1 892 1 .nnn 94"^ 9'S 94"^ QI - 97 4
H . ZHO^
94fi'i 4 94fi4
H . ZH UH .nn
11 RQ'^
O ^J 1 nnn • OJ u 5 .561 94^ 9n 94^ •
ZH_/ 77
/ / 4 . ZHDO
H 94fiR 4 . 94fi7
H Z HU /
nn
52 1 894 1 .000 5.606 247.20 947
ZH mjj
"^R — nfi 4
H 9479
ZH /
. H . 9471
4 ZH / 1
nn
52 1 895 1 nnn 5.675 250.24 94Q 4S .
^9
JZ 4 9477
H . ZH /
4
H.Z 947Q
H 7 /
- . ni
\j 1
52 1896 1 .000 369.840 4.000 176.39 177.61 -.69 4.2402 4.2393 .02
52 1897 1 .000 369.840 4.200 185.21 186.71 -.80 4.2443 4.2438 .01
52 1898 1 .000 369.840 4.400 194.03 195.96 -.99 4.2461 4.2458 .01
52 1899 1 .000 369.840 4.450 196.23 197.88 -.83 4.2463 4.2461 .00
52 1900 1 .000 369.840 4.500 198.44 199.86 -.71 4.2464 4.2463 .00
52 1901 1 .000 369.840 4.550 200.64 205.97 -2.59 4.2466 4.2464 .00
52 1902 0.000 369.840 4.600 202.85 234.49 -13.49 4.2467 4.2465 .00
52 1903 1.000 369.840 5.300 233.^0 240.24 -2.72 4.2470 4.2467 .01
52 1904 1 .000 369.840 5.340 235.49 241 .12 -2.34 4.2471 4.2467 .01
52 1905 1 .000 369.840 5.382 237.32 240.70 -1 .40 4.2471 4.2468 .01
52 1906 1 .000 369.840 5.450 240.35 241 .81 -.60 4.2472 4.2470 .00
52 1907 1 .000 369.840 5.499 242.51 243.66 -.47 4.2474 4.2472 .00
106
. . 4 3 .
Data sources and ID numbers: (l)VIrial Equation, (2)Dawson, (3)BeattIe, (4 )Desciiner (5)Reamer,
,
(l3)Cherney, (1 7)Tomi Inson, (24)Ely, (26 )D ttrnar , 1 (XXXX)Haynes, ( 51 , 52 )Thomas, (78)Teichmann,

(79)Warowny
Data Wei gilt Temp. Dens fy

i Dens ty I Dens tyI ''
expt '
cal c Pressure
:=oInt expt calc Diff DIf f
No. mol/L kg/in^ kg/m-' MPa f-Fa
52 1908 1.000 369.840 5.600 246.96 246.74 .09 4.2479 4.2480 -.00
51 1909 1.000 369.850 4.000 176.39 177.04 -.37 4.2404 4.2400 .01
51 1910 1.000 369.850 4.200 185.21 185.29 -.04 4.2445 4.2445 .00
51 1911 1.000 369.850 4.400 194.03 193.06 .50 4.2464 4.2466 -.00
51 1912 1,000 369.850 4.600 202.85 197.69 2.61 4.2470 4.2473 -.01
51 1913 1.000 369.850 4.800 21 1 .67 198.93 6.40 4.2471 4.2475 -.01
51 1914 0.000 369.850 5.000 220.49 199.95 10.27 4.2472 4.2475 -.01
51 191 5 0.000 369.850 5.000 220.49 199.20 10.68 4.2471 4.2475 -.01
51 1916 0.000 369.850 5.200 229.31 199.49 14.94 4.2471 4.2475 -.01
51 191 7 1 .000 369.850 5.400 238.13 228.29 4.31 4.2475 4.2477 -.01
51 1913 1 .000 369.850 5.600 246.94 241 .74 2.15 4.2480 4.2489 -.02
52 1919 1 .000 369.850 4.000 176.39 177.64 -.70 4.2408 4.2400 .02
52 1920 1 .000 369.850 4.200 1 85.21 186.54 -.71 4.2449 4.2445 .01
52 1921 1 .000 369.850 4.400 194.03 195.62 -.82 4.2468 4.2466 .00
52 1922 1 .000 369.850 4.450 196.23 197.92 -.85 4.2470 4.2468 .00
52 1923 1 .000 369.850 4.500 198.44 200.27 -.92 4.2472 4.2470 .00
52 1924 1 .000 369.850 4.550 200.64 201 .99 -.67 4.2473 4.2472 .00
52 1925 1 .000 369.850 4.600 202.85 207.91 -2.43 4.2474 4.2473 .00
52 1926 0.000 369.850 4.750 209.46 233.13 -10.15 4.2475 4.2474 .00
52 1927 1 .000 369.850 4.900 216.08 233.93 -7.63 4.2476 4.2475 .00
52 1923 1 .000 369.850 5.000 220.49 236.22 -6.66 4.2476 4.2475 .00
52 1929 1 .000 369.850 5.100 224.90 236.65 -4.97 4.2477 4.2475 .00
52 1930 1 .000 369.850 5.150 227.10 237.78 -4.49 4.2477 4.2475 .01
52 1931 1 .000 369.850 5.150 227.10 237.05 -4.20 4.2477 4.2475 .00
52 1932 1 .000 369.850 5.300 233.72 239.00 -2.21 4.2478 4.2475 .01
52 1933 1 .000 369.850 5.350 235.92 238.72 -1.17 4.2478 4.2476 .00
52 1934 1 .000 369.850 5.400 238.13 239.27 -.48 4.2478 4.2477 .00
52 1935 1 .000 369.850 5.500 242.53 242.97 -.18 4.2482 4.2481 .00
52 1936 1 .000 369.850 5.600 246.94 246.01 .38 4.2487 4.2489 -.00
52 1937 1 .000 369.860 4.000 176.39 177.46 -.61 4.241 4.2406 .02
52 1933 1 .000 369.860 4.147 182.87 183.83 -.52 4.2447 4.2443 .01
52 1939 1 .000 369.860 4.400 194.03 194.48 -.23 4.2474 4.2473 .00
52 1940 1 .000 369.860 4.600 202.85 202.38 .23 4.2480 4.2481 -.00
52 1941 1 .000 369.860 4.700 207.26 216.54 -4.29 4.2483 4.2482 .00
52 1942 1 .000 369.860 4.800 21 1 .67 206.69 2.41 4.2482 4.2482 -.00
52 1943 1 .000 369.860 4.900 216.08 228.90 -5.60 4.2483 4.2483 .00
52 1944 1 .000 369.860 5.000 220.49 223.53 -1.36 4.2483 4.2483 .00
52 1945 1 .000 369.860 5.100 224.90 232.66 -3.34 4.2484 4.2483 .00
52 1946 1 .000 369.860 5.200 229.31 232.66 -1 .44 4.2484 4.2483 .00
52 1947 1 .000 369.860 5.300 233.72 234.40 -.29 4.2484 4.2484 .00
52 1948 1 .000 369.860 5.400 238.13 238.52 -.16 4.2486 4.2486 .00
52 1949 1 .000 369.860 5.500 242.53 241 .76 .32 4.2489 4.2490 -.00
52 1950 1 .000 369.860 5.600 246.94 245.46 .60 4.2495 4.2498 -.01
52 1951 1 .000 369.870 4.000 176.39 177.46 -.60 4.2420 4.241 .02
52 1952 1 .000 369.870 4.200 185.21 186.08 -.47 4.2462 4.2459 .01
52 1953 1 .000 369.870 4.400 194.03 194.97 -.48 4.2481 4.2480 .00
52 1954 1 .000 369.870 4.600 202.85 203.41 -.28 4.2488 4.2488 .00
52 1955 1 .000 369.870 4.700 207.26 207.20 .03 4.2490 4.2490 -.00
52 1956 1 .000 369.870 4.800 21 1 .67 218.31 -3.04 4.2491 4.2490 .00
52 1957 1 .000 369.870 4.900 216.08 224.98 -3.96 4.2491 4.2491 .00
52 1958 1 .000 369.870 5.000 220.49 230.36 -4.29 4.2492 4.2491 .00
52 1959 1 .000 369.870 5.100 224.90 231 .39 -2.81 4.2492 4.2491 .00
52 1960 1 .000 369.870 5.200 229.31 232.24 -1.27 4.2492 4.2492 .00
52 1961 1 .000 369.870 5.300 233.72 234.72 -.43 4.2493 4.2493 .00
52 1962 1 .000 369.870 5.400 238.13 237.13 .42 4.2494 4.2495 -.00
52 1963 1 .000 369.870 5.500 242.53 241 .52 .42 4.2498 4.2499 -.00
107
. . m . 4
3
1 ,
Table 7. (Cont-inued)
Data sources and ID numbers: (])Virial Equation, (2)Dawson, (3)Beai-He, (4)Deschner, (5)Reamer,
(l5)Cherney, (1 7)Toinl nson, (24)Ely, ( 26 )D ttrnar , (XXXX )Haynes, ( 51 , 52 )Thomas, ( 78 ) Teichinann
I i
(79)Warowny
ID Data We gh i h Temp Dens ty

i Dens ty i Dens ty i p exp h ca c
1
Pressure
No • K mol /L kg/m kg/ % MPa MPa %
52 1964 1 .000 369.870 5.600 246.94 245.43 .62 4.2504 4.2507 -.01
51 1965 1 .000 369.900 4.000 176.39 176.78 -.22 4.2435 4.2432 .01
51 1966 1 .000 369.900 4.200 185.21 135.09 o06 4.2479 4.2479 -.00
51 1967 1 .000 369.900 4.560 201 .08 1 95 . 1 0 3.07 4.2503 4.2510 -.01
51 1968 1 .000 369.900 4.600 202.85 197.04 2.95 4.2506 4.251 -.01
51 1969 1 .000 369.900 4.700 207.26 198.85 4.22 4.2508 4.251 -.01
51 1 970 1 .000 369.900 4.800 21 1 .67 198.34 6.72 4.2507 4.2514 -.02
51 1971 1 .000 369.900 4.900 216.08 1 97.21 9.57 4.2506 4.251 -.02
51 1972 1 .000 369.900 5.000 220.49 201 .63 9.35 4.2510 4.2515 -.01
51 1973 0.000 369.900 5.100 224.90 199.76 12.58 4.2509 4.2516 -.02
51 1974 0.000 369.900 5.200 229.31 202.26 13.37 4.2510 4.2517 -.02
51 1975 1 .000 369.900 5.300 233.72 21 5.53 8.44 4.2514 4.2513 -.01
51 1976 0.000 369.900 5.400 238.13 207.64 14.68 4.2513 4.2521 -.02
51 1977 1 .000 369.900 5.600 246.94 240.84 2.54 4.2524 4.2535 -.03
51 1978 1 .000 369.900 5.800 255.76 251 .63 1 .64 4.2549 4.2569 -.05
51 1979 1 .000 370.150 2.500 110.24 109.39 .32 3.9553 3.9591 -.10
51 1980 1 .000 370.150 3.000 132.29 132.30 -.00 4.1376 4.1376 .00
51 1981 1 .000 370,150 3.500 154.34 154.33 -.31 4.2262 4.2249 .03
51 1982 1 .000 370.150 4.000 176.39 176.66 -.15 4.2596 4.2594 .01
51 1983 1 .000 370.150 4.500 198.44 194.37 1 .83 4.2683 4.2691 -.02
51 1984 1 .000 3 70.1 50 4.750 209.46 201 .37 4.02 4.2696 4.2706 -.02
51 1985 1 .000 370.150 5.000 220.49 205.72 7.18 4.2702 4.2718 -.04
51 1986 1 .000 370.150 5.250 231 .51 212.74 8.82 4.2710 4.2730 -.05
51 1987 1 .000 370.150 5.500 242.53 227.02 6.83 4.2725 4.2750 -.06
5! 1988 1 .000 370.150 6.000 264.58 259.93 1 .79 4.2845 4.2898 -.12
108
1 1 ,
Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)Beattie, (4)Deschner, (5)Reamer
(13)Cherney, ( 7)Tom nson
1 I i (24)Ely, (26)Dittmar, (XXXX)Haynes, ( 51 52)Thomas, ( 78)Te ichmann
,
(79)Warowny.
ID Data Weight Temp. Density Density Density êxpt '^calc Pressure

No. K mol/L kg/m^ kg/m^ % MPa MPa %
17 1989 0.000 322.594 10.259 452.40 451.56 .19 2.0774 2.2342 -7.02
17 1990 0.000 324.817 10.257 452.29 451.41 .19 2.91 10 3.0809 -5.52
17 1991 0.000 327.594 10.254 452.16 451.30 .19 3.9672 4.1402 -4.18
17 1992 0.000 318.706 10.439 460.31 459.51 .17 2.0864 2.2552 -7.49
17 1993 0.000 323.150 10.434 460.09 459.27 .18 3.8638 4.0467 -4.52
17 1994 0.000 327.594 10.429 459.87 459.09 .17 5.6523 5.8351 -3.13
17 1995 0.000 313.706 10.619 468.29 467.57 .15 1.7382 1.9070 -8.85
17 1996 0.000 320.928 10.611 467.90 467.21 .15 4.8022 4.9781 -3.53
17 1997 0.000 327.594 10.603 467.56 466.92 .14 7.631 7.8069 -2.25
17 1998 0.000 309.261 10.816 476.97 476.40 .12 1.9140 2.0652 -7.32
17 1999 0.000 314.817 10.810 476.67 476.06 .13 4.4064 4.5778 -3.74
17 2000 0.000 320.372 10.802 476.36 475.79 . 12 6.9085 7.0777 -2.39
17 2001 0.000 325.928 10.796 476.07 475.49 .12 9.3913 9.5736 -1.90
17 2002 0.000 304.261 10.997 484.95 484.34 .13 .7127
1 1.8918 -9.47
17 2003 0.000 313.150 10.986 484.44 483.85 . 12 5.9412 6.1290 -3.06
17 2004 0.000 322.039 10.975 483.95 483.42 .1 1 10. 1567 10.3414 -1.79
17 2005 0.000 298.150 11.183 493.13 492.60 .11 1. 1238 1.2935 -13.12
17 2006 0.000 305.372 11.173 492.69 492.19 .10 4.7615 4.9342 -3.50
17 2007 0.000 313.706 11.162 492.21 491.74 .10 8.9370 9.1134 -1.94
17 2008 0.000 322.039 11.151 491.73 491.30 .09 13.0890 13.2597 -1.29
17 2009 0.000 293.150 11.364 501.13 500.68 .09 1.1445 1.3031 -12.17
17 2010 0.000 298.150 11.357 500.81 500.39 .08 3.8100 3.9649 -3.90
17 201 0.000 308.150 11.343 500.20 499.86 .07 9.1 162 9.2563 -1.51
17 2012 0.000 316.483 11.332 499.70 499.43 .05 13.5096 13.6266 -.86
17 2013 0.000 298.150 11.532 508.54 508.21 .07 6.9272 7.0698 -2.02
17 2014 0.000 299.817 11.547 509.17 509.61 -.09 8.5157 8.3215 2.33
17 2015 0.000 303.150 11.525 508.23 507.93 .06 9.7195 9.8542 -1.37
17 2016 0.000 308.706 11.517 507.88 507.64 .05 12.8125 12.9268 -.88
17 2017 0.000 282.594 11.724 517.01 516.63 .07 1 . 1625 1.3245 -12.23
17 2018 0.000 284.261 11.722 516.89 516.52 .07 2. 1484 2.3107 -7.02
17 2019 0.000 291.483 11.710 516.37 516.11 .05 6.4383 6.5580 -1.82
17 2020 0.000 298.150 11.700 515.95 515.73 .04 10.3635 10.4706 -1.02
17 2021 0.000 303.150 11.693 515.63 515.42 .04 13.2765 13.3815 -.78
17 2022 0.000 277.594 11.880 523.87 523.54 .06 1.0563 1.2104 -12.74
17 2023 0.000 285.928 11.866 523.27 523.06 .04 6.2501 6.3549 -1.65
17 2024 0.000 291.483 11.857 522.87 522.75 .02 9.6864 9.7503 -.65
17 2025 0.000 298.150 11.847 522.43 522.37 .01 13.7792 13.8113 -.23
17 2026 0.000 280.372 12.038 530.83 530.84 -.00 6.5769 6.5729 .06
17 2027 0.000 285.928 12.029 530.43 530.49 -.01 10.1780 10.1461 .31
17 2028 0.000 291.483 12.020 530.04 530.20 -.03 13.7881 13.6958 .67
109
2 11 ,
Data sources and ID numbers; (l)Virlal Equation, (2)Dawson, (3)Beattie, (4 Desciiner (5)Reamer,
) ,
(13)Cherney, ( 7 )Tom li nson , (24)Ely, (26)Dittmar, (XXXX)Haynes , ( 51 ,52)Thomas,

1 78)Te ichmann (
(79)Warowny.
ID Data Weight Temp. Density Density Density êxpt ^calc Pressure

No. K mol/L kg/m^ kg/m^ % MPa MPa %
4 2029 0,000 303.150 .041 1,79 1,80 -.80 1013

. . 1005 .80
4 2030 0.000 348.150 .035 1.55 1.56 -. 74 .1013 . 006
1 .74
4 2031 0.000 373,150 .033 1.44 1.45 -.78 .1013 .1005 .78
4 2032 0.000 380.950 .032 1.41 1.42 -.83 .1013 .1005 .83
4 2033 0.000 303.150 .083 3,64 3,67 -.79 .2027 .201 .77
4 2034 0.000 348,150 .071 3,13 3,16 -.79 .2027 .201 1 .78
4 2035 0.000 303.150 .126 5,55 5.59 -,81 .3040 ,3016 .77
4 2036 0.000 380.950 .098 4.30 4.34 -,98 .3040 ,301 .96
4 2037 0.000 303.150 .171 7.53 7.59 -,80 .4053 .4023 .76
4 2038 0.000 348.150 .145 6.40 6.45 -.78 .4053 .4023 .76
4 2039 0.000 303.150 .217 9.59 9.66 -.82 .5066 .5028 .76
4 2040 0.000 373.150 .170 7.48 7.53 -.66 .5066 .5034 .64
4 2041 0.000 380.950 .165 7.28 7.35 -1.03 .5066 ,5016 1.00
4 2042 0.000 398.150 .158 6.95 7.00 -.75 .5066 .5030 .73
4 2043 0.000 303.150 .266 11.73 11.83 -.79 .6080 .6036 .71
4 2044 0.000 348.150 .223 9.82 9,90 -.77 .6080 .6036 .73
4 2045 0.000 303.150 .317 13.99 14.09 -.71 .7093 .7049 ,62
4 2046 0.000 303.150 .371 16.38 16.48 -.59 .8106 .8066 ,50
4 2047 0.000 348.150 .304 13.40 13.51 -.81 .8106 .8046 ,74
4 2048 0.000 303.150 .429 18.93 19.00 -.34 .9119 .9094 .27
4 2049 0.000 303.150 .493 21.73 21.68 .21 1.0133 1.0149 -.17
4 2050 0.000 348.150 .389 17.17 17.31 -.83 1.0133 1.0058 .74
4 2051 0.000 373.150 .355 15.66 15.75 -.54 1.0133 1.0083 .49
4 2052 0.000 380.950 .343 15.15 15.33 -1 .20 1,0133 1.0020 1. 12
4 2053 0.000 398.150 .327 14.41 14.50 -.62 1.0133 1.0074 .58
4 2054 0.000 348.150 .480 21.17 21.33 -.77 1,2159 1.2079 .66
4 2055 0.000 348.150 .577 25.42 25,62 -.76 1 .4 186 1.4096 .63
4 2056 0.000 373.150 ,562 24,78 24,84 -. 27 1 ,5199 1.5164 .23
4 2057 0.000 380.950 .539 23,78 24.07 -1 .22 1 .5199 1.5037 1 .08
4 2058 0.000 398.150 .506 22.29 22.58 -1,28 1 .51 99 1.5025 1 . 16
4 2059 0.000 348,150 .680 29.99 30.22 -.75 1 . 62 1 1.6115 .60
4 2060 0.000 348.150 .792 34.92 35.19 -.76 1 .8239 1.8 34 1 .58
4 2061 0.000 348.150 .915 40.33 40.64 -,75 2.0265 2.01 56 .54
4 2062 0.000 373.150 .796 35.08 35.08 -,01 2.0265 2.0264 .01
4 2063 0.000 380.950 .758 33.44 33.79 -1 ,04 2.0265 2.0091 .87
4 2064 0.000 398.150 .709 31.25 31.37 -.38 2.0265 2,0199 .33
4 2065 0.000 348.150 1.052 46.39 46,71 -.69 2,2292 2,2190 .46
4 2066 0.000 348.150 1.208 53.28 53.65 -.70 2.4318 2,4217 .42
4 2067 0.000 373.150 1.065 46.97 46.93 ,09 2.5331 2,5348 -.07
4 2068 0.000 380.950 1.006 44.35 44.80 -1,00 2.5331 2,5139 .77
4 2069 0.000 398.150 .928 40,92 41,02 -.24 2.5331 2,5283 .19
4 2070 0.000 348.150 1.398 61.66 61.91 -.42 2.6345 2,6287 .22
4 2071 0.000 348.150 1.617 71.29 72.55 -1,73 2.8371 2,8164 .73
4 2072 0.000 373.150 1.391 61,33 61,23 .17 3.0398 3.0430 -.11
4 2073 0.000 380,950 1,292 56.99 57,64 -1.13 3.0398 3.0161 .79
4 2074 0.000 398,150 1,172 51,69 51,77 -.15 3.0398 3.0363 ,11
4 2075 0.000 373,150 1,807 79,68 79.91 -.29 3.5464 3.541 .15
4 2076 0.000 380.950 1.641 72.35 73.36 -1,37 3.5464 3.5174 .83
4 2077 0.000 398,150 1.451 64.00 63.99 .02 3.5464 3,5468 -.01
4 2078 0.000 373.150 2.436 107,41 109,24 -1.67 4.0530 4,0299 .57
4 2079 0.000 380.950 2.099 92.57 94.24 -1.78 4.0530 4,0185 .86
4 2080 0.000 398.150 1.776 78.3.1 78.25 .07 4.0530 4,0547 -.04
4 2081 0.000 373,150 5.216 230.02 248.93 -7.59 4.5596 4,5284 .69
4 2082 0.000 380.950 2.738 120.74 127.28 -5.14 4.5596 4,4818 1.74
4 2083 0.000 398.150 2.161 95.28 95.54 -.27 4.5596 4,5528 .15
4 2084 0.000 373.150 6.656 293.50 294.08 -.20 4.7623 4.7571 .11
110
1
(13)Cherney, ( 1 7)Tom I i nson , (24)Ely, (26)Di ttmar, (XXXX)Haynes , ( 51 ,52)Thomas, (78)Teichmann,
(79) Warowny.
ID Data Weight Temp. Dens ty

êxpt ca c I
Pressure
Point expt ca Ic Dif f. Dif f.
No. K mol/L kg/m- kg/m^ MPa MPa
2085 0.000 373. 150 6.881 303.45 303.69 -.08 4.8636 4.8606 .06
2086 0.000 373.150 7.065 31 1 .56 310.98 .18 4.9649 4.9739 -. 18
2087 0.000 373. 150 7.213 318.06 316.91 .36 5.0663 5.0881 -.43
2088 0.000 380.950 4.076 179.74 203.65 -1 1 .74 5.0663 4.9509 2.33
2089 0.000 398. 150 2.641 116.44 1 17.53 -.93 5.0663 5.0442 .44
2090 0.000 373. 150 7.675 338.43 336.86 .47 5.5729 5.6259 -.94
2091 0.000 380.950 6.078 268.01 280.62 -4.49 5.5729 5.4473 2.31
2092 0.000 398. 150 3.287 144.94 146.83 -1.29 5.5729 5.5444 .51
2093 0.000 380.950 6.472 285.40 295.54 -3.43 5.7755 5.6303 2.58
2094 0.000 380.950 6.774 298.72 306.54 -2.55 5.9782 5.8286 2.57
2095 0.000 373.150 8.007 353.1 349.73 .97 6.0795 6.2424 -2.61
2096 0.000 380.950 6.906 304.55 311.11 -2. 1 1 6.0795 5.9374 2.39
2097 0.000 398. 150 4.134 182.30 184.72 -1.31 6.0795 6.0491 .50
2098 0.000 373.150 8.235 363.12 359.44 1.02 6.5861 6.8106 -3.30
2099 0.000 380.950 7.325 323.03 328.55 -1.68 6.5861 6.4027 2.86
2100 0.000 398.150 5.044 222.42 223.59 -.52 6.5861 6.5697 .25
2101 0.000 373.150 8.409 370.79 367.34 .94 7.0928 7.3438 -3.42
2102 0.000 380.950 7.637 336.78 340.91 -1 .21 7.0928 6.9071 2.69
2103 0.000 398.150 5.774 254.60 255.72 -.44 7.0928 7.0726 .28
2104 0.000 373.150 8.565 377.71 374.05 .98 7.5994 7.9082 -3.91
2105 0.000 380.950 7.862 346.67 350.59 -1.12 7.5994 7.3814 2.95
2106 0.000 398.150 6.320 278.68 279.93 -.44 7.5994 7.5692 .40
2107 0.000 373.150 8.673 382.43 379.91 .67 8. 1060 8.3447 -2.86
2108 0.000 380.950 8.051 355.04 358.59 -.99 8. 1060 7.8705 2.99
2109 0.000 398. 150 6.734 296.93 297.88 -.32 8. 1060 8.0753 .38
21 10 0.000 373.150 8.806 388.31 385.12 .83 8.6126 8.9499 -3.77
2111 0.000 380.950 8.229 362.87 365.44 -.70 8.6126 8.4143 2.36
21 12 0.000 398. 150 7.084 312.38 31 1.73 .21 8.6126 8.6394 -.31
2113 0.000 373.150 8.917 393.20 389.83 .86 9.1 193 9.5117 -4.13
21 14 0.000 380.950 8.369 369.04 371 .45 -.65 9. 1193 8.9092 2.36
2115 0.000 398.150 7.359 324.53 322.88 .51 9.1 193 9.2028 -.91
21 16 0.000 373.150 9.016 397.57 394. 14 .87 9.6259 10.0607 -4.32
2117 0.000 380.950 8.491 374.43 376.82 -.63 9.6259 9.3943 2.47
21 18 0.000 398.150 7.599 335.08 332.19 .87 9.6259 9.8010 -1 .79
2119 0.000 373.150 9. 109 401 .70 398. 12 .90 10.1325 10.6234 -4.62
2120 0.000 380.950 8.602 379.32 381.68 -.62 10. 1325 9.8804 2.55
2121 0.000 398. 150 7.774 342.80 340.18 .77 10.1325 10.3155 -1 .77
2122 0.000 373.150 9. 186 405.07 401.81 .81 10.6391 1 1 . 1 1 66 -4.30
2123 0.000 380.950 8.698 383.55 386. 13 -.67 10.6391 10.3399 2.89
2124 0.000 398. 150 7.939 350.10 347.17 .84 10.6391 10.8709 -2.13
2125 0.000 373.150 9.257 408. 19 405.27 .72 11.1458 11.6003 -3.92
2126 0.000 380.950 8.787 387.47 390.24 -.71 11. 1458 10.8007 3.19
2127 0.000 398.150 8.082 356.41 353.39 .85 11.1458 1 1 .41 15 -2.33
2128 0.000 373.150 9.320 410.97 408.51 .60 11.6524 12.0564 -3.35
2129 0.000 380.950 8.876 391.42 394.06 -.67 1 .6524
1 11.2983 3.13
2130 0.000 398.150 8.204 361.77 359.01 .77 11.6524 11.9203 -2.25
2131 0.000 373.150 9.376 413.46 41 1.58 .46 12.1590 12.4833 -2.60
2132 0.000 380.950 8.960 395.10 397.63 -.64 12. 1590 11.7969 3.07
2133 0.000 398. 150 8.315 366.67 364. 13 .70 12.1590 12.4273 -2. 16
2134 0.000 373. 150 9.431 415.87 414.49 .33 12.6656 12.9157 -1.94
2135 0.000 380.950 9.038 398.55 400.99 -.61 12.6656 12.2950 3.01
2136 0.000 398.150 8.412 370.96 368.83 .58 12.6656 12.9080 -1 .88
2137 0.000 373.150 9.486 418.31 417.25 .25 13. 1723 13.3720 -1 .49
2138 0.000 380.950 9.120 402. 15 404.16 -.50 13. 1723 12.8472 2.53
2139 0.000 398.150 8.501 374.85 373.19 .44 13.1723 13.3749 -1.52
2140 0.000 398.150 8.656 381.70 381.06 .17 14. 1855 14.2734 -.62
111
D . 0 1 1 0
II
1 1 4
0
u
71
1 A1
4
1
Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)Beattie, (4)Deschner, (5)Reanier,
(13)Cherney, ( 7 )Tom 11 nson , (24)Ely, ( 26)D ttmar , (XXXX)Haynes, ( 51 ,52)Thomas, (78)Teich(nann,
1 i
(79)Warowny.
Data Weight Temp. Dens ty Dens ty Dens ty p p Pr essui

1
i i i
''êxpt ^ca c 1
Po nt i expt ca c i u 1 T T . U TT,
1
/ 3 d
No. K mol /L
1
kg/m^ of
ilra To
423. 50 .029 1.27 1 9Q

zo
-7-7 1 A T 1 1AA
UUDC .77
4 2141 0.000 1 1 . . 1
4 2142 0.000 473. 50 1 .026 1.13 1.14A

1 i
-.76 ,1013 . 1 006 ,76
4 2143 0.000 526.370 .023 1.02 1.03 -.77 .1013 . 1005 .77
4 2144 0.000 423. 50 1 .087 3.85 3.88 -. 76 .3040 .301 .75
4 2145 0.000 473, 50 1 .078 3.43 3.45 -.78 .3040 ,3016 .77
4 21 46 0.000 526.370 .070 3.07 3.09 -.83 .3040 ,301 5 ,83
A
-. 7/U C A zo £0
4 2 147 0.000 423. 50 1 .147 6.50 D. D4 . DUOD ,DU3z ,00
CA a OA AAA C AO A
4 2148 0.000 4A TZ
/3 . 50
1
1 .131 5.76 D.oU -. 7/1
/4 • DUDD
7^
,74
4 2149 0.000 526^370 .1 17 5. 14
c 10
D. lO -.00 7/ ,5066 ,
C AO'Z
5023 ,85
.304 13.39 AC
1 "Z
13.46 -, 55 1 A Z
.0133 1 "Z
0079
4 21 50 0.000 423. 50 1 1 1 . ,53
4 2 1 51 0.000 473. 150 .266 1 .75
1 1 1 . 82 -.59 1 .0133 1 ,0074 .58
4 21 52 0. 000 525.3/0 .236 10,41 1
1
A CÂ
U. DU Q 1 1
1.0A 33 1
1
"Z "Z 1
1
AA z
,UUD3 c:
.
7/y
A
4 2 531
A AAA A ox
4Z J . 5Uc:a
1
1 .469 20.69 9 A 70
zu, /y A Q
-.4y 1. D yy 1
1
1 , D jU
A 1 "Z AA
.40
Z 541
A AAA 4 /_> . DU 1 .408 17.99 1(5
10 ,
A7
U/ A
— .4 1
1 1. D yy 1
1
1
R 4U
, D
A 1
1
>1 "ZQ
. jy
4 o 1 A AAA
u.uuu £^9A J
DZD. X~7A
/U .359 5.82
1 1D,y4 -. /J 1
1
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• D yy
c; 1
1
1
1
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, Duyz
7
4 O
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1
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30 u. AAA
n uuu R7A
D /U.4DUA RA .328 14,46 1
1
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4 , DO — . fi7
D/ 1
1
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1
1
1
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AA
.00
u. AAA Z , n9A
A 9"^ Rn A z7
4 Z D 1 / uuu 4Z
/I
J. DU 1
1 .646 28.47 9ft "=10
ZO , Dy — .4 1
1
9 UZODs z,n
9 u 1
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4 Z 1 DC) u. AAA
A uuu /I"7X
4 / J .
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1
1 .555 24.49 Z4 RR
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9 , UZO z n999
9 , uzzz 9
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DZD "^7n
/U .485 2 .391
9
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z, RQ
u 1 Dy 1 . DJ
4 Z 1 DU U» UUU R7n
D /U. A'^n
4 DU .44 19.47 1
1 y , ^1
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9 U AA0^ 1
I . sn
DU
4 Z 1 D 1 u. uuu hZ3 . cn 1
DU 1 .835 36.81 DO, y 1
9 S^'^
Z , DDD 1 9 '^97n
Z , DZ / . 9A
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4 9
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u.uuu 4/I7T
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1
1 .709 3 .241 D •Z 1
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1 U Z , DDD z , jDuy no
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4 9
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n uuu DZD J^7n
'i?^ lU .614 27.09 97 0 ZU
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<^ , Jc,D\> . _30
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n uuu D /U.^DU .557 24. 57 ZH .DO 9 R'^^
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4 9
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u.uuu 9T
4Z_>» DU
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1 1.038 45.78 H D.O / - IS
— .10 Z A
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DO u. AAA
A uuu 4 /D . DU 1 .868 38.26 JO
"^ft 97
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1 J, u jy n"^Q
j,UjyD c; n1
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A .747 32.94 7 A9
J J.UZ — . 97
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U JZZ 7R
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A uuu C7A A c^n
D /U.4DU .675 29.77 9Q
zy .OD Q*^
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zu D. ujyo X (\XA
D, U J4 1
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1 1.258 55.46 DD. Do -.10 J.
cry! A^
X D404 z
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DO, D 1 c;
1 -,13z 1
4.UDDU A A/1 0 1
4.U4y ,
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4 2 1 74 0.000 473. 50 1 1.207 53.24 53, 13 ,2 1 4, 0530 4,0603
/I
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4 2175 0.000 526.370 1.021 45.04 45.07 -, 05 4.0530 4,051 ,05

z
-, 113
4 2176 0.000 570.450 .917 40.44 40.39 , 14 4.0530 4,0583
4 2177 0.000 609.31 .846 37.31 37. 13 ,47 4.0530 4,071 -,45
4 2 1 78 0.000 423. 50 1 1.766 77.89 77.84 ,07 4.5596 4,5617 -,05
4 21 79 0.000 473. 50 1 1.389 61 .27 61 .05 ,36 4. 5596 4,5733 -,30
4 2180 0.000 526.370 1.164 51.31 51 .30 ,02 4.5596 4,5604 -,02
4 2181 0.000 570.450 1 .041 45.88 45.78 ,23 4,5596 4, 5696 -,22
4 2182 0.000 423. 50 1 2.064 91.02 90.88 . 16 5.0663 5,0716 -. 1
4 2183 0.000 473. 50 1 1.580 69.66 69.34 .47 5.0663 5,0856 -.38
4 2 84 1 0.000 526.370 1.309 57.72 57.67 .08 5.0663 5,0698 -.07
4 2185 0.000 570.450 1.165 51 .38 51 .24 .28 5.0663 5,0793 -.26
4 2186 0.000 609.310 1.070 47. 18 46.89 .61 5.0663 5,0957 -.58
4 2187 0.000 423, 150 2.392 105.50 105.56 -.06 5.5729 5,5707 .04
4 2188 0.000 473.150 1.777 78.36 78.01 .45 5,5729 5,5929 -.36
4 2189 0.000 526.370 1.456 64.20 64. 19 ,02 5.5729 5,5741 -.02
4 2190 0.000 570.450 1.291 56.95 56.78 ,29 5.5729 5,5879 -.27
4 2191 0.000 423. 150 2.751 121.30 122. 17 -,71 6.0795 6,0544 .41
4 2192 0,000 473. 150 1.981 87.35 87.08 ,31 6.0795 6.0942 -.24
4 2193 0.000 526.370 1.606 70.83 70.85 -,03 6.0795 6.0779 .03
4 2194 0.000 570.450 1.418 62,54 62.40 ,23 6.0795 6.0923 -.21
4 2195 0.000 609,310 1.297 57.18 56.82 ,64 6.0795 6. 1 165 -.60
4 2196 0.000 423.150 3.150 138,88 140.82 -1,37 6.5861 6.5360 .77
112
1 1 . , 1
Data sources and ID numbers; (l)Virial Equation, (2)Dawson, (3)Beattie, (4)Deschner, (5)Reamer,
(13)Cherney, ( 7 )Tom nson , (24)Ely, (26)Dittmar, (XXXX)Haynes, ( 51 ,52)Thomas, (78)Teichmann,
1 I i
(79)Warowny.
ID Data We ight Temp. Density Dens ty i Dens tyi

