Carbon-Supported KCoMoS2 for Alcohol Synthesis from Synthesis Gas
Abstract
:1. Introduction
2. Results
2.1. Characterization
2.1.1. Elemental Analysis and KCoMoS2 Particle Size
2.1.2. Textural Characteristics
2.1.3. Acidity
2.2. Catalytic Experiments
3. Discussion
4. Materials and Methods
4.1. Preparation of Catalysts
4.2. Physical Characterization
4.2.1. Textural Properties
4.2.2. Elemental Composition
4.2.3. Acidic Properties
4.3. Catalytic Experiments
5. Conclusions
Supplementary Materials
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Content (wt%) | Molar Ratio | Average Slab | |||||
---|---|---|---|---|---|---|---|
Catalyst | Mo | K | Co | r 1 | t 2 | Length (nm) | Stacking (Layers) |
KCoMoS2/Al2O3 | 15.8 | 10.2 | 5.1 | 0.34 | 1.03 | 6.6 | 1.6 |
KCoMoS2/CCA | 14.4 | 11.6 | 4.7 | 0.34 | 1.30 | 11.7 | 3.8 |
KCoMoS2/AG-3 | 14.9 | 12.3 | 5.7 | 0.39 | 1.24 | 17.0 | 2.8 |
KCoMoS2/BAW | 14.8 | 12.0 | 5.2 | 0.36 | 1.27 | 24.5 | 3.2 |
Sample | Stotal, m2/g | Smicro, m2/g | Smeso 1, m2/g | Vtotal, cm3/g | Vmicro, cm3/g | Vmeso 2, cm3/g | Acidity 3, mmol/g |
---|---|---|---|---|---|---|---|
Al2O3 | 161 | 0 | 161 | 0.65 | 0.00 | 0.65 | 286 |
KCoMoS2/Al2O3 | 91 | 0 | 91 | 0.29 | 0.00 | 0.29 | 44 |
CCA | 156 | 13 | 143 | 0.63 | 0.01 | 0.63 | 4 |
KCoMoS2/CCA | 73 | 0 | 73 | 0.26 | 0.00 | 0.26 | 12 |
AG-3 | 854 | 753 | 101 | 0.45 | 0.35 | 0.10 | 4 |
KCoMoS2/AG-3 | 164 | 137 | 27 | 0.09 | 0.06 | 0.03 | 9 |
BAW | 753 | 642 | 111 | 0.39 | 0.26 | 0.13 | 0 |
KCoMoS2/BAW | 404 | 365 | 40 | 0.23 | 0.16 | 0.07 | 7 |
Catalyst | GHSV h−1 | p MPa | T °C | Conv % | Tot Liq Sel % | Ref |
---|---|---|---|---|---|---|
KCoMoS2/Al2O3 | 760 | 5 | 340 | 23 | 48 | [29] |
KCoMoS2/CCA | 760 | 5 | 340 | 19.2 | 65 | [25] |
KCoMoS2/MWCNT | 1200 | 8.3 | 320 | 25 | 40 | [6] |
KCoMoS2/AC-CGP 1 | 1200 | 8.3 | 330 | 44.5 | 27.5 | [30] |
KCoMoS2/AC-RX3 2 | 1200 | 8.3 | 330 | 39.6 | 25.8 | [30] |
KCoMoS2/AC-Darco 3 | 1200 | 8.3 | 330 | 35.6 | 24.8 | [30] |
KCoMoS2/Al2O3 | 760 | 5 | 360 | 30.3 | 69.2 | current 4 |
KCoMoS2/CCA | 760 | 5 | 360 | 36.4 | 71.2 | current 4 |
KCoMoS2/AG-3 | 760 | 5 | 360 | 42.3 | 75.1 | current 4 |
KCoMoS2/BAW | 760 | 5 | 360 | 43.0 | 75.7 | current 4 |
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Osman, M.E.; Maximov, V.V.; Dorokhov, V.S.; Mukhin, V.M.; Sheshko, T.F.; Kooyman, P.J.; Kogan, V.M. Carbon-Supported KCoMoS2 for Alcohol Synthesis from Synthesis Gas. Catalysts 2021, 11, 1321. https://doi.org/10.3390/catal11111321
Osman ME, Maximov VV, Dorokhov VS, Mukhin VM, Sheshko TF, Kooyman PJ, Kogan VM. Carbon-Supported KCoMoS2 for Alcohol Synthesis from Synthesis Gas. Catalysts. 2021; 11(11):1321. https://doi.org/10.3390/catal11111321
Chicago/Turabian StyleOsman, Mohamed E., Vladimir V. Maximov, Viktor S. Dorokhov, Viktor M. Mukhin, Tatiana F. Sheshko, Patricia J. Kooyman, and Viktor M. Kogan. 2021. "Carbon-Supported KCoMoS2 for Alcohol Synthesis from Synthesis Gas" Catalysts 11, no. 11: 1321. https://doi.org/10.3390/catal11111321