êxpt ""^ca I c Pressure
No. K mol/L kg/m^ kg/m^ MPa MPa
2197 0.000 473. 150 2.193 96.70 96.58 .13 6.5861 6.5924 -.10
2198 0.000 526.370 1.760 77.59 77.66 -.09 6.5861 6.5807 .08
2199 0.000 570.450 1.547 68.21 68.09 . 18 6.5861 6.5970 -.16
2200 0.000 423.150 3.596 158.56 161 .20 -1.64 7.0928 7.0289 .91
2201 0.000 473. 150 2.414 106.46 106.50 -.04 7.0928 7.0907 .03
2202 0.000 526.370 1.916 84.47 84.62 -.17 7.0928 7.0821 . 15
2203 0.000 570.450 1.676 73.90 73.84 .08 7.0928 7.0979 -.07
2204 0.000 609.310 1.525 67.26 66.91 .53 7.0928 7. 1281 -.50
2205 0.000 423.150 4.076 179.76 182.37 -1.43 7.5994 7.5369 .83
2206 0.000 473.150 2.642 16.50
1 1 16.81 -.27 7.5994 7.5843 .20
2207 0.000 526.370 2.074 91.46 91.72 -.27 7.5994 7.5816 .23
2208 0.000 570.450 1.806 79.66 79.67 -.01 7.5994 7.5984 .01
2209 0.000 423.150 4.558 200.98 203.00 -.99 8. 1060 8.0550 .63
2210 0.000 473. 150 2.876 126.83 127.46 -.49 8. 1060 8.0764 .37
221 0.000 526.370 2.235 98.57 98.94 -.37 8. 1060 8.0802 .32
2212 0.000 570.450 1.937 85.40 85.56 -. 18 8. 1060 8.0929 .16
2213 0.000 609.310 1.755 77.38 77.14 .31 8. 1060 8.1293 -.29
2214 0.000 423. 150 5.004 220.65 222. 1 -.65 8.6126 8.5723 .47
2215 0.000 473.150 3.1 18 137.48 138.37 -.65 8.6126 8.5715 .48
2216 0.000 526.370 2.399 105.79 106.28 -.45 8.6126 8.5796 .39
2217 0.000 570.450 2.070 91.26 91.50 -.26 8.6126 8.5923 .24
2218 0.000 423. 150 5.389 237.64 239.42 -.74 9. 1 193 9.0646 .60
2219 0.000 473. 150 3.362 148.24 149.44 -.80 9. 1 193 9.0645 .60
2220 0.000 526.370 2.566 1 13. 16 1 13.71 -.49 9. 1 193 9.0817 .41
2221 0.000 570.450 2.203 97.13 97.49 -.37 9. 1 193 9.0887 .34
2222 0.000 609.310 1.987 87.60 87.50 .12 9. 1 193 9. 1294 -. 1
2223 0.000 423. 150 5.740 253.12 254.90 -.70 9.6259 9.5644 .64
2224 0.000 473.150 3.607 159.05 160.54 -.93 9.6259 9.5578 .71
2225 0.000 526.370 2.733 120.52 121.22 -.57 9.6259 9.5790 .49
2226 0.000 570.450 2.334 102.94 103.53 -.56 9.6259 9.5769 .51
2227 0.000 423.150 6.056 267.06 268.58 -.56 10.1325 10.0731 .59
2228 0.000 473.150 3.854 169.94 171 .54 -.93 10. 1325 10,0584 .74
2229 0.000 526.370 2.901 127.92 128.77 -.66 10.1325 10.0756 .56
2230 0.000 570.450 2.468 108.83 109.59 -.70 10.1325 10.0669 .63
2231 0.000 609.310 2.218 97.80 97.94 -. 14 10.1325 10. 193 1 .13
2232 0.000 423. 150 6.340 279.59 280.60 -.36 10.6391 10.5939 .43
2233 0.000 473.150 4. 100 180.81 182.32 -.83 10.6391 10.5673 .68
2234 0.000 526.370 3.068 135.28 136.33 -.77 10.6391 10.5690 .66
2235 0.000 570.450 2.601 114.71 115.67 -.83 10.6391 10.5591 .76
2236 0.000 423.150 6.589 290.57 291. 18 -.21 11.1458 1 1.1 148 .28
2237 0.000 473.150 4.347 191 .67 192.77 -.57 1 ,1458
1 11.0917 .49
2238 0.000 526.370 3.234 142.60 143.88 -.89 11, ,1458 11.0593 .78
2239 0.000 570.450 2.735 120.59 121.75 -.95 11, ,1458 1 .0490
1 .88
2240 0.000 609.310 2.448 107.95 108.42 -.44 11, ,1458 11.0999 .41
2241 0.000 423.150 6.815 300.51 300.54 -.01 11.6524 11.6503 .02
2242 0.000 473.150 4.591 202.44 202.81 -.18 11.6524 11.6334 .16
2243 0.000 526.370 3.400 149.92 151 .39 -.97 11.6524 11.5530 .86
2244 0.000 570.450 2.869 126.52 127.83 -1.03 11.6524 11.5428 .95
2245 0.000 423. 150 7.017 309.41 308.89 .17 12.1590 12. 1924 -.27
2246 0.000 473.150 4.834 213.18 212.42 .35 12.1590 12. 1998 -.33
2247 0.000 526.370 3.563 157.10 158.81 -1.08 12. 1590 12.0419 .97
2248 0.000 570.450 3.001 132.33 133.89 -1.16 12.1590 12.0286 1.08
2249 0.000 609.310 2.676 118.02 118.88 -.72 12. 1590 12.0755 .69
2250 0.000 423.150 7. 184 315.80 316.39 .13 12.6656 12.6947 -.23
2251 0.000 473. 150 5.070 223.57 221.58 .90 12.6656 12.7791 -.89
2252 0.000 526.370 3.728 164.39 166.13 -1.05 12.6656 12.5444 .97
113
m 1
(13)Cherney, ( 7 )Tom nson , (24)Ely, (26)Dittmar , (XXXX)Haynes , ( 51 ,52 )Thomas, {78)Teichmann,
1 I i
(79)Warowny,
1 n
U uaxa We 9 '^'^ Tsmp • Dens ty U" M b nc
ri£i
Uciib 1 TV/ P p Pressui
1 i i 1 1
y 1 1
y êxpt ^cal c
Po nt
i expt C9 C 1 U 1 TT , U TT.
1
INO . fS mo / L
1 kg/ kg/ l^'lrd rtra Jo
i\
4 U.UUU J /U»4!)U 3.134 138.22 1 "^Q on 1 0 \^ •OuDO 1.14
4 2254 0.000 423. 150 7.336 323.50 323.19 .10 13.1723 13. 1965 -. 18
4 2255 0.000 473.150 5.299 233.66 230.30 1.46 13. 1723 13.3747 -1.51
4 2256 0.000 526.370 3.890 171.52 173.32 -1 .04 13. 1723 13.0446 .98
4 2257 0.000 570.450 3.266 144.04 145.88 -1.26 13. 1723 13.0157 1.20
4 2258 0.000 609.310 2.903 128.03 129.27 -.96 13.1723 13.0506 .93
4 2259 0.000 423. 150 7.468 329.32 329.39 -.02 13.6789 13.6728 .04
4 2260 0.000 473. 150 5.518 243.35 238.59 1.99 13.6789 13.9819 -2.17
4 2261 0.000 526.370 4.054 178.75 180.36 -.89 13.6789 13.5619 .86
4 2262 0.000 570.450 3.398 149.84 151 .78 -1 .28 13.6789 13.51 17 1.24
4 2263 0.000 423.150 7.585 334.47 335.08 -.18 14. 1855 14. 1286 .40
4 2264 0.000 609.310 3,127 137.88 139.53 -1.18 14. 1855 14.0217 1.17
114
1 .
1 1
(13)Cherney, ( 7)Tom nson , (24)Ely, (26)Dlttmar, (XXXX)Haynes, ( 51 , 52) Thomas, (78)Teichmann,
1 I i
(79)Warowny.
ID Data Weight Temp. Dens ty i Dens ty i Dens tyi

V n "i"
v>A|J 1
p .
Pressor
Point expt cal c Diff Diff.
No. K mol/L kg/m-^ kg/m-' % MPa MPa %
79 2265 0.000 373.150 3.851 169.83 178.91 -5.07 4.4549 4.4352 .44
79 2266 0.000 373.150 2.457 108.34 108.45 -.10 4.0431 4.0417 .03
79 2267 0.000 373. 150 1.566 69.07 68.85 .31 3.2664 3.2724 -. 18
79 2268 0.000 373. 150 1.000 44.09 44.05 .09 2.4176 2.4191 -.06
79 2269 0.000 373.150 .638 28. 13 28. 16 -.11 1.691 1.6895 .10
79 2270 0.000 373. 150 .407 17.93 17.97 -.23 1.1423 1. 1400 .20
79 2271 0.000 373. 150 .259 11.43 11.47 -.28 .7553 .7533 .26
79 2272 0.000 373. 150 . 165 7.28 7.31 -.30 .4923 .4909 .28
79 2273 0.000 373. 150 .105 4.65 4.66 -.30 .3188 .3179 .29
79 2274 0.000 393. 190 3.405 150. 13 150.66 -.35 5.3854 5.3788 .12
79 2275 0.000 393. 190 2.446 107.86 107.69 .16 4.6967 4.7002 -.07
79 2276 0.000 393.190 1.756 77.43 77.24 .25 3.9155 3.9214 -.15
79 2277 0.000 393. 190 1 .261 55.62 55.57 .08 3. 1362 3. 1381 -.06
79 2278 0.000 393. 190 .906 39.96 40.00 -. 1 2.4358 2.4337 .09
79 2279 0.000 393.190 .651 28.70 28.77 -.24 1.8496 1.8458 .21
79 2280 0.000 393. 190 .467 20.60 20.67 -.32 1.3820 1.3780 .29
79 2281 0.000 393.190 .335 14.79 14.84 -.35 1.0207 1.0174 .32
79 2282 0.000 393.190 .241 10.62 10.66 -.36 .7477 .7451 .34
79 2283 0.000 407.500 3.749 165.34 169. 19 -2.27 6.4103 6.3445 1.04
79 2284 0.000 407.500 2.651 116.89 1 16.78 .10 5.3802 5.3830 -.05
79 2285 0.000 407.500 1.903 83.92 83.73 .23 4.4409 4.4473 -.14
79 2286 0.000 407.500 1.367 60.29 60.24 .08 3.5410 3.5431 -.06
79 2287 0.000 407.500 .982 43.32 43.38 -.13 2.7448 2.7420 .10
79 2288 0.000 407.500 .706 31.12 31 .21 -.28 2.0825 2.0775 .24
79 2289 0.000 407.500 .507 22.35 22.43 -.36 1.5552 1.5502 .32
79 2290 0.000 407.500 .364 16.04 16. 10 -.39 1.1480 1.1438 .36
79 2291 0.000 407.500 .261 11. 51 1 1.56 -.39 .8404 .8373 .37
79 2292 0.000 407.430 2.812 124.01 123.69 .26 5.5377 5.5449 -.13
79 2293 0.000 407.430 1.791 78.97 78.54 .55 4.2594 4.2747 -.36
79 2294 0.000 407.430 1.140 50.28 50. 17 .22 3.081 3.0863 -. 17
79 2295 0.000 407.430 .726 32.02 32.05 -.10 2.1303 2.1285 .09
79 2296 0.000 407.430 .462 20.39 20.44 -.27 1.4294 1.4259 .24
79 2297 0.000 407.430 .294 12.98 13.02 -.33 .9409 .9380 .31
79 2298 0.000 407.430 .187 8.26 8.29 -.34 .61 18 .6098 .33
79 2299 0.000 422.970 2.742 120.92 120.64 .24 6.0287 6.0369 -.14
79 2300 0.000 422.970 1.969 86.84 86.42 .49 4.8951 4.91 13 -.33
79 2301 0.000 422.970 1.414 62.36 62. 15 .33 3.8646 3.8744 -.25
79 2302 0.000 422.970 1.016 44.79 44.76 .07 2.9772 2.9789 -.06
79 2303 0.000 422.970 .729 32. 17 32.21 -.14 2.2502 2.2474 .13
79 2304 0.000 422.970 .524 23.10 23. 16 -.27 1.6766 1.6725 .25
79 2305 0.000 422.970 .376 16.59 16.65 -.34 1.2364 1.2325 .32
79 2306 0.000 422.970 .270 1 1.91 11.96 -.36 .9051 .9020 .35
79 2307 0.000 422.970 .194 8.55 8.58 -.36 .6588 .6565 .35
79 2308 0.000 423.020 1.613 71.14 70.69 .64 4.2539 4.2735 -.46
79 2309 0.000 423.020 1.158 51.07 50.90 .34 3.3068 3.3157 -.27
79 2310 0.000 423.020 .832 36.67 36.65 .05 2.5168 2.5179 -.04
79 231 0.000 423.020 .597 26.33 26.37 -. 14 1.8850 1.8825 .13
79 2312 0.000 423.020 .429 18.90 18.94 -.25 1.3945 1.3913 .23
79 2313 0.000 423.020 .308 13.57 13.61 -.31 1.0237 1.0207 .30
79 2314 0.000 423.020 .221 9.75 9.78 -.33 .7467 .7443 .32
79 2315 0.000 423.020 .159 7.00 7.02 -.33 .5422 .5404 .32
115
5 1 5 0
.
1 1 .
Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)8eattie, (4)Deschner, (5)Reamer,
(13)Cherney, ( 7)Tom nson , (24)Ely, (26)Dittmar, (XXXX)Haynes , ( 51 ,52)Thomas, (78)Teichmann,
1 I i
(79)Warowny.
ID Data Weight Temp. Density Dens ty i Dens ty i

êxpt '^ca 1 c Pressui
Point expt ca c 1 Di f f Di f f
No. K mol/L kg/m-* kg/m-' % MPa MPa at
f>
78 2316 0.000 322.972 10.456 461 .10 460.52 .12 4.0710 4.2016 -3. 1 1
78 2317 0.000 328. 168 10.452 460.92 460.35 ,13 6. 1869 6.3270 -2.22
78 2318 0.000 332.609 10.449 460.78 460.21 ,12 7.9977 8. 1433 -1 .79
78 2319 0.000 337.762 10.445 460.62 460.06 . 1 2 10,0989 10.2485 -1 .46
78 2320 0.000 342.618 10.442 460.47 459.94 . 1 12.0814 12.2303 -1 .22
78 232 i 0.000 347. 144 10.439 460.33 459.82 , 1 1 13,9231 14.0747 -1 .08
78 2322 0.000 352.944 10.435 460. 15 459.66 . 1 1 16.2821 16.4344 -.93
78 2323 0.000 363. 122 10.428 459.84 459.40 .09 20.41 50 20.5634 -.72
78 2324 0.000 372.349 10.422 459.56 459. 1 ,09 24. 1420 24.2915 -.62
78 2325 0.000 382.692 10.41 459.25 458.86 .09 28.2987 28.4532 -.54
78 2326 0.000 393.048 1 0.408 458.94 458.55 .09 32.434 32.5981 -.50
78 2327 0.000 403. 68 1 10.401 458.64 458.24 .09 36.4506 36.6286 -.49
78 2328 0.000 4 4.877
1 10.393 458.30 457.87 ,09 4 1 .0620 4 ,2645
1 -.49
78 2329 0.000 428.006 10.384 457.91 457.73 ,04 46,3353 46,4240 -. 19
78 2330 0.000 446. 59 1 10.372 457.38 456.82 . 12 53. 1897 53,4955 -.57
78 2331 0.000 465,974 10.359 456.79 456.36 , 1 60.8626 61 . 1220 -.42
78 2332 0.000 327.800 10.298 454. 1 453.27 . 19 4.4479 4.6246 -3,82
78 2333 0.000 337.927 10.291 453.79 452.95 . 18 8.3701 8.5693 -2.32
78 2334 0.000 345.864 10.285 453.54 452.74 . 18 1 1 ,4481 1 .6574
1 -1 .80
78 2335 0.000 355. 196 10.279 453.26 452.50 .17 15,0664 15.2826 -1 .42
78 2336 0.000 367,383 10.270 452.90 452.20 . 15 19,7797 20,0013 -1.11
78 2337 0.000 375.052 10.265 452.67 452.00 .15 22,7350 22,9607 -.98
78 2338 0.000 384.818 10.259 452.39 45 .74
1 . 14 26.4836 26.7158 -.87
78 2339 0.000 394.641 10.252 452, 10 451 .47 .14 30.2325 30.4770 -.80
78 2340 0.000 402.913 10.247 451 .86 451 .23 . 14 33.3753 33.6306 -.76
78 2341 0.000 416.717 10.238 451 .46 450.82 .14 38.5825 38.8657 -.73
78 2342 0.000 432.648 10.227 451 .00 450.32 . 15 44.5345 44.8589 -.72
78 2343 0.000 453.599 10.214 450.40 449.63 .17 52.2548 52.6584 -.77
78 2344 0.000 472,842 10.201 449.84 448.96 .20 59.2384 59.7383 -.84
78 2345 0.000 330.263 9.973 439.77 438.99 .18 2.7707 2.8935 -4.25
78 2346 0.000 341.713 9.965 439,41 438.55 .20 6.7553 6.9167 -2.33
78 2347 0.000 352.841 9,957 439.09 438.25 .19 10.6530 10.8328 -1 .66
78 2348 0.000 363.696 9.950 438.77 438.01 . 18 14.4640 14.6504 -1.27
78 2349 0.000 377.648 9.941 438.38 437.69 .16 19.3554 19.5471 -.98
78 2350 0.000 397,297 9.929 437.83 437,21 .14 26.21 15 26.4104 -.75
78 2351 0.000 412.796 9.919 437.40 436,81 .13 31 .5790 31 .7896 -.66
78 2352 0.000 431.026 9.907 436.89 436,30 .14 37.8361 38.0707 -.62
78 2353 0.000 448.440 9.897 436.41 435,79 .14 43.7474 44.0194 -.62
78 2354 0.000 463.694 9.887 435.99 435.32 . 16 48.8692 49. 1862 -.64
78 2355 0.000 480.702 9.876 435,52 434,77 . 17 54. 5166 54.8963 -.69
78 2356 0.000 496.299 9.867 435.09 434.25 . 19 59.6332 60.0842 -.75
78 2357 0.000 330.963 9.940 438.33 437.52 .18 2.7872 2.9129 -4.31
78 2358 0.000 331 .814 9.939 438.30 437.49 . 18 3.0816 3.2087 -3.96
78 2359 0.000 336.848 9.936 438. 14 437,29 . 19 4.8 135 4.9583 -2.92
78 2360 0.000 34 .988 1 9.932 437.99 437. 12 ,20 6.5880 6.7472 -2.36
78 2361 0.000 347.723 9.928 437.82 436.95 .20 8.5731 8,7450 -1 .97
78 2362 0.000 355.121 9.924 437.60 436.77 .19 1 1. 1422 1 1.3224 -1.59
78 2363 0.000 368.842 9.915 437.21 436.46 .17 15.91 17 16.0991 -1.16
78 2364 0.000 383.023 9.906 436.81 436.14 .15 20.8327 21.0224 -.90
78 2365 0.000 402.762 9.893 436.27 435.66 .14 27,6429 27.8412 -.71
78 2366 0.000 422.783 9.881 435.71 435.14 .13 34.4894 34.7048 -.62
78 2367 0.000 443.127 9.868 435.15 .
434.56 .14 41 .3682 41.6160 -.60
78 2368 0.000 342.839 9.231 407.08 406.41 .16 2.7845 2.8447 -2. 12
78 2369 0.000 350.822 9.226 406.86 405.98 .22 4.9609 5.0550 -1.86
78 2370 0.000 361.070 9.220 406.59 405.67 .23 7.7955 7.9133 -1.49
78 2371 0.000 369. 188 9.215 406.37 405.51 .21 10.0616 10. 1875 -1.24
116
0
2
4
1 1 11 . 81
1 511 .
1 / 9 , 51.
Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)Beattie, (4)Deschner, (5)Rearner,
(13)Cherney, ( 17 )Tom nson , (24)Ely, (26)Dittmar, (XXXX)Haynes, (51 , 52) Thomas, ( 78 )Te ichmann
I i
(79)Warowny.
D Data We g ht Temp, Dens ty Dens ty Dens ty p Pr essur

1 i i i i
êxpt "ca c 1
Po nt
i expt ca c 1 Di ff Di f f
No. K rtD l/L kg/m kg/m-^ a MPa MPa
78 2372 0.000 376.679 9.21 406. 1 405,37 .20 12. 1606 12.2905 -1 .06
78 2373 0.000 386. 501 Q 9ns 4ns Q"^ 405,20 .18 14,9208 15.0510 -.87
Q Q'^ 4ns 4n
7R 2374 0.000 407. 554 1
404.84 .14 20,8432 20.9555 -.58
7ft 7375 0 000 432. 150 Q 7Q
1 4n4 7R 404.35 . 1 27,7374 27.8505 -.41
7R 2376 0. 000 457.260 Q fiS
y m \\J
1
J 4n4 s 1
403.79 .09 34 , 7087 34.8212 - 39
7ft 0.000 481 .93 Q 1 SI hU J . -) J 403. 19 .09 4 ,4846
1 4 . 5072
1
- ?Q
7ft 51 .431 1
Q
y• 1
\ DH 4n7 Rn 402,42 09
• \jy 49,4692 49.5225 - "^1
7R n nnn 54R 961 y* % \
4n Rft 1 4ni "^7 1 9 SQ 4 R4 1 SQ ftsns _•
7R n nnn 354 671 R Sfi9 ^7/ 7/ . JD
Sfi S7fi fi9 9S fi4ni _j fionR
. L> yKj<D
7R 9'^R 1 n nnn R SS7 ^77 ^d ^7fi ns ^4 S 74 ^ S -1

7R n nnn 376.625 R ssn "^77 n'^ 375, 73 35 8.5296 ft fi4RQ _ 1
1 •
7R n nnn ^Q? ft"^R R SA9 _) D . 00

/
^7S S"^ • D\) 19
1 z . 9'^9n
z_^zu 1 Z . _?OH O - 1 07
7ft 9'^ft4 n nnn dnQ ?nn O . P Jj) ZTC
J / 0
9Q s , 9S
ZJ 1
S C)Q7Q
1 Jmyyiy 1
1 O. MIS
J J i \
- • o_?
7R Z.JO J
9'^ftS n nnn H-'Z . ^ R S9 '^7S 7/1 -J 1 J •KJ 1 • o
11 ft 91
Z 1
'^9.11
. -Ô/ /
91 Sin''; _• Jcr-t
1
7ft
/ o n nnn H 1 . UvJ 1
R S 1 1 "^7 S 1 ^74 77 1 4 9SJ .
Z 7RR7
oo
/
9s onin - • ^."^
7R n nnn 472.31 R snn ^74 R4 374 ,4 ,
1
1
1
1
"^n SIRS ^n ft99ft
uzzu _ T/l
7R 73ft8 n nnn 497.096 ftAR7 "^74 97 y^ nQ "^fi 1 S1Q ^fi

J o . z. *T ou
94ftfi _ 97
7R 7"^RQ 0 nnn 52 . 48 1 1
R d7S '^T'^ 7"^ ^7"^ 49 nR
, *_/o 41 Sfin4 4 1 fiSft'^
78 2390 0.000 546. 98 1

R . 4fi9
Q t UZ 372.86 nR 47 19Q7 47 9'^ns - 9 1
78 2391 0.000 570.278 8.450 372.61 372.30 ,08 52.4 34 1 52. 5324
78 2392 0.000 364.812 7.541 332. 52 331 .63 ,27 4.0534 4.0800 -.4
78 2393 0.000 376.448 7. 535 332 .28 330. 1 .65 5.9058 5. 9747 -1.15
78 2394 0.000 392.791 7.528 331 .95 329.97 .60 8,5004 8.7020 -1.17
78 2395 0.000 412.648 7.519 331 . 56 330.09 ,45 1 1.9520 12.051 -.91
78 2396 0.000 432.534 7.510 33 . 16 1 330. 15 .31 1 5.3480 15.4477 -.55
78 2397 0.000 452.553 7. 501 330.77 330. 1 .20 18.7801 18.8508 -.43
78 2398 0.000 473.034 7.492 330.37 329.98 .12 22.2902 22.3457 -.25
78 2399 0.000 492.234 7.483 329.99 329.80 .06 25. 5709 25.6024 -. 12
78 2400 0.000 51 2.405 7.474 329.60 329.57 .01 29.0010 29.0057 -.02
78 2401 0.000 530.760 7.466 329. 24 329.34 -.03 32. 1055 32,0843 .07
78 2402 0.000 550. 128 7.458 328.86 329.06 -.06 35.3592 35.3 19 1 . 13
78 2403 0.000 569. 593 7.449 328.48 328.77 -.09 38.6055 38.5319 , 19
78 2404 0.000 369.350 6.587 290.47 287.83 .91 4,2500 4,27 17 -.27
78 2405 0.000 378. 140 6. 584 290,32 284.88 1 .91 5.2858 5,3462 -1.13
78 2406 0.000 393.489 6. 578 290. 05 285.70 1.52 7. 1701 7,2734 -1 .42
78 2407 0.000 413.546 6 57n 289,71 286.74 1,04 9.7096 9,8312 -1 .24
78 2408 0.000 432. 1 29 U. J\JJ 9RQ 4n 287.32 .72 12,0990 12,2175 -.97
78 2409 0.000 452.677 9fiQ nsJ
zo y •\J 987 6R .48 14,7586 14.8615 -.69
78 24 1 0.000 473. 033 Sd7 9Rfl . 7
zoo / 287.84 ,30 17,3975 17.4781 -.45
78 241 0.000 491 .232 ft sdn ZO O . 4n
9RR H VJ 287.89 , 18 19.7553 19.8108 -.28
78 24 1 0.000 51 0.749 9RR »\j
ZOO n7 1 287.86 ,07 22,2751 22.3024 -. 12
78 24 13 0.000 530.884 fiS9S 79,11 •
Z.O 74
1H 28 7 . 78 -,02 24,8659 24.8595 .03
78 24 1 0.000 550.233 6.518 287.41 287.66 -. 09 27,3423 27 .3020 . 1
78 2415 0.000 570.645 6.510 287.07 287.49 -. 1 5 29.9378 29.8617 .25

78 2416 0.000 373.371 6.002 264.69 255.53 3.59 4.5957 4.6220 -.57
78 2417 0.000 384.040 5.997 264.45 257. 17 2.83 5.6751 5.7453 -1.22
78 2418 0.000 393. 158 5.992 264.25 258.51 2.22 5.6267 6.7173 -1.35
78 2419 0.000 412.539 5.984 263.88 260.23 1.40 8.6919 8.7995 -1.22
78 2420 0.000 432.549 5.976 263.53 261.18 .90 10.8549 10.9587 -.95
78 2421 0.000 451.584 5.969 263.22 261.69 .59 12.9243 13.0137 -.69
78 2422 0.000 472.918 5.961 262,88 261 .99 .34 15,2462 15.3121 -.43
78 2423 0.000 492.382 5.953 262,49 262. 14 ,13 17.3626 17,3940 -.18
78 2424 0.000 51 1.062 5.948 262,30 262.18 ,05 19.3858 19,3994 -.07
78 2425 0.000 530.956 5.941 261.97 262.18 -.08 21.5355 21,51 19 .11
78 2426 0.000 550.999 5.934 261 .66 262.1 -.17 23.6887 23.5292 .25
78 2427 0.000 573.416 5.926 261,31 262.00 -.26 25.0839 25.9808 .40
117
(13)Cherney, ( 7)Tom nson , (24)Ely, (26)Dittmar, ( XXXX)Haynes , ( 51 ,52)Thomas, (78)Teichrnann,
1 I i
(79)Warowny.
ID Data We Ight Temp. Dens ty Dens ty Dens ty p p Pressure

i i i
expt ca c
1
Point expt ca c
1 Diff Diff.
No. K mol/L kg/m-^ kg/m-' % MPa MPa %
78 2428 0.000 378.257 5.014 221.09 214.26 3. 19 4.9067 4.9317 -.51

78 2429 0.000 387.620 5.010 220.92 215.93 2.51 5.6512 5.6926 -.73
78 2430 0.000 397.884 5.006 220.73 216.97 1.74 6.4733 6.5245 -.79
78 2431 0.000 412.591 5.000 220.50 217.90 1.19 7.6571 7.7131 -.73
78 2432 0.000 432.441 4.994 220.20 218.63 .72 9.2588 9.3099 -.55
78 2433 0.000 451 .915 4.987 219.93 219.04 .41 10.8290 10.8680 -.36
78 2434 0.000 472.446 4.981 219.66 219.29 .17 12.4804 12.5009 -.16
78 2435 0.000 492.229 4.975 219.40 219.43 -.01 14,0664 14.0642 .02
78 2436 0.000 51 1.521 4.970 219.15 219.48 -.15 15.6053 15.5790 .17
78 2437 0.000 530.931 4.964 218.90 219.49 -.27 17. 1466 17.0930 .31
78 2438 0.000 550.497 4.958 218.64 219.46 -.37 18.6917 18.6090 .44
78 2439 0.000 572.459 4.952 218.36 219.38 -.47 20.4148 20.2977 .58
78 2440 0.000 372.414 3.733 164.60 164.21 .24 4.3777 4.3787 -.02
78 2441 0.000 383. 158 3.729 164.46 163.52 .57 4.9839 4.9904 -. 13
78 2442 0.000 393.257 3.727 164.33 163.39 .58 5.5395 5.5501 -.19
78 2443 0.000 412.606 3.721 164,08 163.37 .44 6.5841 6.5979 -.21
78 2444 0.000 432.037 3.716 163.86 163.43 .26 7.6162 7.6282 -.16
78 2445 0.000 452.165 3.71 1 163.64 163.48 .10 8.6722 8.6783 -.07
78 2446 0.000 472.712 3.706 163.43 163.50 -.04 9.7389 9.7355 .03
78 2447 0.000 492.367 3.702 163.23 163.50 -. 17 10.7498 10.7350 .14
78 2448 0.000 51 1.981 3.697 163.04 163.48 -.27 1 1 .7501 1 .7223
1 .24
78 2449 0.000 531 .510 3.693 162.85 163.44 -.36 12.7383 12.6961 .33
78 2450 0.000 551.623 3.689 162.66 163.38 -.45 13.7487 13.6902 .43
78 2451 0.000 569.383 3.685 162.49 163.33 -.52 14.6348 14.5605 .51
78 24 52 0.000 383. 172 2.474 109. 1 108.37 .69 4.3809 4.3932 -.28
78 2453 0.000 393.351 2.472 109.03 108.10 .86 4.7103 4.7294 -.40
78 2454 0.000 403.287 2.471 108.95 107,85 1.02 5.0237 5.0504 -.53
78 2455 0.000 413.008 2.469 108.87 107.75 1.03 5.3277 5.3590 -.58
78 2456 0.000 432.821 2.465 108.71 107.67 .96 5.9379 5.9745 -.61
78 2457 0.000 452.480 2.462 108.55 107.62 ,86 6.5319 6.5712 -.60
78 2458 0.000 472.835 2.458 108.39 107.59 .74 7.1382 7. 1778 -.55
78 2459 0.000 492.354 2.455 108.25 107.57 .64 7.71 19 7.7506 -,50
78 2460 0.000 512.363 2.452 108.11 107.54 .54 8.2936 8.3302 -,44
78 2461 0.000 532.459 2.449 107.98 107.50 .44 8.8719 8.9056 -.38
78 2462 0.000 551.517 2.446 107.85 107.46 .36 9.4157 9.4454 -.31
78 2463 0.000 570.948 2.443 107.72 107.42 .28 9.9653 9.9908 -.26
118
.
1 . A 8
0
2 95 31 3
9
2
5
Data sources and ID numbers: (l)Vlrial Equation, (2)Dawson, (3)Beattie, (4)Deschner, (5)Reamer,
(13)Cherney, ( 17)Toml inson, (24)Ely, (26)0ittmar, (XXXX)Haynes, ( 51 ,52)Thoma5, ( 78 )Te ichmann ,
(79)Warowny.
1 D Data we gnt 1
Temp Dens ty
êxpt '^ca 1 c Pressu
Po nti expt ca c 1 U 1 TT o U 1 r t .
No w
l\ mo /L / 3
kg/m-'
1
kg/ m'^ Mra MPa

1
% %
52 z4d4 1
1
AAA
UUU
. joy .oDU .800 35.28 TC OT AJ
.U T O
z. AA"7A
UU /y o A A oyl
Z.UUo4 AX
-.03
CO 1
1
AAA
.UUU J /J. DU 1 .800 35.28 c o~j
•
AJ
U X O
Z.UAT CA
j5U Z. AT CC
O -. AT
U3
KO 1
1
AAA
. UUU jyo • pu 1 .800 35.28 X R OA AC
.UD z. zjoy z. Zj /y A^
-.U4
CO z4d / 1
1
AAA
.UUU ÔX
4Zj. RA
3U 1
1 .800 35.28 c
J J. o^;
Ct)
Ayi
.U4
o /» TCC O A XCX
Z.4303 -. AT
U3
CO z4do 1
1
AAA
• UUU
AA Q
440. RA
3U 1
1 .800 35.28 AT
Uj
•
O eiX A
Z.Oj 14 \
Z.OjZU AO
-. uz
CO z4Dy 1
1
AAA
. UUU 4 /_) . 5U 1 .800 35.28 -. A
UUA Z. QO C"7
O oZ 5 /
O QO 5o
Z.oZ C^ AA
.uu
AAA T^TQ OCA
CO Z4 /U A
U.UUU joy .03U .800 35.28 XC 0"7 A"?
.Uj O AA"7Q
z.uu /y O AAQyl
Z.UUo4 -. AT
UJ
CO U. AAA
A ^"7T . 5U XC O"? AT O AT CA O AT CC -. AT
O/I "7 1 c;A
^:4 / UUU J /J
1
1 .800 35.28 -55. Z. 1 .Uj Z. UjI3U Z. UjD5 U3
CO A AAA 70Q
3yo . DUCA .800 35.28 T C ZD
O^^ AC o o T^^n
Z.Z3Dy O O T"7n AA
52 U.UUU 1
1 35. .U5 -.U4
CO
52 Z4 / J A AAA
U.UUU ylOT
4yc3. 5UA 1
1
c:
.800 35.28 TC O^^ AA
.U4 O AX Cyl
Z.4354 O T i^T
Z. 43d3
y1
-. Ad
U4
52 2474 0.000 A A O
44o. CA
5U 1
1 .800 35.28 V c 0"7 AO
.02 2.53 1
O £ T OA
2.5320 -.02
52 2475 0.000 473 . 50 1 .800 35.28 35. 28 -. 01 2.82 58 2.8256 .01
52 2476 1.000 498. 50 1 .800 35.28 35.29 -.02 3,0182 3.0 176 .02
52 2477 1.000 523. 1 50 .800 35.28 35.29 -.04 3.2096 3. 2083 .04
52 2478 1 .000 548. 1 50 .800 35.28 35.30 -.06 3.3998 3.3980 .05
52 2479 1 .000 573. 1 50 .800 35.28 35.30 -.08 3.5894 3.5868 .07
52 2480 1 .000 598. 1 50 .800 35.28 35.31 -. 1 3.7783 3.7748 .09
52 2481 1 .000 623. 1 50 .800 35.28 35.32 -. 1 3.9657 3.9621 . 1
52 2482 0.000 498. 1 50 .800 35.28 35.29 -.02 3.0183 3.0176 .02
52 2483 0.000 523. 1 50 .800 35.28 35.29 -.04 3.2095 3.2083 .04
52 2484 0.000 548. 1 50 .800 35.28 35.30 -.06 3.4001 3.3980 .06
52 2485 0.000 573 . 1 50 .800 35.28 35.31 -.08 3.5894 3.5868 .07
52 2486 0.000 598. 1 50 .800 35.28 35.31 -.10 3.7784 3.7748 . 10
52 2487 0.000 623. 1 50 .800 35.28 35.33 -. 1 5 3.9579 3.962 . 1
52 2488 1.000 359.850 1.000 44. 10 44.02 . 18 2.3808 2.5840 -.13

52 2489 1.000 373. 1 50 1.000 44. 10 44.01 .19 2.4161 2.4195 !4
52 2490 1 .000 398. 1 50 1.000 44.10 43.99 .23 2.5793 2.6843 1
52 2491 1 .000 423. 1 50 1.000 44. 10 44.00 .23 2.9371 2.9427 -. 19

A A ci cr\
52 2492 1 .000 448. 1
1 50 1.000 44. 10 44.00 .21 3. 908
1 3. 1955 -. 18
CO
2493 1 .000 473. 1 50 1.000 44. 10 44 .02 . 1 3.44 1 3.4472 -. 16
CO z4y4 1
1
AAA
.UUU A no
4yo. 1
1
CA
50 1.000 44. 10 44.03 .
1
1
c
5
T ^ AA T
3.5903 T A CT
3.6953 -. T 1
1
CO 2495 1
1
AAA
.000 COT
523. 1
1
CA
50 1.000 44. 10 44 .05 . 1 1 3.9372 3.94 1 -.10
CO ^490 1
1
AAA
.000 Cyl o
54o. 1
1
c
50 1.000 44. 10
A A A
44.07
"7 A1
.07 A
4. O OA
1
829
1 4. 1857 -.07
CO z4y / 1
1
AAA
.000 CTT
5/3. 1
150 CA
1.000 44.10 44.07 .05 4. 4265 4.4287 -.05
CO ^4yo 1
1
AAA
.UUU CAO
59o. 1 CA
1 50 1.000 44. 10 44. 09 AO
.Uz 4.5695 A C ~tf\C
4.5 /Oo -. A
02O
CO 2499 623. 1.000 44. 44.10 -.00 4.91 16 4.91 14
52 1.000 1 50 10 .00
CO 2500 .000 369.850 1.500 66. 65.84 .47 3.1210 3. 295 -.28
1 15 1
CO O CA 1
2501 .000 373. 50 66. 65.81 3. 1795 -.30
1 1 1.500 15 .51 3. 1 8 92
CO 1
1
AAA
. UUU
tCtO 1 CA 1.500 66. 1 5
CC
55. ~7T
73 £i O
.62 T C TO
3.51 32 1 T COO
3.528 7
"7 A T
-.43
CO O C AT
2503 1
1
AAA
.000 A^t
423. cr\
50 1
1 1.500 66. 15 65.74 .62 ilO
4.0344 A AC OA
4.0529 A C
-.45
CO 2504 .000 A A Q
448. CA 1
1.500 66. 65.77 .57 4.4470 4.4670 -.45
1 50 1 15
CO
52 2505 1.000 473. 50 1 1.500 66.15 65.82 .50 4.8537 4.8738 -.41
52 2506 1.000 498. 50 1 1.500 66. 15 55.86 .43 5.2557 5.2751 -.37
52 2507 1.000 523. 50 1 1.500 66.15 65.90 .37 5.6538 5.6721 -.32
52 2508 1.000 548. 150 1.500 66. 15 65.95 .29 6.0496 6.0656 -.25
52 2509 1.000 573.150 1.500 66.15 65.98 .24 6.4416 5.4561 -.22
52 2510 1.000 598.150 1.500 66. 15 66.02 .19 6.8318 5.8442 -.18
52 2511 1.000 623.150 1.500 66. 15 65.07 .12 7.2222 7.2302
52 2512 1.000 369.850 2.000 88. 19 87.72 .54 3.6258 3.5344 -.24
52 2513 1.000 373.150 2.000 88. 19 87.66 .60 3.7111 3.7215 -.28
52 2514 1.000 398. 150 2.000 88. 19 87.50 .79 4.3375 4.3574 -.46
52 2515 1.000 423.150 2.000 88.19 87.54 .74 4.9421 4.9667 -.49
52 2516 1.000 448.150 2.000 88.19 87.50 .58 5.5318 5.5591 -.49
52 2517 1.000 473.150 2.000 88.19 87.58 .58 5.1120 6.1399 -.45
52 2518 1.000 498.150 2.000 88.19 87.78 .47 6.6860 6.71 18 -.38
52 2519 1.000 523.150 2.000 88.19 87.87 .37 7.2538 7.2768 -.32
119
1 11 ,
(13)Cherney, ( 7)Tom nson , (24)Ely, {26)Dittmar, (XXXX)Haynes, ( 51 , 52 )Tiiomas, ( 78)Te ichmann
1 I i
(79)Warowny.
ID Data We ight Temp. Dens ty

i Density Dens ty i
êxpt ^ca c
1
Pressu
Point expt caic Diff. Diff.
No, K mo!/L kg/m-^ kg/m^ i MPa MPa %
52 2520 1.000 548.150 2,000 88'. 19 87.94 .28 7.8167 7.8363 -.25
52 2521 1.000 573. 150 2.000 88. 19 88.02 .19 8.3764 8.391 -.18
52 2522 1.000 598.150 2.000 88. 19 88.08 .13 8.9310 8.9421 -,12
52 2523 1.000 623. 150 2.000 88. 19 88.15 .05 9.4853 9.4896 -,05
52 2524 1.000 369,850 2.500 1 10.24 109.87 .34 3.9444 3.9484 -.10
52 2525 1.000 373, 150 2.500 1 10,24 109.73 .47 4.0591 4.0653 -.15
52 2526 1.000 398. 150 2o500 1 10,24 109.44 .73 4.8954 4.9130 -.36
52 2527 1.000 423. 150 2,500 1 10,24 109.52 .66 5.6994 5.7220 -.39
52 2528 1.000 448,150 2.500 110.24 109.65 .54 6.4842 6.5083 -.37
52 2529 uooo 473,150 2,500 110,24 109,79 .41 7,2567 7.2789 -.31
52 2530 1.000 498.150 2.500 110.24 109.93 .28 8.0199 8,0378 -.22
52 2531 1.000 523. 150 2,500 110.24 110.05 .17 8.7750 8.7877 -.14
52 2532 1.000 548.150 2,500 110.24 110.17 .06 9.5247 9.5301 -.06
52 2533 1.000 573.150 2.500 110.24 110.27 -.03 10.2688 10.2663 .02
52 2534 1.000 598.150 2.500 110.24 110.36 -.11 11.0080 10.9972 .10
52 2535 1.000 623.150 2.500 110.24 110.46 -. 19 1 .7452 1 11.7235 .18
52 2 536 1,000 369.850 3.000 132.29 132.30 -.01 4.1240 4.1240 .00
52 2537 1.000 373. 150 3.000 132.29 132.03 .20 4,2701 4.2720 -.04
52 2538 1.000 398.150 3.000 132.29 131.60 .53 5,3284 5.3404 -.22
52 2539 1.000 423.150 3,000 132.29 131.73 .42 6.3461 6.361 -.24
52 2540 1.000 448,150 3,000 132.29 131.92 .28 7.3417 7.3554 -.19
52 2541 1.000 473, 150 3,000 132,29 132.10 .15 8.3227 8.3317 -.11
52 2542 1,000 498.150 3,000 132.29 132.29 -.00 9.2945 9.2945 .00
52 2543 1oOOO 523.150 3,000 132,29 132,45 -.12 10.2570 10.2466 .10
52 2544 1,000 548.150 3,000 132,29 132.60 -.23 1 1.2133 11. 1901 .21
52 2545 1.000 573.150 3,000 132.29 132,72 -.32 12, 1623 12. 1262 .30
52 2546 1.000 598. 150 3,000 132.29 132,80 -.38 13.1034 13.0558 .36
52 2547 1,000 623.150 3,000 132,29 132,94 -.49 14.0474 13.9798 ,48
52 2548 1,000 369.850 3.500 154,34 154,88 -.35 4,2097 4.2084 .03
52 2549 1.000 373.150 3,500 154,34 154,34 ,00 4.3878 4.3878 -.00
52 2550 1.000 398.150 3.500 154,34 153.78 .37 5.6739 5.6819 -.14
52 2551 1,000 423. 150 3.500 154,34 153,99 .23 6.9174 6.9260 -, 12
52 2552 1,000 448.150 3,500 154.34 154,25 .06 8.1404 8.1434 -,04
52 2553 1.000 473. 150 3.500 154.34 154,49 -.10 9.3497 9.3427 .07
52 2554 1,000 498. 150 3.500 154.34 154.69 -.23 10.5481 10.5282 .19
52 2555 1,000 523.150 3.500 154.34 154,89 -.35 11.7390 11.7026 .31
52 2556 1,000 548, 150 3.500 154o34 155,07 -,47 12.9239 12.8676 .44
52 2557 1.000 573.150 3.500 154.34 155,20 -.55 14. 1002 14.0245 .54
52 2558 1.000 598.150 3.500 154.34 155,33 -.63 15.2713 15. 1742 .64
52 2559 1.000 623.150 3.500 154,34 155.47 -.73 16.441 16.3175 .76
52 2560 1.000 369.850 4.000 176.39 177.04 -.37 4.2404 4.2400 .01
52 2561 1.000 373.150 4.000 176,39 175.89 .28 4.4488 4.4499 -.02
52 2562 1.000 398.150 4.000 176,39 175.57 .47 5.9642 5.9746 -.17
52 2563 1.000 423,150 4.000 176.39 176.00 ,22 7.4470 7.4564 -.13
52 2564 1.000 448. 150 4.000 176.39 176.39 -.00 8.9157 8.9156 .00
52 2565 1.000 473,150 4.000 176.39 176.78 -.22 10.3773 10.3588 .18
52 2566 1.000 498.150 4.000 176.39 176.99 -,34 1 .8249 1 11.7893 .30
52 2567 1.000 523.150 4.000 176.39 177.23 -.48 13,2688 13.2093 ,45
52 2568 1.000 548.150 4.000 176.39 177.43 -.59 14.7061 14.6201 .59
52 2569 1.000 573.150 4.000 176.39 177.59 -.68 16.1355 16.0225 .71
52 2570 1,000 598.150 4.000 176.39 177.74 -.76 17.5605 17.4173 .82
52 2571 1,000 623.150 4.000 176.39 177.89 -.84 18.9818 18.8050 .94
52 2572 1.000 369.850 4.500 198.44 195.20 1.66 4.2467 4.2470 -.01
52 2573 1.000 373.150 4.500 198.44 195.26 1.63 4.4815 4.4859 -.10
52 2574 1,000 398. 150 4.500 198.44 196.62 .93 6.2288 6.2518 -.37
52 2575 1.000 423.150 4.500 198.44 197.57 .44 7.9697 7.9914 -.27
120
1 1 1 1
Data sources and ID numbers: (l)Virial Equation, (2)Dawson, (3)Beattie, (4)Deschner, (5)Reamer
(13)Cherney, ( 7 )Tom nson , (24)Ely,
1 I i 26)D ttmar ( i , (XXXX)Haynes , ( 51 52)Thonrias ( 78)Te ichmann
, , ,
(79) Warowny.
ID Data We ight Temp. Dens ity Dens ty i Dens ty i

'êxpt '^ca 1 c Pressur
Point expt ca c 1 Diff, Diff.
No. K mol/L kg/tTK kg/m-' d MPa MPa
-
/» %
52 2576 1.000 448. 150 4.500 198.44 198. 17 ,14 9,7057 9,7 160 -.1 1
52 2577 1.000 473. 150 4.500 198.44 198.67 -.12 1 1.4409 1 1.4290 .10
52 2578 1.000 498 . 50 1 4.500 198.44 199.03 -.30 13. 1699 13. 1321 .29
52 2579 1.000 523. 50 1 4.500 198.44 199.31 -.44 14.8935 14.8260 ,46
52 2580 1.000 548. 150 4.500 198.44 1 99 . 58 -.57 16.6146 16.51 14 .63
52 2581 1.000 573.150 4.500 198.44 199,77 -.67 18.3266 18.1886 .76
52 2582 1.000 598. 150 4.500 198.44 199.95 -.76 20.0345 19.8581 .89
52 2583 1.000 623. 150 4.500 198.44 200.11 -.84 21.7373 21.5199 1.01
52 2584 0.000 369.850 5.000 220.49 0.00 0.00 4.2471 4.2475 -.01
52 2585 OcOOO 373.150 5.000 220.49 212.08 3.96 4,5040 4,5152 -.25
52 2586 0.000 398 . 50 1 5.000 220.49 216.99 1.61 6,4948 6.5427 -.73
52 2587 1.000 423. 150 5.000 220.49 218.71 .81 8.5190 8.5677 -.57
52 2588 1.000 448. 150 5.000 220.49 219.69 .36 10.5551 10.5885 -.32
52 2589 1.000 473.150 5.000 220.49 220.34 .07 12.5957 12.6038 -.06
52 2590 1.000 498. 150 5.000 220.49 220.82 -. 15 14.6367 14.6128 .16
52 2591 1.000 523. 150 5.000 220.49 221.20 -.32 16.6766 16.6148 .37
52 2592 1.000 548.150 5.000 220.49 221.51 -,46 18.7128 18.6095 ,56
52 2593 1.000 573.150 5.000 220.49 221 .76 -,58 20.7449 20.5964 .72
52 2594 1.000 598.150 5.000 220.49 221.96 -,66 22.7683 22.5754 .85
52 2595 1.000 623.150 5.000 220.49 222. 17 -,76 24.7930 24.5465 1.00
52 2596 0.000 369.850 5.500 242.53 235.74 2.88 4.2476 4.2481 -.01
52 2597 0.000 373. 150 5.500 242.53 230.75 5,1 1 4.5295 4.5479 -.40
52 2598 0.000 398 . 150 5.500 242.53 237.86 1.97 6.7960 6.8693 -1.07
52 2599 1.000 423. 150 5.500 242.53 240.07 1.03 9. 1393 9.2164 -.84
52 2600 1.000 448. 150 5.500 242.53 241.26 .53 11.51 15 1 1.5721 -.52
52 2601 1.000 473. 150 5.500 242.53 242.05 .20 13.8985 13.9296 -.22
52 2602 1.000 498. 150 5.500 242.53 242.61 -.03 16.2915 16.2850 .04
52 2603 1.000 523. 150 5.500 242.53 243.04 -.21 18.6861 18.6361 .27
52 2604 1.000 548. 150 5.500 242.53 243.40 -.35 21 .0802 20.981 .47
52 2605 1.000 573. 150 5.500 242.53 243.67 -.47 23.4690 23.3188 .64
52 2606 1.000 598. 150 5.500 242.53 243.89 -.56 25.8510 25.6486 .79
52 2607 1.000 623. 150 5.500 242.53 244.1 -.65 28.2330 27.9699 .94
52 2608 0.000 369.850 6.000 264 . 58 261 .67 1.11 4.2564 4.2593 -.07
52 2609 0.000 373. 150 6.000 264.58 255.97 3,36 4.5749 4.5986 -.52
52 2610 0.000 398.150 6.000 264 . 58 259.96 1,78 7. 1710 7.2507 -1 .23
52 261 1.000 423. 150 6.000 264.58 262.06 ,96 9.8831 9.9777 -.95
52 2612 1.000 448. 150 6.000 264.58 263.26 .50 12.6421 12.7167 -.59
52 2613 1.000 473. 150 6.000 264.58 264.04 ,21 15.4241 15.4650 -.26
52 2614 1.000 498.150 6.000 264.58 264.58 ,00 18.2157 18.2159 -.00
52 2615 1.000 523. 150 6.000 264.58 265.02 -.17 2 1 . 0 48
1 20.9648 .24
52 2616 1.000 548.150 6.000 264.58 265,37 -.30 23.8137 23.7088 .44
52 2617 1.000 573. 150 6.000 264.58 265.64 -.40 26.6083 26.4460 ,61
52 2618 1.000 598. 150 6.000 264.58 265,88 -.49 29.3984 29. 1748 .77
52 2619 1.000 623. 150 6.000 264.58 266.08 -.56 32. 1819 31 .8943 ,90
52 2620 1.000 369.850 6.500 286.63 284,42 .78 4.3046 4.3135 -.21
52 2621 1.000 373.150 6.500 286.63 282.13 1.60 4.6751 4.7038 -.61
52 2622 1.000 398. 150 6.500 286,63 283.07 1.26 7.6783 7.7722 -1 .21
52 2623 1.000 423.150 6.500 286.63 284,60 .71 10.8232 10.9201 -.89
52 2624 1.000 448.150 6.500 286.63 285.62 .35 14.0320 14. 1022 -.50
52 2625 1.000 473. 150 6.500 286.63 286,28 .12 17.2683 17.3007 -. 19
52 2626 1.000 498. 150 6.500 286.63 286,72 -.03 20.5151 20.5054 .05
52 2627 1.000 523 . 150 6.500 286.63 287, 12 -, 17 23.7767 23.7102 .28
52 2628 1.000 548. 150 6.500 286.63 287,39 -,26 27.031 26.9107 .45
52 2629 1.000 573. 150 6.500 286.63 287,71 -,38 30.2999 30. 1040 .65
52 2630 1.000 598.150 6.500 286.63 287,89 -,44 33.5433 33.2881 .77
52 2631 1.000 623.150 6.500 286.63 288,06 -,50 36,7846 36.4616 .89
121
1 7 7 7
5
(13)Cherney, ( 17)Toml inson, (24)Ely, (26)Dittmar, (XXXX)Haynes , (51 ,52)Thomas, (78)Teichmann,
(79)Warowny.
1 D Data Weight Temp, Dens ty i Dens ty i Dens ty i

'êxpt ^ca c1
Pressui
Po nt
i expt ca c 1 U 1 TT , U 1 t T ,
No. K mo /L1 Kg/m-^ Kg/m^ % Mra MPa %
52 2632 1.000 369.850 7.000 308.68 307.00 ,55 4.4573 4,4755 -,4 1
52 2633 1.000 373. 150 7.000 308.68 306. 19 ,81 4.8957 4.9303 -, 70
52 2634 1.000 398. 150 7.000 308.68 306.35 ,76 8.4013 8.4904 -1 ,05
52 2635 1.000 423. 150 7.000 308.68 307.33 .44 12.0598 12. 1455 -,71
52 2636 1.000 448. 150 7.000 308.68 308.09 ,19 15.7907 15,8436 -,33
52 2637 1.000 473. 150 7.000 308.68 308.61 ,02 19. 5549 19, 5630 -,04
52 2638 1.000 498. 150 7.000 308.68 308.97 -.09 23.3317 23,2910 . 1
52 2639 1.000 523. 150 7.000 308.68 309.23 -, 18 27. 1 102 27,0197 ,34
52 2640 1.000 548. 150 7.000 308.68 309.47 -.26 30,8952 30.7437 .49
52 2641 1.000 573. 150 7.000 308.68 309.74 -.34 34.6896 34.4593 .67
52 2642 1.000 598. 150 7.000 308.68 309.90 -,39 38.4597 38, 1639 .78
52 2643 1.000 369.850 7.500 330.73 329.49 ,37 4.8221 4,8512 -.60
52 2644 1.000 373. 501 7.500 330.73 329.22 ,46 5.3442 5,3857 -.77
52 2645 1.000 398. 150 7.500 330.73 329.36 .42 9.4625 9,5405 -.82
52 2646 1.000 423.150 7.500 330.73 330.03 ,21 13.7340 13,7944 -.44
52 2647 1.000 448. 150 7.500 330.73 330.42 ,09 18.0595 18,0953 -.20
52 2648 1.000 473. 150 7.500 330.73 330.87 -.04 22.4403 22,4191 .09
52 2649 1.000 498. 150 7.500 330.73 331 . 13 -, 12 26.8214 26,7514 .26
52 2650 1.000 523.150 7.500 330.73 331.34 -. 18 31.2082 31.0832 .40
52 2651 1.000 548. 150 7.500 330.73 331 .50 -.23 35.5902 35.4082 .51
52 2652 1.000 573.150 7.500 330.73 33 . 72
1 -.30 39.9842 39.7222 ,66
52 2653 1.000 369.850 8.000 352.78 351 .87 ,26 5.5551 5.5955 -,72
52 2654 1.000 373.150 8.000 352.78 351 .84 ,27 6. 1798 6.2259 -,74
52 2655 1.000 398. 150 8.000 352.78 352.00 .22 1 1 .0271 1 1 .0931 -,59
52 2656 1.000 423. 150 8.000 352.78 352.42 .10 16.0100 16.0528 -,27
52 2657 1.000 448. 150 8.000 352.78 352.79 -.00 21 .0590 21 .0572 .01
52 2658 1.000 473. 1 50 8.000 352.78 353.03 -.07 26. 1301 26.0818 .19
52 2659 1.000 498. 150 8.000 352.78 353.20 -.12 31 .2060 31.1118 .30
52 2660 1.000 523. 1 50 8.000 352.78 353,34 -. 16 36.2829 36. 1374 .40
52 2661 1.000 369.850 8. 500 374.83 374,05 .21 6,8600 6.9189 -.85
52 2662 1.000 373. 501 8.500 374.83 374, 16 . 18 7,6085 7,6628 -.71
52 2663 1.000 398. 1 50 8. 500 374.83 374,51 .09 13,3324 13.3719 -.30
52 2664 1.000 423. 1 50 8.500 374.83 374,65 .05 19. 292 1 19. 583 1 -, 1
52 2665 1.000 448. 1 50 8. 500 374.83 374,73 .02 24.961 24.9806 -,08
52 2666 1.000 473. 1 50 8. 500 374.83 375. 10 -.07 30.8828 30.81 56 ,22
52 2667 1.000 498. 1 50 8.500 374.83 375. 19 -. 10 36.7519 36.6491 ,28
52 2668 1.000 369.850 9.000 396.87 396,40 .12 9.0356 9.0937 -.64
52 2669 1.000 373. 501 9.000 396.87 396.43 . 1 9.9131 9.9700 -.57
52 2670 1.000 398. 150 9.000 396.87 396.94 -.02 16.6730 16.661 .07
52 2671 1.000 423. 150 9.000 396.87 396.82 ,01 23.3965 23,4083 -.05
52 2672 1.000 448. 150 9.000 396.87 396.98 -,03 30.2048 30. 1757 . 10
52 2673 1.000 473. 150 9.000 396.87 397. 10 -,06 37.0155 36.9435 . 19
52 2674 1.000 369.850 9.500 418.92 418.79 ,03 12.4364 12.4614 -.20
52 2675 1.000 373. 150 9.500 418.92 418.99 -.02 13.5032 13.4902 ,10
52 2676 1.000 398. 150 9.500 418.92 418,85 ,02 21 .2979 21 .3154 -,08
52 2677 1.000 423. 150 9.500 418.92 418.98 -.01 29. 1850 29.1674 ,06
52 2678 1.000 448.150 9.500 418.92 418.99 -.02 37.0435 37.0195 .06
52 2679 1.000 369.850 10.000 440.97 440.96 .00 17.4363 17.4398 -.02
52 2680 1.000 373. 150 10.000 440.97 440.91 ,01 18.6257 18.6426 -.09
52 2681 1.000 398.150 10.000 440.97 441.11 -,03 27.8096 27.7624 ,17
52 2682 1.000 423.150 10.000 440.97 441.25 -.06 36.9863 36,8764 .30
52 2683 1.000 369.850 10.500 463.02 463,22 -.04 24,6078 24.5320 ,31
52 2684 1.000 373.150 10.500 463.02 463,28 -.06 26,0340 25.9316 ,39
52 2685 1.000 398.150 10.500 463.02 463,33 -.07 36,6584 36.5180 ,38
52 2686 1.000 369.850 1 1.000 485.07 485.50 -.09 34.5614 34.3368 .65
52 2687 1.000 373.150 1 1.000 485.07 485.54 -.10 36,2066 35.9576 .69
122
. 1
Table 8. Comparisons of data for ideal gas functions with eq (7).
Propane ideal gas functi from Chao, et a I . [131
Temp. C°/R Diff (H° )/RT Diff. S°/R Diff.

K expt. ca c.
I
i expt. cal c. % expt. cal c. %
50.000 4.096 4.084 .296 4.014 4.013 .024 22.353 22.355 -.009
100.000 4.967 4.987 -.409 4.254 4.254 -.001 25.433 25.433 -.001
150.000 5.868 5.854 .230 4.645 4.647 -.045 27.622 27.625 -.010
200.000 6.743 6.730 .201 5.059 5.056 .066 29.429 29.426 .01
273.150 8.268 8.289 -.250 5.707 5.706 .017 31 .749 31 .746 .008
298. 150 8.852 8.874 -.246 5.946 5.947 -.016 32.498 32.497 .004
300.000 8.892 8.917 -.285 5.964 5.965 -.017 32.549 32.552 -.010
400.000 1 .308
1 11.297 .089 6.998 7.002 -.047 35.442 35.444 -.006
500.000 13.542 13.519 .170 8.088 8.087 .01 1 38.210 38.208 .004
600.000 15.479 15.477 .014 9.162 9.159 .033 40.852 40.850 .004
700.000 17.160 17. 172 -.070 10.138 10.186 .019 43.368 43.367 .003
800.000 18.614 18.634 -.103 1 1 . 1 52 1 1 . 1 53 -.006 45.758 45.757 .002
900.000 19.888 19.898 -.050 12.054 12.056 -.017 48.023 48.027 -.008
1000.000 21.000 20.996 .016 12.894 12.896 -.015 50. 182 50. 182 .000
1100.000 21.971 21 .957 .063 13.677 13.677 -.003 52 . 2 30 52.229 .002
1200.000 22.821 22.803 .081 14.404 14.403 .005 54. 177 54. 176 .002
1300.000 23.556 23.552 .018 15.080 15.079 .010 56.034 56.032 .005
1400.000 24.200 24.219 -.076 15.709 15.708 .007 57.801 57.802 -.002
1500.000 24.764 24.816 -.210 16.294 16.296 -.008 59.491 59.494 -.003
Number of points = 19, rms deviation for C? = 0.19 rms deviation for H = 0.03?; rms deviation for
S° = 0.006?.
ji
123
6 ,
Propane ideal gas specific heats
Data sources and ID numbers: (2)A.P.I.44, (3)Beeck, (4)Sage, ( 5 )K i st akowsky/Lacher

i
(6)Kistiakowsky/Rice, (7)Dailey, (8)Ernst, (9)Rossini.
ID Temp. C°/R Diff.

K expt. calc %
2 100.000 4.952 4.987 -.72

2 298.150 8.842 8.874 -.36
2 700.000 17.210 17.172 .22
2 1000.000 21 .050 20.996 .26
3 273.150 7.770 8.289 -6.68
3 373.150 10.135 10.665 -5.23
3 473.150 12.420 12.947 -4.24
3 573.150 14.433 14.978 -3.78
4 294.300 8.81 7 8.783 .39
4 310.900 9.088 9. 177 -.97
4 327.600 9.350 9.576 -2.42
4 344.300 9.617 9.976 -3.74
4 360.900 9.893 10.374 -4.85
4 377.600 10.165 10.771 -5.96
4 394.300 10.432 1 .164
1 -7.02
4 410.900 10.704 11.551 -7.91
4 427.600 10.970 1 .934
1 -8.78
4 444.300 1 1 .242 12.311 -9.51
5 148.200 5.883 5.825 .99
5 157.800 6.059 5.983 1 .26
5 213.100 7.045 6.986 .85
5 219.000 7.131 7.105 .37
5 258.000 7.926 7.944 -.22
6 272.380 8.037 8.271 -2.92
6 300.370 8.796 8.926 -1 .47
6 334.050 9.642 9.731 -.92
6 368.550 10.487 10.556 -.65
7 334.700 9.878 9.746 1 .34
7 360.100 10.236 10.354 -1 .16
7 387.800 10.875 1 1 .012 -1 .26
7 452.600 12.61 12.496 .95
7 521 .000 14.035 13.953 .59
7 562.000 14.644 14.765 -.83
7 603.300 15.479 15.537 -.37
7 693.200 16.918 17.065 -.86
8 293.150 8.740 8.755 -.17
8 313.150 9.154 9.230 -.83
8 333.150 9.658 9.709 -.53
8 353.150 10.151 10.188 -.37
9 338.706 9.840 9.842 -.03
9 352.594 10.186 10.175 .11
9 366.483 10.528 10.507 .20
9 380.372 10.869 10.836 .30
9 394.261 11 .206 1 1 .163 .38
9 408.150 11 .537 1 1 .487 .43
9 422.039 1 1 .857 1 1.807 .42
124
1 8
2
2
1 1 . n •
Table 9. I nterpo ated I ideal gas functions from eq ( 7 )
S°
K J /mot J/mo 1 J/(mol 'K) J/(mol 'K) J/( mo 1
80 2076.0 2741 .1 202.599 29.75 38.07

90 2382. 3130.4 207. 82 1 31 .48 39.79
100 2705.3 3536.8 21 1 .461 33.15 41 .47
110 3044.8 3959.4 21 5.488 34.73 43.04
120 3399.6 4397.3 21 9.297 36.21 44.53
130 3768.9 4849.7 222.91 37.63 45.94
140 4152.0 531 6.0 226.373 39.00 47.31
150 4548.8 5796.0 229.683 40.36 48.67
160 4959.3 6289.6 232.868 41 .73 50.05
170 5383.5 6797.0 235.944 43.1 3 51 .45
180 5822.1 7318.7 238.925 44.58 52.90
190 6275.3 7855.1 241 .825 46.08 54.40
200 6743.9 8406.8 244.654 47.64 55.95
210 7228.3 8974.3 247.423 49.25 57.57
220 7729.2 9558.3 250.139 50.93 59.24
230 82 47 .0 101 59.3 252.81 52.65 60.97
240 8782.4 10777.8 255.443 54.43 62.74
250 9335.7 11414.3 258.041 56.25 64.56
260 9907.4 12069.1 260.609 58.1 66.42
270 10497.9 12742.8 263.1 51 60.00 68.31
280 1 1107.5 13435.5 265.670 61 .92 70.23
290 1 1736.4 141 47.5 268.168 63.86 72.18
300 12384.8 14879.1 270.648 65.83 74.1 4
310 13053.0 15630.4 273. 1 1 67.80 76. 1 2
320 13740.9 16401 .5 275.560 69.79 78.
330 14448.8 17192.5 277.994 71 .78 80.1 0
340 151 76.6 18003.5 280.414 73.78 82.09
350 15924.3 18834.4 282.823 75.77 84 .08
360 16692.0 1 9685.1 285.219 77.76 86.07
370 17479.4 20555.7 287.605 79.74 88.05
380 18286.7 21446.1 289.979 81 .71 90.02
390 191 13.6 22356.2 292.343 83.67 91 .98
400 19960.0 23285.8 294.696 85.62 93.93
410 20825.9 24234.7 297.039 87.55 95.86
420 21 710.9 25203.0 299.372 89.46 97.78
430 2261 5.1 261 90.3 301 .695 91 .36 99.68
440 23538.1 27196.4 304.008 93.24 101 .56
450 24479.9 28221 .3 306.31 95.1 0 103.42
460 25440.1 29264.7 308.605 96.94 105.26
470 26418.6 30326.4 31 0.888 98.76 107.07
480 27415.2 31406.1 31 3. 161 100.56 108.87
490 28429.7 32503.7 315.424 102.33 110.65
500 29461 .8 33619.0 317.677 104.09 112.40
510 3051 .3 1 34751 .6 319.920 105.82 114.13
520 31578.0 35901 .5 322.1 53 107.52 115.84
530 32661 .7 37068.3 324.375 109.21 1 1 7.52
540 33762.1 38251 .9 326.588 110.87 119.19
550 34879.1 39451 .9 328.790 112.51 120.82
560 36012.3 40668.3 330.981 114.13 122.44
570 37161 .5 41900.7 333.163 115.72 124.04
580 38326.6 43148.9 335.334 117.29 125.61
590 39507.3 44412.8 337.494 118.84 127.16
600 40703.4 45692.0 339.644 120.37 128.68
610 41914.6 46986.3 341 .783 121 .87 130.19
620 431 40.7 48295.6 343.91 123.36 131 .67
630 44381 .6 49619.7 346.031 124.82 133.13
640 45637.0 50958.2 348.139 126.26 134.57
650 46906.7 5231 1 .0 350.236 127.67 135.99
125
, 7 1 1 01
1
Table 10. Comparisons of heat of vaporization data with

eq (9).
Data sources and ID numbers; (l)Dana (2)Kemp, (3)Sage, (4)Staveley, ,
(5 He geson
) 1
(6)Yesavage, (7)Carruth, (40)Thermal Loops, (4 )C apeyron 1 1
.
ID Weight Temp. Heat of Vapor zat on

i i Dif f
K kj/mo %
expt. ca c. 1
40 1 .000 85.470 24.824 24.841 -. U /

40 .999 90.000 24.622 24.628 _ no
40 .997 95.000 24.401 24.398 Cl 1
40 .995 100.000 24. 183 24. 172 .U4

40 .993 105.000 23.967 23.952 .Ud
40 .992 1 0.000
1 23.754 23.735 .Uo
7 .991 110.946 23.719 23.695 . 1
40 .990 1 5.000
1 23.544 23.522 .09
7 .988 118.342 23.391 23.382 .04
23.335 23.313 AA
40 .988 120.000 .09
40 .986 125.000 23. 129 23. 107 .09
7 .985 125.739 23.068 23.077 -.04
40 .983 130.000 22.925 22.904 .09
7 .982 133. 135 22.770 22.778 -.03
40 .981 135.000 22.722 22.703 .08
40 .979 140.000 22.520 22.504 .07
7 .979 140. 532 22.460 22.483 -. 10
40 .976 145.000 22,320 22.307 .06
7 .975 147.928 22. 182 22. 192 -.05
40 .974 150.000 22. 121 22. 1 1 .05
40 .97 1 155.000 21.923 21.916 .03
7 .971 155.324 21 .887 21.903 -.07
40 .969 160.000 21 .725 21.721 .02
7 ,967 162.721 21 .631 21.616 ,07
40 .966 165.000 21 .528 21 .527 ,01
40 .963 170.000 21.331 21.332 -.0
7 .963 170. 1 1 21.326 21.328 -,01
40 .960 175.000 21.133 21.137 -.02
7 .958 177.514 20.989 21.038 -.23
40 .956 180.000 20.935 20.940 -.03
7 .9 53 184.910 20.745 20.746 -.00
40 .953 185.000 20.736 20.742 -.03
A"2
40 .949 190.000 20.536 20.543 -.03
7 .947 192.306 20.459 20.450 A c;
40 .945 195.000 20.334 20.340 -.03
7 .942 199.703 20.144 20. 148 AO
40 .941 200.000 20.129 20.135 A
-.03
40 .937 205.000 19.922 19.927 AT
-.03
0.000 207.099 20.014 oo
7 19.839 •oo
40 .933 210.000 19.712 19.716 AO
-.02
7 .928 214.496 19.504 19.522 AA
- .(jy
40 .928 21 5 » 000 19.498 19.500 A
-.01 1
40 .923 220.000 19.280 19.279 .0

7 .921 221 .892 19.189 19. 194 -.03
40 .917 225.000 19.057 19.053 ,02
7 .912 229.288 18.857 18.855 .01
40 .912 230.000 18.830 18.822 .04
40 .910 23 ,000 1 18.783 18.775 ,04
7 .903 236.685 18.500 18.503 -.02
41 -.998 90.000 24.562 24.628 -,27
41 .995 100.000 24. 157 24. 172 -.06
41 .991 1 10.000 23.744 23.73 5 ,04
41 .986 120.000 23.328 23,313 ,06
41 .982 130-000 22.914 22,904 ,04
41 .977 140.000 22.504 22,504 -.00
41 .971 150.000 22. 100 22, 11 -,05
41 .965 160.000 21 .703 21.721 -.08
41 .959 170.000 21.310 21,332 -,10
41 .951 180.000 20.918 20,940 -,10
41 .944 190.000 20.525 20,543 -,09
41 .935 200.000 20,124 20,135 -.06
41 .925 210.000 19,713 19,716 -.01
41 .914 220.000 19.285 19,279 .03
125
1 , . y 1 / . , 8

Data Sources and ID numbers: (l)Dana, (2)Kemp, (3)Sage, (4)Staveley,
(5) Hel geson (6)Yesavage, (7)Carruth, (40)Thermal Loops, (4 C apeyron 1 ) 1
1 U We 19''' Temp Heat of Vapor zation i Di ff

K kj/mo %
expt. ca c 1
41 .902 230.000 1 0 . 0J / 1 ft ft99 Oft
41 .888 240.000 1 ft "^fi? 1ft ^dn 19

41 .872 250.000 17 ft'iR 1
1 /
R9Q
7 %0 iLy 1A
41 .853 260.000 17 1 n 17 9H'^
41 .831 270.000 16.720 16.696 .14
41 .805 280.000 15.078 15.062 .10
41 .774 290.000 15.377 15.372 .04
41 .736 300.000 14.608 14.514 -.04
41 .687 Tin c\r\ f\
31 0.000 13.757 13.775 -. 13
T~i r\r\r\
r\
41 .625 320.000 12.808 12.834 -.20
A "21 r\ r\r\r\
4 1
.541 330. 000 11.733 11.760 -.23
~iA r\
r\r\r\
41 .426 340.000 10.480 10.499 -.19
41 .264 350. 000 8.941 8.946 -.05
A 1 ic r\ r\ r\r\
350.000 6.821
41 .052 5.805 .22
1 0.000 234.070 1ft d4i 1ft fi9Q 1 n 1
1 0.000 237.750 1 ft 4 S 1 99
1 0.000 241 .830 1 ft 949 1ft 94Q
1 0.000 247.100 17 ft7'^ 1
1
QR 1
7 •yO 1
- fin
1 0.000 253.740 17 ft 1 Q 17 fi9Q 1

1 . uo
nft
1 0.000 261 .210 1 7 .397 17.214

1 0.000 269. 100 16.855 16.751 .58
1 0.000 275.420 15.330 15.359 - 1
1 0.000 279.890 16.524 16.069 2.83

1 0.000 281.8 50 15.814 15.939 -.78
1 0.000 285.530 15.738 15.588 .32
1 0.000 287.150 15. 795 15.575 1 .41
1 0.000 292.200 15.355 15.211 .95
1 0.000 292.700 15.595 15. 174 2.78
2 0.000 231.090 18.780 18.771 .05
3 0.000 312.817 13.527 1 3. 521 .78
3 0.000 312.983 13.649 13.505 1.06
3 0.000 316.206 13.360 13.204 1.18
3 0.000 315.372 13.551 13. 189 2.75
3 0.000 316.483 13.551 13. 178 2.83
3 0.000 315.539 13.282 13. 173 .83
3 0.000 318.928 13.171 12.940 1 .78
3 0.000 320.983 13. 127 12.735 uo
. nft
'^4
3 0.000 321. 150 12.718
3 0.000 327.983 1 2. 284 1 .989 1 2.45
3 0.000 328.094 12.224 1 .977 1 2.07
3 0.000 335.594 1 .297 1 1 .082 1 1 Q4
3 0.000 335.650 1 1 "^44 11 n7s 9 4^^
3 0.000 345.706 1 n 9ns S 54

3 0.000 346.039 in 1 ftft Q ftn7 n4
D . UH
3 0.000 348.150 Q f=i4ft y . 4 1 S
4 0.000 185.000 9n fion 90 749 - 9S
4 0.000 213.200 1 Q fifin 1 Q 'i7ft 49
5 0.000 310.928 13.651 13.592 -.30
5 0.000 322.039 1 2.592 12.627 - 9ft
5 0.000 327.594 1
1
1
1 . QftQ
yO 19 n'^'^ -. _J D
""ifi
5 0.000 330.372 11 1 9 11 7 17 - .oy

ftQ
6 0.000 231 .094 18.778 10./77/

IR 11
• n4
u^
6 0.000 253.206 17 4ft 1 17 on 1 9ft
6 0.000 285.928 IS I'Â 47

6 0.000 301.317 14
I
517
H . ij 1 / 1 4 .508 .75
6 0.000 313.428 13.633 13.465 1 .25
6 0.000 323.428 12.649 12.483 1.33
6 0.000 331 .817 1 .624 1 11.547 .67
6 0.000 339.483 10.578 10.570 .07
6 0.000 345.205 9.512 9.581 -.72
6 0.000 352.428 8.405 8.500 1.12
6 0.000 358.039 7.216 7.304 1.20
6 0.000 363.372 5.873 5.787 1.49
6 0.000 357.039 4.449 4,198 5.99
Number of data points used in fit = 76; rms deviation = 0.083?.
127
.
Table 11. Enthalpies of saturated liquid propane from

eq (10).
Temp. Ha' (eq (10)) Di ff

K J /mo 1 J /mo 1
%
90.00 391.6 391 .5 .018

100.00 1253.4 1253.4 -.003
110.00 2113.2 2113.3 -.004
120.00 2973.0 2973.0 .000
130.00 3834.6 3834.5 .003
140.00 4700.4 4700.3 .002
150.00 5572.6 5572.6 .000
160.00 6453.6 6453.7 -.001
170.00 7345.6 7345.7 -.001
180.00 8250.5 8250.7 -.002
190.00 91 70.5 9170.5 -.000
200.00 10106.9 10106.8 .001
210.00 11061 .1 11060.9 .002
220.00 12034.5 12034.3 .002
230.00 13028.3 13028.2 .001
240.00 14043.7 14043.9 -.001
250.00 5082.5
1 15082.6 -.001
260.00 161 45.6 161 45.9 -.002
270.00 7235.5
1 17235.6 -.000
280.00 18354.0 18353.9 .000
290.00 19504.4 19504.1 .002
300.00 20690.5 20690.3 .001
310.00 21918.3 21918.2 .000
320.00 23196.1 23196.4 -.001
330.00 24537.1 24537.6 -.002
340.00 25963.5 25963.4 .000
350.00 2751 7.5 27516.8 .002
360,00 29314.7 29315.0 -.001
369.85 33082.2 33082.2 0.000
Number of points = 28; rms deviation = 0.004|.
Derived from idea! gas functions, the equation of state, and the formulated
heats of vaporization.
128
1 1 J
11 ; 5/
1
Table 12. Entropies and specific tieats of saturated liquid

propane from eq (11).
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290.00 195.544 195.543 .001 114.87

300.00 199.496 199.495 .001 118.33
310.00 203.440 203.439 .001 122.41
320.00 207.401 207.401 -.000 127.39
330.00 21 .412 1 21 1.415 -.001 133.79
340.00 215.532 215.533 -.001 142.79
350.00 219.870 219.867 .002 157.85
360.00 224.725 224.727 -.001 194.14
369.85 234.726 234.726 0.000
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^ Derived from ideal gas functions, equation of state, and formulated heats
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135
1 : 5 w .
Table 14. Comparisons with saturated liquid specific heats.
sources and 1 D numbers (l)Dana, (2)Kemp, (8)Cut-ler, (30)Yesavage, (XXX) Good n.
ID Weight Temp. Cq, J/(mol»K) Di f f

K expt ca c 1
%
106 1 .000 85.598 83.95 84.10 -.17

239 1 .000 85.723 83.83 84.10 -.32
240 1 .000 86.395 83.93 84. 13 -.24
107 1 .000 86.622 84.29 84.14 .17
201 1 .000 86.763 84.32 84 . 1 .20
108 1 .000 86.836 83.81 84.15 -.41
241 1 .000 87.064 84.04 84.16 -.15
109 1 .000 87.856 84.15 84.20 -.06
242 1 .000 87.870 84.33 84.20 .15
110 1.000 88.871 84.1 7 84.25 -.09
243 1 .000 88,931 84.28 84.25 .03
2 1.000 89.720 84.55 84.29 .31
1 1 1 .000 89.379 84,48 84.30 .22
30 1 .000 90.000 34.04 84,30 -.31
202 1 .000 90.366 84.53 84.32 .25
8 1 .000 91,060 83.97 34.35 -.45
112 1 .000 91 .366 84.54 84.37 .20
113 1 .000 93.321 84.73 84.46 .32
8 1 .000 93.430 84.22 84.47 -.29
203 1 .000 95.166 84.78 84.55 .27
2 1 .000 95.530 84.76 84.57 .22
114 1 .000 95.750 84.73 84.58 .18
8 1 .000 95.760 84.48 84.58 -.13
8 1 .000 98.060 84.14 84.70 -.66
115 1 .000 99,797 84.94 84.79 .18
30 1 .000 100.000 34.86 84.80 .07
8 1 .000 100.330 84.06 84.81 -.89
204 1 .000 101.406 85.10 84.87 .27
2 1 .000 101 .960 85.09 84.90 .22
8 1 .000 102.570 84.73 84.93 -.24
116 1 .000 104.646 85.25 85.04 .24
8 1 .000 104.780 85.06 85.05 .01
205 1 .000 108.461 85.43 85.25 .21
2 1 .000 108.500 85.43 85,26 .20
30 1 .000 1 10.000 85.85 85.34 .60
117 1 .000 1 10.300 85.53 85.36 .20
2 1 .000 1 15.160 85.30 85.64 .19
206 1 .000 115.393 85.79 85.66 .16
1 18 1 .000 116.889 85.81 85.75 .08
30 1 .000 120.000 86.72 85.94 .91
2 1 .000 121 .970 86.18 86.06 .14
207 1 .000 122.132 86.18 86.07 .12
119 1 .000 124.009 86.20 86.19 .01
208 1 .000 128.738 86.51 86.51 -.00
2 1 .000 128.900 86.56 86.52 .04
30 1 .000 130.000 87.42 86.60 .95
120 1 .000 131 .003 86.69 86.67 .03
209 1 .000 135.238 86.92 86.97 -.06
2 1 .000 135.950 87.23 87.02 .23
121 1.000 137.870 87.14 87.17 -.03
136
1 , .
sources and ID numbers: (l)Dana, (2)Kemp, (8)Cutler (30)Yes3vage, (XXX)Goodwln
ID Weight Temp. , .J/(mol«K) Oi ff.

K expt ca c 1
%
30 1 .000 140.000 88.04 87.33 .82

210 1 .000 141 .629 87.35 87.45 -.12
2 1 .000 142.790 87.44 87.54 -.13
122 1 .000 145.757 87.68 87.78 -.12
21 1 .000 147.902 87.87 87.96 -.10
2 1 .000 149.740 88.15 88.11 .04
30 1 .000 150.000 88.67 83.14 .61
123 1 .000 152.350 88.16 88.34 -.20
212 1 .000 154.093 88.32 88.49 -.19
2 1 .000 156.850 88.69 88.74 -.05
124 1 .000 158.858 88.77 88.93 -.18
30 1 .000 160.000 89.38 89.03 .39
213 1 .000 160.343 88.97 89.07 -.11
2 1 .000 164.390 89.36 89.46 -.11
125 1 .000 165.298 89.30 89.55 -.28
214 1 .000 166.378 89.58 89.66 -.08
30 1 .000 170.000 90.24 90.03 .24
126 1 .000 171.647 90.11 90.20 -.10
2 1 .000 172.020 89.86 90.24 -.42
215 1 .000 172.363 90.21 90.28 -.08
216 1 .000 178.276 90.82 90.93 -.12
2 1 .000 179.090 90.74 91 .02 -.31
127 1 .000 179.354 90o90 91 .06 -.17
30 1 .000 180.000 91 .26 91 .13 .14
217 1 .000 184.114 91 .46 91 .62 -.17
128 1 .000 185.534 91 .67 91 .79 -.13
2 1 .000 185.900 91 .66 91 .83 -.19
218 1 .000 189.882 92.19 92.34 -.16
30 1 .000 190.000 92.46 92.35 .12
129 1 .000 191 .643 92.48 92.56 -.09
2 1 .000 194.280 92.79 92.91 -.13
219 1.000 195.603 93.01 93.09 -.09
130 1 .000 197.686 93.21 93.33 -.18
30 1 .000 200.000 93.83 93.70 .14
2 1 .000 200.940 93.84 93.83 .00
220 1 .000 202.405 93.74 94,05 -.33
131 1 .000 204.154 94.13 94.30 -.18
2 1.000 207.090 94.26 94.74 -.51
221 1 .000 209.358 95.04 95.09 -.06
30 1 .000 210.000 95.35 95.20 .16
132 1 .000 21 1 .041 95.39 95.36 .03
2 1 .000 213.100 95.43 95.69 -.27
222 1 .000 216.234 96.25 96.21 .05
133 1 .000 217.854 96.43 96.48 -.05
2 1.000 219.250 96.27 96.72 -.47
30 1 .000 220.000 97.04 96.85 .20
223 1 .000 222.998 97.34 97.38 -.04
134 1 .000 224.592 97.55 97.66 -.12
2 1 .000 224.960 97.48 97.73 -.26
224 1 .000 229.651 98.54 98.61 -.07
2 1 .000 229.810 98.28 98.64 -.37
137
3 5, ) 7 .
sources and ID numbers: ( 1 )Dana, (2 )Kemp, (8) CutI er (30 ) Yesavage, (XXX)ooodwin •
ID We ight Temp. , J / ( mo 1
• K Di f f
K expt ca c 1
%
30 1 .000 230.000 98.92 98.68 .25

135 1 .000 231 .245 98.90 98.92 -.02
225 1 .000 236. 231 99.81 99.91 -. 1 0
136 1 .000 238.095 100.16 100 . 30 -.1 4
30 1 .000 240.000 100.99 100.70 .29
1 0.000 241 .760 99.82 1 01 .08 -1 .25
226 1.000 242.764 101 .25 1 01 .30 -.05
1 37 1 .000 244.560 101 .75 101.69 .05
1 0.000 246.880 96.49 102.22 -5.60
30 1 .000 250.000 1 03.31 102.95 .35
1 38 1 .000 250.946 103.20 1 03 . 1 .03
1 0.000 252.820 1 00. 55 103.62 -2.96
1 0.000 255.330 100.74 104.24 -3.36
139 1 .000 257.248 104.75 104.73 .02
30 1.000 260.000 1 05.89 105.44 .43
1 0.000 261 .550 105.72 105.85 -.13
1 40 1 .000 263.551 106.27 106.40 -.12
1 0.000 264.740 97.79 106.72 -8.37
1 0.000 266.440 1 06. 27 107. 20 -.87
1 0.000 269.060 1 07.20 107.95 -.70
1 41 1 .000 269.931 108.1 108.21 -.05
30 1 .000 270.000 1 08.77 108.23 .50
1 A
110.15C 1
-. 1 5
1 42 1 .000 275. 292 1 09.98 1
0 OA
-2.89
1 0.000 276.430 107.01 1 1 0. 20
0.000 275 . 780 1 .44
1 1
S
1
1 A 71
0.31 1
1
AO
.02
1 1
30 1 .000 280.000 111 .98 1 1 1 .36 .56

282 .595 111 /.z4 - . Z5
1 43 1 .000 11 .96
1 1 1
1 0.000 287.550 1 0 7 . 75 1 1 4 .00 -5.48

1 44 1 .000 288. 81 1 1 4.09 1 1 4.46 -.33
30 1 .000 290.000 1 1 5.57 1 1 4.91 .57
1 0.000 291 .590 1 1 0.89 1 1 5 .52 -4 .01
30 1 .000 300.000 1 19.60 118.99 .52
30 1 .000 310.000 124.22 123.76 .37
30 1 .000 320.000 129.70 129.53 .13
30 1 .000 330.000 136.63 136.83 -.15
30 1 .000 340.000 146.28 146.85 -.39
30 1.000 350.000 162.17 162.81 -.39
30 1 .000 360.000 199.63 198.91 .36
Number of data points = 139; rms deviation = 0.29^.
138
1 711 1 3
Table 15. Comparisons with and Cp data.
Cr, data of Ernst (26)
T = 293. 15 K
Pressure Dens ty i Cn, J/(mol'K) Diff. Cp - Cp, J/(mol.K) Diff.

MPa I<g/m3 expt ca c
1
% expt ca c 1
%
n on 72.67 72.80 - 1 7 n nn n nn
.90 73.06 73. 13 • \jj 39 . -j^ .06
1.81 73.51 73.50 .01 .84 .7 1 . 1
1 Q^l 3 .68 74.47 74.39 • 1 1 .80 1 . 59 .21

6.62 76.32 76.09 .30 3.65 3.29 .36
.4903 9.74 78 .48 78 .35 . 16 5.81 5.56 .25
.6374 13.10 81.13 81 .43 -.36 8.46 8.63 -.17
.7845 16.75 84.57 85.79 - 1 .42 1 1 .90 1 3.00 -1.10
T = 313.15 K
0.0000 0.00 76. 1 76.74 -.83 0.00 0.00 0.00

.0490 .84 76.53 77.01 -.63 .42 .21 .15
.0981 1 .69 76 .95 77.31 -.46 .84 .56 .28
. 1961 3.42 77.79 77.97 -.23 1 .68 1 .23 .45
.3432 5. 12 79.19 79. 18 .02 3.08 2.43 .65
4903 8.95 80.63 80.66 - .04 4. 52 3.92 .60
.6374 1 1 .93 82.44 82.49 - .06 6.33 5 .74 .59
. 7845 1 5.08 84.61 84.75 -. 1 8. 50 8.0 .49
1 Q fi9 88.01 88.74 1 1 90 12.00 -.10
1 7fiR
1.1/
1
OO 93.18 94.49 -1 "SQ 1 7 07 17.75 -. 68
T = 333.15 K
0.0000 0.00 80.30 80.72 -.53 0.00 0.00 0.00

.0490 .79 80.55 80.95 -.49 .25 .22 .03
.0981 1.58 80.93 81 .19 -.32 .63 .46 .17
• 1
1
Q^^1
yo 1 81 .54 81 .71 - 9 1 94 .70 9fi
s 7n 82.56 82.62 - 07 9 9fi 1 ftQ .-J /
o • 83.56 83.68 _ 1 c \ 9fi 9 Qfi
• / 1 1 nn 85.00 84.93 •uo 4 7n 4 9 1 4Q

• / Oh-_? 1
1
ft9
J» oz 86.45 86.39 •U / O. 1 J J 90 / . 4R
HO
• you / 1 7 7R 88.65 88.73 OQ
— • uy O. U 1
^4
1
1 • 1
1
7fift
/ OO
99 H"^ 91.28 91 .67 - A9 1
1
n
U . Qfl
70 1n Q4 n4
1 "^790 9*^ ft"^ 94.95 95.44 - ^ 1 14
1H . ftR
DJ 14 71 . UD
T = 353.15 K
0.0000 0.00 84.40 84.71 -.37 0.00 0.00 0.00

.0490 .74 84.59 84.90 -.37 .19 .19 -.00
.0981 1 .49 84.79 85.10 -.36 .39 .39 .00
.1961 3.01 85.36 85.52 -. 19 .96 .81 .15
.3432 5.34 86.19 86.23 -.05 1.79 1 .52 .27
.4903 7.75 86.97 87.05 -.09 2.57 2.34 .23
.6374 10.23 88.01 87.96 .05 3.61 3.25 .36
.7845 12.79 89.02 89.00 .02 4.62 4.29 .33
.9807 16.36 90.65 90.59 .07 6.25 5.88 .37
1.1768 20.10 92.39 92.45 -.06 7.99 7.74 .25
1.3729 24.06 94.37 94.66 -.30 9.97 9.95 .02
Number of data points of Ernst [261 = 40, mean deviation = 0.30$.
139
• J ; 1 .
Cp dat.3 of Yesavage [104,105]
P = 1.7237 MPa
Torn n -
b ry
Lyfe?!! 1
Up , J / 1 .no 1 •l\ Di f f
K kg/(n3 ©xpi" ca c t
%
116.483 702.41 85.79 85.67 .14

144.261 674.46 87.64 87.58 .07
172.039 646.27 89.85 90.1 -.29
199.817 61 7.30 93.17 93.48 -.33
??7 .5Q4 ôo Q7 7Q y / .yo -. 20
255 ,372 1 c\A c\e^
1U4 .(jy -.03
283. 50 1 119
1
7'=;
i. m 1
\
110
1 z. /D
1
A1
-.03
31 0.928 1
1
9R . 41
ZO 1 1 ZD . O'J 1.27
^4 (Si's 1 m Ri^;
1 Uz
. -1.14
U'J • H O-' Z^ . /U yy. u 1 -.21
Ji?^ . ZD 1 ZD. '4 1 1 Uz .(J J 1 00 . DO 1 .36
r - J. 44/4 Mra
1 1« AW^
ID. *+OJ? 70 ^
/UJ) 14
4 85 .63
1 . 1
.41
1 44.261 675.36 R7 > 1 0
172.039 647.40 89.67 89.98 -.35
199.817 618.74 92.80 93.27 -.50
227.594 588.77 97.60 97.62 -.02
255.372 556.63 103.51 103.45 .05
283.150 520.96 112.18 111.49 .62
310.928 479.14 124.17 123.55 .51
338.706 423.88 150.37 147.55 1 .91
366.483 82.76 157.57 165.81 -4.97
394.261 63.07 122.14 120.50 1.36
422.039 53.88 114.02 114.63 -.53
P = 6.8948 MPa
116.483 704.58 85,98 85.54 .51

144.261 677.14 87.64 87.35 .32
172.039 649.60 89.48 89.74 -.29
199.817 621.53 92.62 92.87 -.27
227.594 592.39 97.05 96.97 .08
255.372 561.50 102.77 102.35 .41
283.150 527.90 110.15 109.44 .64
310.928 490.05 118.82 119.12 -.25
338.706 444.87 133.21 133.40 -.14
366.483 384.03 159.23 156.08 1.97
394.261 267.62 267.53 262.28 1.96
422.039 155.32 176.38 177.78 -.79
140
7 6 .
Table 1!3. (Continued).
Cp da ha of Yesavage (104,1051
P = 10.342 1 MPa
Temp. DensI ty Cp , J / ( mo •K)

1
0 i f f
K kg/nv5 expt cat c %
116.483 705.99 86. 1 85. 46 .82

144.261 678.87 87.82 87.22 .69
172.039 651 .75 89.85 89.52 .38
199.31 624.22 92.44 92.52 -.09
227.594 595.82 96.68 96.41 .28
255.372 566.02 102.03 101 .42 .60
283.150 534.12 108.49 107.86 .58
510.928 499.13 1 16.42 116.18 .21
338.706 459.52 126.20 126.99 -.63
366.483 412.55 1 39.30 136.65 1 .90
394 .261 352 . 95 1 59.96 164.44 -2.80
422.039 276.85 1 77.68 180.32 -1 .49
P = 13.7895 MPa
11 6.483 707.38 86.16 85.38 .91

144.261 680.57 88.01 87.09 1 .05
1 72.039 653.84 90.22 89.31 1 .01
199.81 7 626.81 92.44 92.19 .26
22 7.594 599.10 96.31 95.91 .42
255.372 570.25 101 .29 100.63 .65
283.1 50 539.76 107.20 106.60 .56
310.928 506.97 113.84 114.05 -.13
333.706 471 .06 122.51 123.17 -.54
366.483 430.88 131 .55 128.97 1 .96
394.261 385.05 146.13 147.46 -.92
Number of data points of Yesavage [104,1051 = 58; mean deviation = 0.74$.
i'
t
141
8 9
Table 15, (Continued).
Cy data of Goodwin [341
ID Weight Temp. Dsns tyi Cy, J/(mol •K) iff.

K kg/m3 expt ca c 1
%
145 1 .000 296.740 497.86 74.25 73.32 1.25

146 1 .000 301 .507 497.55 74.20 74.23 -.04
147 1 .000 307.514 497.15 75.28 75.41 -.18
148 1 .000 313.479 496.76 76.27 76.62 -.46
149 1.000 319.395 496.40 77.31 77.87 -.72
150 1 .000 325.273 496.01 78.14 79.13 -1 .27
151 1 .000 331 .118 495.61 79.22 80.43 -1 .52
152 1 .000 336.944 495.26 80.26 81 .72 -1 .82
801 1 .000 278.582 526.92 70.78 70.35 .60
802 1 .000 284.558 526.43 71 .75 71 .39 .51
803 nooo 290.482 525.99 72.82 72.44 .52
804 1 .000 296.874 525.51 73.98 73.62 ,48
805 1 .000 303.743 524.98 75.23 74.94 ,39
806 1.000 310.524 524.49 76.47 76.30 .22
807 -
1.000 317.249 523.96 77.67 77.69 -.02
808 1 .000 322.550 523.57 78.69 78.83 -.18
228 1.000 256.127 554.43 67.50 67.31 ,28
229 1 .000 258.883 554.21 68.04 67.72 ,47
230 1 .000 262.933 553.86 68.83 68.33 .72
231 1 .000 268.252 553.38 69.77 69.16 .88
232 1.000 273.524 552.93 70.50 70.00 .71
233 1 .000 278.769 552.45 71 .33 70.86 .56
234 1.000 283.978 552.01 72.26 71 .74 .72
235 1 .000 289.142 551 .52 73.34 72.65 .94
901 1 .000 238.1 72 575.87 66.22 65.37 1.28
902 1 .000 242.833 575.42 66.28 65.99 .43
903 1 .000 248.402 574.85 67.18 66.75 .64
904 1 .000 254.401 574.28 68.15 67.59 .83
905 1 .000 260.329 573.70 69.08 68.44 .92
906 1 .000 265.728 573.13 70.11 69.24 1 .23
907 1 .000 270.590 572.69 70.98 69.99 1.39
301 1 .000 216.834 600.38 64.02 63.58 .69
302 1 .000 220.658 599.99 64.05 64.02 .05
303 1 .000 224.436 599.55 64.27 64.46 -.29
304 1 .000 223.198 599.10 64.87 64.90 -.04
305 1 .000 231 .931 598.71 65.45 65.34 .16
306 1 .000 235.624 598.27 66.07 65.79 .42
307 1 ,000 239.291 597.87 66.66 66.25 .61
401 1 .000 188.878 '
630.46 61 .48 61 .92 -.72
402 1 .000 192.681 629.93 61 .84 62.28 -.71
403 1 .000 196.572 629.40 62.23 62.65 -.63
404 1 .000 200.423 628.91 62.78 63.02 -.39
405 1.000 204.255 628.39 63.27 63.39 -.20
406 1 .000 207.852 627.90 63.83 63.75 .13
501 1 .000 156.982 663.40 60.08 60.91 -1 .38
502 1 .000 160.668 662.83 60.36 61 .19 -1 .38
503 1 .000 164.253 662.25 60.80 61 .46 -1 .09
504 1 .000 167.802 661 .68 61 .15 61 .73 -.95
505 1 .000 171 ,318 661 .1 1 61 .60 62.00 -.64
601 1 . 000 126.412 693.69 59.78 60. 71 -1 . 56
602 1 .000 129.030 693.21 60.02 60.88 -1 .44
603 1 .000 131 .699 692.68 60.22 61 .05 -1 .37
604 1 .000 134.41 692 . 1 60.41 61 .21 -1 .33
605 1 .000 137.115 691 .66 60.60 61 .37 -1 .28
701 1 .000 100.334 7V9.62 60.49 61 .21 -1 .20
702 1 .000 102.729 71 9.09 60.76 61 .35 -.97
703 1 .000 105.095 718.56 60.85 61 .48 -1 .03
704 1 .000 107.444 718.08 60.99 61 .60 -.99
Number of Cy data points of Goodwin [341 = 58; mean deviation = 0.89^.
142
« 6
o
7
1 3
A z
3
D
4
5
1/ y
0
5
2
11
Table 16. Comparisons with velocity of sound data.
Velocities of sound from Younglove [107]
Temp. Pressure Dens ty I Ve 1 . of Sound, m/s Iff.

K MPa kg/mJ expt cal c %
90.00 34.332 739.94 2205.4 2096.3 5.20

90.00 31 . 431 738. 90 21 96.2 2086.5 5.26
90.00 29.537 738.32 21 90.8 2081 .0 5.28
90.00 28. 713 738.06 21 88.8 2078.6 5.50
90.00 OK . 11 3z
2p "ZO
/3o. ys 21 79.0 2068.2 5. 36
90.00 23.31 736.37 21 73.7 2062.9 5.37
90.00 17.218 734. 42 21 55. 2045. 5. 45
90.00 14.584 733.57 21 49.0 2037.4 5.48
0 1 ZO 0 AOO 0
90.00 11
1 1 .411 Q
>1
21 3o. 1
zOzo. 1 C
5.42 4
yu.uu o ooj /j\ .DO 0 1 JZ

Z "ZO 0
1 .z 0 AOA .D
zUzU 5. 5Z
yu.uu D. U4y Tzr\ 1 0
Zl1 0 "Z
ZJ. T 0 Al 0
ZUI Z.J"Z 5.54
OA AA O QAT TO A 0 0 AAO 0
y<j. 00
£.A
z 1 4. 0
1
1
1
>!
zOUz.o 5.55
1 AA AA J">3D / .
01 4
Z ^ "Z "Z
1 J.J OAZ/1 A R "ZT
1
1
AA
UU.UUAA ^y.yy 1
70Q A1 01 "Z A 7 OA1
zu Q y.y
1
A C
5 4o
.
Q /I
1
1
AA
00.00AA ^ -5
ZD.Ol 1 "I
/z T/
"70 OQ
.OO zl1 OA
0 Q
zO.o OAA
zuoy A.C c c
5.54 >1
1
1
AA AA
00 . 00 z3.3jo /ZO. // 0111
Zl 1
I 1 . 1
1 AA A
1 yyy .3
"Z
5 CA
C .5y
A A AA OA TAR 0 1 AO A 1 AQ A 0 C
1 yby.y
"Z
1
Zl Uz .U
AA AA OAno 1 ATA O
1
1 00.00 1 "7 1 O"?
/z4.d3 zuyz . 0 ,
1 y /y .y 5.0/
1 00.00 1 4.272 723.53 0 AO'Z A
zUoj .
1 A TA
1 y /o.y
A C
5. T1
/I
1 00.00 1 1 . 703 722.71 2075 .4 1 952 .9 5.74

1 00.00 o. 5 /z
T0 CO
7211 .59 0 AiC C C
zODD .
1 ACO
1 y5z .
A C
5. Tt;
/D
00.00 5.731 720.55 2056.3 1
1
A Z A
y43.
>1 C TO
1
1 00.00 2.91 71 9.52 2046. 1 935. 5.77

1 0.00
1 34.556 721 .26 2082.4 1 975.8 5.39
1 0.00
1 31 .729 720.26 2073 .5 1 966.6 5.44
AC C CA
1 1 0.00 28.901 71 9.26 2065 .0 1
1 95 T/ .4A 5.50
1 0.00
1 26. 1 1 71 3.26 2056. 1 948. 5.55
1 0.00
1 25.1 22 71 7.90 2053.6 1 945.0 5 .58
1 0.00
1 23.877 71 7.44 2049.4 1940.8 5.59
1 1 0.00 20.485 71 5.20 2038.7 1 929.6 5.65
1 0.00
1 7.505
1 71 5.09 2028.9 1919.6 5.69
1 0.00
1 14.464 71 3.94 201 8.3 1 909.4 5 .73
1 0.00
1 1 1 .682 71 2.87 2009.5 1 900.0 5. 76
1 0.00
1 8.647 71 1 .70 1 999.3 1 889.7 5 .80
1 0.00
1 5.821 710.59 1989.6 1880.1 5.83
1 1 0.00 3.031 709.48 1 979.9 1 870.5 5.85
1 20.00 34.725 71 2. 1 5 2022.8 1920.8 5.31
1 20.00 31 .000 71 0.75 201 1 . 1 908.0 5.40
1 20.00 28.663 709.86 2003.0 1 899.9 5 .43
1 20.00 24.899 708.41 1989.9 1 886.8 5 .46
1 20.00 20.438 706.65 1975.2 1 871 .
c 1
1 20.00 1 7.354 705 .42 1964.4 1860.
1 20.00 1 94
4. 1
TA A
704. 1
1
"Z 1
1
AC .z
y53 0 "Z 1
1
OA Q Q
o4o. •OP
120.00 11 .756 703.13 1944.4 1840.0 5.68
120.00 8.661 701 .84 1933.2 1828.7 5.71
120.00 5.368 700.44 1921 .8 1816.6 5.79
120.00 3.069 699.45 1912.4 1808.1 5.77
140.00 34.903 694.12 1905.1 1815.8 4.92
140.00 32.285 693.00 1395.5 1805.8 4.96
140.00 28.943 591 .55 1882.9 1793.0 5.02
140.00 26.339 690.41 1873.1 1782.9 5.06
140.00 22.925 688.89 1859.9 1769.4 5.11
140.00 20.345 687.72 1850.1 1759.2 5.17
143
Velocities of sound from Younglove [107]
Temp Pressure Dens ty

i Vel . of Sound, m/s Di ff
K MPa kg/m3 expt cal c %
140.00 17.664 686.49 1839.3 1748.4 5.20

140.00 14.149 684.84 1825.1 1 734.1 5.24
140.00 11 .218 683.45 1813.0 1722.1 5.28
140.00 8.444 682.10 1801.6 1710.5 5.32
140.00 5.864 680.83 1790.6 1699.7 5.35
140.00 3.332 679.57 1779.5 1688.9 5.36
160.00 34.565 676.08 1788.3 1713.9 4.34
160.00 31 .986 674.83 1777.3 1703.0 4.39
160.00 28.855 673.29 1764.7 1689.6 4.44
160.00 26.279 672.00 1753.7 1678.5 4.48
160.00 23.072 670.36 1739.5 1664.4 4.52
160.00 20.151 668.85 1726.9 1651 .4 4.57
160.00 17.530 667.46 1715.1 1639.5 4.61
160.00 14.481 665.82 1 701 .0 1625.5 4.64
160.00 8.699 662.61 1673.7 1598.4 4.71
160.00 2.970 659.29 1645.1 1570.6 4.75
180.00 34.078 658.06 1674.7 1614.5 3.73
180.00 31.939 656,88 1664.7 1604.5 3.75
180.00 29.069 655.27 1651 .3 1590.9 3.80
180.00 26.357 653.73 1638.4 1577.9 3.84
180.00 •
23.460 652.04 1624.0 1563.7 3.85
180.00 20.351 650.19 1608.5 1548.2 3.89
180.00 17.298 648.33 1593.2 1532.7 3.95
180.00 14.624 646.67 1579.4 1518.9 3.99
180.00 11.422 644.62 1562.0 1502.0 4.00
180.00 8.599 642.77 1546.2 1486.7 4.00
1 80 .00 5.902 640.96 1551 .6 1471 .9 4.05
180.00 2.978 638.95 1514.5 1455.4 4.06
200.00 34.672 640.69 1568.8 1522.8 3.02
200.00 34.484 640.53 1569.1 1521 .9 3.10
200.00 31 .631 638.80 1554.5 1507.2 3.14
200.00 29.363 637.35 1542.6 1495.3 3.16
200.00 25.937 635.12 1524.4 1477.0 3.20
200.00 24.001 633.83 1513.9 1466.5 3.23
200.00 20.329 631 .32 1493.4 1446.1 3.27
200.00 7.287
1 629.17 1475.7 1428.7 3.28
200.00 14.327 627.03 1458.2 141 1 .4 3.31
200.00 1 1 .454 624.88 1440.7 1394.2 3.33
200.00 8.259 622.42 1420.4 1374.5 3.34
200.00 5.175 619.96 1400.2 1354.9 3.34
200.00 2.291 61 7.59 1380.8 1336.1 3.35
220.00 35.007 623.23 1468.0 1432.6 2.47
220.00 32.297 621 .32 1452.6 1417.4 2.49
220.00 29.240 619.10 1434.9 1399.8 2.51
220.00 26.325 616.92 1417.6 1382.5 2.54
220.00 23.450 614.71 1400.0 1365.1 2.56
220.00 20.294 61 2.21 1380.2 1345.5 2.58
220.00 17.341 609.79 1361 .1 1326.5 2.60
220.00 14.416 607.31 1341 .3 1307.2 2.60
220.00 1.278
1 604.55 1319,3 1285.8 2.60
220.00 8.261 601 .79 1297.4 1264.5 2.60
220.00 5.215 598.88 1274.4 1242.3 2.59
220.00 2.502 596.19 1252.9 1221 .7 2.56
240.00 34.746 605.29 1366.8 1341 .5 1 .89
144
0 1 /
1
Velocities of sound from Younglove [1071
Temp. Pressure Dens ty i Ve 1 . of Sound, m/s Di f f
K MP a kg/nP expt ca c 1
%
240.00 32.790 603.72 1354.8 1329.4 1.91

240.00 29. 186 600.73 1332.0 1306.6 1.94
240.00 26.744 598.63 1316.0 1290.6 1.96
240.00 23.703 595.94 1295.4 1270.2 1 .98
240.00 20.621 593 . 1 1273.9 1248.9 2.00
240.00 1 8 . 1 27 590.72 1255.7 1231 .0 2.01
240.00 14.415 587.03 1227.4 1203.4 1.99
240.00 11 .607 584.09 1205.3 1 181 .6 2.01
240.00 8.064 580.20 1175.7 1152.9 1 .98
240.00 5. 102 576.75 1149.6 1127.6 1 .95
240.00 2.345 573.38 1123.7 1103.0 1 .88
260.00 35.001 587.63 1273.8 1256.0 1 .42

260.00 32. 123 584.98 1254.5 1236.5 1 .45
260.00 29.341 582.32 1235.1 1217.1 1.48
260.00 26.676 579.68 1215.7 1197.9 1 .48
260.00 26.220 579.22 1212.3 1 194 .6 1 .48
260.00 23.713 576.63 1193.4 1175.9 1 .49

260.00 20.287 572 .93 1166.5 1 49.3
1 1 .50
260.00 17.384 569.63 1142.7 1125.7 1 .51
260.00 14.786 566 .53 1120. 1 1103.8 1 .48
260.00 1 .579
1 562.50 1091 .5 1075.4 1 .50
260.00 5 .843 554.60 1 034.5 1020.3 1 .40
260.00 2.867 550.07 1 001 .4 989.0 1 .25
O c 1 r\
280.00 34.560 559. 15 1
1
1
181.5 1
1168.5 1
1 . 10
280.00 32. 36 1 DDD.PO 1 1d3.4 1 1 50. 1.11
OO A AA
280.00 29.397 553 .57 1
1
1
4z
1
o c
.0
>1 1 1 on o 1
1.13 1 "2
280.00 26.225 559.91 11 17.3 1 04.6

1 1.15
280.00 23. 573 556 .69 1095 .3 1082.6 1.17
OO AA
280.00 20.751 553. 10 1070.5 1058.2 1.15
280.00 17.696 548.99 1042.4 1030.5 1.16
280.00 13.668 543. 14 1002.4 991 .5 1.10
280.00 1 1 .297 539.43 977.5 967 .0 1 .08
280.00 8.576 534.88 946.8 937.2 1 .03
280.00 5.555 529.40 910.0 90 .61 .93
280.00 1 .922 522.03 860. 854.3 .67
300.00 34.752 551 . 10 1098.2 1089.2 .83
300.00 31 .349 546.93 1071 .2 1061 .7 .89
300.00 29.489 544.55 1055.7 1045. .92
300.00 28.732 543.55 1049.0 1039.6 .90
300.00 25. 120 538.61 1017.2 1007.7 .95
300.00 24.397 537.57 1010.4 1001 .0 .94
300.00 22. 137 534.23 989. 979.7 .95
300.00 20.804 532. 18 976.0 955.7 .97
300.00 19.782 530.57 965.7 955.5 .97
300.00 17.730 527.20 944.2 935.3 .95
300.00 17.569 526.93 942.3 933.5 .92
300.00 14.537 521.59 908.5 900.4 .90
300.00 14.149 520.87 904.0 896.0 .90
300.00 1 1.832 516.40 876.2 868.5 .88
300.00 1 1.200 515.12 868.4 860.7 .89
300.00 9.608 51 1 .78 847.4 840.4 .82
300.00 8.167 508.57 827.6 821.1 .79
300.00 5.831 502.97 792.5 787.7 .62
300.00 5.504 502.14 787.5 782.7 .61
300.00 3.189 495.86 748.6 745.7 .38
Number of data points of Younglove [1071 = 162; rms deviation = 3.91^.
145
Saturated liquid velocities of sound from Young love 1107]
Temp Pressure Density Ve 1 . of Sound, m/s Diff.

K MPa kg/mi expt cal c %
90.000 .96855E-09 728.67 2106.2 1994.6 5.30

100.000 .25139E-07 718.44 2037.6 1925.7 5.49
110.000 ,3451 1E-06 708.26 1969.2 1860.0 5.54
120.000 .29481E-05 698.12 1900.8 1796.7 5.48
130.000 .17534E-04 687.99 1832.6 1735.0 5.32
MO. 000 .78671E-04 677.87 1764.9 1674.6 5.12
150.000 .28235E-03 667.72 1697.4 1614.9 4.86
160.000 .84700E-03 657.51 1630.3 1555.8 4.57
170.000 .21959E-02 647.23 1563.3 1497.0 4.24
180.000 .50497E-02 636.85 1496.5 1438.3 3.89
190.000 .10512E-01 626.33 1430.0 1379.7 3.52
200.000 .20133E-01 615.66 1364.4 1320.9 3.19
210.000 .35944E-01 604.78 1298.5 1261.9 2.82
230.000 .96633E-01 582.27 1 167.1 1142.8 2.09
250.000 .21783E+00 558.44 1036.5 1021.8 1.42
260.000 .31060E+00 545.88 971.6 960.4 1.16
270.000 .43042E+00 532.78 905.4 898.3 .79
290.000 ,76931E+00 504.56 775.1 771.5 ,47
Number of saturated liquid data points of Younglove [107] = 18; rms deviation = 4.02^.
Saturated 1 iqu id velocities of sound from Rao 1 721
Temp. Dens ty
i Vel . of Sound, m/s Diff.
K kg/m3 expt cal c %
140.000 677.87 1528 1674 -9.52

145.000 672,80 1499 1644 -9.71
150.000 667.72 1469 1614 -9.91
155.000 662.62 1439 1585 -10.13
160.000 657,51 1409 1555 -10.37
165.000 652.38 1379 1526 -10.62
170.000 647.23 1350 1496 -10.89
175.000 642.06 1320 1467 -1 1.17
180.000 636.85 1290 1438 -1 1.47
185.000 631.61 1260 1409 -11.78
190.000 626.33 1230 1379 -12.10
195.000 621.02 1200 1350 -12.44
200.000 615.66 1 171 1320 -12.79
205.000 610.25 1 141 1291 -13.16
210.000 604.78 1111 1261 -13.54
215.000 599.26 1081 1232 -13.93
220.000 593.67 1051 1202 -14.33
225.000 588.01 1021 1172 -14.75
230.000 582.27 992 1142 -15.18
Number of data points of Rao [72] = 19; mean deviation = 11.99^.
146
y y
z
7/ .
Table 16. (Cont-1 nued)
Velocl+Ios of sound from L acam louj
T -— OQQ
1 zyo .15R 1 1/
!\
Pressure Uens ty 1 vel . of Sound, m/s U 1 ft .
MP a kg/ (tv5 expt ca c 1
1
1
« ^\^
ij 1
"^x
jJ)
^ OO • 7
4yz Z5 70 A
11 4 71 A
/I y
RQ
/ AR
4y5 .35 7 4z
/
O y1 717
737 RC
.55
;lAO o
4yo. o
zo 758 7R C
755 .38
4.0530 K A 1 .05
5'Jl
Ac:
1 /4
77 1
/ /I
7O
.32
4. j5 /U CA1 Qc;
5U1 .o5 77O
/ /o 7 7^; oo
• ZZ
5 .Uooj AT .do
5Uj AA
7/yu 7Q7 TR
. 35
A /y?
o.u OK "7 CA^; 1 A
5Ud. 1 OU4 QAO
oUz oo
• ZZ
/ • uy/co RAQ .5y

5Uo RA Q1 A
oi y Ol ^
Q1 D OQ
.Zo
Q
o •
1
1
r\£^r\
'Jou
CIA OA
51 u.yu o3 3 QXf\
o3U OQ
• Zo
O 11 =^1
5 1
7
J>. 17
1Z Qil 7
04 / £3/ A
044 XA
• J>4
1
1
A
U."ôc;
jZ? 1
1
m
51 R
5 7R
Z5 . oDU QR
05 7/ •
rX
J J
1
1
f^C^î^
Z .O05O
'J CO A OQ
5ZU. Zo PQ'7
oyj ODO .50
15.1 ybo CO
5Z4. QX
yj /I OO
yz4 /I Q1
yi O 77
» 1 1
1 /• / ji ROQ Ofi
5Zy .ZD y5j Qyl A
y44 QA
•y4
on » Of^Â
/U ZOjU RT"^
5j J .
XO
jZ Q7Q
y /y yoy •y4
0 î T R/l A 77
54U . / 1 A1 7 1 A1 7 AR
_ •U5
30.3975 547.49 1070 1061 .81
35.4638 553.63 1110 1102 .72
40.5300 559.30 1146 1140 •52
50.6625 569.51 1214 1209 •35
fin 7Qsn 1 97'i 979
1 z
1 z /
1 7
^ OD . UO 1
t
^^l
J-J 1
»n9
Q1 Afinn 1
1
'^RA
JOM- • Vm* J
Q1 1 09=1 1 H JZ _ 1 Q
1 U 1 . JZ fin 7 7ft 1 HOZ 1 HO 1
T -
1 _3Z-^ . t J I\
O AO*^"^ RA 1 1 RRO
55Z RRQ
550
11 cc -ZQ
\J O 1 J OJ - 7fl
40U . 1
fins
DUO fino zo
•
A '^R7n 40
idfil ^R
. 45
1 D 5 1
fil1 fi
D O — • 9R
Zy
A<^fi"< *^''?0 (^X
3 .UODJ 404 . 4Z DjZ 1
•U 1
0 .u /yD 4DO. JO ^;ro

d5z fiRO
D5Z AQ
_ •uo
~7 AQ9 Q / 70 Afi
4 /Z .Uo fi70 fi71
0/ 1
no
•uz
o . 1 AÂ
o AQ
7 R •4y QR 7A
UdU1 4/5
>1
oy5 oyu
oil
y» yj1 1 4 7Q
>1 7X
/O . /J
7AQ
/uy 7A7 • 97
Zj
1 A 1 "ZO R Q
40
y1 1
1 .
"70
/O 70
/z 7/ 70 X
/Z J •
>1*7
4j
1Z.DDDD /loo ~7^
lob /ol •
RO
5Z
15.1 yob vIOR A1
4y5 .Ul QA'^
oU3 /yo 7Q
17 7 7 Q 1 R AA fiQ QXA
oj4 QOQ
ozo • OJ
7A 0<;RA
ZU« Zt35U RAR QQ
5U5. oo 004 QRQ
050 • OJ
Z5 .J J J 1
R1 R
5 Q
5. 1 O
1 1 :^ 1 o 9
Q1 z
y 1
R^
. 50
7A . j>y
JU '7Q7'^
/ 5
RO X X~I yoD yo 1 • 4j
35.4638 530.71 1011 1006 .43

40.5300 537.37 1052 1048 .37
50.6625 549.1 1126 1123 •24
60.7950 559.43 1192 1190 •12
70.9275 568.54 1252 1251 •02
81 .0600 576.77 1308 1308 -.02
91 .1925 584.29 1360 1360 -•06
101 .3250 591 .22 1408 1410 -.15
147
7 .
Velocities of sound from L acam [601
T = 398.15 K
Pressure Density Vel. of Sound, m/s DIff

MPa kg/rn3 expt cal c %
1.0133 14.50 266 271 -1 .99

2.0265 31 .37 251 255 -1 .66
3.0398 51 .77 234 237 -1 .36
4.0530 78.25 212 216 -1 .97
4.3570 88. 18 205 209 -2 .08
5.0663 1 7.53
1 192 192 -.51
6.0795 184.72 182 183 -.70
7.0928 255.72 223 214 3.61
8.1060 297.38 273 262 3.73
9, 11 93 322.88 313 306 3.53
10.1325 340.13 356 344 3.17
12.6656 368.33 433 420 2.80
15.1988 388.02 493 480 2.45
17.7319 402.65 542 531 1 .96
20.2650 41 4.55 589 575 2.31
25.3313 433.45 661 650 1 .57
30.3975 448.32 723 71 4 1.18

35.4638 460.69 788 770 2.22
40.5300 471 .31 827 820 .74
50.6625 489.04 914 909 .49
60.7950 503.61 990 986 .34
70.9275 516.04 1056 1055 .05
81 .0600 526.93 1117 1118 -.09
91 .1925 536.65 1174 1175 -.14
101.3250 545.44 1226 1229 -.27
T = 423.15 K
1 .0133 13.46 277 282 -1 .81

2.0265 28.59 265 269 -1 .61
3.0398 45.87 252 255 -1 .55
4.0530 66.15 238 241 -1 .49
4.3570 73.02 233 237 -1 .74
5.0663 90.88 223 226 -1 .60
6.0795 122.1 213 213 -.31
7.0928 161 .20 211 209 .80
8.1060 203.00 218 220 -1.14
9.1193 239.42 243 242 .40
10.1325 268.58 275 268 2.28
12.6656 316.39 352 341 3.07
15.1988 345.24 41 5 405 2.38
1 7.7319 365.56 468 459 1 .80
20.2650 381 .26 51 5 506 1 .56
25.3313 404.99 597 587 1 .63
30.3975 422.89 660 654 .81
35.4638 437.37 716 713 .36
40.5300 449.59 75 7 765 -1 .18
50.6625 469.59 854 857 -.43
60.7950 485.72 931 937 -.65
70.9275 499.33 1000 1007 -.76
81 .0600 51 1 .14 1064 1071 -.72
91.1925 521 .61 1 124 1130 -.57
101 .3250 531 .02 1 180 1 185 -.43
148
1 3 0
J 0 .
Velocities of sound from Lacam [601
T = 448.15 K
Pressure Dens +y i vel DIff

Mra kg/ iTv5 expt cal c
U JJ O
ZOQ 7/ -1.74
1 . 1
292
Z . U/C O J ZD. J / 9 71^
Z /9 281 -2.44
J . Ujyo 4 • ?y
1 ZDZ 271 -3.59
Do . jy Z9(J 260 -4.32
4 . /U D4 . U 1
9
z4 7/
yl
257 -4.28
!3 .UDDJ / / . 04 9 1
z41 >1
250 -3.78
D .u /yj yy .yj 9
ZJO 240 -1.83
"7 AQOQ 1 ZP . Z Z94 233 .19
0 n^n
Q . 1 udu 1
1
c^"^ 07/
3J . Z z 99 232 1 .04
Q
y. 11 Q'^
y^1 1 1uz . Z 1
97Q
ZJO 239 -.54
in 1 "^^s zvjy . ZD 9/1
Z4 7/ 252 -2.36
9^'^ (CO
ZDJ>.O0 jU4 298 1.70
15.1988 301 .13 364 352 3.16
17.7319 327.55 417 404 3.01
20.2650 347.46 463 451 2.41
25.3313 376.53 540 533 1.13
30.3975 397.69 UV o 603 .79
35 .4638 414.41 663 .51
40.5300 til o . 790 717 .35
50.6625 450.60 81 811 -.17
60 . 7Q50 468.32 RRR 892 -.49
70. 9275 483. 1 QSR 964 -.64
Ri ..nfifin
CJ \J\J\J\J
1
4Q'S . R9 1 099 1029 -.70
Q1 1 Q?'! SOT (T^ 1
1
nH9
uoz 1088 -.62
1 01 . 3250 51 7.06 1 1 38 1144 -.54
1 t J
/ . I J
1 01 "V^ 1 1
1 . 39
1 oz 9QQ
z yy 301 -.81
94
Z4. 95 9Qn
zyu 293 -1.04
9 7/
JO .z ZoU 284 -1.74
RX 1 X 971
z / 1 276 -2.13
4 • J? J /U 9/ . 04 zoy 274 -1 .99
Oy • J4 Z04 268 -1 .81
D•U / Q7 AQ 9RQ
zjy 261 -.91
1UD . 9U Z JD 255 .20
19
1Z 7/ . 40
Af^
Z99 252 1.01
Q 11 QT 14y . 44 z9D 253 1.03
in 1 "^0=% 171
1/
R/1
941
9^1
ZD 1 258 .80
1
1
0 • ^^^R^^
Z DDVO 99
ZZ 1 RQ
901 .
901
zy 1 288 .87
1R 1 QQQ
yoo 9*^1 .U
ZD rii
1 1 JJ / 327 2.96
17.7319 291 .23 380 369 2.69
20.2650 314.61 424 412 2.67
25.331 348.69 500 491 1 .64
30.3975 373.09 564 560 .57
35.4638 392.05 621 621 -.10
40.5300 407.57 674 676 -.31
50.6625 432.19 767 771 -.53
60.7950 451 .47 846 852 -.82
70.9275 467.39 916 925 -1 .04
.0600
81 481 .01 980 991 -1.13
91 .1925 492.93 1040 1051 -1.09
101 .3250 503.56 1096 1107 -1.01
149
/ 0
Velocities of sound from Lacam (601
T = 498.15 K
Uc^ 1 1 o 1 1
y 01 OOUIIU y (ll/ u 1 TT ,
fir a ex pt ca C 1
h
1 . u JJ1
11
11.10
1 1 n — mil
^n 1 _ R9
9Q 'i ~. DO
A ns'îo £.00 9Qn — Q9
H . / u . 'J / <CO /
_ ft9
P . UDDj in 9P9 9Q^ - .csy
97P 97 Q "^n
/ . uy/o y4 . J / 97/ 97yl

I. /4
nc;
-•UP
c•
0 1
1
nÂ
UDU 111 /19 97^ 97 1
• / 1
y . 1 1 yJ 1
1
90 •
zy 17
1
97X Z /U • yo
1/17
14 9D
/ . ZO
97 c: 979
Zl Z. no
1
1
on on
yu »yy zyj 9nn .80
15.1 ybo 90Q f^>1 n
J y 1
1
1
1
0^
.06
1 "7 "7 n 1 o c^n .3o
Z5y "^c Xi^n
3dU 1 .oo
20.2650 284.50 395 389 1.47

25.3313 322.27 465 461 .84
30.3975 349.50 529 527 .29
35.4638 370.53 586 587 -.22
40.5300 387.62 640 641 -.23
50.6625 414.44 734 736 -.34
60.7950 435.22 814 818 -.58
70.9275 452.25 885 891 -.74
81 .0600 466.73 948 957 -1.00
91.1925 479.34 1009 1017 -.89
101.3250 490.54 1065 1074 -.85
Number of data points of Lacam 1601 = 174; mean deviation = 1.06^.
150
1 05 9
06 39
17 o
6
9
J
4
8
5
/
1
Table 17. Calculated P(T) tsochores of propane.
Propane 1 sochore at 25 kg/irr^
1 sotherm 1 C /^V\ r- 1^
sochore
1
Temp. Pressure L'tjr 1 vo T ve 1 L/feJl 1 Va r 1 V© Curvature

K MPa I'lr a/ r\ MPa /k* 2
("ira/N
305.514 1 433
. 1 .79392 .03402 — nrinn99fl
310.000 1 704
. 1 .80096 .Q3544 .00599 — . nonni
UUUU 0 1
318.000 1.2178 .31 244 .03 78L .00587

326.000 1.2644 .82279 .0401 .00577 — nooni Oft
334.000 1 .3102 .83222 .04233 ~ . uuuuuoo
342.000 1 .3555 .84086 .04455
350.000 1.4004 .84882 .04667 .00558 — nnnnnfti
358.000 1.4449 .85620 .04376 .00554 . V W»J L/V-'
366.000 1 ,4890 .86306 .05081 .00550
374.000 1 .5328 .86946 .05285 .00546
382.000 1 .5764 .87546 .05483 .00543
390.000 1 .6197 .881 08 .05680 .00541 -.000003?
398.000 1 .6629 .88637 =05876 .00538 -.0000028
406.000 1 .7059 .89136 .06071 .00536
414.000 1 .7487 .89607 .06263 .00534 -.0000023
422.000 1 .7913 .90052 .06455 .00532 -.0000021
430.000 1 .8338 .90475 .06645 .00531 -.000001
438.000 1 .8762 .90876 .06834 .00529 -.000001
446.000 1 .9185 .91257 .07023 .00528 -.000001
454.000 1 .9607 .91621 .0721 .00527 -.000001
462.000 2.0028 .91967 .07396 .00526 -.000001
470.000 2.0448 .92297 .07582 .00524 000001
478.000 2.0867 .92613 .07767 .00523 - 0000019
486.000 2.1286 .9291 .07952 .00523 -.000001
494.000 2.1 703 .93204 .081 35 .00522 - 000001
502.000 2.2120 .93481 .0831 .00521 - 000001
510.000 2.2537 .93747 .08501 .00520 — OOOOOOQ
51 8.000 2.2953 .94002 .086 R4 .0051 ooooooo
— • UUUU*^'U>
526.000 2.3368 .94247 . U O OvJ_/ . nn J'=ii Qy
VJU 1 ~ • UUUUUUo
534.000 2.3783 .94483 CiQCiAl • \J\JJ I o — • uuuuuuo
542.000 2.4197 .94 71 nQ99P nnsi
9\J\J J O9. 1
_ C\c\(\c\r\(\n
"•UUuUUU
550.000 2.461 .94929 DQ/IOR .nnsi • uuuuuu
558.000 2.5024 .95139 •\J^ J oo nnsi ft " •uuuuuu
566.000 2.5437 .95342 .U^ DO / • UUUUUUD
574.000 2.5850 • 95538 . UU J 1 J ~ •UUUUUUO
582.000 2.6262 .95727 1 ni 97 —•UUUUUUD
590.000 2.6674 .95910 . \J\JD 1 J — .UUUUUUD
598.000 2.7085 .96087 .'Jv J 1 ^ ""• UUUUUUD
606.000 2.7496 .96258 — •UUUUUuI?
614.000 2.7907 .96423 . 0840 1 OOOOOOR
— • UUUUUU-)
622.000 2.8318 .96583 .11018 .00513 -.0000004
630.000 2.8728 .96738 . 96 1 1 1 .0051 -.0000004
638.000 2.9138 .96889 .1 1373 .00512 -.0000004
646.000 2.9548 .97034 .11550 .00512 -.0000004
654.000 2.9957 .97175 .11727 .00512 -.0000004
662.000 3.0366 .97312 .11904 .0051 -.0000004
670.000 3.0775 .97446 .12080 .00511 -.0000004
678.000 3.1 184 .97575 .12257 .0051 -.0000003
686.000 3.1593 .97700 .12433 .00511 -.0000003
694.000 3.2001 .97822 .12609 .00510 -.0000003
151
0
4
7
1 8 8
7 99
41
Propane I sochore at 50 kg/in-
!sotherm 1 sochore 1sochore

Temp. Pressure Z Der vat ve
I i Der vat ve
i 1 Curvature
K MP a iMPaTn3/kg ^Pa/K MPa/K^
333.423 2.1277 .67690 .02371 .01 412 -.000081

334.000 2.1 358 .67831 .02 395 .01 408 -.0000787
342.000 2,2463 .69670 .02707 .01357 -.000051
350.000 2.3534 .71 324 .02996 .01 322 -.0000377
358.000 2.4581 .72832 .03269 .01 296 -.000029/
356.000 2.5609 .7421 .03533 .01 274 -.0000243
374.000 2.6621 .75501 .03789 .01256 -.0000203
382.000 2.7620 .76694 .04039 .01 241 -.00001 74
390.000 2.8608 .77808 .04283 .01229 -.0000150
398.000 2.9586 .78851 .04524 .01 217 -.00001 32
406.000 3.0556 .79831 .04760 .01207 -.00001 16
41 4.000 3.1518 .80754 .04994 .01 199 -.00001 04
422.000 3.2474 .81625 .05225 .01 191 -.0000093
430.000 3.3423 .82449 .05453 .01 184 -.0000084
438.000 3.4368 .83230 .05679 .01177 -.0000076
446.000 3.5307 .83971 .05904 .01 171 -.0000069
454.000 3.6242 .84676 .06126 .01 166 -.0000063
462.000 3.71 73 .85348 .06347 .01 161 -.0000058
470.000 3.8100 .85988 .06566 .01 157 -.0000054
478.000 3.9024 .86599 .06784 .01 153 -.0000050
486.000 3.9945 .87182 .07001 .01 149 -.0000046
494.000 4.0863 .87741 .0721 .01 45
1 -.0000043
502.000 4.1 777 .83276 .07432 .01 142 -.0000040
510.000 4.2690 .88789 .07645 .01 391 -.0000037
51 8.000 4.3600 .89281 .07858 .01 136 -.0000035
526.000 4.4508 .89754 .08070 .01 331 -.0000033
534.000 4.5413 .90209 .08281 .01131 -.0000031
542.000 4.631 .90646 .08491 .01 128 -.0000029
550.000 4.7219 .91067 .08701 .01 261 -.0000028
558.000 4.8119 .91 472 .08910 .01 241 -.0000026
566.000 4.9018 .91 863 .091 1 .01 122 -.0000025
574.000 4.991 .92240 .09326 .01 201 -.0000023
582.000 5.081 .92604 .09533 .01118 -.0000022
590.000 5.1 704 .92955 .09740 .01117 -.0000021
598.000 5.2596 .93295 .09946 .01 1 15 -.0000020
606.000 5.3487 .93623 .101 52 .01113 -.000001
61 4.000 5.4377 .93941 .10357 .01 1 12 -.000001
622.000 5.5266 .94249 .10562 .01 1 10 -.0000018
630.000 5.6154 .94546 .10766 .01 109 -.0000017
638.000 5.7041 .94835 .10970 .01 108 -.0000016
646.000 5.7926 .951 14 . 1 1 1 73 .01 106 -.0000016
654.000 5.881 .95386 .1 1377 .01 105 -.0000015
662.000 5.9694 .95649 .1 1579 .01 104 -.0000015
670.000 6.0577 .95904 .11782 .01 103 -.000001
678.000 6.1459 .96152 . 984
1 1 .01102 -.0000014
686.000 6.2339 .96393 .12185 .01 101 -.0000013
694.000 6.3219 .96626 .12387 .01 100 -.0000013
152
1 2
5 5 7
Propane I sochore at 100 kg/ir^
1sotherm 1 sochore 1sochore

i i Der vat ve
1 1 Curvature
K MPa r>â'm3/kg MPa/K MPa/K^
358.586 3.4591 .51 162 .00877 .03366 -.0003702

366.000 3.7013 .53634 .01224 .03190 -.0001643
374.000 3.9519 .56042 .01558 .03085 -.0001056
382.000 4.1957 .58253 .01875 .03013 -.0000780
390.000 4.4344 .60304 .02182 .02957 -.000061
398.000 4.6692 .62220 .02481 .02913 -.0000507
406.000 4.9007 .64018 .02776 .02876 -.0000428
41 4.000 5.1294 .6571 .03067 .02844 -.0000368
422.000 5.3558 .67311 .03355 .02816 -.0000321
430.000 5.5801 .68826 .03640 .02792 -.0000233
438.000 5.8026 .70263 .03922 .02771 -.0000253
446.000 6.0235 .71629 .04202 .02752 -.0000227
454.000 6.2429 .72930 .04481 .02734 -.0000205
462.000 6.461 .741 71 .04753 .02719 -.0000187
470.000 6.6780 .75357 .05033 .02704 -.0000171
478.000 6.8938 .76490 .05307 .02691 -.0000157
486.000 7.1086 .775 75 .05580 .02679 -.0000145
494.000 7.3225 .7861 .05851 .02668 -.0000135
502.000 7.5355 .79613 .06122 .02658 -.0000125
510.000 7.7477 .80571 .06391 .02648 -.00001 17
518.000 7.9592 .81492 .06660 .02639 -.0000109
526.000 8.1700 .82378 .06928 .02630 -.0000103
534.000 8.3801 .83231 .07195 .02622 -.0000097
542.000 8.5896 .84052 .07461 .0261 -.0000091
550.000 8.7985 .84844 .07726 .02608 -.0000086
558.000 9.0069 .85608 .07991 .02601 -.0000082
566.000 9.2147 .86345 .08254 .02595 -.0000078
574.000 9.4220 .87058 .08518 .02589 -.0000074
582.000 9.6289 .87746 .08780 .02583 -.0000071
590.000 9.8353 .88412 .09042 .02577 -.0000068
598.000 10.0413 .89056 .09304 .02572 -.0000065
606.000 10.2468 .89679 .09565 .02567 -.0000062
614.000 10.4520 .90283 .09825 .02562 -.0000060
622.000 10.6568 .90868 .10085 .02557 -.0000057
630.000 10.8612 .91435 .10344 .02553 -.0000055
638.000 1 .0652
1 .91 985 .10603 .02549 -.0000053
646.000 1 .2690
1 .92518 .10861 .02544 -.0000051
654.000 1 .4724
1 .93036 .11119 .02540 -.0000049
662.000 1 .6754
1 .93538 .11376 .02537 -.0000043
670.000 1 .8782
1 .94027 .1 1633 .02533 -.0000046
678.000 12.0807 .94501 .11889 .02529 -.0000045
686.000 12.2829 .94962 .12145 .02526 -.0000044
694.000 12.4848 .95411 .12401 .02522 -.0000042
153
Propane I sochore at" 150 kg/m-
1 sotherm 1sochore 1sochore

I i Derivative Curvature
K MPa r<Pa'm3/kg MPa/K MPa/K^
367.611 4.0763 .39207 ,00180 .05500 -.0014623

374.000 4.41 44 .41733 .00465 .051 72 -.0002530
382.000 4.821 .44630 ,00795 .05027 -.0001355
390.000 5.2201 .47326 ,01124 .04937 -.0000942
398.000 5.6123 .49859 ,01452 .04871 -.0000 725
406.000 5.9999 ,52252 ,01781 .04819 -.0000588
414.000 6.3037 .54520 ,02111 .04776 -.0000494
422.000 6.7643 ,56675 .02441 .04740 -.0000425
430.000 7.1 421 ,58728 ,02771 .04708 -,0000372
438.000 7.51 76 .60686 .031 03 .04630 -.0000331
446.000 7.8909 ,62557 ,03434 .04655 -.0000297
454.000 8.2624 .64348 ,03766 ,04632 -.0000269
462.000 8.6321 .66063 ,04098 ,04611 -.0000246
470.000 9.0003 ,67708 .04430 ,04593 -.0000226
478.000 9.3669 ,69287 ,04762 ,04575 -.0000210
486,000 9.7323 ,70805 .05094 ,04559 -.0000195
494.000 10.0964 ,72264 .05426 ,04544 -.0000182
502.000 10.4593 ,73669 .05759 ,04530 -.00001 71
510.000 10.8212 .75022 ,06090 .04516 -.0000162
518.000 11.1820 .76326 ,06422 .04504 -.00001 53
526.000 1 .5418
1 .77584 ,06754 ,04492 -.0000145
534.000 1 .9007
1 .78798 .07086 ,04481 -.0000138
542.000 12.2587 .79970 .07417 .04470 -.0000132
550.000 12.61 59 .81 103 .07748 .04459 -.0000126
558.000 12.9722 .82199 ,08079 ,04450 -.0000121
566.000 13.3278 .83258 ,08409 .04440 -.00001 17
574.000 13.6826 .84283 ,08739 .04431 -,0000112
582.000 14.0368 .85276 ,09069 .04422 -,0000108
590.000 1 4.3902 ,86238 ,09399 .04414 -.0000105
598.000 14.7429 .87170 ,09728 .04405 -.00001 01
606.000 1 5.0950 ,88073 .10057 .04397 -.0000098
61 4.000 15.4465 ,88950 .10385 .04390 -.0000095
622.000 15.7974 ,89800 .10713 .04382 -.0000093
630.000 16.1476 ,90626 .11041 .04375 -.0000090
638.000 1 6.4973 ,91427 .11368 .04368 -.0000088
646.000 16.8465 ,92206 .1 1695 .04361 -.0000086
654.000 1 7 . 950
1 .92963 .12022 .04354 -.0000084
662.000 17.5431 ,93698 .12348 ,04347 -.0000082
670.000 17.8906 .94413 .12674 ,04341 -.0000080
678.000 13.2376 ,95109 .12999 .04335 -,0000078
686.000 18.5841 ,95786 .13324 ,04328 -,0000076
694.000 18.9302 .96445 .13648 ,04322 -,0000075
154
• U 1 // 9
1 . D C
/
1/
1
Table 17. (Con M nued)
Propane I sochore af 200 kg/irr^
1 o<j 1 rtcJi III 1 socnore 1 sochore

Temp 1 1 ^17 OO U 1 c 2 nor* I \/ S4'f" I
uoi vdT
1 1 vr3 Curval'ure
K MPa MPa • m3 /k n MPa/K MPs /K 2
369.794 4 .2430 .30427 . 00004 n74Q4 —.V fil 07^^

Dl O
t 1 ^ /
374 .000 4. 5495 .32258 .001 70 n79 9Q - . AnA1fÂ7

WUU 04! /
382.000 5. 241 1 .35571 .0051 • 0 71 48
390.000 5.6941 •3871 7 .008R7 • 071 04 - nnnodRA

398. 000 6.261 .41717 •01 266 0 7n 79 - nnnn'^Rn
406 .000 6.8258 .44583 • 1 "J > n7nA7 - nAnn9QA
41 4.000 7.3886 .47327 .02050 •07025 -.nnnfi9R9
422.000 7.9499 .4995 7 .02450 n7nnf^ - nnnn99R
430.000 8 • 5097 .52479 .02855 — . UUUUZUD
nrion9nfi
. W J Z U-J • UD^ -> /
- AAAAI Q1
9.6254 .57231 • UU ^ JO
in 1 ai s .U4UO^ • U Q y4 4 - AAAAI 71
• O DZO
1
nARDR • UD VJ) 1 ~. AAAA
_ UUUU ft04 1
1
>1
A7n nnn 1 1 9QnA nAQ9

.U4yz j> • uoy o i
_ • AAAAI
— UUUU R90Q 1
/17Q nnn 1 1 •O J 7nA

t U4 • n^ônA
UDÛD AAA A 99
— .UUUU R
1
t
&.9,fs nnn 1 7 ^Q'S'^ .O /o_?4 • \JJ / D4 • U D O V4 — . UUUU

AAAAI 4y AQ
1
AQA nnn 1
1
"?
Z QAÂ
^HOH .Dy4y » uo oo 1
ni^^QPO
• UDOO^C
_ AAAAI
~. UUUU 49 AR
1
^c\o nnn 1 /IQfÂ . /

70R
71 /yv
1
A Aft A 1 n*^Q 7n
•UDO /U _ AAAAI 4Z
—.UUUU A 9
1
Kin nnn 1 '4 . U4^0 A 7A"^^ nf^QRQ

• UDo^y
. AAAA1 jy
—.UUUU 1
c Q nnr\
1
D o •UUU
1 1 4 . 5 yJ y .
1/4
A H
/ 1
1
1
A7/1 c^Q
•Udo4o AAAA 117
-•UUUUl 9
5/0 • UUU 1 D . 1 4 J
1
7£^ T TC^ A7QQ>1 A A A A 1 99
-.00001 1
yj)4 •UUU 3. oo /y 7 70A c; AQ'^ An •UOOZD AAAA1 33 11

1 -.UUUUl
c / 9 nnn AQ _ AAAAI J1^
_)hZ •UUU 1
1 D . O'^'^R
Z J JJ 7Q/10R
. /y4zD •UO 7TR
/j9 •UOO 1
— .UUUUl 1
nnn
-?yU» UUU
^ f: 11 OA QnpQ7
•ouoy AQ1 D
»uy ftl
1 •UOoUD _ AAAAI zy
—.UUUUl 9Q
t^t^^Q nnn
OOo* UUU 1
1
7/ .
"ÔOyl
JZZ4 • csz jzj
AQC Q7 70c;
• Uo /V!)
AAAAI 9Q
- .UUUUl ZO
yOD« nnn
cjs;^:
UUU 1 / .00-50 .OJ /U4 •
1
1
AA1
UU 4A 1
n^^ 7Q^
• Uo loO
_ . AAAA1
— UUUU 9ft zo
1
A nnn I O . 4UoU Qcn A'^ • 1

1
AA AA
w44U • n^^77R
UO / /9 — .UUUU
AAAAI 9R Z9
1
Kp9 nnn
!?dZ •UUU \ o . y4yo . 00 J4z •
1
1
AQftft
UODO • Uo /D9
_ . UUUU
— AAAAI 9Z4 1
son nnn
Û • UUU 1
1
Q . 4yu4
y AQr>A .o /OUZ. 1 1 9QT n^; 7c=;c;
• uo / 00
_ AAAAI Z9
—.UUUU 9"^
1
c^QQ nnn Q
71 _ . AAAAI
pyo • UUU zu . jU J .OotSz ? •
1
1
1
1 y
/ 1 • Uo /4-? — UUUU 9Z 1
OUD • nnn
ftnf=^ UUU 9n
z'j . SftQ7
jDy / .yuu 1 • 1
1 Z AR
91 49
1 • n^
uo 77^^
/ J>D
AAAAI 9A
— .UUUU ZU
1
(^1 A nnn 91 nH9 1 Q1 IftR n^ 77f^

• UD / D
622.000 21 .6459 .92285 .12996 .06717 -.00001 18
630.000 22.1829 .93373 .13421 .06707 -.00001 17
638.000 22.7191 .94431 •13845 .06698 -.00001 16
646.000 23.2545 .95460 .14270 .06689 -.00001 15
654.000 23.7893 .96460 .14694 .06680 -.00001 14
662.000 24.3233 .97434 .151 17 .06671 -.00001 13
670.000 24.8566 .98381 .15540 .06662 -.00001 12
678.000 25.3892 .99303 .15963 .06653 -.00001 1
686.000 25.9210 1 .00201 .16385 .06644 -.00001 10

694.000 26.4522 1 .01076 .16807 .06635 -.0000109
155
Propane I sochore at 220.486 kg/in^

Temp. Pressure Z Der ivatlve Derivative Curvature
K MPa MPa '103 /kg MPa/K MPa/K^
369.850 4.2475 .27625 0.00000 .081 13 -.0000000

374.000 4.5841 .29484 .001 73 .081 12 -.0000007
382.000 5.2331 .32953 .00554 .08111 -.0000020
390,000 5.8819 .36278 .00958 .08109 -.0000031
398.000 6.5306 .39469 .01378 .08106 -.0000041
406.000 7.1 789 .42533 .01808 .08103 -.0000051
414.000 7.8270 .45477 .02247 .08098 -.0000059
422.000 8.4747 .48306 .02692 .08093 -.0000067
430.000 9.1 219 .51028 .03143 .08088 -.0000074
438.000 9.7687 .53648 .03598 .08081 -.0000080
446.000 10.4149 .56171 .04057 .08075 -.0000086
454.000 1 .0606
1 .58603 .04519 .08068 -.0000091
462.000 1 1 . 7057 .60947 .04984 .08060 -.0000096
470.000 12.3502 .63208 .05452 .08052 -.0000100
478.000 12.9941 .65390 .05921 .08044 -.0000104
486.000 13.6373 .67497 .06392 .08036 -.0000107
494.000 14.2798 .69533 .06864 .08027 -.00001 10
502.000 14.9216 .71 500 .07338 .0801 -.00001 13
510.000 15.5627 .73402 .07813 .08009 -.00001 15
518.000 16.2030 .75242 .08288 .08000 -.00001 18
526.000 16.8426 .77022 .08764 .07990 -.00001 19
534.000 17.4814 .78746 .09241 .07981 -.0000121
542.000 18.1195 .80416 .09718 .07971 -.0000122
550.000 18.7568 .82033 .10195 .07961 -.00001 24
558.000 19.3932 .83601 .10673 .07951 -.0000125
566.000 20.0289 .85121 .11151 .07941 -.00001 26
574.000 20.5638 .86595 .11629 .07931 -.0000126
582.000 21 .2979 .88025 .12106 .07921 -.00001 27
590.000 21 .9311 .89413 .12584 .07911 -.0000127
598.000 22.5635 .90761 .13061 .07900 -.00001 28
606.000 23.1952 .92070 .13539 .07890 -.0000128
614.000 23.8260 .93342 .14016 .07880 -.00001 28
622.000 24.4560 .94578 .14492 .07870 -.0000128
630.000 25.0851 .95779 .14969 .07859 -.00001 28
638.000 25.7135 .96947 .15445 .07849 -.0000128
646.000 26.3410 .98083 .15920 .07839 -.00001 28
654.000 26.9677 .99188 .16396 .07829 -.0000127
662.000 27.5936 1 .00264 .16870 .07819 -.0000127
670.000 28.2187 1.01311 .17344 .07808 -.0000127
678.000 28.8430 1.02330 .17813 .07798 -.00001 26
686.000 29.4664 1.03323 .18291 .07788 -.0000126
694.000 30.0891 1.04290 .18764 .07778 -.00001 25
156
Table 17. (ConHnuod).
Propane I soci re ah 250 kg/m-

Temp. Pressure Z Der vati ve
I Der Wat ve I Curvature
K MPa MPaMti3/kg MPa/K MPa/K'^
369.676 4.2336 .24295 .00022 .09181 .0104534

374.000 4.6430 .26337 .00249 .09563 .0002745
382.000 5.4146 .30070 .00708 .09703 .0001 114
390.000 6.1939 .33692 .01 193 .09773 .0000696
398.000 6.9777 .37193 .01695 .09819 .0000490
406.000 7.7646 .40572 .02209 .09853 .0000362
414.000 8.5539 .43833 .02733 .09878 .0000272
422.000 9.3450 .46979 .03264 .09897 .0000205
430.000 10.1374 .50014 .03802 .09911 .0000152
438.000 10.9307 .52943 .04344 .09922 .00001 10
446.000 11 .7248 .55771 .04891 .09929 .0000075
454.000 12.5193 .58501 .05441 .09934 .0000045
462.000 13.3142 .61 137 .05995 .09937 .0000020
470.000 14.1091 .63685 .06551 .09937 -.0000002
478.000 14.9041 .66147 .071 10 .09936 -.0000021
486.000 15.6989 .68528 .07670 .09934 -.0000037
494.000 16.4935 .70831 .08232 .09930 -.0000051
502.000 17.2878 .73058 .08795 .09926 -.0000064
510.000 18.0816 .75215 .09359 .09920 -.0000075
518.000 18.8750 .77302 .09924 .09914 -.0000085
526.000 19.6678 .79324 .10490 .09907 -.0000094
534.000 20.4600 .81 283 .1 1056 .09899 -.0000102
542.000 21.2516 .83182 .11622 .09890 -.0000109
550.000 22.0425 .85022 .12189 .09831 -.00001 15
558.000 22.8326 .86807 .12756 .09872 -.0000120
566.000 23.6220 .88539 .13323 .09862 -.00001 25
574.000 24.4106 .90220 .13890 .09852 -.0000130
582.000 25.1983 .91851 .14457 .09841 -.0000133
590.000 25.9852 .93435 .15024 .09831 -.0000137
598.000 26.7712 .94973 .15590 .09820 -.00001 40
606.000 27.5563 .96468 .16156 .09303 -.0000143
614.000 28.3405 .97921 .16721 .09797 -.00001 45
622.000 29.1238 .99333 .17287 .09785 -.0000147
630.000 29.9061 1 .00706 .17851 .09773 -.00001 49
638.000 30.6875 1 .02041 .18415 .09761 -.0000150
646.000 31.4680 1 .03341 .18979 .09749 -.00001 51
654.000 32.2474 1 .04605 .19542 .09737 -.0000152
662.000 33.0259 1 .05836 .20104 .09725 -.0000153
670.000 33.8034 1 .07034 .20665 .09713 -.0000154
678.000 34.5799 1 .08200 .21226 .09700 -.0000155
686.000 35.3554 1 .09337 .21786 .09638 -.0000155
694.000 36.1300 1 .10444 .22346 .09675 -.0000155
157
Propane I sochore at 300 kg/iir
1sotherm 1sochore 1sochore

Temp. Pressure Z Der vat ive
I Der vat ive
i Curvature
K MPa MPa 'm-^ /kg MPa/K MPa/K^
366.998 4.0312 .19419 .00514 .12483 .0021808

374.000 4.9319 .23313 .01 167 . 3096
1 .0004539
382.000 5.9914 .27728 .01887 .13365 .0002542
390.000 7.0678 .32038 .02614 .13533 .0001 743
398.000 8.1 554 .36226 .03349 .13653 .0001296
406.000 9.251 .40285 .04091 .13744 .0001004
414.000 10.3540 .44214 .04839 .13816 .0000794
422.000 1 .4616
1 .48016 .05592 . 3873
1 .0000635
430.000 12.5733 .51694 .06349 .13918 .0000509
438.000 13.6883 .55250 .071 09 .13955 .0000407
446.000 14.8059 .58689 .07872 .1 3984 .0000323
454.000 15.9256 .6201 4 .08637 .14007 .0000253
462.000 17.0469 .65231 .09404 .14025 .0000192
470.000 18.1694 .68343 .101 72 .14038 .0000141
478.000 19.2928 .71355 .10942 .14047 .0000096
486.000 20.4169 .74269 .1 1712 .14053 .0000057
494.000 21.5413 .77090 .12483 .14057 .0000023
502.000 22.6659 .79822 .13254 .14057 -.0000008
510.000 23.7904 .82468 .14025 .14055 -.0000034
518.000 24.9147 "
.85031 .14796 .14052 -.0000058
526.000 26.0336 .87516 .15567 .14046 -.0000079
534.000 27.1620 .89924 .16338 . 4039
1 -.0000097
542.000 28.2848 .92259 .1 7108 .14031 -.0000114
550.000 29.4069 .94524 .17878 .14021 -.0000129
558.000 30.5282 .96721 .18647 .14010 -.0000142
566.000 31 .6485 .98853 .19415 . 3998
1 -.0000154
574.000 32.7679 1 .00923 .20183 .13985 -.0000165
582.000 33.8862 1 .02933 .20949 .13972 -.0000174
590.000 35.0033 1 .04884 .21 715 .13958 -.0000183
598.000 36.1 194 1 .06781 .22479 . 3943
1 -.00001 90
606.000 37.2342 1 .08623 .23243 .13927 -.0000197
614.000 38.3477 1 .10414 .24005 .1391 -.0000203
622.000 39.4599 1 .12155 .24767 . 3895
1 -.0000209
630.000 40.5708 1 .13848 .25527 .13878 -.0000214
633.000 41 .6804 1 .15495 .26286 .13861 -.0000218
646.000 42.7885 1 .1 7098 .27043 . 3843
1 -.0000222
654.000 43.8952 1 .1 8657 .27800 .13825 -.0000225
662.000 45.0005 1 .20175 .28555 .13807 -.0000228
670.000 46.1043 1 .21652 .29309 .13789 -.0000230
678.000 47.2067 1 .23091 .30061 .13770 -.0000232
686.000 48.3075 1 .24493 .30312 .13751 -.0000234
694.000 49.4069 1 .25858 .31562 .13733 -.0000236
158
3 8
1 . 7
4 6
7
Propane I sochore at 350 kg/in-

Temp. Pressure Z Derivative Der vati ve I Curvature
K MPa MPaTn^/kg MPa/K MPa/K^
359.023 3.4870 .14717 .02596 . 7976

1 .0010206
366.000 4.7602 .19709 .03639 .18469 .00051 42
374.000 6.2518 .25330 .04771 .18796 .0003294
382.000 7.7650 .30802 .05881 .19020 .0002378
390.000 9.2935 .36109 .06980 .19186 .0001812
398.000 10.8337 .41 248 .08074 .1931 .0001 420
406.000 12.3830 .46218 .09164 .19416 .0001129
414.000 13.9396 .51 022 .10251 .19497 .0000903
422.000 1 5.5021 .55665 .11 335 .19561 .0000 723
430.000 1 7.0691 .601 52 .1 241 .1961 3 .0000575
438.000 1 8.6399 .64488 .13498 .19654 .0000451
446.000 20.21 35 .68677 . 4576
1 .19686 .0000346
454.000 21 .7894 .72727 .15653 . 9710
1 .0000257
462 .000 23. 3669 .76642 .16727 .1972 7 .00001 80
470.000 24.9456 .80427 .1 7800 . 9739
1 .00001 13
478.000 26.5250 .84088 .18870 .19745 .0000054
486.000 28. 047
1 .87629 . 9938
1 . 9748
1 .0000003
494 .000 29 .6845 .91 056 .21 004 . 9746
1 -.0000042
502.000 31 .2640 .94373 .22068 . 1 9741 -.0000082
51 0.000 32.8430 .97584 .231 29 .19733 -.00001 1
51 8.000 34.421 1 .00694 .241 88 . 9722

1 -.00001 49
526.000 35.9985 1 .03707 .25245 .19709 -.00001 77
534.000 37.5747 1 .06626 .26299 . 9694
1 -.0000202
542.000 39. 1 496 1 .09455 .27351 .19677 -.0000224
550.000 40.7230 1 . 1 2 1 98 .28401 . 9658
1 -.0000244
558.000 42.2949 1 . 4858
1 .29448 .19638 -.0000262
566.000 43.8651 1 . 7438
1 .30492 . 1 961 -.0000278
574.000 45.4335 1 .19942 .31 534 .19594 -.0000292
582.000 47.0000 1 .22372 .32574 . 1 95 70 -.0000304
590.000 48.5647 1 .24731 .3361 .19545 -.000031
598.000 50.1 272 1 .27022 .34645 .1 9519 -.0000326
606.000 51.6877 1 .29247 .35677 .19493 -.0000335
61 4.000 53.2461 1 .31409 .36706 . 9466
1 -.0000342
622.000 54.8023 1.33510 .37733 .19438 -.0000349
630.000 56.3562 1 .35553 .38758 .1 9410 -.0000356
638.000 57.9079 1 .37538 .39779 .19381 -.0000361
646.000 59.4572 1 .39469 .40799 .19352 -.0000366
654.000 61 .0043 1 .41348 .41816 .19323 -.0000370
662.000 62.5489 1 .43175 .42830 .19293 -.0000373
670.000 64.0912 1 .44954 .43842 .19263 -.0000376
678.000 65.6310 1 .46685 .44851 . 9233
1 -.0000379
686.000 67.1684 1 .48371 .45858 .19203 -.0000381
694.000 68.7034 1 .50012 .46862 . 1 91 72 -.0000382
159
1 4
9
Propane Isochore at 400 kg/m-

Temp, Pressure Z Der vati ve
i Der vat ve
i i Curvature
K NPa MPa.m3/kg MPa/K MPa/K^
344.298 2.6430 . 10178 .07761 .26305 .0005614

350.000 4.151 1 .1 5726 .08994 .26579 .0004125
358.000 6.2892 .23293 .10663 .26857 .0002 939
366.000 8.4463 .30598 .12291 .27061 .0002207
374.000 10.6176 .37642 . 3890
1 ,272 16 .0001698
382 .000 12.7999 .44428 .15469 ,27336 .0001320
390.000 14.9907 .50965 .17032 .27429 .0001025
398.000 17. 1881 .57261 .18581 ,27502 .0000788
406.000 19.3905 .63325 ,20118 .27557 .0000593
414.000 21 .5967 .69168 .21545 .27597 .0000431
422.000 23.8057 .74797 .23162 .27626 .0000293
430.000 26.0167 .80223 .24670 ,27645 .0000175
438.000 28.2287 .85454 .26171 ,27655 .0000074
446.000 30.44 12 .90499 .27664 .27657 -.000001
454.000 32.6536 .95365 .29149 .27653 -.0000091
462.000 34.8655 1 .00062 .30628 .27643 -.00001 58
470.000 37.0763 1 .04596 .32100 .27628 -.0000217
478»000 39.2858 1 .08974 .33565 ,27608 -,0000270
486.000 41.4935 1 .13203 .35024 ,27585 -,0000316
494.000 43.6992 1 .17290 .36477 ,27558 -,0000356
502.000 45.9027 1.21241 ,37924 .27528 -,0000392
510.000 48.1036 1.25061 .39366 .27495 -,0000424
518.000 50.3018 1.28756 .40802 ,27460 -,0000453
526.000 52.4971 1.32332 .42232 .27423 -,0000478
534.000 54.6894 1.35793 .43657 ,27384 -,0000500
542 .000 56.8785 1.39 44 1 .45076 ,27343 -,000051
550.000 59.0642 1.42389 .46490 .27301 -,0000537
558.000 61 .2465 1.45533 .47899 .27257 -,0000552
566.000 63.4253 1.48580 .49303 ,27212 -,0000565
574.000 65.6005 1.51534 .50703 .27167 -,0000577
582.000 67.7719 1.54398 .52097 .27120 -.0000587
590.000 69.9396 1.57176 .53486 .27073 -,0000596
Propane 1 sochore at 450 kg/m^
322.304 1.6818 06 50
. 1 .17785 .38324 ,0002389
326.000 3.0999 .2071 1 .18875 .38406 ,0002047
334.000 6. 1782 .21801 .21 188 .38545 .0001480
342.000 9 . 266 .31933 .23454 .38646 .0001059
350.000 12.3608 . 4 624 1 .25682 .387 17 .0000732
358.000 15.4603 .50898 .27879 .38765 .0000467
366.000 18.5627 .59776 .30047 .38793 .0000249
374.000 21 .6668 .68279 .32192 .38806 .0000065
382.000 24.7713 .76427 ,343 14 .38805 -.0000090
390.000 27.8752 .84240 .36418 .38792 -.0000224
398.000 30.9777 . 9 734 1 ,38502 .38769 -.0000339
406.000 34.0781 .98926 .40571 .38738 -.0000439
414.000 37 . 1756 1.05833 .42623 ,38699 -.0000526
422.000 40.2698 1. 12468 .44660 .38654 -.0000602
430.000 43.3601 1.18846 .46684 .38603 -,0000669
438.000 46.4461 1.24979 .48694 .38547 -,0000727
446.000 49.5275 1,30880 .50691 .38487 -.0000778
454.000 52.6040 1.36560 .52676 .38423 -.0000823
462.000 55.6751 1,42031 .54650 ,38355 -.0000862
470.000 58.7408 1,47300 .56612 .38285 -.0000896
478.000 61.8007 1.52380 .58563 .38212 -.0000926
486.000 64.8546 1.57278 .60504 .38137 -.0000952
494.000 67.9025 1.62002 ,62434 ,38060 -.0000975
502.000 70.9442 1.66562 .64355 .37981 -.0000994
160
21
1 /
Propane I sochore at 500 kg/rn^
1sotherm 1sochore 1 sochorG

Temp. Pressure z Der vat ve
i i Der vat ve
i i Cu rv3 "fur©
K MPa MPa. m3 /kg MPa/K MPa/K^
293. 022 .8338 .03018 .34842 .5 5777 - 0001 17S

1 .3738 .04957 .35223 .55216 - 000 Mf\
1
?Q8- 000 3.5815 .12748 .36772 .55168 -.000 187

1
502.000 5.7873 .20327 .38309 .55120 -.0001 207

5O6.OOO 7.991 .27701 .39834 .55072 -.0001731
310.000 10. 1930 .34878 .41348 .55022 -.0001 260
314.000 12.3929 .41865 .42851 .54971 -.0001291
318.000 14.5907 .48669 .44343 .54919 -.0001 324
322.000 16.7863 .55297 .45826 .54865 -.0001358
326.000 18.9798 .61756 .47300 .54810 -.0001391
330.000 21. 1711 .68051 .48764 .54754 -.0001424
334.000 23.3601 .74188 .50220 .54696 -.0001457
338.000 25.5468 .80172 .51668 .54637 -.0001489
342.000 27.731 .86009 .53107 .54577 -.0001520
346.000 29.9129 . 9 704
1 .54539 .54515 -.000 1550
350.000 32.0923 .97261 .55963 .54453 -.0001579
354.000 34.2691 1 .02684 .57380 .54389 -.0001606
358.000 36.4434 1.07979 .58790 .54324 -.0001632
362.000 38.61 51 1.13150 .60194 .54259 -.000 1657
366.000 40.7841 1. 18199 .61 590 .54192 -.0001680
370.000 42.9504 1.23132 .62980 .54 124 -.000 1702
374.000 45. 140 1 1.27951 .64364 .54056 -.0001723
378.000 47.2749 1.32661 .65742 .53986 -.0001743
382.000 49.4329 1.37264 .671 14 .53916 -.0001761
386.000 51 .5881 1 .4 1765 .68480 .53846 - .000 1778
390.000 53.7405 1.46165 .69840 .53774 -.0001794
394.000 55.8901 1.50468 .71 195 .53702 -.0001808
398.000 58.0367 1.54677 .72544 .53629 -.0001822
402.000 60. 1804 1. 58794 .73888 9 J -J J
406.000 62.321 1.62823 .7 5227 .53483 -.000 846
1
^ 0.000
4 \J
1\ % \J \J\J 64.4590 1.66765 .76561 - 000 1RS7
414.000 66.5939 1#70624 .77890 .53334 - OOOIftfifi
418 .000 68.7758 1 ,74401 .797 14 - 000 1ft7S
477 000 1 TROQQ Rns'^'5 S'^ 184 - OOOIftP"^
1 ôphorp at *S^n kn/m^
256.764 .2778 .01043 6 1 =553 .788 13 - OOOfiSOO

758.000 1 .2512 .04676 .62 175 .78733 -.000fi"^8fi
767.000 1fi178 fi4 87 1
. OHO J - 000f\0^f\
7 'i'^ni 777QR fifi 7Q 1 - 000S77(^
910 000 in
1
fi'ss's
\j %\j JJJ .00 00 1
78077 - • UUU
OOO^^'^sl
J JJ 1
274.000 13,7720 .48469 .70141 .77805 -.OOOS'^"^"^
278.000 16.8800 .58552 .72105 .77595 -.0005 157
282.000 19.9797 .68321 .74059 .77392 -.0005005
286.000 23.0715 .77790 .76001 .77195 -.0004872
290.000 26. 554 1 .86971 .77933 .77002 -.0004756
294.000 29.2317 .95878 .79854 .76814 - .0004654
298.000 32.3005 1.04522 .8 765 1 .76630 -.0004564
302.000 35.3621 1. 12913 .83666 .76449 -.0004485
306.000 38.4 165 1.21062 .85556 .76271 -.0004414
310.000 41 .4638 1.28979 .87437 .76095 -.0004350
314.000 44.5041 1.36673 .89308 .75923 -.0004293
318.000 47.5376 1.44153 .91 169 .75752 -.0004241
322.000 50.5643 1.51426 .93021 .75583 -.0004193
326.000 53.5843 1.58501 .94863 .75416 -.0004 150
330.000 56.5976 1.65385 .96697 .75251 -.00041 10
334.000 59.6044 1.72085 .98522 .75088 -.0004073
338.000 62.6047 1.78609 1.00338 .74925 -.0004038
342.000 65.5985 1.84961 1.02146 .74764 -.0004005
346.000 68.5858 1.91 148 1.03945 .74605 -.0003975
350.000 71.5669 1.97177 1.05736 .74447 -.0003946
161
1 1
Propane I sochore at 600 kg/m-

Temp. Pressure Z Der vat ive
i Deri vati ve Curvature
K MPa MPa.m3/kg MPa/K MPa/K2
214.330 .0453 .00187 1.00752 1.12014 -.0016196

218.000 4.1460 .1681 1.031 1 1.11437 -.0015252
222.000 8.5915 .34209 1.05677 1.10846 -.0014356
226.000 13.0141 .50901 1.08236 1.10287 -.0013576
230.000 17.4149 .66929 1 .10786 1.09758 -.0012895
234.000 21.7951 .82332 1.13327 1.09255 -.0012297
238.000 26.1556 .97143 1.15857 1.08774 -.001 1769
242.000 30.4972 1.1 1396 1.18376 1.08312 -.001 1301
246.000 34.8208 1.25120 1.20883 1.07869 -.0010884
250.000 39.1270 1.38344 1 .23378 1.07441 -.0010512
254.000 43.4163 1.51 uyz 1 O CO
.z5oDl <C 1
-.0010177
1 1.07027
258.000 47.6893 1.63390 1.28332 1.06626 -.0009875
262.000 51.9466 1.75259 1 .30790 1.06237 -.0009602
266.000 56. 1884 1.86719 1.33236 1.05858 -.0009354
270.000 60.4153 1.97791 1 .35669 1.05488 -.0009127
274.000 64,6276 2.08493 1.38089 1.05128 -.0008919
278.000 68.8256 2.18841 1.40497 1.04775 -.0008727
Propane 1 sochore at 650 kg/m^
167.316 .0017 .00008 1.55418 1.60092 -.0037221

168.000 1.0962 .05324 1.55969 1.59840 -.0036695
170.000 4.2857 .20570 1.57585 1.59121 -.0035237
172.000 7.4612 .35395 1.59203 1.58429 -.0033889
174.000 10.6231 .49815 1.60825 1.57764 -.0032640
176.000 13.7719 .63847 1.62448 1.57123 -.0031482
178.000 16.9082 .77507 1.64073 1.56504 -.0030406
180.000 20.0322 .90807 1.65698 1.35906 -.0029405
182.000 23.1446 1.03762 1.67324 1.55328 -.0028473
184.000 26.2455 1.16385 1.68949 1.54767 -.0027603
186.000 29.3354 1 .28689 1.70573 1.54223 -.0026791
188.000 32.4145 1.40684 1.72196 1.53695 -.0026031
190.000 35.4833 1.52381 1.73817 1.53182 -.0025319
192.000 38.5419 1.63792 1.75437 1.52682 -.0024652
194.000 41.5906 1.74926 1.77054 1.52195 -.0024025
196.000 44.6298 1.85793 1.78668 1.51721 -.0023436
198.000 47.6595 1 .96402 1.80280 1.51258 -.0022882
200.000 50.6802 2.06761 1.81889 1.50805 -.0022359
202.000 53.6918 2. 16879 1.83495 1.50363 -.0021866
204.000 56.6947 2.26764 1.85098 1.49931 -.0021400
206.000 59.6891 2.36423 1.86697 1.49507 -.0020959
208.000 62.6751 2.45863 1.88293 1.49092 -.0020541
210.000 65.6528 2.55091 1.89885 1.48685 -.0020145
212.000 68.6225 2.641 15 1.91473 1.48286 -.0019769
214.000 71.5843 2.72939 1.93057 1.47894 -.001 9412
162
•
.
• 0 / A
D
1 1 3
1 n
0
J/
8
Propane I sochore at 700 kg/rn-
1 sotherm 1 sochore 1sochore

PrGSSure 7
Temp« Der vat ve i i Der vat ve
i i Curvature
K Mra Mra» mJ/Kg MPa/K MPa/K^
110 1 >! 1
•
AAAA
UUUU .00000 0 "Z A A CO 0 7 TAAO
2.33998 -.0093942
1 ZU • (JUL) 4 ddjD ./ /JO 1 z^ 3z / 3U 2.32298 -• AAO AA C A
uoyyui^y
Q A£: A 0 7 cc A A 0 00 C
1 •UUU 0 •yo ly 1
. / z •34do4 >i >i
2.30565 -.0084286 yi
1 Z4« UUU I J. z>z>o I .o2o j4 Z^30DZ 0 00 A 0

2. 28924
/I AA T A AC C
-.0079955
26.000 1 0•y4 1 1
1
1
AO 956
.00 A Cj^r 0 0 cn
2.38599 "Z
2.27365 -.00760
1 1
128.000 0 o
ZZ«OP 0 1
1
1
1
t A AO 0
.34082 2.40593 2.25881 nn 0 A on
-.0072429 "1
130.000 27.1551 1 .58265 2.42602 2.24465 -.0069151

132.000 71 C'Tif\0
ojOo 1 0 1 CC ~7
2.44622 n AC c c
-.00561 1
5 1 1 . 0 1 55 / 2. 23 1 1 50
134.000 36.0800 2.04004 2.46652 2.21818 -.0063398
136.000 40.5039 2.25650 2.48690 2.20575 -.0060867
138.000 44.9034 2.46534 2.50734 2. 19382 -.0058536
1 4U«UU(J 4y • z / y4 /• oDoy-? Z • /oz
!)Z
0 0 0 "Z "Z
z« ioz33
1
-• AA CC 0
UUDo3o4 "Z /I
i4z«UUU T
c;
-)^.o^zy OA tf^
Z«OD ID / z •!)4o34 2.17125 n A C ~IC\ A
- .0054394 >t
44» Ann
1 >f
1 UUU
/]
0 1 yD4 / X A/1 Q Q R
-)• U4y oD
0 Rf^ QQ "7
Z • DDOO /
0
Z. ^;A Ci^
oU Z>o
1
1
AA CO C C A
-.U052550
7 0T "7*7 0 CO n 0 AA C A 0 Z 0
14d .UUU DZ © Z / !)4 J .Z^ 1
1 / z • I:)oy4z /I
z . dUzz - .0050o3o
14o •UUU J>«4U / /4 zôuyy 0 • 4Uzz
Z
A no 0
\
1
-.A A A0
UU4y 245 ^
>1 /I
I IPU •UU'J / U .O J)OP J • D / ouz Z •0_)U!?U Z • _)U!?Z

1
— .UU4 1 IOC
kg/rn
,3
ol?
A
Q c #4 "7/U >1
•
AAAA
UUUU A AAAA
•UUUUU
7 A 0 RQ
•u z-)y
-5
1
1
7
J • 1ACO"7
Udz /
i
AO A AO
- .U2U U2 7 1
1
Q • AAA
00 UUU 1 ^ T /I
• JOZ1 1 3» A
"Z "7"^ X
U /J) J 1
1
7
3 • AO
uy 3R / ^
"7 X
-.AU 0^~7yl
95 /4U
1
1
A
AAA
D "7/ .UUU 7 AT 1 AID OA C"7
0 4 • /zyi3 mD^D lO J •Uzd4o JÛ /D44 -.u loyuD
00 AAA
Q Q .UUU / • /yo / •d4U /o AT RQ R T AR*7QA
^. uz> /yu
A 0
- .(J Q o5U
1
1
QÂ 1
1
c>y.UUU 1 U •Oh!?D QQ _>Z

• 00
XO 1
1 J •U4 -340 J) •U'fUUD
_
— .Un 7/ -)
1 R1 J
1
7 1
1
1
yu» AAA
OA UUU 1 1 1 R 1
-2
ARROO
U!3pzy
•7
AOOQ"7/
^ .UZZo -.A
U 5o1
1
Q 7Qn
/tSU
y 1
AAA
A .UUU
1 iconic
1D»oy 0 1
1
1
A Â C
~Z.
•34z4!?
7 AC CZ 1 "Z AACOA
3«uuDzy C 007 A
A ]52o30
-.0 1
AO AAA
92.000 1A 00 AO
19.8898 1 • 563 56 3,07551 0 nAAOA
2 .99029 -.01 57236
93.000 22 .8723 1•77868
"2 AO C 0 0 0 A *7/4o3
z .9
^ 0 "Z A 1 C n "7 1 1
AA AAA
94 .000 25 .8396 1
1
AO 0 AC
.98805 T
3.
AA C A r\
09540 0 A CA0 0
2.95988 A 4701
-.01 1~T A A /I 1
95.000 28.7922 2.19191 3. 10706 2 .94542

n
- .0 1
1
TZ 0
42332 yi "7
96.000 31 .7306
0 TA f\ A A
2.39044 3. 1 7851 2.93141 -.0AIT "7A 0
1379 1
1
y / .000 34.5552 0 c0 70 c
2.58385 "Z
3. 1
1
00
28 *7C
/5 0
2.9A 1
1
0T
"7
/83 A 33
- .Ul T T "7 "7
1
/4 >1
2.77233 A OA 0 A
-.0129804
98.000 37 .5664 3. 13977 2.90465 1 >1
99.000 A r\ A ^ A ^
40.4646 2.95605 3. 15089 0 0n 0c
2.89 186 1 n oc
-.01 1
26073 T m
1 A A AA A n 0 0 C TA
-.0122539
1 00. 000 43.3502 3. 13518 3. 16210 2.87943 1
101.000 46.2236 3.30989 3.17339 2.86735 -.01 19190

102.000 49.0850 3.48033 3.18476 2.85559 -.01 16012
103.000 51.9349 3.64664 3.19620 2.84414 -.01 12995
104.000 54.7734 3.80897 3.20770 2.83298 -.01 10128
105.000 57.6009 3.96745 3.21925 2.8221 -.0107402
106.000 60.4177 4. 12221 3.23086 2.81 150 -.0104807
107.000 63.2240 4.27336 3.24251 2.801 14 -.0102336
108.000 66.0201 4.42103 3.25421 2.79103 -.0099980
109.000 68.8061 4.56533 3.26594 2.781 14 -.0097733
110.000 71 .5824 4.70636 3.27770 2.77148 -.0095588
163
1 . 5 1
Table 18. Calculated P(P) isotherms of propane
Propane 1 sotherm at 90 K
sotherm
1 1sochore 1sochore
Dens ity Pressure Z Der vat ve
i i Der vat ve
1 i Curvature
kg/m3 MPa MPa .m3/kg MPa/K MPa/K^
.00 .0000 1 .00000 .01697 .00000 -.0000000
728.67 .0000 .00000 2.89905 2.97836 -.0178732

728.75 .2195 .01775 2.90152 2.97906 -.0178557
729.37 2.0393 .15477 2.92199 2.98482 -.0177125
730.00 3.8720 .31257 2.94261 2.99065 -.0175726
730.62 5.7176 .461 16 2.95338 2.99554 -.0174358
731.25 7.5762 .61055 2.98431 3.00250 -.0173021
731.88 9.4480 .76074 3.00539 3.00853 -.0171716
732.50 1 .3329
1 .91 173 3.02652 3.01462 -.0170440
733.12 13.2313 1.06354 3.04801 3.02077 -.0159195
733.75 15. 1430 1.21617 3.06956 3.02698 -.0157979
734.37 17.0682 1.36963 3,09126 3.03326 -.0166792
735.00 19.0071 1.52392 3.1 1312 3.03959 -.0165634
735.62 20.9597 1.67904 3.13514 3,04599 -.0164505
736.25 22.9261 1.83501 3.15733 3.05244 -.0163404
736,88 24.9065 1.99183 3.17967 3.05895 -.0162331
737.50 26.9009 2. 14950 3.20218 3.06552 -.0161285
738. 12 28.9091 2.30801 3.22485 3.0721 -.0160266
738.75 30.9318 2.46740 3.24769 3.07883 -.0159274
739.37 32.9688 2.52767 3.27059 3.08555 -.0158308
740.00 35.0202 2.78881 3.29386 3.09235 -.0157368
740.62 37.0851 2.95084 3.31721 3.09919 -.0156454
741.25 39. 1667 3.11375 3.34072 3.10508 -.0155565
741 .88 41.2621 3.27758 3.36440 3.1 1303 -.0154702
742.50 43.3723 3.44229 3.38826 3.12002 -.0153864
743.12 45.4974 3.50792 3.41229 3.12707 -.0153050
743.75 47.6377 3. 77447 3.43649 3. 1 34 16 -.01 52260
.00 .0000 1 .00000 .01885 .00000 -.0000000
718.44 .0000 .00000 2.66954 2.72428 -.0140068

718.75 .8380 .06184 2.67912 2.72726 -.0139584
720»00 4.21 10 .31019 2.71758 2.73928 -.0137706
721.25 7.6324 .55125 2.75675 2.75151 -.0135912
722.50 1 . 03
1 1 .81504 2.79633 2.76393 -.0134201
723.75 14.6235 1.07161 2.83644 2.77655 -.0132570
725.00 18.1944 1.33099 2.87707 2.78937 -.0131018
726.25 21.8164 1.59321 2.91824 2.80238 -.0129542
727.50 25.4904 1.85831 2.95996 2.81555 -.0128141
728.75 29.2166 2.12631 3.00222 2.82893 -.0126814
730.00 32.9961 2.39725 3.04503 2.84247 -.0125557
731 .25 36.8294 2.67118 3.08841 2.85518 -.0124370
732.50 40.7173 2.94812 3.13236 2.87005 -.0123251
733.75 44.6605 3.22812 3. 17689 2.88409 -.0122198
735.00 48.6598 3.51 122 3.22201 2.89828 -.012121
736.25 52.7158 3.79744 3.26772 2.91253 -.0120287
737.50 56.8295 4.08583 3.31404 2.92713 -.01 19424
738.75 61 .001 4.37940 3.36096 2.94176 -.0118523
740.00 55.2319 4.67524 3.40851 2.95654 -.01 17880
741.25 69.5226 4.97435 3.45670 2.97145 -.01 17196
164
Propane Isotherm at 1 10 K
sotherm
I
Isochore Isochore
Dens ity Pressure Derivative Derivative Curvature
kg/m3 MPa MPa.m3/kg MPa/K MPa/K^
.00 .0000 .00000
1
.02074 .00000 -.0000000
708.26 .0000 .00000 2.46350 2.50201 -.01 1736
708.75 1.2165 .08276 2.47767
1
2.50672 -.01 1217

710.00 4.3362 .29446 2.51395
1
2.51881 -.0109942
711. 25 7.5015 .50852 2.55067 2.53106 -.0108 726
712.50 10.7130 .72495 2.58783
713.75 2.54347 -.0107568
13.9713 .94378 2.62544 2.55604 --.0106465
715.00 17.2768 1.16504 2.66351
716.25 2.56877 -.0105417
20.6302 .38874 2.70203
717.50
1
2.58165 -.0104422
24.0321 1.61492 2.74102 2.59468 -.0103479
718.75 27.4830 .84361 2.78048
720.00
1
2.60786 -.0102587
30.9835 2.07482 2.82041 2.621 18 -.0101745
721.25 34.5342 2.30859 2.86083 2.63464 -.0100951
722.50 38.1358 2.54494 2.90173 2.64824 -.0100205
723.75 41.7888 2.78390 2.94313 2.65198 -.0099506
725.00 45.4938 3.02550 2.98503
726.25 2.67584 -.0098852
49.2515 3.26976 3.02743
727.50 2.68984 -.0098243
53.0628 3.51673 3.07034 2.70396
728.75 -.0097677
56.9277 3.76641 3.1 1377 2.71821 -.0097154
730.00 60.8473 4.01884 3.15773 2.73257 -.0096673
731.25 64.8222 4.27406 3.20222 2.74705 -.0096233
732.50 68.8530 4.53208 3.24726 2.76165 -.0095833
Propane sotherm at 120 K

.00 .0000 .99999 .02263 .00000 -.0000000
698.12 .0000 .00000 2.27593 2.30506 -.0090397
698.75 1 .4457 .09144 2.29310 2.31 105 -.0089937
700.00 4.3335 .27361 2.32730 2.32298 -.0089059
701.25 7.2640 .45782 2.36189 2.33505 -.0088224
702.50 10.2382 .64413 2.39687 2.34726 -.0087429
703.75 13.2564 .83253 2.43225 2.35960 -.0086675
705,00 16.3190 .02305 2.46803
1
2.37207 -.0085959
706.25 19.4266 1.21572 2.50420
707.50 2.38467 -.0085282
22.5797 1.41054 2.54079
708.75 2.39739 -.0084642
25.7787 .60754 2.57778
1
2.41024 -.0084038
710.00 29.0243 1.80675 2.61520
71 1.25
2.42321 -.0083470
32.3169 2.00817 2.65303 2.43629 -.0082937
712.50 35.6571 2.21 184 2.69128 2.44950 -.0082438
713.75 39.0453 2.41778 2.72997
715.00 2.46282 -.0081972
42.4822 2.62600 2.76909 2.47626
716.25 -.0081540
4 5.9682 2.83652 2.80865 2.48980 -.0081 139
717.50 49.5040 3.04938 2.84865 2.50346 -.0080770
718.75 53.0900 3.26459 2.88910 2.51722 -.0080432
720.00 56.7269 3.48217 2.93001 2.53109 -.0080125
721.25 60.4152 3.70215 2.97138 2.54506 -.0079847
722.50 64.1556 3.92455 3.01322 2.55913 •.0079598
723.75 67.9485 4.14940 3.05552 2.57330 -.0079378
725.00 71 .7946 4.37670 3.09831 2.58757 .0079186
165
1 41 11 2 7
5
Table 18. (Continued),
Propane Isothenn at 140 K

i i Der ivati ve Curvature
kg/m3 MPa MPa.m3/kg MPa/K MPa/K^
.00 .0001 .99985 .02639 .00000 -.0000000
.0001 .00000 .94295

1 1.96937 -.0061040
678.75 1.7229 .09616 .96429
1 1.97729 -.0060730
680.00 4. 1973 .23383 .99480
1 1.98860 -.0060311
681.25 6.7100 .37313 2.02563 2.00001 -.0059915
682.50 9.2615 .51408 2.05678 2.01 152 -.0059541
683.75 11.8521 .65667 2.08825 2.02312 -.0059189
685.00 14.4823 .80093 2.12004 2.03482 -.0058858
686.25 17, 1524 .94687 2.15216 2.04662 -.0058547
687.50 19.8628 1.094 50 2.18460 2.05850 -.0058257
688.75 22.6140 1.24384 2.21738 2.07049 -.0057986
690.00 25.4064 1.39489 2.25049 2.082 56 -.0057735
691.25 28.2404 1.54769 2.28395 2.09472 -.0057503
692.50 31 .1 164 1.70222 2.31774 2.10697 -.0057290
693.75 34.0349 1.85853 2.35187 2.1 1932 -.0057095
695.00 36.9963 2.01660 2.38635 2. 13175 -.0056918
696.25 40.0010 2. 17647 2.421 19 2.14426 -.0056759
697.50 . 43.0494 2.33814 2.45637 2.15687 -.0056617
698.75 46. 1421 2.50163 2.49192 2. 16956 -.0056492
700.00 49.2794 2.66695 2.52782 2.18233 -.0056384
701.25 52.4617 2,8341 2.56409 2.19518 -.0056293
702.50 55.6897 3.0031 2.6007/ Z . 2 Oo 1 -.00562 1
703.75 58.9636 3. 17404 2.63773 2.221 14 -.0056158

705.00 62 .284 3.34684 2.675 1 2.23423 -.00561 1
706.25 65.6516 3.52155 2.71287 2.24741 -.0056087

707.50 69.0664 3.69818 2.75101 2.26066 -.0056074
. ^
.03 .0008 .99896 .0301 .00001 -.0000000
657.51 .0008 .00004 .65218

1 1.69146 -.0042366
658.75 2.0638 .10385 .67891
1 1.70179 -.0042167
660.00 4.1795 .20991 1.70616 1.71229 -.0041980
661 .25 6.3293 .31728 .73368
1 1.72287 -.0041806
662.50 8.5138 .42598 .76147
1 1.73352 -.0041645
663.75 10.7331 .53601 .78953
1 1.74425 -.0041495
665.00 12.9877 .64739 1.81787 1.75505 -.0041358
666.25 15.2779 .76012 .84650
1 1.76592 -.0041233
667.50 17.6041 .87421 1.87540 1.77687 -.0041 19
1
668.75 19.9665 .98968 1.90458 1.78789 -.0041017

670.00 22.3656 1.10653 1.93405 1.79899 -.0040926
671 .25 24.8018 1.22477 .96381
1 1.81016 -.0040845
672.50 27.2753 1.34441 1.99385 1.82140 -.0040776
673.75 29.7865 1.46547 2.02419 1.83271 -.0040716
675.00 32.3359. 1.58795 2.05482 1.84409 -.0040668
676.25 34.9237 1.71 186 2.08574 1.85554 -.0040629
677.50 37.5502 1.83721 2.1 1697 1.86707 -.0040600
678.75 40.2162 1.96402 2.14849 1.87866 -.0040582
680.00 42.9217 2.09229 2.18032 1.89033 -.0040573
681.25 45.6671 2.22204 2.21245 1.90206 -.0040574
682.50 48.4529 2.35327 2.24489 1.91386 -.0040584
683.75 51 .2795 2.48600 2.27764 1.92573 -.0040603
685.00 54.1472 2.62023 2.31070 1.93766 -.0040632
686.25 57.0564 2.75598 2.34407 1.94967 -.0040670
687.50 60,0075 2.89326 2.37777 1.96174 -.0040717
688.75 63.0009 3,03208 2.41 178 1.97387 -.0040773
690.00 66.0371 3.17244 2.44612 1.98607 -.0040837
691 .25 69.1 164 3.31437 2.48079 1.99834 -.0040910
156
5
t / A
1 u 71
11
Propane Isotherm at 180 K
1
1
QO"f*hof"m
lot 111
\ 1
1
1
c^*\/^Krti~o
OL/^ \S1
1
1
c/^/^ri/^^Q
bocîiurtJ
Den s ty i Pressure z Hpp Iv/rii"
LyC7l V Q \tf^
vv? 1 1
1
1
RciP
\JK3\ I
1 V O 1
i
1
\/o
VC L*U 1 VCl 1 Ul fcS
kg/fn3 MPa MPa •m3 /kn |yipa/f< Fir o/ r\
. 15 .0050 .99585
636.85 .0050 .00023 1 .39334 I • ^ ^ J J c. - nn9Qft 1
637.50 .9157 .04232 1 .40575 1 .46049 -.0099779

638.75 2.6879 .12399 1 .4297o 1 .47007 -.0029703
640.00 4.4902 .20672 1 .45405 1 .^1912 -.002964
641 .25 6.3231 .29054 1 .47856 1 .48942 -.0029587
642.50 8. 1867 .37544 1 .50331 1 .49919 -.0029540
643.75 10.081 .46143 1 .52830 1 .50902 -.0029500
645.00 12.0076 .54853 1 .55354 1 .51891 -.0029468
646.25 13.9654 .63673 1 .57903 1 .52886 -.0029442
647.50 15.9553 .72605 1 .60476 1 .53887 -.0029423
648.75 17.9774 .8 1649 1 .63075 1 .54894 -.002941
650.00 20.0322 .90807 1 .65698 1 .55906 -.0079405
• \J\J C P^\J^
651 .25 22. 200 1 1 .00078 1 .68347 1 .56925 -.0099405

652. 50 24.2410 1 .09464 1 .71022 1 .57950 - .00794 1
653.75 26 .3957 1 . 8966

1 1 .73722 1 .58981 - • nn9Q49's
£.y ^ £. J
655.00 28.5842 1 .28584 1 .76447 - 0099444
656.25 "50.8069 1 .38319 1 .79199 1 .61 061 -.0099469
657.50 33.0643 1 .48172 1 .81977 1 .62 09 1 -.0099500
658 .75 35.3565 1 .581 43 1 .8478 1 .63164
1 .68234 1 .87612 1 .64224 - 009Q5ftO
661 .25 40.0469 1 .78446 1 .90470 1 .65290 0099678
- • \J\J £-7 \J£-\j
663.75 44.8809 1.99232 1.96265 1.67441 -.0029741

665.00 47.3525 2.09809 1.99204 1.68524 -.0029806
. Rfil
OU 1
1 9 90'iOQ 9 09 70 1 - 009Qft77
667.50 52.4069 2.31334 2.05163 1.70709 -.0029952
868.75 54.9903 2.42284 2.08185 1.71810 -.0030034
670.00 57.61 16 2.53360 2.1 1234 1.72917 -.0030120
671 .25 60.2712 2.64563 2.14312 1.74030 -.0030212
672.50 62.9695 2.75893 2.17418 1.75148 -.0030309
673.75 65.7068 2.87352 2.20553 1.76272 -.003041
D / . UU DO . 'toj J 9 9*^7 1
- .UU_)Ui> 0 1
O / O . ^J 71 9QQQ 9 9fiQnQ - OO'Ôfi'^1
1
1
c;nthprm at
3^1 1 cj 900 Kr\
Z.UU III 1
. 0901
UZU 1 . O'^fiflR
u_?oo^ 000 0
.UUU 1
1
0000000
- .uuuuuuu
fil "5 fifi 0901 nnoft? 11 . 16045

UU*T ^
1 1 .251 19 -.0070997
617 . 50 9 RTR 1 1 . 9146
1 1 .96400 -.0070990
5.2 198 1 .23427 1 ,28 56 1 -.0071 004
622.50 8 .3599 • J J\J 1 1 . 27794 1 .29932 -.007 1034
fi9R 00 11 . O
1 1
ft 09
uz 1
1
4Q9ft 1 1 "^9940 1 179ft -.U 007inR9
Ui. uo^ 1
fi97 "SO 1/1 QVÎ • /

1
1
^fi7QA
. _?o / y^ 009 •+
- . UUZ. 4fi
u 1
1
1
1
c-io 00
DjU.UU io .'t
10 4c;n7
3U / • II OOJ> 1 A A9Q
1 0091994
-.U UZ. ^Z. H 1
(^^9 SO 99 OAS'^ Q9497 I .HO J J 1 I.J/ ^-JO - 0091318

00
fi'^S 9S 7SQ9 1 "509 7'5 1.391 15 -.0021 426
637.50 29.5947 1.23106 1.55885 1.41013 -.0021548
640.00 33.5542 1.39031 1.60892 1.42931 -.0021684
642.50 37.6401 1.55354 1.65994 1.44869 -.0021833
645.00 41 .8547 1.72080 1 .71 194 1.46827 -.0021995
647.50 46.2006 1.89214 1.76492 1.48806 -.0022171
650.00 50.6802 2.06761 1.81889 1.50805 -.0022359
652.50 55.2959 2.24728 1.87388 1.52825 -.0022560
655.00 60.0504 2.431 19 1.92988 1.54865 -.0022774
657.50 64.9462 2.61941 1.98692 1.56925 -.0023001
660.00 69.9859 2.81 197 2.04500 1.59005 -.0023239
167
Isotherm 1 sochore 1sochore

Dens tyi Pressure Z Der vat ve i i Der vati ve
i Curvature
kg/m3 MPa MPa •m3/kg MPa/K MPa/K^
1 .50 .0605 .97418 .03937 .00029 -.0000002
593.67 .0605 .00245 .94999 1.07129 -.0014563

595.00 1.3397 .05428 ,96935 1.07964 -.0014605
597.50 3.8091 .15369 1.00626 1.09542 -.0014691
600.00 6.3717 .25601 1.04395 1 . 1 1 137 -.0014788
602.50 9.0295 ,36129 1.08244 1.12749 -.0014894
605.00 11 .7846 .46958 1 . 1 2 1 72 1.14379 -.0015009
607.50 14.6388 .58091 1.16182 1.16026 -.0015133
610.00 17.5944 .69534 1.20274 1. 17691 -.0015265
612.50 20.6532 .81289 1.24449 1 19373
. -.001 5405
615.00 23.8175 .93363 1.28709 1.21072 -.0015554
617.50 27,0894 1.05758 1.33054 1.22790 -.0015710
620.00 30.4710 1. 8480
1 1.37485 1.24525 -.0015874
622.50 33.9644 1.31534 1.42004 1.26278 -.0016046
625.00 37.5719 1.44922 1 .46611 1.28049 -.0016225
627.50 41 .2957 1.58651 1.51308 1.29838 -.0016413
630.00 45. 1380 1.72725 1.56095 1.31645 -.0016607
632.50 49. 1012 1.87148 1.60974 1.33470 -.0016810
c;-z 107c nn 7n
— •UU q
ODD UU jD • \o / D / u
1
y I 1
637.50 57.3993 2. 17059 1.7101 1.37176 -.0017237

640.00 61 ,7389 2.32558 1 .76172 1.39056 -.0017462
DU • Z.UO /
1 ft 1 d7P. .'JUl 1 \jy J
645.00 70.81 11 2.64663 1 .86782 1.42871 -.0017935
2.50 .1091 .96423 .04207 .00049 -.0000003

3.43 .1479 .95125 .04087 .00068 -.0000007
570.55 .1479 .00573 .75993 .91069 -.0009718

572.50 1.6519 .06377 .78402 .92161 -.0009819
575.00 3.6513 .14033 .81555 .93575 -.0009953
577.50 5.7303 .21928 .84779 .95003 -.0010092
580.00 7.8908 .30065 .88074 .96446 -.0010235
582.50 10.1346 .38448 .91441 .97904 -.0010382
585.00 12.4635 .47081 .94882 .99378 -.0010533
587.50 14.8793 .55968 .98397 1.00866 -.0010689
590.00 17.3839 .65112 1.01986 1.02370 -.0010849
592.50 19.9792 .74517 1.05653 1.03889 -.001 1012
595.00 22.6672 .84187 1.09396 1.05424 -.001 1 180
597.50 25.4497 .94126 1.13217 1.06974 -.001 1352
600.00 28.3287 1.04337 1.17118 1.08541 -.001 1528
602.50 31 .3063 1.14825 1.21098 1,10123 -.001 1708
605.00 34.3843 1.25594 1.25160 1.1 1721 -.001 1892
607.50 37.5649 1.36647 1.29304 1 3336
. 1 -.0012080
610.00 40.8502 1.47988 1.33530 1.14967 -.0012273
612.50 44.2422 1.59622 1.37841 1.16614 -.0012470
615.00 47.7430 1.71553 1.42237 1.18277 -.0012671
617.50 51.3547 1.83784 1.46719 1.19957 -.0012877
620.00 55.0796 1,96319 1.51288 1.21654 -.0013087
622.50 58.9199 2.09164 1.55945 1.23368 -.0013302
625.00 62.8776 2.22321 1,60691 1,25098 -.0013521
627.50 66.9552 2.35795 1.65527 1.26845 -.0013745
630.00 7 1 . 1 547 2.49590 1.70454 1.28609 -.0013974
168
3
5 9 . 9
4
Table 18. (ConMnued)
Propane Isot-herm at 260 K
so fhertn
1 1 sochore 1 sochory
Pressure z Der vat ve i I Der vat ve I 1 Cu r vatuce
kg/ MPa r-Pa • in5/kg MPa/K MPa/K^
2.50 .11 88 .96925 .04609 .00048 -.0000001

5.00 .2305 .94022 .04322 .001 00 -.0000009
6.90 .3106 .91 774 .04095 .00143 -.0000023
545.88 .3106 .01 161 .5891 .76557 -.0005947

547.50 1 .2778 .04761 .60574 .77359 -.0006052
550.00 2.8246 .10476 .631 80 .78608 -.000621
552.50 4.4373 .16383 .65843 .79869 -.0006377
555.00 6.1175 .22485 .68578 .81 1 43 -.0006541
557.50 7.8668 .28784 . 71 373 .82429 -.0006705
560.00 9.6867 .35285 .74232 .83729 -.0006872
562.50 1 1.5789 .41990 .771 57 .85043 -.0007039
565.00 1 3.5451 .48903 .801 49 .86369 -.0007207
567. 50 1 5.5869 .56027 .83208 .87710 - .0007376
570.00 1 7.7061 .63365 .86335 .89064 -.0007547
572.50 19.9043 .70921 .89533 .90432 -.000771
575.00 22.1833 .78697 .92800 .91 81 4 -.0007893
577.50 24. 5449 .86698 .961 39 .93210 -.0008068
580.00 26.9909 .94927 .99551 .94620 -.0008245
582.50 29.5230 1 .03387 1 .03036 .96045 -.0008424
585 .00 32. 1 433 1 .1 2082 1 .06595 .97484 -.0008605
587.50 34.8534 1 .21 01 1 . 0229 1 .98938 -.0008787
590 .00 37.6553 1 .301 39 1 . 3940 1 1 .00406 -.0008972
592.50 40.5510 1 .39609 1 . 7727 1 1 .01890 -.0009160
595.00 43.5423 1 .49278 1.21593 1 .03388 -.0009349
597.50 46.6313 1 .59199 1 .25538 1.04902 -.0009541
600.00 49.8199 1 .69376 1 .29563 1 .06430 -.0009736
602.50 53.1101 1 .79813 1.33663 1 .07974 -.0009933
605.00 56.5040 1 .9051 1 .37856 1 .09534 -.0010133
607.50 60.0036 2.01480 1 .42126 1 . 1 1 1 09 -.0010335
610.00 63.61 10 2.12718 1 .46481 1 .12699 -.0010541
612.50 67.3284 2.24230 1.50920 1 .14305 -.0010749
615.00 71 .1577 2.36020 1.55445 1 .15927 -.001 0961
169
51 0
2
5 5 . 3 4
3
Propane 1 sothenn at 280 K
sotherm
1 1 sochore 1sochore
Den s ty
i Pressure Z Der vat ve
i i Der vat ve
I i Curvature
kg/ ir^ MP a M'â • [(v5 /k g MPa/K MPa/K^
2.50 .1234 .97312 .05006 .00048 -.0000001

5.00 .2504 .94841 .04747 .00099 -.0000005
7.50 .3657 .92367 .04483 .00153 -.0000014
1 0.00 .4745 .89871 .0421 .00211 -.0000032
1 2.50 .5764 .87345 .03940 .00274 -.0000065
1 2.64 .581 8 .87206 .03925 .00277 -.0000068
51 9.05 .5818 .021 23 .43728 .63300 -.0002899

520.00 1.0001 .03643 .44501 .63709 -.0002971
522. 50 2.1 385 .07752 .46575 .64795 -.0003157
525 . 00 3.3293 .1 201 .48703 .65891 -.0003340
527. 50 4.5741 . 6425
1 .50883 .66999 -.0003521
530.00 5.8740 .20993 .531 19 .681 1 8 -.0003699
532. 50 7.2305 .25720 .55410 .69243 - .0003875
535 .00 8.6449 .30607 .57758 .70390 -.0004050
53 7.50 1 0. 1 1 88 .35659 .601 63 .71 543 -.0004223
540.00 1 1 .6536 .40877 .62626 .72 709 -.0004395
542 .50 1 3 .2506 .46265 .651 49 .73886 -.0004567
545.00 1 4.91 1 .51 825 .67732 .75076 -.0004738
547. 50 1 6.6378 .5 7561 .70377 . 76273 -.0004908
550.00 1 .4309
3 .63475 .73083 .77493 -.0005078
552.50 20.2925 .69570 . 75853 .78720 -.0005243
555.00 22.2241 .75849 .78686 .79960 -.000541
557 .50 24.22 73 .8231 . 31 585 . 81 21 -.0005588
560.00 26.3039 .88971 .84549 .82479 -.0005759
562.50 28.4553 .95820 .87530 .83758 -.0005930
565.00 30.6334 1 .02866 .90679 .85050 -.00061 02
567.50 32.9899 1.10111 .93847 .86356 -.0006275
570.00 35.3763 1. 75591 .97084 , .87675 -. 0006443
572.50 3 7.3446 1.25212 1.00391 .89003 -.0006623
5 75.00 40.3965 1.33074 1.03770 .90355 -.0006798
577.50 43.0338 1.41 143 1.07222 .91 715 -.0006975
580.00 45.7582 1.49437 1.1074 7 .93090 -.00071 53
582.50 48.571 7 1.57944 1.1 4346 .94478 -.0007333
585.00 51 .4761 1.66674 1.18020 .95831 -.000751
587.50 54.4733 1.75628 1 .21 771 .97298 -.0007696
590.00 57.5653 1 .8481 1 .25593 .98730 -.0007831
592.50 60.7539 1.94224 1 .29503 1.00176 -.0008067
595.00 64.041 2.03873 1 .33488 1.01636 -.0008255
597.50 57.4289 2.13759 1 .37552 1 .031 11 -.0003445
600.00 70.9194 2.23888 1 .41697 1 .04601 -.0008637
170
Propane Isotherm at 298.15 K
I sotherm Isochore Isochore

Dens ty
1 Pressure Der vati ve
i Derivative Curvature
kg/m3 MPa MPaTTi3/kg MPaA MPa/K^
5.00 .2682 .95428 .05123 .00098 -.0000003

10.00 .5123 -91 132 .04640 .00207 -.0000018
15.00 .7321 .86823 .04152 .00328 -.0000056
20.00 .9274 .82489 .03659 .00466 -.0000143
20.69 .9523 .81893 .03591 .00487 -.0000162
492.06 .9523 .03443 .31561 .52153 .0000534

495.00 1 .9078 .06856 .33459 .53258 .0000785
500.00 3.6643 .13036 .36830 .55167 .0001 188
505.00 5.5938 .19704 .40385 .571 14 .0001568
510.00 7.7059 .26878 .44131 .59103 .0001930
515.00 10.0102 .34576 .48075 .61 134 .0002279
520.00 12.5169 .42819 .52225 .63208 .0002618
525.00 15.2363 .51625 .56587 .65326 .0002950
530.00 18.1792 .61015 .61 169 .67490 .0003277
535.00 21.3570 .71011 .65978 .69701 .0003600
540.00 24.7809 .8 633
1 .71020 .71959 .0003921
545.00 28.4630 .92902 .76304 .74266 .0004241
550.00 32.4155 1.04841 .81837 .7 6623 .0004561
555.00 36.6509 1.17471 .87625 .79030 .0004883
560.00 41.1823 1.30817 .93676 .81488 .0005206
565.00 46.0231 1.44900 .99998 .83999 .0005532
570.00 51 .1868 1.59743 1.06598 .86562 .0005862
575.00 56.6876 1.75372 1.13483 .89179 .0006196
580.00 62.5399 1.91809 1.20660 .91851 .0006535
585.00 68.7586 2.09080 1.28138 .94579 .0006879
Propane I sotherm at 300 K
5.00 .2700 .95482 .05161 .00098 -.0000003

10.00 .5161 .91245 .04682 .00206 -.0000017
15.00 .7382 .87002 .04200 .00327 -.0000053
20.00 .9361 .82741 .03714 .00464 -.0000131
21.70 .9979 .81284 .03546 .00515 -.0000177
489.13 .9979 .03607 .30407 .51057 -.0000307

490.00 1.2660 .04567 .30950 .51379 -.0000384
495.00 2.8929 .10332 .34157 .53243 -.0000804
500.00 4.6846 .16564 .37542 .55144 -.0001196
505.00 6.6502 .23281 .411 12 .57085 -.0001567
510.00 8.7990 .30501 .44873 .59067 -.0001922
515.00 11.1408 .38244 .48833 .61092 -.0002266
520.00 13.6858 .46529 .52999 .63159 -.0002600
525.00 16.4443 .55374 .57378 .65272 -.0002928
530.00 19.4272 .64802 .61977 .67430 -.0003251
535.00 22.6458 .74832 .66803 .69635 -.0003571
540.00 26.1115 .85485 .71864 .71887 -.0003888
545.00 29.8 3 62 .96783 .77166 .74188 -.0004206
550.00 33.8322 1.08748 .82717 .76539 -.0004523
555.00 38.1 121 1.21402 .88524 .78940 -.0004842
560.00 42.6890 1.34766 .94594 .81392 -.0005163
565.00 47.5761 1.48865 1.00936 .83897 -.0005487
570.00 52.7872 1.63722 1.07555 .86454 -.0005815
575.00 58.3364 1.79360 1.14460 .89065 -.0006147
580.00 64.2381 1.95802 1.21658 .91731 -.0006484
585.00 70.5072 2.13074 1.29156 .94452 -.0006826
171
4 1
sotherm
Density Pressure Z Der vat ive
i Der vat ive
i Curvature
kg/m--' |vpa MPa • 17)3 /kg Mra/I\ Mra/K
5.00 .2896 .96001 .05569 .00098 -.0000002

10.00 .5571 .92329 .051 30 .00203 -.000001
15.00 .8027 .88695 .04696 .00319 -.0000031
20.00 1.0268 .85089 .04267 .00445 -.0000067
25.00 1 .2295 .81513 .03844 .00584 -.0000126
30.00 1.4112 .77966 .03425 .00737 -.0000224
35.00 1 .5721 .74445 .03009 .00 907 -.0000395
35.90 1 .5988 .7381 .02934 .00939 -.0000439
454.43 1.5988 .05831 .18978 .39604 .0002105

455.00 1.7071 .06218 .19226 .39777 .0002042
460.00 2.7243 .09816 .21485 .41316 .0001530
465.00 3.8580 .13751 .23883 .42886 .0001077
470.00 5.1151 .18038 .26427 .44489 .0000666
475.00 6.5032 .22691 .29122 .461 28 .0000288
480.00 8.0299 .27726 .31974 .47803 -.0000067
485.00 9.7033 .33159 .34990 .49516 -.0000404
490.00 11.5317 .39005 ,38177 .51267 -.0000726
495.00 13.5239 .45282 .41540 .53059 -.0001038
500.00 15.6888 .52005 .45086 .54892 -.0001341
505.00 18.0357 .59192 .48822 .56767 -.0001637
510.00 20.5742 .66862 .52753 .58684 -.0001929
515.00 23.3144 .75031 .56888 .60646 -.0002217
520.00 26.2665 .83719 .61233 .62651 -.0002503
525.00 29.4413 .92944 .65 794 .64703 -.0002787
530.00 32.8496 1 .02726 .70579 .66800 -.0003071
535.00 36.5030 1 . 3084
1 .75594 ,68945 -.0003355
540.00 40.4130 1 .24037 .80847 .71 137 -.0003641
545.00 44.5918 1 .35608 .86346 .73377 -.0003927
550.00 49.0518 1 .47815 .92096 .75667 -.0004216
555.00 53.8057 1 .60680 .98106 .78007 -.0004508
560.00 58.8668 1 .74224 1 .04382 .80398 -.0004804
565.00 64.2485 1 .88469 1 .10932 .52840 -.0005102
570.00 69.9647 2.03437 1 .17763 .85335 -.0005406
172
3
4 8
5
1 4
5 9
Propan e I sotherm at 340 K
sotherm
1 1 socliore 1sochore
Density Pressure Z Der vat ve
i i Der vat ve
i i Curvature
kg/m-5 MPa MPaTTi3/kg MPa/K MPa/K^
5.00 .3091 .96433 .05972 .00097 -.0000002

10.00 .5976 .9321 .05567 .00202 -.0000008
15.00 .8660 .90055 .051 70 .00314 -.0000021
20.00 1.1147 .86943 .04781 .00435 -.0000042
25.00 1 .3443 .83876 .04402 .00565 -.0000075
30.00 1.5550 .80856 .04031 .00704 -.00001 21
35.00 1 .7475 .77882 .03668 .00854 -.0000184
40.00 1.9220 .74953 .0331 .01 01 -.0000270
45.00 2.0791 .72069 .02969 .01 185 -.0000390
50.00 2.2190 .69230 .02632 .01368 -.0000559
55.00 2.3424 .66434 .02302 .01566 -.0000814
59.00 2.4293 .64224 .02042 .01 736 -.0001 1 34
41 1 .22 2.4293 .09215 .09518 .28646 .0004850

415.00 2.8079 .10554 .10536 .29545 .0004259
420.00 3.3701 .12517 .1 969
1 .30755 .000361 2
425.00 4.0065 .14705 .1 3504 .31991 .0003072
430.00 4.7223 .1 7131 .15147 .33254 .0002606
435.00 5.5230 .19805 .1 690 .34548 .0002193
440.00 6.4144 .22741 .18774 .35873 .0001 81
445.00 7.4024 .25948 .20769 .37232 .0001 475
450.00 8.4934 .29442 .22892 .38624 .0001 154
455.00 9.6939 .33234 .251 48 .40051 .0000851
460.00 1 .0106
1 .37338 .27544 .41 515 .0000562
465.00 12.4506 .41767 .30083 .4301 .0000284
470.00 14.0214 .46536 .32773 .44552 .0000014
475.00 15.7305 .51659 .3561 .461 28 -.0000248
480.00 17.5859 .57150 .38625 .47743 -.0000506
485.00 19.5958 .63026 .41 799 .49397 -.0000759
490.00 21 .7687 .69300 .45147 .51093 -.0001010
495.00 24.1 134 .75989 .48675 .52829 -.0001 258
500.00 26.6392 .83109 .52388 .54607 -.0001505
505.00 29.3555 .90676 .56295 .56428 -.0001751
510.00 32.2721 .98708 .60401 .58292 -.0001997
515.00 35.3990 1 .07221 .6471 3 .60200 -.0002244
520.00 38.7469 1 .16233 .69238 .62153 -.0002492
525.00 42.3265 1 .25762 .73982 .64151 -.0002741
530.00 46.1489 1 .35826 .78953 .661 95 -.0002992
535.00 50.2256 1 .46443 .84157 .68286 -.0003245
540.00 54.5686 1 .57632 .89602 .70424 -.0003500
545.00 59.1900 1 .6941 .95295 .72610 -.0003759
550.00 64.1024 1 .81806 1 .01243 .74845 -.0004021
555.00 69.3186 1 .94829 1 .07453 .771 29 -.0004287
173
2
7
5 4
1 4 4

Density Pressure Z Der i V at i ve Der ivati ve Curvature
kg/m3 MPa MPaTn5/kg MPa/K MPa/K^
5.00 .3188 .96623 .061 73 .00097 -.0000001

10.00 .6177 .93599 .05783 .00201 -.0000007
15.00 .8973 .90643 .05402 .00312 -.0000018
20.00 1.1580 .87738 .05030 .00431 -.0000035
25.00 1.4004 .84882 .04667 .00558 -.0000061
30.00 1.6249 .82075 .0431 .00694 -.0000096
35.00 1.8320 .79316 .03971 .00838 -.0000142
40.00 2.0221 .76605 .03636 .00990 -.0000202
45.00 2.1958 .73941 .03311 .01 152 -.0000279
50.00 2.3534 .71324 .02996 .01322 -.0000377
55.00 2.4955 .68755 .02689 .01502 -.0000503
60.00 2.6225 .66233 .02393 .01692 -.0000669
65.00 2.7350 .63761 .02107 .01892 -.0000892
70.00 2.8334 .61 337 .01 831 .02104 -.0001 210
75.00 2.9183 .58963 .01565 .02330 -.0001701
76.97 2.9482 .58039 .01 462 .02425 -.0001981
383.34 2.9482 .1 1654 .05595 .23168 .0006864

385.00 3.0435 .11979 .05895 .23498 .0006467
390.00 3.3618 .13062 .06849 .24504 .0005488
395.00 3.7296 .14308 .07880 .25530 .0004735
400.00 '
4.1 511 .15726 .08994 .26579 .0004125
405.00 4.6305 .17325 .10195 .27654 .0003614
410.00 5.1721 .191 16 .1 1487 .28757 .0003171
415.00 5.7808 .21108 .12876 .29889 .0002780
420.00 6.4614 .23312 .14366 .31051 .0002426
425.00 7.2191 .25740 .15961 .32245 .0002101
430.00 8.0593 .28401 . 7666
1 .33471 .0001799
435.00 8.9876 .31308 .19485 .34731 .0001 51
440.00 10.0098 .34473 .21425 .36025 .0001243
445.00 1 1 .1321 .37907 .23489 .37353 .0000983
450.00 12.3608 .41624 .25682 .38717 .0000732
455.00 13.7026 .45635 .2801 .401 18 .0000487
460.00 15.1643 .49954 .30480 .41555 .0000248
465.00 16.7530 .54594 .33095 .43029 .000001
470.00 18.4763 .59569 .35861 .44542 -.0000218
475.00 20.341 .64893 .38784 .46093 -.0000447
480.00 22.3573 .70581 .41869 .47684 -.0000674
485.00 24.531 .76646 .451 24 .4931 -.0000901
490.00 26.8727 .83104 .48554 .50986 -.0001 126
495.00 29.3899 .89970 .52165 .52698 -.0001352
500.00 32.0923 .97261 .55963 .54453 -.0001 579
505.00 34.9894 1 .04991 .59956 .56250 -.0001806
510.00 38.091 1.13178 .64149 .58090 -.0002034
515.00 41 .4078 1.21838 .68549 .59975 -.0002264
520.00 44.9497 1.30988 .73164 .61903 -.0002496
525.00 48.7279 1 .40645 .77999 .63877 -.0002730
530.00 52.7534 1 .50828 .83063 .55897 -.0002967
535.00 57.0380 1 .61554 .88361 .67963 -.0003207
540.00 61 .5936 1 .72842 .93901 .70076 -.0003449
545.00 66.4323 1 .84710 .99690 .72237 -.0003696
550.00 71 .5669 1 .97177 1 .05736 .74447 -.0003946
174
8 9
4 4
sotherm
Der Wat ve
• -1-
Dens ty 1 rressure L i Der vat ve
i i Curvature
kg/ iâ Mra • nv/ Kg Mra/I\ Mra/l\
10.00 .6377 .93953 .05997 .00200 -.0000006

20.00 1.2009 .88463 .05274 .00428 -.0000030
R'^1 7Q .UUDcSP — .UUUUU /o
7RnQn nnQ79 — OOOni RQ
9.4 f!4n • 7"^1 RQ . \J J J J\J 01 9Qn — nnon9Hi
9 7RRR • fiR4 7ft • \) £^ 1 KJ f 01 ^"^7 - n0004'=iR
70 nn n9ni 9 — nnnn 71
Rn nn 3. 2385 .59639 .ni 7fii n94i fi - nnni oq7
90.00 3 .3928 ,55537 .01 331 .02849 - .noni 799
1 nn . nn 3.5064 .51 657 .00949 .0331
1 05 .05 3.5498 .49781 .00773 .03579 -.nnn4995
345. 52 3.5498 .1 51 36 .02308 . 7379

1 .001 0800
350.00 3.6630 .1 541 .02749 . 8069
1 .0008996
3.9928 .16340 .03884 .1 9646 .nnnfS4Rn
370.00 4 ,4477 • 17709 .05254 .21 305 •nnnsnfi9
5. 0525 .1 9588 .06888 .23062 .noo4oa7
390.00 5 8352
. .22043 .ORfllR .24930
4nn nn 6. 8269 .251 44 -1
• I
07"^
^
1I \j 1 .2691 0009797
41 n
HIV-'. nn R nfil R ?RQfiR 9Qn91 00091 Q9
420.00 9.5773 .33594 • 1 6692 . -* 1 £. JJ 0001 70R
A'^n nn 11 41 44 "^Qi n7 0001 9S7
4/1 n nn 1 fil 7R ^f^1 97 OOOOR9f^
450.00 16.2357 .53153 ,3^11A .0000409
460.00 19.3205 .61878 .33369 .41566 -.0000002
470.00 22.9290 .71872 .38902 .44510 -.0000409
480.00 27.1221 .83244 .45069 .47609 -.0000817
490.00 31 .9654 .96107 .51916 .50868 -.0001228
500.00 37.5296 1.10580 .59493 .54292 -.0001645
510.00 43.8900 1.26785 .67851 .57885 -.0002069
520.00 51 .1276 1.44852 .77043 .61653 -.0002502
530.00 59.3283 1.64914 .87125 .65601 -.0002947
540.00 68.5840 1 .871 12 .98151 .69734 -.0003405
175
0
7 5 e3
4
1 sotherm 1 sochore I ^nr hnr

Den s tyi Pressure z Der vat ve
i i Der vat ve i i Curvature
Wa MPaTTi3/kg MPa/K MPa/K^
10.00 .6477 .94 20 1 .061 03 .00200 -.0000005

20.00 1.2223 .88802 .05394 .00426 -.0000027
30.00 1.7280 .83694 .04726 .00681 -.0000071
40.00 2.1687 .78780 .04095 .00965 -.00001 43
50.00 2.5481 .74051 .03501 .01 277 -.0000248
60.00 2.8701 .69506 .02945 .0161 -.0000394
70.00 3.1386 .651 50 .02432 .01 979 -.0000592
80.00 3.3581 .60993 .01965 .02367 -.0000861
90.00 3.5333 .57045 .01548 .02776 -.0001232
100.00 3.6693 .5331 .01 180 .03207 -.0001 769
1 0.00
1 3.7711 .49814 .00864 .03658 -.0002620
120.00 3.8436 .46541 .00595 .041 34 -.0004220
1 29.01 3.8877 .43786 .00388 .04602 -.0007955
31 6.85 3.8877 .1 7829 .00970 . 4060

1 .001 621
320.00 3.9208 .1 7804 .01 135 . 4449
1 .001 3495
330.00 4.0638 .1 7894 .01 751 .1 5699 .000901
340.00 4.2763 .1 8276 .02528 .17013 .0006853
350.00 4.5758 .18997 .03494 .18416 .0005525
360.00 4. 9823 .201 1 .04674 .19918 .0004589
370.00 5.51 87 673
.21 ,06095 .21 525 .0003865
380.00 6 . 2 031 .23747 .07785 .23245 .0003268
390.00 7.0856 .26399 .09773 .25081 .0002750
400.00 8.1 758 .29700 .12089 .27038 .0009283
41 0.00 9.51 54 .33723 .14766 .291 21 .0001 851
420.00 1 1 . 421
1 .38548 .17837 .31334 .0001 441
430.00 13.0971 .44258 .21 337 .33680 .0001 045
440.00 15.4251 .50940 .25304 .36164 .0000657
450.00 18.1748 .58687 .29777 .38791 .0000274
460.00 21 .3988 .67595 .34797 .41564 -.0000108
470.00 25.1539 .77766 .40407 .44487 -.0000492
480.00 29.5015 .89307 .46653 .47566 -.0000880
490.00 34.5073 1 .02328 .53581 .50805 -.0001 273
500.00 40.2421 1 .16948 .61242 .54209 -.0001674
510.00 46.7817 1 .33287 .69686 .57781 -.0002084
520.00 54.2071 1.51473 .78967 .61528 -.0002505
530.00 62.6047 1 .71 638 .89139 .65454 -.0002938
176
9
3
7 4
8
1 4
2
7
1 3
7 6
9
2
2
Propane Isotherm at 369.85 K
1 soi'h©rm 1
1 ôphnrp
^ \_> 1 1 v./ 1
1 cinrhnr*^
L/C?! lot 1
y \ \ ^^^ U I z l-'^t 1 V U 1 1 V/ u 1 V a uL^
1
k g/ni3 MPa MPa • m3 /k g MPa/K MPa/K^
0.00
1 .6574 .94275 .06206 .00200 -.0000005
20.00 1.2429 .891 1 .0551 .00425 -.0000025
30.00 1 .7609 .841 72 .04856 .00678 -.0000066
40.00 2.21 53 .7941 .04238 .00958 -.00001 30
50.00 2 . 6098 .74848 .03657 .01 265 -.0000272
fin 00 2.9480 .70457 .031 1 .01 598 -.0000346
70.00 3.2339 .66249 .0261 .01 953 -.0000507
80.00 3.471 .62234 .021 55 .02329 -.000071
90.00 3-666fi .58421 .01 747 .02724 -.0000970
1 00 00 3.8229 .5482 .01 388 .031 34 -.0001 294
1 0.00
1 3.9458 .51 439 .01 078 .03556 -.0001 703
1 70 00 4.0402 .48281 .0081 .03989 -.0007278
4 1 1 n7 9 H J -JH J nnfini n449R
. UHH ZQ - nnn?Qi
1 Art nn 4 1 fil 7 49fi9R nn49'i n4R79 • \J\J\J -) 1
1 "in nn A. 1 Q71 .401 24 .00287 .0531 m \J\J\j J 1
1 fin nn 4 99n'^ nni R9 ns7fii

1 10 00 4 9'^44 ^'i 71 Q nni nfi nfi9nn — OOlOOfiS
1 Rn nn 4 9499 ^^7Qfi nnn'i4 .UDD-J
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1
- noi RAO"^
1 on nn 4 94^R '^9n4'=; 00077 9\J n7n4R
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9nn nn 9479
4 . Z*t
^ /z Tn4R9 nnnnfi 9\J n744S
I^HJ - 00'=i'^P7P
Tin nn 4 94 74 9Qnn4 nnnn i 019.00
99n nn 4 947^
^ . Z4 / J . 97fiRfi
Z / DOD . uuuuu nRi n4 —/I 07Q9 997
'j'^n nn H . 947^
4 Z4 / . 9fi4R9
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4 94Q7 94'^7fi nnn'î nQ97Q
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9 fin nn 4 9RCin 9'^4fiR nnn 7Q nQR'';4 • 00999^7
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97n.nn 4 .2668 . 99fifi1 .nni fi'i . 1 0466 .001 ftO'^R

09,0.00 4. 2896 .21 969 .00301 . 1 1 176 001 9"^4S
290.00 4. 3292 .21 407 .00504 .1 1 96 8 .OOOQQ'^4
• WWW-? *-t
^nn 00 .20999 .00790 . 2846

1 000R947
31 0.00 4 .4907 .20773 .01 80 1 .13812 .0007000
• WWW www /
320.00 4.6332 .20762 .01 692 . 1 4872 .0006035

330.00 4.8339 . 21 006 .02349 . 6028
1 .0005259
340.00 5.1 085 .21 546 .031 73 . 7284
1 .000461
350.00 5.4748 .22431 .04188 .18645 .0004057
360.00 5.9533 .2371 .05420 .201 1 .0003565
370.00 6.5669 .25451 .06895 .21 694 .00031 1
380.00 7. 341 .27704 .08641 .23389 .0002706

390.00 8.3051 .30537 . 0687
1 . 25203 .000231
400.00 9. 4897 .34021 . 3063
1 .271 41 .0001 942
41 0.00 1 0.9298 .38228 . 5802
1 .292 04 .0001 578
420.00 1 2.6634 .43236 . 8937
1 .31 398 .0001 220
430.00 1 4.731 .491 29 .22504 .33726 .0000866
440.00 17.1798 .55990 .26539 .361 93 .000051
450.00 20.0564 .63913 .31082 .38801 .0000157
460.00 23.4145 .72992 .361 74 .41556 -.0000202
470.00 27.3110 .83328 .41858 .44462 -.0000566
480.00 31 .8074 .95025 .48180 .47522 -.0000936
490.00 36.9698 1.08193 .55187 .50742 -.0001314
500.00 42.8692 1.22949 .62928 .541 27 -.0001701
510.00 49.5816 1 .39412 .71455 .57680 -.0002099
520.00 57.1883 1 .57708 .80822 .61407 -.0002508
530.00 65.7758 1.77967 .91082 .65312 -.0002929
177
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0
7
1 9
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1 <^t~>r'hnP(=» 1 co^hor"*^
L/c;i 1 o t 1
y \ \ c?o 0 Ul C Lvc?) Va 1vc 1 1 LyCT 1 V a 1 1 vo Vm*
1ir*
ui Vol
V/ ?^ uir~1 0
k 9/ m-^ rir a IT a rrO //If
. llr
r\
n rli a / 1\ rli a/ r\
1 0.00 ,5677 .94434 .0631 .001 99 -.0000005

1 . 2648 .89439 .05633 .00424 - nnnnn9'^
1 7QS7 .04992 nnfi7's
40.00 2. 2645 .80067 .04389 .00952 -.00001 1
50.00 2.6746 . 75655 .03820 .01 254 -.00001 99

60.00 3.0298 .71 41 .03289 .01 581 - .0000306
70.00 3 .3339 .67359 .02799 .01929 -.0000439
80.00 3.591 .63484 .02351 .02295 -.0000601
90.00 3.8057 .59805 .01 951 .02679 -.0000799
1 00-00 3.9827 .56328 .01 598 .03075 -.0001 01
1 1 0.00 4 . 1 2 70 .53062 .01 294 .03481 -.0001
• \J\J \J 958
J \J \ £-
1 20.00 4.2431 .50008 .01 036 .03895 -.0001 523

1 30.00 4 .3356 .47168 .00821 .0431 -.0001797
1 40.00 4.4086 .44537 .00646 .04731 -.0002057
1 50.00 4.4660 .42108 .00507 .051 48 -.0002272
1 60.00 4.5110 .39874 .00399 .05563 -.0002400
1 70.00 4.5466 .37825 .0031 .05975 -.0002397
1 80 .00 4. 5755 .35951 .00263 .06385 -.0002227
190.00 4.5998 .34240 .00228 .06796 -.0001881
200.00 4.621 .32683 .0021 .0721 -.0001 377
2 0 . 00
1 4.6428 .31 268 .00211 .07643 -.0000752
220.00 4.6642 .29985 .0021 .08090 -.0000045
230.00 4.6866 .2881 .00232 .08560 .0000792
240.00 4.71 09 .27761 .00257 .09059 .0001 521
4.7388 .26809 .00304 .09593 .0009302
9f^nno A 779Q . 1 ni 74 .0003000
970 no H. 0 D/ 1 . ^ 1
nnsn"^ 1 nRnQ nnn^'^'^4
4 ft7'=)"^ .nnfi7Q . 1 1 iî n .noo3q"5i
9Qn on 941 fi4 .nnQ94 . 1 2284 .00041 96
s . UD_?
nfiî 1
ni 9Rfi 1 "^1 AO onnAi
Tin nn • Z.D 1 DO . u D y_> 1
1 4nR"'i •UUUf uou
TOO nn n99'i'i • 1
\
S1
J \
1
1
Q
y . nnn"^Qi
UUU-^ -7 1
i
1
~k~kr\
j?j>u •on
uu 949R1 • nnn"^ftRf^
UUU-JOOD
nn
~ÂC\ uu
j)4U. ^ UU4
D. nO/l 1 94Q7fi
.Z4y /D n'^RAn . 1
1
74flfl
/ 400
nno"Â97/
• UUU_J*IZ
j>9U nn
T^^n • uu 0 9^;n9'^ .n4Qi n
U4y 1 .
1
i
RR9Q
oozy • nnn^î 40
UUUJ> a9k 1
TfiA nn
j>DU .uu D. J? -)
974 7^^ nfti QQ
•UD yy 1 . 9n97R
zuz / nnn9RS i
-?7n
J nn
/ u .uu
7 f^RRn . zy->o /
n77'^'^ . 91 R'ÎQ
z aj>y1
nnn9RSQ
.UUUZ!-)9y
?QA nn
joK) « uu ^1 R1Q nQRAn
.Uy94U . 9 j9
^'Sl 0
ft I
nnn99'=jft
"ôn uu
j)yu. nn Q . DUDU
y ^;n^n "^/t RXR
• J'4dJ>9 . D4o
1 1 . Z 9J J 1 •
nnm
uuu 1
qr"^
yi!>_>
/ nn . nn
'tuu uu 1 n RRQQ "^RSnA 4nRQ
1
. 979
Z / Z J> J
'^^ nnm DH J
.uuu !
A
t u • nn
\ n
1 uu •
400QO
4zoyo . f^RQ4
DO y4
1
1 . 9Q97Q
z yz / y • nnm
uuu JJ>H
'^'\a 1
Aic\
4Z nn
u .uu 1 A 9P1 . 4 ou y J 9nnQ7
. zuuy . J 490 1
nnm ni
•UUU u q 1 1
A~KC\
4 nn
j)u • uu 1 0 .4Dy / . SAl
!-)4 7n
/U 1 . 3 J /D / •uuuu /uu
440.00 19.0443 215
.61 .27841 .36215 .0000375
450.00 22.0549 .69316 .32458 .38806 .0000045
460.00 25.5543 .78569 .37627 .41543 -.0000293
470.00 29.6000 .89071 .43389 .44431 -.0000638
480.00 34.2535 1 .00927 .49792 .47473 -.0000992
490.00 39.5813 1 .14245 .56882 .50674 -.0001355
500.00 45.6545 1 .29139 .64709 .54038 -.0001728
510.00 52.5494 1 .45727 .73324 .57572 -.00021 13
520.00 60.3474 1.64134 .82781 .61278 -.0002510
530.00 . 69.1355 1.84488 .93134 .65161 -.0002920
178
1 6 53 5 111 1 A
T//1
1/
*ô1"h(^rm Ô(^hor"*a c
Density
1 -J Vi* 1 1 1 1 1 1 1
1 Z>\J \j \\J\
\
1sochor©
Pressure z Der \/ri+
V (J \/^ Hi^r" I1 \/?*+
Va
kg/m3
'-'Vi'l 1
1 1
r
1 L-'C/i 1
1
1
\icx
V t? Curvature
MPa ypa • m3 /k n MPa/K MD ^ /I/ 2
10.00 .6777 .94583 .06421 .001 99 •UUUUUU4

20.00 1.2859 .89739 .05752 .00423
30.00 1. 8294 .85109 .051 24 .00672
40.00 2.31 19 .80669 .04533 .00946 "• UUUU (Jo
50.00 2.7371 .76404 .03977 — nnnni qa
1
.01 245
60.00 3.1085 .72308 .03457 .01 566 UUUU^: / J
70.00 3.4298 .68384 .02976 . 0 908 1 — •UUUUJJO /
80.00 3.7050 .64639 .02537
90.00 3.9387 .61080 .021 44 — AAAAC7I
.02642
100.00 4.1353 .5771 .01 797 _ AAAA D"^ c;
.03029
110.00 4.2996 .54554 .01 496 — nnAiAA*^
.03425
120.00 4.4361 .51 595 .01 241 _ AAA 1 1 T K
130.00 4.5492 .48840 .01028 — AAA1 "KOQ
.04235
140.00 4.6429 .46286 .00853 _ AAA
,04645 "•UUU 1 yl c:0
150.00 4.7209 .43927 .0071
160.00
• \) j\j j\j "•UUU Dl
4. 7866 .41 754 . U JÔO "• UUU d3o
1 70.00 4.8428 .39760 .00525 . AAA 4Dy
" •UUUl ylCn1
180.00 4.8924 .37935 .00471 _ AAA D\ 0 "7 1

"•UUUl 01
190.00 4.9377 .36271 AAA1 AQQ

— •UUU
~ UOO
200.00 4.9810 .34760
1
0 71 fi"^ -• AAA
UUUU 00
A /oo "7
210.00 5.0242 .33392 AAA A A

"•UUUU4.54
220.00 5.0686 .321 56 .00455 _ UUUUU^
AAAAAT"?
"•
230.00 5.1154 .31041 A A A A "ZOT
. \JO^ OD • UUUU-59J
240.00 5.1654 .30039 DO'S? noi 1 A
250.00 •0000846
5.2208 .291 47 A A A 1 1 A"Z
• UUUl j>\j5
260.00 5.2846 .28368 .00693 n9Rf^
1
•UUUl /42
270.00 5.3609 .27712 .00842 1 OQ/IR A A AO 1 "Z *^
.00021 36
280.00 5.4550 .271 91 AAA 0 ^0
. 11 11 D04
f^fÂ
.0002452 /I
290.00 5.5735 .26824 .01 333 . li.^^^ AAAO"7A(C

. 1 \ J\J .UUUz /Uo
300.00 5.7246 .26633 .01 706 ^"^1 A AAOO A
310.00
. 1 1
.UUUzooO
5.9183 .26646 .02 87 A A AO AO
1 .
. 11 î-J J .uuuzy^y
320.00 6.1663 .26895 .02795 AAAOAO
330.00 6.4824 .27416 .03553 nnn9R/i q
. 1641
340.00 6.8825 .28253 .04481 nnno7o
. 1 7641 .uuuz / z 9r
350.00 7.3851 .29449 .05604 AAAOC/r-z
. 8970 1 .UUUZDuJ
360.00 8.0107 .31057 .06948 .20408 .uuuz j)oy
370.00 8.7829 .33131 .08539 AAAO 1 c:o
.21 956
380.00 9.7277 .35729 . 0404 AAA yi
A11
1 . £- -JDZ \} .UUUl
390.00 10.8739 .38915 . 1 2573 AAA CC~}
•UUUlDD \
400.00 12.2535 .42755 9 7-? no A A A 1 4U5

AC
.UUUl it
410.00 13.9014 .47322 . 7945 A A A 1 1 dZ

TO
1 . ^ 1 •UUU 1
420.00 15.8559 .52691 .21 21 AAAAQ/I Q

.uuuuo4y
430.00 18.1588 .58940 .24919 .0000557
440.00 20.8555 .661 55 .29097 .36231 .0000256
450.00 23.9952 .74422 .33786 .38806 -.0000054
460.00 27.631 .83836 .39028 .41527 -.0000373
470.00 31 .8207 .94494 .44867 .44397 -.0000702
480.00 36.6259 .06497 .51348
1
.47422 -.0001041
490.00 42.1133 .19954 .58519
1
.50605 -.0001391
500.00 48.3542 .34976 .66428
1
.53951 -.0001752
510.00 55.4253 .51680 .75129
1
.57466 -.0002125
520.00 63.4081 .70190 .84673
1
.61 152 -.000251
179

Dens ty
i i Der ivati ve Curvature
kg/nn3 MPa MPa-niS/kg MPa A MPa A2
20.00 1 .3281 .90305 .05987 .00421 -.0000019
40.00 2,4050 .81800 .04817 .00935 -.0000091
60.00 3.2638 .73975 .03784 .01542 -.0000224
80.00 3.9294 .66795 .02898 .02222 -.0000407
100.00 4.4344 .60304 .02182 .02957 -.0000617
120.00 4.8137 .54552 .01640 .03731 -.0000809
140.00 5.1012 .49551 .01260 .04530 -.0000928
160.00 5.3270 .45277 .01020 '
.05351 -.0000920
180.00 5.5171 .41682 .00900 .05202 -.0000759
200.00 5.6941 .38717 .00887 .07104 -.0000454
220.00 5.8773 .36330 .00956 .08084 -.0000042
240.00 6.0802 .34452 .01087 .09175 .0000441
260.00 6.3202 .33057 .01342 .10413 .0000950
280.00 6.6314 .32208 .01814 .1 1848 .0001409
300.00 7.0678 .32038 .02614 .13533 .0001743
320.00 7.7077 .32755 ,03874 .15523 .0001902
340.00 8.5586 .34632 .05753 . 17867 ,0001882
360.00 10.0621 .38010 ,08432 ,20609 ,0001707
380.00 12.0984 .43297 .121 16 .23785 ,0001412
400.00 14.9907 .50965 .17032 .27429 ,0001025
420.00 19.0099 .61552 .23429 .31573 .0000568
440.00 24.4795 .75659 .31585 .36246 .0000053
460.00 31.7816 .93957 .41807 .41482 -.0000513
480.00 41.3627 1.17187 .54434 .47313 -.0001 128
500.00 53.7405 1.46165 .69840 .53774 -.0001794
520.00 69.5108 1.81785 .88428 .60901 -.0002512
20.00 1.3701 .90830 .06220 .00419 -.0000017

40.00 2.4992 .82844 .05096 ,00928 -.0000079
60.00 3.4169 .75509 .04103 .01521 -.0000187
80.00 4.1497 .68776 .03249 .02185 -.0000331
100.00 4.7273 .62580 .02556 .02903 -.0000485
120.00 5.1832 ,57270 .02030 ,03651 -.0000514
140.00 5.5500 .52563 .01663 .04451 -.0000683
160.00 5.8580 .48545 .01438 .05273 -.0000663
180.00 6.1339 .45183 .01341 .06138 -.0000543
200.00 6.4024 .42445 .01363 .07055 -.0000332
220.00 5.6855 .40293 .01481 .08080 -.0000051
240.00 6.9995 .38670 .01676 .09210 .0000278
260.00 7.3657 .37563 ,02017 .10490 .0000628
280.00 7.822^ .37042 ,02599 .1 1964 .0000956
300.00 8.4288 .37253 ,03534 .13678 ,0001213
320.00 9.2684 .38403 .04956 .1 5683 ,0001360
340.00 10.4538 .40767 .07019 .18028 ,0001378
360.00 12.1307 .44679 .09904 .20755 ,0001270
380.00 14.4833 .50536 ,13811 .23907 ,0001050
400.00 17.7382 .58798 .18966 .27517 ,0000736
420.00 22. 1695 .69988 .25619 .31618 .0000344
440.00 28.1041 .84690 '
.34047 .35243 -.00001 14
460.00 35.9271 1.03557 .44557 .41425 -.0000631
480.00 46.0882 1.27310 .57489 .47197 -.0001202
500.00 59.1089 1.56747 .73217 .53593 -.0001828
180
1 1
Pro pa n e Isotherm at 420 K

i i Der vati ve
i Curvature
kg/m3 MPa MPa .m3/kg MPa/K MPa/K-^
20.00 1 .4535 .91774 .06680 .00416 -.0000013

40.00 2.6834 .84712 .05641 .00914 -.0000060
60.00 3.7178 .78245 .04723 .01489 -.0000138
80.00 4.5808 ,72306 .03929 .02129 -.0000235
100.00 5.2994 .66919 .03283 .02823 -.0000332
120.00 5.9047 .62136 .02796 .03561 -.0000407
140.00 6.4284 .57983 .02467 .04341 -.0000442
160.00 6.9013 .54467 .02286 .05168 -.0000425
180.00 7.3522 .51579 .02248 .06052 -.0000353
200.00 7.8097 .49309 .02349 .0701 -.0000231
220.00 8.3002 .47642 .02573 .08067 -.0000070
240.00 8.8458 .46543 .02904 .09248 .0000120
260.00 9.4739 .46013 .03415 . 10581 .0000321
280.00 10.2307 .46139 .04210 .12105 .0000514
300.00 1 .1843
1 .47078 .05404 .13860 .0000671
320.00 12.4276 .49042 .07131 .15889 .0000768
340.00 14.0824 .52303 .09545 .18239 .0000787
360.00 16.3032 .57187 .12823 .20950 .0000719
380.00 19.2822 .64076 .17161 .24065 .0000564
400.00 23.2533 .73409 .22783 .27620 .0000326
420.00 28.4976 .85681 .29937 .31651 .0000012
440.00 35.3486 1.01448 .38899 .361 93 -.0000370
460.00 44.1981 1.21331 .49976 .41279 -.0000814
480.00 55.5027 1.46015 .63510 .46944 -.0001317
500.00 69.7906 1.76259 .79874 .53222 -.0001879
20.00 1.5778 .92977 .07360 .00413 -.0000010

40.00 2.9552 .87074 .06435 .00899 -.0000042
60.00 4 . 1 590 .81697 .05620 .01455 -.0000094
80.00 5.2103 .76761 .04913 .02072 -.0000156
100.00 6.1334 .72288 .04342 .02743 -.0000216
120.00 6.9573 .68332 .03924 .03464 -.0000261
140.00 7.7138 .64939 .03668 .04236 -.0000282
160.00 8.4352 .62135 .03573 .05066 -.0000275
180.00 9.1539 .59937 .03643 .05965 -.0000238
200.00 9.9036 .58361 .03881 .06951 -.0000175
220.00 10.7170 .57413 .04276 .08043 -.0000091
240.00 11.6234 .57080 .04817 .09265 .0000007
260.00 12.6589 .57383 .05585 .10642 .000011
280.00 13.8798 .58424 .06690 .12208 .0000209

300.00 15.3655 .60365 .08254 .13996 .0000286
320.00 17.2212 .63427 .10414 .16046 .0000329
340.00 19.5812 .67877 .13325 .18397 .0000324
360.00 22.6127 .74031 .17159 .21090 .0000261
380.00 26.5196 .82252 .22114 .24164 .0000136
400.00 31.5475 .92954 .28407 .27656 -.0000054
420.00 37.9881 1 .06601 .36286 .31603 -.0000307
440.00 46.1856 1.23713 .46024 .36041 -.0000622
460.00 56.5421 1 .44869 .57930 .41005 -.0000996
480.00 69.5247 1.70710 .72344 .46531 -.0001427
181

Dens ty
i 1 Der ivat ve i Curvature
kg/m3 MPa MPa .nn3/kg MPa/K MPa/K^
20.00 1.7830 .94565 .08473 .00409 -.0000006

40.00 3.4002 .90168 .07719 .00882 -.0000026
60.00 4.8766 .86212 .07059 .01418 -.0000057
80.00 6.2300 .82604 .06493 .02012 -.0000093
100.00 7.4823 .79367 .06054 .02660 -.0000127
120.00 8.6621 .76568 .05771 .03364 -.0000155
140.00 9.8023 .74268 .05661 .04127 -.0000171
160.00 10.9390 .72521 .05738 '
.04958 -.0000174
180.00 12.1 108 .71368 .06015 .05868 - -.0000164
200.00 13.3590 .70851 .06504 .06873 -.0000143
220.00 14.7262 .71002 .07200 .07992 -.00001 13
240,00 16.2522 .71830 .08100 .09244 -.0000079
260.00 17.9859 . 73378 .09296 .10653 -.0000044
280.00 19.9982 .75760 .10906 .12248 -.0000016
300.00 22.3847 .79147 .13061 .14057 -.0000000
320.00 25.2683 .83759 .15902 .16^15 -.0000006
340.00 28.8019 .89856 .19588 .18455 -.0000042
360.00 33. 71 1 .97739 .24294 .21114 -.00001 13
380.00 38.6002 1.07749 .30213 .24129 -.0000226
400.00 45.3520 1.20266 .37563 .27535 -.0000384
420.00 53.7371 1.35716 .46589 .31370 -.0000589
440.00 64.1 173 1.54571 .57563 .35667 -.0000844
20.00 1 .9867 .95788 .09569 .00406 -.0000004

40.00 3.8386 ,92539 .08968 .00872 -.0000018
60.00 5.5794 .89671 .08453 .01395 -.0000039
80.00 7.2257 .87097 .08027 .01974 -.0000063
100.00 8.7985 .84844 .07726 .02608 -.0000086
120.00 10.3270 .82986 .07589 .03300 -.0000107
140.00 1 .8468
1 .81599 .07643 .04055 -.0000121
160.00 13.3982 .80749 .07909 .04883 -.0000130
180.00 15.0258 .80497 .08408 .05795 -.0000132
200.00 16.7784 .80897 .09161 .06805 -.0000129
220.00 18.7073 .81997 .10168 .07932 -.0000124
240.00 20.8623 .83823 .11431 .09193 -.00001 17
260.00 23.3036 .86429 .13052 .10612 -.00001 13
280.00 26.1151 .89939 .15155 .12212 -.00001 16
300.00 29.4069 .94524 .17878 .14021 -.0000129
320.00 33.3174 1.00400 .21368 .16069 -.0000158
340.00 38.0160 1.07820 .25788 .18387 -.0000209
360.00 43.7061 1.17072 .31314 .21009 -.0000286
380.00 50.6282 1.28476 .38142 .23969 -.0000394
400.00 59.0642 1.42389 .46490 .27301 -.0000537
420.00 69.3419 1.59206 .56602 .31039 -.0000717
182
1 1 1 3
0

Density Pressure Z Der vat vei i Der vat ve
i i Curvature
kg/m-> NPa MPa .rrp/ kg MPa/K MPa/K^
20.00 2. 1893 .95760 . 10653 .00404 -.0000003

40.00 4.2724 .94414 . 101 95 .00864 -.000001
60.00 6.2725 .92409 .098 18 .01378 -.0000028
80.00 8.2055 .90665 .09529 .01947 -.0000046
100.00 10.0927 .89214 .09369 .02571 -.0000064
120.00 1 .9648
1 .88135 .09385 .03254 -.0000081
140.00 13.8605 .87514 .09610 .04002 -.0000095
160.00 15.8246 .87425 .10073 .04825 -.0000106
180.00 17.9076 .87940 . 10803 .05734 -.00001 14
200.00 20.1653 .89125 .1 1825 .06743 -.0000121
220.00 22.6576 .91036 .13145 ,07869 -.0000128
240.00 25.4434 .93710 .14771 .09130 -.0000135
260.00 28.5936 .97212 .16811 .10546 -.0000147
280.00 32.2042 1.01666 .19397 .12140 -.0000165
300.00 36.3982 1.07246 .22670 .13939 -.0000192
320.00 41 .3284 1 . 14162 .26786 .1 5969 -.0000233
340.00 47. 1796 1.22659 .31908 ,18260 -.0000291
360.00 54. 1709 1 .3301 .38219 .20843 -.0000370
380.00 62.5595 1 .45524 .459 15 ,23749 -.0000474
20.00 2.391 .97549 . 1 1 730 ,00403 - .0000002

40.00 4.7029 .95934 . 1 1 406 ,00858 -.000001
60.00 6.9585 .94630 . 1 1 1 62 ,01 366 -.0000022
80.00 9. 1737 .93566 . 008
1 1 ,01 927 -.0000036
100.00 1 .3707
1 .92779 . 0990
1 .02542 -.0000050
120.00 13.5823 .92353 .11161 .032 18 -,0000055
140.00 15.8504 .92379 . 1 1 561 .03959 -,0000078
160.00 18.2244 .92938 . 2226
1 ,04776 -,0000091
180.00 20.7606 .94109 .13189 ,05680 -,0000102
200.00 23.5220 .95963 .14482 ,06684 -,00001 14
220.00 26.5760 .98566 .161 14 .07805 -,0000127
240.00 29.9908 1.01962 .18100 .09060 -,0000143
260.00 33.8473 1 .06221 .20554 .10468 -,0000162
280.00 38.2525 1.1 1471 .23612 .12051 -,0000188
300.00 43.3420 1.17883 .27422 .13834 -,0000223
320.00 49.2819 1.25661 .32143 .15842 -,0000270
340.00 56.2712 1.35042 .37945 .18103 -.0000331
360.00 64.5440 1.46290 .4501 .20646 -.0000409
183

i i Der vat! ve
i Curvature
kg/ m3 NPa MPa -m^/kg Wa/K MPa/K^
20.00 2.5922 .98202 .12800 .00402 -.0000002

40.00 5.1309 .971 88 .12604 .00854 -.0000008
60.00 7.6391 .96465 .12490 .01356 -.0000017
80.00 10.1329 .95967 .12468 .0191 -.0000029
100.00 12.6360 .95739 .12592 .02520 -.0000041
120.00 15.1834 .95866 .12920 .03188 -.0000054
140.00 17.8206 .96443 .13497 .03923 - .0000067
160.00 20.601 .97556 .14364 .04733 -.0000080
180.00 23.5881 .99288 .15561 .05631 -.0000094
200.00 26.8501 1 .01 71 .17123 .06629 -.0000108
220.00 30.4627 1 .04912 . 1 9066 .07742 -.0000125
240.00 34.5027 1 .08923 .21408 .08988 -.00001 44
260.00 39.0606 1 .1 3826 .24268 .10385 -.0000168
280.00 44.2541 1 .19749 .27789 .1 1954 -.0000198
300.00 50.2304 1 .26859 .32123 .1 3718 -.0000237
320.00 57.1685 1 .35358 .37434 .1 5703 -.0000286
340.00 65.2806 1 .45473 .43894 .17933 -.0000347
184
1 1
Table 19. The Joule-Thomson inversion locus for propane.
Temp. Dens ty i Pressure

K kg/in3 MPa
300 491. 1 .607

310 485.4 4.875
320 479.8 7.952
330 474.2 10.847
340 468.6 13.574
350 463.1 16.143
360 457.7 18.564
370 452.3 20.848
380 447.0 23.001
390 441.7 25.030
400 436.5 26.945
410 431.4 28.749
420 426.3 30.449
430 421.2 32.051
440 416.2 33.558
450 41 1 .3 34.976
460 406.3 36.309
470 401.5 37.561
480 396.7 38.734
490 391.9 39.835
500 387.2 40.862
510 382.5 41.823
520 377.9 42.716
530 373.3 43.549
540 368.7 44.319
550 364.1 45=031
560 359.6 45,688
570 355.2 46.289
580 350.7 46.839
590 346.3 47.337
600 341.9 47.787
610 337.5 48.191
620 333.2 48.548
630 328.8 48.862
640 324.5 49.132
650 320.3 49.363
660 316,0 49.552
670 311.7 49.705
680 307.5 49.819
690 303.3 49.899
700 299.1 49.945
710 294 .9 49.957
720 290.8 49.940
730 286.6 49.892
740 282.5 49.814
750 278.4 49.71
760 274.4 49.582
770 270.3 49.430
780 266.3 49.255
790 262.3 49.060
800 258.4 48.846
810 254.4 48.615
185
51 1 1
Table 20. Thermophys ica I properties of saturated liquid propane.

1 sochore 1 sotherm
Temp. Pg P £ ^9 dP(j/dT dPg^/dT Der vati ve
i Der vat i i vi
K MPa kg/in3 MPa/K kn/f m3.K MPa ,m3 /kn

85.470 .16895E-09 733.34 .10484E-07 .00000 1.00000 .6882E--10 -1.031 3,1063 ,3013E+01
90.000 .96854E-09 728.67 .57076E-07 .00000 1.00000 ,3532E--09 -1 .0274 2,9784 .2899E+01
95.000 .54123E-08 723.55 .30216E-06 .00000 1.00000 , 1757E--08 -1.0237 2,8469 ,2781 E+01
100.000 .25139E-07 718.44 .13333E-05 .00000 1.00000 ,7304E.-08 -1.0205 2,7243 .2670E+01
105.000 .99697E-07 713.34 .50358E-05 .00000 1.00000 ,2605E--07 -1 .0178 2,6096 .2564 E+01
110.000 .34511E-05 708.26 .16639E-04 .00000 1.00000 .8145E--07 -1.0156 2.5020 .2464E+01
115.000 .10618E-05 703.18 .48970E-04 .00000 1.00000 .2273E--06 -1 .0140 2.4007 .2368E+01
120.000 .29480E-05 698.12 .13030E-03 .00000 .99999 .5744E--06 -1.0128 2.3051 .2276E+01
125.000 .74804E-05 693.06 .31740E-03 .00000 .99998 ,1 33 E--05
1 -1 .0122 2,2145 .2188E+01
130.000 .17534E-04 687.99 .71538E-03 .00000 .99996 ,2859E'-05 -1 .0121 2,1287 .2103E+01
135.000 .38315E-04 682.93 . 15054 E-02 .00000 .99992 .5742E--05 -1 .0126 2,0471 .2022 E+01
140.000 .78671E-04 677.87 .29807E-02 ,00000 .99985 ,1087E--04 -1.0136 1,9694 . 1943E+01
145.000 .15279E-03 672.80 .55902E-02 .00001 .99974 . 1950E--04 -1.0152 1,8952 ,1867E+01
150.000 .28235E-03 667.72 .99876E-02 .00001 .99957 .3337E--04 -1 .0174 1,8243 . 1793E+01
155.000 .49897E-03 662.62 . 17085E-01 .00003 .99932 .5475E--04 -1 .0203 1,7565 .1722E+01
160.000 .84700E-03 657.51 .28105E-01 .00004 .99896 .8646E'-04 -1 .0237 1,6915 . 1652E+01
165.000 .13864E-02 652.38 .44633E-01 .00007 .99847 . 1319E--03 -1.0278 1,6290 , 1585E+01
170.000 .21959E-02 647.23 .68659E-01 .0001 .99781 . 1952E--03 -1.0326 1.5690 ,1519E+01
175.000 .33756E-02 642.06 . 10262 E+00 .00016 .99695 ,2808E--03 -1 .0381 1.51 12 ,1455E+01
180.000 ,50497E-02 636.85 .14941 E+00 ,00023 .99585 ,3938E--03 -1 .0443 1.4555 ,1393 E+01
185.000 .73689E-02 631.61 .21243E+00 .00033 .99447 ,5398E--03 -1.0513 1.4018 ,1333 E+01
190.000 .10512E-01 626.33 .29556E+00 .00047 .99279 ,7244E--03 -1 .0591 1.3499 , 1274E+01
195.000 .14687E-01 621.02 .40319E+00 .00054 .99076 .9536E--03 -1 .0677 1.2997 .1216E+01
200,000 .20133E-01 615.66 .54018E+00 .00087 .98835 ,1234E--02 -1.0771 1,2512 ,1 160E+01
205.000 .27119E-01 610.25 .71 191E+00 .001 15 .98552 .1571E--02 -1 .0875 1,2042 .1106E+01
210.000 .35944E-01 604.78 .92419E+00 .00150 .98223 . 1970E--02 -1.0988 1,1585 .1053E+01
215.000 .46937E-01 599.26 . 11833E+01 .00193 .97847 .2439E'-02 -1.1111 1, 143 1 ,1001 E+01
220.000 .60455E-01 593.67 .14961E+01 .00245 ,97418 .2982E--02 -1.1246 1.0713 .9500E+00
225.000 .76884E-01 588.01 . 18696E+01 .00308 .96935 .3604E--02 -1 . 1391 1.0295 ,9006E+00
231.068 .10133E+00 581.04 .24158E+01 .00400 .96270 .4473E--02 -1.1584 .9803 ,8424E+00
235.000 .12014E+00 576.46 .28305E+01 .00470 .95791 .5106E--02 -1.1720 .9493 ,8056E+00
240.000 .14785E+00 570.55 .34347E+01 .00573 .95125 .5995E--02 -1 . 1905 .9107 .7599E+00
245.000 .18025E+00 564.55 .41338E+01 .00691 .94393 .698 IE--02 -1 .2106 ,873 1 .7155E+00
250.000 .21783E+00 558.44 .49376E+01 .00828 .93593 .8068E--02 -1.2323 ,8364 .6722E+00
255.000 .26111E+00 552.22 .58570E+01 .00983 .92720 .9259E--02 -1 .2559 ,8006 .6301 E+00
260.000 .31060E+00 545.88 .69037E+01 .01 161 .91774 .1056E--01 -1.2815 ,7656 .5892E+O0
265.000 .36685E+00 539.41 .80903E+01 .01361 .90752 .1196E--01 -1 .3093 ,7314 .5495E+00
270.000 .43042E+00 532.78 .94307E+01 .01587 .89651 .1348E--01 -1.3396 ,6979 .51 09 E+00
275.000 .50186E+00 526.00 . 10940E+02 .01840 .88470 .1512E--01 -1.3727 .6651 .473 5E+00
280.000 .58177E+00 519.05 .12636E+02 .02123 .87206 ,1687E--01 -1 .4090 .6330 .4373E+00
285.000 .67072E+00 511.91 . 14537E+02 .02438 .85858 . 1873E--01 -1 .4489 .6015 .4022E+00
290.000 .76931 E+00 504.56 . 16665E+02 .02788 .84424 .2072E--01 -1 .4930 .5707 .3683E+00
295.000 .87816E+00 496.97 .19045E+02 .03177 .82900 .2284E--01 -1.5420 .5403 .3356E+00
300.000 .99790E+00 489.13 .21704E+02 .03607 .81284 .2508E--01 -1 .5966 .5106 .3041 E+00
305.000 .11292E+01 480.99 .24676E+02 .04082 .79573 .2745E--01 -1,6581 .4813 .2737E+00
310.000 .12726E+01 472.53 .27999E+02 .04608 .77762 .2995E--01 -1 ,7278 .4525 ,2445E+00
315.000 .14289E+01 463.70 .31720E+02 .05188 .75845 .3259E--01 -1 ,8078 .4241 ,2166E+00
320.000 .15988E+01 454.43 .35898E+02 .05831 .73814 .3538E--01 -1 ,9004 ,3960 .1898E+00
325.000 .17829E+01 444.67 .40603E+02 .06543 .71658 .3831E--01 -2,0095 .3683 , 1642E+00
330.000 .19822E+01 434.30 .45931E+02 .07335 ,69358 .4141E--01 -2, 1403 .3409 .1399E+00
335.000 .21973E+01 423.21 .52006E+02 .08220 ,66892 .4468E--01 -2,3008 .3136 .1 169E+00
340.000 .24293E+01 411.22 .59004E+02 .0921 ,64224 .4815E--01 -2.5037 .2865 .9518E-01
345.000 .26792E+01 398.07 .67188E+02 .10347 ,61301 .5184E-01 -2,7709 ,2592 .7484E-01
350.000 .29482E+01 383.34 .76974E+02 .1 1654 .58039 .5579E--01 -3.1437 .2317 .5595E-01
355.000 .32377E+01 366.31 .89094E+02 .13205 .54292 .6009E--01 -3,71 16 ,2035 .3863E-01
360.000 .35498E+01 345.52 . 10505E+03 .15136 .49781 .6486E--01 -4,7195 .1738 .2308E-01
365.000 .38877E+01 316.85 .12901E+03 .17829 •
.43786 .7047E--01 -7,2322 ,1406 .9697E-02
369.850 .42475E+01 220.49 .22049E+03 .27625 .27625 .81 13E--01 ,0811 0.
186
I I I J
11 1 11 1

Heat of I nterna Fugac ty/ i Ve . of
I
Temp. Vap. Energy Enthalpy Entropy Cy Co Cp Pressure Sound D el ectr ic

I
K J/mo J/mo I J/mo J/(mol .K) J/(mol -I J/(mol .K) J/(mol .K) Rat io m/s Constant
85.470 24840.8 .0 .0 82.561 61.54 84.09 84.09 1 . uuuuu 9n97 2.09041
90.000 24627.8 391.5 391.6 87.074 51.43 84.30 84.30 1 .uuuuu yy^
1 2.08021
95.000 24397.6 822.9 822.9 91.767 61.22 84.54 84.54 1
1
onnnn
. uuuuu
1
1
Q
V \>y 2.06918
100.000 24172.3 1253.4 1253.4 96.197 61.05 84.80 84.80 1 .uuuuu 1Q9
yCJ^
1 2.05836
105.000 23951.6 1683.4 1683.4 100.397 60.89 85.05 85.05 1 nnnnn 1RQ9
\Oy £. 2.04772
110.000 23735.1 2113.2 2113.2 104.394 60.77 85.34 85.34 1
1
nnnnn
.uuuuu 1
1
Rfin
ODU 2.03725
115.000 23522.5 2543.0 2543.0 108.210 50.67 85.53 85.53 . nnnnn
uuuuu 2.02692
1
1
120.000 23313.3 2973.0 2973.0 111.854 60.59 85.94 85.94 1

\
nnnnn
. uuuuu 1 / y\j 2.01673
125.000 23107.3 3403.4 3403.4 115.374 60.54 86.26 86.25 1 nnnnn 1755 2.00656
130.000 22904.0 3834.6 3834.6 118.753 60.50 86.50 86.50 1 nnnno 1735 1.99670
135.000 22703.1 4266.9 4266.9 122.013 60.50 86.95 86.95 .99996 1704 1.98683
140.000 22504.2 4700.4 4700.4 125.165 60.51 87.33 87.33 .99988 1574 1.97705
145.000 22307.0 5135.5 5135.5 128.220 60.54 87.72 87.72 .99977 1544 1.95734
150.000 22111.0 5572.5 5572.5 131.185 60.60 88.14 88.14 .99958 1614 1.95769
155.000 21915.9 6011.8 6011.9 134.068 60.68 88.57 88.57 .9993 1585 1.94810
160.000 21721.4 6453.6 6453.6 136.877 50.77 89.03 89.03 .99891 1555 1.93855
165.000 21526.9 6898.0 6898.1 139.616 60.89 89.52 89.52 .99836 1526 1.92904
170.000 21332.2 7345.5 7345.6 142.292 61.03 90.03 90.03 .99760 1496 1.91955
175.000 21136.8 7795.2 7796.4 144.908 61.20 90.56 90.57 .99572 1467 1.91008
180.000 20940.4 8250.4 8250.7 147.471 51.38 91.13 91 .14 .99550 1438 1.90062
185.000 20742.4 8708.3 8708.8 149.983 61.59 91 .72 91 .74 .99409 1409 1 .891 17
190.000 20542.6 9169.9 9170.7 152.448 61.82 92.35 92.37 .99227 1379 1.88170
195.000 20340.4 9535.7 9635.7 154.870 62.07 93.01 93.03 QQCl 1 7 1.87222
200.000 20135.5 10105.6 10107.0 157.251 62.34 93.70 93.73 1.86272
205.000 19927.3 10579.9 10581.9 159.594 62.54 94.43 94.47 QR47n 1\ 9Q
£-y 1
\ 1.85319
210.000 19715.5 11058.6 11051.3 161.902 62.96 95.20 95.25 Qfi 1 9R 1 .84361
215.000 19499.6 11542.1 11545.5 164.177 63.31 96.00 95.07 1.83399
220.000 19279.0 12030.1 12034.6 166.421 53.69 96.85 96.94 1 9n9 1.82430
225.000 19053.3 12523.1 12528.9 168.535 64.09 97.74 97.86 1 1 79 1.81455
231.068 18771.8 13128.2 13135.9 171.288 64.61 98.88 99.04 Qfi 1 7fi 1
1
1
1
'^f,
_>D 1.80261
235.000 18584.5 13524.2 13533.4 172.987 54.97 99.66 99.85 J 1 1 -> 1119
111^ 1.79481
240.000 18340.2 14032.5 14043.9 175.125 55.45 100.70 100.93 QSn77 1
I
nR9
uoz 1.78479
245.000 18088.6 14545.1 14550.2 177.242 55.97 101 .79 102.08 OA ZQ9 1 n'i9 1.77467
250.000 17828.9 15055.4 15082.6 179.339 65.51 102.95 103.30 1
1
n9
uz 1 1.76442
255.000 17560.7 15590.1 15611.0 181.416 67.09 104. 16 104.59 • yi-O to QQ
yy 1
1 1.75403
260.000 17283.0 16120.7 16145.8 183.476 67.69 105.44 105.97 ^DU 1.74349
265.000 16995.2 16657.3 15687.3 185.519 68.34 106.80 107.44 • y 1 1 / J Q9Q
yZ.y 1.73279
270.000 16696.4 17200.0 17235.6 187.547 59.02 108.23 109.00 RQR 1.72191
275.000 16385.7 17749.1 17791.1 189.563 69.73 109.75 110.68 QQ9RQ ODD 1.71082
280.000 16062.1 18304.7 18354.2 191.566 70.48 1 1.36
1 112.48 OD J 1.69951
285.000 15724.5 18867.3 18925.1 193.550 71.28 113.08 114.42 P.17AA Rn'^
OUJ? 1.68795
290.000 15371.6 19437.3 19504.5 195.544 72.11 1 14.91 116.52 Rfil 7/
.00 1
1 77
/ / 1 1.6761
295.000 15001.9 20014.9 20092.8 197.523 72.99 116.87 1 18.81 .0 D 1 / yy 1.66397
300.000 14613.9 20600.7 20690.6 199.496 73.91 118.99 121.32 • ODy ^.Z. 1 uo 1.65149
305.000 14205.6 21195.3 21298.8 201.468 74.88 121.27 124.08 1.63862
310.000 13774.8 21799.6 21918.3 203.440 75.90 123.76 127. 15 R SfiA
1
DHL/ 1.62531
315.000 13318.6 22414.5 22550.4 205.417 76.97 125.50 130.52 . OUJ J 1.61 150
320.000 12833.7 23041.1 23196.2 207.401 78.10 129.53 134.58 7Q 9n 1
J 1 1.5971
325.000 12315.9 23680.9 23857.7 209.397 79.29 132.94 139.17 • II 0\jy 1.58204
330.000 11759.6 24336.0 24537.2 211.412 80.54 136.83 144.61 . 1 K>\J\J C. sni 1.55615
335.000 11157.5 25008.8 25237.8 213.454 81.86 141.38 151.27 464 1.54930
340.000 10499.3 25703.0 25963.5 215.532 83.26 145.85 159.69 .74024 427 1.53122
345.000 9769.9 25423.6 26720.4 217.663 84.74 153.70 170.94 .72714 388 1 .51 156
I 350.000 8945.7 27178.4 27517.6 219.870 86.32 152.81 187.08 .71383 348 1.48975
j
355.000 7985.7 27981.5 28371.2 222.195 88.01 176.11 213.03 .70027 305 1.46483
I
360.000 6806.1 28861.6 29314.7 224.725 89.85 198.91 263.85 .68637 260 1.43480
365.000 5175.8 29903.9 30444.9 227.718 91.80 254.84 418.67 .57194 210 1.39412
,
369.850 0.0 32232.7 33082.2 234.726 .65558 0 1.25352
187
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244
. —
NBS-n4A (REV. 2-8C)

U.S. DEPT. OF COMM. 1. PUBLICATION OR 2. Performing Organ. Report No. 3. Publication Date
REPORT NO.
BIBLIOGRAPHIC DATA
SHEET (See insiructions) NBS Monogr. 170 April 1982
4. TITLE AND SUBTITLE
THERMOPHYSICAL PROPERTIES OF PROPANE- FROM 85 TO 700 K AT PRESSURES TO 70 MPa
5. AUTHOR(S)
6. PERFORMING ORGANIZATION (If joint or other than NBS. see instructions] 7. Contract/Grant No.
NATIONAL BUREAU OF STANDARDS

DEPARTMENT OF COMMERCE 8. Type of Report & Period Covered
WASHINGTON, D.C. 20234
Final
9. SPONSORING ORGANIZATION NAME AND COMPLETE ADDRESS (Street. City. State, ZIP)
Same as No. 6
10. SUPPLEMENTARY NOTES
Library of Congress Catalog Card Number: 82-600514
I I
Document describes a computer program; SF-185, FIPS Software Summary, is attached.
11. ABSTRACT (A 200-word or less factual summary of most significant information. If document includes a significant
bi bl iography or literature survey, mention it here)
Thermophysical properties of propane are tabulated at integral temperatures over the

entire range of fluid states from 85 to 700 K along isobars to 70 MPa by using a
modified form of the nonanalytic equation of state. These tables, along with a table
for the saturated liquid, include values for density, compressibility factor,
internal energy, enthalpy, entropy, heat capacities, fugacity, sound velocity,
dielectric constant, and isochore and isotherm derivatives. In addition to the
equation of state, equations are presented for vapor pressures, orthobaric vapor and
liquid densities, ideal gas properties, virial coefficients, dielectric constants,
heats of vaporization, melting pressures, and orthobaric liquid specific heats,
enthalpies, and entropies. Coefficients were determined by a least squares fit of
selected experimental data, including several new sets of data not included in
previous propane correlations. Comparisons between experimental and calculated
values are given, including those for sound velocities, heat capacities, P-P-T data,
etc
12.KEY WORDS (Six to twelve entries; alphabetical order; capitalize only proper names; and separate key words by semicolons)
Densities; dielectric constants; enthalpies; entropies; equation of state; fugaci-
ties; internal energies; isobars; isochores; isotherms; Joule-Thomson inversion;
latent heats of vaporization; melting line; orthobaric densities; propane; specific
heat s vapor pr e ssur e s;—velocitieo of sound.
;
ISrAVAlLABTlTlTY 14. NO. OF

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Thermophysical Properties of Propane, National Bureau of Standars.

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Thermophysical Properties of Propane, National Bureau of Standars.

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NATL INST OF STANDARDS & TECH R.I.C.

U.S. DEPARTMENT OF COMMERCE/National Bureau of Standards

THE NATIONAL MEASUREMENT LABORATORY provides the national system of

Absolute Physical Quantities' — Radiation Research — Thermodynamics and

Applied Mathematics — Electronics andElectrical Engineering^ — Mechanical

THE INSTITUTE FOR COMPUTER SCIENCES AND TECHNOLOGY conducts

Programming Science and Technology — Computer Systems Engineering.

'Headquarters and Laboratories at Gaithersburg, MD, unless otherwise noted;

Thermophysical Properties of Propane 29 (33?

from 85 to 700 K at Pressures to 70 MPa ^

Robert D. Goodwin and William M. Haynes

Thermophysical Properties Division

Demco, Inc. 38-293

U.S. DEPARTMENT OF COMMERCE, Malcolm Baldrige, Secretary

Issued April 1982

National Bureau of Standards Monograph 170

U.S. GOVERNMENT PRINTING OFFICE

2. Physical Properties and Their Formulation . ; . , 7.

?.l Fixed-Point Values 2

2.2 Melting Line and Vapor Pressures 3

2.3 The Orthobaric Densities 3

2.4 The Virial Equation 4

2.5 The Equation of State ..... 5

2.6 The Ideal Gas Functions 8

2.7 Thermal Loop Computations 8

2.8 The Heats of Vaporization 9

2.9 Saturated Liquid Enthalpies and Entropies 9

2.10 Dielectric Constants 10

3.1 The Homogeneous Domain 11

3.2 The Saturated Liquid 12

3.3 The Compressed Liquid 13

3.4 Fugacity Coefficients 13

3.5 Simplified Computation 13

4. Tests and Comparisons 13

4.1 Specific Heats 14

4.2 Sound Velocities 14

5. Tables of Physical and Thermodynamic Properties 14

5.1 Calculated P-p-T Isochores and Isotherms 14

5.2 The Joule-Thomson Inversion Locus 15

5.3 Thermophysical Properties of the Saturated Liquid 15

5.4 Thermophysical Properties Along Selected Isobars 15

APPENDIX A. Symbols and Units 26

APPENDIX B. Conversion of Units 28

APPENDIX C. Fixed-Point Values for Propane 29

APPENDIX D. Propane Properties Reference Index 30

APPENDIX E. Computer Program 35

Figure 1. Density-temperature diagram of propane 54

Table 2. Comparisons of saturated liquid density data with eq (3) . . 60

Table 3. Comparisons of saturated vapor density data with eq (4) . . 65

Table 4. Comparisons of virial coefficients with eq (5) 68

Table 5. Behavior of coefficients of equation of state for

Table 6. Calculated P(p) critical isotherm of propane 72

Table 7. Comparisons of experimental P-p-T data of propane with

Table 9. Interpolated ideal gas functions from eq (7) 125

Table 10. Comparisons of heat of vaporization data with eq (9) . . . . 126

Table 12. Entropies and specific heats of saturated liquid propane

Table 15. Comparisons with C and C data 139

Table 18. Calculated P(p) isotherms of propane 164

Thermophysical properties of propane are tabulated at integral

Key words: Densities; dielectric constants; enthalpies; entropies;

2. Physical Properties and Their Formulation

2.1 Fixed-Point Values

critical density was derived by the liquid volume fraction procedure of

2.2 Melting Line and Vapor Pressures

P = P^(p) + p^-R-[T - T^(p)] + p^ RT^-F(p,T) , (6)

CMF = + A2P^ + A3-p^ + A^£n (1 + 1/x) + A^-P/10 (12b)